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0 10 20 30 40 50 60 70 80 -10 10 30 50 70 90 110 130 150 170 Solubility of boric acid in water Column Column Chanson 30 Column Column Column Column Column Column Column w% H3BO3 t/C 90 140 190 240 290 340 390 440 B2O3+H2O Column B Column B 30 Column B Column B Column B Column B Column B Column B Column B Column B Column K t/C

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Page 1: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

0 10 20 30 40 50 60 70 80 90 100-10

10

30

50

70

90

110

130

150

170 Solubility of boric acid in water

Column BColumn BChanson and Millero 200630Column BColumn BColumn BColumn BColumn BColumn BColumn K

w% H3BO3

t/C

0 10 20 30 40 50 60 70 80 90 100-10

40

90

140

190

240

290

340

390

440 B2O3+H2OColumn BColumn B30Column BColumn BColumn BColumn BColumn BColumn BColumn BColumn BColumn K

w% B2O3

t/C

Page 2: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

Dukelski, M. P.Über BorateZeitschrift für anorganische Chemie 1906, 50 (1), 38-48

w% t w%H3BO3 C B2O36.2881714 30 3.54

Blasdale, Walter C.; Slansky, Cyril M.The solubility curves of boric acid and the borates of sodiumJournal of the American Chemical Society 1939, 61 (4), 917-924

w% t w%H3BO3 C B2O32.7000058 0 1.523.1440857 5 1.77

3.51711281 10 1.984.17435107 15 2.354.65395736 20 2.625.43553799 25 3.066.34146098 30 3.577.19409439 35 4.058.17107018 40 4.69.32567792 45 5.2510.2316009 50 5.7611.5460774 55 6.512.9671331 60 7.314.4237152 65 8.1215.7559549 70 8.8717.4079321 75 9.819.0599093 80 10.7321.0138609 85 11.8323.2697868 90 13.125.2237384 95 14.227.5329539 100 15.529.2737471 103.3 16.48

Chanson, Mareva; Millero, Frank J.The solubility of boric acid in electrolyte solutionsJournal of Solution Chemistry 2006, 35 (5), 689-703

w% t m w%H3BO3 C H3BO3 B2O35.29927157 25 0.905 2.98328722009

Menzel, HeinrichZur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die freien BorsäurenZeitschrift für anorganische und allgemeine Chemie 1927, 164 (1), 1-21

0 10 20 30 40 50 60 70 80 90 100-10

40

90

140

190

240

290

340

390

440 B2O3+H2OColumn BColumn B30Column BColumn BColumn BColumn BColumn BColumn BColumn BColumn BColumn K

w% B2O3t/C

Page 3: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

w% t m w%H3BO3 C H3BO3 B2O34.48832534 18 0.76 2.526755507775.45981113 25 0.934 3.07366485081

w% t m w%H3BO3 C H3BO3 B2O30.27931723 -0.084 0.0453 0.157244916530.7706269 -0.236 0.1256 0.4338334714

1.46167129 -0.441 0.2399 0.82286503521.79852851 -0.552 0.2962 1.012502766561.92418261 -0.582 0.3173 1.083241219262.16624377 -0.665 0.3581 1.219512392952.46655692 -0.76 0.409 eut 1.38857720855

Nies, Nelson P.; Hulbert, Richard W.Solubility isotherms in the system sodium oxide-boric oxide-water. Revised solubility-temperature curves of boric acid, borax, sodium pentaborate, and sodium metaborateJournal of the Chemical and Engineering Data 1967, 12 (3), 303-313

w% t m w%H3BO3 C H3BO3 B2O3

2.466 -0.76 0.40890531826 1.388263685842.52 0 0.41809092665 1.418663620572.98 5 0.49675324887 1.67762602753.49 10 0.58484237721 1.964736522144.08 15 0.68791806664 2.296883957114.72 20 0.80117238689 2.65717947985.46 25 0.9340341758 3.07377117796.23 30 1.07450849422 3.507251728637.12 35 1.2397768119 4.008287689868.08 40 1.421631597 4.548730973899.12 45 1.62297654062 5.13421119825

10.27 50 1.85105148447 5.7816172155811.55 55 2.11188307341 6.5022082609512.97 60 2.41022016116 7.301613951914.42 65 2.7250765129 8.1179084954815.75 70 3.02340530633 8.8666476285617.41 75 3.40923569885 9.80116414053

19.1 80 3.81830457655 10.752569505121.01 85 4.3016954585 11.827826455623.27 90 4.904750357 13.100120020125.22 95 5.45437940186 14.197895440827.53 100 6.14375194204 15.49833709329.27 103.3 6.69275283554 16.4778905453

Platford, R. F.Osmotic and activity coefficients of some simple borates in aqueous solutions at 25°C.Canadian Journal of Chemistry 1969, 47, 2271-2273

w% t m w%H3BO3 C H3BO3 B2O35.42111006 25 0.927 3.051877627395.43493551 25 0.9295 3.0596608265.38237729 25 0.92 3.03007255898

Page 4: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

Benrath, AfredÜber die Löslichkeit von Salzen und Salzgemischen bei Temperaturen oberhalb von 100°. IVZeitschrift für anorganische und allgemeine Chemie 1942, 249 (3), 245-250

w% t m w%H3BO3 C H3BO3 B2O3

2.27 -0.76 0.37565024879 1.2779231820231 110 7.26604905343 17.45181438

35.2 120 8.78523493677 19.816253747639.2 126 10.4272121603 22.068100764445.7 138 13.6113779363 25.727352166747.9 141 14.8690599508 26.965868025949.4 145 15.7892737495 27.810310657256.5 152 21.0060750722 31.80733911263.4 160 28.0152108136 35.691775215970.6 166 38.8367691013 39.745099846177.6 172 56.0272653394 43.6858321255

85 176 91.6459735449 47.851749106592 179 185.9874169 51.7924813859

100 181 56.2961754195

Nasini, R.; Ageno, J.Solubilita e idrati dell’ acido boricoZeitschrift für physikalische Chemie 1910, 69, 482-485

w% t m w%H3BO3 C H3BO3 B2O3

2.27 -0.76 0.37565024879 1.277923182022.59 0 0.43001335437 1.458070943363.69 12.2 0.61964179832 2.077328872984.9 21 0.83329981512 2.75851259555

6.44 31 1.11322096477 3.625473697018.02 40 1.41015446036 4.51495326864

10.35 50 1.86713525053 5.8266541559112.9 60 2.39528545701 7.26220662911

15.58 69.5 2.98474908615 8.7709441303519.11 80 3.82077597269 10.7581991227

23.3 90 4.91299451706 13.117008872728.1 99.5 6.32067051447 15.819225292936.7 108 9.37665801254 20.6606963789

45 115 13.2323063407 25.333278938852.4 120 17.803691351 29.4991959198

w% t m w%H3BO3 C H3BO3 B2O3

2.06 100.16 0.34016751943 1.159701213642.286 100.19 0.37835994756 1.286930570094.083 100.32 0.68844542061 2.298572842387.693 100.61 1.34786631021 4.33086477502

9.4 100.77 1.6779745838 5.2918404894313.34 101.035 2.48956154632 7.5099098009515.65 101.26 3.00064748278 8.81035145314

Page 5: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

21.5 101.785 4.42949815935 12.103677715222.38 101.9 4.66307248269 12.599084058930.15 102.27 6.98082303014 16.973296889

McCulloch, L.A crystalline boric oxideJournal of the American Chemical Society 1937, 59 (12), 2650-2652

from figure 2, related to Stackelberg, Quatram and Dressel

w% t m w%H3BO3 C H3BO3 B2O335.5263921 111.764706 8.91158292794 2044.4079901 128.235294 12.9191655563 2553.2895881 141.176471 18.4507654854 3062.1711861 152.941176 26.5798270808 3571.0527841 161.176471 39.6972134739 4079.9343822 165.882353 64.4268366695 4588.8159802 169.411765 128.433674282 50

100 170 56.2961754195

t w%C B2O3

465 99.6295 85250 82.8220 80.1

Kukuljan, Juan A.; Alvarez, Jorge L.; Fernández-Prini, RobertoDistribution of B(OH)3 between water and steam at high temperaturesJournal of the Chemical Thermodynamics 1999, 31, 1511–1521

t m y x K=y/xC H3BO3 H3BO3 H3BO3 0

179.15 0.0204 1.4015981E-05 0.00036738 0.03815127088179.75 0.0199 1.3241319E-05 0.00035838 0.03694791469179.75 0.0201 1.2790934E-05 0.00036198 0.03533617402195.15 0.0191 1.2899026E-05 0.00034398 0.03749981002199.55 0.02 1.3817812E-05 0.00036018 0.03836381781199.55 0.0197 1.394392E-05 0.00035478 0.03930328402223.85 0.0201 1.7132645E-05 0.00036198 0.04733056548223.85 0.0199 1.7006538E-05 0.00035838 0.04745419247226.75 0.0201 1.8555862E-05 0.00036198 0.05126233696226.75 0.0206 1.9636786E-05 0.00037098 0.05293225815227.45 0.02 1.7601046E-05 0.00036018 0.04886760105233.55 0.0976 0.00008737469 0.00175522 0.04977999764233.65 0.0961 8.7915152E-05 0.00172829 0.0508683522246.75 0.0207 2.0897864E-05 0.00037278 0.05605954521246.85 0.0207 2.0537556E-05 0.00037278 0.05509300132257.45 0.0205 2.3780328E-05 0.00036918 0.06441402423

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270.55 0.021 2.8464332E-05 0.00037818 0.07526655957270.55 0.0211 2.8644486E-05 0.00037998 0.07538409472284.05 0.0211 0.00003332849 0.00037998 0.08771105361284.05 0.0212 3.6571262E-05 0.00038178 0.09579128824284.95 0.102 0.00016339968 0.0018342 0.08908496831285.05 0.101 0.0001644806 0.00181625 0.09056052021285.05 0.0224 3.6751416E-05 0.00040338 0.09110817999294.15 0.0214 3.9994188E-05 0.00038538 0.10377831195294.35 0.0212 3.9273572E-05 0.00038178 0.10286946225294.45 0.021 4.2516344E-05 0.00037818 0.11242346872295.65 0.0201 3.9994188E-05 0.00036198 0.11048775538310.65 0.109 0.00024140636 0.00195983 0.12317718618310.85 0.0222 5.2785122E-05 0.00039978 0.1320347671316.35 0.109 0.000270231 0.00195983 0.1378849099316.65 0.11 0.000270231 0.00197777 0.13663386736321.95 0.0229 6.5395902E-05 0.00041238 0.15858067974322.05 0.0231 0.00006575621 0.00041598 0.15807441422332.85 0.024 8.0708992E-05 0.00043218 0.18674737566332.95 0.0237 8.3231148E-05 0.00042678 0.19501994001338.55 0.021 7.4223448E-05 0.00037818 0.19626469964338.85 0.0205 7.7646374E-05 0.00036918 0.21032154881352.35 0.0225 0.00010935348 0.00040518 0.26988713126352.45 0.0217 0.00011007409 0.00039078 0.28167689437361.55 0.0211 0.0001417812 0.00037998 0.37312756319364.45 0.0243 0.00017619061 0.00043758 0.40264532641364.45 0.0241 0.00017619061 0.00043398 0.40598531924368.45 0.0246 0.0001981694 0.00044298 0.44735264094368.45 0.0245 0.00019636786 0.00044118 0.44509432704370.05 0.026 0.00022699404 0.00046818 0.48484237866370.15 0.0254 0.00023600174 0.00045738 0.51598403324370.35 0.0245 0.00020357402 0.00044118 0.46142806382370.45 0.0249 0.0002161848 0.00044838 0.48214389564371.85 0.0246 0.00026482638 0.00044298 0.59782580199371.85 0.0245 0.00027563562 0.00044118 0.62476543154

von Stackelberg, M.; Quatram, F.; Dressel, JuttaDie Flüchtigkeit der Borsäuren mit Wasserdampf. Das System B2O3-WasserZeitschrift fuer Elektrochemie. Berichte der Bunsengesellschaft fuer physikalische Chemie 1937, 43, 14Zeitschrift für Elektrochemie und angewandte physikalische Chemie 1937, 43 (1), 14-28

t p 1/T log(p)C atm

109 0.00081579 H3BO3 0.00261677352 -3.0884219119 0.00172368 H3BO3 0.00255004463 -2.7635423129 0.00355263 H3BO3 0.00248663434 -2.4494498134 0.00565789 H3BO3 0.00245609726 -2.2473451

138.5 0.00793421 H3BO3 0.00242924815 -2.1004963140 0.00822368 H3BO3 0.00242042842 -2.0849336142 0.00828947 HBO2 0.00240876792 -2.081473145 0.00847368 HBO2 0.00239148631 -2.0719277149 0.01065789 HBO2 0.00236882625 -1.9723286

157.5 0.01289474 HBO2 0.00232207129 -1.8895875158.8 0.01140789 HBO2 0.00231508276 -1.9427945159.2 0.01167105 HBO2 0.0023129409 -1.93289

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160 0.01232895 HBO2 0.00230866905 -1.909074167 0.01578947 HBO2 0.00227195274 -1.8016323

169.8 0.01631579 HBO2 0.00225759115 -1.7873919180 0.01973684 HBO2 0.0022067748 -1.7047223

t m y x K=y/xC H3BO3 H3BO3 H3BO3

100.5 1.06740604 6.846992E-05 0.01886694 0.00362909508100.65 1.16444296 6.6667788E-05 0.02054688 0.00324466798100.7 1.29382551 7.3876412E-05 0.02277786 0.00324334298

100.75 1.43938088 9.0096739E-05 0.0252756 0.00356457367100.85 1.61728189 0.00010812083 0.02831111 0.00381902482100.95 1.85987417 0.0001153309 0.0324201 0.00355738916101.05 2.16715773 0.00012975181 0.03757519 0.00345312421101.2 2.58765102 0.00014056816 0.04454117 0.00315591554

101.55 3.21839095 0.00016761152 0.05480308 0.00305843224102.2 4.23727854 0.00023433368 0.07092232 0.00330408921103.2 6.14567117 0.00033716424 0.09968043 0.00338245162

w% t m p p B 1/T log(p) w%H3BO3 C H3BO3 atm atm B2O32.37388528 -2 0.39325970113 0.00516957 1.1583094E-07 0.00368799557 -6.9361754 1.336406582.45923045 -1 0.40775450904 0.00556322 1.3174439E-07 0.00367444424 -6.8802679 1.384452642.54648781 0 0.42260032732 0.00598324 1.4970014E-07 0.00366099213 -6.8247778 1.433575192.63570695 1 0.43780743141 0.00643072 1.699408E-07 0.00364763815 -6.7697023 1.483802152.72688416 2 0.45337710447 0.00690752 1.9273721E-07 0.00363438125 -6.7150344 1.535131432.82005226 3 0.46931692589 0.00741528 2.183882E-07 0.00362122035 -6.6607708 1.58758152.91525621 4 0.48563665913 0.00795569 2.4722481E-07 0.00360815443 -6.6069079 1.641177683.01253146 5 0.50234454438 0.00853055 2.7961379E-07 0.00359518246 -6.5534414 1.695939923.11191655 6 0.51944946031 0.00914172 3.1596293E-07 0.00358230342 -6.5003639 1.751889923.21344885 7 0.53696020311 0.00979111 3.5671674E-07 0.00356951633 -6.4476765 1.809048723.31716608 8 0.55488574336 0.0104807 4.0237107E-07 0.0035568202 -6.3953733 1.867437553.42310832 9 0.57323558299 0.0112127 4.5347325E-07 0.00354421407 -6.3434483 1.927078973.53132185 10 0.59202043332 0.0119892 5.1062441E-07 0.00353169698 -6.2918984 1.987999043.6418332 11 0.61124770866 0.0128126 5.7449086E-07 0.00351926799 -6.2407169 2.0502127

3.75469743 12 0.63092992392 0.0136851 6.4579374E-07 0.00350692618 -6.1899062 2.113750943.86996566 13 0.65107907314 0.0146093 7.2534279E-07 0.00349467063 -6.1394567 2.178642543.98766628 14 0.67170333113 0.0155877 8.1401412E-07 0.00348250044 -6.0893681 2.244903474.10781735 15 0.69280919472 0.016623 9.1278046E-07 0.00347041471 -6.0396337 2.312543924.23047166 16 0.71440940557 0.017718 1.0227045E-06 0.00345841259 -5.9902498 2.38159364.35568539 17 0.73651749326 0.0188754 1.1449428E-06 0.00344649319 -5.9412162 2.452084134.48350601 18 0.75914564601 0.0200983 1.2807731E-06 0.00343465568 -5.8925278 2.524042244.61396071 19 0.78230264406 0.0213897 1.4315923E-06 0.0034228992 -5.8441807 2.597483244.74712782 20 0.80600654463 0.0227529 1.5989315E-06 0.00341122292 -5.7961702 2.672451224.88296164 21 0.83025350104 0.0241912 1.7844639E-06 0.00339962604 -5.7484922 2.748920465.02160607 22 0.85507368652 0.0257079 1.989999E-06 0.00338810774 -5.7011471 2.826971965.16305536 23 0.8804707845 0.0273066 2.2175394E-06 0.00337666723 -5.6541287 2.906602485.30734782 24 0.90645655155 0.0289909 2.4692462E-06 0.00336530372 -5.6074356 2.987833615.4545349 25 0.93304533203 0.0307647 2.747502E-06 0.00335401643 -5.561062 3.07069429

5.60466246 26 0.96025071873 0.0326319 3.0548864E-06 0.00334280461 -5.5150049 3.15521035

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5.7577812 27 0.98808743591 0.0345964 3.3941891E-06 0.0033316675 -5.469264 3.241410335.91393535 28 1.01656930294 0.0366625 3.768481E-06 0.00332060435 -5.4238337 3.329319136.0731687 29 1.04571032502 0.0388345 4.181097E-06 0.00330961443 -5.3787098 3.41896146.235518 30 1.07552349239 0.0411167 4.6356426E-06 0.00329869701 -5.3338901 3.51035783

6.4010363 31 1.10602507216 0.0435138 5.1360024E-06 0.00328785139 -5.2893748 3.603538296.56976481 32 1.13722946254 0.0460304 5.6864901E-06 0.00327707685 -5.2451557 3.698525976.74170696 33 1.16914434011 0.0486714 6.2916882E-06 0.00326637269 -5.2012328 3.79532286.91700546 34 1.20180358337 0.0514419 6.9565797E-06 0.00325573824 -5.1576042 3.894009147.09559444 35 1.23520260312 0.0543468 7.6866399E-06 0.00324517281 -5.1142635 3.994547887.27758461 36 1.26937005537 0.0573916 8.4877027E-06 0.00323467572 -5.0712098 4.097001367.46301193 37 1.30432103495 0.0605816 9.366048E-06 0.00322424633 -5.0284436 4.201389837.65194135 38 1.34007648109 0.0639225 1.0328682E-05 0.00321388398 -4.9859551 4.307749857.84434679 39 1.3766404483 0.0674199 1.1382935E-05 0.00320358802 -4.9437457 4.416066738.0403505 40 1.41404554029 0.0710798 1.2536806E-05 0.00319335782 -4.9018131 4.52640929

8.23993183 41 1.45229758002 0.0749082 1.3798966E-05 0.00318319274 -4.8601534 4.638765928.44318853 42 1.49142545031 0.0789112 1.5178716E-05 0.00317309218 -4.818765 4.753191648.65013414 43 1.53144234304 0.0830953 1.6686216E-05 0.00316305551 -4.7776421 4.869694088.86084183 44 1.57237342065 0.087467 1.8332249E-05 0.00315308214 -4.7367842 4.988314429.07532993 45 1.61423370437 0.0920329 2.0128397E-05 0.00314317146 -4.6961908 5.109062989.29364084 46 1.65704335674 0.0967998 2.2087284E-05 0.00313332289 -4.6558577 5.231963649.51581932 47 1.70082351493 0.101775 2.4222476E-05 0.00312353584 -4.6157815 5.35704169.7419258 48 1.74559896911 0.106965 2.6548452E-05 0.00311380975 -4.5759608 5.48433086

9.97197299 49 1.7913856184 0.112378 2.908096E-05 0.00310414403 -4.5363913 5.6138385910.206028 50 1.83821071434 0.118021 3.1836695E-05 0.00309453814 -4.497072 5.74560255

10.4441288 51 1.88609636186 0.123901 3.483351E-05 0.00308499152 -4.4580028 5.8796441610.6863303 52 1.93506867602 0.130027 3.8090946E-05 0.00307550361 -4.4191782 6.0159943310.9326201 53 1.98514074187 0.136406 4.1629739E-05 0.00306607389 -4.3805963 6.1546460111.1831354 54 2.03635677503 0.143047 4.5472019E-05 0.00305670182 -4.3422558 6.2956765211.4378223 55 2.08872267853 0.149958 4.9641843E-05 0.00304738687 -4.3041521 6.4390554611.6967691 56 2.14227413695 0.157147 5.4164516E-05 0.00303812851 -4.2662851 6.5848325311.9600024 57 2.19703495027 0.164623 5.9067226E-05 0.00302892625 -4.2286534 6.7330227412.2275579 58 2.25303152268 0.172395 6.4379307E-05 0.00301977956 -4.1912537 6.8836462212.4994912 59 2.31029521757 0.180471 7.0132116E-05 0.00301068794 -4.1540831 7.0367342112.7758235 60 2.36885101828 0.188862 7.6359333E-05 0.00300165091 -4.1171379 7.1922986713.0565967 61 2.42872910362 0.197575 8.3095969E-05 0.00299266796 -4.08042 7.350363213.3418659 62 2.48996339044 0.206621 9.0380642E-05 0.00298373862 -4.0439246 7.510958813.6316308 63 2.55257680108 0.216008 9.8253412E-05 0.00297486241 -4.0076524 7.6740852613.9259937 64 2.61661543214 0.225748 0.00010675886 0.00296603886 -3.9715961 7.8398002414.2248987 65 2.68209197392 0.235849 0.00011594232 0.00295726748 -3.935758 8.0080722914.5284585 66 2.74905686679 0.246321 0.00012585287 0.00294854784 -3.9001369 8.1789647714.8366651 67 2.81753523889 0.257176 0.00013654462 0.00293987946 -3.8647254 8.3524732115.1495619 68 2.88756459096 0.268422 0.00014807202 0.00293126191 -3.829527 8.5286220715.4671883 69 2.95918271912 0.28007 0.00016049501 0.00292269472 -3.7945385 8.70743352

15.78956 70 3.03242323188 0.292132 0.00017387809 0.00291417747 -3.7597551 8.8889163816.1167118 71 3.10732527061 0.304617 0.0001882874 0.00290570972 -3.7251787 9.0730902416.4487021 72 3.18393473714 0.317536 0.00020379569 0.00289729103 -3.690805 9.2599879816.7855292 73 3.26228504279 0.330901 0.0002204789 0.00288892099 -3.656633 9.4496086617.1272565 74 3.34242606255 0.344722 0.00023841838 0.00288059916 -3.6226603 9.6419879817.4738781 75 3.4243928944 0.359011 0.00025770033 0.00287232515 -3.588885 9.8371225717.8254173 76 3.50822890079 0.373778 0.00027841522 0.00286409852 -3.555307 10.035025618.1819241 77 3.59398534395 0.389035 0.00030066102 0.00285591889 -3.5219229 10.235725218.5434166 78 3.68170754775 0.404793 0.0003245398 0.00284778585 -3.488732 10.439231518.9099343 79 3.77144770944 0.421064 0.00035016137 0.00283969899 -3.4557318 10.645566919.2814868 80 3.86325243232 0.437859 0.00037764098 0.00283165794 -3.4229209 10.8547366

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19.6580746 81 3.95716779514 0.455191 0.00040710232 0.00282366229 -3.3902964 11.06674120.0397539 82 4.05325552959 0.47307 0.00043867346 0.00281571167 -3.3578586 11.281611720.4265437 83 4.15157020839 0.491508 0.00047249268 0.0028078057 -3.3256049 11.499359420.8184369 84 4.25216169245 0.510517 0.00050870488 0.002799944 -3.2935341 11.719980221.2154937 85 4.35509916471 0.530109 0.00054746488 0.0027921262 -3.2616437 11.943507921.6177351 86 4.46044414668 0.550295 0.00058893159 0.00278435194 -3.2299351 12.169954322.0251302 87 4.56824668709 0.571088 0.00063328687 0.00277662085 -3.1983995 12.399301922.4377473 88 4.6785854047 0.592499 0.00068070193 0.00276893258 -3.167043 12.631589522.855596 89 4.79152595841 0.61454 0.00073137619 0.00276128676 -3.1358592 12.8668221

23.2786876 90 4.90713709678 0.637222 0.0007855071 0.00275368305 -3.1048499 13.105006423.7070069 91 5.02548284028 0.660557 0.00084330818 0.0027461211 -3.0740137 13.346133624.1406252 92 5.14665405696 0.684557 0.0009050116 0.00273860058 -3.0433459 13.590243924.5795048 93 5.2707142589 0.709234 0.00097084888 0.00273112113 -3.0128484 13.837316225.0237303 94 5.39776464989 0.734598 0.00104107993 0.00272368242 -2.9825159 14.08739825.4732608 95 5.52787412226 0.760662 0.00111596237 0.00271628412 -2.9523504 14.340466325.9281127 96 5.66113118224 0.787436 0.00119577625 0.00270892591 -2.9223501 14.596530326.3883224 97 5.79763391417 0.814931 0.00128081599 0.00270160746 -2.8925133 14.855610626.8539248 98 5.9374841386 0.843159 0.0013714033 0.00269432844 -2.8628348 15.117726727.3248849 99 6.08076661572 0.872129 0.00146784295 0.00268708854 -2.8333204 15.38285927.8012368 100 6.22759098088 0.901853 0.00157049683 0.00267988744 -2.8039629 15.651026728.283048 101 6.37808216024 0.932341 0.00167971485 0.00267272484 -2.7747644 15.9222678

28.7703329 102 6.5323537552 0.963603 0.00179588655 0.00266560043 -2.7457211 16.196590329.2629452 103 6.69047240366 0.995649 0.00191940638 0.00265851389 -2.7168331 16.47391229.7609202 104 6.85256658645 1.02849 0.00205070787 0.00265146493 -2.6880962 16.754252630.2645902 105 7.01886942595 1.06213 0.00219019999 0.00264445326 -2.6595162 17.037799330.7736177 106 7.18939988769 1.09658 0.00233836678 0.00263747857 -2.6310874 17.324362131.2883042 107 7.36439510678 1.13185 0.0024957057 0.00263054058 -2.6028066 17.614110631.8085449 108 7.54396331889 1.16795 0.00266270984 0.00262363899 -2.5746762 17.90698632.3342411 109 7.72821931031 1.20489 0.00283994401 0.00261677352 -2.5466902 18.202932532.865477 110 7.91734837623 1.24267 0.00302794264 0.00260994389 -2.5188524 18.5019977

33.4023314 111 8.11154304129 1.28129 0.00322728124 0.00260314981 -2.4911632 18.804225933.9448753 112 8.31100269506 1.32077 0.003438615 0.00259639102 -2.4636164 19.109657134.4932059 113 8.51594675391 1.36112 0.00366259842 0.00258966723 -2.4362107 19.418345935.0470498 114 8.72646409095 1.40232 0.0038998594 0.00258297817 -2.4089511 19.730138635.6068145 115 8.94291154612 1.4444 0.00415116019 0.00257632359 -2.3818305 20.045264436.1722309 116 9.16539846904 1.48735 0.00441723784 0.0025697032 -2.3548492 20.363571836.7435495 117 9.39424780913 1.53118 0.00469886006 0.00256311675 -2.3280075 20.68520237.3207008 118 9.62966948163 1.57588 0.00499682607 0.00255656398 -2.3013058 21.010115837.9037455 119 9.87193858362 1.62147 0.00531204907 0.00255004463 -2.2747379 21.338347338.4927402 120 10.1213436734 1.66794 0.00564539001 0.00254355844 -2.248306 21.669928439.0879543 121 10.3782822975 1.71528 0.00599774818 0.00253710516 -2.2220118 22.005010839.6891324 122 10.6429433648 1.7635 0.0063701519 0.00253068455 -2.1958502 22.343450740.296512 123 10.915747326 1.8126 0.00676360928 0.00252429635 -2.1698215 22.6853818

40.9101755 124 11.197069264 1.86256 0.00717915886 0.00251794032 -2.1439264 23.030850441.5302336 125 11.4873205002 1.9134 0.00761797924 0.00251161623 -2.1181602 23.37991942.1568823 126 11.786979144 1.96509 0.00808115514 0.00250532381 -2.0925266 23.732697942.7899536 127 12.0963749051 2.01763 0.00856994151 0.00249906285 -2.0670221 24.089092443.429768 128 12.4161020053 2.07101 0.009085575 0.0024928331 -2.0416476 24.4492829

44.0763646 129 12.7466509525 2.12523 0.00962943947 0.00248663434 -2.016399 24.813291644.7301217 130 13.0887235264 2.18026 0.01020283927 0.00248046633 -1.991279 25.181331445.3908375 131 13.4427586677 2.2361 0.0108072534 0.00247432884 -1.9662847 25.553288646.0589291 132 13.8095648354 2.29272 0.01144411371 0.00246822165 -1.9414178 25.929398146.7346417 133 14.1899147537 2.35011 0.01211504775 0.00246214453 -1.9166749 26.30979847.4180289 134 14.5845272869 2.40825 0.01282164442 0.00245609726 -1.8920563 26.6945183

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48.1093133 135 14.9942747028 2.46711 0.01356556412 0.00245007963 -1.8675621 27.083684548.8088787 136 15.4201966091 2.52667 0.01434857439 0.00244409141 -1.8431912 27.477512549.5169511 137 15.8633184439 2.5869 0.0151724976 0.00243813239 -1.8189429 27.876129650.2339185 138 16.3248549796 2.64777 0.01603926774 0.00243220236 -1.7948155 28.279754250.9600846 139 16.8060693243 2.70925 0.01695082196 0.0024263011 -1.7708092 28.688557351.695709 140 17.308303668 2.77129 0.01790915025 0.00242042842 -1.746925 29.1026851

52.4413921 141 17.8332624605 2.83385 0.01891639677 0.00241458409 -1.7231616 29.522475653.1974716 142 18.3826195392 2.89689 0.01997479817 0.00240876792 -1.6995176 29.948118853.9646201 143 18.9584625418 2.96035 0.0210865491 0.00240297969 -1.6759945 30.379993354.7433157 144 19.562938445 3.02419 0.02225416763 0.00239721923 -1.6525886 30.818368555.5342284 145 20.1985703929 3.08834 0.02347995465 0.00239148631 -1.6293027 31.263621456.3380923 146 20.868207744 3.15272 0.02476641721 0.00238578075 -1.6061368 31.716165257.155696 147 21.5750667687 3.21728 0.026116367 0.00238010234 -1.5830872 32.1764441

57.9879643 148 22.3228611901 3.28192 0.02753234655 0.00237445091 -1.5601568 32.644978558.8359213 149 23.1158507285 3.34656 0.02901721892 0.00236882625 -1.5373442 33.122345159.700692 150 23.9589343874 3.4111 0.03057384367 0.00236322817 -1.51465 33.6091771

60.5836948 151 24.8579646427 3.47542 0.03220514932 0.00235765649 -1.4920747 34.10627361.4862876 152 25.819546564 3.53941 0.03391433857 0.00235211102 -1.4696166 34.614397362.4102202 153 26.8516919539 3.60292 0.03570441391 0.00234659158 -1.4472781 35.134535163.3575382 154 27.9640051298 3.66581 0.03757857686 0.00234109797 -1.4250597 35.66783864.3304329 155 29.167845911 3.7279 0.0395405603 0.00233563004 -1.4029572 36.215539465.3316618 156 30.4772939578 3.78899 0.04159314958 0.00233018758 -1.3809782 36.77919266.3643082 157 31.909494862 3.84886 0.04373980166 0.00232477043 -1.3591232 37.360531367.4321148 158 33.4859745978 3.90726 0.04598469526 0.00231937841 -1.3373867 37.961664468.5395881 159 35.2340696741 3.96389 0.04833111312 0.00231401134 -1.3157732 38.585128369.6920126 160 37.1887542229 4.0184 0.050782343 0.00230866905 -1.2942873 39.233897970.8962643 161 39.3967444568 4.07037 0.05334209475 0.00230335138 -1.2729299 39.911844172.1605529 162 41.9203566324 4.11929 0.05601406438 0.00229805814 -1.2517029 40.623588873.4955297 163 44.8463928727 4.16456 0.05880180592 0.00229278918 -1.2306093 41.375128174.9151448 164 48.2996237446 4.2054 0.06170787995 0.00228754432 -1.2096594 42.174315476.4381217 165 52.4669501927 4.24079 0.06473602915 0.00228232341 -1.1888539 43.031691278.0904576 166 57.6435054399 4.26938 0.0678882736 0.00227712627 -1.1682052 43.96189179.9103051 167 64.3302396182 4.28924 0.07116597833 0.00227195274 -1.1477276 44.986393281.9570985 168 73.4625362321 4.29746 0.07456888434 0.00226680267 -1.1274424 46.138656984.3328393 169 87.0546844556 4.28916 0.07809330155 0.0022616759 -1.1073862 47.476104987.2413504 170 110.586825766 4.2548 0.08172704333 0.00225657227 -1.0876342 49.113481387.5763269 170.1 114.004615663 4.24924 0.0820952145 0.00225606317 -1.0856822 49.302059887.9219921 170.2 117.730213461 4.24317 0.08246444409 0.0022555543 -1.0837333 49.496655588.2793407 170.3 121.812753329 4.23655 0.08283448898 0.00225504566 -1.0817888 49.697828688.6494573 170.4 126.31216416 4.22932 0.08320468116 0.00225453726 -1.0798522 49.906189688.7251002 170.42 127.268090705 4.22779 0.08327863209 0.0022544356 -1.0794664 49.9487735

t p0 H2O m x p y p H3BO3 p0' H3BO3C atm H3BO3 H3BO3 atm H3BO3 atm atm

0 0.00602853 0.02000706738 0.00036031 0.00602636 9.28788E-07 5.5972E-09 5.5001E-061 0.00648114 0.02000709498 0.00036031 0.00647881 9.48631E-07 6.146E-09 6.0333E-062 0.00696361 0.0200070674 0.00036031 0.00696111 9.68953E-07 6.745E-09 6.6146E-063 0.0074776 0.02000709573 0.00036031 0.00747491 9.89752E-07 7.3983E-09 7.2481E-064 0.00802487 0.02000706879 0.00036031 0.00802199 0.00000101103 8.1105E-09 7.938E-065 0.00860727 0.02000709767 0.00036031 0.00860418 0.00000103278 8.8862E-09 8.6888E-066 0.00922671 0.02000707119 0.00036031 0.00922339 0.00000105501 9.7308E-09 9.5053E-067 0.00988518 0.02000710044 0.00036031 0.00988163 0.00000107771 1.065E-08 1.0393E-05

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8 0.0105848 0.02000707426 0.00036031 0.010581 0.00000110088 1.1648E-08 1.1357E-059 0.0113277 0.02000710375 0.00036031 0.0113236 0.00000112453 1.2734E-08 1.2403E-05

10 0.0121162 0.02000707774 0.00036031 0.0121119 0.00000114865 1.3912E-08 1.3539E-0511 0.0129527 0.02000710736 0.00036031 0.012948 0.00000117325 1.5191E-08 1.477E-0512 0.0138396 0.02000708143 0.00036031 0.0138346 0.00000119831 1.6578E-08 1.6103E-0513 0.0147794 0.02000711107 0.00036031 0.0147741 0.00000122386 1.8081E-08 1.7547E-0514 0.0157749 0.02000708512 0.00036031 0.0157693 0.00000124987 1.971E-08 1.911E-0515 0.0168289 0.02000705913 0.00036031 0.0168229 0.00000127636 2.1472E-08 2.0801E-0516 0.0179442 0.02000708865 0.00036031 0.0179378 0.00000130332 2.3379E-08 2.2628E-0517 0.0191238 0.02000706254 0.00036031 0.019117 0.00000133075 2.544E-08 2.4601E-0518 0.0203709 0.02000709189 0.00036031 0.0203636 0.00000135866 2.7667E-08 2.6732E-0519 0.0216887 0.02000706558 0.00036031 0.0216809 0.00000138705 3.0072E-08 2.903E-0520 0.0230805 0.02000709471 0.00036031 0.0230722 0.00000141591 3.2668E-08 3.1509E-0521 0.0245498 0.02000706814 0.00036031 0.024541 0.00000144524 3.5468E-08 3.418E-0522 0.0261003 0.020007097 0.00036031 0.026091 0.00000147505 3.8486E-08 3.7057E-0523 0.0277357 0.02000707012 0.00036031 0.0277258 0.00000150533 4.1736E-08 4.0154E-0524 0.0294599 0.02000709866 0.00036031 0.0294494 0.00000153608 4.5237E-08 4.3485E-0525 0.0312769 0.02000707144 0.00036031 0.0312657 0.00000156732 4.9003E-08 4.7067E-0526 0.0331909 0.02000709961 0.00036031 0.033179 0.00000159902 5.3054E-08 5.0916E-0527 0.0352062 0.02000707201 0.00036031 0.0351936 0.00000163121 5.7408E-08 5.5049E-0528 0.0373272 0.02000709977 0.00036031 0.0373138 0.00000166386 6.2085E-08 5.9486E-0529 0.0395586 0.02000707175 0.00036031 0.0395444 0.000001697 6.7107E-08 6.4246E-0530 0.0419051 0.02000709908 0.00036031 0.04189 0.0000017306 7.2495E-08 6.9349E-0531 0.0443716 0.02000707061 0.00036031 0.0443557 0.00000176469 7.8274E-08 7.4818E-0532 0.0469633 0.02000709747 0.00036031 0.0469464 0.00000179924 8.4468E-08 8.0675E-0533 0.0496854 0.02000706852 0.00036031 0.0496675 0.00000183427 9.1104E-08 8.6944E-0534 0.0525432 0.02000709489 0.00036031 0.0525244 0.00000186978 9.8209E-08 9.3652E-0535 0.0555425 0.02000706544 0.00036031 0.0555226 0.00000190576 1.0581E-07 0.0001008236 0.058689 0.02000709129 0.00036031 0.0586679 0.00000194221 1.1395E-07 0.0001084937 0.0619886 0.0200070613 0.00036031 0.0619663 0.00000197914 1.2264E-07 0.0001166838 0.0654474 0.02000708661 0.00036031 0.0654239 0.00000201653 1.3193E-07 0.0001254239 0.0690718 0.02000705608 0.00036031 0.0690471 0.0000020544 1.4185E-07 0.0001347540 0.0728683 0.02000708083 0.00036031 0.0728422 0.00000209274 1.5244E-07 0.000144741 0.0768437 0.0200071053 0.00036031 0.0768161 0.00000213155 1.6374E-07 0.000155342 0.0810047 0.02000707391 0.00036031 0.0809756 0.00000217084 1.7579E-07 0.000166643 0.0853585 0.02000709779 0.00036031 0.0853278 0.00000221059 1.8862E-07 0.0001786444 0.0899123 0.0200070658 0.00036031 0.0898801 0.00000225081 2.023E-07 0.0001914545 0.0946738 0.02000708908 0.00036031 0.0946399 0.00000229149 2.1687E-07 0.0002050846 0.0996507 0.02000705648 0.00036031 0.0996149 0.00000233265 2.3237E-07 0.0002195747 0.104851 0.02000707913 0.00036031 0.104813 0.00000237427 2.4885E-07 0.0002349748 0.110282 0.02000710148 0.00036031 0.110243 0.00000241635 2.6639E-07 0.0002513449 0.115954 0.02000706794 0.00036031 0.115912 0.0000024589 2.8502E-07 0.0002687150 0.121873 0.02000708965 0.00036031 0.12183 0.00000250191 3.0481E-07 0.0002871651 0.12805 0.02000705546 0.00036031 0.128004 0.00000254539 3.2582E-07 0.0003067352 0.134493 0.02000707653 0.00036031 0.134445 0.00000258932 3.4812E-07 0.0003274853 0.141212 0.02000709726 0.00036031 0.141161 0.00000263372 3.7178E-07 0.0003494754 0.148216 0.02000706209 0.00036031 0.148163 0.00000267857 3.9686E-07 0.0003727755 0.155514 0.02000708216 0.00036031 0.155459 0.00000272389 4.2345E-07 0.0003974456 0.163118 0.02000710189 0.00036031 0.163059 0.00000276966 4.5162E-07 0.0004235657 0.171036 0.02000706572 0.00036031 0.170975 0.00000281588 4.8145E-07 0.000451258 0.179281 0.02000708477 0.00036031 0.179216 0.00000286256 5.1302E-07 0.0004804259 0.187861 0.02000710349 0.00036031 0.187794 0.0000029097 5.4642E-07 0.0005113260 0.196789 0.02000706629 0.00036031 0.196719 0.00000295728 5.8175E-07 0.0005439761 0.206076 0.02000708431 0.00036031 0.206002 0.00000300532 6.191E-07 0.00057845

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62 0.215733 0.02000710199 0.00036031 0.215655 0.0000030538 6.5857E-07 0.0006148663 0.225772 0.02000706375 0.00036031 0.225691 0.00000310274 7.0026E-07 0.0006532864 0.236205 0.02000708073 0.00036031 0.23612 0.00000315212 7.4428E-07 0.0006938265 0.247044 0.02000709735 0.00036031 0.246956 0.00000320195 7.9074E-07 0.0007365666 0.258303 0.02000705806 0.00036031 0.25821 0.00000325222 8.3976E-07 0.0007816167 0.269994 0.02000707398 0.00036031 0.269897 0.00000330293 8.9145E-07 0.0008290868 0.282129 0.02000708954 0.00036031 0.282028 0.00000335409 9.4595E-07 0.0008790769 0.294724 0.02000710475 0.00036031 0.294618 0.00000340569 1.0034E-06 0.000931770 0.30779 0.02000706403 0.00036031 0.30768 0.00000345773 1.0639E-06 0.0009870971 0.321344 0.02000707852 0.00036031 0.321229 0.0000035102 1.1276E-06 0.0010453672 0.335398 0.02000709265 0.00036031 0.335277 0.00000356312 1.1946E-06 0.0011066373 0.349967 0.02000710642 0.00036031 0.349842 0.00000361647 1.2652E-06 0.0011710474 0.365067 0.02000706426 0.00036031 0.364936 0.00000367025 1.3394E-06 0.0012387275 0.380712 0.02000707731 0.00036031 0.380575 0.00000372447 1.4174E-06 0.0013098176 0.396918 0.02000709 0.00036031 0.396776 0.00000377913 1.4995E-06 0.0013844577 0.413701 0.02000710232 0.00036031 0.413553 0.00000383421 1.5856E-06 0.0014627978 0.431078 0.02000705871 0.00036031 0.430923 0.00000388972 1.6762E-06 0.0015449979 0.449063 0.0200070703 0.00036031 0.448902 0.00000394567 1.7712E-06 0.0016312180 0.467675 0.02000708153 0.00036031 0.467507 0.00000400204 1.871E-06 0.001721681 0.48693 0.02000709239 0.00036031 0.486756 0.00000405884 1.9757E-06 0.0018163482 0.506846 0.02000710289 0.00036031 0.506665 0.00000411606 2.0855E-06 0.0019156183 0.527441 0.02000705746 0.00036031 0.527252 0.00000417371 2.2006E-06 0.0020195784 0.548732 0.02000706723 0.00036031 0.548535 0.00000423179 2.3213E-06 0.0021284185 0.570737 0.02000707663 0.00036031 0.570532 0.00000429029 2.4477E-06 0.0022423486 0.593476 0.02000708566 0.00036031 0.593263 0.00000434921 2.5802E-06 0.0023615387 0.616968 0.02000709433 0.00036031 0.616746 0.00000440856 2.719E-06 0.0024862188 0.641231 0.02000710264 0.00036031 0.641001 0.00000446833 2.8642E-06 0.0026165689 0.666286 0.02000711058 0.00036031 0.666047 0.00000452852 3.0162E-06 0.0027528190 0.692152 0.02000706258 0.00036031 0.691904 0.00000458913 3.1752E-06 0.0028951791 0.71885 0.02000706979 0.00036031 0.718592 0.00000465016 3.3416E-06 0.0030438892 0.746401 0.02000707663 0.00036031 0.746133 0.00000471161 3.5155E-06 0.0031991693 0.774825 0.02000708311 0.00036031 0.774547 0.00000477348 3.6973E-06 0.0033612694 0.804144 0.02000708922 0.00036031 0.803855 0.00000483576 3.8872E-06 0.0035304195 0.834379 0.02000709497 0.00036031 0.83408 0.00000489847 4.0857E-06 0.0037068796 0.865553 0.02000710035 0.00036031 0.865242 0.0000049616 4.293E-06 0.0038909197 0.897688 0.02000710537 0.00036031 0.897366 0.00000502514 4.5094E-06 0.0040827898 0.930807 0.02000711003 0.00036031 0.930472 0.0000050891 4.7353E-06 0.0042827599 0.964932 0.02000705876 0.00036031 0.964585 0.00000515348 4.971E-06 0.00449112

100 1.00009 0.02000706269 0.00036031 0.999728 0.00000521828 5.2169E-06 0.00470816101 1.0363 0.02000706627 0.00036031 1.03592 0.00000528349 5.4733E-06 0.00493416102 1.07358 0.02000706949 0.00036031 1.0732 0.00000534913 5.7407E-06 0.00516943103 1.11197 0.02000707234 0.00036031 1.11157 0.00000541518 6.0194E-06 0.00541427104 1.15149 0.02000707484 0.00036031 1.15108 0.00000548166 6.3098E-06 0.00566901105 1.19216 0.02000707698 0.00036031 1.19173 0.00000554855 6.6124E-06 0.00593397106 1.23401 0.02000707877 0.00036031 1.23356 0.00000561587 6.9275E-06 0.00620947107 1.27706 0.0200070802 0.00036031 1.2766 0.0000056836 7.2557E-06 0.00649585108 1.32134 0.02000708127 0.00036031 1.32086 0.00000575176 7.5973E-06 0.00679347109 1.36688 0.020007082 0.00036031 1.36639 0.00000582034 7.9529E-06 0.00710268110 1.4137 0.02000708237 0.00036031 1.41319 0.00000588935 8.3228E-06 0.00742383111 1.46183 0.02000708239 0.00036031 1.46131 0.00000595877 8.7076E-06 0.0077573112 1.5113 0.02000708206 0.00036031 1.51076 0.00000602863 9.1078E-06 0.00810347113 1.56214 0.02000708139 0.00036031 1.56158 0.00000609891 9.5239E-06 0.00846273114 1.61438 0.02000708037 0.00036031 1.61379 0.00000616962 9.9565E-06 0.00883549115 1.66803 0.020007079 0.00036031 1.66743 0.00000624076 1.0406E-05 0.0092221

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116 1.72314 0.02000707729 0.00036031 1.72252 0.00000631233 1.0873E-05 0.00962304117 1.77974 0.02000707524 0.00036031 1.7791 0.00000638434 1.1358E-05 0.01003864118 1.83784 0.02000707285 0.00036031 1.83718 0.00000645678 1.1862E-05 0.01046947119 1.89749 0.02000707012 0.00036031 1.89681 0.00000652965 1.2386E-05 0.01091579120 1.95871 0.02000706706 0.00036031 1.95801 0.00000660297 1.2929E-05 0.0113782121 2.02154 0.02000706366 0.00036031 2.02081 0.00000667672 1.3492E-05 0.01185718122 2.086 0.02000705992 0.00036031 2.08525 0.00000675092 1.4077E-05 0.01235294123 2.15213 0.02000705586 0.00036031 2.15135 0.00000682556 1.4684E-05 0.01286629124 2.21996 0.02000710704 0.00036031 2.21915 0.00000690065 1.5314E-05 0.01339743125 2.28952 0.02000710231 0.00036031 2.28869 0.00000697619 1.5966E-05 0.01394715126 2.36084 0.02000709727 0.00036031 2.35999 0.00000705218 1.6643E-05 0.01451569127 2.43396 0.02000709191 0.00036031 2.43308 0.00000712863 1.7345E-05 0.0151035128 2.50891 0.02000708622 0.00036031 2.50801 0.00000720554 1.8072E-05 0.01571143129 2.58573 0.02000708022 0.00036031 2.5848 0.0000072829 1.8825E-05 0.01633974130 2.66445 0.02000707389 0.00036031 2.66349 0.00000736073 1.9605E-05 0.01698915131 2.7451 0.02000706726 0.00036031 2.74411 0.00000743903 2.0414E-05 0.01766004132 2.82772 0.02000706031 0.00036031 2.8267 0.0000075178 2.1251E-05 0.01835306133 2.91235 0.02000710862 0.00036031 2.91129 0.00000759705 2.2117E-05 0.01906873134 2.99901 0.02000710106 0.00036031 2.99793 0.00000767677 2.3014E-05 0.01980773135 3.08775 0.0200070932 0.00036031 3.08664 0.00000775698 2.3943E-05 0.02057044136 3.17861 0.02000708503 0.00036031 3.17746 0.00000783767 2.4904E-05 0.02135771137 3.27161 0.02000707657 0.00036031 3.27043 0.00000791885 2.5898E-05 0.0221701138 3.3668 0.02000706781 0.00036031 3.36558 0.00000800052 2.6926E-05 0.02300802139 3.46422 0.02000705876 0.00036031 3.46296 0.0000080827 2.799E-05 0.02387221140 3.56389 0.02000710498 0.00036031 3.5626 0.00000816538 2.909E-05 0.02476344141 3.66587 0.02000709536 0.00036031 3.66454 0.00000824856 3.0227E-05 0.02568224142 3.77019 0.02000708544 0.00036031 3.76882 0.00000833226 3.1403E-05 0.02662911143 3.87688 0.02000707525 0.00036031 3.87547 0.00000841647 3.2618E-05 0.02760496144 3.98599 0.02000706477 0.00036031 3.98454 0.00000850121 3.3873E-05 0.02861027145 4.09756 0.0200071096 0.00036031 4.09607 0.00000858648 3.5171E-05 0.02964602146 4.21163 0.02000709858 0.00036031 4.2101 0.00000867227 3.6511E-05 0.03071265147 4.32823 0.02000708729 0.00036031 4.32666 0.00000875861 3.7896E-05 0.03181103148 4.44742 0.02000707573 0.00036031 4.4458 0.00000884549 3.9325E-05 0.03294181149 4.56922 0.02000706392 0.00036031 4.56756 0.00000893292 4.0802E-05 0.03410529150 4.69369 0.02000710741 0.00036031 4.69197 0.00000902091 4.2326E-05 0.03530307151 4.82085 0.02000709508 0.00036031 4.8191 0.00000910946 4.3899E-05 0.03653515152 4.95077 0.0200070825 0.00036031 4.94896 0.00000919858 4.5523E-05 0.0378027153 5.08347 0.02000706967 0.00036031 5.08162 0.00000928827 4.7199E-05 0.03910635154 5.21901 0.02000705659 0.00036031 5.2171 0.00000937855 4.8929E-05 0.04044676155 5.35741 0.02000709884 0.00036031 5.35546 0.00000946942 5.0713E-05 0.04182507156 5.49874 0.02000708529 0.00036031 5.49673 0.00000956088 5.2554E-05 0.04324165157 5.64303 0.02000707149 0.00036031 5.64097 0.00000965294 5.4452E-05 0.04469762158 5.79033 0.02000705747 0.00036031 5.78821 0.00000974562 5.641E-05 0.04619353159 5.94068 0.0200070988 0.00036031 5.9385 0.00000983891 5.8428E-05 0.04773038160 6.09412 0.02000708432 0.00036031 6.09189 0.00000993283 6.051E-05 0.04930919161 6.25071 0.02000706963 0.00036031 6.24842 0.0000100274 6.2655E-05 0.05093053162 6.41049 0.02000711029 0.00036031 6.40814 0.0000101226 6.4867E-05 0.05259537163 6.5735 0.02000709517 0.00036031 6.57108 0.0000102184 6.7146E-05 0.05430458164 6.73979 0.02000707984 0.00036031 6.73731 0.0000103149 6.9495E-05 0.05605873165 6.90941 0.02000706431 0.00036031 6.90687 0.0000104121 7.1915E-05 0.05785929166 7.0824 0.02000710415 0.00036031 7.0798 0.0000105099 7.4408E-05 0.05970644167 7.25882 0.02000708822 0.00036031 7.25615 0.0000106085 7.6977E-05 0.06160195168 7.43871 0.02000707211 0.00036031 7.43597 0.0000107077 7.9622E-05 0.06354599169 7.62212 0.0200070558 0.00036031 7.61931 0.0000108076 8.2346E-05 0.06554012

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170 7.80909 0.02000709489 0.00036031 7.80621 0.0000109083 8.5152E-05 0.06758473171 7.99968 0.02000707822 0.00036031 7.99673 0.0000110097 8.8042E-05 0.06968094172 8.19394 0.02000706137 0.00036031 8.19091 0.0000111118 9.1016E-05 0.07182997173 8.39191 0.02000709992 0.00036031 8.38881 0.0000112146 9.4077E-05 0.07403263174 8.59365 0.02000708273 0.00036031 8.59047 0.0000113182 9.7229E-05 0.07628961175 8.7992 0.02000706538 0.00036031 8.79594 0.0000114226 0.00010047 0.07860235176 9.00862 0.02000710344 0.00036031 9.00528 0.0000115277 0.00010381 0.08097149177 9.22196 0.02000708576 0.00036031 9.21854 0.0000116337 0.00010725 0.08339832178 9.43926 0.02000706793 0.00036031 9.43576 0.0000117404 0.00011078 0.08588367179 9.66059 0.02000710553 0.00036031 9.657 0.000011848 0.00011442 0.08842887180 9.88599 0.0200070874 0.00036031 9.88232 0.0000119563 0.00011816 0.09103458181 10.1155 0.02000706914 0.00036031 10.1118 0.0000120655 0.000122 0.09370207182 10.3492 0.0200071063 0.00036031 10.3454 0.0000121756 0.00012596 0.09643221183 10.5871 0.02000708776 0.00036031 10.5832 0.0000122865 0.00013003 0.09922673184 10.8294 0.02000706909 0.00036031 10.8253 0.0000123983 0.00013422 0.10208567185 11.0759 0.02000710586 0.00036031 11.0718 0.000012511 0.00013852 0.10501085186 11.3269 0.02000708693 0.00036031 11.3226 0.0000126246 0.00014294 0.10800311187 11.5823 0.0200070679 0.00036031 11.5779 0.0000127391 0.00014749 0.11106371188 11.8421 0.0200071043 0.00036031 11.8377 0.0000128545 0.00015217 0.11419366189 12.1066 0.02000708503 0.00036031 12.1021 0.0000129709 0.00015698 0.11739442190 12.3757 0.02000706565 0.00036031 12.371 0.0000130882 0.00016191 0.12066652191 12.6494 0.02000710173 0.00036031 12.6446 0.0000132065 0.00016699 0.12401152192 12.9278 0.02000708215 0.00036031 12.923 0.0000133258 0.00017221 0.12743067193 13.2111 0.02000706247 0.00036031 13.2061 0.0000134461 0.00017757 0.1309251194 13.4991 0.02000709826 0.00036031 13.494 0.0000135674 0.00018308 0.1344955195 13.7921 0.02000707839 0.00036031 13.7869 0.0000136898 0.00018874 0.13814365196 14.09 0.02000705844 0.00036031 14.0847 0.0000138132 0.00019455 0.14187059197 14.3929 0.02000709397 0.00036031 14.3875 0.0000139376 0.00020053 0.14567747198 14.7009 0.02000707386 0.00036031 14.6953 0.0000140632 0.00020666 0.14956568199 15.014 0.02000710924 0.00036031 15.0083 0.0000141899 0.00021297 0.15353593200 15.3322 0.02000708898 0.00036031 15.3264 0.0000143177 0.00021944 0.15759052201 15.6557 0.02000706865 0.00036031 15.6498 0.0000144466 0.00022609 0.16172974202 15.9846 0.02000710383 0.00036031 15.9785 0.0000145767 0.00023291 0.16595463203 16.3187 0.02000708338 0.00036031 16.3126 0.000014708 0.00023993 0.17026792204 16.6583 0.02000706287 0.00036031 16.652 0.0000148405 0.00024712 0.17466951205 17.0034 0.02000709788 0.00036031 16.997 0.0000149741 0.00025451 0.17916144206 17.354 0.02000707727 0.00036031 17.3474 0.0000151091 0.0002621 0.18374455207 17.7102 0.02000705661 0.00036031 17.7035 0.0000152453 0.0002699 0.18842018208 18.0721 0.02000709148 0.00036031 18.0652 0.0000153827 0.00027789 0.1931903209 18.4397 0.02000707074 0.00036031 18.4327 0.0000155215 0.0002861 0.19805589210 18.8131 0.02000710553 0.00036031 18.8059 0.0000156616 0.00029453 0.20301765211 19.1923 0.02000708473 0.00036031 19.185 0.000015803 0.00030318 0.20807772212 19.5774 0.02000706389 0.00036031 19.5699 0.0000159458 0.00031206 0.21323799213 19.9685 0.0200070986 0.00036031 19.9609 0.00001609 0.00032117 0.21849826214 20.3657 0.02000707771 0.00036031 20.3579 0.0000162356 0.00033052 0.22386109215 20.7689 0.02000705681 0.00036031 20.7609 0.0000163827 0.00034012 0.22932744216 21.1783 0.02000709146 0.00036031 21.1701 0.0000165312 0.00034997 0.23489914217 21.5939 0.02000707053 0.00036031 21.5856 0.0000166812 0.00036007 0.24057713218 22.0158 0.02000710516 0.00036031 22.0073 0.0000168327 0.00037044 0.24636352219 22.444 0.02000708421 0.00036031 22.4354 0.0000169858 0.00038108 0.2522584220 22.8787 0.02000706326 0.00036031 22.8698 0.0000171404 0.000392 0.25826506221 23.3198 0.02000709788 0.00036031 23.3108 0.0000172966 0.0004032 0.26438385222 23.7675 0.02000707693 0.00036031 23.7583 0.0000174545 0.00041469 0.27061603223 24.2218 0.02000705599 0.00036031 24.2124 0.000017614 0.00042648 0.2769642

