determination of stability of blends with high percentage ...palm oil fractionation palm oil iv 52...

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Dr SIVARUBY KANAGARATNAM POFP 2017

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Page 1: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Dr SIVARUBY KANAGARATNAM

POFP 2017

Page 2: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Outline of Presentation

Palm Oil and its products Palm Kernel Oil and its products

APPLICATION IN FOOD

Page 3: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Fruit

Page 4: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

TWO Type Of Oil :

PALM KERNEL OIL

PALM FRUIT OIL

Page 5: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Fruit

Palm Oil (mesocarp)

Palm Kernel Oil

Page 6: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

TWO Type Of Oil :

PALM KERNEL OIL

4%/bunch

PALM FRUIT OIL

20-25%/ bunch

Page 7: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Page 8: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Milling

Palm Fruit

Crude Palm Oil

Page 9: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

REFINING

VIRGIN PALM OIL

RBD PALM OIL

Page 10: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters Quality

Iodine Value 50 to 55

Slip Melting

Point

36 to 38°C

Free Fatty Acids 5% Max

Colour 32 to 34 red

Dark red

Virgin

Palm Oil

Page 11: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters Quality

Iodine Value 50 to 55

Slip Melting

Point

36 to 38°C

Free Fatty Acids 0.1% Max

Colour 3 red

RBD

Palm Oil

Page 12: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

FRACTIONATION

RBD PALM OIL

RBD PALM

STEARIN

RBD PALM

OLEIN

Page 13: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

80% to 85% 15% to 20%

Palm Oil Fractionated to

Palm Olein and Palm Stearin

RBD

Palm Olein

RBD

Palm Oil

RBD

Palm Stearin

Page 14: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Oil & Fractions

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TEMPERATURE ( ⁰C )

Palm Oil Palm Stearin Palm Olein

Page 15: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Specification Of

Palm Oil Products

Iodine Value Slip Melting

point

( celcius)

RBD PALM OIL 50 to 52 37 to 39

RBD PALM OLEIN 56 to 57 23 to 24

RBD PALM

STEARIN

30 to 32 52 to 54

Page 16: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm kernel Oil

Page 17: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

CRUSHING

Palm Kernel Nuts

Crude Palm

Kernel Oil

Page 18: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

REFINING

CRUDE PALM KERNEL OIL

RBD PALM KERNEL OIL

Page 19: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

FRACTIONATION

RBD PALM KERNEL OIL

RBD PALM

KERNEL

STEARIN

RBD PALM

KERNEL OLEIN

Page 20: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Kernel Oil Fractionated to

Palm Kernel Stearin and Palm Kernel Olein

60% to 65% 35% to 40%

RBD

Palm Kernel

Olein

RBD

Palm Kernel

Oil

RBD

Palm Stearin

Page 21: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Kernel Oil Fractions

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TEMPERATURE (⁰C)

Palm Kernel Oil Palm Kernel Olein Palm Kernel Stearin

Page 22: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Specification Of

Palm Kernel Oil Products

Iodine Value Slip Melting

point

( celcius)

RBD PALM

KERNEL OIL

19 max 27 max

RBD PALM

KERNEL OLEIN

21 min 24 max

RBD PALM

KERNEL STEARIN

8 max 44 min

Page 23: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil Fractionation

Palm Oil IV 52

Palm Stearin IV 30-36 Palm Olein IV 56-60

Further Fractionated Further Fractionated

Page 24: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm oil-based Liquid Fractions

