derakane epoxy vinyl esters
TRANSCRIPT
DERAKANEEpoxy Vinyl Ester Resins
EVERYWHERE YOU NEED PROTECTION
Providing exceptional corrosion protection, superior heat resistance and high structural strength
EPOXY VINYL ESTER RESINS
DERAKANE® Epoxy Vinyl Ester Resins
Product Grades and Properties
Typical Physical Properties
411-350 441-400 470-300 510A-40 510C-350 510N 8084
LIQUID PROPERTIES¹
Epoxy Base Bisphenol-A Bisphenol-A Novolac Brominated Bisphenol-A
Brominated Bisphenol-A
Brominated Novolac
Elastomer Modified
Bisphenol-A
Density g/mL 1.046 1.07 1.08 1.23 1.14 1.15 1.02
Viscosity, cps @ 25°C mPa’s 370 430 325 400 400-440 275 360
Styrene content, wt% 45 33 33 38 35 37 40
TYPICAL PROPERTIES OF POSTCURED RESIN CLEAR CASTING²,³
Tensile strength, MPa 86 90 85 86 86 76 76
Tensile modulus, GPa 3.2 3.3 3.6 3.4 3.2 3.4 2.9
Elongation, % 5-6 5-6 3-4 4-5 5-6 3-4 8-10
Flexural strength, MPa 150 145 130 150 150 138 130
Flexural modulus, GPa 3.4 3.4 3.8 3.6 3.4 3.6 3.3
HDT,°C4 105 120 150 113 105 121 82
Barcol Hardness 35 35 40 40 35 40 30
¹ Typical property values only, not to be construed as specifications. ² Typical property values only, not to be construed as specifications. Sl values reported to two significant figures; US
standard values based on conversion. ³ Cure schedule: 24 hours at room temperature; 2 hours at 120°C (250°F) 4 Maximum Stress: 1.8MPa
PRODUCT FAMILY RESINS/DESCRIPTION PROPERTIESBisphenol – A Epoxy Vinyl Ester Resins
DERAKANE 411-350, MOMENTUM 411-350, 441-400, 441-800 PAT, MOMENTUM 640-900
Good toughness Broad corrosion resistance Improved elongation Higher HDT and solvent resistance than standard resins FDA compliance
Novolac Epoxy Vinyl Ester Resins
470-300, MOMENTUM 470-300, 470HT-400- when corrosion resistance and high temperature performance are needed.
Superior oxidizing acid and solvent resistance Very high temperature service
Brominated Bisphenol-A- Epoxy Vinyl Ester
510A-40, 510C-350, MOMENTUM 510C-350, 510C-350FR – when flame retardancy is a must.
Broad corrosion resistance Superior toughness Excellent fire retardancy
Brominated Novolac Epoxy Vinyl Ester Resin
510N - when flame retardancy and high temperature resistance are needed.
Designed to combine outstanding corrosion and high temperature resistance with excellent fire retardance.
Elastomer-Modified Bisphenol-A Epoxy Vinyl Ester Resins
8084, 8090 –when toughness and more flexibility are required.
Excellent adhesion and abrasion resistance Excellent impact strength
FGI SPV Vinyl Ester Resins
SPV series of Vinyl Ester Resins were developed by FGI to meet the demand for increased quality and performance from traditional fibreglass products and the demand for resins more suited to the exotic reinforcements used in today’s high tech applications. SPV series vinyl ester resin is based on the Derakane™ family of Vinyl Ester Resins. Derakane™ resins having proven performance in the chemical industry from their development in the USA in the mid 1960’s. The objective of the research work and development of the SPV series was firstly to allow the product to be used in common factory conditions while still achieving laboratory performance. Secondly, as we were developing the resins for the performance market, we examined the reinforcement/resin interface. The high strength of the reinforcement can only be optimised if the correct conditions exist at the reinforcement/resin interface. Increased laminate properties have been achieved by improvement in fibre wetting, increase wetting speed and reduction of air entrapments in the laminate. SPV Vinyl Ester Resins have significantly contributed to the improved production of Australian made boats, yachts, swimming pools, safety equipment and industrial process equipment which equals or exceeds the quality and performance of similar products made anywhere in the world. SPV has been a leader in preventing osmosis in swimming pools, marine craft, and solving high heat and highly corrosive applications. The emergence and acceptance of composites in structural and infrastructure applications is now broadening this scope to less traditional applications such as rail cars, bridge deckings, electrical cross-arms and marine pilings, to name just a few. The SPV series is also tailor made to suit specific climate and workshop conditions, project type etc. Consult FGI technical staff for the correct grade of SPV vinyl ester resin to suit your specific application. FGI technical staff have many years of engineering and application experience to help ensure your projects success. Case histories and specific technical data available on request.