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224 24.6827 0.02000709062 0.00036031 24.6732 0.0000177751 0.00043857 0.28342881225 25.1504 0.0200070697 0.00036031 25.1407 0.000017938 0.00045097 0.29001179226 25.625 0.02000710435 0.00036031 25.615 0.0000181026 0.0004637 0.29671492227 26.1063 0.02000708346 0.00036031 26.0962 0.000018269 0.00047675 0.30353902228 26.5947 0.02000706258 0.00036031 26.5843 0.0000184372 0.00049014 0.31048609229 27.09 0.0200070973 0.00036031 27.0794 0.0000186072 0.00050387 0.31755833230 27.5924 0.02000707646 0.00036031 27.5816 0.0000187791 0.00051796 0.32475682231 28.102 0.02000705566 0.00036031 28.091 0.0000189529 0.00053241 0.33208261232 28.6187 0.02000709044 0.00036031 28.6075 0.0000191286 0.00054722 0.33953794233 29.1428 0.02000706969 0.00036031 29.1313 0.0000193063 0.00056242 0.34712432234 29.6741 0.02000710455 0.00036031 29.6625 0.000019486 0.000578 0.35484279235 30.2129 0.02000708387 0.00036031 30.2011 0.0000196677 0.00059399 0.36269681236 30.7592 0.02000706322 0.00036031 30.7471 0.0000198515 0.00061038 0.37068596237 31.3131 0.02000709819 0.00036031 31.3007 0.0000200374 0.00062718 0.37881271238 31.8745 0.02000707762 0.00036031 31.8619 0.0000202255 0.00064442 0.38707908239 32.4437 0.0200070571 0.00036031 32.4308 0.0000204157 0.0006621 0.39548606240 33.0206 0.0200070922 0.00036031 33.0075 0.0000206082 0.00068023 0.40403671241 33.6053 0.02000707176 0.00036031 33.592 0.000020803 0.00069881 0.41273094242 34.198 0.02000710695 0.00036031 34.1844 0.0000210001 0.00071788 0.42157129243 34.7986 0.02000708662 0.00036031 34.7848 0.0000211995 0.00073742 0.43056027244 35.4073 0.02000706634 0.00036031 35.3932 0.0000214014 0.00075746 0.43969915245 36.0241 0.02000710168 0.00036031 36.0097 0.0000216057 0.00077801 0.44898989246 36.649 0.0200070815 0.00036031 36.6344 0.0000218125 0.00079909 0.45843342247 37.2823 0.02000706138 0.00036031 37.2673 0.0000220218 0.00082069 0.46803255248 37.9238 0.02000709689 0.00036031 37.9086 0.0000222337 0.00084285 0.47778959249 38.5738 0.02000707689 0.00036031 38.5583 0.0000224483 0.00086557 0.48770507250 39.2322 0.02000705695 0.00036031 39.2165 0.0000226655 0.00088886 0.49778163251 39.8992 0.02000709264 0.00036031 39.8832 0.0000228855 0.00091275 0.50802031252 40.5748 0.02000707283 0.00036031 40.5585 0.0000231083 0.00093724 0.51842485253 41.2591 0.02000710864 0.00036031 41.2425 0.0000233339 0.00096235 0.5289961254 41.9522 0.02000708895 0.00036031 41.9352 0.0000235624 0.00098809 0.53973539255 42.6541 0.02000706933 0.00036031 42.6369 0.0000237939 0.0010145 0.55064616256 43.365 0.02000710534 0.00036031 43.3474 0.0000240284 0.00104157 0.56172954257 44.0848 0.02000708586 0.00036031 44.0669 0.000024266 0.00106933 0.57298761258 44.8137 0.02000706644 0.00036031 44.7955 0.0000245067 0.00109779 0.58442014259 45.5517 0.02000710266 0.00036031 45.5332 0.0000247506 0.00112697 0.59603642260 46.299 0.02000708338 0.00036031 46.2801 0.0000249977 0.0011569 0.60783044261 47.0555 0.02000706418 0.00036031 47.0363 0.0000252482 0.00118758 0.61981226262 47.8214 0.02000710061 0.00036031 47.8018 0.0000255021 0.00121905 0.63197393263 48.5968 0.02000708155 0.00036031 48.5768 0.0000257595 0.00125131 0.64432241264 49.3816 0.02000706256 0.00036031 49.3613 0.0000260203 0.0012844 0.65686589265 50.1761 0.02000709921 0.00036031 50.1554 0.0000262848 0.00131832 0.66959832266 50.9802 0.02000708037 0.00036031 50.9592 0.0000265529 0.00135311 0.68253072267 51.7941 0.0200070616 0.00036031 51.7727 0.0000268248 0.00138879 0.69565409268 52.6178 0.02000709848 0.00036031 52.596 0.0000271006 0.00142538 0.70897443269 53.4514 0.02000707986 0.00036031 53.4292 0.0000273802 0.0014629 0.72250285270 54.295 0.02000706132 0.00036031 54.2724 0.0000276638 0.00150138 0.73623022271 55.1486 0.02000709842 0.00036031 55.1257 0.0000279515 0.00154085 0.75016768272 56.0124 0.02000708003 0.00036031 55.9891 0.0000282433 0.00158132 0.76431108273 56.8864 0.02000706172 0.00036031 56.8626 0.0000285394 0.00162282 0.77866649274 57.7707 0.02000709905 0.00036031 57.7465 0.0000288398 0.0016654 0.7932336275 58.6653 0.02000708089 0.00036031 58.6407 0.0000291446 0.00170906 0.80802097276 59.5704 0.02000706281 0.00036031 59.5454 0.000029454 0.00175385 0.82302179277 60.486 0.02000710037 0.00036031 60.4606 0.0000297679 0.00179979 0.83824989

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278 61.4123 0.02000708244 0.00036031 61.3864 0.0000300866 0.00184691 0.85370491279 62.3492 0.02000706458 0.00036031 62.3228 0.0000304101 0.00189524 0.86938243280 63.2968 0.02000710237 0.00036031 63.27 0.0000307385 0.00194482 0.88528851281 64.2553 0.02000708467 0.00036031 64.2281 0.000031072 0.0019957 0.90143057282 65.2248 0.02000706704 0.00036031 65.1971 0.0000314106 0.00204788 0.91780807283 66.2052 0.02000710506 0.00036031 66.1771 0.0000317544 0.00210141 0.93442986284 67.1968 0.02000708759 0.00036031 67.1681 0.0000321037 0.00215634 0.95128723285 68.1995 0.02000707019 0.00036031 68.1703 0.0000324584 0.0022127 0.96839041286 69.2134 0.02000710843 0.00036031 69.1838 0.0000328187 0.00227052 0.98573726287 70.2387 0.02000709118 0.00036031 70.2085 0.0000331848 0.00232986 1.00334354288 71.2753 0.020007074 0.00036031 71.2447 0.0000335568 0.00239074 1.02120169289 72.3235 0.0200070569 0.00036031 72.2923 0.0000339347 0.00245322 1.03931922290 73.3832 0.02000709544 0.00036031 73.3516 0.0000343189 0.00251735 1.05769678291 74.4546 0.02000707847 0.00036031 74.4224 0.0000347093 0.00258315 1.07634036292 75.5377 0.02000706159 0.00036031 75.505 0.0000351061 0.00265069 1.09525212293 76.6327 0.02000710033 0.00036031 76.5994 0.0000355096 0.00272001 1.11443106294 77.7395 0.02000708359 0.00036031 77.7057 0.0000359198 0.00279117 1.13389335295 78.8583 0.02000706691 0.00036031 78.8239 0.0000363369 0.00286422 1.15363636296 79.9892 0.02000710587 0.00036031 79.9542 0.0000367611 0.0029392 1.17365349297 81.1322 0.02000708932 0.00036031 81.0966 0.0000371926 0.00301619 1.19396978298 82.2882 0.02000707287 0.00036031 82.2521 0.000037632 0.00309531 1.21458964299 83.4572 0.02000705651 0.00036031 83.4205 0.0000380795 0.00317661 1.23551534300 84.6243 0.02000709536 0.00036031 84.587 0.0000385253 0.00325874 1.25660377301 85.7464 0.02000707696 0.00036031 85.7085 0.0000389406 0.00333754 1.27665878302 86.875 0.02000705854 0.00036031 86.8365 0.0000393602 0.0034179 1.2970618303 88.0084 0.02000709561 0.00036031 87.9694 0.0000397828 0.00349967 1.31771016304 89.1535 0.02000707724 0.00036031 89.114 0.000040213 0.00358354 1.33861656305 90.3076 0.02000705894 0.00036031 90.2675 0.0000406491 0.00366929 1.35979936306 91.4706 0.02000709624 0.00036031 91.4298 0.0000410912 0.00375696 1.38125134307 92.6424 0.02000707806 0.00036031 92.6011 0.0000415392 0.00384658 1.40298734308 93.8231 0.02000705993 0.00036031 93.7812 0.0000419932 0.00393817 1.42499262309 95.0126 0.02000709745 0.00036031 94.9701 0.0000424533 0.00403179 1.44729335310 96.2109 0.02000707947 0.00036031 96.1677 0.0000429194 0.00412746 1.46986529311 97.4179 0.02000706157 0.00036031 97.3741 0.0000433916 0.00422522 1.49273281312 98.6336 0.02000709931 0.00036031 98.5891 0.0000438699 0.00432509 1.515896313 99.8579 0.02000708158 0.00036031 99.8128 0.0000443543 0.00442713 1.53934934314 101.091 0.02000706394 0.00036031 101.045 0.0000448449 0.00453135 1.56310034315 102.332 0.02000710195 0.00036031 102.286 0.0000453416 0.00463781 1.58714897316 103.582 0.02000708449 0.00036031 103.535 0.0000458444 0.0047465 1.61149933317 104.841 0.02000706713 0.00036031 104.793 0.0000463533 0.0048575 1.6361548318 106.107 0.02000710543 0.00036031 106.059 0.0000468684 0.00497082 1.66112721319 107.382 0.02000708827 0.00036031 107.333 0.0000473896 0.00508647 1.68640113320 108.666 0.02000707122 0.00036031 108.616 0.0000479169 0.00520454 1.71200177321 109.957 0.02000710984 0.00036031 109.907 0.0000484502 0.00532502 1.73791139322 111.257 0.020007093 0.00036031 111.206 0.0000489895 0.00544793 1.7641498323 112.564 0.02000707629 0.00036031 112.512 0.0000495348 0.00557326 1.79070689324 113.88 0.02000705968 0.00036031 113.827 0.000050086 0.00570114 1.81759486325 115.203 0.02000709877 0.00036031 115.15 0.000050643 0.00583154 1.84480896326 116.534 0.02000708241 0.00036031 116.48 0.0000512058 0.00596445 1.87236387327 117.873 0.02000706617 0.00036031 117.818 0.0000517743 0.00609994 1.90024684328 119.219 0.02000710562 0.00036031 119.164 0.0000523485 0.00623806 1.92848067329 120.573 0.02000708964 0.00036031 120.517 0.0000529281 0.00637874 1.95705246330 121.934 0.02000707378 0.00036031 121.878 0.0000535131 0.00652207 1.98597235331 123.303 0.02000705806 0.00036031 123.245 0.0000541034 0.00666797 2.01524263

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332 124.678 0.02000709804 0.00036031 124.62 0.0000546988 0.00681656 2.0448711333 126.061 0.02000708259 0.00036031 126.002 0.0000552992 0.00696781 2.07484954334 127.45 0.02000706727 0.00036031 127.391 0.0000559044 0.00712172 2.10518828335 128.847 0.02000710767 0.00036031 128.787 0.0000565142 0.00727829 2.13589779336 130.25 0.02000709264 0.00036031 130.189 0.0000571286 0.00743752 2.16697259337 131.659 0.02000707775 0.00036031 131.598 0.0000577471 0.0075994 2.19842042338 133.075 0.020007063 0.00036031 133.013 0.0000583698 0.00776394 2.23023564339 134.498 0.02000710397 0.00036031 134.435 0.0000589962 0.00793115 2.26243153340 135.926 0.02000708952 0.00036031 135.862 0.0000596262 0.00810093 2.29501601341 137.36 0.02000707522 0.00036031 137.296 0.0000602596 0.0082734 2.32798071342 138.801 0.02000706108 0.00036031 138.735 0.000060896 0.00844841 2.36133637343 140.246 0.02000710265 0.00036031 140.18 0.0000615352 0.008626 2.39507982344 141.698 0.02000708882 0.00036031 141.631 0.0000621768 0.00880616 2.4292248345 143.154 0.02000707513 0.00036031 143.087 0.0000628206 0.00898881 2.46375991346 144.616 0.02000706161 0.00036031 144.548 0.0000634662 0.00917391 2.49871251347 146.083 0.02000710381 0.00036031 146.014 0.0000641133 0.00936144 2.53406588348 147.555 0.02000709061 0.00036031 147.485 0.0000647616 0.00955136 2.56982794349 149.031 0.02000707756 0.00036031 148.961 0.0000654106 0.00974363 2.60600976350 150.512 0.02000706468 0.00036031 150.441 0.00006606 0.00993813 2.64260277351 151.997 0.02000710753 0.00036031 151.925 0.0000667095 0.01013484 2.67962649352 153.486 0.02000709498 0.00036031 153.414 0.0000673585 0.01033374 2.71707746353 154.979 0.0200070826 0.00036031 154.906 0.0000680068 0.01053466 2.75495023354 156.476 0.02000707038 0.00036031 156.402 0.000068654 0.01073762 2.79326957355 157.977 0.02000705833 0.00036031 157.902 0.0000692995 0.01094253 2.83201841356 159.48 0.02000710203 0.00036031 159.405 0.000069943 0.01114926 2.87121157357 160.987 0.02000709032 0.00036031 160.911 0.000070584 0.01135774 2.91085036358 162.497 0.0200070788 0.00036031 162.419 0.0000712222 0.01156784 2.95094135359 164.009 0.02000706744 0.00036031 163.931 0.0000718572 0.01177962 2.99149272360 165.524 0.02000705625 0.00036031 165.445 0.0000724884 0.01199284 3.03249218361 167.041 0.02000710082 0.00036031 166.962 0.0000731155 0.01220751 3.07395982362 168.56 0.02000709 0.00036031 168.48 0.0000737381 0.0124234 3.11589899363 170.081 0.02000707935 0.00036031 170.001 0.0000743558 0.01264056 3.15830574364 171.604 0.02000706888 0.00036031 171.523 0.0000749682 0.01285877 3.20118715365 173.129 0.0200070586 0.00036031 173.047 0.000075575 0.01307803 3.24455247

t p0 H2O m x p y p H3BO3 p0' H3BO3C atm H3BO3 H3BO3 atm H3BO3 atm atm

99.998 0 0 1 0 099.998 9.9999337E-07 1.8015E-08 1 2.9314744E-10 2.9315E-1099.998 9.9999102E-06 1.8015E-07 1 2.9315144E-09 2.9315E-0999.998 9.9999251E-05 1.8015E-06 1 2.9318644E-08 2.9319E-0899.998 0.00099999547 1.8015E-05 1 2.933364E-07 2.9334E-07

100.003 0.00999995288 0.00018012 1 2.9349156E-06 2.9349E-06100.023 0.0499997133 0.00089995 1 1.4675888E-05 1.4676E-05100.048 0.09999911674 0.00179828 1 2.9349569E-05 2.935E-05100.098 0.19999867023 0.00359012 1 5.8687229E-05 5.8687E-05100.148 0.29999809992 0.00537553 1 8.8012093E-05 8.8012E-05100.198 0.39999759946 0.00715456 1 0.00011732459 0.00011732100.248 0.49999730613 0.00892724 1 0.00014662547 0.00014663100.297 0.59999912713 0.01069363 1 0.00017591427 0.00017591100.347 0.69999611696 0.01245366 1 0.00020519111 0.00020519100.396 0.79999724614 0.01420751 1 0.00023445499 0.00023445100.446 0.89999235459 0.01595503 1 0.00026370717 0.00026371100.495 0.99999333955 0.01769647 1 0.00029294717 0.00029295

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100.544 1.09999073643 0.0194317 1 0.0003221742 0.00032217100.593 1.19999504028 0.02116093 1 0.00035138928 0.00035139100.642 1.29999167809 0.02288393 1 0.00038059078 0.00038059100.691 1.39999140914 0.02460094 1 0.00040977998 0.00040978100.739 1.49999391088 0.02631196 1 0.00043895523 0.00043896100.788 1.59998709104 0.02801684 1 0.00046811752 0.00046812100.836 1.69999097037 0.02971594 1 0.00049726687 0.00049727100.885 1.7999908432 0.03140904 1 0.00052640127 0.0005264100.933 1.89998861017 0.0330962 1 0.00055552328 0.00055552100.981 1.99998428805 0.03477747 1 0.00058463081 0.00058463101.029 2.09998979228 0.03645306 1 0.00061372341 0.00061372101.077 2.19998750226 0.03812271 1 0.00064280206 0.0006428101.125 2.29998634351 0.03978661 1 0.00067186676 0.00067187101.173 2.39998520967 0.04144476 1 0.00070091553 0.00070092101.22 2.4999846158 0.0430972 1 0.00072995036 0.00072995

101.268 2.59998551849 0.04474398 1 0.00075896926 0.00075897101.315 2.69998420588 0.04638507 1 0.00078797321 0.00078797101.363 2.79998349393 0.04802053 1 0.00081696124 0.00081696101.41 2.89998348024 0.04965041 1 0.00084593333 0.00084593

101.457 2.99998049299 0.05127467 1 0.00087488949 0.00087489101.504 3.09997984805 0.05289342 1 0.00090382973 0.00090383101.551 3.19998254615 0.05450671 1 0.00093275403 0.00093275101.598 3.29997773167 0.05611439 1 0.00096166141 0.00096166101.644 3.39997960409 0.05771673 1 0.00099055187 0.00099055101.691 3.49998302094 0.05931365 1 0.00101942138 0.00101942101.737 3.5999789828 0.06090506 1 0.00104827997 0.00104828101.784 3.69997944961 0.06249116 1 0.00107711863 0.00107712101.83 3.79997885449 0.0640719 1 0.00110593738 0.00110594

101.876 3.89997698333 0.06564729 1 0.00113474621 0.00113475101.922 3.99997995861 0.06721747 1 0.00116353512 0.00116354101.968 4.0999734493 0.06878222 1 0.00119229294 0.00119229102.014 4.19997206947 0.07034182 1 0.00122104201 0.00122104102.06 4.29997037652 0.0718962 1 0.00124978116 0.00124978

102.106 4.39997066547 0.07344542 1 0.00127848914 0.00127849102.151 4.49997209962 0.07498949 1 0.00130717846 0.00130718102.197 4.5999675609 0.07652833 1 0.00133584788 0.00133585102.242 4.69996699205 0.07806213 1 0.00136450739 0.00136451102.287 4.79996827251 0.07959086 1 0.00139313562 0.00139314102.333 4.89997062335 0.08111455 1 0.0014217553 0.00142176102.378 4.99997166973 0.08263318 1 0.00145034365 0.00145034102.423 5.09996499263 0.08414669 1 0.00147892352 0.00147892102.468 5.19997224997 0.08565542 1 0.001507472 0.00150747102.512 5.29996713256 0.087159 1 0.00153600207 0.001536102.557 5.39996710419 0.08865772 1 0.00156451226 0.00156451102.602 5.49997114302 0.09015158 1 0.00159300096 0.001593102.646 5.59996995245 0.09164048 1 0.00162146972 0.00162147102.69 5.69996321128 0.09312444 1 0.00164992019 0.00164992

102.735 5.79996738972 0.09460371 1 0.0016783491 0.00167835102.779 5.89996860306 0.09607812 1 0.0017067498 0.00170675102.823 5.99995937208 0.09754759 1 0.00173512888 0.00173513102.867 6.09996235548 0.09901246 1 0.00176348804 0.00176349102.911 6.1999639721 0.10047256 1 0.00179181907 0.00179182102.955 6.29996258603 0.1019279 1 0.00182013839 0.00182014102.998 6.39996302662 0.10337856 1 0.0018484278 0.00184843

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103.042 6.49993883736 0.10482419 1 0.00187668918 0.00187669103.085 6.59998764299 0.10626621 1 0.00190493877 0.00190494103.129 6.69994051165 0.10770222 1 0.00193314847 0.00193315103.134 6.71191304213 0.10787392 1 0.00193653088 0.00193653103.134 6.71191304213 0.10787392 1 0.00193653088 0.00193653

w% t m p p B 1/T log(p) w%H3BO3 C H3BO3 atm atm B2O345.2613913 -2 13.372723547 0.00426219 2.8057407E-06 0.00368799557 -5.5519525 25.480415445.7438007 -1 13.6354225497 0.00457262 3.1234029E-06 0.00367444424 -5.505372 25.751993246.2171017 0 13.897741416 0.00490285 3.4739671E-06 0.00366099213 -5.4591743 26.018443146.6797693 1 14.1586681834 0.00525367 3.8603161E-06 0.00364763815 -5.4133771 26.27890747.1331385 2 14.4187812755 0.00562641 4.2859165E-06 0.00363438125 -5.3679563 26.534136247.5778787 3 14.6783150907 0.00602223 4.7543715E-06 0.00362122035 -5.3229069 26.784507548.0140619 4 14.9371686683 0.00644231 5.2695503E-06 0.00360815443 -5.2782264 27.030061648.4422635 5 15.195545926 0.00688791 5.8356551E-06 0.00359518246 -5.2339104 27.271122448.8626906 6 15.4534420002 0.00736033 6.4572149E-06 0.00358230342 -5.1899548 27.507806549.2755755 7 15.7108723133 0.00786092 7.1391056E-06 0.00356951633 -5.1463562 27.740244549.6814188 8 15.9680294806 0.00839109 7.8865946E-06 0.0035568202 -5.1031105 27.968718550.0802939 9 16.2248455697 0.0089523 8.7053406E-06 0.00354421407 -5.0602142 28.193269650.4727056 10 16.4815368034 0.00954606 9.6014426E-06 0.00353169698 -5.0176635 28.414182

50.85864 11 16.7379895976 0.0101739 1.058138E-05 0.00351926799 -4.9754577 28.63144851.23852 12 16.9943837055 0.0108376 1.1652388E-05 0.00350692618 -4.9335851 28.8453056

51.6125689 13 17.2507758558 0.0115387 1.2821824E-05 0.00349467063 -4.8920502 29.055880551.9809445 14 17.5071831743 0.0122789 1.4097799E-05 0.00348250044 -4.8508487 29.263261652.3439967 15 17.7637635913 0.0130602 1.5489038E-05 0.00347041471 -4.8099756 29.467645752.7017679 16 18.0204652197 0.0138844 1.7004961E-05 0.00345841259 -4.7694244 29.66905753.0544628 17 18.2773543057 0.0147534 1.8655268E-05 0.00344649319 -4.7291985 29.867610453.402351 18 18.5345519965 0.0156693 2.0450993E-05 0.00343465568 -4.6892856 30.0634578

53.7455604 19 18.7920818205 0.016634 2.240307E-05 0.0034228992 -4.6496925 30.256671354.0843498 20 19.0500709501 0.0176498 2.4523753E-05 0.00341122292 -4.6104131 30.447396554.4188702 21 19.3085720504 0.0187189 2.6826326E-05 0.00339962604 -4.5714388 30.635718354.7491735 22 19.5675645153 0.0198436 2.9324583E-05 0.00338810774 -4.5327682 30.821666255.0754097 23 19.827106224 0.0210262 3.2032889E-05 0.00337666723 -4.4944039 31.005324455.3979095 24 20.0874072299 0.0222691 3.4967073E-05 0.00336530372 -4.4563407 31.186879255.7166897 25 20.3484320729 0.0235749 3.8144352E-05 0.00335401643 -4.4185698 31.3663456.0318813 26 20.6102397179 0.0249462 4.158202E-05 0.00334280461 -4.3810944 31.543780556.3436231 27 20.8729004476 0.0263856 4.5299294E-05 0.0033316675 -4.3439086 31.719278956.652075 28 21.1365076393 0.0278958 4.9315859E-05 0.00332060435 -4.3070134 31.892925256.957302 29 21.4010778252 0.0294797 5.3653653E-05 0.00330961443 -4.2704007 32.0647561

57.2595844 30 21.6668198928 0.0311402 5.8334963E-05 0.00329869701 -4.2340711 32.234929257.5588193 31 21.9336112421 0.0328803 6.3384115E-05 0.00328785139 -4.1980196 32.403386757.8552744 32 22.2016601397 0.0347029 6.8826029E-05 0.00327707685 -4.1622473 32.570279458.1490135 33 22.4709986604 0.0366114 7.4688545E-05 0.00326637269 -4.126746 32.735642958.4401007 34 22.7416615134 0.0386089 8.0999424E-05 0.00325573824 -4.0915181 32.899513658.7286346 35 23.0137181065 0.0406988 8.7789688E-05 0.00324517281 -4.0565565 33.061946959.0148308 36 23.2873546132 0.0428844 9.509099E-05 0.00323467572 -4.0218606 33.223064159.2986629 37 23.5625314441 0.0451692 0.00010293666 0.00322424633 -3.9874299 33.382850559.5803164 38 23.8394163301 0.0475569 0.00011136329 0.00321388398 -3.9532579 33.541410459.859811 39 24.1180199843 0.050051 0.00012040758 0.00320358802 -3.9193462 33.6987548

60.1372344 40 24.3984225597 0.0526555 0.00013011014 0.00319335782 -3.8856888 33.854933360.4127417 41 24.6807778448 0.0553741 0.00014051309 0.00318319274 -3.8522832 34.010033160.6863934 42 24.965149013 0.0582107 0.00015165952 0.00317309218 -3.8191303 34.164088360.9582153 43 25.2515652208 0.0611694 0.00016359619 0.00316305551 -3.7862268 34.3171133

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61.2282904 44 25.5401183122 0.0642544 0.00017637337 0.00315308214 -3.753567 34.469155161.4967763 45 25.8309857834 0.0674698 0.00019004134 0.00314317146 -3.7211519 34.620302161.7637675 46 26.1242847276 0.07082 0.00020465504 0.00313332289 -3.6889776 34.770607662.0292051 47 26.4199657262 0.0743093 0.00022027097 0.00312353584 -3.6570427 34.920038662.2932453 48 26.7182201139 0.0779423 0.00023694933 0.00311380975 -3.6253445 35.068682862.5559742 49 27.0191684513 0.0817236 0.00025475336 0.00310414403 -3.5938801 35.216588962.8173937 50 27.3228380335 0.0856578 0.00027374889 0.00309453814 -3.5626476 35.363757863.0776405 51 27.6294166415 0.0897497 0.00029400385 0.00308499152 -3.531647 35.510266563.3367965 52 27.9390352524 0.0940041 0.00031559204 0.00307550361 -3.500874 35.656161263.5948624 53 28.251731952 0.0984261 0.00033858913 0.00306607389 -3.470327 35.801442163.8520139 54 28.5677617797 0.103021 0.00036307707 0.00305670182 -3.4400012 35.946208464.1081204 55 28.8870081416 0.107793 0.00038913399 0.00304738687 -3.4099008 36.090386264.3634488 56 29.2098523445 0.112749 0.00041685345 0.00303812851 -3.3800166 36.234126164.6179827 57 29.5363297789 0.117892 0.00044631941 0.00302892625 -3.3503542 36.377418764.8717749 58 29.8665662847 0.12323 0.00047763627 0.00301977956 -3.3209027 36.520293765.1248804 59 30.2006963097 0.128767 0.00051089696 0.00301068794 -3.2916667 36.662782265.377359 60 30.5388657687 0.134509 0.00054620888 0.00300165091 -3.2626412 36.8049177

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135.656302 69 -61.530351839 0.0170632 0.0003751861 0.00292269472 -3.4257533 76.3691589135.609475 70 -61.589997235 0.018069 0.0004013426 0.00291417747 -3.3964847 76.3427973135.563956 71 -61.648127617 0.0191247 0.00042904689 0.00290570972 -3.3674952 76.317172135.51976 72 -61.704711432 0.0202322 0.00045837089 0.00289729103 -3.338783 76.2922912

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135.107195 123 -62.239782305 0.207367 0.00661651454 0.00252429635 -2.1793707 76.0600341135.134885 124 -62.203477312 0.215095 0.00689236314 0.00251794032 -2.1616318 76.0756222135.163835 125 -62.165580907 0.223045 0.00717707696 0.00251161623 -2.1440524 76.0919198135.194066 126 -62.126073911 0.231221 0.00747081377 0.00250532381 -2.1266321 76.1089387135.225606 127 -62.084928658 0.239627 0.00777378283 0.00249906285 -2.1093676 76.1266945135.258443 128 -62.042169229 0.248266 0.00808609287 0.0024928331 -2.0922613 76.1451806135.292554 129 -61.997835227 0.257143 0.00840797092 0.00248663434 -2.0753088 76.1643838135.327872 130 -61.952023828 0.266262 0.00873959577 0.00248046633 -2.0585087 76.1842661135.364496 131 -61.90461395 0.275627 0.00908115604 0.00247432884 -2.0418589 76.204884135.402388 132 -61.855665815 0.285241 0.00943278975 0.00246822165 -2.0253598 76.2262158135.441462 133 -61.805301619 0.295108 0.00979464712 0.00246214453 -2.0090112 76.2482125135.481853 134 -61.753355122 0.305232 0.01016696381 0.00245609726 -1.9928087 76.2709512135.523426 135 -61.700012842 0.315618 0.01054990453 0.00245007963 -1.9767515 76.2943549135.566219 136 -61.645234811 0.326268 0.0109436006 0.00244409141 -1.9608398 76.3184456135.610255 137 -61.589002414 0.337186 0.01134824151 0.00243813239 -1.9450714 76.3432365135.655477 138 -61.531400794 0.348377 0.01176402985 0.00243220236 -1.9294439 76.3686946135.701941 139 -61.472369083 0.359843 0.01219107678 0.0024263011 -1.9139579 76.3948521135.749541 140 -61.412053946 0.371589 0.01262955882 0.00242042842 -1.8986118 76.4216487135.798347 141 -61.350375971 0.383618 0.01307970387 0.00241458409 -1.8834021 76.4491248135.84834 142 -61.287373397 0.395933 0.01354158536 0.00240876792 -1.8683305 76.4772685

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138.273665 177 -58.428555419 1.02938 0.03823588162 0.00222148173 -1.4175289 77.8426281138.360248 178 -58.333179577 1.05367 0.03921152933 0.00221655769 -1.4065862 77.891371138.447633 179 -58.237355933 1.07833 0.04020411986 0.00221165542 -1.3957294 77.9405653138.53592 180 -58.140985342 1.10333 0.0412124774 0.0022067748 -1.3849713 77.990267

138.624965 181 -58.044232656 1.12869 0.0422377687 0.00220191567 -1.374299 78.0403959138.714801 182 -57.947072174 1.1544 0.04327937486 0.00219707789 -1.363719 78.0909698138.805553 183 -57.849377397 1.18046 0.04433773491 0.00219226132 -1.3532265 78.1420595138.896995 184 -57.751400455 1.20686 0.04541250749 0.00218746582 -1.3428245 78.1935379138.989245 185 -57.653023729 1.23362 0.04650456728 0.00218269126 -1.3325044 78.2454711139.082294 186 -57.554266113 1.26072 0.04761345011 0.00217793749 -1.3222703 78.2978537139.176039 187 -57.455243264 1.28816 0.04873904804 0.00217320439 -1.312123 78.3506286139.270584 188 -57.355855161 1.31595 0.04988221462 0.00216849181 -1.3020543 78.4038533139.365823 189 -57.256219474 1.34408 0.05104249706 0.00216379963 -1.2920681 78.4574692139.461813 190 -57.156285376 1.37254 0.05221995492 0.00215912771 -1.2821635 78.5115074139.558499 191 -57.056116826 1.40134 0.05341495004 0.00215447592 -1.2723372 78.5659376139.655981 192 -56.955617839 1.43048 0.05462791229 0.00214984414 -1.2625854 78.620816139.754053 193 -56.855007591 1.45994 0.05585820837 0.00214523222 -1.252913 78.6760268139.852867 194 -56.754137058 1.48973 0.05710623675 0.00214064005 -1.2433165 78.7316552139.952373 195 -56.653064675 1.51985 0.05837274043 0.0021360675 -1.2337899 78.787673140.052467 196 -56.551901867 1.55029 0.05965714113 0.00213151444 -1.2243376 78.8440217140.153251 197 -56.450550959 1.58104 0.06095953261 0.00212698075 -1.2149584 78.9007591140.254719 198 -56.349025037 1.61211 0.06228059166 0.00212246631 -1.2056473 78.9578814140.356771 199 -56.247429953 1.64349 0.06362021646 0.00211797098 -1.1964049 79.0153324140.459457 200 -56.14572067 1.67517 0.06497846153 0.00211349466 -1.1872306 79.0731404140.562776 201 -56.043904179 1.70716 0.06635583196 0.00210903722 -1.1781209 79.1313048140.666722 202 -55.941991718 1.73944 0.06775196427 0.00210459855 -1.1690781 79.1898223140.771193 203 -55.840088488 1.77202 0.06916780248 0.00210017852 -1.160096 79.2486351140.876298 204 -55.738091615 1.80489 0.07060313504 0.00209577701 -1.151176 79.3078053140.981968 205 -55.63607502 1.83804 0.0720580877 0.00209139391 -1.1423173 79.3672929141.088163 206 -55.534078948 1.87147 0.07353307233 0.00208702911 -1.1335173 79.4270769141.194925 207 -55.432069139 1.90518 0.07502851617 0.0020826825 -1.1247736 79.4871795141.302205 208 -55.330095626 1.93915 0.0765439958 0.00207835394 -1.1160889 79.5475738141.410053 209 -55.228115065 1.97339 0.07808062422 0.00207404335 -1.1074567 79.6082876141.518415 210 -55.126181307 2.00789 0.07963833347 0.0020697506 -1.0988778 79.6692913141.627232 211 -55.024354678 2.04264 0.08121727462 0.00206547558 -1.0903516 79.7305505141.736606 212 -54.922540782 2.07764 0.08281822879 0.00206121818 -1.0818741 79.7921239141.846489 213 -54.8207896 2.11288 0.08444093144 0.0020569783 -1.073447 79.8539835141.956826 214 -54.719154339 2.14835 0.08608602515 0.00205275582 -1.0650673 79.9160986142.067608 215 -54.617644864 2.18405 0.0877538548 0.00204855065 -1.0567338 79.9784647142.17889 216 -54.516215279 2.21998 0.0894452101 0.00204436267 -1.0484429 80.0411115

142.290563 217 -54.414964829 2.25612 0.09115984024 0.00204019178 -1.0401964 80.1039791142.40269 218 -54.313839908 2.29247 0.09289885695 0.00203603787 -1.0319896 80.1671019

142.515256 219 -54.212855267 2.32903 0.09466232216 0.00203190084 -1.0238228 80.2304721142.628234 220 -54.112037359 2.36577 0.0964503783 0.00202778059 -1.0156961 80.2940741142.741614 221 -54.011396711 2.40271 0.0982641722 0.00202367702 -1.0076048 80.3579024142.855424 222 -53.910909613 2.43983 0.10010397738 0.00201959002 -0.9995487 80.421973142.969608 223 -53.810627887 2.47713 0.10197065311 0.0020155195 -0.9915248 80.4862536143.08416 224 -53.710556097 2.51459 0.10386419787 0.00201146535 -0.9835341 80.5507421

143.199062 225 -53.610712553 2.55221 0.10578549495 0.00200742748 -0.9755739 80.615427143.314352 226 -53.511063782 2.58999 0.10773572072 0.00200340579 -0.9676403 80.6803307143.429968 227 -53.411664554 2.62791 0.1097147091 0.00199940018 -0.9597351 80.745418143.545955 228 -53.312476739 2.66597 0.11172359484 0.00199541056 -0.9518551 80.810714143.662296 229 -53.213516156 2.70415 0.11376262014 0.00199143682 -0.9440004 80.876209143.77893 230 -53.114833807 2.74246 0.11583345694 0.00198747888 -0.936166 80.9418693

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143.895842 231 -53.016442956 2.78089 0.11793659071 0.00198353665 -0.9283514 81.0076857144.013081 232 -52.918300742 2.81942 0.12007230334 0.00197961002 -0.9205572 81.073687144.130628 233 -52.82042536 2.85804 0.12224159668 0.0019756989 -0.912781 81.1398609144.248478 234 -52.722819168 2.89676 0.12444608998 0.00197180321 -0.9050187 81.2062057144.366613 235 -52.6254977 2.93556 0.1266860201 0.00196792286 -0.8972713 81.2727108144.484974 236 -52.528507849 2.97444 0.12896320359 0.00196405774 -0.8895342 81.3393435144.603598 237 -52.431819608 3.01338 0.13127744117 0.00196020778 -0.8818099 81.4061237144.72249 238 -52.335427095 3.05237 0.13363005495 0.00195637288 -0.8740959 81.4730552

144.841664 239 -52.239318985 3.09142 0.13602329229 0.00195255296 -0.8663867 81.5401454144.961029 240 -52.143567536 3.13051 0.13845729025 0.00194874793 -0.8586842 81.6073432145.080613 241 -52.048149187 3.16963 0.14093326558 0.0019449577 -0.8509865 81.674664145.200462 242 -51.953026006 3.20877 0.14345249261 0.00194118218 -0.8432919 81.7421339145.32047 243 -51.858280697 3.24794 0.14601730603 0.00193742129 -0.8355957 81.8096934

145.440714 244 -51.763850231 3.2871 0.14862706421 0.00193367495 -0.8279021 81.8773863145.561192 245 -51.669736429 3.32627 0.151284481 0.00192994307 -0.8202056 81.9452105145.681794 246 -51.57602342 3.36543 0.15399117418 0.00192622556 -0.8125042 82.0131042145.802609 247 -51.482638631 3.40458 0.15674769878 0.00192252235 -0.8047988 82.0811186145.923581 248 -51.389625968 3.4437 0.1595558852 0.00191883335 -0.7970872 82.1492205146.044744 249 -51.296955808 3.48278 0.16241758107 0.00191515848 -0.789367 82.2174304146.16609 250 -51.204633064 3.52183 0.16533425114 0.00191149766 -0.7816372 82.2857433146.28756 251 -51.112700945 3.56082 0.1683071775 0.00190785081 -0.7738974 82.354126

146.409151 252 -51.021158814 3.59976 0.17133911464 0.00190421784 -0.7661435 82.4225771146.530942 253 -50.929946377 3.63863 0.17443088331 0.00190059869 -0.7583766 82.4911402146.65283 254 -50.839137652 3.67743 0.17758462632 0.00189699327 -0.7505946 82.5597583

146.774868 255 -50.748691908 3.71615 0.18080240454 0.0018934015 -0.7427958 82.6284604146.897023 256 -50.658630204 3.75478 0.1840859832 0.0018898233 -0.7349793 82.6972289147.019298 257 -50.56894864 3.79332 0.18743820418 0.00188625861 -0.7271419 82.766065147.141648 258 -50.479678426 3.83175 0.19085963686 0.00188270733 -0.7192859 82.8349427147.264136 259 -50.390769569 3.87007 0.19435358255 0.00187916941 -0.7114074 82.9038988147.38673 260 -50.30224476 3.90827 0.19792136169 0.00187564475 -0.7035073 82.972914

147.509408 261 -50.2141164 3.94634 0.20156564379 0.0018721333 -0.6955835 83.0419767147.632167 262 -50.126384038 3.98428 0.20528932842 0.00186863496 -0.6876336 83.1110851147.755046 263 -50.039017575 4.02208 0.20909421615 0.00186514968 -0.679658 83.1802611147.877977 264 -49.952062955 4.05973 0.21298292921 0.00186167737 -0.6716552 83.2494664148.000981 265 -49.865503211 4.09723 0.21695873216 0.00185821797 -0.6636229 83.3187121148.124066 266 -49.779328796 4.13457 0.22102306654 0.0018547714 -0.6555624 83.388004148.247198 267 -49.693560833 4.17175 0.2251796875 0.00185133759 -0.6474708 83.4573227148.370412 268 -49.60817355 4.20875 0.22943022343 0.00184791647 -0.6393494 83.5266871148.493656 269 -49.523199372 4.24557 0.23377895457 0.00184450798 -0.6311946 83.5960685148.61701 270 -49.438580829 4.2822 0.23822730319 0.00184111203 -0.6230085 83.6655117

148.740336 271 -49.354409699 4.31865 0.24277951976 0.00183772857 -0.614788 83.7349392148.863752 272 -49.270602105 4.3549 0.24743804877 0.00183435752 -0.6065335 83.8044176148.987216 273 -49.187184801 4.39094 0.25220594897 0.00183099881 -0.5982447 83.8739228149.110725 274 -49.104157202 4.42678 0.25708677973 0.00182765238 -0.5899203 83.9434529149.234223 275 -49.021552699 4.46241 0.26208410749 0.00182431816 -0.5815593 84.0129775149.357791 276 -48.939315281 4.49782 0.26720097912 0.00182099608 -0.573162 84.0825413149.481378 277 -48.857476076 4.53301 0.27244088014 0.00181768609 -0.5647277 84.1521158149.604985 278 -48.776031923 4.56797 0.27780810936 0.0018143881 -0.5562551 84.2217012149.728646 279 -48.694956758 4.6027 0.28330521869 0.00181110206 -0.5477454 84.2913176149.852272 280 -48.614306697 4.6372 0.28893759034 0.00180782789 -0.539196 84.3609141149.975974 281 -48.534006539 4.67146 0.29470721365 0.00180456555 -0.5306092 84.4305533150.099678 282 -48.454101938 4.70548 0.30062038733 0.00180131496 -0.5219816 84.5001934150.223369 283 -48.374598747 4.73925 0.30667826825 0.00179807606 -0.513317 84.5698266150.34709 284 -48.295467816 4.77278 0.31288838898 0.00179484878 -0.5046106 84.6394761

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150.470835 285 -48.21670875 4.80605 0.31925185964 0.00179163307 -0.4958666 84.7091398150.594539 286 -48.138361128 4.83908 0.32577573545 0.00178842887 -0.4870813 84.7787802150.718315 287 -48.060350738 4.87185 0.33246382314 0.0017852361 -0.4782556 84.8484609150.842043 288 -47.98275025 4.90436 0.33931940387 0.00178205471 -0.4693913 84.9181145150.965822 289 -47.905494356 4.93661 0.34634857739 0.00177888464 -0.4604866 84.9877971151.08956 290 -47.82863809 4.96861 0.35355633155 0.00177572583 -0.4515414 85.0574569

151.213334 291 -47.75213123 5.00034 0.36094690724 0.00177257822 -0.4425567 85.1271367151.337084 292 -47.676008658 5.03181 0.36852609369 0.00176944174 -0.4335318 85.1968023151.460837 293 -47.600249586 5.06302 0.3762988617 0.00176631635 -0.4244671 85.2664704151.584613 294 -47.524840183 5.09397 0.38427094004 0.00176320197 -0.4153625 85.3361513151.708396 295 -47.44978789 5.12466 0.39244799449 0.00176009857 -0.4062179 85.4058359151.832123 296 -47.375127368 5.15508 0.40083481564 0.00175700606 -0.3970346 85.4754893151.955898 297 -47.30079395 5.18525 0.40943865353 0.00175392441 -0.3878112 85.5451695152.079644 298 -47.226831048 5.21515 0.41826366474 0.00175085354 -0.3785499 85.6148334152.20343 299 -47.153195059 5.2448 0.42731782983 0.00174779341 -0.369249 85.6845199

152.327171 300 -47.07993404 5.2742 0.4366072459 0.00174474396 -0.3599091 85.754181152.451233 301 -47.006829636 5.30351 0.44614861228 0.00174170513 -0.3505205 85.8240232152.574992 302 -46.93424806 5.33241 0.45592725661 0.00173867687 -0.3411044 85.8936942152.69878 303 -46.861990262 5.36106 0.46595990531 0.00173565912 -0.3316515 85.9633819

152.822527 304 -46.790094859 5.38946 0.47625465918 0.00173265182 -0.3221608 86.0330465152.946301 305 -46.71851985 5.41763 0.48681886437 0.00172965493 -0.3126326 86.1027264153.070079 306 -46.647276885 5.44557 0.49765990691 0.00172666839 -0.3030673 86.172408153.193851 307 -46.576368684 5.47327 0.50878323833 0.00172369215 -0.2934672 86.2420865153.317595 308 -46.505805265 5.50075 0.52019946224 0.00172072615 -0.2838301 86.3117496153.441388 309 -46.435541307 5.52801 0.53191639974 0.00171777033 -0.2741566 86.3814399153.565159 310 -46.365614061 5.55505 0.54393926572 0.00171482466 -0.2644496 86.4511183153.688943 311 -46.296002392 5.5819 0.55628145246 0.00171188907 -0.2547054 86.5208034153.812722 312 -46.226713817 5.60854 0.56894825829 0.00170896351 -0.2449272 86.5904858153.936544 313 -46.157718985 5.63499 0.58194852927 0.00170604794 -0.2351154 86.6601927154.060326 314 -46.089062415 5.66126 0.5952938822 0.0017031423 -0.2252686 86.729877154.184158 315 -46.020692226 5.68736 0.60899329958 0.00170024654 -0.2153875 86.7995893154.308007 316 -45.952624447 5.71329 0.62305360395 0.0016973606 -0.2054746 86.8693111154.43185 317 -45.884869636 5.73907 0.63748956954 0.00169448445 -0.1955269 86.9390297

154.555695 318 -45.817421276 5.76471 0.65230849761 0.00169161803 -0.185547 87.0087494154.679589 319 -45.750251849 5.79022 0.66752279383 0.00168876129 -0.1755339 87.0784968154.803485 320 -45.683385243 5.81561 0.68314347639 0.00168591419 -0.1654881 87.1482452154.927393 321 -45.61681384 5.8409 0.69918178295 0.00168307666 -0.1554099 87.2180003155.051358 322 -45.550511904 5.8661 0.71564923473 0.00168024868 -0.1452998 87.2877873155.175303 323 -45.484518156 5.89122 0.73255927848 0.00167743018 -0.1351572 87.3575634155.299285 324 -45.418800518 5.91629 0.74992516196 0.00167462112 -0.1249821 87.4273605155.423321 325 -45.353349124 5.94131 0.7677574011 0.00167182145 -0.114776 87.4971873155.547369 326 -45.288183267 5.9663 0.78607195584 0.00166903113 -0.1045377 87.5670214155.671445 327 -45.223293235 5.9913 0.80488662808 0.0016662501 -0.0942653 87.6368712155.795563 328 -45.158670214 6.0163 0.82420556719 0.00166347833 -0.0839645 87.7067444155.919685 329 -45.09433172 6.04135 0.84405166667 0.00166071577 -0.073631 87.7766201156.043871 330 -45.030245148 6.06645 0.86444460358 0.00165796236 -0.0632628 87.846532156.168079 331 -44.966431256 6.09164 0.88539387228 0.00165521807 -0.0528635 87.9164557156.29235 332 -44.902866309 6.11694 0.9069221259 0.00165248286 -0.04243 87.9864154

156.416636 333 -44.839574011 6.14238 0.92903863684 0.00164975666 -0.0319662 88.0563832156.540939 334 -44.776551074 6.168 0.95177605203 0.00164703945 -0.0214652 88.126361156.665332 335 -44.713759475 6.19381 0.97513659416 0.00164433117 -0.0109345 88.1963892156.78973 336 -44.651240574 6.21987 0.99915832437 0.00164163178 -0.0003657 88.2664201

156.914198 337 -44.588960008 6.24619 1.02385143536 0.00163894124 0.01023694 88.3364905157.038694 338 -44.526937349 6.27284 1.0492431213 0.00163625951 0.02087613 88.4065765

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157.163254 339 -44.465153041 6.29984 1.07536066284 0.00163358654 0.03155415 88.4766988157.287836 340 -44.403626768 6.32724 1.10221690424 0.00163092229 0.04226707 88.5468332157.412478 341 -44.342337839 6.3551 1.129846847 0.00162826671 0.05301958 88.6170017157.537157 342 -44.281296581 6.38348 1.15828350925 0.00162561977 0.06381487 88.6871907157.661871 343 -44.220502128 6.41242 1.18754583345 0.00162298142 0.07465038 88.7573996157.786606 344 -44.159959905 6.442 1.21766506075 0.00162035162 0.08552784 88.8276204157.911426 345 -44.099637433 6.47229 1.2486840963 0.00161773032 0.09645258 88.897889158.036249 346 -44.039573246 6.50338 1.28063029322 0.0016151175 0.10742377 88.9681591158.161121 347 -43.979743249 6.53533 1.31354245635 0.0016125131 0.11844411 89.038457158.286002 348 -43.920165257 6.56828 1.34746848717 0.00160991709 0.12951862 89.10876158.410915 349 -43.860826743 6.6023 1.3824432191 0.00160732942 0.1406473 89.1790812158.535837 350 -43.801737542 6.63751 1.41851077098 0.00160475006 0.15183264 89.2494071159.164422 355 -43.508197561 6.81173 1.61367245291 0.00159197644 0.20781539 89.6032747159.803299 360 -43.216174383 6.95853 1.83223616587 0.00157940456 0.26298145 89.9629365161.116139 370 -42.635254319 7.12123 2.34225785283 0.00155484724 0.3696347 90.7020116161.789882 375 -42.346713832 7.13564 2.63860285363 0.00154285273 0.42137403 91.0813014162.474705 380 -42.059806027 7.10945 2.96716871641 0.00153104187 0.47234224 91.4668286163.169409 385 -41.775114376 7.04781 3.33259241487 0.00151941047 0.5227822 91.8579188163.873866 390 -41.492749976 6.95464 3.74011470687 0.00150795446 0.57288492 92.254499164.588192 395 -41.212719065 6.83325 4.19577227604 0.00149666991 0.62281191 92.6566354165.31269 400 -40.93495741 6.68616 4.70651905003 0.001485553 0.67269982 93.0644982

166.047927 405 -40.659308562 6.51498 5.28030664499 0.00147460001 0.72265914 93.4784064166.794577 410 -40.385591358 6.32038 5.92619549272 0.00146380736 0.77277597 93.8987394167.553376 415 -40.113619242 6.10193 6.65436971333 0.00145317155 0.82310693 94.3259123168.32525 420 -39.843158605 5.85811 7.47630971932 0.00144268917 0.87368728 94.760446

169.111101 425 -39.574006973 5.58618 8.40466357685 0.00143235694 0.92452033 95.202848169.911972 430 -39.305936563 5.28205 9.45320415741 0.00142217166 0.97557904 95.6537055170.728823 435 -39.038771071 4.94025 10.6367105859 0.0014121302 1.02680734 96.1135588171.562716 440 -38.772322934 4.55379 11.9705815617 0.00140222954 1.07811525 96.5830062172.414696 445 -38.506433237 4.11402 13.4702894876 0.00139246675 1.12937693 97.0626359173.285743 450 -38.240984157 3.61054 15.1507089243 0.00138283897 1.18043295 97.5529997

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150

170 Solubility of boric acid in water

Column BColumn BChanson and Millero 200630Column BColumn BColumn BColumn BColumn BColumn BColumn K

w% H3BO3

t/C

0 50 100 150 200 250 300 350 4000

0.1

0.2

0.3

0.4

0.5

0.6

0.7 Volatility of boric acid from aqueous solution

Kukuljan 1999von Stackelberg et al. 1937prediction

t/C

K=y

/x

0 10 20 30 40 50 60 70 80 90 100-10

40

90

140

190

240

290

340

390

440 B2O3+H2OColumn BColumn B30Column BColumn BColumn BColumn BColumn BColumn BColumn BColumn BColumn K

w% B2O3

t/C

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0 10 20 30 40 50 60 70 80 90 100-10

40

90

140

190

240

290

340

390

440 B2O3+H2OColumn BColumn B30Column BColumn BColumn BColumn BColumn BColumn BColumn BColumn BColumn K

w% B2O3

t/C

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Solubility isotherms in the system sodium oxide-boric oxide-water. Revised solubility-temperature curves of boric acid, borax, sodium pentaborate, and sodium metaborate

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w% t w%H3BO3 C B2O30.68447694156 -30.976 0.38533433.38372520683 8.609 1.90490786.67320164445 32.605 3.756756912.9848609852 60.763 7.309978718.9635290403 79.168 10.67573924.6349166941 93.151 13.86851130.0221781364 104.546 16.90133135.1458779909 114.203 19.78577540.0252072372 122.578 22.53264844.6771873229 129.94 25.15153149.1172255463 136.454 27.651153.3595309504 142.225 30.03935257.4170818508 147.323 32.32359461.3015182382 151.798 34.51037965.0238929629 155.696 36.6059368.5941458478 159.048 38.61584272.0212473898 161.892 40.54516575.313698539 164.269 42.398685

78.4793358897 166.223 44.18081481.525299356 167.8 45.89557184.458292561 169.048 47.54673

87.2844449404 170.013 49.13774290.0094891515 170.737 50.67183492.6387489824 171.257 52.15200295.1772350506 171.604 53.58106997.6295545771 171.801 54.96162798.8247301863 171.849 55.63446399.999998606 171.865 56.296093

101.155779301 171.849 56.946751

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102.292625313 171.802 57.58675104.511179223 171.612 58.835707106.659205322 171.285 60.04496108.739961887 170.806 61.216343110.756647638 170.15 62.351656112.712186561 169.291 63.452546114.609217228 168.198 64.520498116.450389392 166.84 65.557004118.238153773 165.19 66.563444119.974760898 163.223 67.541084121.662369191 160.921 68.491139123.303060724 158.273 69.414783124.89874748 155.277 70.31309

126.451242072 151.934 71.187082127.962286807 148.258 72.037739129.433557968 144.25 72.866006130.866516683 139.912 73.672703132.262741808 135.244 74.458722133.62354038 130.236 75.224796

134.950329023 124.867 75.971725136.244260791 119.097 76.700156137.506650066 112.861 77.41083138.738553318 106.052 78.104342139.941088652 98.497 78.78132

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K H H tatm/(mol/kg) atm C

0.00257778 2.7976168E-07 1.5534627E-05 1.554E-05 0.9995402 1.18E-07 00.00263285 3.0719102E-07 1.7057725E-05 1.706E-05 0.9995103 1.341E-07 10.00268925 3.3713029E-07 1.8720195E-05 1.873E-05 0.9994788 1.523E-07 20.00274698 3.6978416E-07 2.0533402E-05 2.054E-05 0.9994456 1.727E-07 30.00280604 4.0538035E-07 2.2509989E-05 2.252E-05 0.9994105 1.957E-07 40.0028664 4.4415363E-07 2.4662995E-05 2.467E-05 0.9993736 2.215E-07 50.0029281 4.8636647E-07 2.7006993E-05 2.701E-05 0.9993348 2.506E-07 60.0029911 5.322876E-07 2.9556904E-05 2.956E-05 0.9992939 2.831E-07 7

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0.00305541 5.8221463E-07 3.2329256E-05 3.233E-05 0.9992509 3.197E-07 80.00312104 6.3646033E-07 3.5341415E-05 3.534E-05 0.9992058 3.606E-07 90.00318799 6.9537061E-07 3.861259E-05 3.861E-05 0.9991583 4.064E-07 100.00325626 7.5929222E-07 4.2162033E-05 4.216E-05 0.9991084 4.576E-07 110.00332581 8.2861359E-07 4.6011315E-05 4.601E-05 0.9990561 5.149E-07 120.00339672 9.0375017E-07 5.0183505E-05 5.017E-05 0.9990012 5.788E-07 130.00346891 9.8512976E-07 5.4702357E-05 5.469E-05 0.9989436 6.501E-07 140.00354244 1.073225E-06 5.9594117E-05 5.958E-05 0.9988832 7.296E-07 150.00361726 1.1685205E-06 6.4885692E-05 6.486E-05 0.9988199 8.181E-07 160.00369339 1.2715484E-06 7.060663E-05 7.058E-05 0.9987537 9.167E-07 170.00377085 1.3828701E-06 7.678811E-05 7.675E-05 0.9986844 1.026E-06 180.00384965 1.5030936E-06 8.3463891E-05 8.342E-05 0.9986119 1.148E-06 190.00392974 1.6328287E-06 9.0667831E-05 9.061E-05 0.998536 1.283E-06 200.00401115 1.7727552E-06 9.8437681E-05 9.837E-05 0.9984567 1.433E-06 210.00409388 1.9235939E-06 0.00010681346 0.0001067 0.9983738 1.6E-06 220.00417793 2.0860865E-06 0.00011583636 0.0001157 0.9982873 1.784E-06 230.00426326 2.2610292E-06 0.00012555059 0.0001254 0.9981969 1.988E-06 240.00434997 2.4493018E-06 0.00013600501 0.0001359 0.9981027 2.214E-06 250.00443795 2.6517529E-06 0.00014724673 0.0001471 0.9980043 2.463E-06 260.0045273 2.869393E-06 0.00015933186 0.0001591 0.9979017 2.739E-06 27

0.00461791 3.1031454E-06 0.00017231168 0.0001721 0.9977949 3.043E-06 280.00470989 3.3541564E-06 0.00018624984 0.000186 0.9976835 3.378E-06 290.00480314 3.6234555E-06 0.0002012035 0.0002009 0.9975675 3.748E-06 300.00489776 3.9123199E-06 0.00021724358 0.0002169 0.9974468 4.156E-06 310.00499364 4.2218938E-06 0.00023443362 0.000234 0.9973211 4.604E-06 320.00509087 4.5535709E-06 0.00025285102 0.0002524 0.9971904 5.098E-06 330.00518942 4.9087123E-06 0.00027257133 0.000272 0.9970545 5.64E-06 340.00528929 5.2887691E-06 0.00029367516 0.000293 0.9969133 6.236E-06 350.00539045 5.6952498E-06 0.00031624624 0.0003155 0.9967665 6.891E-06 360.00549295 6.1298349E-06 0.00034037792 0.0003395 0.996614 7.609E-06 370.00559672 6.5941264E-06 0.00036615913 0.0003652 0.9964557 8.396E-06 380.00570183 7.0900167E-06 0.00039369496 0.0003926 0.9962915 9.259E-06 390.00580823 7.6192917E-06 0.00042308458 0.0004218 0.996121 1.02E-05 400.00591594 8.1839604E-06 0.00045443955 0.000453 0.9959442 1.124E-05 41