Page 25: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters

Iodine Value 56 min

Slip Melting

Point

24°C max

Cloud Point 10°C max

Free Fatty Acids 0.1 Max

Colour 3 red

PALM OLEIN IV 56

RBD

Palm Olein

IV 56

Page 26: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters

Iodine Value 58 min

Slip Melting

Point

21°C max

Cloud Point 8°C max

Free Fatty Acids 0.1 Max

Colour 3 red

PALM OLEIN IV 58

RBD

Palm Olein

IV 58

Page 27: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters

Iodine Value 60 min

Slip Melting

Point

19°C max

Cloud Point 6°C max

Free Fatty Acids 0.1 Max

Colour 3 red

PALM OLEIN IV 60

RBD

Palm Olein

IV 60

Page 28: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters

Iodine Value 62 min

Slip Melting

Point

17°C max

Cloud Point 5°C max

Free Fatty Acids 0.1 Max

Colour 3 red

PALM OLEIN IV 62

RBD

Palm Olein

IV 62

Page 29: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Quality Parameters

Iodine Value 64 min

Slip Melting

Point

15°C max

Cloud Point 4°C max

Free Fatty Acids 0.1 Max

Colour 3 red

PALM OLEIN IV 64

RBD

Palm Olein

IV 64

Page 30: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm oil –based Solid Fractions

Page 32: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Solid Fractions : BASED ON TAG COMPOSITION

Group Main TAG PERCENTAGE

PMF Soft

POP 40-60 %

Hard PMF

POP 65-75 %

Soft Stearin

PPP 5–15 %

Common Stearin PPP 15–20 %

Common Stearin PPP 20–30 %

Palm Stearin IV 20 PPP 40–50 %

Palm Stearin IV 14

PPP 55–60 %

Palm Stearin IV 12

PPP 60-63%

Palm Stearin IV 10

PPP 67-68%

Page 33: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Mid Fraction

Soft

Page 34: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

1 2 3 4 5 6 7 8

POO 19.29±0.48 16.59± 0.01 14.58 ±0.11 15.72 ±0.09 14.73 ± 0.05 15.75 ± 0.08 12.28±0.09 11.90±0.07

POP 43.53±0.19 45.6 ±0.12 48.27± 0.40 49.20 ± .16 49.33 ± 0.24 49.6 ± 0.16 51.5 ±0.22 55.95±0.10

PPP 0.69 ± 0.04 2.3± 0.04 2.26 ± 0.05 1.44 ± 0.01 1.49 ± 0.20 1.55±0.02 2.57 ± 0.04 0.76±0.04

TRISATURATED 2.45 ± 0.22 4.75 ± 0.12 4.72 ± 0.12 3.91 ± 0.06 3.44 ± 0.29 3.83±0.10 5.41±0.03 2.41 ± 0.07

DISATURATED 61.83±0.15 63.85 ± 0.16 67.15 ±0.11 68.21 ±0.13 69.16 ± 0.06 68.01 ± 0.06 71.55±0.17 80.07± 0.13

MONOSATURATED 30.56±0.23 26.79 ± 0.17 23.77 ±0.07 24.04 ±0.13 23.66 ± 0.35 24.25 ± 0.18 19.66±0.27 14.33± 0.12

TRIUNSATURATED 5.16 ± 0.44 4.61 ± 0.10 4.36 ± 0.11 3.84 ± 0.21 3.74 ± 0.00 3.91 ± 0.15 3.37±0.02 3.19 ± 0.23

IV 49.50 ± 0.13 45.83 ± 0.23 45.98 ±0.09 43.27 ±0.08 44.38 ± 0.17 45.18 ± 0.08 40.91±0.20 43.26±0.12

D. Point 23.4 ± 0.21 31.6 ± 0.14 31.8 ± 0.10 28.3 ± 0.21 28.0 ± 0.14 27.6 ± 0.14 32.5±0.10 25.4 ± 0.14

Triacylglycerol composition, iodine value and dropping point of

Palm Mid Fraction soft with 40 - 60% of POP content

Page 35: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of PMF (soft)

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TEMPERATURE (°C)