FGI Vinyl Ester Resins
Classic Series
Momentum Series
Product Code F01112 F01115 F01116 F01385 Product Name SPV1265 SPV1356 SPV1359 SPV1385
Chemical Type Bisphenol-A Epoxy Bisphenol-A Epoxy Bisphenol-A Epoxy Bisphenol-A Epoxy
Solids % 55 55 55 55
Viscosity mPas 420-580 420-580 420-580 800-1000
El. At Break % 5-6 5-6 5-6 5-6
Tensile Strength MPa 86 86 86 86
HDT °C 105 105 105 105
LSE No No No No
Thix Standard Standard Standard High
Curing Systems
Product Code F01300 F01302 F01301 F01314
Product Name SPV6001 SPV6003 SPV6002 SPV6014
Chemical Type Bisphenol-A Epoxy Bisphenol-A Epoxy Bisphenol-A Epoxy Bisphenol-A Epoxy
Solids % 55 55 55 55
Viscosity mPas 420-580 420-580 420-580 700-1100
El. At Break % 5-6 5-6 5-6 5-6
Tensile Strength MPa 86 86 86 86
HDT °C 105 105 105 105
LSE No No No No
Thix Standard Standard Standard High
Curing Systems Norox 925H 1%
Norox 925H 1%
Norox 925H 1%
Norox 925H 1.5%
Gel Time (Min) 25-35 @ 25°C 35-45 @ 25°C 60-75 @ 25°C 50-60 @ 25°C
Description Fast to medium geltime Medium geltime Slow geltime Hi Thix, slow
geltime
Norox 925H Curox M100 1.5%
Norox 925H Curox M100 1.5%
Norox 925H Norox 925H Curox M100 1.5% Curox M100 1.5%
Gel Time (Min) 25-35 @ 25°C 35-45 @ 25°C 60-75 @ 25°C 45-55 @ 25°C
Description Fast to medium geltime Medium geltime Slow geltime Hi Thix, slow
geltime
FGI Vinyl Ester Resins
Low Exotherm Infusion Series (using Norox CHM50 initiator)
Derakane Unpromoted Series
Product Code F01635 F01636 F01637 F01638 F01639
Product Name SPV6035 SPV6036 SPV6037 SPV6038 SPV6039
Chemical Type Bisphenol-A Epoxy
Bisphenol-A Epoxy
Bisphenol-A Epoxy
Bisphenol-A Epoxy
Bisphenol-A Epoxy
Solids % 50 50 50 50 50
Viscosity mPas 120-230 120-230 120-230 120-230 120-230
El. At Break % 3-5 3-5 3-5 3-5 3-5
Tensile Strength MPa 70-85 70-85 70-85 70-85 70-85
HDT °C 90-105 90-105 90-105 90-105 90-105
LSE No No No No No
Thix None None None None None
Curing Systems CHM501.5%
CHM501.5%
CHM501.5%
CHM50 CHM501.5% 1.5%
Gel Time @ 25°C/minutes 20-30 40-50 60-70 90-100 120-130
Product Code F01110 F01080 F01030 F01082 F01083 F01005 F01006
Product Name Classic 411-350 Momentum 411-350 LSE 441-400 Momentum
470-300 Momentum 510C-
350 Derakane 510A-40 Derakane 8084
Chemical Type Bisphenol-A Epoxy
Bisphenol-A Epoxy Bisphenol-A Epoxy Novalac Epoxy Brominated
Novalac Brominated Bisphenol-A
Elastomer – Modified
Solids % 55 55 50 67 65 62 60
Viscosity mPa.s 370 370 430 325 400-440 400 360
El. At Break % 5-6 5-6 5-6 3-4 5-6 4-5 8-10
Tensile Strength MPa 86 86 90 85 86 86 76
Flexural Strength MPa 150 150 145 130 150 150 130
HDT °C 105 105 120 150 105 113 82
LSE No No Yes No No No No
Thix None None None None None None None
Curing Systems Norox 925H Norox 925H Norox 925H Norox CHM-50 Norox 925H Norox 925H Norox 925H
Gel Time (Min) Unpromoted Unpromoted Unpromoted Unpromoted Unpromoted Unpromoted Unpromoted