0.006025 8.786146E-06 0.00048787775 0.0004862 0.9957609 1.237E-05 420.00613531 9.4278932E-06 0.00052351274 0.0005217 0.9955709 1.36E-05 430.00624695 1.0111579E-05 0.00056147649 0.0005594 0.9953741 1.495E-05 440.00635985 1.0839477E-05 0.00060189527 0.0005995 0.9951702 1.643E-05 450.00647409 1.1614237E-05 0.0006449162 0.0006422 0.9949591 1.804E-05 460.0065896 1.2438315E-05 0.00069067568 0.0006877 0.9947407 1.979E-05 47

0.00670638 1.3314556E-05 0.00073933163 0.0007359 0.9945146 2.17E-05 480.00682449 1.4245766E-05 0.00079103995 0.0007872 0.9942808 2.378E-05 490.00694385 1.5234984E-05 0.00084596931 0.0008417 0.994039 2.605E-05 500.00706454 1.628526E-05 0.0009042891 0.0008995 0.9937891 2.852E-05 510.00718645 1.73999E-05 0.0009661829 0.0009608 0.9935308 3.12E-05 520.00730968 1.8582333E-05 0.00103184115 0.0010258 0.993264 3.411E-05 530.00743417 1.9836244E-05 0.0011014684 0.0010947 0.9929885 3.728E-05 540.00755994 2.1165166E-05 0.00117526087 0.0011677 0.992704 4.071E-05 550.00768696 2.2572884E-05 0.00125342874 0.001245 0.9924104 4.444E-05 560.00781526 2.4063753E-05 0.00133621381 0.0013269 0.9921075 4.848E-05 570.00794481 2.5641744E-05 0.00142383664 0.0014134 0.9917951 5.286E-05 580.00807563 2.731151E-05 0.00151655549 0.001505 0.9914729 5.761E-05 590.0082077 2.9077385E-05 0.00161461113 0.0016018 0.9911407 6.274E-05 60

0.00834103 3.0944136E-05 0.0017182682 0.001704 0.9907985 6.83E-05 61

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0.00847557 3.2916673E-05 0.00182779942 0.001812 0.9904458 7.432E-05 620.00861142 3.5000663E-05 0.00194351934 0.001926 0.9900826 8.082E-05 630.00874846 3.7200758E-05 0.0020656864 0.0020463 0.9897086 8.784E-05 640.00888675 3.9523013E-05 0.00219463672 0.0021732 0.9893236 9.542E-05 650.00902629 4.1972974E-05 0.00233067833 0.002307 0.9889275 0.0001036 660.00916702 4.4556785E-05 0.0024741524 0.002448 0.9885198 0.0001124 670.00930901 4.7280605E-05 0.00262540085 0.0025966 0.9881006 0.000122 680.00945221 5.0151063E-05 0.00278479187 0.002753 0.9876695 0.0001322 690.00959666 5.3174937E-05 0.00295270174 0.0029177 0.9872263 0.0001433 700.00974228 5.6358955E-05 0.00312950413 0.003091 0.9867708 0.0001552 710.00988915 5.9710434E-05 0.0033156053 0.0032732 0.9863029 0.000168 720.01003721 6.3237185E-05 0.00351143901 0.0034649 0.9858222 0.0001818 730.0101865 6.6946671E-05 0.00371741961 0.0036663 0.9853285 0.0001966 74

0.01033697 7.0846938E-05 0.00393399391 0.0038779 0.9848217 0.0002126 750.01048867 7.4946836E-05 0.00416165331 0.0041001 0.9843014 0.0002297 760.01064154 7.9254308E-05 0.00440083895 0.0043335 0.9837677 0.000248 770.01079562 8.3778922E-05 0.00465208205 0.0045783 0.98322 0.0002678 780.0109509 8.8529661E-05 0.00491588143 0.0048352 0.9826583 0.0002889 79

0.01110735 9.3515974E-05 0.00519276177 0.0051045 0.9820824 0.0003116 800.01126498 9.8748218E-05 0.0054832982 0.0053869 0.9814919 0.000336 810.01142379 0.00010423616 0.00578803294 0.0056828 0.9808868 0.000362 820.01158382 0.00010999103 0.00610759012 0.0059927 0.9802667 0.00039 830.01174501 0.00011602325 0.00644254733 0.0063173 0.9796315 0.0004199 840.01190736 0.0001223441 0.00679353191 0.006657 0.9789808 0.0004518 850.01207089 0.00012896558 0.00716120997 0.0070125 0.9783147 0.0004861 860.0122356 0.00013589988 0.00754625845 0.0073844 0.9776327 0.0005226 87

0.01240148 0.00014315936 0.00794936328 0.0077734 0.9769348 0.0005617 880.01256853 0.00015075676 0.00837123227 0.0081799 0.9762205 0.0006035 890.01273678 0.00015870583 0.00881262862 0.0086048 0.9754899 0.0006481 900.01290616 0.00016701935 0.00927426251 0.0090486 0.9747424 0.0006958 910.0130767 0.00017571221 0.00975696047 0.0095121 0.9739783 0.0007466 92

0.01324842 0.00018479878 0.01026152021 0.009996 0.973197 0.0008008 930.01342126 0.00019429362 0.01078875038 0.0105009 0.9723983 0.0008586 940.01359531 0.00020421335 0.0113395736 0.0110279 0.9715822 0.0009202 950.01377052 0.00021457306 0.01191482831 0.0115773 0.9707484 0.0009858 960.01394686 0.00022538942 0.01251543978 0.0121503 0.9698966 0.0010557 970.01412437 0.00023667911 0.01314233493 0.0127475 0.9690267 0.0011301 980.01430309 0.00024846078 0.0137965484 0.0133698 0.9681384 0.0012093 990.01448294 0.00026075095 0.01447899769 0.0140179 0.9672317 0.0012936 1000.01466392 0.00027356699 0.0151906478 0.0146929 0.9663061 0.0013832 1010.0148461 0.00028693289 0.01593283042 0.0153957 0.9653617 0.0014784 102

0.01502941 0.00030086119 0.01670624205 0.016127 0.9643982 0.0015796 1030.01521392 0.0003153799 0.01751243773 0.0168879 0.9634153 0.0016872 1040.01539957 0.00033050173 0.01835212382 0.0176793 0.9624129 0.0018013 1050.01558641 0.00034625308 0.01922676596 0.0185023 0.9613908 0.0019225 1060.01577438 0.0003626558 0.02013757775 0.0193578 0.9603488 0.0020511 1070.01596356 0.00037972904 0.02108562148 0.0202468 0.9592868 0.0021876 1080.01615389 0.00039750196 0.0220725178 0.0211704 0.9582046 0.0023323 1090.01634542 0.00041599122 0.02309919037 0.0221296 0.9571018 0.0024856 1100.01653809 0.00043522639 0.02416728235 0.0231257 0.9559785 0.0026482 1110.01673199 0.00045522945 0.02527801412 0.0241597 0.9548344 0.0028203 1120.01692704 0.00047602825 0.02643293095 0.0252328 0.9536693 0.0030026 1130.01712329 0.00049764738 0.02763339956 0.026346 0.9524831 0.0031957 1140.01732074 0.00052011743 0.02888111813 0.0275005 0.9512757 0.0033999 115

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0.01751938 0.00054346342 0.0301774762 0.0286979 0.9500467 0.0036161 1160.01771924 0.00056771813 0.03152429329 0.0299391 0.9487963 0.0038446 1170.01792029 0.00059290368 0.03292279836 0.0312255 0.947524 0.0040863 1180.01812254 0.00061905643 0.03437501029 0.0325584 0.9462298 0.0043417 1190.01832603 0.00064620573 0.03588255832 0.0339387 0.9449136 0.0046116 1200.01853072 0.00067438095 0.03744707406 0.0353686 0.9435752 0.0048966 1210.01873666 0.00070361942 0.03907063017 0.0368489 0.9422144 0.0051977 1220.01894383 0.00073394949 0.04075480057 0.0383807 0.9408311 0.0055154 1230.01915218 0.00076540688 0.04250156888 0.0399662 0.9394253 0.0058507 1240.01936184 0.00079803342 0.04431325756 0.0416065 0.9379967 0.0062045 1250.01957275 0.00083185852 0.0461915 0.0433027 0.9365452 0.0065776 1260.01978494 0.00086691895 0.04813833816 0.0450569 0.9350707 0.006971 1270.0199984 0.00090325828 0.05015619143 0.0468703 0.9335731 0.0073856 128

0.02021311 0.0009409089 0.05224685775 0.0487446 0.9320523 0.0078225 1290.02042913 0.00097991495 0.05441278811 0.0506812 0.9305081 0.0082828 1300.02064645 0.00102031529 0.05665614124 0.0526815 0.9289405 8.95E-12 1310.02086508 0.00106215331 0.05897932568 0.0547482 0.9273494 9.478E-12 1320.02108498 0.00110546787 0.06138449979 0.0568818 0.9257345 1.003E-11 1330.02130625 0.00115031253 0.06387463759 0.0590843 0.9240959 1.062E-11 1340.02152887 0.00119672581 0.06645187725 0.0613574 0.9224335 1.124E-11 1350.02175283 0.00124475319 0.06911874527 0.0637032 0.9207472 1.189E-11 1360.02197815 0.00129444422 0.07187799231 0.0661236 0.9190368 1.257E-11 1370.02220483 0.0013458439 0.07473211732 0.0686194 0.9173024 1.329E-11 1380.02243292 0.00139900958 0.077684305 0.0711931 0.9155439 1.405E-11 1390.02266234 0.00145398261 0.08073685187 0.073847 0.913761 1.484E-11 1400.02289321 0.00151082291 0.08389308405 0.0765822 0.9119539 1.568E-11 1410.02312552 0.00156958335 0.08715593775 0.0794005 0.9101226 1.656E-11 1420.02335925 0.00163031211 0.09052808868 0.0823053 0.9082667 1.749E-11 1430.02359446 0.00169307251 0.09401305267 0.0852967 0.9063864 1.846E-11 1440.02383106 0.00175791625 0.09761370102 0.0883773 0.9044819 1.948E-11 1450.02406918 0.00182490848 0.10133365044 0.0915491 0.902552 2.056E-11 1460.02430882 0.00189410517 0.10517600922 0.0948148 0.9005983 2.168E-11 1470.02454997 0.00196556858 0.10914423442 0.0981763 0.89862 2.287E-11 1480.02479263 0.00203936211 0.11324184682 0.1016347 0.8966165 2.411E-11 1490.02503679 0.00211554015 0.11747186687 0.1051939 0.8945889 2.541E-11 1500.02528257 0.00219419154 0.12183922651 0.1088538 0.8925364 2.678E-11 1510.02552993 0.00227536446 0.12634660248 0.1126184 0.8904592 2.822E-11 1520.02577887 0.00235913901 0.1309984419 0.1164888 0.8883575 2.972E-11 1530.02602946 0.00244557879 0.13579827594 0.1204681 0.8862307 3.13E-11 1540.0262816 0.00253475531 0.14075007643 0.1245585 0.8840789 3.295E-11 155

0.02653546 0.00262674823 0.14585826606 0.1287607 0.8819032 3.469E-11 1560.02679098 0.00272163495 0.15112714233 0.1330793 0.8797029 3.65E-11 1570.02704823 0.00281948983 0.15656083553 0.1375153 0.8774775 3.841E-11 1580.02730709 0.00292038179 0.16216317164 0.1420708 0.875227 4.04E-11 1590.02756778 0.00302441409 0.16793988464 0.1467492 0.8729526 4.249E-11 1600.02783027 0.00313166335 0.17389522922 0.151553 0.8706537 4.468E-11 1610.02809444 0.00324219925 0.18003307478 0.1564842 0.8683295 4.696E-11 1620.02836034 0.00335610559 0.18635807404 0.1615452 0.8659813 4.936E-11 1630.02862819 0.00347350435 0.19287700117 0.1667366 0.8636091 5.186E-11 1640.02889798 0.00359448143 0.19959462502 0.1720655 0.8612116 5.448E-11 1650.02916936 0.00371907846 0.20651325792 0.1775292 0.8587899 5.722E-11 1660.02944304 0.00384747977 0.21364313549 0.1831353 0.8563441 6.008E-11 1670.02971839 0.00397969956 0.22098504503 0.1888825 0.8538745 6.304E-11 1680.02999568 0.0041158707 0.2285463661 0.194775 0.8513806 6.608E-11 169

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0.0302751 0.00425611419 0.23633381723 0.2008152 0.8488617 6.907E-11 1700.03055656 0.00440052252 0.24435253318 0.2070076 0.8463198 7.161E-11 1710.03083995 0.00454918151 0.25260728037 0.2133524 0.8437534 0.07183 1720.03112521 0.00470218817 0.2611034454 0.2198522 0.8411637 0.0740326 1730.03141277 0.00485971188 0.26985043292 0.2265114 0.8385501 0.0762896 1740.03170255 0.00502185115 0.27885371402 0.2333327 0.8359119 0.0786024 1750.03199418 0.00518866545 0.28811659063 0.2403161 0.8332513 0.0809715 1760.03228841 0.00536038732 0.29765197518 0.247469 0.8305667 0.0833983 1770.03258457 0.00553702307 0.30746021782 0.2547914 0.8278594 0.0858837 1780.03288315 0.00571877505 0.3175525554 0.2622859 0.8251286 0.0884289 1790.03318376 0.00590570632 0.3279324884 0.2699577 0.8223748 0.0910346 1800.03348686 0.00609804075 0.33861244824 0.2778066 0.8195974 0.0937021 1810.03379237 0.00629583561 0.34959561556 0.285838 0.8167984 0.0964322 1820.0341002 0.00649922109 0.36088921948 0.2940545 0.8139755 0.0992267 183

0.03441052 0.00670839474 0.37250422858 0.3024558 0.8111308 0.1020857 1840.03472325 0.00692350462 0.38444886588 0.3110505 0.8082636 0.1050109 1850.03503857 0.00714463312 0.39672770529 0.3198382 0.8053736 0.1080031 1860.03535639 0.00737199607 0.40935273142 0.3288249 0.8024626 0.1110637 1870.03567661 0.00760568408 0.42232897638 0.3380099 0.7995286 0.1141937 1880.0359997 0.007845977 0.43567197875 0.347396 0.7965734 0.1173944 189

0.03632529 0.00809284705 0.44938019679 0.3569891 0.7935966 0.1206665 1900.03665356 0.00834658174 0.46346959512 0.3667921 0.7905985 0.1240115 1910.0369847 0.00860741772 0.4779533144 0.3768089 0.7875787 0.1274307 192

0.03731862 0.00887539295 0.49283346226 0.3870405 0.7845382 0.1309251 1930.03765521 0.00915067709 0.50811945998 0.397491 0.7814767 0.1344955 1940.03799496 0.00943365643 0.52383275697 0.4081637 0.7783944 0.1381437 1950.03833749 0.00972430698 0.53997202186 0.4190617 0.7752916 0.1418706 1960.03868268 0.01002280592 0.55654709315 0.4301888 0.7721689 0.1456775 1970.03903131 0.01032949368 0.57357687282 0.4415482 0.7690256 0.1495657 1980.03938289 0.01064453008 0.59107023751 0.4531428 0.7658622 0.1535359 1990.03973763 0.01096805225 0.60903479953 0.4649762 0.7626798 0.1575905 2000.04009542 0.01130032613 0.62748532744 0.4770524 0.7594779 0.1617297 2010.04045643 0.01164155507 0.64643311291 0.4893736 0.7562563 0.1659546 2020.04082089 0.01199203883 0.66589480068 0.5019444 0.7530159 0.1702679 2030.04118867 0.01235183833 0.68587377272 0.5147675 0.7497563 0.1746695 2040.0415594 0.0127212242 0.70638505859 0.5278464 0.7464788 0.1791614 205

0.04193412 0.01310054426 0.72744797031 0.5411851 0.7431822 0.1837446 2060.04231218 0.01348999875 0.74907362676 0.554787 0.7398676 0.1884202 2070.04269345 0.01388965269 0.77126564062 0.5686552 0.7365354 0.1931903 2080.04307872 0.01430010204 0.79405710119 0.5827937 0.7331859 0.1980559 2090.04346748 0.01472129404 0.81744508177 0.5972061 0.7298181 0.2030176 2100.04385997 0.01515365977 0.84145351707 0.611896 0.7264337 0.2080777 2110.04425635 0.01559737667 0.8660922605 0.6268669 0.7230326 0.213238 2120.04465648 0.01605284642 0.8913836184 0.642122 0.7196142 0.2184983 2130.04506063 0.01652028977 0.91733984626 0.657666 0.7161798 0.2238611 2140.04546894 0.01699998154 0.94397620522 0.6735015 0.7127297 0.2293274 2150.04588102 0.01749215561 0.97130568336 0.6896335 0.7092629 0.2348991 2160.04629738 0.017997323 0.99935665467 0.7060643 0.7057805 0.2405771 2170.04671777 0.01851553615 1.02813203217 0.7227991 0.7022836 0.2463635 2180.04714274 0.01904741407 1.05766618771 0.7398402 0.6987711 0.2522584 2190.04757187 0.01959295649 1.08795910625 0.7571931 0.6952436 0.2582651 2200.04800531 0.02015272709 1.11904208904 0.7748599 0.6917013 0.2643838 2210.0484436 0.02072712814 1.15093747219 0.7928454 0.6881455 0.270616 222

0.04888633 0.02131634029 1.18365528649 0.8111535 0.684575 0.2769642 223

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0.04933336 0.02192065831 1.217211902 0.829788 0.6809918 0.2834288 2240.04978553 0.02254072603 1.25164306653 0.8487531 0.6773941 0.2900118 2250.05024228 0.02317667219 1.28695593175 0.8680517 0.6737838 0.2967149 2260.05070416 0.02382913425 1.32318589225 0.8876897 0.6701612 0.303539 2270.05117104 0.02449835172 1.36034624744 0.9076689 0.6665254 0.3104861 2280.05164277 0.02518465344 1.39845525995 0.9279948 0.6628769 0.3175583 2290.05211992 0.0258887212 1.43755078515 0.9486709 0.6592173 0.3247568 2300.05260234 0.02661090782 1.47765241565 0.9697015 0.6555459 0.3320826 2310.05308989 0.02735137456 1.51876910695 0.9910905 0.6518629 0.3395379 2320.05358314 0.02811094407 1.56094653729 1.0128422 0.6481689 0.3471243 2330.05408179 0.02888991126 1.60420108488 1.0349606 0.6444642 0.3548428 2340.05458614 0.02968879315 1.64856145546 1.0574502 0.6407487 0.3626968 2350.05509632 0.03050802853 1.69405201649 1.0803148 0.6370233 0.370686 2360.05561217 0.03134810657 1.74069993196 1.1035589 0.633288 0.3788127 2370.05613429 0.0322097445 1.78854502455 1.1271868 0.6295437 0.3870791 2380.05666223 0.03309319707 1.83760144214 1.1512024 0.6257896 0.3954861 2390.0571964 0.03399920163 1.88791012988 1.175611 0.6220262 0.4040367 240

0.05773711 0.03492836854 1.93950497693 1.2004158 0.6182552 0.4127309 2410.05828404 0.03588104069 1.99240502616 1.2256214 0.614475 0.4215713 2420.05883752 0.03685795847 2.04665138683 1.2512324 0.6106874 0.4305603 2430.05939794 0.03785982501 2.10228310394 1.2772534 0.6068917 0.4396991 2440.05996485 0.03888693065 2.15931630125 1.3036904 0.6030887 0.4489899 2450.06053887 0.03994025066 2.21780513022 1.3305442 0.599279 0.4584334 2460.06111983 0.0410201684 2.27777088012 1.3578234 0.5954624 0.4680326 2470.06170783 0.04212747328 2.33925738723 1.385529 0.5916394 0.4777896 2480.0623035 0.04326310588 2.40231687532 1.4136684 0.5878097 0.4877051 249

0.06290638 0.04442740294 2.46696804595 1.4422451 0.5839751 0.4977816 2500.06351686 0.04562116995 2.53325562871 1.4712642 0.5801347 0.5080203 2510.06413529 0.04684533283 2.60123103266 1.5007305 0.576289 0.5184249 2520.06476131 0.04810032214 2.67091817173 1.5306477 0.5724385 0.5289961 2530.06539555 0.04938719265 2.74237560974 1.5610224 0.5685836 0.5397354 2540.06603813 0.05070698352 2.81566105166 1.5918582 0.5647241 0.5506462 2550.06668884 0.05205993812 2.89078801433 1.6231602 0.5608611 0.5617295 2560.06734835 0.05344743372 2.9678329695 1.6549321 0.5569945 0.5729876 2570.06801646 0.05487010718 3.04683128323 1.6871825 0.5531246 0.5844201 2580.06869326 0.05632869682 3.12782395667 1.7199135 0.549252 0.5960364 2590.06937913 0.05782432321 3.21087320574 1.7531304 0.5453764 0.6078304 2600.07007444 0.05935812966 3.29604252074 1.7868405 0.5414985 0.6198123 2610.07077899 0.06093068195 3.38336331986 1.8210459 0.5376185 0.6319739 2620.07149345 0.06254355873 3.47292325726 1.8557557 0.5337376 0.6443224 2630.07221735 0.06419712193 3.56474243347 1.890972 0.5298544 0.6568659 2640.07295132 0.06589284354 3.65890258792 1.9267006 0.5259706 0.6695983 2650.07369548 0.06763178419 3.75546260902 1.9629491 0.522086 0.6825307 2660.07445018 0.06941510705 3.85448708895 1.9997197 0.518201 0.6956541 2670.07521551 0.07124387173 3.95603486915 2.0370221 0.5143162 0.7089744 2680.07599159 0.0731192254 4.06016964217 2.0748586 0.5104309 0.7225029 2690.07677877 0.07504254599 4.1669679257 2.1132372 0.5065466 0.7362302 2700.07757711 0.07701496594 4.27649260615 2.1521622 0.5026632 0.7501677 2710.07838705 0.07903786788 4.38882044989 2.1916397 0.4987806 0.7643111 2720.07920893 0.0811125846 4.50402546878 2.2316763 0.4948998 0.7786665 2730.08004251 0.08324032916 4.62217502604 2.2722783 0.4910202 0.7932336 2740.08088853 0.0854227438 4.74336030233 2.3134502 0.4871433 0.808021 2750.08174732 0.08766155375 4.86767710226 2.3552008 0.4832684 0.8230218 2760.08261837 0.08995731823 4.99515648145 2.3975323 0.4793961 0.8382499 277

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0.08350297 0.09231271316 5.12594702021 2.4404562 0.4755268 0.8537049 2780.0844009 0.09472866808 5.26010033839 2.4839772 0.4716604 0.8693824 279

0.08531219 0.09720672484 5.39770205703 2.5280999 0.4677979 0.8852885 2800.08623786 0.09974944155 5.53889421279 2.572834 0.4639396 0.9014306 2810.0871777 0.1023578331 5.68373316587 2.6181868 0.460085 0.9178081 282

0.08813172 0.10503339178 5.83230178606 2.6641605 0.4562347 0.9344299 2830.08910125 0.10777903193 5.98476188911 2.7107653 0.4523894 0.9512872 2840.09008577 0.1105958466 6.14117417604 2.7580116 0.4485487 0.9683904 2850.09108558 0.11348578355 6.30164680886 2.8058878 0.4447135 0.9857373 2860.09210174 0.11645146262 6.46632524894 2.8544523 0.4408842 1.0033435 2870.09313428 0.11949494206 6.63532379388 2.9036542 0.4370603 1.0212017 2880.09418319 0.12261761066 6.80871955952 2.9535269 0.4332428 1.0393192 2890.09524933 0.12582267293 6.98669049429 3.0040759 0.4294315 1.0576968 2900.09633293 0.12911177472 7.16932797449 3.0553068 0.425627 1.0763404 2910.0974343 0.13248752542 7.35677690136 3.1072249 0.4218295 1.0952521 292

0.09855399 0.13595243732 7.54917678548 3.1598672 0.4180392 1.1144311 2930.09969255 0.13950924886 7.74667967181 3.2132086 0.4142565 1.1338933 2940.10085027 0.14316022356 7.94941125703 3.2672871 0.4104817 1.1536364 2950.1020274 0.14690802164 8.15751926587 3.3220764 0.4067144 1.1736535 296

0.10322508 0.15075623227 8.37120298183 3.3775818 0.402956 1.1939698 2970.10444468 0.15471083884 8.5907946594 3.4339115 0.3992011 1.2145896 2980.10568677 0.15877452676 8.81644341374 3.4910062 0.3954516 1.2355153 2990.10692385 0.16287919325 9.0443676381 3.548163 0.3917936 1.2566038 3000.10807658 0.16681799252 9.26308156628 3.6031555 0.3884682 1.2766588 3010.10924125 0.17083480817 9.48612759293 3.6586711 0.3851787 1.2970618 3020.11041394 0.17492139357 9.71304780979 3.7146706 0.3819353 1.3177102 3030.11160802 0.17911368254 9.94583753156 3.7714894 0.3786985 1.3386166 3040.11281849 0.18339990131 10.1838429946 3.8289859 0.3754849 1.3597994 3050.11404529 0.18778138275 10.4271382204 3.8871646 0.3722945 1.3812513 3060.11528878 0.19226073902 10.6758682358 3.9460694 0.3691279 1.4029873 3070.11654893 0.19683915083 10.9300986147 4.0056666 0.3659861 1.4249926 3080.11782568 0.20151819407 11.1899168741 4.0659605 0.3628666 1.4472933 3090.11911941 0.20629997448 11.4554399193 4.1269969 0.3597737 1.4698653 3100.12043007 0.21118633455 11.7267700711 4.1887401 0.3567072 1.4927328 3110.12175733 0.21617796214 12.0039455375 4.2511945 0.3536668 1.515896 3120.12310185 0.22127799385 12.2871404638 4.3144075 0.3506524 1.5393493 3130.12446358 0.22648765131 12.5764226967 4.3783853 0.3476636 1.5631003 3140.1258419 0.23180823039 12.8718642058 4.4430896 0.3447003 1.587149 315

0.12723749 0.23724096115 13.1735332685 4.5085699 0.3417657 1.6114993 3160.12865001 0.24278927723 13.4816205615 4.5747864 0.3388594 1.6361548 3170.13007938 0.24845251369 13.7960891752 4.6417433 0.3359846 1.6611272 3180.13152604 0.25423329313 14.11708471 4.7095389 0.3331342 1.6864011 3190.13298963 0.26013512693 14.4448021604 4.7780858 0.3303145 1.7120018 3200.13446951 0.26615619023 14.779140209 4.847388 0.3275253 1.7379114 3210.1359664 0.27229974568 15.1202799966 4.9175478 0.3247661 1.7641498 322

0.13747996 0.27856441082 15.4681447715 4.9884239 0.3220366 1.7907069 3230.13900988 0.28495637102 15.8230779956 5.0601696 0.3193397 1.8175949 3240.14055552 0.29147361734 16.1849681325 5.1327419 0.3166748 1.844809 3250.14211764 0.29811700992 16.553862912 5.2060947 0.3140384 1.8723639 3260.14369559 0.30488950384 16.9299264396 5.2802846 0.3114396 1.9002468 3270.14528895 0.31179205885 17.3132120259 5.3553175 0.3088684 1.9284807 3280.1468977 0.31882377416 17.7036696181 5.4311451 0.3063338 1.9570525 329

0.14852143 0.32598818158 18.1014953472 5.5078811 0.3038351 1.9859723 3300.15015988 0.33328106079 18.5064548663 5.5854221 0.301369 2.0152426 331

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0.15181207 0.34070730513 18.9188199133 5.6638847 0.2989377 2.0448711 3320.15347855 0.34826715829 19.3386039818 5.7431624 0.2965409 2.0748495 3330.15515835 0.35596008763 19.7657775135 5.8233168 0.294181 2.1051883 3340.15685049 0.36378543044 20.2003037301 5.9043537 0.2918574 2.1358978 3350.15855582 0.37174393305 20.6422240342 5.9863388 0.2895724 2.1669726 3360.16027254 0.37983572422 21.0915455942 6.0691587 0.2873225 2.1984204 3370.16200091 0.38806006694 21.5482274868 6.1528784 0.2851129 2.2302356 3380.1637391 0.39641690057 22.0122663657 6.2375034 0.2829401 2.2624315 339

0.16548774 0.40490321069 22.4834948026 6.3231026 0.2808092 2.295016 3400.16724581 0.41352381339 22.9621802476 6.409556 0.2787138 2.3279807 3410.1690122 0.4222712434 23.4479081687 6.4969316 0.2766616 2.3613364 3420.1707859 0.43114710238 23.9407675268 6.5853007 0.2746494 2.3950798 343

0.17256673 0.44015211014 24.4407982436 6.6746048 0.272679 2.4292248 3440.17435366 0.44928162323 24.9477425014 6.7648494 0.2707498 2.4637599 3450.17614559 0.45853371461 25.4614932949 6.8560399 0.2688612 2.4987125 3460.1779412 0.46790577359 25.9819056842 6.9482512 0.2670178 2.5340659 347

0.17974062 0.47739897639 26.5090449308 7.0413506 0.2652162 2.5698279 3480.18154198 0.48700907747 27.0426753129 7.1354834 0.2634583 2.6060098 3490.18334446 0.49673116062 27.5825238436 7.2305854 0.2617436 2.6426028 3500.1851467 0.50656201909 28.1284124859 7.3267351 0.2600738 2.6796265 351

0.18694806 0.51650361683 28.6804502389 7.4238664 0.2584508 2.7170775 3520.18874748 0.52654660214 29.2381178482 7.5219845 0.2568713 2.7549502 3530.19054385 0.53669141482 29.8014397346 7.6210945 0.2553373 2.7932696 3540.1923355 0.54693346055 30.3701607845 7.7212788 0.2538504 2.8320184 355

0.19412107 0.55726531 30.9438684933 7.8224672 0.2524076 2.8712116 3560.19590022 0.56768584738 31.5225008408 7.9247439 0.2510131 2.9108504 3570.19767161 0.57818728161 32.1056252342 8.0280367 0.2496663 2.9509413 3580.19943412 0.58877307688 32.6934340339 8.1323505 0.2483665 2.9914927 3590.20118608 0.59943068014 33.2852301922 8.2377727 0.2471129 3.0324922 3600.20292609 0.610158874 33.880946145 8.3443111 0.245905 3.0739598 3610.20465418 0.62094962785 34.4801358995 8.4518893 0.2447471 3.115899 3620.20636866 0.6318043796 35.0828793338 8.560512 0.243636 3.1583057 3630.20806844 0.64271136588 35.6885232512 8.6702706 0.2425736 3.2011871 3640.20975268 0.6536706514 36.297071244 8.7810852 0.241557 3.2445525 365

K H Hatm/(mol/kg) atm

#DIV/0! #DIV/0! #DIV/0!0.01627216 0.00029314938 0.016272155290.01627242 0.00029315407 0.016272418190.01627436 0.00029318864 0.016274363240.0162829 0.00029333773 0.01628290295

0.01629416 0.00029349294 0.016294160440.01630737 0.00029351944 0.016307371910.01632087 0.00029349828 0.016320871260.01634687 0.00029343809 0.016346868130.01637272 0.0002933755 0.016372718510.01639857 0.00029331324 0.016398574990.01642451 0.00029325252 0.016424505780.01645037 0.00029319088 0.016450372910.01647637 0.00029313179 0.016476369490.01650219 0.00029306975 0.016502189720.01652815 0.00029301046 0.016528150980.01655399 0.00029294912 0.01655398584

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0.01657983 0.0002928881 0.016579826080.01660557 0.00029282561 0.01660557220.01663135 0.00029276401 0.016631354720.01665709 0.00029270178 0.016657089570.01668272 0.00029263801 0.016682724750.01670843 0.00029257581 0.016708434840.01673401 0.00029251148 0.016734013030.01675955 0.00029244664 0.016759548310.01678511 0.00029238243 0.016785106030.01681062 0.0002923177 0.016810620960.01683599 0.00029225066 0.01683599220.01686139 0.00029218441 0.016861393490.01688676 0.00029211772 0.016886756140.01691204 0.00029204994 0.016912042550.0169373 0.00029198194 0.01693730304

0.01696249 0.00029191288 0.016962488350.01698765 0.00029184364 0.016987648950.01701275 0.00029177359 0.017012748780.01703779 0.00029170281 0.017037791980.0170628 0.00029163173 0.01706280247

0.01708775 0.00029155987 0.017087754130.01711265 0.00029148722 0.017112645940.01713752 0.00029141452 0.017137517370.0171623 0.00029134053 0.01716230116

0.01718696 0.00029126467 0.017186959460.01721171 0.00029119058 0.017211705660.01723634 0.00029111476 0.017236335760.01726088 0.00029103777 0.017260881060.0172855 0.00029096228 0.01728549962

0.01731001 0.00029088524 0.017310011890.01733432 0.00029080504 0.017334318130.01735869 0.00029072622 0.017358692130.01738313 0.00029064878 0.017383132820.01740734 0.00029056765 0.017407337230.01743149 0.0002904859 0.017431488940.0174556 0.00029040376 0.01745559882

0.01747976 0.00029032276 0.017479762110.01750371 0.00029023851 0.017503713550.01752775 0.00029015588 0.017527747010.01755159 0.00029007037 0.017551588950.01757554 0.00028998699 0.017575540560.01759926 0.00028990001 0.017599260640.01762299 0.00028981351 0.017622989270.01764666 0.00028972626 0.017646656240.01767025 0.00028963806 0.017670249170.01769381 0.00028954972 0.017693814370.01771737 0.00028946155 0.017717370850.01774084 0.00028937216 0.017740837960.01776419 0.00028928117 0.017764187680.01778751 0.00028919011 0.017787512150.01781077 0.00028909818 0.017810768880.01783391 0.00028900475 0.017833913860.01785712 0.00028891257 0.017857116240.01788018 0.00028881851 0.01788018462

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0.01790321 0.00028872413 0.017903206970.0179261 0.00028862763 0.01792609989

0.01794901 0.00028853218 0.017949011810.0179518 0.00028852145 0.017951798380.0179518 0.00028852145 0.01795179838

w% t w%H3BO3 C B2O353.3594725456 17.893 30.03931957.4170189708 30.58 32.32355961.301578966 44.364 34.51041465.023942248 58.724 36.605958

68.5941269803 72.992 38.61583172.0212033472 86.512 40.5451475.3137259726 98.794 42.39870178.4792900654 109.593 44.18078881.5253092778 118.884 45.89557784.4582778965 126.789 47.54672287.2844657239 133.496 49.13775490.0094600171 139.214 50.67181792.6387272377 144.137 52.15199

95.17728902 148.439 53.58109997.6295560935 152.271 54.96162899.9999729858 155.779 56.296078102.292606611 159.041 57.58674104.511140531 162.136 58.835686106.659172934 165.12 60.044942108.739986903 168.033 61.216357110.756671419 170.895 62.35167112.712189483 173.714 63.452548114.609219748 176.484 64.5205116.450423662 179.193 65.557024118.238143059 181.821 66.563438119.974746486 184.35 67.541076121.662359106 186.76 68.491134123.303071408 189.033 69.414789124.898756388 191.153 70.313095126.45123089 193.111 71.187076127.96229223 194.897 72.037742129.43354782 196.506 72.866

130.866531484 197.935 73.672712132.262738585 199.184 74.45872133.623550354 200.255 75.224802134.950319754 201.149 75.97172136.24428673 201.871 76.700171

137.506647368 202.424 77.410828138.738508839 202.812 78.104317139.941116449 203.042 78.781336141.115298919 203.118 79.442353142.262216519 203.044 80.088021143.382739683 202.825 80.71883144.477756267 202.467 81.33528145.548128753 201.972 81.937856146.594674531 201.346 82.527019

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147.618225666 200.591 83.103237148.619528564 199.711 83.66693149.599246007 198.708 84.218471150.558096924 197.585 84.758265151.49672788 196.343 85.286676

152.415821681 194.985 85.804088153.315910221 193.51 86.310801154.197633779 191.919 86.807176155.061555374 190.211 87.293528155.90814439 188.387 87.770123

156.737950227 186.444 88.23727157.551498123 184.38 88.695264158.349227924 182.193 89.144354159.131593975 179.88 89.584794159.899061295 177.435 90.016847160.652034586 174.855 90.44074161.390913849 172.133 90.856699162.116089971 169.262 91.264943162.82795797 166.234 91.665696

163.526875102 163.038 92.059157164.213188427 159.664 92.445524164.88724399 156.099 92.824989165.54934389 152.326 93.197724

166.199822762 148.357 93.563917166.838987167 144.141 93.923741

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#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!

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#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!#DIV/0! -273.15 #DIV/0!

134.950329231 83.841 75.971725136.244286545 150.532 76.70017137.506632394 168.276 77.41082138.73860308 182.565 78.10437

139.941111284 195.007 78.781333141.115356174 206.279 79.442385142.262245032 216.747 80.088037143.382742766 226.592 80.718832144.47775511 235.939 81.335279

145.548126776 244.892 81.937855146.594692818 253.523 82.527029147.618222737 261.886 83.103235148.619500101 270.02 83.666913149.599239465 277.953 84.218467150.55807665 285.705 84.758253

151.496724296 293.29 85.286674152.415790714 300.714 85.804071153.31592013 307.986 86.310807

154.197632575 315.109 86.807175155.061538836 322.082 87.293519155.908133993 328.907 87.770117156.737969484 335.584 88.237281157.551497488 342.115 88.695264158.34921823 348.506 89.144348

159.131599193 354.741 89.584797159.899068723 360.742 90.016851160.652035661 366.504 90.44074161.390902776 372.05 90.856692162.116104982 377.391 91.264951162.82796149 382.551 91.665698

163.526865027 387.546 92.059152164.21318421 392.384 92.445521

164.887232707 397.073 92.824983165.549343692 401.618 93.197724166.19982462 406.024 93.563918

166.838990712 410.295 93.923743167.467125577 414.436 94.277357

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168.084512739 418.45 94.624921168.69143154 422.341 94.966591

169.288137998 426.114 95.302512169.87489509 429.771 95.632832

170.451942764 433.317 95.957687171.019515457 436.755 96.277207171.577879667 440.09 96.591543172.127214484 443.325 96.900796172.667738581 446.464 97.205089173.199711597 449.511 97.504568173.723282643 452.469 97.799317174.238652224 455.343 98.089449174.746045262 458.135 98.37509175.245621564 460.848 98.656331175.73756849 463.487 98.933277

176.222053962 466.055 99.206022176.699250959 468.554 99.474664177.169320091 470.989 99.739294177.40173084 472.182 99.870132

177.586418778 473.127 99.9741030 -0.012 0

0.06862387295 -0.033 0.03863260.34272728247 -0.116 0.19294240.68447488178 -0.221 0.38533321.36505437393 -0.43 0.76847342.04176512364 -0.64 1.14943562.71464377819 -0.851 1.52824063.38373264657 -1.063 1.9049124.04902870999 -1.275 2.27944824.71058988459 -1.489 2.65188185.36846248748 -1.704 3.02223886.02266824344 -1.92 3.39053166.67321212828 -2.137 3.75676288.28385346053 -2.683 4.66349219.8723624029 -3.235 5.5577617

11.4392491866 -3.794 6.439858712.9848541114 -4.359 7.309974914.5097113778 -4.931 8.168410816.0141527832 -5.509 9.015353417.4986386295 -6.094 9.851061818.9635367969 -6.686 10.67574320.409245761 -7.285 11.489621

21.8361484127 -7.891 12.29291323.2445776482 -8.505 13.08580424.6349047914 -9.125 13.86850426.0075235091 -9.753 14.64123627.3626970208 -10.388 15.40414628.7007186677 -11.031 16.157430.022045438 -11.682 16.901256

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0 50 100 150 200 250 300 350 4000

0.1

0.2

0.3

0.4

0.5

0.6

0.7 Volatility of boric acid from aqueous solution

Kukuljan 1999von Stackelberg et al. 1937prediction

t/C

K=y

/x

0 1 2 3 4 5 6 7100

100.5

101

101.5

102

102.5

103

103.5

104 Boiling of boric acid solutions

Nasini and Ageno 1940von Stackelberg et al. 1937prediction

m H3BO3

tB [C

]

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p0 H2O m x p y p H3BO3 p0' H3BO3 K Hatm H3BO3 H3BO3 atm H3BO3 atm atm atm/(mol/kg0.0060285 0.0199999 0.0003602 0.0060264 1.19E-06 7.173E-09 7.6042979E-06 0.0033046 3.586E-070.0064811 0.0199999 0.0003602 0.0064788 1.214E-06 7.863E-09 8.3559726E-06 0.0033696 3.932E-070.0069636 0.0199999 0.0003602 0.0069611 1.238E-06 8.615E-09 9.1766789E-06 0.0034362 4.308E-070.0074776 0.0199999 0.0003602 0.0074749 1.262E-06 9.434E-09 1.0072062E-05 0.0035042 4.717E-070.0080249 0.0199999 0.0003602 0.008022 1.287E-06 1.033E-08 1.1048372E-05 0.0035738 5.163E-070.0086073 0.0199998 0.0003602 0.0086042 1.313E-06 1.13E-08 1.211213E-05 0.0036448 5.648E-070.0092267 0.0199999 0.0003602 0.0092234 1.339E-06 1.235E-08 1.3270356E-05 0.0037173 6.175E-070.0098852 0.0199999 0.0003602 0.0098816 1.366E-06 1.349E-08 1.4530631E-05 0.0037913 6.747E-07

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0.0105848 0.0199999 0.0003602 0.010581 1.393E-06 1.474E-08 1.5900913E-05 0.0038667 7.368E-070.0113277 0.0199999 0.0003602 0.0113236 1.42E-06 1.608E-08 1.7389977E-05 0.0039436 8.042E-070.0121162 0.0199999 0.0003602 0.0121119 1.449E-06 1.755E-08 1.9006882E-05 0.0040219 8.773E-070.0129527 0.0199999 0.0003602 0.012948 1.477E-06 1.913E-08 2.0761483E-05 0.0041017 9.564E-070.0138396 0.0199999 0.0003602 0.0138346 1.507E-06 2.084E-08 2.2664229E-05 0.0041829 1.042E-060.0147794 0.0199999 0.0003602 0.0147741 1.536E-06 2.27E-08 2.4726283E-05 0.0042655 1.135E-060.0157749 0.0199999 0.0003602 0.0157693 1.567E-06 2.47E-08 2.6959547E-05 0.0043495 1.235E-060.0168289 0.0199999 0.0003602 0.0168229 1.597E-06 2.687E-08 2.9376639E-05 0.004435 1.344E-060.0179442 0.0199999 0.0003602 0.0179378 1.629E-06 2.921E-08 3.1991003E-05 0.0045218 1.461E-060.0191238 0.0199999 0.0003602 0.019117 1.66E-06 3.174E-08 3.4816752E-05 0.0046101 1.587E-060.0203709 0.0199999 0.0003602 0.0203636 1.693E-06 3.447E-08 3.7869332E-05 0.0046998 1.724E-060.0216887 0.0199998 0.0003602 0.0216809 1.726E-06 3.741E-08 4.1164643E-05 0.0047909 1.871E-060.0230805 0.0199999 0.0003602 0.0230722 1.759E-06 4.058E-08 4.4719646E-05 0.0048834 2.029E-060.0245498 0.0199999 0.0003602 0.024541 1.793E-06 4.399E-08 4.8552952E-05 0.0049773 2.2E-060.0261003 0.0199999 0.0003602 0.026091 1.827E-06 4.767E-08 5.2683048E-05 0.0050725 2.383E-060.0277357 0.0199999 0.0003602 0.0277258 1.862E-06 5.162E-08 5.7130257E-05 0.0051692 2.581E-060.0294599 0.0199999 0.0003602 0.0294494 1.897E-06 5.587E-08 6.1916698E-05 0.0052672 2.793E-060.0312769 0.0199999 0.0003602 0.0312657 1.933E-06 6.043E-08 6.706432E-05 0.0053666 3.022E-060.0331909 0.0199999 0.0003602 0.033179 1.969E-06 6.534E-08 7.2596967E-05 0.0054674 3.267E-060.0352062 0.0199999 0.0003602 0.0351936 2.006E-06 7.06E-08 7.8540852E-05 0.0055696 3.53E-060.0373272 0.0199999 0.0003602 0.0373138 2.043E-06 7.624E-08 8.4921842E-05 0.005673 3.812E-060.0395586 0.0199999 0.0003602 0.0395444 2.081E-06 8.229E-08 9.1768036E-05 0.0057779 4.115E-060.0419051 0.0199999 0.0003602 0.0418901 2.119E-06 8.878E-08 9.9109387E-05 0.0058841 4.439E-060.0443716 0.0199999 0.0003602 0.0443557 2.158E-06 9.572E-08 0.00010697743 0.0059916 4.786E-060.0469633 0.0199999 0.0003602 0.0469465 2.197E-06 1.032E-07 0.0001154044 0.0061005 5.158E-060.0496854 0.0199999 0.0003602 0.0496675 2.237E-06 1.111E-07 0.00012442454 0.0062108 5.555E-060.0525432 0.0199999 0.0003602 0.0525244 2.277E-06 1.196E-07 0.0001340755 0.0063224 5.98E-060.0555425 0.0199999 0.0003602 0.0555226 2.318E-06 1.287E-07 0.00014439381 0.0064352 6.435E-060.058689 0.0199999 0.0003602 0.0586679 2.359E-06 1.384E-07 0.00015542126 0.0065495 6.92E-06

0.0619886 0.0199999 0.0003602 0.0619663 2.401E-06 1.488E-07 0.00016719774 0.006665 7.438E-060.0654474 0.0199999 0.0003602 0.065424 2.443E-06 1.598E-07 0.00017976964 0.0067818 7.99E-060.0690718 0.0199999 0.0003602 0.0690471 2.485E-06 1.716E-07 0.00019318209 0.0068999 8.58E-060.0728683 0.0199999 0.0003602 0.0728422 2.528E-06 1.842E-07 0.00020748361 0.0070194 9.208E-060.0768437 0.0199999 0.0003602 0.0768161 2.572E-06 1.975E-07 0.00022272476 0.0071401 9.877E-060.0810047 0.0199999 0.0003602 0.0809756 2.616E-06 2.118E-07 0.00023895915 0.0072621 1.059E-050.0853585 0.0199999 0.0003602 0.0853279 2.66E-06 2.27E-07 0.00025624231 0.0073854 1.135E-050.0899123 0.0199999 0.0003602 0.0898801 2.705E-06 2.431E-07 0.0002746322 0.0075099 1.216E-050.0946738 0.0199999 0.0003602 0.0946399 2.75E-06 2.603E-07 0.00029418872 0.0076357 1.301E-050.0996507 0.0199999 0.0003602 0.099615 2.796E-06 2.785E-07 0.00031497648 0.0077628 1.393E-050.104851 0.0199999 0.0003602 0.104813 2.842E-06 2.979E-07 0.00033706021 0.0078912 1.49E-050.110282 0.0199999 0.0003602 0.110243 2.889E-06 3.185E-07 0.00036051139 0.0080207 1.592E-050.115954 0.0199999 0.0003602 0.115912 2.936E-06 3.403E-07 0.00038539918 0.0081515 1.702E-050.121873 0.0199999 0.0003602 0.12183 2.984E-06 3.635E-07 0.00041179963 0.0082836 1.817E-050.12805 0.0199999 0.0003602 0.128004 3.032E-06 3.881E-07 0.00043979141 0.0084169 1.94E-05

0.134493 0.0199999 0.0003602 0.134445 3.08E-06 4.141E-07 0.00046945645 0.0085514 2.07E-050.141212 0.0199999 0.0003602 0.141161 3.129E-06 4.417E-07 0.00050087767 0.0086871 2.208E-050.148216 0.0199999 0.0003602 0.148163 3.178E-06 4.709E-07 0.00053414377 0.008824 2.354E-050.155514 0.0199999 0.0003602 0.155459 3.228E-06 5.018E-07 0.00056934602 0.008962 2.509E-050.163118 0.0199999 0.0003602 0.163059 3.278E-06 5.345E-07 0.00060658109 0.0091013 2.673E-050.171036 0.0199999 0.0003602 0.170975 3.329E-06 5.691E-07 0.00064594504 0.0092418 2.846E-050.179281 0.0199999 0.0003602 0.179216 3.38E-06 6.057E-07 0.00068754407 0.0093834 3.028E-050.187861 0.0199999 0.0003602 0.187794 3.431E-06 6.443E-07 0.00073148074 0.0095262 3.222E-050.196789 0.0199999 0.0003602 0.196719 3.483E-06 6.852E-07 0.00077786866 0.0096702 3.426E-050.206076 0.0199999 0.0003602 0.206002 3.535E-06 7.283E-07 0.0008268194 0.0098153 3.641E-05

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0.215733 0.0199999 0.0003602 0.215656 3.588E-06 7.738E-07 0.00087845542 0.0099615 3.869E-050.225772 0.0199999 0.0003602 0.225691 3.641E-06 8.217E-07 0.00093289595 0.0101089 4.109E-050.236205 0.0199999 0.0003602 0.23612 3.694E-06 8.723E-07 0.00099027268 0.0102574 4.362E-050.247044 0.0199999 0.0003602 0.246956 3.748E-06 9.257E-07 0.00105070667 0.010407 4.628E-050.258303 0.0199999 0.0003602 0.25821 3.803E-06 9.819E-07 0.00111434133 0.0105578 4.909E-050.269994 0.0199999 0.0003602 0.269897 3.857E-06 1.041E-06 0.00118133341 0.0107096 5.205E-050.282129 0.0199999 0.0003602 0.282028 3.912E-06 1.103E-06 0.0012518043 0.0108626 5.517E-050.294724 0.0199999 0.0003602 0.294618 3.968E-06 1.169E-06 0.00132591266 0.0110166 5.845E-050.30779 0.0199999 0.0003602 0.30768 4.024E-06 1.238E-06 0.00140380282 0.0111717 6.19E-05

0.321344 0.0199999 0.0003602 0.321229 4.08E-06 1.311E-06 0.00148565753 0.0113279 6.553E-050.335398 0.0199999 0.0003602 0.335278 4.137E-06 1.387E-06 0.00157162178 0.0114852 6.935E-050.349967 0.0199999 0.0003602 0.349842 4.194E-06 1.467E-06 0.00166188711 0.0116435 7.336E-050.365067 0.0199999 0.0003602 0.364936 4.251E-06 1.551E-06 0.00175661408 0.0118029 7.757E-050.380712 0.0199999 0.0003602 0.380576 4.309E-06 1.64E-06 0.00185598233 0.0119634 8.199E-050.396918 0.0199999 0.0003602 0.396776 4.367E-06 1.733E-06 0.00196019812 0.0121248 8.664E-050.413701 0.0199999 0.0003602 0.413553 4.426E-06 1.83E-06 0.00206940848 0.0122873 9.151E-050.431078 0.0199999 0.0003602 0.430923 4.485E-06 1.932E-06 0.00218386821 0.0124509 9.662E-050.449063 0.0199999 0.0003602 0.448902 4.544E-06 2.04E-06 0.00230375347 0.0126155 0.0001020.467675 0.0199999 0.0003602 0.467508 4.603E-06 2.152E-06 0.00242924916 0.012781 0.00010760.48693 0.0199998 0.0003602 0.486756 4.663E-06 2.27E-06 0.00256063247 0.0129476 0.0001135

0.506846 0.0199999 0.0003602 0.506665 4.724E-06 2.393E-06 0.00269806444 0.0131152 0.00011970.527441 0.0199999 0.0003602 0.527252 4.784E-06 2.523E-06 0.00284180517 0.0132838 0.00012610.548732 0.0199999 0.0003602 0.548535 4.846E-06 2.658E-06 0.00299209246 0.0134533 0.00013290.570737 0.0199999 0.0003602 0.570533 4.907E-06 2.8E-06 0.00314913165 0.0136238 0.000140.593476 0.0199999 0.0003602 0.593264 4.969E-06 2.948E-06 0.00331320071 0.0137954 0.00014740.616968 0.0199999 0.0003602 0.616747 5.031E-06 3.103E-06 0.00348454072 0.0139679 0.00015510.641231 0.0199998 0.0003602 0.641001 5.093E-06 3.265E-06 0.00366343253 0.0141414 0.00016320.666286 0.0199999 0.0003602 0.666047 5.156E-06 3.434E-06 0.00385009318 0.0143158 0.00017170.692152 0.0199999 0.0003602 0.691904 5.219E-06 3.611E-06 0.00404484898 0.0144912 0.00018060.71885 0.0199999 0.0003602 0.718593 5.283E-06 3.796E-06 0.00424793072 0.0146676 0.0001898

0.746401 0.0199999 0.0003602 0.746134 5.347E-06 3.989E-06 0.00445965567 0.0148449 0.00019950.774825 0.0199999 0.0003602 0.774547 5.411E-06 4.191E-06 0.0046803147 0.0150231 0.00020960.804144 0.0199999 0.0003602 0.803856 5.475E-06 4.402E-06 0.00491019854 0.0152023 0.00022010.834379 0.0199999 0.0003602 0.83408 5.54E-06 4.621E-06 0.00514961933 0.0153824 0.00023110.865553 0.0199999 0.0003602 0.865243 5.606E-06 4.85E-06 0.00539886463 0.0155635 0.00024250.897688 0.0199999 0.0003602 0.897366 5.671E-06 5.089E-06 0.00565831837 0.0157454 0.00025450.930807 0.0199999 0.0003602 0.930473 5.737E-06 5.338E-06 0.00592824556 0.0159283 0.00026690.964932 0.0199998 0.0003602 0.964586 5.803E-06 5.598E-06 0.00620896977 0.0161121 0.00027991.00009 0.0199999 0.0003602 0.999728 5.87E-06 5.868E-06 0.00650090118 0.0162969 0.0002934

1.0363 0.0199999 0.0003602 1.03592 5.937E-06 6.15E-06 0.00680438079 0.0164825 0.00030751.07358 0.0199999 0.0003602 1.0732 6.004E-06 6.443E-06 0.00711972106 0.0166691 0.00032221.11197 0.0199999 0.0003602 1.11157 6.071E-06 6.749E-06 0.00744729605 0.0168566 0.00033741.15149 0.0199999 0.0003602 1.15108 6.139E-06 7.067E-06 0.00778746763 0.017045 0.00035331.19216 0.0199999 0.0003602 1.19173 6.207E-06 7.397E-06 0.0081406689 0.0172342 0.00036991.23401 0.0199999 0.0003602 1.23356 6.276E-06 7.742E-06 0.00850723065 0.0174244 0.00038711.27706 0.0199999 0.0003602 1.2766 6.345E-06 8.1E-06 0.00888757687 0.0176155 0.0004051.32134 0.0199999 0.0003602 1.32087 6.414E-06 8.472E-06 0.00928211333 0.0178076 0.00042361.36688 0.0199999 0.0003602 1.36639 6.483E-06 8.859E-06 0.0096912415 0.0180004 0.0004429

1.4137 0.0199999 0.0003602 1.41319 6.553E-06 9.261E-06 0.01011536401 0.0181943 0.0004631.46183 0.0199999 0.0003602 1.46131 6.623E-06 9.679E-06 0.01055487915 0.018389 0.0004839

1.5113 0.0199999 0.0003602 1.51076 6.694E-06 1.011E-05 0.01101033178 0.0185846 0.00050561.56214 0.0199999 0.0003602 1.56158 6.765E-06 1.056E-05 0.01148207532 0.0187812 0.00052821.61438 0.0199999 0.0003602 1.6138 6.836E-06 1.103E-05 0.01197060125 0.0189786 0.00055161.66803 0.0199999 0.0003602 1.66743 6.907E-06 1.152E-05 0.01247627758 0.0191769 0.0005759

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1.72314 0.0199999 0.0003602 1.72252 6.979E-06 1.202E-05 0.01299966217 0.0193761 0.00060111.77974 0.0199998 0.0003602 1.7791 7.051E-06 1.254E-05 0.01354124714 0.0195763 0.00062721.83784 0.0199999 0.0003602 1.83718 7.123E-06 1.309E-05 0.01410142705 0.0197773 0.00065431.89749 0.0199999 0.0003602 1.89681 7.196E-06 1.365E-05 0.01468072802 0.0199793 0.00068251.95871 0.0199998 0.0003602 1.95801 7.269E-06 1.423E-05 0.01527963773 0.0201822 0.00071172.02154 0.0199999 0.0003602 2.02081 7.343E-06 1.484E-05 0.01589866976 0.0203859 0.0007419

2.086 0.0199999 0.0003602 2.08525 7.416E-06 1.546E-05 0.01653835092 0.0205907 0.00077322.15213 0.0199998 0.0003602 2.15135 7.49E-06 1.611E-05 0.01719921975 0.0207963 0.00080572.21996 0.0199999 0.0003602 2.21916 7.565E-06 1.679E-05 0.01788181749 0.0210029 0.00083942.28952 0.0199999 0.0003602 2.28869 7.639E-06 1.748E-05 0.01858662659 0.0212104 0.00087422.36084 0.0199999 0.0003602 2.35999 7.715E-06 1.821E-05 0.01931411676 0.0214188 0.00091032.43396 0.0199998 0.0003602 2.43308 7.79E-06 1.895E-05 0.02006503219 0.0216282 0.00094772.50891 0.0199999 0.0003602 2.50801 7.866E-06 1.973E-05 0.02083969389 0.0218385 0.00098642.58573 0.0199999 0.0003602 2.5848 7.942E-06 2.053E-05 0.02163901104 0.0220497 0.00102642.66445 0.0199999 0.0003602 2.66349 8.018E-06 2.136E-05 0.02246337753 0.022262 0.0010678