Page 36: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Mid Fraction

Hard

65 - 70% of POP content

Page 37: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

1 2 3 4 5

POO 5.79 ± 0.01 4.32 ± 0.87 3.35 ± 0.01 4.24 ± 0.02 0.14 ± 0.03

POP 65.41 ± 0.05 67.87 ± 0.55 68.02 ± 0.71 69.09 ± 0.2 74.84 ± 0.22

PPP 2.26 ± 0.01 2.36 ± 0.31 2.34 ± 0.01 2.14 ± 0.03 2.61 ± 0.03

TRISATURATED 4.33 ± 0.02 4.43 ± 0.49 4.41 ± 0.01 5.21 ± 0.07 4.83 ± 0.11

DISATURATED 84.79 ± 0.08 86.79 ± 0.10 90.42 ± 0.71 86.22 ± 0.19 92.19 ± 0.09

MONOSATURATED 8.87 ± 0.02 6.93 ± 0.56 4.69 ± 0.01 7.06 ± 0.17 2.07 ± 0.04

TRIUNSATURATED 2.08 ± 0.02 1.85 ± 0.03 0.91 ± 0.02 1.51 ± 0.08 0.91 ± 0.16

Iodide Value 34.4 ± 0.12 33.65 ± 0.11 32.40 ± 0.02 33.20 ± 0.12 27.95 ± 0.13

Dropping Point 32.4 ± 0.2 32.3 ± 0.04 32.17 ± 0.04 32.0 ± 0.10 31.5 ± 0.10

Triacylglycerol composition, iodine value and dropping point of

Palm Mid Fraction Hard with 65% to 75% of POP content

Page 38: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Mid Fraction Hard

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TEMPERATURE (°C)

1

2

3

4

5

Page 39: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Stearin

Soft

5 - 15% of PPP content

Page 40: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Triacylglycerol composition, iodine value and dropping point of

Palm stearin soft with 5-15% of PPP content

1 2 3 4

POO 18.14 ± 0.07 15.59 ± 0.24 14.86 ± 0.08 12.99 ± 0.38

POP 39.77 ± 0.22 38.36 ± 0.25 38.61 ± 0.02 41.81 ± 0.03

PPP 6.31 ± 0.18 9.32 ± 0.01 13.39 ± 0.03 13.88 ± 0.16

TRISATURATED 10.46 ± 0.09 14.03 ± 0.13 17.94 ± 0.03 18.52 ± 0.30

DISATURATED 55.56 ± 0.13 56.00 ± 1.28 53.68 ± 0.10 57.33 ± 0.28

MONOSATURATED 28.70 ± 0.13 23.69 ± 0.21 23.53 ± 0.04 20.07 ± 0.35

TRIUNSATURATED 5.41 ± 0.01 6.28 ± 0.26 4.86 ± 0.17 4.28 ± 0.23

Iodine Value 45.69 ± 0.08 41.93 ± 0.15 40.68 ± 0.15 37.05 ± 0.18

Dropping Point 40.3 ± 0.10 42.5 ± 0.10 49.9 ± 0.10 50.1 ± 0.10

Page 41: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Stearin Soft

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TEMPERATURE (CELCIUS)

1

2

3

4

43 to 62% at 20C

Page 42: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Stearin

15 - 20% of PPP content

Page 43: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Triacylglycerol composition, iodine value and dropping point of

Palm stearin with 15-20% of PPP content

1 2 3 4

POO 11.45 ± 0.06 14.61 ± 0.18 15.08 ± 0.26 14.06 ± 0.09

POP 37.99 ± 0.23 34.55 ± 0.73 31.75 ± 0.14 34.51 ± 0.57

PPP 18.77 ± 0.23 18.92 ± 0.70 19.48 ± 0.10 19.50 ± 0.01

TRISATURATED 25.63 ± 0.1 8 24.56 ± 0.26 25.38 ± 0.05 26.85 ± 0.10

DISATURATED 51.69 ± 0.13 47.31± 0.34 45.24 ± 0.21 46.38 ± 0.28

MONOSATURATED 17.85 ± 0.20 22.88 ± 0.17 23.97 ± 0.22 21.59 ± 0.23

TRIUNSATURATED 4.84 ± 0.05 5.06 ± 0.26 5.42 ± 0.14 5.18 ± 0.06

IV 34.27 ± 0.13 36.63 ± 0.17 37.76 ± 0.09 34.20 ± 0.18

D. Point 52.2 ± 0.10 52.7 ± 0.01 53.6 ± 0.21 52.6± 0.07

Page 44: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Stearin

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TEMPERATURE (CELCIUS)