Description Original Derakane 411 series
Higherreactivity/lighter
colour than Classic Series
LSE/Higher HDT Vinyl Ester Resin
High resistance to solvents & acid
oxidizing environments
Fire retardant brominated epoxy
vinyl ester resin
Maximum degree of fire retardance combined with
enhanced chemical resistance and
toughness
High elongation tough epoxy vinyl
ester resin
INSTRUCTIONS FOR USE OF FGI FIBRETECH OSMOSIS REPAIR SYSTEM ON MARINE CRAFT
1. Remove gelcoat with 1mm of laminate.
2. Only when dry, primer coat with Fibretech Primer Coat using SR Catalyst at a ratio of 2%. Resin rich application: see usage rate. 3. Laminate with 225g Chopped Strand Mat and Fibretech Laminate coat using FGI SR Catalyst at a ratio of 1.5%. Resin to glass ratio 3:1. Number of layers will be determined by condition of hull. 4. Once laminate has cured sand off sharp fibres and repair any bubbles by repeat process. 5. Apply Fibretech Fillcoat using FGI SR Catalyst at a ratio of minimum 1.5% by weight (low temperature eg 15° use 2%). Apply with long nap application roller or spray gun (pressure pot) to 0.5mm thick. 6. Allow to cure (minimum 24 hours at 20°C). 7. Sand surface to ensure complete adhesion of high build epoxy. 8. Apply high build epoxy to data sheet recommendations. 9. Sand surface once cured. 10. Never apply to damp or dust coated surface. 11. Approximate material usage per metre of hull:
Fibretech Primer Coat - 0.4kg 1 x 225g CSM - 0.25kg/m Fibretech Laminate Resin with 1 x 225g CSM - 0.8kg/m Fibretech Fillcoat - 0.6kg/m
INSTRUCTIONS FOR USE OF FGI FIBRETECH POOL RESURFACING SYSTEM ON CONCRETE SWIMMING POOLS
1. A: Acid wash new rendered concrete with 20:1 HCL or, B: Sand blast painted surfaces C: Acid wash marblesheen with 5:1 HCL 2. When dry, primer coat with Fibretech Primer Coat using SR Catalyst at a ratio of 2%. 3. Laminate with 225g Chopped Strand Mat and Fibretech Laminate coat using FGI SR Catalyst at a ratio of 1.5%. 4. Once laminate has cured sand off sharp fibres and repair air bubbles. 5. Apply Fibretech Fillcoat using FGI SR Catalyst at a ratio of minimum 1.5% by weight (low temperature eg 15°C use 2%). Apply with long nap application roller. 6. Allow to cure (minimum two hours). 7. Sand off any defects. 8. Only apply Fibretech Topcoat out of direct sunlight (either late in the afternoon or preferably early morning). Use a minimum of 1.5% NR20 MEKP Catalyst. Keep a wet edge at all times. Use a long nap application roller. 9. Never apply to damp or dust coated surface. 10. Approximate material usage per m² of pool:
Fibretech Primer Coat - 0.4kg 225g CSM - 0.25kg/m² Fibretech Laminate Resin - 0.8kg/m² Fibretech Fillcoat - 0.6kg/m² Fibretech Topcoat - 0.6kg/m² 11. To use on existing Fibreglass pools without osmosis, sand the entire surface, tile around the waterline and complete steps 5 onwards.