2.7451 0.0199999 0.0003602 2.74411 8.095E-06 2.221E-05 0.02331329201 0.0224752 0.00111072.82772 0.0199999 0.0003602 2.8267 8.172E-06 2.31E-05 0.02418947238 0.0226893 0.0011552.91235 0.0199999 0.0003602 2.9113 8.25E-06 2.402E-05 0.02509246151 0.0229045 0.00120092.99901 0.0199999 0.0003602 2.99793 8.327E-06 2.497E-05 0.02602280639 0.0231206 0.00124833.08775 0.0199999 0.0003602 3.08664 8.406E-06 2.595E-05 0.02698146433 0.0233377 0.00129733.17861 0.0199999 0.0003602 3.17746 8.484E-06 2.696E-05 0.02796872015 0.0235559 0.00134793.27161 0.0199999 0.0003602 3.27043 8.563E-06 2.801E-05 0.02898521457 0.023775 0.0014003

3.3668 0.0199999 0.0003602 3.36558 8.642E-06 2.909E-05 0.03003179297 0.0239952 0.00145443.46422 0.0199999 0.0003602 3.46296 8.722E-06 3.02E-05 0.03110905243 0.0242163 0.00151023.56389 0.0199999 0.0003602 3.5626 8.802E-06 3.136E-05 0.03221755583 0.0244385 0.00156793.66587 0.0199999 0.0003602 3.66454 8.883E-06 3.255E-05 0.03335792334 0.0246618 0.00162753.77019 0.0199999 0.0003602 3.76882 8.963E-06 3.378E-05 0.03453114401 0.0248862 0.00168913.87688 0.0199999 0.0003602 3.87547 9.045E-06 3.505E-05 0.03573762367 0.0251115 0.00175263.98599 0.0199999 0.0003602 3.98455 9.126E-06 3.636E-05 0.03697829573 0.025338 0.00181824.09756 0.0199999 0.0003602 4.09607 9.208E-06 3.772E-05 0.03825370961 0.0255656 0.00188594.21163 0.0199999 0.0003602 4.2101 9.29E-06 3.911E-05 0.03956430035 0.0257943 0.00195574.32823 0.0199999 0.0003602 4.32666 9.373E-06 4.055E-05 0.04091158953 0.0260241 0.00202784.44742 0.0199999 0.0003602 4.4458 9.456E-06 4.204E-05 0.04229565078 0.026255 0.00210214.56922 0.0199999 0.0003602 4.56756 9.54E-06 4.357E-05 0.04371739213 0.0264872 0.00217874.69369 0.0199999 0.0003602 4.69198 9.624E-06 4.516E-05 0.04517742265 0.0267204 0.00225784.82085 0.0199999 0.0003602 4.8191 9.708E-06 4.679E-05 0.04667689672 0.0269548 0.00233934.95077 0.0199999 0.0003602 4.94897 9.793E-06 4.847E-05 0.04821634693 0.0271905 0.00242345.08347 0.0199999 0.0003602 5.08162 9.879E-06 5.02E-05 0.0497964205 0.0274273 0.002515.21901 0.0199999 0.0003602 5.2171 9.964E-06 5.199E-05 0.05141802419 0.0276653 0.00259935.35741 0.0199999 0.0003602 5.35546 1.005E-05 5.383E-05 0.05308209919 0.0279047 0.00269135.49874 0.0199999 0.0003602 5.49673 1.014E-05 5.572E-05 0.05478957833 0.0281453 0.00278615.64303 0.0199999 0.0003602 5.64097 1.022E-05 5.767E-05 0.05654073571 0.0283869 0.00288385.79033 0.0199999 0.0003602 5.78821 1.031E-05 5.969E-05 0.05833698929 0.0286303 0.00298445.94068 0.0199999 0.0003602 5.9385 1.04E-05 6.176E-05 0.06017871708 0.0288746 0.0030886.09412 0.0199998 0.0003602 6.09189 1.049E-05 6.389E-05 0.06206694963 0.0291203 0.00319476.25071 0.0199999 0.0003602 6.24842 1.058E-05 6.609E-05 0.06400286415 0.0293674 0.00330466.41049 0.0199999 0.0003602 6.40814 1.067E-05 6.836E-05 0.06598675139 0.0296161 0.0034178

6.5735 0.0199999 0.0003602 6.57109 1.076E-05 7.068E-05 0.06802001826 0.0298657 0.00353436.73979 0.0199999 0.0003602 6.73732 1.085E-05 7.308E-05 0.07010332712 0.0301173 0.00365426.90941 0.0199999 0.0003602 6.90687 1.094E-05 7.555E-05 0.07223750126 0.0303701 0.0037776

7.0824 0.0199999 0.0003602 7.0798 1.103E-05 7.809E-05 0.07442326859 0.0306242 0.00390467.25882 0.0199999 0.0003602 7.25615 1.112E-05 8.07E-05 0.07666241188 0.0308799 0.00403527.43871 0.0199999 0.0003602 7.43597 1.121E-05 8.339E-05 0.07895503181 0.0311371 0.00416977.62212 0.0199998 0.0003602 7.61931 1.131E-05 8.616E-05 0.08130188018 0.031396 0.004308

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7.80909 0.0199999 0.0003602 7.80621 1.14E-05 8.9E-05 0.08370494507 0.0316562 0.00445037.99968 0.0199999 0.0003602 7.99673 1.15E-05 9.193E-05 0.08616482291 0.0319181 0.00459668.19394 0.0199999 0.0003602 8.19092 1.159E-05 9.494E-05 0.0886816792 0.0321816 0.00474718.39191 0.0199999 0.0003602 8.38881 1.169E-05 9.804E-05 0.09125782376 0.0324469 0.00490198.59365 0.0199999 0.0003602 8.59047 1.178E-05 0.0001012 0.09389336287 0.0327138 0.005061

8.7992 0.0199999 0.0003602 8.79595 1.188E-05 0.0001045 0.09658964914 0.0329824 0.00522469.00862 0.0199999 0.0003602 9.00529 1.198E-05 0.0001079 0.09934761795 0.0332526 0.00539289.22196 0.0199999 0.0003602 9.21854 1.207E-05 0.0001113 0.10216807043 0.0335245 0.00556569.43926 0.0199999 0.0003602 9.43577 1.217E-05 0.0001149 0.1050527204 0.0337983 0.00574339.66059 0.0199999 0.0003602 9.65701 1.227E-05 0.0001185 0.10800217837 0.0340741 0.00592599.88599 0.0199999 0.0003602 9.88232 1.237E-05 0.0001223 0.11101787238 0.0343516 0.006113510.1155 0.0199999 0.0003602 10.1118 1.247E-05 0.0001261 0.11410065119 0.0346311 0.006306410.3492 0.0199999 0.0003602 10.3454 1.257E-05 0.0001301 0.11725122544 0.0349126 0.006504510.5871 0.0199999 0.0003602 10.5832 1.268E-05 0.0001342 0.12047177353 0.0351957 0.00670810.8294 0.0199999 0.0003602 10.8253 1.278E-05 0.0001383 0.12376268289 0.0354812 0.006917111.0759 0.0199999 0.0003602 11.0718 1.288E-05 0.0001426 0.12712568167 0.0357685 0.007131911.3269 0.0199999 0.0003602 11.3226 1.299E-05 0.000147 0.13056140993 0.0360581 0.007352511.5823 0.0199999 0.0003602 11.5779 1.309E-05 0.0001516 0.13407139053 0.0363494 0.00757911.8421 0.0199999 0.0003602 11.8377 1.32E-05 0.0001562 0.13765663093 0.0366434 0.007811812.1066 0.0199999 0.0003602 12.1021 1.33E-05 0.000161 0.14131857212 0.0369392 0.008050712.3757 0.0199999 0.0003602 12.371 1.341E-05 0.0001659 0.14505878499 0.0372374 0.00829612.6494 0.0199999 0.0003602 12.6446 1.352E-05 0.000171 0.14887832893 0.037538 0.00854812.9278 0.0199999 0.0003602 12.923 1.363E-05 0.0001761 0.15277794762 0.0378406 0.008806613.2111 0.0199999 0.0003602 13.2061 1.374E-05 0.0001814 0.15675929918 0.0381458 0.009072113.4991 0.0199999 0.0003602 13.494 1.385E-05 0.0001869 0.16082479734 0.0384534 0.009344613.7921 0.0199999 0.0003602 13.7869 1.396E-05 0.0001925 0.16497436733 0.0387635 0.0096245

14.09 0.0199999 0.0003602 14.0847 1.407E-05 0.0001982 0.16920974731 0.039076 0.009911614.3929 0.0199999 0.0003602 14.3875 1.419E-05 0.0002041 0.17353311827 0.0393914 0.010206414.7009 0.0199999 0.0003602 14.6953 1.43E-05 0.0002102 0.17794555522 0.0397089 0.0105088

15.014 0.0199999 0.0003602 15.0083 1.442E-05 0.0002164 0.18244767895 0.0400297 0.010819315.3322 0.0199999 0.0003602 15.3264 1.453E-05 0.0002228 0.18704223385 0.0403526 0.011137815.6557 0.0199999 0.0003602 15.6498 1.465E-05 0.0002293 0.19173011929 0.0406788 0.011464715.9846 0.0199999 0.0003602 15.9785 1.477E-05 0.000236 0.19651276961 0.0410075 0.011800116.3187 0.0199999 0.0003602 16.3126 1.489E-05 0.0002429 0.20139228529 0.0413395 0.012144416.6583 0.0199999 0.0003602 16.652 1.501E-05 0.0002499 0.20636983411 0.041674 0.012497417.0034 0.0199999 0.0003602 16.997 1.513E-05 0.0002572 0.21144738565 0.0420119 0.0128597

17.354 0.0199999 0.0003602 17.3474 1.525E-05 0.0002646 0.21662587034 0.0423528 0.013231317.7102 0.0199999 0.0003602 17.7035 1.538E-05 0.0002722 0.22190869627 0.0426966 0.013612618.0721 0.0199999 0.0003602 18.0652 1.55E-05 0.0002801 0.22729546035 0.0430439 0.014003718.4397 0.0199999 0.0003602 18.4327 1.563E-05 0.0002881 0.23278908386 0.0433944 0.014404918.8131 0.0199999 0.0003602 18.8059 1.576E-05 0.0002963 0.23839110821 0.0437481 0.014816319.1923 0.0199999 0.0003602 19.185 1.589E-05 0.0003048 0.24410458905 0.0441055 0.015238519.5774 0.0199999 0.0003602 19.5699 1.602E-05 0.0003134 0.24992977023 0.0444663 0.015671419.9685 0.0199999 0.0003602 19.9609 1.615E-05 0.0003223 0.25586880596 0.0448306 0.016115420.3657 0.0199999 0.0003602 20.3579 1.628E-05 0.0003314 0.26192437817 0.0451987 0.016570920.7689 0.0199999 0.0003602 20.7609 1.641E-05 0.0003408 0.26809671813 0.0455704 0.017037921.1783 0.0199999 0.0003602 21.1701 1.655E-05 0.0003503 0.27439096341 0.045946 0.017516921.5939 0.0199999 0.0003602 21.5856 1.669E-05 0.0003602 0.28080761516 0.0463256 0.018008322.0158 0.0199999 0.0003602 22.0073 1.682E-05 0.0003702 0.28734724478 0.046709 0.0185121

22.444 0.0199998 0.0003602 22.4354 1.696E-05 0.0003806 0.29401540855 0.0470965 0.019028722.8787 0.0199999 0.0003602 22.8698 1.71E-05 0.0003912 0.30081252894 0.0474881 0.019558523.3198 0.0199999 0.0003602 23.3108 1.725E-05 0.000402 0.30773920336 0.0478842 0.020101923.7675 0.0199999 0.0003602 23.7583 1.739E-05 0.0004132 0.31479986419 0.0482844 0.02065924.2218 0.0199999 0.0003602 24.2124 1.754E-05 0.0004246 0.32199696273 0.0486893 0.0212304

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24.6827 0.0199999 0.0003602 24.6732 1.768E-05 0.0004363 0.32933259527 0.0490984 0.021816325.1504 0.0199998 0.0003602 25.1407 1.783E-05 0.0004483 0.33681054758 0.0495124 0.0224171

25.625 0.0199998 0.0003602 25.615 1.798E-05 0.0004607 0.34442831498 0.0499313 0.023033226.1063 0.0199999 0.0003602 26.0962 1.814E-05 0.0004733 0.35219515565 0.0503546 0.023664926.5947 0.0199999 0.0003602 26.5843 1.829E-05 0.0004862 0.36010815406 0.050783 0.0243126

27.09 0.0199999 0.0003602 27.0794 1.845E-05 0.0004995 0.36817539784 0.0512168 0.024976927.5924 0.0199999 0.0003602 27.5816 1.861E-05 0.0005132 0.3763962741 0.0516556 0.0256581

28.102 0.0199999 0.0003602 28.091 1.877E-05 0.0005271 0.3847721193 0.0520999 0.026356728.6187 0.0199999 0.0003602 28.6075 1.893E-05 0.0005415 0.39331179711 0.0525493 0.027072929.1428 0.0199999 0.0003602 29.1313 1.909E-05 0.0005561 0.40201314403 0.0530046 0.027807429.6741 0.0199999 0.0003602 29.6625 1.926E-05 0.0005712 0.41087894637 0.0534653 0.028560630.2129 0.0199999 0.0003602 30.201 1.943E-05 0.0005867 0.41991585583 0.053932 0.029332930.7592 0.0199999 0.0003602 30.7471 1.96E-05 0.0006025 0.42912701699 0.0544046 0.03012531.3131 0.0199999 0.0003602 31.3007 1.977E-05 0.0006187 0.4385122037 0.0548836 0.030937431.8745 0.0199999 0.0003602 31.8619 1.994E-05 0.0006354 0.44807843039 0.0553685 0.031770332.4437 0.0199999 0.0003602 32.4308 2.012E-05 0.0006525 0.45782642116 0.0558599 0.032624633.0206 0.0199999 0.0003602 33.0075 2.03E-05 0.00067 0.46776441143 0.0563577 0.033500633.6053 0.0199999 0.0003602 33.592 2.048E-05 0.000688 0.4778900138 0.0568625 0.0343993

34.198 0.0199999 0.0003602 34.1844 2.066E-05 0.0007064 0.48821080977 0.057374 0.035320834.7986 0.0199999 0.0003602 34.7847 2.085E-05 0.0007253 0.49872824827 0.0578925 0.036265935.4073 0.0199999 0.0003602 35.3932 2.104E-05 0.0007447 0.50945165616 0.0584185 0.037235636.0241 0.0199999 0.0003602 36.0097 2.123E-05 0.0007646 0.52037987092 0.0589518 0.03823

36.649 0.0199998 0.0003602 36.6344 2.143E-05 0.000785 0.53152098241 0.0594926 0.0392537.2823 0.0199999 0.0003602 37.2673 2.163E-05 0.0008059 0.54287314109 0.060041 0.040296137.9238 0.0199998 0.0003602 37.9086 2.183E-05 0.0008274 0.55445033596 0.0605977 0.041369638.5738 0.0199999 0.0003602 38.5583 2.203E-05 0.0008494 0.56624611599 0.0611621 0.042470639.2322 0.0199999 0.0003602 39.2164 2.224E-05 0.000872 0.57827701562 0.0617351 0.043600139.8992 0.0199999 0.0003602 39.8831 2.244E-05 0.0008952 0.59053820804 0.0623167 0.044759140.5748 0.0199999 0.0003602 40.5584 2.266E-05 0.000919 0.60303889671 0.0629071 0.045948241.2591 0.0199999 0.0003602 41.2425 2.287E-05 0.0009434 0.61578288643 0.0635062 0.047168141.9522 0.0199999 0.0003602 41.9352 2.309E-05 0.0009684 0.62878139315 0.0641148 0.0484242.6541 0.0199999 0.0003602 42.6368 2.332E-05 0.0009941 0.64203193052 0.0647326 0.0497045

43.365 0.0199999 0.0003602 43.3473 2.354E-05 0.0010205 0.65554377338 0.0653606 0.051022944.0848 0.0199999 0.0003602 44.0669 2.377E-05 0.0010475 0.66932043397 0.065998 0.052375844.8137 0.0199999 0.0003602 44.7954 2.4E-05 0.0010753 0.68337006091 0.0666459 0.053764445.5517 0.0199999 0.0003602 45.5331 2.424E-05 0.0011038 0.69769957166 0.0673041 0.0551895

46.299 0.0199999 0.0003602 46.28 2.448E-05 0.001133 0.71231481833 0.0679731 0.056652447.0555 0.0199999 0.0003602 47.0362 2.473E-05 0.0011631 0.72721977904 0.0686531 0.05815447.8214 0.0199999 0.0003602 47.8018 2.498E-05 0.0011939 0.74242570793 0.0693444 0.059695748.5968 0.0199998 0.0003602 48.5768 2.523E-05 0.0012256 0.75793503029 0.0700473 0.061278449.3816 0.0199999 0.0003602 49.3613 2.549E-05 0.0012581 0.77375961745 0.070762 0.062903450.1761 0.0199999 0.0003602 50.1554 2.575E-05 0.0012914 0.78990260062 0.0714892 0.064572250.9802 0.0199999 0.0003602 50.9592 2.602E-05 0.0013257 0.8063715259 0.0722288 0.066285851.7941 0.0199999 0.0003602 51.7727 2.629E-05 0.0013609 0.82317679637 0.0729811 0.068045452.6178 0.0199999 0.0003602 52.596 2.656E-05 0.0013971 0.84032747092 0.0737471 0.069853153.4514 0.0199999 0.0003602 53.4292 2.684E-05 0.0014342 0.85783083823 0.0745264 0.0717095

54.295 0.0199999 0.0003602 54.2724 2.713E-05 0.0014723 0.87568909637 0.0753197 0.073616555.1486 0.0199999 0.0003602 55.1256 2.742E-05 0.0015115 0.89392115589 0.0761273 0.075575556.0124 0.0199999 0.0003602 55.989 2.772E-05 0.0015518 0.91252853628 0.0769499 0.077588656.8864 0.0199999 0.0003602 56.8626 2.802E-05 0.0015931 0.93152748607 0.0777871 0.079656657.7707 0.0199999 0.0003602 57.7465 2.832E-05 0.0016356 0.95092051788 0.0786403 0.081782158.6653 0.0199999 0.0003602 58.6407 2.864E-05 0.0016793 0.97072155734 0.0795096 0.083966559.5704 0.0199999 0.0003602 59.5453 2.896E-05 0.0017242 0.99094146714 0.0803951 0.0862114

60.486 0.0199998 0.0003602 60.4605 2.928E-05 0.0017704 1.01158748561 0.0812978 0.0885193

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61.4122 0.0199999 0.0003602 61.3863 2.961E-05 0.0018178 1.03267326031 0.0822172 0.090891262.3492 0.0199999 0.0003602 62.3228 2.995E-05 0.0018666 1.05421145738 0.0831552 0.093330663.2968 0.0199999 0.0003602 63.27 3.029E-05 0.0019168 1.07621283336 0.0841113 0.095838464.2553 0.0199999 0.0003602 64.2281 3.065E-05 0.0019683 1.09868881167 0.0850863 0.098417565.2248 0.0199999 0.0003602 65.197 3.1E-05 0.0020214 1.12164814502 0.0860809 0.101069966.2052 0.0199998 0.0003602 66.177 3.137E-05 0.002076 1.14511120161 0.0870958 0.103798667.1968 0.0199999 0.0003602 67.1681 3.174E-05 0.0021321 1.16909022047 0.088131 0.106605368.1995 0.0199999 0.0003602 68.1703 3.212E-05 0.0021898 1.19359224745 0.0891875 0.10949369.2134 0.0199999 0.0003602 69.1837 3.251E-05 0.0022493 1.21863680221 0.0902656 0.11246470.2387 0.0199999 0.0003602 70.2085 3.291E-05 0.0023104 1.24423605426 0.0913666 0.115521971.2753 0.0199999 0.0003602 71.2447 3.331E-05 0.0023734 1.27041054344 0.0924905 0.118668972.3235 0.0199999 0.0003602 72.2923 3.373E-05 0.0024382 1.29716674899 0.0936385 0.121908573.3832 0.0199999 0.0003602 73.3515 3.415E-05 0.0025049 1.32453311565 0.0948112 0.125243874.4546 0.0199998 0.0003602 74.4224 3.458E-05 0.0025735 1.35251627993 0.0960092 0.128677875.5377 0.0199999 0.0003602 75.505 3.502E-05 0.0026443 1.38114019049 0.0972328 0.132213676.6327 0.0199999 0.0003602 76.5994 3.547E-05 0.0027171 1.41041704423 0.0984837 0.135855577.7395 0.0199999 0.0003602 77.7056 3.593E-05 0.0027921 1.44037390857 0.0997622 0.139606678.8583 0.0199998 0.0003602 78.8239 3.64E-05 0.0028694 1.47101912166 0.1010699 0.14347279.9892 0.0199999 0.0003602 79.9542 3.688E-05 0.0029491 1.5023801614 0.1024066 0.147454181.1322 0.0199999 0.0003602 81.0967 3.738E-05 0.0030311 1.5344766174 0.1037735 0.1515574

82.286 0.0199999 0.0003602 82.2499 3.788E-05 0.0031156 1.56731004958 0.1051715 0.155783483.4534 0.0199999 0.0003602 83.4167 3.84E-05 0.0032028 1.60094508235 0.1066026 0.160143184.6294 0.0199999 0.0003602 84.5922 3.892E-05 0.0032922 1.63541696688 0.1080545 0.164611785.9007 0.0199999 0.0003602 85.8628 3.947E-05 0.0033893 1.671636248 0.1095955 0.16946787.1104 0.0199999 0.0003602 87.0718 4.003E-05 0.0034853 1.70782025709 0.1111337 0.174265288.3345 0.0199999 0.0003602 88.2954 4.06E-05 0.0035844 1.74490505895 0.1127097 0.179220189.5701 0.0199999 0.0003602 89.5303 4.118E-05 0.0036866 1.78288660533 0.1143235 0.184328790.8188 0.0199999 0.0003602 90.7784 4.177E-05 0.003792 1.82179948888 0.1159771 0.189601692.0808 0.0199999 0.0003602 92.0397 4.238E-05 0.0039009 1.86167742443 0.1176713 0.195044393.3561 0.0199999 0.0003602 93.3143 4.301E-05 0.0040133 1.90255758639 0.1194084 0.200664594.6448 0.0199999 0.0003602 94.6024 4.365E-05 0.0041294 1.94446785903 0.1211894 0.206468795.9472 0.0199999 0.0003602 95.9041 4.431E-05 0.0042493 1.98743672334 0.123016 0.212464497.2633 0.0199999 0.0003602 97.2196 4.498E-05 0.0043732 2.03150823512 0.1248896 0.218659198.5934 0.0199998 0.0003602 98.5489 4.567E-05 0.0045012 2.07671757721 0.126812 0.225060799.9374 0.0199999 0.0003602 99.8923 4.639E-05 0.0046335 2.12309426062 0.1287848 0.2316777101.296 0.0199999 0.0003602 101.25 4.711E-05 0.0047704 2.17068381432 0.1308101 0.2385195102.668 0.0199999 0.0003602 102.622 4.786E-05 0.0049119 2.21953005154 0.1328904 0.2455962104.055 0.0199999 0.0003602 104.008 4.863E-05 0.0050583 2.26966926168 0.1350267 0.2529145105.457 0.0199999 0.0003602 105.409 4.942E-05 0.0052097 2.32115799016 0.1372214 0.2604875106.873 0.0199999 0.0003602 106.824 5.024E-05 0.0053664 2.3740217987 0.1394772 0.268324108.304 0.0199999 0.0003602 108.255 5.107E-05 0.0055287 2.42832970075 0.1417958 0.2764386109.751 0.0199999 0.0003602 109.701 5.193E-05 0.0056968 2.48413254136 0.1441808 0.284843111.213 0.0199999 0.0003602 111.162 5.281E-05 0.0058709 2.5414730787 0.1466337 0.293547

112.69 0.0199999 0.0003602 112.638 5.372E-05 0.0060513 2.60041192868 0.1491574 0.302564114.182 0.0199999 0.0003602 114.13 5.466E-05 0.0062382 2.66101212638 0.1517557 0.3119122115.691 0.0199999 0.0003602 115.638 5.562E-05 0.0064321 2.72333301976 0.1544311 0.3216049117.215 0.0199999 0.0003602 117.161 5.661E-05 0.006633 2.78743261793 0.1571862 0.3316537118.756 0.0199999 0.0003602 118.701 5.764E-05 0.0068416 2.85339862308 0.1600255 0.3420827120.313 0.0199999 0.0003602 120.257 5.869E-05 0.0070581 2.92127603424 0.1629518 0.3529044121.887 0.0199999 0.0003602 121.83 5.978E-05 0.0072828 2.99116741243 0.1659697 0.3641419123.477 0.0199999 0.0003602 123.42 6.09E-05 0.0075162 3.06314390754 0.1690831 0.3758142125.084 0.0199999 0.0003602 125.026 6.206E-05 0.0077587 3.13728070531 0.172295 0.3879362126.709 0.0199999 0.0003602 126.65 6.325E-05 0.0080108 3.21366975728 0.1756117 0.4005402128.351 0.0199999 0.0003602 128.291 6.449E-05 0.0082729 3.29242328804 0.1790376 0.4136452

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130.011 0.0199999 0.0003602 129.95 6.576E-05 0.0085455 3.37360852813 0.1825779 0.4272794131.688 0.0199999 0.0003602 131.626 6.708E-05 0.0088292 3.45737311112 0.1862373 0.4414645133.384 0.0199999 0.0003602 133.321 6.844E-05 0.0091247 3.54379066482 0.1900233 0.4562395135.098 0.0199999 0.0003602 135.034 6.985E-05 0.0094325 3.63299512377 0.1939408 0.4716282

136.83 0.0199999 0.0003602 136.766 7.131E-05 0.0097533 3.725119609 0.1979973 0.4876687138.582 0.0199999 0.0003602 138.516 7.283E-05 0.0100878 3.82028812052 0.2022008 0.5043944140.353 0.0199999 0.0003602 140.286 7.44E-05 0.0104369 3.91866744384 0.2065578 0.5218473142.143 0.0199999 0.0003602 142.076 7.603E-05 0.0108013 4.02037503373 0.2110774 0.5400698143.953 0.0199999 0.0003602 143.885 7.771E-05 0.011182 4.12560750214 0.2157694 0.5591042145.783 0.0199999 0.0003602 145.714 7.947E-05 0.0115799 4.23453711234 0.2206424 0.5789988147.633 0.0199999 0.0003602 147.563 8.129E-05 0.0119961 4.34734346907 0.2257086 0.5998091149.504 0.0199999 0.0003602 149.434 8.319E-05 0.0124319 4.46424433949 0.2309795 0.621599151.397 0.0199999 0.0003602 151.325 8.517E-05 0.0128883 4.58544529505 0.236467 0.6444194

153.31 0.0199998 0.0003602 153.238 8.723E-05 0.0133669 4.71121429927 0.2421867 0.6683504155.246 0.0199999 0.0003602 155.172 8.938E-05 0.013869 4.84179471061 0.2481521 0.6934557157.204 0.0199999 0.0003602 157.129 9.162E-05 0.0143965 4.97748197904 0.2543825 0.7198319159.184 0.0199999 0.0003602 159.109 9.397E-05 0.0149512 5.11857564022 0.2608955 0.7475646161.187 0.0199999 0.0003602 161.111 9.642E-05 0.0155349 5.26545428868 0.2677125 0.7767502163.212 0.0199999 0.0003602 163.12 9.897E-05 0.0161438 5.41838554505 0.2747796 0.8071963165.264 0.0199999 0.0003602 165.186 0.0001017 0.0167978 5.57762234317 0.2823345 0.8398944167.338 0.0199998 0.0003602 167.26 0.0001045 0.0174792 5.74261928226 0.2901458 0.8739686169.438 0.0199999 0.0003602 169.361 0.0001075 0.018198 5.91404936849 0.2983294 0.909907171.563 0.0199999 0.0003602 171.484 0.0001105 0.0189547 6.09189935213 0.3068865 0.9477391173.722 0.0199999 0.0003602 173.634 0.0001138 0.019753 6.27638746201 0.3158521 0.9876566175.916 0.0199999 0.0003602 175.813 0.0001172 0.0205974 6.46771463895 0.3252721 1.0298767178.139 0.0199999 0.0003602 178.034 0.0001208 0.0214982 6.6661167905 0.3352618 1.074916180.393 0.0199999 0.0003602 180.287 0.0001246 0.0224555 6.87190975353 0.3458151 1.1227831182.679 0.0199999 0.0003602 182.571 0.0001286 0.0234758 7.0854353198 0.3570042 1.1737959

185 0.0199999 0.0003602 184.889 0.0001329 0.0245679 7.30705831552 0.3689288 1.2284038187.296 0.0199999 0.0003602 187.222 0.0001374 0.0257176 7.53723585133 0.3813796 1.285884189.191 0.0199999 0.0003602 189.111 0.0001401 0.0265032 7.77645405299 0.3891049 1.3251682191.063 0.0199999 0.0003602 190.989 0.0001427 0.0272521 8.02519940795 0.3961654 1.3626125192.945 0.0199999 0.0003602 192.869 0.0001451 0.0279942 8.28406745767 0.4029859 1.3997152194.837 0.0199999 0.0003602 194.76 0.0001476 0.0287406 8.55385016296 0.4097151 1.4370411

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0 1 2 3 4 5 6 7100

100.5

101

101.5

102

102.5

103

103.5

104 Boiling of boric acid solutions

Nasini and Ageno 1940von Stackelberg et al. 1937prediction

m H3BO3

tB [C

]

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Hatm1.991E-052.183E-052.392E-052.619E-052.867E-053.136E-053.429E-053.746E-05

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4.091E-054.466E-054.871E-055.311E-055.787E-056.302E-056.859E-057.461E-058.111E-058.813E-059.571E-050.00010390.00011270.00012210.00013230.00014330.00015510.00016780.00018140.000196

0.00021170.00022850.00024650.00026580.00028640.00030850.00033210.00035730.00038420.000413

0.00044370.00047640.00051130.00054850.00058810.00063020.000675

0.00072260.00077330.00082710.00088420.00094490.00100920.00107740.00114970.00122630.00130740.00139320.00148410.00158010.00168170.001789

0.00190230.002022

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0.00214830.00228150.002422

0.00257010.00272610.00289050.00306360.00324570.00343730.00363890.00385070.00407340.00430730.004553

0.00481080.00508150.00536540.00566310.00597520.00630230.006645

0.00700390.00737960.00777290.00818430.00861470.00906470.009535

0.01002650.01054

0.01107630.01163610.01222040.01283010.01346620.01412940.01482090.01554150.01629240.01707460.01788920.01873730.01962010.02053850.02149410.022488

0.02352150.02459560.0257120.026872

0.02807690.02932830.03062760.0319761

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0.03337580.03482820.03633440.03789690.03951690.04119610.04293670.04474010.04660870.04854390.05054820.05262310.05477110.05699410.05929450.06167430.06413580.06668180.06931390.07203520.07484780.07775440.08075760.08386020.08706470.09037410.09379150.09731890.10096070.10471860.10859650.11259750.11672470.12098170.12537150.12989780.13456470.139375

0.14433280.14944230.15470710.16012970.165718

0.17147190.17739740.18349990.18978410.19625040.20290980.20976220.21681310.224069

0.23153440.2392158

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0.24711460.25524070.26359670.27219090.28102680.29011170.29944950.30904680.31891310.329054

0.33947350.35018260.36118480.37248320.38409480.39602140.40827090.42084990.43377360.44704180.46066340.47465240.48901440.50375770.51888970.534428

0.55037420.56674320.58353450.60077730.61846030.63661450.65523820.67435480.6939560.714076

0.73471130.75587960.77759620.799876

0.82272280.84616380.87020050.89485920.92015050.94608270.97268110.9999668

1.027941.056629

1.08604311.11621941.14715561.1788847

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1.21141521.24477731.278989

1.31406431.35003181.38692161.42474371.463538

1.50330551.54409151.58591511.62879911.672785

1.71789451.7641451

1.811581.86022521.91012511.96129562.01377392.06761882.12283762.17947682.23756462.29717482.35830812.42102832.48538382.55141292.61915512.68866722.75999282.83320492.90832872.98543143.06456493.14579623.22918043.31478683.402673

3.49290363.58557023.6807223.778429

3.87880483.98188774.087781

4.19656254.30834714.42317814.54120194.66249684.78714974.9153053

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5.0470125.18246555.32172255.46493075.61221465.76373665.91958856.07993696.24491066.41470886.58945526.76934346.95454657.14523197.34156337.54379147.75208217.96672068.18784018.41569058.65034868.89243539.14056859.4101759

9.676619.951746710.23541710.52821110.83043411.14251111.46481

11.79773612.14171712.49718812.86461313.24452813.63748114.04385314.46436814.89951415.35010115.81678116.30009816.80079617.319883

17.858118.41608718.99519119.59609820.22009320.86823821.54134922.24122222.968915

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23.72600124.51366825.33409926.18860327.07929828.00804628.97716929.98903

31.04597332.15068233.30624134.51619235.78336237.11220238.50625539.97087441.51081743.13143444.82205

46.63771148.52978550.52537452.62612154.84266157.18705959.68800862.34597165.17861568.21088471.40265

73.58402475.66323677.72347879.796114

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0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6 log Q1,1 of boric acid

Mesmer 1972 - B(OH)3

Palmer 2000 - B(OH)3

Byers 2000 - B(OH)3

prediciton - B(OH)3

t/C

logQ

11

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6 log Q2,1 of boric acid

Mesmer 1972 - I=1M

Palmer 2000 - B(OH)3

Palmer 2000 - I=1M

Byers 2000

prediction - B(OH)3

t/C

logQ

21

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6

7

8

9 log Q3,1 of boric acid

Mesmer 1972 - I=1MPalmer 2000 - B(OH)3Palmer 2000 - I=1MByers 2000prediction - B(OH)3

t/C

logQ

31

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0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6

7

8

9 log Q3,1 of boric acid

Mesmer 1972 - I=1MPalmer 2000 - B(OH)3Palmer 2000 - I=1MByers 2000prediction - B(OH)3

t/C

logQ

31

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

2

4

6

8

10

12

14

16 log Q4,2 of boric acid

Mesmer 1972 - I=1MPalmer 2000Palmer 2000 - I=1MByers 2000prediciton

t/C

logQ

42

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

5

10

15

20

25 log Q5,3 of boric acid

Mesmer 1972 - I=1MPalmer 2000Palmer 2000 - I=1Mprediction

t/C

logQ

53

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Mesmer, R. E.; Baes, C. F. Jr.; Sweeton, F. H.Acidity measurements at elevated temperatures. VI. Boric acid equilibriaInorganic Chemistry 1972, 11 (3), 537-543

t Q1,1 Q2,1 Q3,1 Q4,2 Q5,3C I=1 I=1 I=1 I=1

0 5.4411601 5.3404614 7.7891758 14.958592 21.7891981 5.4112395 5.312917 7.746956 14.854216 21.6584312 5.3815481 5.2856063 7.7050517 14.750842 21.5288223 5.3520836 5.2585268 7.6634595 14.648457 21.4003594 5.3228438 5.2316758 7.6221759 14.54705 21.2730295 5.2938266 5.2050507 7.5811976 14.446609 21.1468186 5.2650299 5.178649 7.5405212 14.347123 21.0217147 5.2364515 5.1524683 7.5001436 14.248582 20.8977058 5.2080894 5.1265059 7.4600614 14.150973 20.7747789 5.1799416 5.1007595 7.4202715 14.054287 20.65292

10 5.152006 5.0752267 7.3807709 13.958513 20.5321211 5.1242807 5.0499051 7.3415563 13.86364 20.41236612 5.0967636 5.0247924 7.3026248 13.769658 20.29364613 5.0694529 4.9998862 7.2639734 13.676557 20.17594914 5.0423466 4.9751844 7.2255991 13.584327 20.05926315 5.0154428 4.9506847 7.187499 13.492959 19.94357716 4.9887398 4.9263848 7.1496703 13.402442 19.8288817 4.9622356 4.9022826 7.11211 13.312766 19.71516218 4.9359285 4.878376 7.0748155 13.223923 19.60241119 4.9098166 4.8546628 7.0377839 13.135904 19.49061620 4.8838981 4.8311411 7.0010125 13.048698 19.37976921 4.8581715 4.8078086 6.9644987 12.962297 19.26985722 4.8326348 4.7846634 6.9282399 12.876693 19.160872

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

5

10

15

20

25 log Q5,3 of boric acid

Mesmer 1972 - I=1MPalmer 2000Palmer 2000 - I=1Mprediction

t/C

logQ

53

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23 4.8072864 4.7617035 6.8922333 12.791876 19.05280224 4.7821247 4.738927 6.8564764 12.707837 18.94563925 4.7571479 4.7163318 6.8209668 12.624569 18.83937226 4.7323545 4.6939162 6.7857018 12.542062 18.73399227 4.7077428 4.6716781 6.7506791 12.460308 18.6294928 4.6833112 4.6496157 6.7158962 12.3793 18.52585629 4.6590582 4.6277272 6.6813506 12.29903 18.4230830 4.6349821 4.6060108 6.6470401 12.219488 18.32115531 4.6110815 4.5844646 6.6129622 12.140668 18.2200732 4.5873548 4.563087 6.5791147 12.062561 18.11981833 4.5638005 4.5418762 6.5454952 11.98516 18.02038934 4.5404172 4.5208304 6.5121016 11.908458 17.92177435 4.5172033 4.499948 6.4789316 11.832447 17.82396636 4.4941574 4.4792273 6.4459829 11.757119 17.72695637 4.4712782 4.4586667 6.4132536 11.682468 17.63073638 4.4485641 4.4382644 6.3807413 11.608486 17.53529739 4.4260138 4.418019 6.3484441 11.535167 17.44063240 4.4036258 4.3979288 6.3163598 11.462503 17.34673241 4.381399 4.3779923 6.2844863 11.390487 17.2535942 4.3593318 4.3582079 6.2528217 11.319113 17.16119843 4.337423 4.338574 6.221364 11.248374 17.06954944 4.3156712 4.3190893 6.1901111 11.178264 16.97863545 4.2940751 4.2997522 6.1590611 11.108775 16.88844846 4.2726335 4.2805612 6.1282121 11.039903 16.79898147 4.2513451 4.2615148 6.0975621 10.971639 16.71022748 4.2302086 4.2426118 6.0671094 10.903978 16.62217949 4.2092228 4.2238506 6.036852 10.836914 16.53482950 4.1883865 4.2052298 6.0067881 10.770441 16.44817251 4.1676984 4.1867482 5.976916 10.704553 16.36219952 4.1471574 4.1684042 5.9472337 10.639243 16.27690553 4.1267622 4.1501967 5.9177396 10.574506 16.19228254 4.1065117 4.1321242 5.8884319 10.510337 16.10832355 4.0864047 4.1141854 5.8593088 10.446728 16.02502356 4.0664402 4.0963792 5.8303688 10.383676 15.94237557 4.0466168 4.0787041 5.80161 10.321174 15.86037358 4.0269336 4.0611589 5.7730309 10.259216 15.77900959 4.0073895 4.0437424 5.7446298 10.197798 15.69827960 3.9879832 4.0264534 5.716405 10.136914 15.61817561 3.9687138 4.0092906 5.688355 10.076559 15.53869362 3.9495802 3.9922529 5.6604783 10.016727 15.45982563 3.9305813 3.975339 5.6327731 9.957413 15.38156664 3.9117161 3.9585479 5.605238 9.8986124 15.3039165 3.8929835 3.9418782 5.5778715 9.8403201 15.22685166 3.8743825 3.925329 5.5506721 9.782531 15.15038467 3.8559121 3.908899 5.5236382 9.7252401 15.07450468 3.8375713 3.8925872 5.4967684 9.6684427 14.99920369 3.8193591 3.8763925 5.4700612 9.612134 14.92447870 3.8012745 3.8603137 5.4435152 9.5563092 14.85032271 3.7833166 3.8443498 5.417129 9.5009636 14.7767372 3.7654843 3.8284998 5.3909012 9.4460927 14.70369873 3.7477768 3.8127625 5.3648304 9.3916919 14.631219

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74 3.7301931 3.797137 5.3389151 9.3377567 14.55928875 3.7127323 3.7816223 5.3131541 9.2842826 14.48790176 3.6953934 3.7662172 5.2875461 9.2312653 14.41705377 3.6781756 3.7509209 5.2620896 9.1787004 14.34673778 3.6610779 3.7357323 5.2367834 9.1265835 14.27695179 3.6440994 3.7206505 5.2116261 9.0749106 14.20768780 3.6272394 3.7056744 5.1866166 9.0236773 14.13894381 3.6104968 3.6908032 5.1617535 8.9728796 14.07071382 3.5938708 3.6760359 5.1370356 8.9225133 14.00299283 3.5773607 3.6613715 5.1124617 8.8725744 13.93577684 3.5609654 3.6468092 5.0880304 8.8230589 13.8690685 3.5446843 3.632348 5.0637407 8.7739629 13.80283986 3.5285164 3.6179871 5.0395913 8.7252824 13.7371187 3.512461 3.6037255 5.015581 8.6770137 13.67186788 3.4965172 3.5895623 4.9917087 8.6291528 13.60710789 3.4806843 3.5754968 4.9679732 8.5816961 13.54282490 3.4649614 3.561528 4.9443734 8.5346398 13.47901591 3.4493477 3.547655 4.9209081 8.4879802 13.41567692 3.4338425 3.5338771 4.8975762 8.4417137 13.35280293 3.4184451 3.5201934 4.8743766 8.3958366 13.29038994 3.4031545 3.5066031 4.8513082 8.3503455 13.22843495 3.3879702 3.4931054 4.82837 8.3052369 13.16693196 3.3728913 3.4796995 4.8055608 8.2605071 13.10587797 3.3579171 3.4663845 4.7828796 8.2161529 13.04526898 3.3430468 3.4531597 4.7603254 8.1721708 12.98510199 3.3282798 3.4400244 4.7378971 8.1285574 12.92537

100 3.3136153 3.4269777 4.7155936 8.0853095 12.866074101 3.2990527 3.4140189 4.6934141 8.0424238 12.807206102 3.2845911 3.4011472 4.6713574 7.9998969 12.748765103 3.2702299 3.388362 4.6494227 7.9577258 12.690746104 3.2559685 3.3756623 4.6276088 7.9159071 12.633146105 3.2418061 3.3630477 4.6059148 7.8744379 12.575961106 3.227742 3.3505172 4.5843398 7.833315 12.519187107 3.2137757 3.3380703 4.5628829 7.7925352 12.462821108 3.1999063 3.3257061 4.541543 7.7520957 12.406859109 3.1861333 3.3134241 4.5203193 7.7119933 12.351298110 3.1724561 3.3012235 4.4992107 7.6722252 12.296135111 3.1588738 3.2891036 4.4782165 7.6327883 12.241366112 3.1453861 3.2770638 4.4573358 7.5936799 12.186988113 3.1319921 3.2651033 4.4365675 7.5548969 12.132997114 3.1186912 3.2532216 4.4159109 7.5164366 12.07939115 3.1054829 3.241418 4.395365 7.4782961 12.026164116 3.0923666 3.2296919 4.374929 7.4404728 11.973316117 3.0793416 3.2180425 4.3546021 7.4029637 11.920843118 3.0664072 3.2064693 4.3343834 7.3657663 11.868741119 3.053563 3.1949717 4.314272 7.3288778 11.817007120 3.0408084 3.183549 4.2942671 7.2922956 11.765639121 3.0281426 3.1722006 4.274368 7.2560169 11.714633122 3.0155653 3.1609259 4.2545737 7.2200394 11.663986123 3.0030757 3.1497243 4.2348836 7.1843602 11.613695124 2.9906733 3.1385952 4.2152967 7.148977 11.563757

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125 2.9783576 3.1275381 4.1958123 7.1138872 11.51417126 2.9661279 3.1165523 4.1764297 7.0790882 11.464931127 2.9539838 3.1056373 4.157148 7.0445776 11.416036128 2.9419246 3.0947925 4.1379664 7.0103531 11.367482129 2.9299499 3.0840173 4.1188843 6.9764121 11.319268130 2.9180591 3.0733112 4.0999009 6.9427522 11.27139131 2.9062517 3.0626737 4.0810154 6.9093712 11.223846132 2.8945271 3.0521041 4.0622271 6.8762666 11.176632133 2.8828847 3.041602 4.0435353 6.8434361 11.129747134 2.8713242 3.0311668 4.0249392 6.8108776 11.083187135 2.8598449 3.020798 4.0064382 6.7785885 11.03695136 2.8484464 3.010495 3.9880314 6.7465669 10.991033137 2.8371282 3.0002574 3.9697184 6.7148103 10.945434138 2.8258897 2.9900846 3.9514982 6.6833166 10.90015139 2.8147304 2.9799762 3.9333703 6.6520837 10.855178140 2.8036499 2.9699315 3.915334 6.6211094 10.810517141 2.7926477 2.9599502 3.8973886 6.5903915 10.766163142 2.7817232 2.9500317 3.8795334 6.559928 10.722115143 2.7708761 2.9401755 3.8617678 6.5297167 10.678369144 2.7601057 2.9303812 3.8440911 6.4997556 10.634924145 2.7494118 2.9206482 3.8265027 6.4700426 10.591777146 2.7387937 2.9109762 3.8090019 6.4405757 10.548925147 2.728251 2.9013646 3.7915881 6.411353 10.506367148 2.7177833 2.8918129 3.7742607 6.3823723 10.4641149 2.7073901 2.8823208 3.757019 6.3536318 10.422121150 2.697071 2.8728877 3.7398625 6.3251295 10.38043151 2.6868254 2.8635132 3.7227905 6.2968635 10.339022152 2.6766531 2.8541968 3.7058024 6.2688319 10.297896153 2.6665534 2.8449382 3.6888976 6.2410328 10.257051154 2.656526 2.8357368 3.6720756 6.2134642 10.216483155 2.6465705 2.8265923 3.6553356 6.1861245 10.17619156 2.6366864 2.8175042 3.6386773 6.1590116 10.136171157 2.6268734 2.8084721 3.6220999 6.1321239 10.096424158 2.6171308 2.7994955 3.6056029 6.1054596 10.056945159 2.6074585 2.7905741 3.5891857 6.0790167 10.017734160 2.5978559 2.7817074 3.5728479 6.0527937 9.9787877161 2.5883226 2.772895 3.5565887 6.0267886 9.9401047162 2.5788582 2.7641365 3.5404077 6.0009999 9.9016827163 2.5694624 2.7554316 3.5243044 5.9754259 9.8635199164 2.5601347 2.7467798 3.5082781 5.9500647 9.8256142165 2.5508747 2.7381807 3.4923284 5.9249147 9.7879637166 2.541682 2.7296339 3.4764547 5.8999743 9.7505664167 2.5325563 2.7211391 3.4606564 5.8752419 9.7134205168 2.5234971 2.7126958 3.4449332 5.8507158 9.6765241169 2.514504 2.7043037 3.4292844 5.8263943 9.6398752170 2.5055768 2.6959625 3.4137096 5.8022759 9.603472171 2.496715 2.6876716 3.3982082 5.7783591 9.5673128172 2.4879181 2.6794309 3.3827797 5.7546422 9.5313956173 2.479186 2.6712398 3.3674236 5.7311237 9.4957186174 2.4705181 2.6630981 3.3521395 5.707802 9.4602801175 2.4619142 2.6550053 3.3369269 5.6846757 9.4250783

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176 2.4533738 2.6469612 3.3217852 5.6617431 9.3901114177 2.4448966 2.6389654 3.306714 5.639003 9.3553777178 2.4364822 2.6310174 3.2917129 5.6164536 9.3208755179 2.4281304 2.6231171 3.2767812 5.5940937 9.2866031180 2.4198406 2.615264 3.2619187 5.5719217 9.2525587181 2.4116127 2.6074578 3.2471247 5.5499362 9.2187407182 2.4034462 2.5996981 3.232399 5.5281357 9.1851474183 2.3953408 2.5919847 3.2177409 5.5065189 9.1517773184 2.3872961 2.5843172 3.20315 5.4850844 9.1186286185 2.3793119 2.5766953 3.188626 5.4638308 9.0856997186 2.3713877 2.5691185 3.1741683 5.4427566 9.0529891187 2.3635233 2.5615868 3.1597765 5.4218606 9.0204952188 2.3557184 2.5540996 3.1454502 5.4011414 8.9882164189 2.3479725 2.5466567 3.131189 5.3805977 8.956151190 2.3402854 2.5392578 3.1169923 5.3602281 8.9242977191 2.3326567 2.5319026 3.1028599 5.3400314 8.8926549192 2.3250862 2.5245907 3.0887913 5.3200062 8.8612209193 2.3175734 2.5173219 3.074786 5.3001512 8.8299945194 2.3101182 2.5100959 3.0608436 5.2804652 8.798974195 2.3027202 2.5029123 3.0469638 5.2609469 8.7681579196 2.295379 2.4957708 3.0331461 5.2415951 8.7375449197 2.2880944 2.4886713 3.0193902 5.2224086 8.7071335198 2.280866 2.4816133 3.0056955 5.203386 8.6769222199 2.2736936 2.4745966 2.9920619 5.1845262 8.6469096200 2.2665769 2.4676209 2.9784887 5.1658279 8.6170944201 2.2595156 2.4606859 2.9649757 5.1472901 8.587475202 2.2525093 2.4537914 2.9515225 5.1289114 8.5580502203 2.2455577 2.446937 2.9381286 5.1106908 8.5288186204 2.2386607 2.4401225 2.9247938 5.092627 8.4997787205 2.2318179 2.4333476 2.9115175 5.0747189 8.4709293206 2.2250289 2.4266121 2.8982996 5.0569654 8.442269207 2.2182936 2.4199156 2.8851395 5.0393654 8.4137964208 2.2116116 2.413258 2.8720369 5.0219176 8.3855104209 2.2049827 2.4066388 2.8589915 5.004621 8.3574095210 2.1984065 2.400058 2.8460028 4.9874746 8.3294925211 2.1918829 2.3935152 2.8330706 4.9704771 8.3017581212 2.1854115 2.3870101 2.8201945 4.9536276 8.274205213 2.178992 2.3805425 2.8073742 4.9369249 8.246832214 2.1726243 2.3741122 2.7946091 4.9203679 8.2196379215 2.1663079 2.3677189 2.7818992 4.9039558 8.1926213216 2.1600427 2.3613624 2.7692439 4.8876873 8.1657811217 2.1538284 2.3550423 2.756643 4.8715614 8.1391161218 2.1476648 2.3487585 2.744096 4.8555772 8.112625219 2.1415514 2.3425108 2.7316028 4.8397336 8.0863067220 2.1354883 2.3362988 2.7191629 4.8240296 8.06016221 2.1294749 2.3301223 2.706776 4.8084642 8.0341836222 2.1235112 2.3239812 2.6944418 4.7930364 8.0083766223 2.1175968 2.3178751 2.68216 4.7777452 7.9827376224 2.1117315 2.3118039 2.6699302 4.7625896 7.9572655225 2.105915 2.3057673 2.6577522 4.7475688 7.9319593226 2.1001472 2.299765 2.6456256 4.7326817 7.9068177

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227 2.0944277 2.2937969 2.63355 4.7179273 7.8818397228 2.0887563 2.2878628 2.6215252 4.7033048 7.8570242229 2.0831328 2.2819623 2.609551 4.6888132 7.8323701230 2.0775569 2.2760953 2.5976269 4.6744516 7.8078762231 2.0720284 2.2702616 2.5857526 4.660219 7.7835416232 2.066547 2.264461 2.5739279 4.6461146 7.7593651233 2.0611126 2.2586931 2.5621525 4.6321374 7.7353457234 2.0557248 2.2529579 2.5504261 4.6182866 7.7114823235 2.0503836 2.2472551 2.5387483 4.6045612 7.6877739236 2.0450885 2.2415845 2.5271189 4.5909605 7.6642195237 2.0398394 2.2359459 2.5155376 4.5774835 7.640818238 2.0346361 2.230339 2.5040042 4.5641293 7.6175684239 2.0294784 2.2247637 2.4925182 4.5508971 7.5944697240 2.0243659 2.2192199 2.4810795 4.5377861 7.571521241 2.0192986 2.2137071 2.4696877 4.5247954 7.5487211242 2.0142761 2.2082254 2.4583426 4.5119242 7.5260692243 2.0092983 2.2027744 2.447044 4.4991716 7.5035642244 2.004365 2.197354 2.4357914 4.4865368 7.4812053245 1.9994758 2.1919639 2.4245848 4.474019 7.4589913246 1.9946307 2.1866041 2.4134237 4.4616175 7.4369215247 1.9898294 2.1812742 2.4023079 4.4493313 7.4149948248 1.9850717 2.1759742 2.3912372 4.4371598 7.3932103249 1.9803573 2.1707038 2.3802113 4.4251021 7.371567250 1.9756861 2.1654627 2.3692299 4.4131574 7.3500642251 1.9710579 2.160251 2.3582928 4.401325 7.3287007252 1.9664725 2.1550683 2.3473997 4.389604 7.3074758253 1.9619295 2.1499144 2.3365504 4.3779938 7.2863886254 1.957429 2.1447893 2.3257445 4.3664936 7.2654381255 1.9529706 2.1396926 2.3149819 4.3551026 7.2446234256 1.9485541 2.1346243 2.3042624 4.3438201 7.2239437257 1.9441794 2.1295841 2.2935856 4.3326454 7.2033982258 1.9398462 2.124572 2.2829513 4.3215776 7.1829859259 1.9355544 2.1195876 2.2723592 4.3106162 7.1627059260 1.9313038 2.1146308 2.2618092 4.2997603 7.1425576261 1.9270941 2.1097015 2.251301 4.2890093 7.1225399262 1.9229252 2.1047995 2.2408343 4.2783624 7.1026521263 1.9187969 2.0999246 2.230409 4.267819 7.0828933264 1.914709 2.0950767 2.2200247 4.2573783 7.0632628265 1.9106613 2.0902556 2.2096812 4.2470397 7.0437596266 1.9066537 2.085461 2.1993784 4.2368025 7.0243831267 1.9026858 2.0806929 2.1891159 4.2266659 7.0051323268 1.8987576 2.0759512 2.1788936 4.2166294 6.9860065269 1.8948689 2.0712355 2.1687112 4.2066922 6.9670049270 1.8910195 2.0665458 2.1585685 4.1968537 6.9481267271 1.8872092 2.0618819 2.1484653 4.1871133 6.9293712272 1.8834378 2.0572437 2.1384014 4.1774702 6.9107375273 1.8797051 2.052631 2.1283765 4.1679239 6.8922249274 1.876011 2.0480436 2.1183904 4.1584736 6.8738327275 1.8723553 2.0434814 2.1084429 4.1491188 6.85556276 1.8687379 2.0389442 2.0985338 4.1398589 6.8374061277 1.8651585 2.0344319 2.0886629 4.1306931 6.8193704

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278 1.8616169 2.0299444 2.07883 4.1216208 6.801452279 1.8581131 2.0254814 2.0690348 4.1126416 6.7836502280 1.8546468 2.0210429 2.0592771 4.1037546 6.7659643281 1.8512178 2.0166286 2.0495568 4.0949594 6.7483935282 1.8478261 2.0122385 2.0398736 4.0862553 6.7309373283 1.8444714 2.0078724 2.0302273 4.0776418 6.7135947284 1.8411535 2.0035301 2.0206178 4.0691181 6.6963653285 1.8378723 1.9992116 2.0110448 4.0606839 6.6792481286 1.8346277 1.9949166 2.0015081 4.0523384 6.6622426287 1.8314194 1.990645 1.9920075 4.044081 6.6453481288 1.8282474 1.9863968 1.9825429 4.0359113 6.6285639289 1.8251114 1.9821716 1.973114 4.0278286 6.6118892290 1.8220113 1.9779695 1.9637207 4.0198324 6.5953235291 1.8189469 1.9737903 1.9543627 4.011922 6.5788661292 1.8159181 1.9696338 1.9450398 4.0040971 6.5625163293 1.8129247 1.9654999 1.9357519 3.9963569 6.5462734294 1.8099665 1.9613884 1.9264988 3.9887009 6.5301368295 1.8070435 1.9572993 1.9172803 3.9811287 6.5141058296 1.8041554 1.9532324 1.9080962 3.9736396 6.4981798297 1.8013021 1.9491876 1.8989463 3.9662331 6.4823583298 1.7984835 1.9451648 1.8898304 3.9589088 6.4666404299 1.7956993 1.9411637 1.8807484 3.951666 6.4510256300 1.7929495 1.9371843 1.8717001 3.9445042 6.4355133301 1.7902339 1.9332265 1.8626853 3.9374229 6.4201029302 1.7875523 1.9292902 1.8537037 3.9304217 6.4047937303 1.7849047 1.9253751 1.8447554 3.9234999 6.3895852304 1.7822908 1.9214813 1.8358399 3.9166571 6.3744767305 1.7797105 1.9176085 1.8269573 3.9098928 6.3594676306 1.7771637 1.9137566 1.8181073 3.9032064 6.3445573307 1.7746502 1.9099256 1.8092898 3.8965975 6.3297453308 1.7721698 1.9061152 1.8005045 3.8900656 6.315031309 1.7697226 1.9023255 1.7917513 3.8836102 6.3004137310 1.7673082 1.8985562 1.78303 3.8772308 6.2858929311 1.7649265 1.8948072 1.7743405 3.8709269 6.271468312 1.7625775 1.8910785 1.7656827 3.8646981 6.2571384313 1.760261 1.8873699 1.7570562 3.8585438 6.2429037314 1.7579768 1.8836813 1.7484611 3.8524636 6.2287631315 1.7557248 1.8800125 1.739897 3.8464571 6.2147162316 1.7535049 1.8763636 1.7313639 3.8405237 6.2007624317 1.7513169 1.8727343 1.7228616 3.834663 6.1869012318 1.7491607 1.8691245 1.7143899 3.8288746 6.173132319 1.7470362 1.8655342 1.7059486 3.8231579 6.1594542320 1.7449433 1.8619632 1.6975377 3.8175126 6.1458674321 1.7428817 1.8584113 1.689157 3.8119382 6.1323709322 1.7408514 1.8548786 1.6808062 3.8064342 6.1189643323 1.7388522 1.8513649 1.6724853 3.8010002 6.1056471324 1.7368841 1.8478701 1.6641941 3.7956358 6.0924186325 1.7349468 1.8443941 1.6559325 3.7903405 6.0792785326 1.7330403 1.8409367 1.6477002 3.785114 6.0662261327 1.7311644 1.8374979 1.6394972 3.7799557 6.053261328 1.7293191 1.8340776 1.6313232 3.7748652 6.0403826