1

2

3

4

60 to 70% at 20C

Page 45: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm stearin

20 - 30% of PPP content

Page 46: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Triacylglycerol composition, iodine value and dropping of

Palm Stearin with 20-30% of PPP content

1 2 3 4 5 6 7

POO 14.02 ± 0.04 12.42 ± 0.15 12.95 ± 0.13 11.86 ± 0.12 12.71 ± 0.13 12.91 ± 0.1 12.54 ± 0.05

POP 30.52 ± 0.04 32.74 ± 0.11 30.59 ± 0.22 30.56 ± 0.07 28.11 ± 0.13 29.86 ± 0.21 28.90 ± 0.14

PPP 23.08 ± 0.02 23.66 ± 0.13 24.82 ± 0.14 26.82 ± 0.07 26.97 ± 0.05 26.99 ± 0.08 28.43 ± 0.02

TRISATURATED

29.36 ± 0.17 30.33 ± 0.09 32.08 ± 0.60 33.86 ± 0.1 7 34.84 ± 0.01 34.17 ± 0.03 35.43 ± 0.07

DISATURATED

43.06 ± 0.12 45.00 ± 0.24 42.41 ± 0.05 42.49 ± 0.22 39.51 ± 0.03 41.41 ± 0.33 39.94 ± 0.17

MONOSATURATED

22.38 ± 0.07 19.43 ± 0.26 20.51 ± 0.39 18.65 ± 0.16 20.35 ± 0.04 19.41 ± 0.13 19.24 ± 0.18

TRIUNSATURATED

5.20 ± 0.02 4.99 ± 0.09 5.01 ± 0.06 5.01 ± 0.08 5.30 ± 0.09 5.01 ± 0.16 5.39 ± 0.16

IV 34.48 ± 0.11 33.14 ± 0.18 32.76 ± 0.18 32.14 ± 0.19 32.06 ± 0.16 31.77 ± 0.05 31.43 ± 0.12

D. Point 54.3 ± 0.01 54.4 ± 0.14 54.6 ± 0.21 55.9 ± 0.14 56.0 ± 0.07 55.6 ± 0.21 56.4 ± 0.14

Page 47: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm stearin

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1

2

3

4

5

6

7

65 to 73% at 20C

Page 48: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm stearin

IV 18 to 20

40 - 50% of PPP content

Page 49: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Triacylglycerol composition, iodine value and dropping of

Palm Stearin IV 18 - 20 with 40% to 50% of PPP content.

1 2 3 4 5 6

POO 4.93 ± 0.05 6.83 ± 0.01 7.17 ± 0.01 3.80 ± 0.13 6.16 ± 0.00 5.34 ± 0.04

POP 26.70 ± 0.13 20.92 ± 0.05 19.82 ± 0.13 23.15 ± 0.15 17.80 ± 0.04 18.89 ± 0.15

PPP 42.35 ± 0.21 44.63 ± 0.14 45.41± 0.26 47.36 ± 0.28 48.76 ± 0.12 48.80 ± 0.16

TRISATURATED 51.99 ±0.21 55.97 ±0.28 56.30 ± 0.24 58.76 ±0.17 59.96 ± 0.21 61.34±0.24

DISATURATED 36.17 ±0.15 28.46 ±0.06 27.39 ± 0.09 30.88 ±0.09 24.84 ± 0.11 25.53±0.17

MONOSATURATED 7.80 ± 0.07 10.08 ±0.14 10.67 ± 0.06 6.15 ± 0.16 9.37 ± 0.08 7.89 ± 0.07

TRIUNSATURATED 4.04 ± 0.01 5.47 ± 0.02 5.63 ± 0.01 4.21 ± 0.00 5.81 ± 0.06 5.24 ± 0.07

Iodine Value 20.60 ± 0.13 20.31 ± 0.14 20.09 ± 0.15 20.90 ± 0.12 18.32 ± 0.09 17.94 ± 0.14

Dropping Point 59.00 ± 0.15 59.50 ± 0.25 60.10 ± 0.15 60.0 ± 0.11 60.10 ± 0.15 60.00 ± 0.15