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329 1.7275041 1.8306756 1.6231782 3.7698422 6.0275905330 1.7257193 1.8272919 1.615062 3.7648861 6.0148841331 1.7239647 1.8239263 1.6069745 3.7599967 6.002263332 1.7222401 1.8205788 1.5989155 3.7551734 5.9897267333 1.7205454 1.8172493 1.5908848 3.7504159 5.9772746334 1.7188804 1.8139376 1.5828823 3.7457238 5.9649063335 1.7172451 1.8106436 1.574908 3.7410966 5.9526213336 1.7156393 1.8073673 1.5669615 3.7365339 5.9404191337 1.7140629 1.8041086 1.5590429 3.7320354 5.9282992338 1.7125157 1.8008673 1.5511519 3.7276007 5.9162613339 1.7109978 1.7976434 1.5432885 3.7232294 5.9043047340 1.7095089 1.7944368 1.5354524 3.718921 5.892429341 1.7080489 1.7912473 1.5276435 3.7146752 5.8806338342 1.7066177 1.7880749 1.5198618 3.7104916 5.8689186343 1.7052152 1.7849195 1.5121071 3.7063699 5.857283344 1.7038413 1.781781 1.5043792 3.7023095 5.8457264345 1.7024959 1.7786593 1.4966779 3.6983103 5.8342485346 1.7011788 1.7755543 1.4890033 3.6943718 5.8228488347 1.6998899 1.7724659 1.4813551 3.6904935 5.8115269348 1.6986292 1.769394 1.4737333 3.6866753 5.8002822349 1.6973965 1.7663386 1.4661376 3.6829166 5.7891145350 1.6961917 1.7632995 1.4585679 3.6792172 5.7780231

Palmer, Donald A.; Benezeth, Pascale; Wesolowski, David J.Boric acid hydrolysis: A new look at the available dataPowerPlant Chemistry 2000

t Q1,1 Q2,1 Q2,1 Q3,1 Q4,2C I=1 I=1 I=1

0 5.4437599 4.9024362 5.0604225 7.6092126 7.7669757 13.633028 14.206574 19.504161 5.4138644 4.8801701 5.0380828 7.5677355 7.7254255 13.550733 14.125033 19.3891352 5.3841678 4.8580713 5.0159055 7.5265653 7.6841774 13.469028 14.044084 19.2749223 5.3546761 4.8361379 4.9938888 7.4856988 7.643228 13.387908 13.963722 19.1615134 5.3253822 4.8143683 4.972031 7.4451325 7.6025741 13.307365 13.883939 19.0488995 5.2962963 4.7927605 4.9503304 7.4048633 7.5622125 13.227393 13.804731 18.9370736 5.2674072 4.7713129 4.9287852 7.364888 7.5221401 13.147987 13.726089 18.8260247 5.2387249 4.7500236 4.9073939 7.3252033 7.4823537 13.06914 13.648009 18.7157468 5.2102427 4.7288911 4.8861547 7.2858061 7.4428504 12.990846 13.570485 18.606239 5.1819663 4.7079136 4.8650661 7.2466935 7.4036271 12.9131 13.49351 18.497468

10 5.1538848 4.6870894 4.8441264 7.2078622 7.3646809 12.835896 13.417079 18.38945111 5.1260083 4.6664169 4.8233342 7.1693095 7.3260088 12.759228 13.341185 18.28217412 5.0983342 4.6458946 4.8026877 7.1310322 7.2876079 12.68309 13.265824 18.17562713 5.0708559 4.6255207 4.7821856 7.0930275 7.2494754 12.607478 13.19099 18.06980214 5.0435751 4.6052937 4.7618262 7.0552926 7.2116086 12.532385 13.116677 17.96469415 5.0164935 4.5852122 4.7416082 7.0178246 7.1740045 12.457805 13.04288 17.86029316 4.9896087 4.5652745 4.72153 6.9806207 7.1366606 12.383735 12.969593 17.75659417 4.9629225 4.5454792 4.7015902 6.9436782 7.099574 12.310168 12.896811 17.65358818 4.9364243 4.5258247 4.6817874 6.9069943 7.0627422 12.2371 12.82453 17.55126919 4.9101241 4.5063097 4.6621201 6.8705664 7.0261626 12.164525 12.752743 17.44962920 4.8840156 4.4869326 4.6425871 6.8343919 6.9898325 12.092438 12.681446 17.34866221 4.8580964 4.4676921 4.6231868 6.7984681 6.9537494 12.020834 12.610633 17.248362

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22 4.8323684 4.4485867 4.603918 6.7627926 6.9179109 11.949709 12.540301 17.1487223 4.8068295 4.429615 4.5847793 6.7273626 6.8823144 11.879057 12.470443 17.04973224 4.7814773 4.4107758 4.5657695 6.6921759 6.8469574 11.808875 12.401056 16.95138925 4.7563099 4.3920676 4.5468871 6.6572298 6.8118377 11.739156 12.332134 16.85368626 4.731329 4.373489 4.528131 6.622522 6.7769527 11.669897 12.263673 16.75661727 4.7065287 4.3550389 4.5094999 6.5880501 6.7423002 11.601093 12.195668 16.66017428 4.6819148 4.3367159 4.4909925 6.5538117 6.7078778 11.532739 12.128115 16.56435329 4.6574772 4.3185188 4.4726076 6.5198045 6.6736833 11.464831 12.061009 16.46914630 4.633222 4.3004462 4.4543441 6.4860261 6.6397143 11.397365 11.994345 16.37454831 4.6091432 4.2824969 4.4362006 6.4524744 6.6059688 11.330336 11.92812 16.28055332 4.5852388 4.2646697 4.418176 6.419147 6.5724444 11.26374 11.862329 16.18715533 4.5615149 4.2469634 4.4002691 6.3860417 6.539139 11.197572 11.796968 16.09434934 4.5379615 4.2293768 4.3824789 6.3531564 6.5060505 11.13183 11.732033 16.00212835 4.5145807 4.2119087 4.3648042 6.3204889 6.4731767 11.066508 11.667518 15.91048636 4.4913707 4.1945579 4.3472437 6.2880371 6.4405156 11.001602 11.603422 15.81941937 4.4683336 4.1773234 4.3297966 6.2557989 6.4080651 10.937108 11.539738 15.72892138 4.4454596 4.1602039 4.3124615 6.2237722 6.3758232 10.873023 11.476464 15.63898639 4.4227588 4.1431983 4.2952375 6.1919549 6.3437879 10.809343 11.413595 15.54960940 4.4002176 4.1263056 4.2781236 6.160345 6.3119572 10.746063 11.351128 15.46078541 4.377846 4.1095246 4.2611186 6.1289406 6.2803291 10.68318 11.289059 15.37250842 4.3556345 4.0928544 4.2442215 6.0977397 6.2489018 10.62069 11.227383 15.28477443 4.3335853 4.0762937 4.2274313 6.0667403 6.2176733 10.55859 11.166098 15.19757744 4.3116966 4.0598415 4.210747 6.0359405 6.1866417 10.496875 11.105199 15.11091345 4.2899668 4.0434969 4.1941675 6.0053385 6.1558051 10.435543 11.044683 15.02477546 4.2683982 4.0272588 4.177692 5.9749322 6.1251618 10.374589 10.984546 14.9391647 4.2469814 4.0111262 4.1613194 5.94472 6.09471 10.31401 10.924785 14.85406348 4.2257224 3.9950981 4.1450487 5.9147 6.0644478 10.253802 10.865396 14.76947849 4.2046198 3.9791734 4.1288791 5.8848703 6.0343734 10.193963 10.806375 14.68540150 4.1836681 3.9633513 4.1128095 5.8552292 6.0044852 10.134488 10.74772 14.60182851 4.1628657 3.9476308 4.0968391 5.8257749 5.9747814 10.075375 10.689427 14.51875352 4.1422151 3.9320109 4.0809669 5.7965057 5.9452603 10.01662 10.631493 14.43617353 4.1217108 3.9164906 4.0651921 5.7674199 5.9159203 9.9582192 10.573913 14.35408254 4.101359 3.9010692 4.0495137 5.7385158 5.8867596 9.9001701 10.516686 14.27247755 4.0811507 3.8857455 4.0339308 5.7097917 5.8577766 9.8424693 10.459807 14.19135256 4.0610882 3.8705188 4.0184427 5.681246 5.8289698 9.7851137 10.403274 14.11070457 4.04117 3.8553882 4.0030483 5.652877 5.8003374 9.7281001 10.347084 14.03052958 4.0213948 3.8403527 3.9877469 5.6246831 5.771878 9.6714254 10.291233 13.95082159 4.0017612 3.8254115 3.9725377 5.5966628 5.7435899 9.6150867 10.235718 13.87157760 3.9822678 3.8105637 3.9574198 5.5688144 5.7154717 9.5590808 10.180537 13.79279361 3.9629132 3.7958085 3.9423923 5.5411364 5.6875218 9.5034049 10.125685 13.71446562 3.9436962 3.7811451 3.9274546 5.5136272 5.6597386 9.4480559 10.071162 13.63658863 3.9246191 3.7665725 3.9126057 5.4862854 5.6321208 9.3930311 10.016962 13.55915964 3.9056733 3.7520901 3.8978449 5.4591094 5.6046668 9.3383274 9.9630841 13.48217465 3.8868685 3.7376969 3.8831714 5.4320978 5.5773751 9.2839421 9.9095248 13.40562966 3.8681923 3.7233923 3.8685844 5.4052491 5.5502444 9.2298724 9.8562813 13.32951967 3.849651 3.7091753 3.8540832 5.3785618 5.5232733 9.1761155 9.8033509 13.25384268 3.8312433 3.6950452 3.839667 5.3520346 5.4964602 9.1226686 9.7507308 13.17859369 3.8129642 3.6810013 3.8253351 5.3256659 5.4698039 9.0695292 9.6984182 13.10376970 3.7948126 3.6670427 3.8110867 5.2994545 5.4433029 9.0166944 9.6464106 13.02936571 3.776791 3.6531688 3.7969211 5.2733989 5.416956 8.9641617 9.5947052 12.9553872 3.7588982 3.6393787 3.7828376 5.2474977 5.3907617 8.9119284 9.5432994 12.881808

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73 3.741133 3.6256718 3.7688355 5.2217497 5.3647188 8.859992 9.4921907 12.80864674 3.7234907 3.6120473 3.754914 5.1961534 5.3388259 8.8083499 9.4413764 12.73589175 3.7059737 3.5985044 3.7410725 5.1707076 5.3130817 8.7569995 9.3908539 12.6635476 3.6885809 3.5850426 3.7273103 5.145411 5.287485 8.7059385 9.3406209 12.59158877 3.6713077 3.571661 3.7136267 5.1202622 5.2620346 8.6551643 9.2906749 12.52003378 3.6541565 3.558359 3.7000211 5.0952601 5.236729 8.6046745 9.2410132 12.44887179 3.6371299 3.5451359 3.6864927 5.0704032 5.2115672 8.5544667 9.1916337 12.37809980 3.6202196 3.531991 3.6730409 5.0456905 5.1865479 8.5045385 9.1425338 12.30771481 3.6034282 3.5189236 3.6596651 5.0211206 5.1616699 8.4548876 9.0937111 12.23771182 3.5867546 3.5059331 3.6463646 4.9966924 5.136932 8.4055115 9.0451635 12.16808983 3.5701978 3.4930188 3.6331388 4.9724047 5.112333 8.3564081 8.9968884 12.09884484 3.5537605 3.4801801 3.6199871 4.9482562 5.0878718 8.307575 8.9488837 12.02997385 3.5374343 3.4674164 3.6069088 4.9242457 5.0635471 8.25901 8.901147 11.96147386 3.5212221 3.4547269 3.5939034 4.9003722 5.0393579 8.2107109 8.8536762 11.8933487 3.5051262 3.442111 3.5809702 4.8766345 5.0153031 8.1626754 8.806469 11.82557288 3.4891387 3.4295683 3.5681085 4.8530314 4.9913814 8.1149014 8.7595232 11.75816689 3.4732658 3.4170979 3.555318 4.8295618 4.9675919 8.0673868 8.7128367 11.69111890 3.4575029 3.4046994 3.5425978 4.8062246 4.9439334 8.0201293 8.6664073 11.62442791 3.4418491 3.3923721 3.5299475 4.7830187 4.9204048 7.9731269 8.6202329 11.55808892 3.426307 3.3801154 3.5173666 4.759943 4.8970051 7.9263776 8.5743114 11.49209993 3.4108688 3.3679287 3.5048543 4.7369965 4.8737332 7.8798792 8.5286407 11.42645894 3.3955405 3.3558116 3.4924102 4.714178 4.850588 7.8336297 8.4832188 11.36116195 3.3803212 3.3437633 3.4800337 4.6914866 4.8275687 7.787627 8.4380437 11.29620596 3.3652032 3.3317833 3.4677242 4.6689211 4.804674 7.7418693 8.3931134 11.23158897 3.3501925 3.3198711 3.4554813 4.6464806 4.781903 7.6963545 8.3484258 11.16730898 3.3352883 3.3080261 3.4433043 4.624164 4.7592547 7.6510807 8.303979 11.10336199 3.3204862 3.2962477 3.4311928 4.6019704 4.7367282 7.606046 8.2597711 11.039745

100 3.3057856 3.2845354 3.4191462 4.5798987 4.7143224 7.5612483 8.2158001 10.976458101 3.2911889 3.2728887 3.407164 4.5579479 4.6920363 7.5166859 8.1720641 10.913495102 3.276692 3.2613071 3.3952456 4.5361171 4.6698691 7.4723569 8.1285614 10.850856103 3.2622941 3.2497899 3.3833907 4.5144053 4.6478198 7.4282594 8.0852899 10.788538104 3.2479978 3.2383367 3.3715986 4.4928115 4.6258873 7.3843916 8.0422479 10.726537105 3.2338023 3.2269471 3.3598688 4.4713348 4.6040709 7.3407516 7.9994336 10.664852106 3.2197035 3.2156203 3.348201 4.4499744 4.5823695 7.2973378 7.956845 10.60348107 3.2057007 3.2043561 3.3365945 4.4287291 4.5607823 7.2541482 7.9144806 10.542419108 3.1917998 3.1931538 3.3250489 4.4075982 4.5393084 7.2111813 7.8723384 10.481666109 3.17799 3.1820129 3.3135638 4.3865808 4.5179469 7.1684351 7.8304169 10.421218110 3.1642774 3.170933 3.3021386 4.3656758 4.4966969 7.1259081 7.7887141 10.361075111 3.1506611 3.1599137 3.2907729 4.3448825 4.4755575 7.0835984 7.7472284 10.301232112 3.1371405 3.1489543 3.2794662 4.3242 4.4545278 7.0415045 7.7059582 10.241688113 3.1237116 3.1380545 3.268218 4.3036274 4.4336071 6.9996246 7.6649017 10.18244114 3.1103736 3.1272138 3.257028 4.2831638 4.4127945 6.9579572 7.6240573 10.123487115 3.0971326 3.1164316 3.2458957 4.2628084 4.3920891 6.9165005 7.5834234 10.064826116 3.0839812 3.1057076 3.2348205 4.2425604 4.3714902 6.875253 7.5429983 10.006455117 3.0709187 3.0950414 3.2238021 4.2224189 4.3509968 6.834213 7.5027805 9.9483707118 3.0579479 3.0844323 3.2128401 4.202383 4.3306082 6.793379 7.4627682 9.8905723119 3.0450681 3.0738801 3.201934 4.1824521 4.3103236 6.7527495 7.4229601 9.8330571120 3.0322787 3.0633842 3.1910833 4.1626252 4.2901422 6.7123228 7.3833544 9.775823121 3.0195756 3.0529443 3.1802877 4.1429016 4.2700632 6.6720974 7.3439498 9.7188679122 3.0069617 3.0425598 3.1695468 4.1232805 4.2500858 6.6320718 7.3047445 9.6621898123 2.9944362 3.0322304 3.15886 4.1037611 4.2302093 6.5922446 7.2657372 9.6057864

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124 2.9819953 3.0219557 3.1482271 4.0843426 4.2104328 6.5526141 7.2269264 9.5496559125 2.9696417 3.0117352 3.1376476 4.0650243 4.1907557 6.513179 7.1883104 9.4937962126 2.9573748 3.0015685 3.1271211 4.0458053 4.1711773 6.4739378 7.149888 9.4382052127 2.945194 2.9914552 3.1166473 4.026685 4.1516966 6.4348891 7.1116576 9.382881128 2.9330955 2.9813949 3.1062256 4.0076627 4.1323131 6.3960313 7.0736178 9.3278217129 2.9210819 2.9713871 3.0958558 3.9887374 4.113026 6.3573632 7.0357673 9.2730252130 2.9091527 2.9614316 3.0855374 3.9699087 4.0938346 6.3188832 6.9981044 9.2184896131 2.8973042 2.9515279 3.0752701 3.9511756 4.0747381 6.2805901 6.960628 9.164213132 2.8855389 2.9416756 3.0650534 3.9325375 4.0557359 6.2424823 6.9233365 9.1101936133 2.8738565 2.9318744 3.0548871 3.9139937 4.0368273 6.2045587 6.8862287 9.0564295134 2.8622562 2.9221237 3.0447707 3.8955436 4.0180115 6.1668178 6.8493032 9.0029187135 2.8507345 2.9124234 3.0347039 3.8771863 3.999288 6.1292582 6.8125586 8.9496595136 2.8392971 2.9027729 3.0246863 3.8589212 3.980656 6.0918788 6.7759936 8.8966501137 2.8279372 2.893172 3.0147175 3.8407476 3.9621148 6.0546781 6.739607 8.8438886138 2.8166543 2.8836202 3.0047973 3.8226649 3.9436639 6.0176548 6.7033973 8.7913733139 2.8054543 2.8741172 2.9949251 3.8046724 3.9253024 5.9808078 6.6673633 8.7391024140 2.7943303 2.8646626 2.9851008 3.7867694 3.9070299 5.9441356 6.6315038 8.6870742141 2.783285 2.8552561 2.9753239 3.7689553 3.8888456 5.9076371 6.5958175 8.6352868142 2.7723179 2.8458974 2.9655941 3.7512294 3.8707489 5.871311 6.560303 8.5837387143 2.7614255 2.836586 2.9559111 3.7335911 3.8527392 5.8351561 6.5249593 8.5324281144 2.7506103 2.8273216 2.9462745 3.7160398 3.8348158 5.7991711 6.489785 8.4813533145 2.739872 2.8181039 2.936684 3.6985748 3.8169781 5.7633549 6.4547789 8.4305126146 2.72921 2.8089326 2.9271392 3.6811954 3.7992256 5.7277062 6.4199399 8.3799044147 2.718621 2.7998072 2.9176399 3.6639011 3.7815575 5.6922238 6.3852667 8.3295271148 2.7081074 2.7907275 2.9081857 3.6466913 3.7639734 5.6569066 6.3507582 8.2793791149 2.6976688 2.7816932 2.8987763 3.6295654 3.7464726 5.6217534 6.3164131 8.2294587150 2.6873049 2.7727039 2.8894113 3.6125227 3.7290545 5.5867631 6.2822304 8.1797643151 2.6770121 2.7637592 2.8800905 3.5955627 3.7117185 5.5519345 6.2482089 8.1302944152 2.6667931 2.754859 2.8708136 3.5786847 3.6944641 5.5172664 6.2143474 8.0810475153 2.6566475 2.7460028 2.8615802 3.5618883 3.6772906 5.4827578 6.1806448 8.0320218154 2.6465719 2.7371903 2.85239 3.5451728 3.6601976 5.4484075 6.1471001 7.9832161155 2.6365689 2.7284213 2.8432428 3.5285376 3.6431844 5.4142145 6.113712 7.9346286156 2.626638 2.7196953 2.8341382 3.5119822 3.6262505 5.3801776 6.0804796 7.886258157 2.616779 2.7110122 2.8250759 3.495506 3.6093953 5.3462958 6.0474016 7.8381026158 2.6069883 2.7023716 2.8160557 3.4791084 3.5926183 5.312568 6.0144771 7.7901611159 2.5972687 2.6937732 2.8070772 3.462789 3.575919 5.2789931 5.981705 7.742432160 2.5876169 2.6852167 2.7981401 3.4465471 3.5592968 5.2455701 5.9490842 7.6949139161 2.5780353 2.6767018 2.7892443 3.4303822 3.5427511 5.2122979 5.9166136 7.6476052162 2.5685237 2.6682283 2.7803893 3.4142939 3.5262815 5.1791755 5.8842923 7.6005046163 2.5590787 2.6597957 2.7715749 3.3982814 3.5098874 5.1462019 5.8521192 7.5536107164 2.549703 2.651404 2.7628009 3.3823445 3.4935683 5.113376 5.8200933 7.5069221165 2.5403962 2.6430527 2.7540669 3.3664824 3.4773237 5.080697 5.7882136 7.4604373166 2.5311551 2.6347415 2.7453727 3.3506947 3.4611531 5.0481637 5.7564791 7.414155167 2.5219793 2.6264703 2.7367179 3.3349808 3.445056 5.0157751 5.7248888 7.3680739168 2.5128714 2.6182387 2.7281025 3.3193404 3.4290318 4.9835304 5.6934417 7.3221927169 2.503831 2.6100465 2.719526 3.3037728 3.4130802 4.9514285 5.6621368 7.2765098170 2.4948551 2.6018933 2.7109882 3.2882776 3.3972005 4.9194685 5.6309733 7.2310242171 2.4859461 2.593779 2.7024888 3.2728542 3.3813923 4.8876494 5.59995 7.1857343172 2.4771037 2.5857032 2.6940276 3.2575023 3.3656552 4.8559702 5.5690662 7.140639173 2.4683221 2.5776657 2.6856044 3.2422212 3.3499886 4.8244301 5.5383207 7.095737174 2.4596092 2.5696662 2.6772188 3.2270106 3.334392 4.7930282 5.5077128 7.0510269

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175 2.4509565 2.5617044 2.6688707 3.2118699 3.3188651 4.7617634 5.4772415 7.0065076176 2.4423692 2.5537802 2.6605597 3.1967987 3.3034073 4.7306349 5.4469059 6.9621776177 2.4338471 2.5458933 2.6522857 3.1817965 3.2880182 4.6996418 5.4167051 6.9180359178 2.4253872 2.5380433 2.6440483 3.1668628 3.2726973 4.6687832 5.3866381 6.8740812179 2.416989 2.5302301 2.6358474 3.1519972 3.2574442 4.6380582 5.3567042 6.8303123180 2.4086552 2.5224533 2.6276827 3.1371992 3.2422584 4.607466 5.3269024 6.7867278181 2.4003827 2.5147129 2.6195539 3.1224685 3.2271395 4.5770056 5.2972318 6.7433268182 2.3921713 2.5070084 2.6114608 3.1078044 3.212087 4.5466762 5.2676915 6.7001079183 2.3840234 2.4993397 2.6034033 3.0932066 3.1971005 4.5164769 5.2382808 6.6570699184 2.3759362 2.4917066 2.5953809 3.0786747 3.1821796 4.4864069 5.2089988 6.6142118185 2.3679093 2.4841087 2.5873936 3.0642082 3.1673238 4.4564654 5.1798446 6.5715323186 2.3599424 2.4765459 2.5794411 3.0498067 3.1525327 4.4266515 5.1508174 6.5290303187 2.3520382 2.469018 2.5715232 3.0354697 3.1378059 4.3969644 5.1219163 6.4867047188 2.3441937 2.4615246 2.5636396 3.0211968 3.123143 4.3674033 5.0931406 6.4445543189 2.3364085 2.4540656 2.5557901 3.0069877 3.1085435 4.3379673 5.0644895 6.4025781190 2.3286826 2.4466407 2.5479745 2.9928418 3.0940071 4.3086557 5.035962 6.3607748191 2.3210158 2.4392498 2.5401926 2.9787589 3.0795333 4.2794676 5.0075575 6.3191434192 2.3134104 2.4318926 2.5324442 2.9647384 3.0651218 4.2504024 4.9792751 6.2776829193 2.3058609 2.4245688 2.5247289 2.9507799 3.0507721 4.2214591 4.951114 6.236392194 2.2983725 2.4172783 2.5170468 2.9368831 3.0364838 4.192637 4.9230735 6.1952699195 2.2909397 2.4100208 2.5093974 2.9230476 3.0222565 4.1639353 4.8951528 6.1543153196 2.2835675 2.4027961 2.5017807 2.9092729 3.0080899 4.1353533 4.8673512 6.1135273197 2.2762505 2.395604 2.4941963 2.8955587 2.9939836 4.1068903 4.8396678 6.0729047198 2.2689939 2.3884444 2.4866442 2.8819046 2.9799372 4.0785454 4.8121019 6.0324467199 2.261792 2.3813169 2.479124 2.8683102 2.9659502 4.0503179 4.7846528 5.992152200 2.2546476 2.3742214 2.4716356 2.8547751 2.9520224 4.0222071 4.7573197 5.9520198201 2.2475602 2.3671577 2.4641788 2.8412989 2.9381533 3.9942122 4.7301019 5.9120489202 2.2405299 2.3601255 2.4567534 2.8278813 2.9243426 3.9663326 4.7029986 5.8722385203 2.2335563 2.3531247 2.4493592 2.8145219 2.9105899 3.9385675 4.6760092 5.8325874204 2.2266369 2.3461551 2.441996 2.8012203 2.8968949 3.9109161 4.649133 5.7930948205 2.219774 2.3392164 2.4346636 2.7879761 2.8832571 3.8833778 4.6223691 5.7537596206 2.2129674 2.3323085 2.4273618 2.774789 2.8696763 3.8559519 4.595717 5.7145809207 2.2062146 2.3254312 2.4200904 2.7616587 2.856152 3.8286377 4.5691759 5.6755577208 2.1995178 2.3185842 2.4128492 2.7485847 2.842684 3.8014344 4.5427451 5.636689209 2.192877 2.3117675 2.4056381 2.7355667 2.8292718 3.7743415 4.5164239 5.597974210 2.1862895 2.3049807 2.3984568 2.7226044 2.8159151 3.7473582 4.4902117 5.5594116211 2.1797577 2.2982237 2.3913052 2.7096974 2.8026137 3.7204838 4.4641078 5.521001212 2.173279 2.2914964 2.384183 2.6968454 2.789367 3.6937177 4.4381115 5.4827412213 2.1668558 2.2847984 2.3770902 2.684048 2.7761748 3.6670592 4.4122222 5.4446312214 2.1604854 2.2781297 2.3700265 2.6713049 2.7630368 3.6405077 4.3864391 5.4066703215 2.1541678 2.2714901 2.3629917 2.6586157 2.7499527 3.6140625 4.3607617 5.3688575216 2.1479028 2.2648794 2.3559857 2.6459802 2.736922 3.5877229 4.3351892 5.3311919217 2.1416929 2.2582973 2.3490083 2.6333979 2.7239445 3.5614884 4.3097211 5.2936725218 2.1355355 2.2517438 2.3420592 2.6208686 2.7110199 3.5353582 4.2843567 5.2562987219 2.129433 2.2452186 2.3351385 2.6083919 2.6981477 3.5093318 4.2590954 5.2190694220 2.1233803 2.2387216 2.3282458 2.5959675 2.6853278 3.4834085 4.2339365 5.1819837221 2.1173823 2.2322526 2.321381 2.5835951 2.6725597 3.4575877 4.2088795 5.145041222 2.1114341 2.2258113 2.3145439 2.5712744 2.6598433 3.4318688 4.1839237 5.1082402223 2.1055404 2.2193978 2.3077344 2.559005 2.6471781 3.4062512 4.1590684 5.0715806224 2.0996963 2.2130117 2.3009522 2.5467867 2.6345638 3.3807343 4.1343132 5.0350612225 2.0939066 2.2066529 2.2941973 2.534619 2.6220002 3.3553174 4.1096573 4.9986814

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226 2.0881665 2.2003213 2.2874695 2.5225018 2.6094869 3.33 4.0851003 4.9624402227 2.0824783 2.1940166 2.2807686 2.5104347 2.5970237 3.3047814 4.0606414 4.9263369228 2.0768419 2.1877388 2.2740944 2.4984174 2.5846102 3.2796612 4.0362802 4.8903706229 2.0712549 2.1814876 2.2674468 2.4864496 2.5722461 3.2546386 4.0120159 4.8545405230 2.0657197 2.1752629 2.2608256 2.474531 2.5599312 3.2297132 3.9878482 4.8188458231 2.0602363 2.1690645 2.2542307 2.4626614 2.5476652 3.2048844 3.9637763 4.7832858232 2.0548022 2.1628922 2.2476619 2.4508403 2.5354477 3.1801515 3.9397997 4.7478596233 2.0494197 2.156746 2.241119 2.4390676 2.5232785 3.155514 3.9159178 4.7125664234 2.0440866 2.1506256 2.234602 2.4273429 2.5111573 3.1309715 3.8921301 4.6774056235 2.0388052 2.1445309 2.2281106 2.4156659 2.4990837 3.1065232 3.8684361 4.6423763236 2.033573 2.1384618 2.2216447 2.4040365 2.4870576 3.0821687 3.8448351 4.6074778237 2.0283902 2.132418 2.2152042 2.3924542 2.4750787 3.0579074 3.8213267 4.5727092238 2.0232567 2.1263995 2.2087888 2.3809188 2.4631466 3.0337388 3.7979102 4.53807239 2.0181726 2.1204061 2.2023985 2.36943 2.4512612 3.0096622 3.7745852 4.5035592240 2.0131378 2.1144376 2.1960331 2.3579876 2.439422 2.9856773 3.7513511 4.4691762241 2.0081546 2.1084938 2.1896925 2.3465913 2.4276289 2.9617835 3.7282073 4.4349203242 2.0032186 2.1025747 2.1833765 2.3352408 2.4158816 2.9379802 3.7051535 4.4007907243 1.9983319 2.0966801 2.177085 2.3239358 2.4041798 2.9142669 3.6821889 4.3667867244 1.9934948 2.0908099 2.1708178 2.3126761 2.3925233 2.8906431 3.6593132 4.3329075245 1.9887049 2.0849638 2.1645747 2.3014613 2.3809117 2.8671083 3.6365257 4.2991526246 1.9839668 2.0791418 2.1583558 2.2902914 2.3693449 2.843662 3.6138261 4.2655211247 1.9792738 2.0733437 2.1521607 2.2791659 2.3578226 2.8203036 3.5912137 4.2320123248 1.9746304 2.0675694 2.1459894 2.2680846 2.3463444 2.7970327 3.5686881 4.1986257249 1.9700368 2.0618188 2.1398418 2.2570473 2.3349103 2.7738488 3.5462488 4.1653604250 1.9654907 2.0560916 2.1337177 2.2460537 2.3235198 2.7507514 3.5238952 4.1322158251 1.9609922 2.0503878 2.1276169 2.2351035 2.3121729 2.7277399 3.501627 4.0991913252 1.9565414 2.0447072 2.1215394 2.2241966 2.3008691 2.7048139 3.4794436 4.0662861253 1.9521385 2.0390497 2.1154849 2.2133326 2.2896083 2.681973 3.4573445 4.0334995254 1.9477855 2.0334151 2.1094535 2.2025113 2.2783902 2.6592166 3.4353292 4.000831255 1.9434784 2.0278034 2.1034449 2.1917325 2.2672146 2.6365442 3.4133973 3.9682799256 1.9392194 2.0222144 2.0974589 2.1809959 2.2560813 2.6139554 3.3915483 3.9358454257 1.9350065 2.0166479 2.0914956 2.1703013 2.2449899 2.5914498 3.3697818 3.903527258 1.9308418 2.0111039 2.0855547 2.1596484 2.2339403 2.5690268 3.3480971 3.871324259 1.9267256 2.0055821 2.0796362 2.149037 2.2229323 2.5466859 3.326494 3.8392358260 1.9226557 2.0000826 2.0737398 2.1384669 2.2119655 2.5244268 3.304972 3.8072618261 1.9186345 1.994605 2.0678656 2.1279378 2.2010398 2.502249 3.2835305 3.7754012262 1.914658 1.9891494 2.0620133 2.1174495 2.1901549 2.480152 3.2621691 3.7436535263 1.9107303 1.9837156 2.0561828 2.1070018 2.1793106 2.4581354 3.2408874 3.7120181264 1.9068497 1.9783034 2.050374 2.0965944 2.1685067 2.4361987 3.219685 3.6804944265 1.9030141 1.9729128 2.0445868 2.0862271 2.157743 2.4143415 3.1985614 3.6490817266 1.8992279 1.9675436 2.0388211 2.0758997 2.1470192 2.3925633 3.1775161 3.6177794267 1.8954851 1.9621957 2.0330767 2.065612 2.1363351 2.3708638 3.1565487 3.5865869268 1.891792 1.956869 2.0273536 2.0553637 2.1256905 2.3492424 3.1356589 3.5555037269 1.8881447 1.9515634 2.0216516 2.0451546 2.1150851 2.3276988 3.1148461 3.5245291270 1.8845434 1.9462787 2.0159705 2.0349845 2.1045188 2.3062325 3.0941099 3.4936626271 1.8809883 1.9410148 2.0103104 2.0248532 2.0939914 2.2848431 3.07345 3.4629035272 1.8774796 1.9357716 2.004671 2.0147604 2.0835025 2.2635302 3.0528658 3.4322513273 1.8740195 1.930549 1.9990523 2.004706 2.0730521 2.2422934 3.032357 3.4017055274 1.8706043 1.9253469 1.9934541 1.9946897 2.0626399 2.2211322 3.0119232 3.3712653275 1.8672343 1.9201651 1.9878763 1.9847114 2.0522656 2.2000463 2.991564 3.3409304276 1.8639115 1.9150036 1.9823189 1.9747708 2.0419292 2.1790352 2.9712789 3.3107

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277 1.8606343 1.9098622 1.9767816 1.9648676 2.0316303 2.1580985 2.9510675 3.2805737278 1.8574049 1.9047409 1.9712644 1.9550018 2.0213688 2.1372359 2.9309295 3.2505509279 1.8542197 1.8996394 1.9657673 1.9451731 2.0111444 2.1164469 2.9108644 3.220631280 1.851081 1.8945577 1.96029 1.9353812 2.0009571 2.0957311 2.8908719 3.1908135281 1.8479888 1.8894958 1.9548324 1.9256261 1.9908065 2.0750882 2.8709515 3.1610979282 1.8449436 1.8844534 1.9493946 1.9159074 1.9806924 2.0545177 2.8511029 3.1314835283 1.8419419 1.8794305 1.9439763 1.906225 1.9706148 2.0340193 2.8313257 3.1019699284 1.8389878 1.8744269 1.9385774 1.8965788 1.9605733 2.0135926 2.8116195 3.0725566285 1.8360796 1.8694426 1.9331979 1.8869684 1.9505678 1.9932372 2.7919839 3.043243286 1.8332177 1.8644775 1.9278376 1.8773937 1.9405981 1.9729527 2.7724185 3.0140286287 1.8304006 1.8595314 1.9224965 1.8678545 1.9306639 1.9527387 2.752923 2.9849128288 1.8276287 1.8546042 1.9171744 1.8583506 1.9207652 1.932595 2.7334969 2.9558952289 1.8249041 1.8496959 1.9118712 1.8488819 1.9109017 1.912521 2.71414 2.9269752290 1.8222254 1.8448064 1.9065869 1.8394481 1.9010732 1.8925164 2.6948518 2.8981523291 1.8195911 1.8399354 1.9013213 1.830049 1.8912796 1.8725809 2.675632 2.869426292 1.8170034 1.835083 1.8960743 1.8206845 1.8815207 1.8527141 2.6564802 2.8407959293 1.8144628 1.8302491 1.8908459 1.8113543 1.8717962 1.8329156 2.6373961 2.8122614294 1.8119661 1.8254334 1.8856359 1.8020584 1.862106 1.8131852 2.6183793 2.7838219295 1.8095172 1.820636 1.8804442 1.7927965 1.8524499 1.7935223 2.5994294 2.7554772296 1.8071113 1.8158568 1.8752708 1.7835683 1.8428277 1.7739267 2.5805461 2.7272265297 1.8047541 1.8110955 1.8701156 1.7743739 1.8332393 1.7543981 2.561729 2.6990695298 1.8024409 1.8063523 1.8649784 1.7652129 1.8236845 1.734936 2.5429779 2.6710057299 1.8001738 1.8016268 1.8598591 1.7560851 1.8141631 1.7155402 2.5242922 2.6430345300 1.7979516 1.7969191 1.8547577 1.7469905 1.8046749 1.6962102 2.5056718 2.6151556

Byers, W. A.; Lindsay, W. T.; Kunig, R. H.Solubility of lithium monoborate in high-temperature water,Journal of Solution Chemistry 2000, 29 (6), 541-559

t Q1,1 Q2,1 Q3,1 Q4,2C

0 5.4411601 5.1968009 7.6355153 14.8149311 5.4112395 5.1695865 7.5936255 14.7108862 5.3815481 5.1426058 7.5520512 14.6078423 5.3520836 5.1158563 7.510789 14.5057874 5.3228438 5.0893353 7.4698354 14.4047095 5.2938266 5.0630402 7.4291871 14.3045996 5.2650299 5.0369685 7.3888407 14.2054437 5.2364515 5.0111178 7.3487931 14.1072318 5.2080894 4.9854854 7.3090409 14.0099539 5.1799416 4.960069 7.269581 13.913597

10 5.152006 4.9348662 7.2304104 13.81815211 5.1242807 4.9098746 7.1915258 13.72360912 5.0967636 4.8850919 7.1529243 13.62995813 5.0694529 4.8605157 7.1146029 13.53718714 5.0423466 4.8361439 7.0765586 13.44528715 5.0154428 4.8119742 7.0387885 13.35424816 4.9887398 4.7880043 7.0012898 13.264061

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17 4.9622356 4.7642321 6.9640595 13.17471618 4.9359285 4.7406555 6.927095 13.08620319 4.9098166 4.7172723 6.8903934 12.99851320 4.8838981 4.6940806 6.853952 12.91163821 4.8581715 4.6710781 6.8177682 12.82556722 4.8326348 4.6482629 6.7818394 12.74029223 4.8072864 4.625633 6.7461628 12.65580524 4.7821247 4.6031865 6.7107359 12.57209625 4.7571479 4.5809213 6.6755563 12.48915826 4.7323545 4.5588357 6.6406213 12.40698127 4.7077428 4.5369276 6.6059286 12.32555828 4.6833112 4.5151952 6.5714757 12.2448829 4.6590582 4.4936367 6.5372601 12.16493930 4.6349821 4.4722503 6.5032796 12.08572731 4.6110815 4.4510341 6.4695317 12.00723732 4.5873548 4.4299865 6.4360142 11.9294633 4.5638005 4.4091057 6.4027247 11.8523934 4.5404172 4.3883899 6.3696611 11.77601735 4.5172033 4.3678375 6.3368211 11.70033636 4.4941574 4.3474468 6.3042024 11.62533937 4.4712782 4.3272162 6.2718031 11.55101838 4.4485641 4.3071439 6.2396208 11.47736639 4.4260138 4.2872285 6.2076536 11.40437640 4.4036258 4.2674683 6.1758993 11.33204241 4.381399 4.2478618 6.1443558 11.26035742 4.3593318 4.2284074 6.1130212 11.18931343 4.337423 4.2091035 6.0818935 11.11890444 4.3156712 4.1899488 6.0509706 11.04912345 4.2940751 4.1709417 6.0202506 10.97996546 4.2726335 4.1520807 5.9897316 10.91142247 4.2513451 4.1333643 5.9594116 10.84348848 4.2302086 4.1147913 5.9292889 10.77615849 4.2092228 4.0963601 5.8993615 10.70942450 4.1883865 4.0780693 5.8696276 10.64328151 4.1676984 4.0599177 5.8400855 10.57772252 4.1471574 4.0419037 5.8107332 10.51274253 4.1267622 4.0240262 5.7815691 10.44833654 4.1065117 4.0062837 5.7525914 10.38449655 4.0864047 3.9886749 5.7237983 10.32121856 4.0664402 3.9711987 5.6951883 10.25849557 4.0466168 3.9538536 5.6667595 10.19632358 4.0269336 3.9366384 5.6385104 10.13469659 4.0073895 3.9195519 5.6104393 10.07360860 3.9879832 3.9025929 5.5825445 10.01305461 3.9687138 3.8857601 5.5548245 9.953028262 3.9495802 3.8690524 5.5272778 9.893526263 3.9305813 3.8524685 5.4999026 9.834542564 3.9117161 3.8360074 5.4726975 9.776071965 3.8929835 3.8196677 5.445661 9.718109666 3.8743825 3.8034485 5.4187916 9.660650567 3.8559121 3.7873485 5.3920877 9.6036896

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68 3.8375713 3.7713667 5.3655479 9.547222269 3.8193591 3.755502 5.3391707 9.491243570 3.8012745 3.7397532 5.3129547 9.435748771 3.7833166 3.7241193 5.2868985 9.380733172 3.7654843 3.7085993 5.2610007 9.326192273 3.7477768 3.693192 5.2352599 9.272121474 3.7301931 3.6778965 5.2096746 9.218516275 3.7127323 3.6627118 5.1842436 9.165372176 3.6953934 3.6476367 5.1589656 9.112684877 3.6781756 3.6326704 5.1338391 9.060449978 3.6610779 3.6178118 5.1088629 9.00866379 3.6440994 3.60306 5.0840356 8.957320180 3.6272394 3.5884139 5.0593561 8.906416881 3.6104968 3.5738727 5.034823 8.855949182 3.5938708 3.5594354 5.0104351 8.805912883 3.5773607 3.545101 4.9861912 8.756303984 3.5609654 3.5308687 4.9620899 8.707118485 3.5446843 3.5167375 4.9381302 8.658352486 3.5285164 3.5027066 4.9143108 8.610001987 3.512461 3.488775 4.8906305 8.562063288 3.4965172 3.4749418 4.8670882 8.514532389 3.4806843 3.4612063 4.8436827 8.467405690 3.4649614 3.4475675 4.8204129 8.420679391 3.4493477 3.4340245 4.7972776 8.374349792 3.4338425 3.4205766 4.7742757 8.328413293 3.4184451 3.4072229 4.7514061 8.282866194 3.4031545 3.3939626 4.7286677 8.23770595 3.3879702 3.3807949 4.7060595 8.192926496 3.3728913 3.367719 4.6835803 8.148526697 3.3579171 3.354734 4.6612291 8.104502498 3.3430468 3.3418392 4.6390049 8.060850399 3.3282798 3.3290339 4.6169066 8.0175669

100 3.3136153 3.3163172 4.5949331 7.974649101 3.2990527 3.3036884 4.5730836 7.9320933102 3.2845911 3.2911467 4.5513569 7.8898964103 3.2702299 3.2786915 4.5297522 7.8480553104 3.2559685 3.2663218 4.5082683 7.8065666105 3.2418061 3.2540372 4.4869043 7.7654274106 3.227742 3.2418367 4.4656593 7.7246345107 3.2137757 3.2297198 4.4445324 7.6841847108 3.1999063 3.2176856 4.4235225 7.6440752109 3.1861333 3.2057336 4.4026288 7.6043028110 3.1724561 3.193863 4.3818502 7.5648647111 3.1588738 3.1820731 4.361186 7.5257578112 3.1453861 3.1703633 4.3406353 7.4869794113 3.1319921 3.1587328 4.320197 7.4485264114 3.1186912 3.1471811 4.2998704 7.4103961115 3.1054829 3.1357075 4.2796545 7.3725856116 3.0923666 3.1243114 4.2595485 7.3350923117 3.0793416 3.112992 4.2395516 7.2979132118 3.0664072 3.1017488 4.2196629 7.2610458

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119 3.053563 3.0905812 4.1998815 7.2244873120 3.0408084 3.0794885 4.1802066 7.1882351121 3.0281426 3.0684701 4.1606375 7.1522864122 3.0155653 3.0575254 4.1411732 7.1166389123 3.0030757 3.0466538 4.1218131 7.0812897124 2.9906733 3.0358547 4.1025562 7.0462365125 2.9783576 3.0251276 4.0834018 7.0114767126 2.9661279 3.0144718 4.0643492 6.9770077127 2.9539838 3.0038868 4.0453975 6.9428271128 2.9419246 2.993372 4.0265459 6.9089326129 2.9299499 2.9829268 4.0077938 6.8753216130 2.9180591 2.9725507 3.9891404 6.8419917131 2.9062517 2.9622432 3.9705849 6.8089407132 2.8945271 2.9520036 3.9521266 6.7761661133 2.8828847 2.9418315 3.9337648 6.7436656134 2.8713242 2.9317263 3.9154987 6.7114371135 2.8598449 2.9216875 3.8973277 6.679478136 2.8484464 2.9117145 3.8792509 6.6477864137 2.8371282 2.9018069 3.8612679 6.6163598138 2.8258897 2.8919641 3.8433777 6.5851961139 2.8147304 2.8821857 3.8255798 6.5542932140 2.8036499 2.872471 3.8078735 6.5236489141 2.7926477 2.8628197 3.7902581 6.493261142 2.7817232 2.8532312 3.7727329 6.4631275143 2.7708761 2.843705 3.7552973 6.4332462144 2.7601057 2.8342407 3.7379506 6.4036151145 2.7494118 2.8248377 3.7206922 6.3742321146 2.7387937 2.8154957 3.7035214 6.3450952147 2.728251 2.8062141 3.6864376 6.3162025148 2.7177833 2.7969924 3.6694402 6.2875518149 2.7073901 2.7878303 3.6525285 6.2591413150 2.697071 2.7787272 3.635702 6.230969151 2.6868254 2.7696827 3.61896 6.203033152 2.6766531 2.7606963 3.6023019 6.1753314153 2.6665534 2.7517677 3.5857271 6.1478623154 2.656526 2.7428963 3.5692351 6.1206237155 2.6465705 2.7340818 3.5528251 6.093614156 2.6366864 2.7253237 3.5364968 6.0668311157 2.6268734 2.7166216 3.5202494 6.0402734158 2.6171308 2.707975 3.5040824 6.0139391159 2.6074585 2.6993836 3.4879952 5.9878262160 2.5978559 2.6908469 3.4719874 5.9619332161 2.5883226 2.6823645 3.4560582 5.9362581162 2.5788582 2.673936 3.4402072 5.9107994163 2.5694624 2.6655611 3.4244339 5.8855554164 2.5601347 2.6572393 3.4087376 5.8605242165 2.5508747 2.6489702 3.3931179 5.8357042166 2.541682 2.6407534 3.3775742 5.8110938167 2.5325563 2.6325886 3.3621059 5.7866914168 2.5234971 2.6244753 3.3467127 5.7624953169 2.514504 2.6164132 3.3313939 5.7385038

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170 2.5055768 2.608402 3.3161491 5.7147154171 2.496715 2.6004411 3.3009777 5.6911286172 2.4879181 2.5925304 3.2858792 5.6677417173 2.479186 2.5846693 3.2708531 5.6445532174 2.4705181 2.5768576 3.255899 5.6215615175 2.4619142 2.5690948 3.2410164 5.5987652176 2.4533738 2.5613807 3.2262047 5.5761626177 2.4448966 2.5537149 3.2114635 5.5537525178 2.4364822 2.5460969 3.1967924 5.5315331179 2.4281304 2.5385266 3.1821907 5.5095032180 2.4198406 2.5310035 3.1676582 5.4876612181 2.4116127 2.5235273 3.1531942 5.4660057182 2.4034462 2.5160976 3.1387985 5.4445352183 2.3953408 2.5087142 3.1244704 5.4232484184 2.3872961 2.5013767 3.1102095 5.4021439185 2.3793119 2.4940848 3.0960155 5.3812203186 2.3713877 2.486838 3.0818878 5.3604761187 2.3635233 2.4796363 3.067826 5.3399101188 2.3557184 2.4724791 3.0538297 5.3195209189 2.3479725 2.4653662 3.0398985 5.2993072190 2.3402854 2.4582973 3.0260318 5.2792676191 2.3326567 2.4512721 3.0122294 5.2594009192 2.3250862 2.4442902 2.9984908 5.2397057193 2.3175734 2.4373514 2.9848155 5.2201807194 2.3101182 2.4304554 2.9712031 5.2008247195 2.3027202 2.4236018 2.9576533 5.1816364196 2.295379 2.4167903 2.9441656 5.1626146197 2.2880944 2.4100208 2.9307397 5.1437581198 2.280866 2.4032928 2.917375 5.1250655199 2.2736936 2.3966061 2.9040714 5.1065357200 2.2665769 2.3899604 2.8908282 5.0881674201 2.2595156 2.3833554 2.8776452 5.0699596202 2.2525093 2.3767909 2.864522 5.0519109203 2.2455577 2.3702665 2.8514581 5.0340203204 2.2386607 2.363782 2.8384533 5.0162865205 2.2318179 2.3573371 2.825507 4.9987084206 2.2250289 2.3509316 2.8126191 4.9812849207 2.2182936 2.3445651 2.799789 4.9640149208 2.2116116 2.3382375 2.7870164 4.9468971209 2.2049827 2.3319483 2.774301 4.9299305210 2.1984065 2.3256975 2.7616423 4.9131141211 2.1918829 2.3194847 2.7490401 4.8964466212 2.1854115 2.3133096 2.736494 4.8799271213 2.178992 2.307172 2.7240037 4.8635544214 2.1726243 2.3010717 2.7115686 4.8473274215 2.1663079 2.2950084 2.6991887 4.8312453216 2.1600427 2.2889819 2.6868634 4.8153068217 2.1538284 2.2829918 2.6745925 4.7995109218 2.1476648 2.277038 2.6623755 4.7838567219 2.1415514 2.2711203 2.6502123 4.7683431220 2.1354883 2.2652383 2.6381024 4.7529691

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221 2.1294749 2.2593918 2.6260455 4.7377337222 2.1235112 2.2535807 2.6140413 4.7226359223 2.1175968 2.2478046 2.6020895 4.7076747224 2.1117315 2.2420634 2.5901897 4.6928491225 2.105915 2.2363568 2.5783417 4.6781583226 2.1001472 2.2306845 2.5665451 4.6636012227 2.0944277 2.2250464 2.5547995 4.6491768228 2.0887563 2.2194423 2.5431047 4.6348843229 2.0831328 2.2138718 2.5314605 4.6207227230 2.0775569 2.2083348 2.5198664 4.6066911231 2.0720284 2.2028311 2.5083221 4.5927885232 2.066547 2.1973605 2.4968274 4.5790141233 2.0611126 2.1919226 2.485382 4.5653669234 2.0557248 2.1865174 2.4739856 4.5518461235 2.0503836 2.1811446 2.4626378 4.5384507236 2.0450885 2.175804 2.4513384 4.52518237 2.0398394 2.1704954 2.4400871 4.512033238 2.0346361 2.1652185 2.4288837 4.4990088239 2.0294784 2.1599732 2.4177277 4.4861066240 2.0243659 2.1547594 2.406619 4.4733256241 2.0192986 2.1495766 2.3955572 4.4606649242 2.0142761 2.1444249 2.3845421 4.4481237243 2.0092983 2.1393039 2.3735735 4.4357011244 2.004365 2.1342135 2.3626509 4.4233963245 1.9994758 2.1291534 2.3517743 4.4112085246 1.9946307 2.1241236 2.3409432 4.399137247 1.9898294 2.1191237 2.3301574 4.3871808248 1.9850717 2.1141537 2.3194167 4.3753393249 1.9803573 2.1092133 2.3087208 4.3636116250 1.9756861 2.1043022 2.2980694 4.3519969251 1.9710579 2.0994205 2.2874623 4.3404945252 1.9664725 2.0945678 2.2768992 4.3291035253 1.9619295 2.0897439 2.2663799 4.3178233254 1.957429 2.0849488 2.255904 4.3066531255 1.9529706 2.0801821 2.2454714 4.2955921256 1.9485541 2.0754438 2.2350819 4.2846396257 1.9441794 2.0707336 2.2247351 4.2737949258 1.9398462 2.0660515 2.2144308 4.2630571259 1.9355544 2.0613971 2.2041687 4.2524257260 1.9313038 2.0567703 2.1939487 4.2418998261 1.9270941 2.052171 2.1837705 4.2314788262 1.9229252 2.047599 2.1736338 4.2211619263 1.9187969 2.0430541 2.1635385 4.2109485264 1.914709 2.0385362 2.1534842 4.2008378265 1.9106613 2.0340451 2.1434707 4.1908292266 1.9066537 2.0295805 2.1334979 4.180922267 1.9026858 2.0251424 2.1235654 4.1711154268 1.8987576 2.0207307 2.1136731 4.1614089269 1.8948689 2.016345 2.1038207 4.1518017270 1.8910195 2.0119853 2.094008 4.1422932271 1.8872092 2.0076514 2.0842348 4.1328828

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272 1.8834378 2.0033432 2.0745009 4.1235697273 1.8797051 1.9990605 2.064806 4.1143534274 1.876011 1.9948031 2.0551499 4.1052331275 1.8723553 1.9905709 2.0455324 4.0962083276 1.8687379 1.9863637 2.0359533 4.0872784277 1.8651585 1.9821814 2.0264124 4.0784426278 1.8616169 1.9780239 2.0169095 4.0697003279 1.8581131 1.9738909 2.0074443 4.0610511280 1.8546468 1.9697824 1.9980166 4.0524941281 1.8512178 1.9656981 1.9886263 4.0440289282 1.8478261 1.961638 1.9792731 4.0356548283 1.8444714 1.9576019 1.9699568 4.0273713284 1.8411535 1.9535896 1.9606773 4.0191776285 1.8378723 1.9496011 1.9514343 4.0110734286 1.8346277 1.9456361 1.9422276 4.0030579287 1.8314194 1.9416945 1.933057 3.9951305288 1.8282474 1.9377763 1.9239224 3.9872908289 1.8251114 1.9338811 1.9148235 3.9795381290 1.8220113 1.930009 1.9057602 3.9718719291 1.8189469 1.9261598 1.8967322 3.9642915292 1.8159181 1.9223333 1.8877393 3.9567966293 1.8129247 1.9185294 1.8787814 3.9493864294 1.8099665 1.9147479 1.8698583 3.9420604295 1.8070435 1.9109888 1.8609698 3.9348182296 1.8041554 1.9072519 1.8521157 3.9276591297 1.8013021 1.9035371 1.8432958 3.9205826298 1.7984835 1.8998443 1.8345099 3.9135883299 1.7956993 1.8961732 1.8257579 3.9066755300 1.7929495 1.8925238 1.8170396 3.8998437301 1.7902339 1.888896 1.8083548 3.8930924302 1.7875523 1.8852897 1.7997032 3.8864212303 1.7849047 1.8817046 1.7910849 3.8798294304 1.7822908 1.8781408 1.7824994 3.8733166305 1.7797105 1.874598 1.7739468 3.8668823306 1.7771637 1.8710761 1.7654268 3.8605259307 1.7746502 1.8675751 1.7569393 3.854247308 1.7721698 1.8640947 1.748484 3.8480451309 1.7697226 1.860635 1.7400608 3.8419197310 1.7673082 1.8571957 1.7316695 3.8358703311 1.7649265 1.8537767 1.72331 3.8298964312 1.7625775 1.850378 1.7149822 3.8239976313 1.760261 1.8469994 1.7066857 3.8181733314 1.7579768 1.8436408 1.6984206 3.8124231315 1.7557248 1.840302 1.6901865 3.8067466316 1.7535049 1.8369831 1.6819834 3.8011432317 1.7513169 1.8336838 1.6738111 3.7956125318 1.7491607 1.830404 1.6656694 3.7901541319 1.7470362 1.8271437 1.6575581 3.7847674320 1.7449433 1.8239027 1.6494772 3.7794521321 1.7428817 1.8206808 1.6414265 3.7742077322 1.7408514 1.8174781 1.6334057 3.7690337

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323 1.7388522 1.8142944 1.6254148 3.7639297324 1.7368841 1.8111296 1.6174536 3.7588953325 1.7349468 1.8079836 1.609522 3.75393326 1.7330403 1.8048562 1.6016197 3.7490335327 1.7311644 1.8017474 1.5937467 3.7442052328 1.7293191 1.7986571 1.5859027 3.7394447329 1.7275041 1.7955851 1.5780877 3.7347517330 1.7257193 1.7925314 1.5703015 3.7301256331 1.7239647 1.7894958 1.562544 3.7255662332 1.7222401 1.7864783 1.554815 3.7210729333 1.7205454 1.7834788 1.5471143 3.7166454334 1.7188804 1.7804971 1.5394418 3.7122833335 1.7172451 1.7775331 1.5317975 3.7079861336 1.7156393 1.7745868 1.524181 3.7037534337 1.7140629 1.7716581 1.5165924 3.6995849338 1.7125157 1.7687468 1.5090314 3.6954802339 1.7109978 1.7658529 1.501498 3.6914389340 1.7095089 1.7629763 1.4939919 3.6874605341 1.7080489 1.7601168 1.486513 3.6835447342 1.7066177 1.7572744 1.4790613 3.6796911343 1.7052152 1.754449 1.4716366 3.6758994344 1.7038413 1.7516405 1.4642387 3.672169345 1.7024959 1.7488488 1.4568674 3.6684998346 1.7011788 1.7460738 1.4495228 3.6648913347 1.6998899 1.7433154 1.4422046 3.661343348 1.6986292 1.7405735 1.4349128 3.6578548349 1.6973965 1.7378481 1.4276471 3.6544261350 1.6961917 1.735139 1.4204074 3.6510567