Page 50: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Stearin IV 18 -20

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TEMPERATURE (°C)

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2

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4

5

6

66 to 75% at 35C

Page 51: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm stearin IV 14

55 - 60% of PPP content

Page 52: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

1 2 3 4 5 6 7

POO

3.68 ± 0.15 4.10 ± 0.04 4.92 ± 0.07 4.74 ± 0.00 4.62 ± 0.01 3.93 ± 0.26 4.16 ± 0.01

POP

16.11 ± 0.16 14.45 ± 0.07 16.10 ± 0.01 15.89 ± 0.01 13.95 ± 0.00 14.59 ± 0.12 15.24 ± 0.01

PPP

55.70 ± 0.06 56.99 ± 0.35 56.29 ± 0.01 57.52 ± 0.00 58.28 ± 0.01 59.58 ± 0.82 60.54 ± 0.01

TRISATURATED 69.66 ± 0.16 68.95 ± 0.53

66.78 ± 0.01 67.27 ± 0.02 69.94 ± 0.01

70.54 ± 0.81

70.63 ± 0.00

DISATURATED 20.31 ± 0.09 19.67 ± 0.16

21.82 ± 0.05 21.53 ± 0.01 19.22 ± 0.01

19.42 ± 0.25

20.04 ± 0.01

MONOSATURATED 5.23 ± 0.15 7.13 ± 0.48

7.20 ± 0.07 7.18 ± 0.01 6.85 ± 0.00

6.44 ± 0.48

5.74 ± 0.00

TRIUNSATURATED 4.80 ± 0.08 4.26 ± 0.10 4.20 ± 0.03 4.04 ± 0.01 4.00 ± 0.01 3.59 ± 0.08 3.60 ± 0.01

Iodine Value 14.01 ± 0.17 13.97 ± 0.12 14.7 ± 0.15 13.85 ± 0.24 13.88 ± 0.18 13.69 ± 0.10 14.1 ± 0.22

Dropping Point 61.40 ± 0.25 61.0 ± 0.15 61.70 ± 0.20 62.35 ± 0.15 62.25 ± 0.25 62.30 ± 0.20- 62.25 ± 0.30

Triacylglycerol composition, iodine value and dropping point of

Palm stearin IV 14 with minimum 55 - 60% of PPP content

Page 53: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

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TEMPERATURE (CELCIUS)

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7

SFC of Palm stearin IV 14

81 to 85% at 35C

Page 54: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm stearin IV 12

60 - 63% of PPP content

Page 55: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Triacylglycerol composition, iodine value and dropping point of

Palm Stearin IV 12 with 60-63 % of PPP content

1 2 3 4

POO 3.98 ± 0.49 3.82 ± 0.34 4.03 ± 0.00 3.47 ± 0.00

POP 13.02 ± 0.42 13.06 ± 0.49 12.94 ± 0.00 11.01 ± 0.00

PPP 60.59 ± 0.53 62.23 ± 1.64 63.05 ± 0.00 63.17 ± 0.00

TRISATURATED 71.73 ± 0.58 72.94 ± 0.15 73.42 ± 0.00 74.08 ± 0.00

DISATURATED 17.22 ± 0.59 17.15 ± 0.11 16.96 ± 0.00 14.31 ± 0.00

MONOSATURATED 6.74 ± 0.37 6.20 ± 0.17 6.27 ± 0.00 5.73 ± 0.00

TRIUNSATURATED 4.31 ± 0.38 3.71 ± 0.07 3.35 ± 0.00 4.47 ± 0.00

Iodine Value 11.98 ± 0.11 11.78 ± 0.21 11.76 ± 0.00 11.98 ± 0.00

Dropping Point 62.2 ± 0.25 62.3 ± 0.25 62.95 ± 0.15 62.40 ± 0.25

Page 56: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm stearin IV 12

0

10

20

30

40

50

60

70

80

90

100

0 5 10 15 20 25 30 35 40 45 50 55 60 65

SO

LID

FA

T C

ON

TE

NT

(%

)