0 5.47188 4.92926 7.6733 13.8398 19.56551 5.43972 4.90299 7.62483 13.7383 19.43842 5.40791 4.87727 7.57722 13.6387 19.31333 5.37644 4.85208 7.53044 13.541 19.19024 5.34529 4.82739 7.48445 13.4451 19.06895 5.31447 4.80318 7.43922 13.3509 18.94956 5.28397 4.77942 7.39472 13.2583 18.83177 5.25377 4.75609 7.35092 13.1672 18.71578 5.22388 4.73318 7.30778 13.0777 18.60129 5.19428 4.71065 7.26528 12.9896 18.4882

10 5.16497 4.68851 7.2234 12.9029 18.376711 5.13595 4.66673 7.18211 12.8174 18.266612 5.10721 4.64529 7.14139 12.7333 18.157813 5.07873 4.62417 7.10123 12.6504 18.050414 5.05053 4.60338 7.06158 12.5686 17.944215 5.02259 4.58289 7.02245 12.488 17.839216 4.99491 4.56268 6.98382 12.4084 17.735417 4.96749 4.54276 6.94565 12.3299 17.632718 4.94031 4.5231 6.90795 12.2524 17.531119 4.91338 4.5037 6.87069 12.1759 17.4305

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20 4.88669 4.48454 6.83386 12.1004 17.33121 4.86024 4.46563 6.79744 12.0257 17.232422 4.83402 4.44694 6.76142 11.9519 17.134823 4.80803 4.42847 6.7258 11.879 17.038224 4.78227 4.41022 6.69055 11.8069 16.942425 4.75673 4.39216 6.65567 11.7356 16.847526 4.73141 4.37431 6.62114 11.6651 16.753527 4.70631 4.35664 6.58696 11.5953 16.660328 4.68142 4.33916 6.55312 11.5263 16.567829 4.65674 4.32186 6.51959 11.4579 16.476230 4.63227 4.30472 6.48639 11.3903 16.385331 4.608 4.28775 6.45349 11.3233 16.295132 4.58393 4.27095 6.42089 11.2569 16.205733 4.56006 4.25429 6.38858 11.1912 16.116934 4.53639 4.23779 6.35656 11.1261 16.028835 4.51291 4.22143 6.32481 11.0615 15.941436 4.48962 4.20521 6.29333 10.9976 15.854737 4.46652 4.18913 6.26211 10.9342 15.768538 4.44361 4.17318 6.23115 10.8714 15.68339 4.42088 4.15735 6.20044 10.8091 15.598140 4.39833 4.14165 6.16997 10.7473 15.513741 4.37595 4.12608 6.13974 10.686 15.429942 4.35376 4.11062 6.10974 10.6252 15.346743 4.33174 4.09527 6.07996 10.5649 15.26444 4.30989 4.08003 6.05041 10.505 15.181945 4.28821 4.0649 6.02108 10.4456 15.100346 4.2667 4.04988 5.99195 10.3867 15.019247 4.24536 4.03495 5.96304 10.3282 14.938648 4.22418 4.02013 5.93433 10.2701 14.858549 4.20317 4.0054 5.90581 10.2125 14.778950 4.18231 3.99077 5.87749 10.1552 14.699751 4.16162 3.97623 5.84936 10.0983 14.62152 4.14108 3.96177 5.82142 10.0419 14.542853 4.12069 3.94741 5.79366 9.98579 14.46554 4.10047 3.93313 5.76608 9.93008 14.387655 4.08039 3.91893 5.73867 9.87473 14.310756 4.06046 3.90481 5.71144 9.81974 14.234157 4.04068 3.89078 5.68438 9.7651 14.15858 4.02105 3.87682 5.65748 9.71081 14.082359 4.00157 3.86293 5.63075 9.65685 14.007160 3.98222 3.84912 5.60417 9.60323 13.932161 3.96303 3.83538 5.57776 9.54992 13.857662 3.94397 3.82172 5.55149 9.49694 13.783563 3.92505 3.80812 5.52538 9.44427 13.709764 3.90627 3.79459 5.49942 9.3919 13.636365 3.88763 3.78112 5.47361 9.33984 13.563366 3.86912 3.76773 5.44794 9.28807 13.490667 3.85075 3.75439 5.42241 9.23659 13.418368 3.83251 3.74112 5.39702 9.18539 13.346369 3.8144 3.72791 5.37177 9.13448 13.274770 3.79643 3.71476 5.34666 9.08384 13.2033

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71 3.77858 3.70167 5.32168 9.03347 13.132472 3.76086 3.68864 5.29683 8.98337 13.061773 3.74327 3.67566 5.27211 8.93353 12.991474 3.7258 3.66275 5.24751 8.88395 12.921475 3.70846 3.64988 5.22305 8.83463 12.851776 3.69124 3.63708 5.1987 8.78555 12.782377 3.67414 3.62432 5.17448 8.73672 12.713278 3.65716 3.61162 5.15038 8.68814 12.644479 3.6403 3.59897 5.1264 8.63979 12.57680 3.62357 3.58637 5.10254 8.59168 12.507881 3.60695 3.57382 5.07879 8.5438 12.439982 3.59044 3.56133 5.05516 8.49615 12.372383 3.57406 3.54888 5.03164 8.44872 12.30584 3.55778 3.53648 5.00823 8.40152 12.237985 3.54162 3.52412 4.98493 8.35454 12.171286 3.52558 3.51182 4.96174 8.30778 12.104787 3.50964 3.49956 4.93866 8.26123 12.038588 3.49382 3.48735 4.91568 8.21489 11.972589 3.47811 3.47518 4.89281 8.16876 11.906890 3.4625 3.46306 4.87004 8.12284 11.841491 3.44701 3.45098 4.84738 8.07712 11.776392 3.43162 3.43895 4.82481 8.0316 11.711493 3.41633 3.42695 4.80235 7.98628 11.646794 3.40116 3.41501 4.77999 7.94116 11.582495 3.38608 3.4031 4.75772 7.89623 11.518296 3.37111 3.39124 4.73556 7.85149 11.454497 3.35625 3.37942 4.71348 7.80695 11.390798 3.34148 3.36764 4.69151 7.76259 11.327399 3.32682 3.3559 4.66963 7.71842 11.2642

100 3.31226 3.34421 4.64784 7.67443 11.2013101 3.2978 3.33255 4.62614 7.63062 11.1386102 3.28343 3.32093 4.60454 7.587 11.0762103 3.26917 3.30935 4.58303 7.54355 11.014104 3.255 3.29782 4.56161 7.50028 10.9521105 3.24093 3.28632 4.54028 7.45718 10.8903106 3.22695 3.27486 4.51903 7.41426 10.8288107 3.21307 3.26344 4.49788 7.37151 10.7676108 3.19929 3.25205 4.47681 7.32893 10.7065109 3.1856 3.24071 4.45582 7.28652 10.6457110 3.172 3.2294 4.43493 7.24428 10.5851111 3.15849 3.21814 4.41412 7.2022 10.5248112 3.14508 3.2069 4.39339 7.16029 10.4646113 3.13176 3.19571 4.37275 7.11854 10.4047114 3.11853 3.18455 4.35219 7.07695 10.345115 3.10538 3.17343 4.33171 7.03553 10.2855116 3.09233 3.16235 4.31131 6.99426 10.2262117 3.07937 3.15131 4.291 6.95315 10.1672118 3.06649 3.1403 4.27077 6.9122 10.1083119 3.0537 3.12932 4.25061 6.8714 10.0497120 3.041 3.11839 4.23054 6.83076 9.99128121 3.02839 3.10749 4.21055 6.79027 9.93307

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122 3.01586 3.09662 4.19063 6.74993 9.87507123 3.00341 3.08579 4.17079 6.70975 9.81728124 2.99105 3.075 4.15104 6.66972 9.75969125 2.97878 3.06425 4.13135 6.62984 9.70231126 2.96658 3.05353 4.11175 6.5901 9.64514127 2.95447 3.04284 4.09222 6.55051 9.58817128 2.94245 3.03219 4.07277 6.51107 9.5314129 2.9305 3.02158 4.05339 6.47178 9.47483130 2.91864 3.011 4.03409 6.43263 9.41847131 2.90686 3.00046 4.01487 6.39363 9.36231132 2.89515 2.98995 3.99571 6.35477 9.30635133 2.88353 2.97948 3.97664 6.31606 9.25059134 2.87199 2.96904 3.95763 6.27748 9.19502135 2.86052 2.95864 3.9387 6.23905 9.13966136 2.84914 2.94828 3.91985 6.20076 9.08449137 2.83783 2.93795 3.90106 6.16261 9.02952138 2.8266 2.92765 3.88235 6.1246 8.97475139 2.81545 2.91739 3.86371 6.08673 8.92017140 2.80437 2.90717 3.84515 6.04899 8.86578141 2.79337 2.89698 3.82665 6.0114 8.8116142 2.78245 2.88683 3.80823 5.97394 8.7576143 2.7716 2.87672 3.78988 5.93662 8.7038144 2.76083 2.86664 3.7716 5.89944 8.6502145 2.75013 2.85659 3.75338 5.86239 8.59678146 2.73951 2.84658 3.73524 5.82548 8.54356147 2.72896 2.83661 3.71718 5.78871 8.49053148 2.71848 2.82667 3.69918 5.75206 8.4377149 2.70808 2.81677 3.68125 5.71556 8.38505150 2.69775 2.80691 3.66339 5.67919 8.3326151 2.68749 2.79708 3.6456 5.64295 8.28033152 2.6773 2.78729 3.62788 5.60684 8.22826153 2.66719 2.77753 3.61023 5.57087 8.17638154 2.65715 2.76781 3.59264 5.53503 8.12469155 2.64717 2.75813 3.57513 5.49933 8.07319156 2.63727 2.74848 3.55769 5.46375 8.02188157 2.62744 2.73888 3.54031 5.42831 7.97076158 2.61768 2.72931 3.52301 5.393 7.91983159 2.60799 2.71977 3.50577 5.35782 7.86909160 2.59837 2.71028 3.4886 5.32278 7.81854161 2.58882 2.70082 3.4715 5.28786 7.76818162 2.57934 2.6914 3.45447 5.25308 7.718163 2.56992 2.68201 3.4375 5.21843 7.66802164 2.56058 2.67267 3.42061 5.18391 7.61823165 2.55129 2.66336 3.40378 5.14951 7.56862166 2.54207 2.65408 3.38701 5.11523 7.51918167 2.53291 2.64483 3.3703 5.08107 7.46991168 2.52381 2.63562 3.35365 5.04703 7.4208169 2.51476 2.62644 3.33707 5.0131 7.37187170 2.50578 2.61729 3.32054 4.97929 7.32311171 2.49685 2.60817 3.30408 4.9456 7.27452172 2.48798 2.59909 3.28768 4.91203 7.22609

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173 2.47917 2.59004 3.27134 4.87857 7.17784174 2.47041 2.58102 3.25506 4.84523 7.12976175 2.46172 2.57203 3.23885 4.81201 7.08185176 2.45308 2.56308 3.22269 4.7789 7.03411177 2.4445 2.55417 3.2066 4.74592 6.98655178 2.43597 2.54529 3.19057 4.71305 6.93915179 2.4275 2.53644 3.17459 4.6803 6.89193180 2.41909 2.52763 3.15869 4.64766 6.84488181 2.41073 2.51885 3.14284 4.61515 6.798182 2.40243 2.51011 3.12705 4.58275 6.7513183 2.39419 2.5014 3.11133 4.55047 6.70476184 2.386 2.49273 3.09567 4.51831 6.65841185 2.37787 2.48409 3.08007 4.48627 6.61222186 2.36979 2.47549 3.06453 4.45435 6.56622187 2.36176 2.46693 3.04905 4.42255 6.52038188 2.3538 2.45841 3.03364 4.39087 6.47473189 2.34588 2.44992 3.01829 4.35931 6.42925190 2.33802 2.44147 3.00301 4.32786 6.38395191 2.33022 2.43306 2.98778 4.29654 6.33882192 2.32247 2.42469 2.97262 4.26535 6.29388193 2.31478 2.41636 2.95753 4.23427 6.24911194 2.30714 2.40806 2.94249 4.20332 6.20453195 2.29955 2.39981 2.92752 4.17248 6.16012196 2.29202 2.39159 2.91262 4.14178 6.1159197 2.28454 2.38342 2.89778 4.11119 6.07186198 2.27712 2.37529 2.883 4.08073 6.02801199 2.26975 2.36719 2.86829 4.0504 5.98433200 2.26243 2.35914 2.85365 4.02019 5.94085201 2.25517 2.35114 2.83907 3.9901 5.89755202 2.24796 2.34317 2.82455 3.96015 5.85444203 2.24081 2.33525 2.81011 3.93032 5.81151204 2.23371 2.32737 2.79572 3.90062 5.76878205 2.22666 2.31954 2.78141 3.87104 5.72624206 2.21967 2.31175 2.76716 3.8416 5.68389207 2.21273 2.304 2.75298 3.81229 5.64173208 2.20585 2.2963 2.73887 3.7831 5.59976209 2.19902 2.28865 2.72483 3.75405 5.558210 2.19224 2.28105 2.71086 3.72514 5.51643211 2.18552 2.27349 2.69695 3.69635 5.47505212 2.17885 2.26598 2.68312 3.6677 5.43388213 2.17224 2.25852 2.66935 3.63919 5.39291214 2.16568 2.2511 2.65566 3.61081 5.35214215 2.15918 2.24374 2.64204 3.58257 5.31158216 2.15273 2.23643 2.62849 3.55447 5.27122217 2.14633 2.22917 2.61501 3.52651 5.23107218 2.13999 2.22196 2.60161 3.49869 5.19113219 2.13371 2.21481 2.58828 3.47102 5.1514220 2.12748 2.2077 2.57502 3.44348 5.11188221 2.1213 2.20065 2.56184 3.41609 5.07258222 2.11518 2.19366 2.54873 3.38884 5.03349223 2.10911 2.18672 2.53569 3.36173 4.99461

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224 2.1031 2.17983 2.52273 3.33477 4.95595225 2.09714 2.173 2.50985 3.30796 4.91751226 2.09123 2.16622 2.49704 3.28129 4.87928227 2.08538 2.1595 2.48431 3.25477 4.84128228 2.07958 2.15284 2.47166 3.2284 4.80349229 2.07383 2.14623 2.45908 3.20217 4.76593230 2.06814 2.13968 2.44658 3.1761 4.7286231 2.0625 2.1332 2.43416 3.15018 4.69148232 2.05692 2.12677 2.42182 3.12441 4.6546233 2.05138 2.1204 2.40955 3.09879 4.61794234 2.0459 2.11409 2.39737 3.07333 4.58151235 2.04047 2.10784 2.38526 3.04802 4.54531236 2.0351 2.10165 2.37324 3.02287 4.50935237 2.02977 2.09552 2.3613 2.99788 4.47362238 2.0245 2.08946 2.34944 2.97304 4.43813239 2.01929 2.08347 2.33766 2.94837 4.40287240 2.01412 2.07753 2.32597 2.92385 4.36786241 2.00901 2.07166 2.31436 2.8995 4.33309242 2.00395 2.06586 2.30284 2.87531 4.29856243 1.99894 2.06013 2.2914 2.85129 4.26428244 1.99398 2.05446 2.28004 2.82743 4.23025245 1.98908 2.04886 2.26878 2.80374 4.19646246 1.98422 2.04333 2.2576 2.78022 4.16293247 1.97942 2.03787 2.2465 2.75687 4.12965248 1.97467 2.03248 2.2355 2.73369 4.09664249 1.96997 2.02716 2.22459 2.71068 4.06387250 1.96533 2.02192 2.21377 2.68785 4.03138251 1.96074 2.01674 2.20304 2.6652 3.99914252 1.95619 2.01165 2.1924 2.64273 3.96718253 1.9517 2.00663 2.18185 2.62044 3.93548254 1.94727 2.00168 2.1714 2.59833 3.90405255 1.94288 1.99682 2.16105 2.5764 3.8729256 1.93854 1.99203 2.15079 2.55466 3.84203257 1.93426 1.98732 2.14063 2.53311 3.81144258 1.93003 1.98269 2.13057 2.51175 3.78113259 1.92585 1.97815 2.1206 2.49058 3.75111260 1.92172 1.97368 2.11074 2.46961 3.72138261 1.91765 1.96931 2.10098 2.44883 3.69195262 1.91363 1.96502 2.09132 2.42825 3.66281263 1.90965 1.96081 2.08177 2.40788 3.63397264 1.90573 1.95669 2.07232 2.3877 3.60544265 1.90187 1.95267 2.06298 2.36774 3.57721266 1.89805 1.94873 2.05374 2.34798 3.5493267 1.89429 1.94489 2.04462 2.32844 3.5217268 1.89058 1.94114 2.03561 2.30911 3.49442269 1.88692 1.93749 2.02671 2.28999 3.46747270 1.88332 1.93393 2.01792 2.2711 3.44084271 1.87976 1.93047 2.00925 2.25243 3.41455272 1.87626 1.92711 2.0007 2.23399 3.38859273 1.87282 1.92386 1.99226 2.21577 3.36298274 1.86942 1.92071 1.98395 2.19779 3.33771

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275 1.86608 1.91766 1.97575 2.18005 3.3128276 1.86279 1.91472 1.96768 2.16254 3.28824277 1.85956 1.91189 1.95974 2.14528 3.26405278 1.85638 1.90917 1.95193 2.12827 3.24023279 1.85325 1.90657 1.94424 2.1115 3.21677280 1.85018 1.90408 1.93669 2.095 3.1937281 1.84716 1.9017 1.92927 2.07875 3.17102282 1.8442 1.89945 1.92199 2.06276 3.14872283 1.84129 1.89732 1.91485 2.04704 3.12683284 1.83843 1.89531 1.90784 2.0316 3.10534285 1.83563 1.89343 1.90098 2.01643 3.08426286 1.83289 1.89168 1.89427 2.00154 3.0636287 1.8302 1.89006 1.88771 1.98694 3.04337288 1.82756 1.88857 1.88129 1.97263 3.02357289 1.82499 1.88722 1.87503 1.95861 3.00421290 1.82247 1.88601 1.86893 1.9449 2.9853291 1.82 1.88495 1.86299 1.9315 2.96686292 1.81759 1.88403 1.85721 1.91841 2.94888293 1.81524 1.88326 1.85159 1.90565 2.93137294 1.81295 1.88264 1.84615 1.89321 2.91436295 1.81072 1.88217 1.84088 1.8811 2.89783296 1.80854 1.88187 1.83578 1.86933 2.88182297 1.80642 1.88173 1.83087 1.85791 2.86631298 1.80439 1.88179 1.82618 1.84692 2.85145299 1.80239 1.88198 1.82163 1.83622 2.83702300 1.80043 1.88239 1.81731 1.82601 2.82334301 1.79727 1.88137 1.8111 1.81204 2.80434302 1.7954 1.88204 1.80706 1.80231 2.79136303 1.79354 1.88285 1.80317 1.79286 2.7788304 1.79175 1.88385 1.7995 1.78383 2.76687305 1.78998 1.88501 1.79601 1.77515 2.75545306 1.78823 1.88634 1.79269 1.7668 2.74452307 1.7865 1.88782 1.78955 1.75878 2.73409308 1.78477 1.88945 1.78658 1.75109 2.72413309 1.78303 1.89123 1.78378 1.74371 2.71464310 1.78129 1.89317 1.78114 1.73665 2.70562311 1.77952 1.89524 1.77867 1.72989 2.69705312 1.77773 1.89746 1.77636 1.72344 2.68892313 1.77591 1.89982 1.7742 1.71728 2.68124314 1.77404 1.90233 1.77221 1.71142 2.67399315 1.77212 1.90497 1.77037 1.70585 2.66718316 1.77014 1.90775 1.76869 1.70058 2.66079317 1.76809 1.91066 1.76716 1.69558 2.65482318 1.76597 1.91372 1.76579 1.69088 2.64928319 1.76377 1.91691 1.76458 1.68646 2.64415320 1.76148 1.92024 1.76352 1.68233 2.63944321 1.75908 1.9237 1.76262 1.67848 2.63516322 1.75658 1.9273 1.76187 1.67492 2.63129323 1.75395 1.93104 1.76128 1.67165 2.62785324 1.75121 1.93493 1.76086 1.66867 2.62483325 1.74832 1.93896 1.7606 1.66599 2.62225

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326 1.74529 1.94313 1.7605 1.66361 2.62011327 1.74211 1.94745 1.76058 1.66153 2.61841328 1.73876 1.95192 1.76083 1.65977 2.61717329 1.73523 1.95655 1.76125 1.65833 2.6164330 1.73152 1.96134 1.76187 1.65721 2.6161331 1.72762 1.9663 1.76267 1.65644 2.6163332 1.7235 1.97143 1.76366 1.65601 2.617333 1.71917 1.97674 1.76487 1.65595 2.61824334 1.71461 1.98224 1.76628 1.65627 2.62002335 1.7098 1.98793 1.76792 1.65699 2.62238336 1.70474 1.99382 1.76978 1.65811 2.62534337 1.6994 1.99993 1.7719 1.65967 2.62893338 1.69378 2.00627 1.77427 1.66169 2.63317339 1.68786 2.01284 1.7769 1.66419 2.63812340 1.68162 2.01967 1.77983 1.66719 2.6438341 1.67504 2.02677 1.78306 1.67074 2.65026342 1.66812 2.03415 1.78661 1.67486 2.65756343 1.66082 2.04184 1.79051 1.6796 2.66575344 1.65313 2.04987 1.79478 1.685 2.6749345 1.64502 2.05824 1.79944 1.6911 2.68507346 1.63647 2.06699 1.80452 1.69796 2.69633347 1.62746 2.07616 1.81007 1.70564 2.70878348 1.61778 2.08589 1.81623 1.71446 2.7229349 1.60773 2.096 1.82283 1.72403 2.73809350 1.59763 2.10625 1.82961 1.73388 2.75367

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0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6 log Q1,1 of boric acid

Mesmer 1972 - B(OH)3

Palmer 2000 - B(OH)3

Byers 2000 - B(OH)3

prediciton - B(OH)3

t/C

logQ

11

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6 log Q2,1 of boric acid

Mesmer 1972 - I=1M

Palmer 2000 - B(OH)3

Palmer 2000 - I=1M

Byers 2000

prediction - B(OH)3

t/C

logQ

21

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6

7

8

9 log Q3,1 of boric acid

Mesmer 1972 - I=1MPalmer 2000 - B(OH)3Palmer 2000 - I=1MByers 2000prediction - B(OH)3

t/C

logQ

31

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0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

1

2

3

4

5

6

7

8

9 log Q3,1 of boric acid

Mesmer 1972 - I=1MPalmer 2000 - B(OH)3Palmer 2000 - I=1MByers 2000prediction - B(OH)3

t/C

logQ

31

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

2

4

6

8

10

12

14

16 log Q4,2 of boric acid

Mesmer 1972 - I=1MPalmer 2000Palmer 2000 - I=1MByers 2000prediciton

t/C

logQ

42

0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

5

10

15

20

25 log Q5,3 of boric acid

Mesmer 1972 - I=1MPalmer 2000Palmer 2000 - I=1Mprediction

t/C

logQ

53

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0 25 50 75 100 125 150 175 200 225 250 275 300 325 3500

5

10

15

20

25 log Q5,3 of boric acid

Mesmer 1972 - I=1MPalmer 2000Palmer 2000 - I=1Mprediction

t/C

logQ

53

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Q5,3I=121.22580921.11304721.00110420.88997220.77964220.67010520.56135320.45337820.34617

20.23972320.13402720.02907519.92486

19.82137319.71860619.61655319.51520619.414557

19.314619.21532719.11673119.018806

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18.92154418.82493918.72898518.633674

18.53918.44495718.35153818.25873818.16655118.07496917.98398817.89360117.80380217.71458617.62594817.53788117.4503817.36344

17.27705517.1912217.10593

17.02117916.93696316.85327616.77011416.68747116.60534316.52372416.44261116.36199816.28188216.20225616.12311716.04446115.96628215.88857715.81134215.73457115.65826115.58240815.50700815.43205715.35754915.28348315.20985315.13665715.06388914.99154714.91962614.84812414.777035

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14.70635814.63608814.56622114.49675414.42768514.35900814.29072214.22282314.15530714.08817114.02141213.95502713.88901213.82336613.75808413.69316313.62860113.56439413.50054

13.43703613.37387913.31106613.24859413.18646

13.12466213.06319813.00206312.94125612.88077512.82061512.76077612.70125412.64204612.58315112.52456612.46628812.40831612.35064512.29327612.23620412.17942712.12294412.06675212.01084911.955232

11.899911.8448511.79008

11.73558711.68137111.627428

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11.57375811.52035611.46722211.41435411.36174911.30940611.25732311.20549711.15392811.10261211.05154811.00073510.95016910.89985110.84977710.79994610.75035710.70100610.65189410.60301810.55437610.50596610.45778810.40983910.36211810.31462210.26735210.22030410.17347710.12687

10.08048210.03431

9.98835339.94261039.89707949.85175939.80664859.76174559.71704889.67255719.6282699.584183

9.54029789.49661219.45312439.40983339.36673779.32383619.28112739.23860999.1962827

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9.15414449.11219379.07042949.02885038.987455

8.94624258.90521158.86436088.82368918.78319558.74287858.70273728.66277048.62297698.58335568.54390548.50462528.46551398.42657048.38779368.34918258.3107368.272453

8.23433268.19637368.15857518.120936

8.08345538.04613218.00896537.971954

7.93509727.89839387.86184317.82544397.78919557.75309687.71714697.68134497.64568987.61018097.57481717.53959777.50452167.46958817.43479637.40014537.36563437.33126237.29702877.2629325

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7.22897297.19514917.16146027.12790567.09448437.06119577.02803886.99501296.96211736.92935126.89671376.86420436.831822

6.79956616.767436

6.73543096.70355

6.67179276.64015826.60864586.57725476.54598446.51483416.48380316.45289086.42209636.39141926.36085876.33041416.30008486.26987026.23976956.20978226.17990756.150145

6.12049396.09095366.06152356.03220296.00299145.97388825.94489275.91600445.88722275.858547

5.82997675.80151115.77314995.74489235.71673785.6886858

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5.66073585.63288725.60513955.57749225.54994465.52249635.49514665.46789525.44074145.41368475.38672465.35986065.33309225.30641895.27984015.25335545.22696425.20066615.17446065.14834725.12232545.09639465.07055465.0448047

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Reburn, William T.; Gale, William A.The system lithium oxide – boric oxide – waterThe Journal of Physical Chemistry 1955, 59 (1), 19-24

t w% w% solidC LiOH H3BO3

0 0.4236099 1.0937202 LiBO2.8H2O0 0.6230712 3.2174206 Li2B4O7.3H2O

10 10.755451 0.8881598 LiBO2.8H2O+LiOH.H2O10 10.691335 0.8881598 LiBO2.8H2O+LiOH.H2O10 7.8702332 0.728291 LiBO2.8H2O10 3.0134498 0.817107 LiBO2.8H2O10 0.6835523 1.7648666 LiBO2.8H2O10 0.6732175 1.7763196 LiBO2.8H2O10 0.7693914 2.5934266 LiBO2.8H2O10 0.8495364 3.3394809 Li2B4O7.3H2O+LiBO2.8H2O10 0.8495364 3.3750072 Li2B4O7.3H2O+LiBO2.8H2O10 0.7221962 3.7292829 Li2B4O7.3H2O10 0.7213045 3.7302712 Li2B4O7.3H2O10 1.4746669 15.365165 Li2B4O7.3H2O10 1.6028988 17.301353 Li2B4O7.3H2O+H3BO310 1.6028988 17.478985 Li2B4O7.3H2O+H3BO3

0 10 20 30 40 50 60 70 80 900

10

20Column B Column B Column B Column B

Column B Column B Column B Column B

Column B Column B Column B Column G

Column G Column G Column G Column G

Column G Column G Column G Column G

w% H3BO3

w%

LiO

H

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10 1.2502611 14.636874 H3BO320 11.188234 2.0782939 LiBO2.8H2O+LiOH.H2O20 11.124118 2.0960571 LiBO2.8H2O+LiOH.H2O20 7.9183201 1.7763196 LiBO2.8H2O20 3.5584354 1.8651356 LiBO2.8H2O20 1.2082509 3.1195882 LiBO2.8H2O20 1.1861451 3.1440857 LiBO2.8H2O20 1.362464 4.2098775 Li2B4O7.3H2O+LiBO2.8H2O20 1.346435 4.1921143 Li2B4O7.3H2O+LiBO2.8H2O20 0.9777683 3.6592184 Li2B4O7.3H2O20 0.7958319 4.1095236 Li2B4O7.3H2O20 0.7854204 4.1210615 Li2B4O7.3H2O20 0.8014494 5.3289588 Li2B4O7.3H2O20 1.6509858 18.17175 Li2B4O7.3H2O20 1.9395076 21.759915 LiB5O8.5H2O+Li2B4O7.3H2O20 1.9395076 21.848731 LiB5O8.5H2O+Li2B4O7.3H2O20 1.8914206 21.653336 LiB5O8.5H2O+H3BO320 1.8914206 21.724389 LiB5O8.5H2O+H3BO320 1.8753916 21.61781 LiB5O8.5H2O+H3BO320 1.6670148 19.734911 H3BO330 11.701161 3.6414552 LiBO2.2H2O+LiOH.H2O30 11.701161 3.6414552 LiBO2.2H2O+LiOH.H2O30 10.915741 3.7835608 LiBO2.2H2O30 9.9540016 4.0500087 LiBO2.2H2O30 11.925567 5.2401428 LiBO2.8H2O (metastable)+LiOH.H2O30 11.941596 5.4000116 LiBO2.8H2O (metastable)+LiOH.H2O30 10.755451 5.0980373 LiBO2.8H2O (metastable)30 9.489161 4.7250101 LiBO2.8H2O (metastable)30 8.7999145 4.3875094 LiBO2.2H2O30 6.2673344 4.2098775 LiBO2.8H2O30 4.3919427 4.351983 LiBO2.8H2O30 2.7730149 4.9736949 LiBO2.8H2O30 2.2287657 5.7544595 LiBO2.8H2O30 2.2120004 5.7730387 LiBO2.8H2O30 2.3402323 6.5723825 Li2B4O7.3H2O+LiBO2.8H2O30 2.5486091 7.7980431 LiBO2.8H2O30 1.5067249 4.618431 Li2B4O7.3H2O30 5.465885 24.406631 LiBO2.8H2O30 0.8524747 4.4020163 Li2B4O7.3H2O30 0.8495364 4.4052726 Li2B4O7.3H2O30 6.3795373 47.676418 LiB5O8.5H2O30 1.0899712 10.000679 Li2B4O7.3H2O30 2.0036235 22.861233 Li2B4O7.3H2O30 2.2120004 25.738871 LiB5O8.5H2O30 2.2280293 26.005319 LiB5O8.5H2O+Li2B4O7.3H2O30 2.2120004 25.880977 LiB5O8.5H2O+Li2B4O7.3H2O30 2.0997974 25.330318 LiB5O8.5H2O+H3BO330 2.0837685 25.330318 LiB5O8.5H2O+H3BO330 2.0677395 25.383607 LiB5O8.5H2O+H3BO330 0.9617393 15.400691 H3BO334 2.873808 7.4198971 LiBO2.8H2O35 3.0856129 7.9667572 LiBO2.8H2O36 3.2926041 8.5011886 LiBO2.8H2O

36.9 3.4658991 8.9486196 LiBO2.8H2O+LiBO2.2H2O

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36.9 3.4658991 8.9486196 LiBO2.2H2O+LiBO2.8H2O37 3.4947816 9.0231914 LiBO2.2H2O38 3.5284778 9.1101919 LiBO2.2H2O39 3.5332916 9.1226205 LiBO2.2H2O40 12.117915 4.1210615 LiBO2.2H2O+LiOH.H2O40 12.117915 4.1565879 LiBO2.2H2O+LiOH.H2O40 8.9762334 4.9381685 LiBO2.2H2O40 5.9948416 6.252645 LiBO2.2H2O40 4.5249238 11.68292 LiBO2.8H2O40 3.5621741 9.1971923 LiBO2.2H2O40 3.7507832 10.000679 Li2B4O7.3H2O+LiBO2.2H2O40 3.7187252 9.9829162 Li2B4O7.3H2O+LiBO2.2H2O40 2.1158264 6.0927762 Li2B4O7.3H2O40 0.9232783 4.7676323 Li2B4O7.3H2O40 0.9136523 4.7782997 Li2B4O7.3H2O40 1.2662901 12.771738 Li2B4O7.3H2O40 2.2761163 26.875716 Li2B4O7.3H2O40 2.5325801 30.250723 LiB5O8.5H2O+Li2B4O7.3H2O40 2.5005221 30.268486 LiB5O8.5H2O+Li2B4O7.3H2O40 2.2921453 29.327037 LiB5O8.5H2O+H3BO340 2.2921453 29.3448 LiB5O8.5H2O+H3BO340 1.9875945 26.7869 H3BO345 2.4418875 31.523599 LiB5O8.5H2O50 3.773979 9.7440524 LiBO2.2H2O50 2.6459061 34.157381 LiB5O8.5H2O60 13.288031 5.7375123 LiBO2.2H2O+LiOH.H2O60 13.175828 5.7375123 LiBO2.2H2O+LiOH.H2O60 9.425045 6.3059346 LiBO2.2H2O60 6.1391025 7.7092271 LiBO2.2H2O60 4.0579902 10.477342 LiBO2.2H2O60 4.039305 10.498049 LiBO2.2H2O60 4.2316529 11.492788 Li2B4O7.3H2O+LiBO2.2H2O60 4.2156239 11.475025 Li2B4O7.3H2O+LiBO2.2H2O60 2.9172758 8.1888334 Li2B4O7.3H2O60 1.0648854 5.4988643 Li2B4O7.3H2O60 1.0579132 5.5065908 Li2B4O7.3H2O60 1.0258552 6.6789617 Li2B4O7.3H2O60 2.9172758 36.432315 Li2B4O7.3H2O60 3.2057976 40.322455 LiB5O8.5H2O+Li2B4O7.3H2O60 3.2057976 40.357981 LiB5O8.5H2O+Li2B4O7.3H2O60 3.0935947 39.807322 LiB5O8.5H2O60 3.0843561 39.81756 LiB5O8.5H2O60 2.7730149 38.84811 LiB5O8.5H2O+H3BO360 2.7730149 39.043505 LiB5O8.5H2O+H3BO360 2.7730149 39.132321 LiB5O8.5H2O+H3BO360 2.3402323 36.077051 H3BO370 4.5634338 11.782349 LiBO2.2H2O70 3.5456156 45.7722 LiB5O8.5H2O80 15.195481 8.2954125 LiBO2.2H2O+LiOH.H2O80 15.195481 8.3664653 LiBO2.2H2O+LiOH.H2O80 11.348524 8.4197549 LiBO2.2H2O80 5.1933922 11.190814 LiBO2.2H2O80 5.0929462 13.149499 LiBO2.2H2O80 5.0491313 13.162528 LiBO2.2H2O

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80 5.0491313 13.819767 Li2B4O7.3H2O+LiBO2.2H2O80 5.0651602 13.926346 Li2B4O7.3H2O+LiBO2.2H2O80 3.6866673 10.320417 Li2B4O7.3H2O80 1.2342321 6.3592242 Li2B4O7.3H2O80 1.2319818 6.361718 Li2B4O7.3H2O80 1.362464 12.398711 Li2B4O7.3H2O80 3.7187252 47.605365 Li2B4O7.3H2O80 4.055334 52.348139 LiB5O8.5H2O+Li2B4O7.3H2O80 4.0284174 52.00494 LiB5O8.5H2O80 3.9591601 52.081691 LiB5O8.5H2O80 3.9271021 52.24156 LiB5O8.5H2O+Li2B4O7.3H2O80 3.3500585 50.962609 LiB5O8.5H2O+H3BO380 3.3180005 50.998136 LiB5O8.5H2O+H3BO380 3.0294788 48.084972 H3BO3

100 1.4642174 7.5609384 Li2B4O7.3H2O101.2 6.4504233 16.654375 LiBO2.2H2O

Rollet, A. P.; Bouaziz, R.Compt. rend. 1955, 240, 1229

t w% w% solidC LiOH H3BO3

30 12.085857 4.7605365 LiOH.H2O+LiBO2.8H2O30 2.660812 6.7500145 LiBO2.8H2O+Li2B4O7.4H2O30 2.3402323 27.159927 LiB5O8.5H2O+Li2B4O7.4H2O30 0.6571885 12.789501 LiB5O8.5H2O+H3BO3

Bouaziz, R.Ann. Chim. 1961, 6, 345-393Annales di chimie, ser. 13 (Masson)

t w% w% solidC LiOH H3BO3

30 11.156176 0 LiOH.H2O30 11.460727 1.7763196 LiOH.H2O30 11.701161 2.9309273 LiOH.H2O30 11.781306 3.8368503 LiOH.H2O+LiBO2.2H2O30 12.101886 4.7960629 LiOH.H2O+LiBO2.8H2O (metastable)30 10.739422 4.440799 LiBO2.8H2O (metastable)30 9.6173929 4.618431 LiBO2.8H2O (metastable)30 10.258552 4.0855351 LiBO2.2H2O30 8.6556536 4.6539574 LiBO2.2H2O+LiBO2.8H2O30 7.6137694 4.440799 LiBO2.8H2O30 7.4534795 4.440799 LiBO2.8H2O30 7.2130447 4.440799 LiBO2.8H2O30 5.2575081 4.351983 LiBO2.8H2O30 4.7285515 4.440799 LiBO2.8H2O30 4.3278268 4.529615 LiBO2.8H2O30 3.5263774 4.7960629 LiBO2.8H2O30 2.3081743 5.9684339 LiBO2.8H2O30 2.6127251 6.7500145 LiBO2.8H2O+Li2B4O7.4H2O30 2.5646381 7.1940944 LiBO2.8H2O (metastable)30 2.724928 7.6381743 LiBO2.8H2O (metastable)

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30 2.8852179 9.7697578 LiBO2.8H2O (metastable)30 3.0455077 10.800023 LiBO2.8H2O (metastable)30 4.8086964 20.960571 LiBO2.8H2O (metastable)30 2.4043482 6.6611985 LiBO2.2H2O30 1.7631887 4.7960629 LiBO2.2H2O30 1.6509858 4.7072469 LiBO2.2H2O30 1.1220292 4.0855351 Li2B4O7.4H2O30 0.9617393 4.0855351 Li2B4O7.4H2O30 0.8655654 4.4585622 Li2B4O7.4H2O30 0.9617393 5.8618547 Li2B4O7.4H2O30 0.9617393 6.6611985 Li2B4O7.4H2O30 1.0899712 8.3487021 Li2B4O7.4H2O30 1.1220292 9.6809418 Li2B4O7.4H2O30 1.2502611 11.190814 Li2B4O7.4H2O30 1.2823191 12.523053 Li2B4O7.4H2O30 1.4426089 14.743453 Li2B4O7.4H2O30 1.5708408 15.720428 Li2B4O7.4H2O30 1.6830438 18.651356 Li2B4O7.4H2O30 2.0517105 22.914523 Li2B4O7.4H2O30 2.0837685 23.625051 Li2B4O7.4H2O30 2.2440583 25.579002 Li2B4O7.4H2O30 2.3242033 26.28953 Li2B4O7.4H2O30 2.3242033 27.532954 Li2B4O7.4H2O+LiB5O8.5H2O30 2.0837685 25.756634 LiB5O8.5H2O+H3BO330 2.0837685 25.223738 H3BO330 1.9234786 23.980315 H3BO330 1.6830438 22.203995 H3BO330 1.4426089 20.516491 H3BO330 1.1220292 18.11846 H3BO330 0.8014494 13.855293 H3BO330 0.6411595 11.190814 H3BO330 0 6.2171186 H3BO356 11.893509 0 LiOH.H2O56 11.957625 0.8881598 LiOH.H2O56 12.230118 1.7763196 LiOH.H2O56 12.98348 5.0625109 LiOH.H2O56 13.063625 5.4177748 LiOH.H2O+LiBO2.2H2O56 12.149973 5.5954068 LiBO2.2H2O56 10.627219 5.7730387 LiBO2.2H2O56 9.9379726 5.9506707 LiBO2.2H2O56 8.3350738 6.3947506 LiBO2.2H2O56 7.9503781 6.5723825 LiBO2.2H2O56 5.369711 7.9934382 LiBO2.2H2O56 5.0811892 8.2598862 LiBO2.2H2O56 3.991218 10.302654 LiBO2.2H2O56 4.071363 10.83555 LiBO2.2H2O56 4.1675369 11.546077 LiBO2.2H2O+Li2B4O7.4H2O56 3.4462324 9.4144939 Li2B4O7.4H2O56 2.0036235 6.2171186 Li2B4O7.4H2O56 1.0899712 5.3289588 Li2B4O7.4H2O56 1.0418842 7.9046222 Li2B4O7.4H2O56 1.362464 13.233581 Li2B4O7.4H2O56 1.8112757 21.404651 Li2B4O7.4H2O56 2.3242033 27.710586 Li2B4O7.4H2O

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56 2.5646381 30.552697 Li2B4O7.4H2O56 2.69287 33.394809 Li2B4O7.4H2O56 2.8852179 35.34876 Li2B4O7.4H2O56 3.0134498 36.148104 Li2B4O7.4H2O56 3.0455077 36.947448 Li2B4O7.4H2O56 3.1256527 38.190871 Li2B4O7.4H2O56 3.2057976 38.723767 Li2B4O7.4H2O+LiB5O8.5H2O56 2.9813918 38.368503 LiB5O8.5H2O56 2.724928 38.01324 LiB5O8.5H2O+H3BO356 2.724928 37.302712 H3BO356 2.644783 36.947448 H3BO356 2.0837685 31.618489 H3BO356 1.7631887 28.332298 H3BO356 1.4426089 24.868474 H3BO356 1.2182031 23.625051 H3BO356 0.9617393 20.960571 H3BO356 0.6411595 17.67438 H3BO356 0.4488117 15.631613 H3BO356 0.3205798 14.565821 H3BO356 0.3205798 14.477005 H3BO356 0 11.812525 H3BO3

100 15.067249 0 LiOH.H2O100 15.868698 3.7302712 LiOH.H2O100 16.189278 4.263167 LiOH.H2O100 16.670148 5.5065908 LiOH.H2O100 16.910582 6.8388305 LiOH.H2O100 16.990727 6.6611985 LiOH.H2O100 17.631887 8.3487021 LiOH.H2O100 18.112757 10.302654 LiOH.H2O100 18.273046 11.368445 LiOH.H2O100 18.753916 13.322397 LiOH.H2O100 19.875945 15.453981 LiOH.H2O+LiBO2.2H2O100 16.990727 13.500029 LiBO2.2H2O100 14.826814 12.611869 LiBO2.2H2O100 13.384205 12.700685 LiBO2.2H2O100 13.223915 12.789501 LiBO2.2H2O100 12.98348 12.611869 LiBO2.2H2O100 12.662901 12.434237 LiBO2.2H2O100 11.861451 12.078973 LiBO2.2H2O100 8.0144941 11.190814 LiBO2.2H2O100 7.9343491 10.569102 LiBO2.2H2O100 6.4115953 11.190814 LiBO2.2H2O100 4.8086964 12.434237 LiBO2.2H2O100 5.9307256 16.519772 LiBO2.2H2O metastable100 6.5718851 18.384908 LiBO2.2H2O metastable100 6.8924649 19.273068 LiBO2.2H2O metastable100 7.3733345 19.539516 LiBO2.2H2O metastable100 7.4534795 19.983596 LiBO2.2H2O metastable100 4.8086964 13.322397 LiBO2.2H2O+Li2B4O7.4H2O100 4.4881167 12.256605 Li2B4O7.4H2O100 4.3278268 11.901341 Li2B4O7.4H2O100 4.1675369 11.723709 Li2B4O7.4H2O100 3.6866673 10.746734 Li2B4O7.4H2O100 1.6028988 8.3487021 Li2B4O7.4H2O

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100 1.5708408 8.1355438 Li2B4O7.4H2O100 1.4426089 11.013182 Li2B4O7.4H2O100 2.0837685 24.157947 Li2B4O7.4H2O100 2.1639134 25.756634 Li2B4O7.4H2O100 3.8469572 48.671157 Li2B4O7.4H2O100 4.007247 50.092213 Li2B4O7.4H2O100 4.8086964 60.75013 Li2B4O7.4H2O100 5.0491313 64.30277 Li2B4O7.4H2O100 5.6101458 69.276465 Li2B4O7.4H2O+LiB5O8.5H2O100 5.2414791 67.411329 LiB5O8.5H2O100 4.6484066 64.835666 LiB5O8.5H2O100 4.3278268 63.41461 LiB5O8.5H2O100 4.3278268 62.171186 LiB5O8.5H2O100 3.8469572 58.618547 LiB5O8.5H2O+H3BO3100 2.8050729 46.361942 H3BO3100 1.2021741 38.190871 H3BO3100 0.7213045 34.105336 H3BO3100 0.4808696 31.618489 H3BO3100 0 28.421114 H3BO3

Dukelski, M. P.Über BorateZeitschrift für anorganische Chemie 1906, 50 (1), 38-48

w% w%LiOH H3BO3

30 11.236321 0 LiOH.H2O30 11.989683 4.1921143 LiOH.H2O30 12.03777 5.2934324 LiOH.H2O30 12.35835 6.0039603 LiOH.H2O+LiBO2.8H2O30 12.310263 6.3236978 LiBO2.8H2O30 8.6556536 4.9381685 LiBO2.8H2O30 5.5620589 4.2986934 LiBO2.8H2O30 5.3216241 4.5473782 LiBO2.8H2O30 4.8728124 4.5829046 LiBO2.8H2O30 4.7125225 4.4585622 LiBO2.8H2O30 2.5325801 5.8085651 LiBO2.8H2O30 3.4622614 12.452 LiBO2.8H2O30 3.4782904 12.256605 LiBO2.8H2O30 5.8666097 26.254004 LiBO2.8H2O30 6.6680591 29.540195 LiBO2.8H2O30 8.3671318 38.510609 LiBO2.8H2O30 8.4152188 39.079031 LiBO2.8H2O30 9.1044653 41.992195 LiBO2.8H2O30 9.0243203 42.347459 LiBO2.8H2O30 2.9012469 11.013182 Li2B4O7.3H2O amorphous30 2.1158264 5.9684339 Li2B4O7.3H2O amorphous30 1.5227539 4.6361942 Li2B4O7.3H2O amorphous30 1.378493 4.3875094 Li2B4O7.3H2O amorphous30 1.1220292 4.440799 Li2B4O7.3H2O amorphous30 0.8495364 4.3875094 Li2B4O7.3H2O amorphous30 3.4782904 23.394129 Li2B4O7.3H2O amorphous30 3.5424064 23.696104 Li2B4O7.3H2O amorphous30 4.071363 26.875716 Li2B4O7.3H2O amorphous

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30 4.1835659 29.113878 Li2B4O7.3H2O amorphous30 8.142726 54.728407 LiB5O8.5H2O30 7.9984651 53.715905 LiB5O8.5H2O30 7.6778853 53.289588 LiB5O8.5H2O30 7.3252476 51.211294 LiB5O8.5H2O30 6.5718851 48.084972 LiB5O8.5H2O30 5.1613342 40.748772 LiB5O8.5H2O30 2.4844932 27.355322 LiB5O8.5H2O30 2.1318554 25.294791 LiB5O8.5H2O30 2.0837685 25.117159 LiB5O8.5H2O+H3BO330 1.5387829 20.374386 H3BO330 1.4426089 16.146745 H3BO330 1.0098263 8.6151501 H3BO330 1.0258552 8.2954125 H3BO330 0 6.2881714 H3BO3

t w% H3BO3 w%LiOH10 0 10.849919 10 0 10.83464810 0.3385765 10.914884 10 0.338687 10.89984110 0.663209 10.977512 10 0.6634213 10.9626810 0.8164152 11.007184 10 0.8090579 10.99096910 0.8066613 10.839831 10 0.7998945 10.83949510 0.7971689 10.670519 10 0.790048 10.6701410 0.7881376 10.502791 10 0.7806996 10.5023510 0.7795496 10.336583 10 0.7718248 10.3360810 0.7713886 10.17191 10 0.7634065 10.17134310 0.7636415 10.008734 10 0.7554315 10.00811910 0.7563006 9.8470577 10 0.7478765 9.846378810 0.7493445 9.6868487 10 0.7407349 9.686110310 0.742767 9.5281027 10 0.7339831 9.527313310 0.7365543 9.3708208 10 0.727616 9.369956810 0.7306992 9.2149515 10 0.7216133 9.214032210 0.7251902 9.0604911 10 0.7159691 9.059517110 0.7200143 8.9074489 10 0.7106686 8.906418210 0.7151709 8.7557843 10 0.7057059 8.754701810 0.7106423 8.6054913 10 0.7010678 8.604347910 0.706425 8.4565655 10 0.696743 8.455355310 0.702514 8.3089711 10 0.6927293 8.307704510 0.6988958 8.1627023 10 0.6890153 8.161382210 0.6955705 8.0177587 10 0.6855954 8.016370110 0.6925322 7.8740987 10 0.6824648 7.872659510 0.689773 7.7317231 10 0.6796151 7.730228810 0.6872882 7.5906401 10 0.6770416 7.58908310 0.6850764 7.4508091 10 0.6747395 7.449187810 0.6831291 7.3122139 10 0.6727071 7.31052810 0.6814489 7.1748703 10 0.670937 7.173117210 0.6800276 7.0387298 10 0.6694315 7.036921510 0.6788638 6.9038021 10 0.668182 6.9019410 0.6779601 6.7700733 10 0.667191 6.768153610 0.6773127 6.6375354 10 0.6664548 6.635549110 0.6769163 6.5061689 10 0.6659751 6.5041266

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10 0.6767762 6.3759666 10 0.6657471 6.37384810 0.6768932 6.2469031 10 0.6657746 6.244732810 0.6772618 6.1189992 10 0.6660589 6.116749610 0.6778877 5.9922112 10 0.6665999 5.989899910 0.6787747 5.8665398 10 0.6673967 5.864177710 0.6799172 5.7419891 10 0.6684585 5.739558910 0.6813254 5.6185418 10 0.6697814 5.616044610 0.6830022 5.4961744 10 0.6713712 5.493624210 0.6849457 5.3748985 10 0.6732312 5.372272310 0.6871665 5.2546975 10 0.6753704 5.252017810 0.6896707 5.1355622 10 0.6777914 5.132816910 0.6924603 5.0174792 10 0.6805006 5.014665610 0.695542 4.9004588 10 0.6835083 4.897577610 0.6989284 4.7844748 10 0.6868157 4.781538910 0.7026227 4.6695379 10 0.6904375 4.66654210 0.7066407 4.5556357 10 0.6943818 4.552573310 0.7109859 4.4427532 10 0.6986597 4.43962510 0.7156747 4.3308963 10 0.7032828 4.327710710 0.7207193 4.2200671 10 0.7082649 4.216817910 0.7261293 4.1102465 10 0.7136196 4.106933710 0.7319287 4.0014452 10 0.7193654 3.998072710 0.7381263 3.8936534 10 0.725516 3.890222210 0.7447466 3.7868733 10 0.7320919 3.783382610 0.7518038 3.6810874 10 0.7391114 3.677555810 0.7593267 3.576328 10 0.7466018 3.572742510 0.7673332 3.4725825 10 0.7545833 3.468942610 0.7758515 3.3698395 10 0.7630888 3.366162310 0.784913 3.2681263 10 0.7721409 3.264398410 0.794545 3.1674286 10 0.7817738 3.163651310 0.8047881 3.0677576 10 0.7920264 3.063953610 0.8156776 2.9691315 10 0.8029326 2.965279110 0.8272509 2.8715493 10 0.8145388 2.867663910 0.8395603 2.7750163 10 0.8268913 2.77111810 0.85265 2.6795732 10 0.8400409 2.675640910 0.8665792 2.5851997 10 0.8540393 2.581253310 0.8814082 2.4919334 10 0.8689538 2.487980810 0.8971995 2.3997964 10 0.8848514 2.395835710 0.9140328 2.3088106 10 0.901804 2.30485210 0.9319814 2.2190009 10 0.9198958 2.215044310 0.9511387 2.130391 10 0.9392185 2.126459510 0.9716037 2.0430427 10 0.9598661 2.039125210 0.9934783 1.9569521 10 0.9819565 1.953075210 1.0168886 1.8721954 10 1.0056043 1.868364910 1.041958 1.7888253 10 1.030942 1.785052710 1.0688332 1.7068749 10 1.0581174 1.703166910 1.0976714 1.6264111 10 1.0872884 1.622797610 1.128641 1.5475198 10 1.1186272 1.544005310 1.1619284 1.4702541 10 1.1523264 1.46685710 1.1977384 1.3947146 10 1.188583 1.391456810 1.2362853 1.3209918 10 1.2276201 1.317874410 1.2777975 1.2491719 10 1.2696684 1.246225510 1.3225218 1.1793682 10 1.3149715 1.176608710 1.3707083 1.111689 10 1.3637859 1.109138810 1.4226198 1.0462512 10 1.416362 1.04393

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10 1.4785066 0.9831728 10 1.4729579 0.981099410 1.5386259 0.922572 10 1.5338251 0.920764510 1.6032131 0.8645657 10 1.5991901 0.863040510 1.6724865 0.8092622 10 1.6692686 0.808033110 1.7466893 0.7567841 10 1.7442877 0.7558610 1.762171 0.7466491 10 1.759927 0.745784610 1.777902 0.736648 10 1.7758209 0.735845910 1.7939689 0.7268162 10 1.7920388 0.726071410 1.8107636 0.7173052 10 1.8089651 0.716609910 1.82021 0.7129712 10 1.8184505 0.712289110 1.8334556 0.7101175 10 1.8316998 0.709437410 1.8545334 0.7103124 10 1.8528379 0.709654710 1.8796885 0.7121058 10 1.8780541 0.711471310 1.90626 0.7144668 10 1.9046732 0.713850510 1.9334775 0.7170996 10 1.9319392 0.716501510 1.9610672 0.7198954 10 1.9595719 0.719313910 1.9888888 0.7228012 10 1.9874304 0.722235110 2.0168616 0.7257865 10 2.0154439 0.725236310 2.0449365 0.7288336 10 2.0435658 0.72829810 2.0730855 0.7319281 10 2.0717536 0.731407710 2.1012829 0.7350602 10 2.0999933 0.734556410 2.1295143 0.7382274 10 2.1282584 0.737737510 2.1577594 0.7414191 10 2.1565464 0.74094510 2.1860155 0.7446359 10 2.1848408 0.744176410 2.2142668 0.7478715 10 2.2131298 0.747427110 2.2425108 0.7511244 10 2.2414156 0.750695810 2.270744 0.7543913 10 2.2696907 0.753979210 2.2989582 0.7576723 10 2.2979408 0.75727410 2.3271495 0.7609655 10 2.3261719 0.760582210 2.3553172 0.7642673 10 2.3543782 0.763899310 2.3834588 0.7675795 10 2.382559 0.767226410 2.4396382 0.7742241 10 2.4388204 0.773902510 2.4956844 0.7808944 10 2.4949427 0.780602210 2.5515755 0.7875836 10 2.5509139 0.787322810 2.6073023 0.7942873 10 2.6067185 0.794057810 2.6628613 0.8010027 10 2.6623561 0.800803310 2.8009624 0.8178185 10 2.800657 0.817696410 2.9378783 0.8346452 10 2.9377694 0.834601510 3.0735509 0.8514567 10 3.0736469 0.851493410 3.1750845 0.8641194 10 3.1745373 0.864117810 3.1754732 0.8569222 10 3.1749338 0.856819610 3.1804964 0.8384377 10 3.1799668 0.838335510 3.1913148 0.8212097 10 3.1907786 0.821106210 3.2078863 0.8052329 10 3.2073347 0.805126910 3.2301497 0.7904979 10 3.2295736 0.790387510 3.2579904 0.7769829 10 3.2573815 0.776865410 3.291282 0.7646649 10 3.2906319 0.764540510 3.329858 0.7535133 10 3.3291626 0.75337910 3.3735235 0.7434923 10 3.3727739 0.743348110 3.4220688 0.734561 10 3.4212649 0.734406210 3.4752683 0.7266768 10 3.4744061 0.726510510 3.5328724 0.719794 10 3.5319456 0.719615510 3.5946392 0.7138637 10 3.5936423 0.713671510 3.6602918 0.7088367 10 3.6592308 0.708631

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10 3.7295934 0.7046619 10 3.7284573 0.704442610 3.8022628 0.7012911 10 3.8010553 0.701055210 3.8780674 0.6986728 10 3.8767674 0.698421910 3.9567383 0.6967594 10 3.95536 0.696491710 4.0380466 0.6955056 10 4.0365689 0.695218210 4.1217511 0.6948623 10 4.1201694 0.694554410 4.2076423 0.6947886 10 4.2059401 0.694458410 4.2954884 0.6952422 10 4.2936665 0.694888410 4.3851 0.6961829 10 4.383147 0.695801910 4.4762968 0.6975733 10 4.4742058 0.697164810 4.5689056 0.6993799 10 4.5666528 0.698940310 4.6627465 0.7015678 10 4.6603236 0.701094610 4.7576655 0.7041076 10 4.7550734 0.703598810 4.8535361 0.7069703 10 4.8507431 0.706423910 4.9502227 0.7101288 10 4.9472276 0.709541810 5.0476004 0.7135569 10 5.0443829 0.712927510 5.1455391 0.7172334 10 5.1421071 0.716558610 5.2439722 0.7211372 10 5.2402981 0.720415310 5.3427766 0.7252453 10 5.3388508 0.724474710 5.4418702 0.7295422 10 5.4376911 0.728720210 5.9391034 0.7532917 10 5.9335038 0.752185310 6.4340139 0.7796624 10 6.4268046 0.778234310 6.9215589 0.8075008 10 6.9126227 0.805724510 7.3986145 0.8360355 10 7.3878839 0.83389510 7.8633601 0.8647503 10 7.8507764 0.862232810 8.314788 0.8933015 10 8.3003371 0.89040210 8.7524425 0.9214635 10 8.736125 0.918177710 9.1762523 0.9490891 10 9.1580534 0.945417110 9.5863541 0.9760879 10 9.5662941 0.9720310 9.9830534 1.0024074 10 9.9611518 0.997963510 10.366719 1.028016 10 10.342988 1.023189410 10.737816 1.052906 10 10.712273 1.047698510 11.09678 1.0770757 10 11.069484 1.071493510 11.444137 1.1005374 10 11.415065 1.094582910 11.780329 1.123306 10 11.749545 1.116982610 12.105816 1.1453978 10 12.073345 1.138712110 12.413469 1.1663149 10 12.138109 1.143062110 12.41346 1.1663138 10 12.138109 1.143062110 12.413469 1.1663149 10 12.138109 1.143062110 12.41346 1.1663138 10 12.138109 1.143062110 12.413469 1.1663149 10 12.138109 1.143062110 11.997337 1.1100358 10 11.905208 1.111196810 11.568829 1.0521948 10 11.4808 1.053240510 11.18198 1.0000913 10 11.097665 1.001041110 10.831002 0.9529117 10 10.750005 0.953777410 10.51106 0.9099889 10 10.433067 0.910781810 10.218243 0.8707708 10 10.142953 0.871500610 9.9491894 0.8347975 10 9.8763683 0.835473210 9.7010909 0.8016821 10 9.6305493 0.802307910 9.471606 0.7710962 10 9.4031488 0.771679110 9.2587094 0.7427602 10 9.1921777 0.743305210 9.0606397 0.7164361 10 8.9958553 0.716947210 8.8759047 0.6919158 10 8.8127719 0.692394710 8.7032022 0.6690193 10 8.6415707 0.66947

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10 8.541385 0.6475906 10 8.4811514 0.648017110 8.3894138 0.6274935 10 8.3305255 0.627896810 8.2464949 0.6086061 10 8.1888224 0.608988710 8.1117626 0.590825 10 8.0552742 0.591187910 7.9845809 0.5740541 10 7.9291804 0.574399610 7.8642935 0.5582086 10 7.8099094 0.558538510 7.7504189 0.5432157 10 7.6969629 0.543530510 7.6423831 0.5290067 10 7.5898286 0.52930810 7.5397776 0.515523 10 7.488099 0.515810710 7.4422043 0.5027103 10 7.3913335 0.502986410 7.3492861 0.4905193 10 7.299201 0.490784610 7.2607189 0.4789053 10 7.2113467 0.479161210 7.1762043 0.46783 10 7.1275164 0.468074610 6.5036253 0.3799628 10 6.4603228 0.380138510 6.0416727 0.3198897 10 6.0019488 0.320024610 5.7047997 0.2762216 10 5.6676049 0.276330910 5.4482033 0.2430461 10 5.412947 0.243136310 5.2462848 0.2169856 10 5.2124663 0.21706310 5.0832077 0.1959731 10 5.0505832 0.196040510 4.9487808 0.1786715 10 4.9171069 0.178730710 4.8360508 0.1641768 10 4.8051752 0.164230210 4.7401596 0.1518574 10 4.7099646 0.151904910 4.6576173 0.1412581 10 4.6279804 0.141301710 4.5857577 0.1320419 10 4.5566238 0.132082310 4.5226994 0.1239547 10 4.4940041 0.123991910 4.4668827 0.116801 10 4.4385675 0.116835610 4.4171526 0.1104279 10 4.3891606 0.110460310 4.3725345 0.1047145 10 4.3448326 0.104744910 4.3322766 0.0995631 10 4.3048693 0.099591710 3.631666 0.010103 10 3.6088566 0.010105410 3.5606433 0.0010118 10 3.538282 0.00101210 3.5540679 0 10 3.5317566 1.012E-0820 0 10.964277 20 0 10.91644620 0.4566531 11.050956 20 0.4571198 11.00364420 0.8973258 11.135209 20 0.8982422 11.08835920 1.3228334 11.217107 20 1.3241741 11.17071120 1.7339298 11.296743 20 1.73567 11.25076820 2.1313194 11.3742 20 2.133446 11.3286220 2.1624367 11.380288 20 2.1496664 11.3318120 2.1506974 11.306823 20 2.1454409 11.30663320 2.1283985 11.163933 20 2.1219359 11.16368220 2.1067167 11.020485 20 2.0991242 11.02014220 2.0856473 10.876441 20 2.0770079 10.87601620 2.0651989 10.73184 20 2.0555798 10.73131420 2.0453706 10.586668 20 2.034843 10.58605320 2.0261645 10.440964 20 2.0147859 10.44023420 2.007578 10.294691 20 1.9954065 10.29385920 1.9896207 10.147884 20 1.976709 10.14693920 1.9722898 10.000542 20 1.9586826 9.999467120 1.9555921 9.8526636 20 1.9413322 9.851481620 1.939527 9.7042743 20 1.9246511 9.702956120 1.9241013 9.5553662 20 1.9086424 9.553920620 1.9093126 9.4059567 20 1.8933056 9.404385820 1.8951722 9.2560412 20 1.8786397 9.2543406

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20 1.8816789 9.1056301 20 1.8646435 9.103803120 1.8688428 8.9547536 20 1.8513278 8.952769920 1.8566642 8.8034014 20 1.8386863 8.801269420 1.8451518 8.65157 20 1.8267224 8.649293320 1.834314 8.499282 20 1.8154514 8.49686120 1.8241541 8.3465441 20 1.8048692 8.343977920 1.8146909 8.1933773 20 1.7949822 8.190649820 1.8059241 8.0397693 20 1.7858051 8.036881320 1.797867 7.8857411 20 1.7773464 7.882700620 1.7905366 7.731307 20 1.7696137 7.72809220 1.7839435 7.5764743 20 1.7626218 7.573086120 1.7781039 7.4212551 20 1.7563821 7.417696920 1.7730328 7.2656638 20 1.750919 7.261925620 1.7687541 7.1097044 20 1.7462391 7.105779320 1.7652826 6.9533992 20 1.7423736 6.949299220 1.7626489 6.7967568 20 1.7393399 6.792459520 1.7608745 6.6398134 20 1.7371666 6.635314820 1.759989 6.4825582 20 1.735881 6.477852920 1.7600248 6.32502 20 1.7355213 6.320112920 1.7610176 6.1672147 20 1.7361163 6.162103620 1.7630107 6.0091838 20 1.737714 6.003850720 1.766046 5.8509175 20 1.7403585 5.845381520 1.770172 5.6924698 20 1.7440954 5.686703820 1.775443 5.5338637 20 1.748985 5.527869120 1.7819262 5.3751191 20 1.7550914 5.368903920 1.7896822 5.2162787 20 1.7624849 5.209834320 1.798792 5.0573651 20 1.7712433 5.050692620 1.8093407 4.8984496 20 1.7814567 4.891543520 1.8214214 4.7395417 20 1.7932223 4.732405320 1.8351445 4.5807198 20 1.8066514 4.573348220 1.8506297 4.422024 20 1.8218683 4.414436520 1.8680081 4.263528 20 1.8390148 4.255717820 1.8874313 4.1052975 20 1.8582496 4.097286820 1.9090742 3.9474183 20 1.8797453 3.939207120 1.933129 3.7899769 20 1.9037008 3.781564120 1.9598073 3.6330766 20 1.930347 3.624493720 1.9893606 3.4768277 20 1.9599366 3.468091820 2.0220645 3.3213582 20 1.9927567 3.312499420 2.0582363 3.1668419 20 2.029135 3.157873620 2.0982288 3.0134091 20 2.0694382 3.004395520 2.1424436 2.8612837 20 2.1140853 2.852239820 2.1913383 2.7106624 20 2.163546 2.701644620 2.2454211 2.5618088 20 2.2183489 2.552867820 2.3052713 2.4149981 20 2.2790853 2.406207620 2.3715265 2.2705482 20 2.3464117 2.261968220 2.4449038 2.1288086 20 2.4210636 2.120523920 2.5261732 1.9901848 20 2.5038279 1.982300820 2.6161859 1.8551095 20 2.5955637 1.847710520 2.7158272 1.7240631 20 2.6971628 1.717261120 2.8260198 1.5975493 20 2.8095481 1.591458620 2.9476949 1.4761227 20 2.9336428 1.470837320 3.081881 1.3603516 20 3.0704216 1.355973920 3.1103624 1.3379438 20 3.0994433 1.333763620 3.1394937 1.3158419 20 3.1291101 1.3118557

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25 3.7917075 0.8864474 25 3.738288 0.907195625 3.8550174 0.8678262 25 3.7891177 0.885948925 3.9303815 0.8517544 25 3.8524856 0.867338125 4.0171739 0.8381231 25 3.9278744 0.851270725 4.1147022 0.826804 25 4.0146635 0.837638125 4.2222248 0.8176559 25 4.1121628 0.826310825 4.3389315 0.8105374 25 4.2196137 0.817150925 4.4640546 0.8052966 25 4.3362392 0.810013925 4.5967948 0.8017856 25 4.4612434 0.804749425 4.7364022 0.7998612 25 4.593848 0.801211725 4.8821276 0.7993838 25 4.7332881 0.79925525 5.0332881 0.8002218 25 4.8788408 0.79874225 5.1892311 0.802247 25 5.0298079 0.799540825 5.3493712 0.8053472 25 5.1855531 0.801526625 5.5131309 0.8094123 25 5.3454752 0.804583325 5.6800139 0.8143431 25 5.5090173 0.808604725 5.8495438 0.8200493 25 5.675672 0.8134925 6.0213098 0.8264456 25 5.8449779 0.819150425 6.1949259 0.8334575 25 6.0165111 0.825500225 6.3700489 0.8410152 25 6.1898946 0.832465325 6.5463543 0.8490571 25 6.3647758 0.839975625 6.7235691 0.8575249 25 6.5408545 0.847969825 6.9014356 0.8663678 25 6.7178299 0.8563925 7.0797452 0.8755402 25 6.8954782 0.865185425 7.2582907 0.8850015 25 7.0735549 0.874311625 7.4368831 0.8947111 25 7.2518586 0.883724225 8.3256373 0.9459326 25 7.4302194 0.893385125 9.1981062 0.9995481 25 8.3178102 0.944366325 10.046637 1.0537133 25 9.1890814 0.997730425 10.867515 1.1073715 25 10.036334 1.05162825 11.65933 1.1599339 25 10.855875 1.105000425 12.421916 1.2110832 25 11.64623 1.157253925 13.155857 1.2606676 25 12.40729 1.208073425 13.862122 1.3086178 25 13.139613 1.257302125 14.541819 1.3549544 25 13.84419 1.304903825 15.196162 1.3996867 25 14.522147 1.350847525 15.826423 1.4428867 25 15.174761 1.395191325 16.433825 1.4845855 25 15.803172 1.43797325 17.01957 1.5248788 25 16.408725 1.479268525 17.584592 1.5637978 25 16.992524 1.519132125 17.909532 1.5862142 25 17.545564 1.556943425 17.637956 1.5512041 25 17.545564 1.556943425 17.191715 1.4937014 25 17.518808 1.553449625 16.777151 1.4403045 25 17.077213 1.495756725 16.391083 1.3906091 25 16.66699 1.442207825 16.030611 1.3442141 25 16.28488 1.392373125 15.693171 1.3008327 25 15.928109 1.345860125 15.37676 1.2601609 25 15.594128 1.302358525 15.079336 1.2219587 25 15.280906 1.261586925 14.799327 1.1860042 25 14.986536 1.22329125 14.535169 1.1521078 25 14.709318 1.18725725 14.285593 1.1200967 25 14.447842 1.153285525 14.049394 1.0898173 25 14.200787 1.121205225 13.825553 1.0611334 25 13.966988 1.0908626

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25 13.613092 1.0339221 25 13.745372 1.062120525 13.411181 1.0080725 25 13.535026 1.034856425 13.219026 0.9834841 25 13.335133 1.008956125 13.035965 0.960067 25 13.144915 0.984323825 12.861346 0.9377412 25 12.963673 0.96086625 12.694613 0.9164299 25 12.790784 0.938500125 12.535203 0.896067 25 12.625704 0.917153325 12.382701 0.8765888 25 12.46786 0.896756225 11.155139 0.7200851 25 12.316884 0.877246825 10.297199 0.6110155 25 11.101346 0.720521525 9.6637438 0.5306478 25 10.251746 0.611325125 9.17676 0.4689677 25 9.6243968 0.530878525 8.790721 0.4201354 25 9.1420893 0.469146925 8.4771733 0.3805158 25 8.759741 0.420278125 8.2174267 0.3477251 25 8.4491892 0.380632125 7.9987819 0.3201382 25 8.191918 0.347821525 7.8121389 0.2966062 25 7.9753308 0.320219225 7.6509985 0.2762979 25 7.7904491 0.29667625 7.5104243 0.2585924 25 7.6308393 0.276357825 7.3867447 0.2430196 25 7.4916087 0.258644825 7.27706 0.2292154 25 7.3690695 0.243066225 7.17917 0.2168957 25 7.2604257 0.229257325 7.0912136 0.2058335 25 7.1634617 0.216932225 7.0117797 0.1958444 25 7.0763427 0.205865525 5.6116917 0.0201171 25 6.9976517 0.195873825 5.4678069 0.0020172 25 5.6106435 0.020117425 5.4542984 0 25 5.4680695 0.0020172

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80 12.798034 1.4026834 80 12.822005 1.407587280 13.211439 1.4263721 80 13.23717 1.431661180 13.622734 1.4503734 80 13.650278 1.456041880 14.031538 1.474605 80 14.060915 1.480671280 16.029489 1.5968853 80 16.067837 1.604930680 17.938009 1.7175799 80 17.98477 1.727520480 19.751654 1.8342406 80 19.805935 1.845942780 21.47234 1.9460197 80 21.533348 1.959332380 23.104718 2.0527396 80 23.171637 2.067547580 24.654439 2.1545439 80 24.726594 2.170708180 26.127169 2.2516722 80 26.204038 2.26911480 27.52829 2.3444404 80 27.609404 2.3630680 28.863037 2.433138 80 28.948009 2.452881680 30.135961 2.5180551 80 30.224574 2.538858280 31.351384 2.599449 80 31.443274 2.6212780 32.513106 2.6775731 80 32.608227 2.700377480 33.62478 2.7526376 80 33.722846 2.776406380 34.689563 2.8248549 80 34.790504 2.849554280 35.710466 2.8943886 80 35.81417 2.92002780 36.690137 2.9614136 80 36.796534 2.987971980 37.631079 3.0260855 80 37.740051 3.053550380 38.535492 3.0885432 80 38.647088 3.116896280 39.405621 3.1488948 80 39.519748 3.178154380 40.243285 3.2072613 80 40.359906 3.237428180 41.050342 3.2637544 80 41.169442 3.294811880 41.828397 3.3184685 80 41.949949 3.350433480 42.579048 3.3714949 80 42.70303 3.4043680 43.303669 3.4229107 80 43.430024 3.456673980 44.003598 3.4727903 80 44.132379 3.507461280 44.680031 3.5212118 80 44.811224 3.556804380 45.334221 3.5682487 80 45.467815 3.604743580 45.967191 3.6139516 80 46.103156 3.651366580 46.579992 3.6583742 80 46.718317 3.696704380 47.173508 3.7015895 80 47.314163 3.740843380 47.748646 3.7436353 80 47.891668 3.783808980 48.306284 3.7845539 80 48.451649 3.825655180 48.847155 3.8244089 80 48.994815 3.866433480 49.372001 3.8632328 80 49.521994 3.906181280 49.881539 3.9010655 80 50.033835 3.944940780 49.981685 3.9085142 80 50.134429 3.952584380 50.081195 3.9159263 80 50.234386 3.960182880 50.180189 3.9233045 80 50.333826 3.967743580 50.278585 3.9306369 80 50.432699 3.97526580 50.376416 3.9379471 80 50.530992 3.982756280 50.473677 3.9452102 80 50.628693 3.990205880 50.570426 3.9524324 80 50.725843 3.997620680 50.666551 3.9596279 80 50.82249 4.005002480 50.762133 3.9667888 80 50.918562 4.012338580 50.857264 3.9739064 80 51.014098 4.019647980 50.951751 3.9809904 80 51.109067 4.026915880 51.045779 3.988041 80 51.203496 4.034158380 51.139252 3.9950542 80 51.29745 4.041359280 51.232186 4.0020385 80 51.390836 4.04852480 51.324656 4.0089854 80 51.483704 4.0556544

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80 42.726542 2.7286939 80 41.623242 2.713266180 42.305983 2.6815334 80 41.22911 2.666409380 41.900076 2.6359678 80 40.848612 2.621127880 41.50822 2.5918962 80 40.481024 2.57734780 41.129584 2.5492662 80 40.125733 2.535001180 40.763565 2.5079908 80 39.782114 2.494008580 40.40954 2.4680202 80 39.449613 2.45431780 40.066932 2.4292983 80 39.127678 2.415862880 39.735164 2.3917598 80 36.394918 2.08840680 36.917709 2.0712415 80 34.322552 1.838895180 34.779688 1.8260985 80 32.697165 1.64252480 33.102041 1.6326438 80 31.388397 1.483987880 31.750731 1.476151 80 30.311935 1.353327880 30.638956 1.3469738 80 29.41099 1.243784280 29.708288 1.2385416 80 28.645875 1.150638480 28.917808 1.1462516 80 27.988052 1.070454180 28.238088 1.0667371 80 27.416433 1.000714880 27.647373 0.9975308 80 26.915122 0.939580 27.129229 0.9367485 80 26.471894 0.88534180 26.671102 0.8829422 80 26.077209 0.837083180 26.263104 0.8349771 80 25.7235 0.793811680 25.897451 0.7919523 80 25.404693 0.754792380 25.567885 0.7531408 80 25.115922 0.719428980 25.269288 0.7179554 80 24.853061 0.687229580 24.997505 0.6859086 80 19.879521 0.075868480 19.852738 0.0758937 80 19.330839 0.00766680 19.285055 0.0076703 80 19.28047 7.674E-0880 19.233068 7.678E-08

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100 8.0997033 2.7793072 100 6.9844677 2.1271745100 7.7716757 2.6077227 100 6.824175 1.9855954100 7.4731643 2.4411513 100 6.7282399 1.8560933100 7.2115733 2.2810895 100 6.7049267 1.7404524100 6.9954483 2.1292256 100 6.7604071 1.6400704100 6.8340235 1.9874407 100 6.8977323 1.5557796100 6.7366032 1.8576728 100 7.1163834 1.487746100 6.711556 1.7417077 100 7.412451 1.4354621100 6.7651627 1.6409781 100 7.7793842 1.3978957100 6.9006657 1.5563498 100 8.208909 1.3736489100 7.1176548 1.4879922 100 8.6919742 1.3611308100 7.4123089 1.4354353 100 9.2194949 1.358709100 7.7780262 1.3976314 100 9.7828352 1.3647994100 8.206435 1.3731649 100 10.374189 1.3779398100 8.6883529 1.3604181 100 10.986627 1.3968325100 9.214514 1.357721 100 11.61427 1.4203365100 9.776204 1.3634798 100 12.252142 1.4474979100 10.365524 1.3762055 100 12.896206 1.4775100 10.975575 1.3946096 100 13.543141 1.5096784100 11.600461 1.4175536 100 14.190305 1.5435046100 12.235302 1.4440745 100 14.835649 1.578539100 12.876075 1.4733887 100 15.477515 1.6144262100 13.519534 1.5048381 100 16.114652 1.6508859100 14.163107 1.5379057 100 16.746139 1.6876933100 14.804793 1.5721486 100 17.3712 1.7246805100 15.44294 1.6072316 100 17.989342 1.7617114100 16.076383 1.6428777 100 18.600176 1.7986625100 16.704237 1.6788802 100 19.203414 1.8354667100 17.325633 1.715062 100 22.101808 2.0152913100 17.940273 1.7512949 100 24.805776 2.1858828100 18.547612 1.7874554 100 27.32731 2.3465303100 19.147433 1.8234781 100 29.68222 2.4976785100 22.030226 1.9995951 100 31.886066 2.6401276100 24.720596 2.1667863 100 33.953032 2.7746833100 27.230241 2.3243092 100 35.895772 2.9021253100 29.574611 2.472529 100 37.725429 3.0231161100 31.769007 2.6122058 100 39.45182 3.1382497100 33.827215 2.74409 100 41.083621 3.2480277100 35.761731 2.8689255 100 42.628526 3.3529086100 37.583611 2.987349 100 44.093377 3.4532745100 39.302585 3.0999376 100 45.484292 3.5494511100 40.927173 3.2071779 100 46.80674 3.6417564100 42.465077 3.3095094 100 48.06569 3.7304438100 43.923029 3.4073111 100 49.26551 3.8157541100 45.307217 3.500917 100 50.410383 3.8979033100 46.623006 3.5906242 100 51.503857 3.9770677100 47.875394 3.676689 100 52.549295 4.053437100 49.068807 3.7593574 100 53.549838 4.1271529100 50.207222 3.8388431 100 54.508155 4.1983778100 51.294403 3.9153296 100 55.426915 4.2672249100 52.333597 3.9889957 100 56.308472 4.3338201100 53.327935 4.0600045 100 57.154928 4.3982807100 54.28022 4.1284952 100 57.968322 4.4607045100 55.192944 4.1946062 100 58.750561 4.5211962

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100 56.068549 4.2584653 100 59.503333 4.5798372100 56.909225 4.3201822 100 60.228206 4.6367177100 57.716898 4.3798582 100 60.92672 4.6919042100 58.493542 4.4375926 100 61.600288 4.7454837100 59.240798 4.4934854 100 62.250068 4.7975208100 59.960285 4.547623 100 62.877367 4.8480807100 60.653505 4.6000706 100 63.483308 4.8972101100 61.321818 4.650926 100 64.068833 4.9449893100 61.966486 4.7002384 100 64.635116 4.9914567100 62.588757 4.7480988 100 64.408073 4.8921944100 63.189785 4.794546 100 64.353064 4.8740538100 63.770672 4.8396397 100 64.299354 4.8560068100 63.831882 4.844414 100 64.246987 4.8380597100 63.831854 4.8444088 100 64.004713 4.7498783100 63.794958 4.8294899 100 63.795392 4.664375100 63.753677 4.8122733 100 63.618875 4.5816847100 63.714086 4.7951982 100 63.474785 4.5019331100 63.542203 4.7119893 100 63.362559 4.425184100 63.413222 4.6325168 100 63.281273 4.3515033100 63.326486 4.5568937 100 63.229992 4.2809176100 63.28087 4.4852165 100 63.208839 4.221496100 63.275015 4.4175067 100 63.208839 4.221496100 63.307311 4.3538105 100 63.208839 4.221496100 63.375852 4.2941046 100 63.208839 4.221496100 63.478734 4.2383378 100 63.208839 4.221496100 63.613793 4.1864408 100 63.208839 4.221496100 63.778917 4.1383269 100 63.208839 4.221496100 63.971801 4.0939028 100 63.208839 4.221496100 64.190282 4.0530439 100 63.01075 4.1989989100 64.432131 4.0156306 100 62.67286 4.1605788100 64.454448 4.0125036 100 62.341279 4.1228349100 64.454385 4.0124959 100 62.015899 4.0857434100 64.454448 4.0125036 100 61.696428 4.0492984100 64.216353 3.9885386 100 61.382653 4.0134929100 63.878836 3.9545017 100 58.533665 3.6867193100 63.547357 3.9210115 100 56.124761 3.4082821100 63.221702 3.8880482 100 54.062291 3.1683883100 62.901851 3.8556051 100 52.27741 2.9596555100 59.988744 3.5573512 100 50.718008 2.7764553100 57.515319 3.3002593 100 49.344167 2.6144176100 55.391175 3.0767343 100 48.124871 2.4701007100 53.548365 2.8808332 100 47.035403 2.3407851100 51.935367 2.7078701 100 46.056319 2.2242503100 50.511951 2.5541433 100 45.171539 2.1187246100 49.246967 2.4166675 100 44.368391 2.0226937100 48.115705 2.2930423 100 43.635818 1.9349611100 47.098005 2.1813056 100 42.965137 1.8544961100 46.177649 2.0798388 100 42.348771 1.7804224100 45.341465 1.9873166 100 41.780238 1.712034100 44.578496 1.9025966 100 41.254425 1.6486834100 43.879489 1.8247606 100 29.512921 0.2147399100 43.236701 1.7530016 100 27.959261 0.0221367100 42.643867 1.6866396 100 27.801246 2.221E-07100 42.095163 1.6250848

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100 29.797819 0.213872100 28.165634 0.0220732100 28.000023 0

150 0 14.209379150 1.8766361 14.741041150 3.6450617 15.252655150 5.313713 15.745966150 6.0649191 15.971715150 6.0649191 15.971715150 6.0805934 15.621874150 6.1006621 15.225032150 6.123109 14.831116150 6.1479476 14.440124150 6.1751961 14.052049150 6.2048582 13.666955150 6.2369806 13.284793150 6.2716164 12.905637150 6.308759 12.529481150 6.3484984 12.156353150 6.3908834 11.786272150 6.4359468 11.419258150 6.4837561 11.055349150 6.534406 10.694587150 6.5879568 10.336995150 6.6445544 9.982615150 6.7042947 9.6315198150 6.7673012 9.2837546150 6.8338123 8.9393887150 6.9039484 8.5985184150 6.9779758 8.2612175150 7.0561863 7.9276179150 7.1388771 7.597841150 7.2264506 7.2720578150 7.3193361 6.9504329150 7.4181065 6.6332238150 7.5234177 6.3206708150 7.6360224 6.0131098150 7.7568951 5.7109423150 7.887177 5.4146394150 8.028351 5.1248134150 8.1823025 4.842237150 8.3516738 4.5680106150 8.5406116 4.3038084150 8.7576447 4.0530402150 9.0306329 3.8266392150 9.0997807 3.7873409150 9.1780207 3.7516856150 9.2684095 3.7208884150 9.3742063 3.6962075150 9.433661 3.6864775150 9.4975425 3.6785059150 9.5657948 3.6722878150 9.6381647 3.6677022150 9.7142108 3.6646234

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150 9.7935924 3.6628911150 9.8758298 3.6623262150 9.9605387 3.6627865150 10.04731 3.6641093150 10.135812 3.6661855150 10.225808 3.6689003150 10.317006 3.67214150 10.409203 3.6758632150 10.502293 3.679975150 10.596102 3.6844554150 10.69047 3.6892113150 10.785355 3.6942539150 10.880669 3.6995199150 10.97629 3.7049832150 11.072254 3.7106421150 11.168414 3.7164496150 11.264718 3.7223899150 11.220598 3.691821150 10.834697 3.4685149150 10.490815 3.2520901150 10.198021 3.0444089150 9.9660682 2.8474899150 9.8049263 2.6634934150 9.7241402 2.494511150 9.7317666 2.3424497150 9.8334526 2.2087937150 10.031613 2.0944105150 10.324973 1.9994928150 10.708811 1.9235375150 11.17538 1.8654479150 11.714887 1.823617150 12.316417 1.7961941150 12.968831 1.7812135150 13.661483 1.7767265150 14.384734 1.7809432150 15.130126 1.7922385150 15.89056 1.8092267150 16.66007 1.8307387150 17.433903 1.8557922150 18.208313 1.8836150 18.9802 1.9135057150 19.747322 1.9449933150 20.507834 1.9776508150 21.260512 2.0111413150 22.004197 2.0451974150 22.738184 2.0796149150 23.462001 2.1142284150 24.175318 2.1488945150 27.578851 2.3201081150 30.71524 2.483751150 33.603727 2.6379171150 36.26852 2.7825651150 38.732933 2.9182866150 41.018047 3.0458516

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150 43.142498 3.16599150 45.122577 3.2794057150 46.972337 3.3867139150 48.704259 3.4884574150 50.329219 3.585106150 51.856687 3.6770769150 53.295147 3.7647515150 54.652067 3.8484364150 55.934278 3.9284137150 57.147438 4.0049706150 58.297127 4.0783089150 59.388043 4.1486499150 62.133888 4.3290957150 62.133888 4.3290957150 62.760119 4.3362707150 63.477256 4.3450431150 64.175767 4.3541466150 64.85648 4.3635364150 65.519751 4.3731854150 66.166414 4.3830529150 66.796917 4.3931199150 67.411742 4.4033668150 68.011591 4.4137549150 68.596839 4.4242778150 69.168099 4.4349132150 69.725779 4.4456424150 70.270412 4.4564447150 70.377745 4.4586235150 70.48463 4.4607923150 70.590991 4.4629706150 70.696902 4.4651489150 70.802286 4.4673374150 70.907181 4.4695172150 71.011615 4.4717053150 71.115522 4.4738924150 71.167296 4.4749872150 71.218958 4.476082150 71.229321 4.4762981150 71.239605 4.4765241150 71.249915 4.4767413150 71.260233 4.4769548150 71.270525 4.4771794150 71.280802 4.4773983150 71.29115 4.4776141150 71.301385 4.4778305150 71.311676 4.4780543150 71.321965 4.478278150 71.332192 4.4784943150 71.342475 4.4787179150 71.352787 4.4789284150 71.363028 4.4791495150 71.373283 4.479368150 71.383519 4.479589150 71.393769 4.4798074

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150 71.404 4.4800283150 71.414245 4.4802465150 71.424471 4.4804674150 71.526508 4.4826576150 71.628081 4.4848572150 71.729116 4.4870645150 71.829813 4.48926150 71.929972 4.4914585150 72.029718 4.493662150 72.128962 4.4958714150 72.227819 4.4980748150 72.326183 4.5002889150 72.811492 4.5113351150 73.286092 4.5224032150 73.750303 4.5334927150 74.204497 4.5445742150 74.648889 4.5556646150 75.083869 4.5667353150 75.509715 4.5778018150 75.926702 4.5888393150 76.335129 4.599852150 76.735166 4.6108372150 77.127111 4.621791150 77.511185 4.6327093150 77.887644 4.6435821150 78.256656 4.6544126150 78.618522 4.6651891150 78.973316 4.6759188150 79.321315 4.6865907150 79.662768 4.6972046150 80.326398 4.7182558150 80.965604 4.7390553150 81.581673 4.7595767150 82.175793 4.7798155150 82.749116 4.7997483150 83.302556 4.8193865150 83.837132 4.8387004150 84.015491 4.7853151150 84.140684 4.7229859150 84.262674 4.6622683150 84.82834 4.3806603150 85.329558 4.1311349150 85.776748 3.9085043150 86.178228 3.7086401150 86.540634 3.5282282150 86.869421 3.3645494150 87.169065 3.2153874150 87.183201 3.142648150 86.989174 3.1229376150 86.797724 3.1034493150 86.608719 3.0841786150 86.422178 3.0651255150 86.237966 3.0462907150 86.056121 3.0276612

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150 85.876583 3.0092333150 85.699285 2.9910196150 85.52422 2.9730022150 85.351363 2.9551792150 85.180637 2.9375554150 85.01205 2.9201247150 84.845488 2.902879150 84.681024 2.8858225150 84.518493 2.8689533150 84.357984 2.8522588150 84.199425 2.8357412150 84.042732 2.8194056150 82.574077 2.6651709150 81.26481 2.5259899150 80.091478 2.3999037150 79.034762 2.2852553150 78.078777 2.1806273150 77.210213 2.0848218150 76.417844 1.996813150 75.692479 1.9157202150 75.025996 1.840784150 74.41173 1.7713477150 73.843877 1.7068476150 73.317452 1.6467874150 72.828182 1.5907297150 72.372274 1.5382924150 71.946502 1.4891523150 71.54797 1.4430086150 61.383086 0.2171168150 59.849722 0.0228216150 59.697683 2.294E-07

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0 10 20 30 40 50 60 70 80 900

10

20Column B Column B Column B Column B

Column B Column B Column B Column B

Column B Column B Column B Column G

Column G Column G Column G Column G

Column G Column G Column G Column G

w% H3BO3

w%

LiO

H

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Industry Table (275C)

pHt 6.7 6.8 6.9 7 7.1 7.2 7.3 7.4B, ppm Li, ppm

0 0.21 0.26 0.33 0.42 0.53 0.68 0.86 1.0950 0.28 0.36 0.45 0.57 0.72 0.91 1.16 1.47

100 0.36 0.45 0.57 0.72 0.92 1.16 1.47 1.87150 0.43 0.55 0.69 0.88 1.11 1.41 1.79 2.28200 0.51 0.65 0.82 1.04 1.31 1.67 2.12 2.69250 0.59 0.75 0.94 1.2 1.52 1.93 2.45 3.12300 0.67 0.85 1.07 1.36 1.73 2.2 2.79 3.55400 0.83 1.06 1.34 1.7 2.16 2.75 3.5500 1 1.27 1.62 2.05 2.61 3.32600 1.18 1.5 1.9 2.42 3.08 3.92700 1.36 1.73 2.2 2.8 3.56800 1.55 1.97 2.51 3.19 4.07900 1.74 2.22 2.82 3.59

1000 1.94 2.48 3.15 4.021100 2.16 2.74 3.491200 2.37 3.01 3.841300 2.59 3.31400 2.82 3.591500 3.05 3.91600 3.31700 3.551800 3.81900 4.08

0 200 400 600 800 1000 1200 1400 1600 1800 20000

0.5

1

1.5

2

2.5

3

3.5

4

Column B Column DColumn C Column FColumn D Column HColumn E Column JColumn F Column LColumn G Column NColumn H Column PColumn I Column RColumn J Column T

ppm B

ppm

Li

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2000

Boron added as Boric AcidLithium added as Lithium Hydroxide

t m m pH ppm B ppm LiC B(OH)3 LiOH

275 0 3.0255464E-05 6.7 0 0.21 0275 0 3.7459153E-05 6.8 0 0.26 0275 0 4.7544321E-05 6.9 0 0.33 0275 0 6.0510972E-05 7 0 0.42 0275 0 7.6359113E-05 7.1 0 0.53 0275 0 9.7970234E-05 7.2 0 0.68 0275 0 0.00012390361 7.3 0 0.86 0275 0 0.00015704074 7.4 0 1.09 0275 0 0.00019882243 7.5 0 1.38 0275 0.00462666 4.0352169E-05 6.7 50 0.28 49.999981275 0.00462666 5.1881375E-05 6.8 50 0.36 49.999968275 0.00462666 6.4851739E-05 6.9 50 0.45 49.999951275 0.00462667 8.214557E-05 7 50 0.57 50.000039275 0.00462667 0.00010376288 7.1 50 0.72 50.000013275 0.00462667 0.00013114484 7.2 50 0.91 49.99998275 0.00462668 0.00016717378 7.3 50 1.16 50.000046275 0.00462668 0.00021184976 7.4 50 1.47 49.999993275 0.00462669 0.00026949632 7.5 50 1.87 50.000034275 0.00925597 5.1896221E-05 6.7 100 0.36 99.999958275 0.00925598 6.4870297E-05 6.8 100 0.45 100.00003275 0.00925598 8.2169076E-05 6.9 100 0.57 99.999993275 0.00925599 0.00010379257 7 100 0.72 99.999941275 0.00925599 0.00013262393 7.1 100 0.92 99.999983275 0.009256 0.00016722162 7.2 100 1.16 100.00001275 0.00925601 0.00021191038 7.3 100 1.47 100.00001275 0.00925602 0.00026957344 7.4 100 1.87 99.999983275 0.00925604 0.00034309408 7.5 100 2.38 100.00003275 0.01388794 6.2004911E-05 6.7 150 0.43 149.99958275 0.01388794 7.930864E-05 6.8 150 0.55 149.99952275 0.01388795 9.9496342E-05 6.9 150 0.69 150.00053275 0.01388796 0.00012689397 7 150 0.88 150.00043275 0.01388797 0.00016005957 7.1 150 1.11 150.00032275 0.01388799 0.00020331912 7.2 150 1.41 150.00016275 0.013888 0.00025811468 7.3 150 1.79 149.99997275 0.01388803 0.00032877233 7.4 150 2.28 149.99973275 0.01388806 0.00041817622 7.5 150 2.9 150.00049275 0.01852256 7.3561785E-05 6.7 200 0.51 200.00045275 0.01852257 9.3755262E-05 6.8 200 0.65 200.00036275 0.01852258 0.00011827594 6.9 200 0.82 200.00024275 0.01852259 0.00015000862 7 200 1.04 200.00009275 0.01852261 0.00018895334 7.1 200 1.31 199.9999275 0.01852263 0.00024087975 7.2 200 1.67 199.99967275 0.01852266 0.00030578795 7.3 200 2.12 200.00044275 0.0185227 0.00038800528 7.4 200 2.69 200.00006

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275 0.01852275 0.00049474406 7.5 200 3.43 199.99957275 0.02315984 8.5125286E-05 6.7 250 0.59 249.99962275 0.02315985 0.00010821017 6.8 250 0.75 249.99949275 0.02315986 0.0001356235 6.9 250 0.94 250.0004275 0.02315988 0.00017313654 7 250 1.2 250.00018275 0.02315991 0.00021930653 7.1 250 1.52 249.99991275 0.02315994 0.00027846197 7.2 250 1.93 249.99957275 0.02315998 0.00035348863 7.3 250 2.45 250.00021275 0.02316004 0.00045015799 7.4 250 3.12 249.99965275 0.02316011 0.0005742417 7.5 250 3.98 250.00002275 0.02779977 9.6695418E-05 6.7 300 0.67 300.00031275 0.02779979 0.00012267337 6.8 300 0.85 300.00012275 0.02779981 0.00015442424 6.9 300 1.07 299.99989275 0.02779984 0.00019627773 7 300 1.36 299.9996275 0.02779987 0.00024967714 7.1 300 1.73 300.00031275 0.02779992 0.00031750902 7.2 300 2.2 299.99984275 0.02779998 0.00040265999 7.3 300 2.79 300.00032275 0.02780005 0.00051234649 7.4 300 3.55 299.99956275 0.03708763 0.0001198556 6.7 400 0.83 399.99965275 0.03708766 0.00015306872 6.8 400 1.06 400.00042275 0.0370877 0.00019350216 6.9 400 1.34 400.00004275 0.03708775 0.00024548812 7 400 1.7 399.99956275 0.0370878 0.00031191481 7.1 400 2.16 400.00002275 0.03708788 0.00039711457 7.2 400 2.75 400.00031275 0.03708798 0.00050541985 7.3 400 3.5 400.0004275 0.04638616 0.00014448726 6.7 500 1 500.00042275 0.04638621 0.00018349899 6.8 500 1.27 499.99997275 0.04638626 0.00023406986 6.9 500 1.62 500.00047275 0.04638633 0.00029619996 7 500 2.05 499.99975275 0.04638642 0.00037711385 7.1 500 2.61 499.9999275 0.04638653 0.00047970155 7.2 500 3.32 499.99979275 0.05569538 0.00017059293 6.7 600 1.18 600.00028275 0.05569544 0.00021685566 6.8 600 1.5 599.99965275 0.05569552 0.00027468421 6.9 600 1.9 599.99991275 0.05569562 0.00034986158 7 600 2.42 599.99996275 0.05569574 0.00044527939 7.1 600 3.08 599.99973275 0.05569591 0.00056672087 7.2 600 3.92 600.00022275 0.0650153 0.00019672862 6.7 700 1.36 700.0001275 0.06501538 0.00025025069 6.8 700 1.73 700.00031275 0.06501549 0.00031823839 6.9 700 2.2 700.0003275 0.06501562 0.00040503153 7 700 2.8 699.99999275 0.06501579 0.00051497001 7.1 700 3.56 700.00038275 0.07434594 0.00022434175 6.7 800 1.55 799.99966275 0.07434605 0.00028513154 6.8 800 1.97 800.0007275 0.07434619 0.0003632901 6.9 800 2.51 800.00036275 0.07434637 0.00046171241 7 800 3.19 800.00071275 0.07434659 0.00058908315 7.1 800 4.07 800.00056275 0.08368733 0.00025198667 6.7 900 1.74 899.99985275 0.08368747 0.00032150076 6.8 900 2.22 900.00059275 0.08368764 0.00040839371 6.9 900 2.82 899.99987275 0.08368787 0.00051990686 7 900 3.59 900.00082275 0.09303948 0.00028111247 6.7 1000 1.94 1000.0004275 0.09303965 0.00035936095 6.8 1000 2.48 1000.0009275 0.09303987 0.00045644742 6.9 1000 3.15 1000.0008

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275 0.09304015 0.00058251561 7 1000 4.02 1000.0012275 0.10240242 0.00031317161 6.7 1100 2.16 1099.9959275 0.10240262 0.00039726478 6.8 1100 2.74 1100.0045275 0.10240289 0.00050600646 6.9 1100 3.49 1100.0018275 0.11177615 0.000343817 6.7 1200 2.37 1199.9989275 0.1117764 0.00043666307 6.8 1200 3.01 1199.9963275 0.11177672 0.00055707343 6.9 1200 3.84 1200.0038275 0.1211607 0.00037594932 6.7 1300 2.59 1300.0037275 0.121161 0.00047900997 6.8 1300 3.3 1300.0008275 0.1305561 0.00040957113 6.7 1400 2.82 1399.9997275 0.13055645 0.00052140578 6.8 1400 3.59 1399.9962275 0.13996235 0.0004432318 6.7 1500 3.05 1499.9971275 0.13996276 0.00056675709 6.8 1500 3.9 1500.0037275 0.14937948 0.00047983953 6.7 1600 3.3 1599.9959275 0.15880752 0.00051648962 6.7 1700 3.55 1700.0064275 0.16824646 0.00055318214 6.7 1800 3.8 1799.9966275 0.17769636 0.00059428697 6.7 1900 4.08 1899.998275 0 3.0255464E-05 6.7 0 0.21 0275 0.00462666 4.0352169E-05 6.7 50 0.28 49.999981275 0.00925597 5.1896221E-05 6.7 100 0.36 99.999958275 0.01388794 6.2004911E-05 6.7 150 0.43 149.99958275 0.01852256 7.3561785E-05 6.7 200 0.51 200.00045275 0.02315984 8.5125286E-05 6.7 250 0.59 249.99962275 0.02779977 9.6695418E-05 6.7 300 0.67 300.00031275 0.03708763 0.0001198556 6.7 400 0.83 399.99965275 0.04638616 0.00014448726 6.7 500 1 500.00042275 0.05569538 0.00017059293 6.7 600 1.18 600.00028275 0.0650153 0.00019672862 6.7 700 1.36 700.0001275 0.07434594 0.00022434175 6.7 800 1.55 799.99966275 0.08368733 0.00025198667 6.7 900 1.74 899.99985275 0.09303948 0.00028111247 6.7 1000 1.94 1000.0004275 0.10240242 0.00031317161 6.7 1100 2.16 1099.9959275 0.11177615 0.000343817 6.7 1200 2.37 1199.9989275 0.1211607 0.00037594932 6.7 1300 2.59 1300.0037275 0.1305561 0.00040957113 6.7 1400 2.82 1399.9997275 0.13996235 0.0004432318 6.7 1500 3.05 1499.9971275 0.14937948 0.00047983953 6.7 1600 3.3 1599.9959275 0.15880752 0.00051648962 6.7 1700 3.55 1700.0064275 0.16824646 0.00055318214 6.7 1800 3.8 1799.9966275 0.17769636 0.00059428697 6.7 1900 4.08 1899.998275 0 3.7459153E-05 6.8 0 0.26 0275 0.00462666 5.1881375E-05 6.8 50 0.36 49.999968275 0.00925598 6.4870297E-05 6.8 100 0.45 100.00003275 0.01388794 7.930864E-05 6.8 150 0.55 149.99952275 0.01852257 9.3755262E-05 6.8 200 0.65 200.00036275 0.02315985 0.00010821017 6.8 250 0.75 249.99949275 0.02779979 0.00012267337 6.8 300 0.85 300.00012275 0.03708766 0.00015306872 6.8 400 1.06 400.00042275 0.04638621 0.00018349899 6.8 500 1.27 499.99997275 0.05569544 0.00021685566 6.8 600 1.5 599.99965275 0.06501538 0.00025025069 6.8 700 1.73 700.00031275 0.07434605 0.00028513154 6.8 800 1.97 800.0007275 0.08368747 0.00032150076 6.8 900 2.22 900.00059275 0.09303965 0.00035936095 6.8 1000 2.48 1000.0009

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275 0.10240262 0.00039726478 6.8 1100 2.74 1100.0045275 0.1117764 0.00043666307 6.8 1200 3.01 1199.9963275 0.121161 0.00047900997 6.8 1300 3.3 1300.0008275 0.13055645 0.00052140578 6.8 1400 3.59 1399.9962275 0.13996276 0.00056675709 6.8 1500 3.9 1500.0037275 0 4.7544321E-05 6.9 0 0.33 0275 0.00462666 6.4851739E-05 6.9 50 0.45 49.999951275 0.00925598 8.2169076E-05 6.9 100 0.57 99.999993275 0.01388795 9.9496342E-05 6.9 150 0.69 150.00053275 0.01852258 0.00011827594 6.9 200 0.82 200.00024275 0.02315986 0.0001356235 6.9 250 0.94 250.0004275 0.02779981 0.00015442424 6.9 300 1.07 299.99989275 0.0370877 0.00019350216 6.9 400 1.34 400.00004275 0.04638626 0.00023406986 6.9 500 1.62 500.00047275 0.05569552 0.00027468421 6.9 600 1.9 599.99991275 0.06501549 0.00031823839 6.9 700 2.2 700.0003275 0.07434619 0.0003632901 6.9 800 2.51 800.00036275 0.08368764 0.00040839371 6.9 900 2.82 899.99987275 0.09303987 0.00045644742 6.9 1000 3.15 1000.0008275 0.10240289 0.00050600646 6.9 1100 3.49 1100.0018275 0.11177672 0.00055707343 6.9 1200 3.84 1200.0038275 0 6.0510972E-05 7 0 0.42 0275 0.00462667 8.214557E-05 7 50 0.57 50.000039275 0.00925599 0.00010379257 7 100 0.72 99.999941275 0.01388796 0.00012689397 7 150 0.88 150.00043275 0.01852259 0.00015000862 7 200 1.04 200.00009275 0.02315988 0.00017313654 7 250 1.2 250.00018275 0.02779984 0.00019627773 7 300 1.36 299.9996275 0.03708775 0.00024548812 7 400 1.7 399.99956275 0.04638633 0.00029619996 7 500 2.05 499.99975275 0.05569562 0.00034986158 7 600 2.42 599.99996275 0.06501562 0.00040503153 7 700 2.8 699.99999275 0.07434637 0.00046171241 7 800 3.19 800.00071275 0.08368787 0.00051990686 7 900 3.59 900.00082275 0.09304015 0.00058251561 7 1000 4.02 1000.0012275 0 7.6359113E-05 7.1 0 0.53 0275 0.00462667 0.00010376288 7.1 50 0.72 50.000013275 0.00925599 0.00013262393 7.1 100 0.92 99.999983275 0.01388797 0.00016005957 7.1 150 1.11 150.00032275 0.01852261 0.00018895334 7.1 200 1.31 199.9999275 0.02315991 0.00021930653 7.1 250 1.52 249.99991275 0.02779987 0.00024967714 7.1 300 1.73 300.00031275 0.0370878 0.00031191481 7.1 400 2.16 400.00002275 0.04638642 0.00037711385 7.1 500 2.61 499.9999275 0.05569574 0.00044527939 7.1 600 3.08 599.99973275 0.06501579 0.00051497001 7.1 700 3.56 700.00038275 0.07434659 0.00058908315 7.1 800 4.07 800.00056275 0 9.7970234E-05 7.2 0 0.68 0275 0.00462667 0.00013114484 7.2 50 0.91 49.99998275 0.009256 0.00016722162 7.2 100 1.16 100.00001275 0.01388799 0.00020331912 7.2 150 1.41 150.00016275 0.01852263 0.00024087975 7.2 200 1.67 199.99967275 0.02315994 0.00027846197 7.2 250 1.93 249.99957275 0.02779992 0.00031750902 7.2 300 2.2 299.99984

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275 0.03708788 0.00039711457 7.2 400 2.75 400.00031275 0.04638653 0.00047970155 7.2 500 3.32 499.99979275 0.05569591 0.00056672087 7.2 600 3.92 600.00022275 0 0.00012390361 7.3 0 0.86 0275 0.00462668 0.00016717378 7.3 50 1.16 50.000046275 0.00925601 0.00021191038 7.3 100 1.47 100.00001275 0.013888 0.00025811468 7.3 150 1.79 149.99997275 0.01852266 0.00030578795 7.3 200 2.12 200.00044275 0.02315998 0.00035348863 7.3 250 2.45 250.00021275 0.02779998 0.00040265999 7.3 300 2.79 300.00032275 0.03708798 0.00050541985 7.3 400 3.5 400.0004275 0 0.00015704074 7.4 0 1.09 0275 0.00462668 0.00021184976 7.4 50 1.47 49.999993275 0.00925602 0.00026957344 7.4 100 1.87 99.999983275 0.01388803 0.00032877233 7.4 150 2.28 149.99973275 0.0185227 0.00038800528 7.4 200 2.69 200.00006275 0.02316004 0.00045015799 7.4 250 3.12 249.99965275 0.02780005 0.00051234649 7.4 300 3.55 299.99956275 0 0.00019882243 7.5 0 1.38 0275 0.00462669 0.00026949632 7.5 50 1.87 50.000034275 0.00925604 0.00034309408 7.5 100 2.38 100.00003275 0.01388806 0.00041817622 7.5 150 2.9 150.00049275 0.01852275 0.00049474406 7.5 200 3.43 199.99957275 0.02316011 0.0005742417 7.5 250 3.98 250.00002

949 1010 1071 1132 1193 1254 1315 13760 50 100 150 200 250 300 400

0 5.61179 5.54793 5.49817 5.45731 5.42259 5.39236 5.36555 5.319520.1 6.38996 6.26638 6.17086 6.09307 6.02749 5.97083 5.92096 5.836240.2 6.68003 6.55367 6.45538 6.37487 6.30661 6.24733 6.1949 6.10520.3 6.85282 6.72598 6.62715 6.54606 6.47723 6.41737 6.36435 6.273490.4 6.97579 6.84885 6.74984 6.66855 6.59951 6.53944 6.48621 6.394910.5 7.0712 6.94425 6.84518 6.76381 6.69467 6.63449 6.58116 6.489660.6 7.1491 7.0222 6.92311 6.84169 6.7725 6.71227 6.65888 6.567260.7 7.21491 7.08807 6.98897 6.90754 6.83832 6.77805 6.72463 6.632940.8 7.27184 7.14509 7.046 6.96456 6.89532 6.83503 6.78158 6.689840.9 7.32201 7.19534 7.09627 7.01482 6.94557 6.88527 6.8318 6.74002

1 7.36683 7.24025 7.1412 7.05976 6.9905 6.93018 6.8767 6.784891.1 7.40733 7.28084 7.18182 7.10037 7.03111 6.97078 6.9173 6.825471.2 7.44427 7.31786 7.21887 7.13743 7.06816 7.00783 6.95433 6.862481.3 7.4782 7.35189 7.25293 7.17149 7.10222 7.04188 6.98838 6.896521.4 7.50959 7.38337 7.28443 7.203 7.13373 7.07339 7.01988 6.928011.5 7.53877 7.41265 7.31374 7.23232 7.16305 7.10271 7.04919 6.95731.6 7.56604 7.44001 7.34114 7.25973 7.19046 7.13011 7.07659 6.984691.7 7.59163 7.4657 7.36686 7.28545 7.21618 7.15583 7.1023 7.01041.8 7.61574 7.4899 7.39108 7.30969 7.24042 7.18006 7.12654 7.034621.9 7.63851 7.51277 7.41398 7.3326 7.26333 7.20297 7.14944 7.05752

2 7.6601 7.53445 7.4357 7.35432 7.28505 7.22469 7.17116 7.079232.1 7.68061 7.55505 7.45633 7.37497 7.3057 7.24534 7.1918 7.099862.2 7.70015 7.57469 7.476 7.39464 7.32538 7.26501 7.21147 7.119522.3 7.7188 7.59343 7.49477 7.41343 7.34417 7.2838 7.23026 7.13832.4 7.73664 7.61137 7.51274 7.43141 7.36214 7.30178 7.24823 7.156272.5 7.75373 7.62856 7.52996 7.44864 7.37938 7.31901 7.26546 7.17349

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2.6 7.77015 7.64506 7.5465 7.46518 7.39593 7.33556 7.282 7.190032.7 7.78592 7.66093 7.5624 7.4811 7.41184 7.35147 7.29791 7.205932.8 7.80111 7.67621 7.57772 7.49642 7.42717 7.3668 7.31324 7.221252.9 7.81575 7.69095 7.59248 7.5112 7.44195 7.38158 7.32801 7.23602

3 7.82988 7.70518 7.60674 7.52547 7.45622 7.39585 7.34228 7.250283.1 7.84354 7.71893 7.62053 7.53926 7.47002 7.40964 7.35607 7.264073.2 7.85675 7.73223 7.63386 7.55261 7.48337 7.42299 7.36942 7.277413.3 7.86955 7.74512 7.64679 7.56554 7.4963 7.43592 7.38235 7.290333.4 7.88195 7.75762 7.65931 7.57808 7.50884 7.44846 7.39489 7.302863.5 7.89398 7.76975 7.67147 7.59025 7.52101 7.46063 7.40705 7.315023.6 7.90567 7.78152 7.68328 7.60207 7.53284 7.47245 7.41887 7.326833.7 7.91702 7.79297 7.69476 7.61356 7.54433 7.48395 7.43036 7.338323.8 7.92807 7.80411 7.70593 7.62474 7.55551 7.49513 7.44154 7.349493.9 7.93881 7.81495 7.7168 7.63562 7.5664 7.50601 7.45242 7.36036

4 7.94928 7.82551 7.72739 7.64623 7.577 7.51661 7.46302 7.370964.1 7.95948 7.8358 7.73772 7.65656 7.58734 7.52695 7.47336 7.381294.2 7.96943 7.84584 7.74779 7.66664 7.59742 7.53703 7.48344 7.391364.3 7.97913 7.85563 7.75762 7.67648 7.60726 7.54688 7.49327 7.401194.4 7.98861 7.8652 7.76722 7.68609 7.61688 7.55649 7.50288 7.41084.5 7.99786 7.87455 7.7766 7.69548 7.62627 7.56588 7.51227 7.420184.6 8.00691 7.88368 7.78576 7.70466 7.63545 7.57506 7.52145 7.429354.7 8.01575 7.89262 7.79473 7.71364 7.64443 7.58404 7.53043 7.438324.8 8.0244 7.90136 7.8035 7.72242 7.65322 7.59282 7.53921 7.44714.9 8.03287 7.90992 7.81209 7.73103 7.66182 7.60142 7.54781 7.45569

5 8.04115 7.9183 7.82051 7.73945 7.67025 7.60985 7.55623 7.464115.1 8.04927 7.92651 7.82875 7.7477 7.6785 7.6181 7.56448 7.472355.2 8.05723 7.93455 7.83683 7.75579 7.68659 7.62619 7.57257 7.480445.3 8.06503 7.94244 7.84475 7.76372 7.69453 7.63413 7.5805 7.488365.4 8.07267 7.95018 7.85252 7.7715 7.70231 7.64191 7.58828 7.496145.5 8.08017 7.95777 7.86014 7.77914 7.70995 7.64955 7.59592 7.503765.6 8.08753 7.96522 7.86763 7.78663 7.71745 7.65704 7.60341 7.511255.7 8.09476 7.97254 7.87497 7.79399 7.72481 7.6644 7.61077 7.51865.8 8.10186 7.97972 7.88219 7.80122 7.73204 7.67163 7.618 7.525825.9 8.10882 7.98678 7.88928 7.80832 7.73914 7.67874 7.6251 7.53292

6 8.11567 7.99372 7.89625 7.8153 7.74613 7.68572 7.63208 7.53989

232 353 474 595 7166.6 6.7 6.8 6.9 7

0 0.166 0 0.21 0 0.265 0 0.335 01 0.167 1 0.211 1 0.267 1 0.337 12 0.168 2 0.213 2 0.269 2 0.34 23 0.169 3 0.214 3 0.271 3 0.342 34 0.17 4 0.215 4 0.272 4 0.344 45 0.171 5 0.217 5 0.274 5 0.347 56 0.172 6 0.218 6 0.276 6 0.349 67 0.174 7 0.22 7 0.278 7 0.351 78 0.175 8 0.221 8 0.28 8 0.353 89 0.176 9 0.223 9 0.282 9 0.356 9

10 0.177 10 0.224 10 0.283 10 0.358 1012 0.179 12 0.227 12 0.287 12 0.363 1214 0.182 14 0.23 14 0.291 14 0.367 1416 0.184 16 0.233 16 0.294 16 0.372 1618 0.186 18 0.236 18 0.298 18 0.377 1820 0.188 20 0.239 20 0.302 20 0.381 20

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25 0.194 25 0.246 25 0.311 25 0.393 2530 0.2 30 0.253 30 0.32 30 0.404 3035 0.206 35 0.26 35 0.329 35 0.416 3540 0.212 40 0.268 40 0.338 40 0.428 4045 0.217 45 0.275 45 0.348 45 0.439 45