TEMPERATURE (°C)

1

2

3

4

85 to 88% at 35C

Page 57: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm stearin IV 10

67 - 68% of PPP content

Page 58: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Triacylglycerol composition, iodine value and dropping point of

Palm Stearin IV 10 with 67-68 % of PPP content

1 2 3

POO 2.68 ± 0.02 3.30 ± 0.00 3.81 ± 0.01

POP 10.91 ± 0.00 10.21 ± 0.00 10.36 ± 0.01

PPP 67.27 ± 0.07 67.23 ± 0.01 67.67 ± 0.00

TRISATURATED 78.21 ± 0.05 77.73 ± 0.01 77.46 ± 0.01

DISATURATED 14.55 ± 0.03 13.91 ± 0.00 13.97 ± 0.01

MONOSATURATED 4.06 ± 0.02 5.16 ± 0.01 5.34 ± 0.01

TRIUNSATURATED 3.19 ± 0.06 3.20 ± 0.00 3.23 ± 0.00

Iodine Value 9.64 ± 0.12 9.97 ± 0.211 10.10 ± 0.17

Dropping Point 63.70 ± 0.25 63.65 ± 0.30 63.15 ± 0.20

Page 59: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

SFC of Palm Stearin IV 10

0

10

20

30

40

50

60

70

80

90

100

0 5 10 15 20 25 30 35 40 45 50 55 60 65

PE

RC

EN

TA

GE

OF

SO

LID

FA

T

TEMPERATURE (CELCIUS)

1

2

3

88 to 90% at 35C

Page 60: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

PALM STEARIN FLAKES and PRILLS

Page 61: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Trans Fatty Acids ?????

Page 62: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

What are trans fats?

There are two broad types of trans fats found in

foods:

Naturally-occurring and artificial trans fats.

Naturally-occurring trans fats are produced in the gut of

some animals and foods made from these animals (e.g.,

milk and meat products) may contain small quantities of

these fats.

Artificial trans fats (or trans fatty acids) are created in an

industrial process that adds hydrogen to liquid vegetable

oils to make them more solid.

Page 64: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

PALM OIL AND ITS FRACTIONS are

Natural solid fats Free of trans fatty acids

Very Versatile

Page 65: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

PALM OIL AND ITS FRACTIONS ARE ABLE TO CATER FOR A WIDE RANGE OF FOOD PRODUCTS

Page 66: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Frying Oils (Cooking Oil)

Frying Fats

Margarine

Shortening

Vegetable Ghee

Confectionery Fats

Ice Cream

Palm oil and its Fractions in Food

Page 67: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Olein as Cooking Oil

Page 68: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 69: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

0

5

10

15

20

25

100% Palm

olein

75% palm

olein + 25%

soybean/

canola oil

50% palm

olein + 50%

soybean/

canola oil

25% palm

olein + 75%

soybean/

canola oil

100%

soybean/

canola oil

Soybean Oil Canola OilO

xid

ativ

e Sta

bili

ty, h

Source: Miskandar and Azmil (unpublished)

Palm Olein

OXIDATIVE STABILITY OF COOKING OILS: STABILITY OF OILS BEFORE FRYING

Page 70: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 71: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 72: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 73: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 74: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 75: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 76: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 77: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 78: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 79: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated
Page 80: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 81: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 82: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 83: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 84: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 85: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 86: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 87: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 88: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 89: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 90: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 91: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 92: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 93: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

CONFECTIONERY FATS

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 94: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 95: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 96: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

Palm Oil

Palm Olein

Palm Stearin

Plam Mid Fractions

Palm Kernel Oil

Palm Kernel Olein

Palm Kernel Stearin

Page 97: Determination of stability of blends with high percentage ...Palm Oil Fractionation Palm Oil IV 52 Palm Stearin IV 30-36 Palm Olein IV 56-60 Further Fractionated Further Fractionated

PALM OIL AND ITS FRACTIONS are

Unique oil with liquid oils and solid fats Natural solid fats

Free of trans fatty acids Very Versatile