50.001 0.223 50.001 0.282 50.001 0.357 50 0.451 5055.001 0.229 55.001 0.29 55 0.366 55 0.463 5560.001 0.235 60.001 0.297 60.001 0.375 60 0.474 6065.001 0.241 65.001 0.304 65.001 0.385 65.001 0.486 65.00170.001 0.246 70.001 0.312 70.001 0.394 70.001 0.498 70.00175.001 0.252 75.001 0.319 75.001 0.403 75.001 0.509 75.00180.001 0.258 80.001 0.326 80.001 0.412 80.001 0.521 80.00185.001 0.264 85.001 0.334 85.001 0.422 85.001 0.533 85.00190.001 0.27 90.001 0.341 90.001 0.431 90.001 0.545 90.00195.001 0.276 95.001 0.349 95.001 0.44 95.001 0.557 95.001

100.001 0.281 100.001 0.356 100.001 0.45 100.001 0.568 100.001110.001 0.293 110 0.371 110 0.469 110 0.592 110120.001 0.305 120.001 0.386 120.001 0.487 120.001 0.616 120130.001 0.317 130.001 0.401 130.001 0.506 130.001 0.64 130.001140.001 0.329 140.001 0.416 140.001 0.525 140.001 0.664 140.001150.002 0.341 150.002 0.431 150.002 0.544 150.002 0.688 150.002175.002 0.37 175.002 0.468 175.002 0.592 175.002 0.748 175.002200.002 0.4 200.002 0.506 200.001 0.64 200.001 0.809 200.001225.002 0.431 225.001 0.545 225.001 0.688 225.001 0.87 225.001250.002 0.461 250.002 0.583 250.002 0.737 250.001 0.932 250.001275.003 0.492 275.002 0.622 275.002 0.786 275.002 0.994 275.002300.003 0.523 300.002 0.661 300.002 0.835 300.002 1.056 300.002325.003 0.554 325.003 0.7 325.003 0.885 325.002 1.119 325.002350.003 0.585 350.002 0.739 350.002 0.935 350.002 1.183 350.002375.003 0.616 375.003 0.779 375.002 0.985 375.002 1.246 375.001400.003 0.648 400.003 0.819 400.003 1.036 400.002 1.311 400.002425.004 0.68 425.004 0.86 425.003 1.087 425.003 1.375 425.002450.004 0.712 450.004 0.9 450.003 1.139 450.003 1.441 450.002475.003 0.744 475.003 0.941 475.003 1.19 475.002 1.506 475.001500.004 0.777 500.004 0.982 500.003 1.242 500.003 1.572 500.002525.004 0.809 525.004 1.024 525.003 1.295 525.003 1.639 525.002550.004 0.842 550.004 1.065 550.003 1.348 550.003 1.706 550.002575.004 0.875 575.004 1.107 575.003 1.401 575.002 1.774 575.001600.004 0.908 600.004 1.149 600.003 1.454 600.002 1.841 600.001625.004 0.942 625.004 1.192 625.003 1.508 625.002 1.91 625.001650.005 0.976 650.004 1.234 650.004 1.563 650.003 1.979 650.002675.005 1.01 675.004 1.278 675.003 1.617 675.002 2.048 675.001700.005 1.044 700.004 1.321 700.004 1.672 700.002 2.118 700.001725.005 1.078 725.004 1.364 725.003 1.727 725.002 2.188 725750.005 1.113 750.005 1.408 750.004 1.783 750.002 2.259 750.001775.004 1.148 775.004 1.452 775.003 1.839 775.001 2.33 775800.005 1.183 800.004 1.497 800.003 1.896 800.001 2.402 800825.006 1.218 825.005 1.542 825.003 1.952 825.002 2.474 825850.006 1.253 850.005 1.587 850.003 2.01 850.002 2.547 850875.005 1.289 875.004 1.632 875.002 2.067 875.001 2.621 874.999900.005 1.325 900.004 1.678 900.003 2.125 900.001 2.694 899.999925.005 1.361 925.004 1.723 925.002 2.184 925.001 2.769 924.998950.005 1.398 950.004 1.77 950.002 2.242 950 2.843 949.998975.005 1.434 975.004 1.816 975.003 2.301 975 2.919 974.998

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1000.005 1.471 1000.004 1.863 1000.002 2.361 1000 2.994 999.9971025.005 1.508 1025.003 1.91 1025.002 2.421 1024.999 3.071 1024.9961050.005 1.545 1050.004 1.958 1050.002 2.481 1049.999 3.148 1049.9961075.005 1.583 1075.004 2.005 1075.002 2.542 1074.999 3.225 1074.9961100.008 1.621 1100.007 2.053 1100.005 2.603 1100.002 3.303 1099.9991125.004 1.659 1125.002 2.102 1125 2.665 1124.997 3.381 1124.9941150.003 1.697 1150.001 2.15 1149.999 2.726 1149.996 3.46 1149.9921175.006 1.736 1175.004 2.199 1175.001 2.789 1174.998 3.54 1174.9941200.001 1.774 1199.999 2.249 1199.996 2.852 1199.993 3.62 1199.989

1225 1.813 1224.998 2.298 1224.995 2.915 1224.992 3.7 1224.9871250.002 1.853 1250 2.348 1249.997 2.978 1249.994 3.781 1249.9891275.008 1.892 1275.005 2.398 1275.003 3.042 1274.999 3.863 1274.9941300.006 1.932 1300.004 2.449 1300.001 3.107 1299.997 3.945 1299.9921325.008 1.972 1325.006 2.5 1325.003 3.172 1324.999 4.028 1324.9941350.003 2.012 1350 2.551 1349.997 3.237 1349.993 4.111 1349.9881375.001 2.053 1374.998 2.603 1374.995 3.303 1374.991 4.195 1374.9851400.002 2.094 1400 2.655 1399.996 3.369 1399.992 4.279 1399.9861425.007 2.135 1425.005 2.707 1425.001 3.435 1424.997 4.364 1424.9911450.005 2.176 1450.002 2.759 1449.999 3.502 1449.994 4.45 1449.9881475.006 2.218 1475.003 2.812 1475 3.57 1474.995 4.536 1474.988

1500 2.259 1499.997 2.866 1499.993 3.637 1499.988 4.623 1499.9821525.008 2.301 1525.005 2.919 1525.001 3.706 1524.996 4.71 1524.9891549.999 2.344 1549.995 2.973 1549.991 3.775 1549.985 4.798 1549.9781575.003 2.386 1574.999 3.027 1574.995 3.844 1574.989 4.887 1574.982

1600 2.429 1599.996 3.082 1599.991 3.914 1599.986 4.976 1599.9781625 2.473 1624.996 3.137 1624.992 3.984 1624.985 5.065 1624.978

1650.004 2.516 1650 3.192 1649.995 4.054 1649.989 5.156 1649.9811675 2.56 1674.996 3.248 1674.991 4.125 1674.985 5.247 1674.9761700 2.604 1699.996 3.304 1699.991 4.197 1699.984 5.338 1699.975

1725.003 2.648 1724.999 3.36 1724.994 4.269 1724.987 5.43 1724.9781749.999 2.693 1749.995 3.417 1749.989 4.341 1749.982 5.523 1749.9731774.999 2.737 1774.994 3.474 1774.988 4.414 1774.981 5.616 1774.9721800.001 2.783 1799.997 3.532 1799.991 4.488 1799.983 5.71 1799.9741824.997 2.828 1824.992 3.59 1824.986 4.562 1824.978 5.805 1824.9681849.996 2.874 1849.991 3.648 1849.985 4.636 1849.976 5.9 1849.9661874.998 2.92 1874.993 3.706 1874.986 4.711 1874.978 5.996 1874.9671900.003 2.966 1899.998 3.765 1899.992 4.786 1899.983 6.092 1899.9721925.002 3.012 1924.996 3.825 1924.989 4.862 1924.981 6.189 1924.9691950.003 3.059 1949.998 3.885 1949.991 4.938 1949.982 6.287 1949.971974.998 3.106 1974.992 3.945 1974.985 5.015 1974.975 6.386 1974.9631999.995 3.154 1999.99 4.005 1999.982 5.093 1999.973 6.485 1999.962024.997 3.202 2024.99 4.066 2024.983 5.17 2024.973 6.584 2024.962050.001 3.25 2049.995 4.127 2049.987 5.249 2049.977 6.685 2049.9642074.998 3.298 2074.992 4.189 2074.983 5.328 2074.973 6.786 2074.962099.998 3.347 2099.992 4.251 2099.983 5.407 2099.973 6.887 2099.9592125.002 3.395 2124.995 4.314 2124.987 5.487 2124.976 6.99 2124.9622240.979 3.626 2240.972 4.609 2240.962 5.864 2240.95 7.473 2240.9342346.259 3.842 2346.25 4.884 2346.24 6.217 2346.226 7.925 2346.2082451.41 4.063 2451.4 5.166 2451.388 6.578 2451.373 8.389 2451.353

2556.432 4.29 2556.422 5.456 2556.409 6.949 2556.392 8.865 2556.372661.326 4.522 2661.315 5.752 2661.301 7.329 2661.282 9.354 2661.258

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7.5Li, ppm

1.381.872.382.93.433.98

0 200 400 600 800 1000 1200 1400 1600 1800 20000

0.5

1

1.5

2

2.5

3

3.5

4

Column B Column DColumn C Column FColumn D Column HColumn E Column JColumn F Column LColumn G Column NColumn H Column PColumn I Column RColumn J Column T

ppm B

ppm

Li

0 0.5 1 1.5 2 2.5 3 3.5 4 4.56.6

6.8

7

7.2

7.4

7.6

7.8

8Column D Column BColumn D Column CColumn D Column DColumn D Column EColumn D Column FColumn D Column GColumn D Column HColumn D Column IColumn D Column J

ppm Li

pH

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0.21046670.26617980.33644030.42516140.53732110.67926260.85910041.08722541.37701940.28349460.35838830.45291340.57234760.72340780.914671

1.15708031.46467961.85551640.35755940.45195760.57117870.72191060.91266121.15430751.46075751.84985232.34452460.43265740.54688040.69122440.87382121.10503761.39812671.77006452.24263282.84388890.50879030.64315540.81304671.028078

1.30053421.64610412.08494782.6429588

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3.35351010.58596140.74078760.93664891.18469281.49914131.89824292.40542333.05082353.87337190.66417890.83978421.06204391.34366341.70088372.15455332.73147893.46622710.82378411.04192081.31826151.668747

2.11381912.67977073.40048390.98769271.24965931.58181792.00349842.539546

3.22199641.15599841.46312781.85286612.34809422.97829073.78153851.32879721.68245432.13157932.70276533.43034081.50620521.90777342.41812313.06772883.89598331.68833152.13922622.71269773.44322831.8752922.376981

3.0154887

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3.82952782.06721572.62118513.32671572.26421782.87199943.64657022.46642683.12958372.67397123.39410522.88697883.66573683.1055913.329935

3.56014513.79636120.21046670.2834946 6.699060.3575594 6.789980.4326574 6.891740.5087903 6.994780.5859614 7.094140.6641789 7.200460.8237841 7.300450.9876927 7.401081.1559984 7.500911.3287972 6.694721.5062052 6.801921.6883315 6.897241.875292 6.99824

2.0672157 7.097982.2642178 7.197822.4664268 7.301072.6739712 7.401532.8869788 7.503283.105591 6.70293.329935 6.79815

3.5601451 6.899123.7963612 6.998870.2661798 7.103410.3583883 7.202090.4519576 7.302670.5468804 7.404580.6431554 7.506320.7407876 6.697370.8397842 6.802431.0419208 6.899241.2496593 7.0031.4631278 7.101911.6824543 7.203591.9077734 7.304742.1392262 7.406972.376981 7.50821

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2.6211851 6.701012.8719994 6.804523.1295837 6.903633.3941052 7.004913.6657368 7.103080.3364403 7.206110.4529134 7.307040.5711787 7.407420.6912244 7.509450.8130467 6.702930.9366489 6.805271.0620439 6.901521.3182615 7.005461.5818179 7.105861.8528661 7.207022.1315793 7.307742.4181231 7.409412.7126977 7.511353.0154887 6.703723.3267157 6.805153.6465702 6.903170.4251614 7.005130.5723476 7.107190.7219106 7.208810.8738212 7.308921.028078 7.41

1.1846928 6.70321.3436634 6.807321.668747 6.90694

2.0034984 7.007862.3480942 7.109122.7027653 7.210883.0677288 7.312083.4432283 6.705273.8295278 6.806860.5373211 6.910110.7234078 7.009690.9126612 7.111521.1050376 7.212561.3005342 6.708731.4991413 6.810551.7008837 6.910622.1138191 7.012712.539546 7.11409

2.9782907 7.215023.4303408 6.709853.8959833 6.811790.6792626 6.913330.914671 7.01485

1.1543075 7.115521.3981267 6.712141.6461041 6.813561.8982429 6.91572.1545533 7.01638

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2.6797707 7.118233.2219964 6.712753.7815385 6.815630.8591004 6.91631.1570803 7.017461.4607575 6.714331.7700645 6.817862.0849478 6.91832.4054233 7.020252.7314789 6.718523.4004839 6.818631.0872254 6.920051.4646796 6.719231.8498523 6.819692.2426328 6.921582.6429588 6.720563.0508235 6.822213.4662271 6.722331.3770194 6.823461.8555164 6.723042.3445246 6.825862.8438889 6.725433.3535101 6.726773.8733719 6.72724

1437 1498 1559 1620 1681 1742 1803 1864 1925500 600.001 700 800 900 1000.001 1100.004 1199.998 1300.004

5.28078 5.24722 5.21755 5.19089 5.16663 5.14433 5.12366 5.10437 5.086275.76593 5.70583 5.65334 5.60674 5.56481 5.52669 5.49173 5.45942 5.42938

6.0301 5.96539 5.90846 5.85756 5.81149 5.76935 5.73049 5.6944 5.660696.19723 6.13137 6.07328 6.02123 5.97401 5.93072 5.89071 5.85348 5.818626.31822 6.25191 6.19338 6.14089 6.09321 6.04947 6.009 5.97131 5.935986.41275 6.34624 6.28749 6.23478 6.18688 6.14292 6.10223 6.06431 6.028756.49024 6.4236 6.36474 6.3119 6.26388 6.21979 6.17898 6.14093 6.105246.55584 6.48913 6.43019 6.37728 6.32918 6.28502 6.24413 6.206 6.170236.61269 6.54593 6.48694 6.43398 6.38584 6.34162 6.30068 6.2625 6.226686.66283 6.59604 6.53702 6.48402 6.43584 6.39159 6.35061 6.3124 6.276546.70768 6.64086 6.58181 6.52879 6.48058 6.43631 6.3953 6.35706 6.321186.74823 6.68139 6.62232 6.56928 6.52105 6.47676 6.43574 6.39747 6.361586.78523 6.71837 6.65929 6.60623 6.55799 6.51368 6.47264 6.43437 6.398456.81925 6.75238 6.69328 6.64021 6.59196 6.54763 6.50658 6.4683 6.432376.85073 6.78384 6.72473 6.67165 6.62339 6.57906 6.538 6.4997 6.463776.88001 6.81312 6.75399 6.70091 6.65263 6.6083 6.56723 6.52892 6.492986.90739 6.84048 6.78135 6.72826 6.67998 6.63563 6.59456 6.55625 6.52036.93309 6.86617 6.80703 6.75393 6.70565 6.66129 6.62021 6.5819 6.54595

6.9573 6.89038 6.83123 6.77812 6.72983 6.68548 6.64439 6.60607 6.570126.98019 6.91326 6.85411 6.80099 6.7527 6.70834 6.66725 6.62892 6.592967.00189 6.93495 6.8758 6.82268 6.77438 6.73001 6.68892 6.65059 6.614637.02252 6.95558 6.89641 6.84329 6.79498 6.75061 6.70952 6.67119 6.635227.04218 6.97523 6.91606 6.86293 6.81462 6.77025 6.72915 6.69081 6.654857.06095 6.99399 6.93482 6.88168 6.83337 6.789 6.74789 6.70956 6.673597.07891 7.01194 6.95277 6.89963 6.85131 6.80694 6.76583 6.72749 6.691527.09612 7.02916 6.96997 6.91683 6.86851 6.82413 6.78302 6.74468 6.70871

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7.11265 7.04568 6.98649 6.93335 6.88503 6.84064 6.79953 6.76119 6.725227.12855 7.06157 7.00238 6.94923 6.90091 6.85652 6.81541 6.77707 6.741097.14386 7.07688 7.01768 6.96453 6.9162 6.87181 6.8307 6.79235 6.756387.15862 7.09164 7.03244 6.97928 6.93095 6.88656 6.84544 6.8071 6.771127.17288 7.10589 7.04668 6.99352 6.94519 6.9008 6.85968 6.82133 6.785357.18666 7.11966 7.06045 7.00729 6.95895 6.91456 6.87344 6.83509 6.799117.19999 7.13299 7.07378 7.02061 6.97228 6.92788 6.88676 6.84841 6.812427.21291 7.1459 7.08669 7.03352 6.98518 6.94078 6.89966 6.8613 6.825327.22544 7.15842 7.0992 7.04603 6.99769 6.95329 6.91216 6.87381 6.837837.23759 7.17058 7.11135 7.05818 7.00983 6.96543 6.9243 6.88595 6.84996

7.2494 7.18238 7.12315 7.06997 7.02162 6.97722 6.93609 6.89774 6.861757.26088 7.19385 7.13462 7.08144 7.03309 6.98868 6.94755 6.90919 6.873217.27204 7.20501 7.14577 7.09259 7.04424 6.99983 6.9587 6.92034 6.884357.28291 7.21587 7.15664 7.10345 7.05509 7.01068 6.96955 6.93119 6.8952

7.2935 7.22646 7.16722 7.11403 7.06567 7.02125 6.98012 6.94176 6.905787.30382 7.23678 7.17753 7.12434 7.07598 7.03156 6.99043 6.95207 6.916087.31389 7.24684 7.18759 7.13439 7.08603 7.04162 7.00048 6.96212 6.926137.32372 7.25666 7.19741 7.14421 7.09585 7.05143 7.01029 6.97193 6.935947.33332 7.26626 7.207 7.1538 7.10543 7.06101 7.01987 6.98151 6.945527.34269 7.27563 7.21637 7.16316 7.11479 7.07037 7.02923 6.99087 6.954877.35186 7.28479 7.22552 7.17232 7.12394 7.07952 7.03838 7.00002 6.964027.36082 7.29375 7.23448 7.18127 7.1329 7.08847 7.04733 7.00896 6.97297

7.3696 7.30252 7.24324 7.19003 7.14165 7.09723 7.05609 7.01772 6.981727.37818 7.3111 7.25182 7.19861 7.15023 7.1058 7.06466 7.02629 6.990297.38659 7.31951 7.26022 7.20701 7.15862 7.11419 7.07305 7.03468 6.998687.39483 7.32774 7.26846 7.21523 7.16685 7.12242 7.08127 7.0429 7.006917.40291 7.33581 7.27652 7.2233 7.17491 7.13048 7.08933 7.05096 7.014977.41083 7.34373 7.28444 7.23121 7.18282 7.13838 7.09724 7.05886 7.02287

7.4186 7.35149 7.29219 7.23896 7.19057 7.14614 7.10499 7.06661 7.030627.42622 7.35911 7.29981 7.24657 7.19818 7.15374 7.11259 7.07422 7.03822

7.4337 7.36659 7.30728 7.25404 7.20565 7.16121 7.12006 7.08168 7.045687.44105 7.37393 7.31462 7.26138 7.21298 7.16854 7.12739 7.08901 7.053017.44826 7.38114 7.32183 7.26858 7.22018 7.17574 7.13459 7.09621 7.060217.45535 7.38822 7.32891 7.27566 7.22726 7.18281 7.14166 7.10328 7.067287.46232 7.39519 7.33587 7.28262 7.23421 7.18977 7.14861 7.11023 7.07423

837 958 1079 12007.1 7.2 7.3 7.4

0.423 0 0.535 0 0.676 0 0.855 0 1.0810.426 1 0.539 1 0.681 1 0.861 1 1.0890.429 2 0.542 2 0.685 2 0.866 2 1.0960.432 3 0.546 3 0.69 3 0.872 3 1.1030.435 4 0.55 4 0.695 4 0.878 4 1.1110.438 5 0.553 5 0.699 5 0.884 5 1.1180.441 6 0.557 6 0.704 6 0.89 6 1.1260.444 7 0.561 7 0.708 7 0.896 7 1.1330.447 8 0.564 8 0.713 8 0.902 8 1.1410.449 9 0.568 9 0.718 9 0.908 9 1.1480.452 10 0.572 10 0.722 10 0.913 10 1.1560.458 12 0.579 12 0.732 12 0.925 12 1.170.464 14 0.586 14 0.741 14 0.937 14 1.185

0.47 16 0.594 16 0.75 16 0.949 16 1.20.476 18 0.601 18 0.76 18 0.961 18 1.2150.482 20 0.608 20 0.769 20 0.972 20 1.23

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0.496 25 0.627 25 0.792 25 1.002 25 1.2680.511 30 0.645 30 0.816 30 1.032 30 1.3050.525 35 0.664 35 0.839 35 1.061 35 1.343

0.54 40 0.683 40 0.863 40 1.091 40 1.380.555 45 0.701 45 0.886 45 1.121 45 1.418

0.57 50 0.72 50 0.91 50 1.151 50 1.4560.584 55 0.738 55 0.934 55 1.181 55 1.4940.599 60 0.757 60 0.957 60 1.211 60 1.5320.614 65 0.776 65 0.981 65 1.241 65 1.570.629 70.001 0.795 70 1.005 70 1.271 70 1.6080.644 75.001 0.814 75.001 1.028 75 1.301 75 1.6460.659 80.001 0.832 80.001 1.052 80 1.331 80 1.6850.673 85.001 0.851 85.001 1.076 85 1.361 85 1.7230.688 90.001 0.87 90.001 1.1 90.001 1.392 90 1.7610.703 95.001 0.889 95.001 1.124 95 1.422 95 1.80.718 100.001 0.908 100.001 1.148 100.001 1.452 100 1.8380.748 110 0.946 110 1.196 110 1.513 110 1.9160.778 120 0.984 120 1.244 120 1.574 120 1.9930.809 130 1.022 130 1.293 130 1.636 130 2.0710.839 140 1.061 140 1.341 140 1.698 140 2.150.869 150.001 1.099 150.001 1.39 150.001 1.759 150.001 2.2280.946 175.002 1.196 175.001 1.513 175.001 1.915 175.001 2.4261.023 200.001 1.293 200.001 1.636 200 2.072 200 2.625

1.1 225.001 1.392 225.001 1.761 225 2.23 225 2.8271.178 250.001 1.491 250.001 1.887 250 2.39 250 3.031.257 275.002 1.59 275.001 2.013 275.001 2.551 275 3.2351.336 300.001 1.691 300.001 2.141 300 2.714 300 3.4421.416 325.002 1.792 325.001 2.27 325 2.877 325 3.651.496 350.001 1.894 350 2.4 350 3.043 349.999 3.8611.577 375.001 1.997 375 2.531 374.999 3.209 374.998 4.0731.659 400.001 2.101 400 2.662 399.999 3.377 399.998 4.2881.741 425.002 2.205 425.001 2.795 425 3.546 424.998 4.5041.824 450.001 2.31 450 2.929 449.999 3.717 449.998 4.7221.907 475.001 2.416 474.999 3.064 474.998 3.889 474.996 4.9421.991 500.001 2.523 500 3.2 499.998 4.063 499.996 5.1642.076 525.001 2.631 524.999 3.337 524.998 4.238 524.996 5.3882.161 550.001 2.739 549.999 3.475 549.998 4.414 549.995 5.6132.247 575 2.848 574.999 3.614 574.997 4.592 574.994 5.8412.333 600 2.958 599.998 3.755 599.996 4.771 599.993 6.07

2.42 625 3.069 624.998 3.896 624.996 4.952 624.993 6.3022.508 650 3.181 649.998 4.039 649.996 5.134 649.992 6.5352.596 675 3.293 674.997 4.182 674.995 5.317 674.991 6.772.685 699.999 3.407 699.997 4.327 699.994 5.503 699.991 7.0082.774 724.998 3.521 724.996 4.473 724.993 5.689 724.989 7.2472.865 749.999 3.636 749.996 4.619 749.993 5.877 749.989 7.4882.955 774.997 3.751 774.995 4.767 774.991 6.067 774.987 7.7313.047 799.997 3.868 799.995 4.916 799.991 6.258 799.986 7.9773.139 824.998 3.985 824.995 5.067 824.991 6.45 824.986 8.2243.232 849.997 4.104 849.994 5.218 849.99 6.644 849.984 8.4733.325 874.996 4.223 874.992 5.371 874.988 6.84 874.982 8.7253.419 899.996 4.343 899.992 5.524 899.988 7.037 899.981 8.9783.514 924.995 4.464 924.991 5.679 924.986 7.235 924.98 9.2333.609 949.995 4.586 949.991 5.835 949.985 7.436 949.979 9.4913.705 974.994 4.709 974.99 5.992 974.985 7.637 974.977 9.75

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3.802 999.993 4.832 999.989 6.151 999.983 7.841 999.976 10.0123.899 1024.993 4.957 1024.988 6.31 1024.982 8.045 1024.974 10.2763.997 1049.992 5.082 1049.987 6.471 1049.981 8.252 1049.972 10.5424.096 1074.992 5.208 1074.987 6.633 1074.98 8.46 1074.971 10.814.195 1099.994 5.335 1099.989 6.796 1099.982 8.669 1099.972 11.084.295 1124.989 5.464 1124.983 6.96 1124.976 8.881 1124.966 11.3524.396 1149.988 5.593 1149.981 7.125 1149.974 9.094 1149.964 11.6274.498 1174.989 5.723 1174.983 7.292 1174.975 9.308 1174.964 11.903

4.6 1199.984 5.854 1199.977 7.46 1199.969 9.524 1199.958 12.1824.703 1224.982 5.985 1224.975 7.629 1224.966 9.742 1224.955 12.4634.806 1249.984 6.118 1249.976 7.8 1249.967 9.961 1249.955 12.7464.911 1274.988 6.252 1274.981 7.971 1274.971 10.182 1274.959 13.0325.016 1299.986 6.386 1299.978 8.144 1299.968 10.405 1299.955 13.3195.122 1324.987 6.522 1324.979 8.319 1324.968 10.629 1324.955 13.6095.228 1349.981 6.659 1349.973 8.494 1349.962 10.856 1349.947 13.9025.335 1374.978 6.796 1374.97 8.671 1374.958 11.083 1374.943 14.1965.444 1399.979 6.935 1399.97 8.849 1399.958 11.313 1399.943 14.4935.552 1424.983 7.074 1424.974 9.028 1424.961 11.544 1424.945 14.7925.662 1449.98 7.215 1449.97 9.209 1449.957 11.777 1449.941 15.0935.772 1474.98 7.356 1474.97 9.391 1474.957 12.012 1474.939 15.3975.883 1499.973 7.499 1499.963 9.574 1499.949 12.248 1499.931 15.7035.995 1524.98 7.642 1524.969 9.759 1524.955 12.486 1524.936 16.0126.108 1549.969 7.787 1549.958 9.945 1549.943 12.726 1549.924 16.3236.221 1574.973 7.932 1574.961 10.132 1574.945 12.968 1574.925 16.6366.335 1599.968 8.079 1599.956 10.321 1599.94 13.212 1599.919 16.951

6.45 1624.968 8.226 1624.955 10.511 1624.938 13.457 1624.917 17.2696.566 1649.97 8.375 1649.957 10.702 1649.94 13.704 1649.918 17.596.682 1674.966 8.524 1674.952 10.895 1674.934 13.954 1674.911 17.9126.799 1699.964 8.675 1699.95 11.089 1699.932 14.204 1699.908 18.2386.917 1724.967 8.827 1724.952 11.285 1724.933 14.457 1724.909 18.5667.036 1749.961 8.98 1749.946 11.482 1749.927 14.712 1749.901 18.8967.156 1774.96 9.133 1774.944 11.68 1774.924 14.968 1774.898 19.2287.277 1799.961 9.288 1799.945 11.879 1799.924 15.227 1799.897 19.5647.398 1824.955 9.444 1824.939 12.08 1824.917 15.487 1824.889 19.901

7.52 1849.953 9.601 1849.936 12.283 1849.914 15.749 1849.885 20.2427.643 1874.954 9.76 1874.936 12.487 1874.913 16.013 1874.884 20.5847.767 1899.958 9.919 1899.94 12.693 1899.916 16.279 1899.886 20.937.891 1924.955 10.079 1924.936 12.9 1924.912 16.547 1924.88 21.2788.017 1949.955 10.241 1949.936 13.108 1949.911 16.817 1949.878 21.6288.143 1974.948 10.403 1974.928 13.318 1974.903 17.089 1974.869 21.981

8.27 1999.944 10.567 1999.924 13.529 1999.897 17.362 1999.863 22.3378.398 2024.944 10.732 2024.923 13.742 2024.896 17.638 2024.86 22.6958.527 2049.947 10.898 2049.925 13.956 2049.897 17.916 2049.861 23.0568.657 2074.942 11.065 2074.92 14.172 2074.891 18.195 2074.854 23.428.788 2099.941 11.233 2099.918 14.39 2099.889 18.477 2099.85 23.7868.919 2124.943 11.403 2124.92 14.609 2124.889 18.761 2124.85 24.1559.541 2240.913 12.204 2240.886 15.644 2240.852 20.104 2240.807 25.902

10.122 2346.185 12.953 2346.155 16.613 2346.117 21.362 2346.067 27.5410.719 2451.328 13.723 2451.295 17.61 2451.252 22.655 2451.197 29.22511.331 2556.342 14.514 2556.306 18.634 2556.258 23.986 2556.197 30.95911.96 2661.227 15.326 2661.187 19.687 2661.135 25.354 2661.067 32.742

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0 0.5 1 1.5 2 2.5 3 3.5 4 4.56.6

6.8

7

7.2

7.4

7.6

7.8

8Column D Column BColumn D Column CColumn D Column DColumn D Column EColumn D Column FColumn D Column GColumn D Column HColumn D Column IColumn D Column J

ppm Li

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1986 2047 2108 2169 2230 2291 23521400.002 1500.001 1600.002 1700.005 1799.998 1900.002 1999.9965.06918 5.05298 5.03757 5.02285 5.00876 4.99523 4.9822 05.40129 5.37489 5.35 5.32642 5.30402 5.28268 5.26229 15.62903 5.59916 5.57089 5.54402 5.51841 5.49393 5.47049 25.78582 5.75481 5.72539 5.69739 5.67064 5.64503 5.62045 35.90271 5.87123 5.84133 5.81284 5.78561 5.75952 5.73444 45.99524 5.96353 5.9334 5.90466 5.87719 5.85084 5.82552 56.07161 6.03976 6.00949 5.98062 5.95301 5.92652 5.90105 66.13652 6.10459 6.07424 6.04528 6.01758 5.99101 5.96545 76.19291 6.16093 6.13052 6.10152 6.07376 6.04713 6.02151 86.24274 6.21072 6.18027 6.15123 6.12343 6.09676 6.07111 96.28735 6.2553 6.22483 6.19576 6.16794 6.14124 6.11555 106.32772 6.29566 6.26517 6.23607 6.20823 6.18151 6.1558 116.36459 6.33251 6.302 6.27289 6.24503 6.2183 6.19257 126.39849 6.3664 6.33588 6.30676 6.27889 6.25214 6.22641 136.42988 6.39778 6.36725 6.33812 6.31024 6.28348 6.25774 146.45909 6.42698 6.39644 6.36731 6.33942 6.31265 6.2869 15

6.4864 6.45428 6.42374 6.3946 6.36671 6.33993 6.31418 166.51204 6.47992 6.44938 6.42023 6.39233 6.36555 6.33979 17

6.5362 6.50408 6.47353 6.44438 6.41648 6.3897 6.36393 186.55905 6.52692 6.49637 6.46721 6.43931 6.41252 6.38676 196.58071 6.54858 6.51803 6.48887 6.46096 6.43417 6.4084 20

6.6013 6.56917 6.53861 6.50945 6.48154 6.45475 6.42898 216.62092 6.58879 6.55823 6.52907 6.50116 6.47437 6.44859 226.63966 6.60753 6.57696 6.5478 6.51989 6.4931 6.46732 236.65759 6.62546 6.59489 6.56573 6.53781 6.51102 6.48524 246.67478 6.64264 6.61208 6.58291 6.555 6.5282 6.50243 25

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6.69129 6.65915 6.62858 6.59942 6.5715 6.5447 6.51892 266.70716 6.67502 6.64445 6.61528 6.58737 6.56057 6.53479 276.72244 6.6903 6.65974 6.63057 6.60265 6.57585 6.55007 286.73718 6.70504 6.67448 6.64531 6.61739 6.59059 6.56481 296.75142 6.71927 6.68871 6.65954 6.63162 6.60482 6.57904 306.76518 6.73303 6.70246 6.67329 6.64538 6.61858 6.5928 316.77849 6.74634 6.71578 6.68661 6.65869 6.63189 6.60611 326.79139 6.75924 6.72867 6.6995 6.67158 6.64479 6.61901 336.80389 6.77174 6.74118 6.71201 6.68409 6.65729 6.63151 346.81603 6.78388 6.75331 6.72414 6.69622 6.66942 6.64364 356.82781 6.79567 6.7651 6.73593 6.70801 6.68121 6.65543 366.83927 6.80712 6.77655 6.74738 6.71946 6.69267 6.66689 376.85042 6.81827 6.7877 6.75853 6.73061 6.70381 6.67803 386.86127 6.82912 6.79855 6.76938 6.74146 6.71466 6.68889 396.87184 6.83969 6.80912 6.77995 6.75203 6.72523 6.69946 406.88214 6.84999 6.81942 6.79025 6.76233 6.73554 6.70976 416.89219 6.86004 6.82947 6.8003 6.77238 6.74559 6.71981 42

6.902 6.86985 6.83928 6.81011 6.78219 6.7554 6.72962 436.91158 6.87943 6.84886 6.81969 6.79177 6.76498 6.7392 446.92093 6.88879 6.85821 6.82905 6.80113 6.77434 6.74856 456.93008 6.89793 6.86736 6.83819 6.81028 6.78348 6.75771 466.93903 6.90688 6.87631 6.84714 6.81922 6.79243 6.76665 476.94778 6.91563 6.88506 6.85589 6.82798 6.80118 6.77541 486.95635 6.9242 6.89363 6.86446 6.83655 6.80975 6.78398 496.96474 6.93259 6.90202 6.87285 6.84494 6.81815 6.79237 506.97296 6.94081 6.91024 6.88108 6.85316 6.82637 6.8006 516.98102 6.94887 6.9183 6.88913 6.86122 6.83443 6.80865 526.98892 6.95677 6.9262 6.89703 6.86912 6.84233 6.81656 536.99667 6.96452 6.93395 6.90478 6.87687 6.85008 6.82431 547.00428 6.97213 6.94156 6.91239 6.88447 6.85768 6.83191 557.01174 6.97959 6.94902 6.91985 6.89194 6.86515 6.83938 567.01907 6.98692 6.95635 6.92718 6.89927 6.87248 6.84671 577.02626 6.99411 6.96354 6.93438 6.90646 6.87967 6.8539 587.03333 7.00118 6.97061 6.94145 6.91353 6.88675 6.86098 597.04028 7.00813 6.97756 6.9484 6.92048 6.8937 6.86793 60

1321 14427.5 7.6

0 1.369 0 1.734 01 1.378 1 1.746 12 1.388 2 1.758 23 1.397 3 1.77 34 1.406 4 1.782 45 1.416 5 1.794 56 1.425 6 1.806 67 1.435 7 1.818 78 1.444 8 1.83 89 1.453 9 1.841 9

10 1.463 10 1.853 1012 1.482 12 1.877 1114 1.501 14 1.901 1216 1.52 16 1.925 1318 1.538 18 1.949 1420 1.557 20 1.973 15

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25 1.605 25 2.033 1630 1.652 30 2.094 1735 1.7 35 2.154 1840 1.748 40 2.215 1945 1.796 45 2.275 2050 1.844 50 2.336 2155 1.892 55 2.397 2260 1.94 60 2.458 2365 1.988 65 2.52 2470 2.036 70 2.581 2575 2.085 75 2.643 2680 2.133 80 2.704 2785 2.182 85 2.766 2890 2.231 90 2.828 2995 2.28 95 2.89 30

100 2.329 100 2.952 31110 2.427 109.999 3.077 32120 2.526 119.999 3.203 33130 2.625 129.999 3.329 34140 2.724 139.999 3.455 35

150.001 2.824 150 3.582 36175 3.075 175 3.902 37200 3.329 199.999 4.226 38

224.999 3.586 224.998 4.553 39249.999 3.844 249.998 4.883 40274.999 4.106 274.998 5.217 41299.999 4.37 299.997 5.554 42324.998 4.636 324.997 5.895 43349.997 4.905 349.996 6.239 44374.997 5.176 374.995 6.587 45399.996 5.451 399.994 6.937 46424.996 5.727 424.994 7.292 47449.996 6.006 449.993 7.65 48474.994 6.288 474.991 8.011 49499.994 6.572 499.991 8.376 50524.993 6.859 524.99 8.744 51549.992 7.148 549.989 9.115 52574.991 7.44 574.987 9.491 53

599.99 7.734 599.985 9.869 54624.989 8.031 624.984 10.252 55649.988 8.331 649.983 10.638 56674.987 8.633 674.982 11.027 57699.986 8.938 699.98 11.42 58724.984 9.246 724.978 11.817 59749.984 9.556 749.977 12.216 60774.981 9.869 774.974 12.62 61

799.98 10.185 799.972 13.028 62824.979 10.503 824.971 13.439 63849.977 10.825 849.969 13.854 64874.975 11.148 874.966 14.272 65899.974 11.475 899.964 14.695 66924.972 11.805 924.961 15.121 67

949.97 12.136 949.959 15.55 68974.968 12.471 974.957 15.984 69

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999.966 12.809 999.953 16.421 701024.964 13.15 1024.951 16.863 711049.962 13.493 1049.948 17.308 721074.96 13.84 1074.945 17.757 73

1099.961 14.189 1099.945 18.209 741124.954 14.541 1124.938 18.666 751149.951 14.896 1149.934 19.126 761174.951 15.254 1174.933 19.591 771199.944 15.615 1199.925 20.059 781224.94 15.979 1224.921 20.532 79

1249.939 16.345 1249.919 21.008 801274.942 16.715 1274.921 21.489 811299.938 17.088 1299.916 21.973 821324.937 17.464 1324.914 22.462 831349.929 17.843 1349.905 22.954 841374.924 18.224 1374.899 23.451 851399.923 18.609 1399.897 23.952 861424.925 18.997 1424.898 24.457 871449.919 19.389 1449.891 24.966 881474.917 19.783 1474.888 25.479 891499.908 20.18 1499.878 25.998 901524.912 20.581 1524.881 26.519 911549.899 20.984 1549.866 27.045 921574.899 21.391 1574.866 27.576 931599.893 21.801 1599.858 28.11 941624.889 22.215 1624.853 28.649 951649.889 22.631 1649.852 29.192 961674.882 23.051 1674.843 29.739 971699.878 23.474 1699.838 30.291 981724.877 23.9 1724.835 30.847 991749.869 24.33 1749.826 31.408 1001774.864 24.763 1774.82 31.973 1011799.862 25.199 1799.817 32.543 1021824.853 25.639 1824.806 33.116 1031849.848 26.083 1849.799 33.695 1041874.845 26.529 1874.795 34.278 1051899.846 26.979 1899.794 34.865 1061924.84 27.432 1924.786 35.457 107

1949.836 27.889 1949.781 36.054 1081974.826 28.349 1974.769 36.655 1091999.818 28.813 1999.76 37.261 1102024.814 29.28 2024.754 37.872 1112049.813 29.75 2049.752 38.487 1122074.805 30.224 2074.742 39.107 113

2099.8 30.702 2099.735 39.731 1142124.798 31.183 2124.731 40.36 1152240.749 33.463 2240.672 43.342 1162346.002 35.6 2345.916 46.139 1172451.124 37.801 2451.029 49.02 1182556.117 40.066 2556.011 51.986 1192660.979 42.397 2660.863 55.039 120

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PT. TT NA2OIN^0.5 B2O3IN solid NA2OIN ref t/C1 94 0 2.36528 BOH3PPT 0 1967NH 942 94 0.447213595 3.14611 BOH3PPT 0.2 1967NH 943 94 0.632455532 3.94312 BOH3PPT 0.4 1967NH 944 94 0.774596669 4.75445 BOH3PPT 0.6 1967NH 945 94 0.894427191 5.58046 BOH3PPT 0.8 1967NH 946 94 1 6.42142 BOH3PPT 1 1967NH 947 94 1.095445115 7.27746 BOH3PPT 1.2 1967NH 948 94 1.140175425 7.71114 BOH3PPT 1.3 1967NH 949 94 1.183215957 8.14856 BOH3PPT 1.4 1967NH 9410 94 1.264911064 9.03444 BOH3PPT 1.6 1967NH 9411 94 1.341640786 9.95369 BOH3PPT 1.8 1967NH 9412 94 1.414213562 10.9028 BOH3PPT 2 1967NH 941 94 1.303840481 9.62833 NA2B10O.10H2O 1.72 94 1.341640786 9.57695 NA2B10O.10H2O 1.8 1967NH 943 94 1.414213562 9.92325 NA2B10O.10H2O 2 1967NH 944 94 1.449137675 10.1672 NA2B10O.10H2O 2.1 1967NH 945 94 1.483239697 10.44 NA2B10O.10H2O 2.2 1967NH 946 94 1.516575089 10.7355 NA2B10O.10H2O 2.3 1967NH 947 94 1.549193338 11.0499 NA2B10O.10H2O 2.4 1967NH 948 94 1.58113883 11.381 NA2B10O.10H2O 2.5 1967NH 949 94 1.61245155 11.7271 NA2B10O.10H2O 2.6 1967NH 9410 94 1.643167673 12.0873 NA2B10O.10H2O 2.7 1967NH 9411 94 1.673320053 12.461 NA2B10O.10H2O 2.8 1967NH 9412 94 1.702938637 12.8479 NA2B10O.10H2O 2.9 1967NH 9413 94 1.732050808 13.2479 NA2B10O.10H2O 3 1967NH 9414 94 1.843908891 14.9797 NA2B10O.10H2O 3.4 1967NH 9415 94 1.949358869 16.9113 NA2B10O.10H2O 3.8 1967NH 9416 94 2 17.9203 NA2B10O.10H2O 4 1967NH 9417 94 2.097617696 19.8433 NA2B10O.10H2O 4.4 1967NH 9418 94 2.19089023 21.4596 NA2B10O.10H2O 4.8 1967NH 9419 94 2.236067977 22.1583 NA2B10O.10H2O 5 1967NH 9420 94 2.323790008 23.4037 NA2B10O.10H2O 5.4 1967NH 9421 94 2.34520788 23.6913 NA2B10O.10H2O 5.5 1967NH 9422 94 2.366431913 23.9717 NA2B10O.10H2O 5.6 1967NH 9423 94 2.387467277 24.2458 NA2B10O.10H2O 5.7 1967NH 9424 94 2.408318916 24.5145 NA2B10O.10H2O 5.8 1967NH 9425 94 2.449489743 25.0391 NA2B10O.10H2O 6 1967NH 9426 94 2.469817807 25.2035 NA2B10O.10H2O 6.1 1967NH 9427 94 2.48997992 25.3596 NA2B10O.10H2O 6.2 1967NH 9428 94 2.48997992 25.3596 NA2B10O.10H2O 6.2 1967NH 9429 94 2.529822128 25.6719 NA2B10O.10H2O 6.4 1967NH 941 94 1.861464477 15 NA4B102O.7H2O 3.46505 1967NH 942 94 1.795068244 14 NA4B102O.7H2O 3.22227 1967NH 943 94 1.727558971 13 NA4B102O.7H2O 2.98446 1967NH 944 94 1.658876126 12 NA4B102O.7H2O 2.75187 1967NH 945 94 1.588980805 11 NA4B102O.7H2O 2.52486 1967NH 946 94 1.517843865 10 NA4B102O.7H2O 2.303857 94 1.445448027 9 NA4B102O.7H2O 2.089328 94 1.371801735 8 NA4B102O.7H2O 1.881849 94 1.33451864 7.5 NA4B102O.7H2O 1.7809410 94 1.296954124 7 NA4B102O.7H2O 1.6820911 94 1.259146536 6.5 NA4B102O.7H2O 1.5854512 94 1.22116338 6 NA4B102O.7H2O 1.49124

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

5

10

15

20

25

30

35

t=94C

BOH3PPTNA2B10O.10H2ONA4B102O.7H2ONA2B4O7.4H2ONA4B10O.5H2ONA2B2O4.4H2ONA2B2O4.1H2O

m^0.5 Na2O

m-B

2O3

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13 94 1.183165246 5.5 NA4B102O.7H2O 1.3998814 94 1.145486796 5 NA4B102O.7H2O 1.3121415 94 1.108873302 4.5 NA4B102O.7H2O 1.229616 94 1.075165104 4 NA4B102O.7H2O 1.1559817 94 1.049947618 3.5 NA4B102O.7H2O 1.1023918 94 1.065645344 3 NA4B102O.7H2O 1.135619 94 1.048808848 3.15936 NA4B102O.7H2O 1.120 94 1.095445115 2.92626 NA4B102O.7H2O 1.221 94 1.13137085 2.91824 NA4B102O.7H2O 1.2822 94 1.140175425 2.92287 NA4B102O.7H2O 1.31 94 1.183215957 2.96835 NA4B102O.7H2O 1.42 94 1.264911064 3.12063 NA4B102O.7H2O 1.63 94 1.303840481 3.2131 NA4B102O.7H2O 1.74 94 1.341640786 3.31215 NA4B102O.7H2O 1.85 94 1.414213562 3.65497 NA4B102O.7H2O 21 94 1.378404875 3.37457 NA2B4O7.4H2O 1.92 94 1.414213562 3.39736 NA2B4O7.4H2O 23 94 1.58113883 3.7528 NA2B4O7.4H2O 2.54 94 1.732050808 4.23295 NA2B4O7.4H2O 35 94 1.870828693 4.75338 NA2B4O7.4H2O 3.56 94 2 5.29484 NA2B4O7.4H2O 47 94 2.121320344 5.85226 NA2B4O7.4H2O 4.58 94 2.236067977 6.42554 NA2B4O7.4H2O 59 94 2.323790008 6.89702 NA2B4O7.4H2O 5.410 94 2.408318916 7.38173 NA2B4O7.4H2O 5.811 94 2.449489743 7.62966 NA2B4O7.4H2O 612 94 2.529822128 8.13796 NA2B4O7.4H2O 6.413 94 2.607680962 8.66452 NA2B4O7.4H2O 6.814 94 2.645751311 8.93522 NA2B4O7.4H2O 715 94 2.720294102 9.4924 NA2B4O7.4H2O 7.416 94 2.792848009 10.0714 NA2B4O7.4H2O 7.817 94 2.828427125 10.3693 NA2B4O7.4H2O 818 94 2.898275349 10.9816 NA2B4O7.4H2O 8.419 94 2.966479395 11.6155 NA2B4O7.4H2O 8.820 94 3 11.9404 NA2B4O7.4H2O 921 94 3.065941943 12.6053 NA2B4O7.4H2O 9.422 94 3.130495168 13.2894 NA2B4O7.4H2O 9.823 94 3.16227766 13.6383 NA2B4O7.4H2O 1024 94 3.224903099 14.3491 NA2B4O7.4H2O 10.425 94 3.286335345 15.076 NA2B4O7.4H2O 10.826 94 3.31662479 15.4449 NA2B4O7.4H2O 1127 94 3.376388603 16.1921 NA2B4O7.4H2O 11.428 94 3.435112807 16.9484 NA2B4O7.4H2O 11.829 94 3.464101615 17.3284 NA2B4O7.4H2O 1230 94 3.521363372 18.0878 NA2B4O7.4H2O 12.431 94 3.577708764 18.8397 NA2B4O7.4H2O 12.832 94 3.605551275 19.2105 NA2B4O7.4H2O 1333 94 3.660601044 19.9381 NA2B4O7.4H2O 13.434 94 3.714835124 20.6455 NA2B4O7.4H2O 13.835 94 3.741657387 20.9922 NA2B4O7.4H2O 1436 94 3.794733192 21.6751 NA2B4O7.4H2O 14.437 94 3.847076812 22.3507 NA2B4O7.4H2O 14.838 94 3.872983346 22.6889 NA2B4O7.4H2O 1539 94 3.924283374 23.3725 NA2B4O7.4H2O 15.4

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40 94 3.974921383 24.0754 NA2B4O7.4H2O 15.841 94 4 24.4377 NA2B4O7.4H2O 1642 94 4.049691346 25.1918 NA2B4O7.4H2O 16.443 94 4.098780306 25.9962 NA2B4O7.4H2O 16.844 94 4.123105626 26.4216 NA2B4O7.4H2O 1745 94 4.135214626 26.6409 NA2B4O7.4H2O 17.146 94 4.147288271 26.8648 NA2B4O7.4H2O 17.247 94 4.159326869 27.0937 NA2B4O7.4H2O 17.348 94 4.171330723 27.6531 NA2B4O7.4H2O 17.449 94 4.219004622 29.9727 NA2B4O7.4H2O 17.850 94 4.242640687 31.1325 NA2B4O7.4H2O 181 94 4.123105626 27.165 NA4B10O.5H2O 172 94 4.16533312 27.1581 NA4B10O.5H2O 17.353 94 4.183300133 27.3332 NA4B10O.5H2O 17.54 94 4.207136794 27.5728 NA4B10O.5H2O 17.75 94 4.242640687 27.9477 NA4B10O.5H2O 186 94 4.266145802 28.2099 NA4B10O.5H2O 18.27 94 4.301162634 28.6251 NA4B10O.5H2O 18.58 94 4.335896678 29.0326 NA4B10O.5H2O 18.89 94 4.358898944 29.1768 NA4B10O.5H2O 1910 94 4.38178046 29.3211 NA4B10O.5H2O 19.211 94 4.415880433 29.5375 NA4B10O.5H2O 19.512 94 4.438468204 29.6817 NA4B10O.5H2O 19.713 94 4.460941605 29.826 NA4B10O.5H2O 19.914 94 4.472135955 29.8981 NA4B10O.5H2O 2015 94 4.494441011 30.0423 NA4B10O.5H2O 20.216 94 4.527692569 30.2587 NA4B10O.5H2O 20.517 94 4.549725266 30.403 NA4B10O.5H2O 20.71 94 4.376071297 29.6814 NA2B4O7.2H2O 19.152 94 4.38178046 29.6988 NA2B4O7.2H2O 19.23 94 4.393176527 29.7345 NA2B4O7.2H2O 19.34 94 4.404543109 29.772 NA2B4O7.2H2O 19.45 94 4.415880433 29.8118 NA2B4O7.2H2O 19.56 94 4.472135955 30.1051 NA2B4O7.2H2O 207 94 4.527692569 30.6675 NA2B4O7.2H2O 20.58 94 4.582575695 31.4535 NA2B4O7.2H2O 219 94 4.636809248 32.3775 NA2B4O7.2H2O 21.510 94 4.69041576 33.3854 NA2B4O7.2H2O 2211 94 4.74341649 34.4453 NA2B4O7.2H2O 22.512 94 4.795831523 35.5471 NA2B4O7.2H2O 231 94 4.16533312 23.1856 NA2B2O4.4H2O 17.352 94 4.062019202 22.4077 NA2B2O4.4H2O 16.53 94 4 21.7741 NA2B2O4.4H2O 164 94 3.937003937 21.0779 NA2B2O4.4H2O 15.55 94 3.872983346 20.3264 NA2B2O4.4H2O 156 94 3.807886553 19.5308 NA2B2O4.4H2O 14.57 94 3.741657387 18.7064 NA2B2O4.4H2O 148 94 3.674234614 17.8689 NA2B2O4.4H2O 13.59 94 3.605551275 17.0302 NA2B2O4.4H2O 1310 94 3.535533906 16.197 NA2B2O4.4H2O 12.511 94 3.464101615 15.3719 NA2B2O4.4H2O 1212 94 3.391164992 14.555 NA2B2O4.4H2O 11.513 94 3.31662479 13.7447 NA2B2O4.4H2O 1114 94 3.240370349 12.9385 NA2B2O4.4H2O 10.5

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15 94 3.16227766 12.1337 NA2B2O4.4H2O 1016 94 3.082207001 11.3265 NA2B2O4.4H2O 9.517 94 3 10.5125 NA2B2O4.4H2O 918 94 2.915475947 9.68439 NA2B2O4.4H2O 8.519 94 2.828427125 8.82757 NA2B2O4.4H2O 820 94 2.738612788 7.89154 NA2B2O4.4H2O 7.521 94 2.645751311 6.90728 NA2B2O4.4H2O 722 94 2.644772202 6.9 NA2B2O4.4H2O 6.9948222 94 2.631301959 6.8 NA2B2O4.4H2O 6.9237523 94 2.590920686 6.5 NA2B2O4.4H2O 6.71287

94 2.524824746 6 NA2B2O4.4H2O 6.3747494 2.461789999 5.5 NA2B2O4.4H2O 6.0604194 2.40426704 5 NA2B2O4.4H2O 5.780594 2.356342505 4.5 NA2B2O4.4H2O 5.5523594 2.325471995 4 NA2B2O4.4H2O 5.4078294 2.326542499 3.5 NA2B2O4.4H2O 5.412894 2.40094773 3 NA2B2O4.4H2O 5.7645594 2.43710484 2.9 NA2B2O4.4H2O 5.9394894 2.492245975 2.8 NA2B2O4.4H2O 6.2112994 2.613937643 2.7 NA2B2O4.4H2O 6.83267

1 94 3.937003937 18.9418 NA2B2O4.1H2O 15.52 94 4 20.5023 NA2B2O4.1H2O 163 94 4.062019202 22.0628 NA2B2O4.1H2O 16.54 94 4.123105626 23.4917 NA2B2O4.1H2O 175 94 4.183300133 24.9561 NA2B2O4.1H2O 17.56 94 4.207136794 25.5739 NA2B2O4.1H2O 17.77 94 4.242640687 26.5271 NA2B2O4.1H2O 188 94 4.266145802 27.176 NA2B2O4.1H2O 18.29 94 4.301162634 28.1625 NA2B2O4.1H2O 18.510 94 4.335896678 29.3664 NA2B2O4.1H2O 18.811 94 4.358898944 30.9026 NA2B2O4.1H2O 19

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wt% Na2O wt% Na2O wt% B2O3 m Na2O m Na2O m B2O3 solid2.4 2.4 23.04 0.7207 0.5193 4.4387 H3BO34.48 4.48 31.92 1.0661 1.1365 7.2092 H3BO3 + 2Na2O.9B2O3.11H2O6.1 6.1 38.59 1.3339 1.7794 10.022 H3BO3 + Na2O.5B2O3.10H2O (m)4.48 4.48 31.92 1.0661 1.1365 7.2092 H3BO3 + 2Na2O.9B2O3.11H2O5.1 5.1 30.94 1.1342 1.2865 6.9485 2Na2O.9B2O3.11H2O5.96 5.96 31.06 1.2357 1.5268 7.084 2Na2O.9B2O3.11H2O7.07 7.07 32.78 1.3771 1.8964 7.828 2Na2O.9B2O3.11H2O + 2Na2O.5.1B2O3.7H2O7.5 7.5 33.56 1.4328 2.0531 8.1788 2Na2O.9B2O3.11H2O + 2Na2O.5B2O3.5H2O (m)7.11 7.11 39.8 1.47 2.1608 10.768 Na2O.5B2O3.10H2O (m)7.07 7.07 32.78 1.3771 1.8964 7.828 2Na2O.5.1B2O3.7H2O + 2Na2O.9B2O3.11H2O5.85 5.85 23.94 1.1595 1.3443 4.8978 2Na2O.5.1B2O3.7H2O5.48 5.48 18.96 1.0817 1.1701 3.6043 2Na2O.5.1B2O3.7H2O (m)

5.95 5.95 16.71 1.1141 1.2413 3.1035 2Na2O.5.1B2O3.7H2O (m)7.45 7.45 17.72 1.2674 1.6063 3.4015 2Na2O.5.1B2O3.7H2O (m)9.46 9.46 20.43 1.4755 2.177 4.1857 2Na2O.5.1B2O3.7H2O + Na2O.2B2O3.5H2O (m)7.5 7.5 33.56 1.4328 2.0531 8.1788 2Na2O.9B2O3.11H2O + 2Na2O.5B2O3.5H2O (m)6.22 6.22 25.4 1.2114 1.4676 5.3356 2Na2O.5B2O3.5H2O (m)5.36 5.36 18.6 1.0664 1.1373 3.5136 2Na2O.5B2O3.5H2O5.75 5.75 16.22 1.0904 1.1889 2.9858 2Na2O.5B2O3.5H2O6.27 6.27 16.2 1.1423 1.3048 3.0014 2Na2O.5B2O3.5H2O7.55 7.55 17.1 1.2715 1.6166 3.2598 2Na2O.5B2O3.5H2O + Na2O.2B2O3.4H2O9.78 9.78 20.11 1.5002 2.2506 4.1201 2Na2O.5B2O3.5H2O + Na2O.2B2O3.5H2O (m)7.67 7.67 19.16 1.3005 1.6913 3.7613 Na2O.2B2O3.4H2O (m)7.55 7.55 17.1 1.2715 1.6166 3.2598 Na2O.2B2O3.4H2O + 2Na2O.5B2O3.5H2O7.54 7.54 16.95 1.2693 1.6111 3.2244 Na2O.2B2O3.4H2O7.66 7.66 16.48 1.2764 1.6292 3.1205 Na2O.2B2O3.4H2O8.3 8.3 15.86 1.3288 1.7657 3.0039 Na2O.2B2O3.4H2O9.58 9.58 16.5 1.446 2.091 3.2063 Na2O.2B2O3.4H2O10.3 10.3 17.2 1.514 2.2922 3.4078 Na2O.2B2O3.4H2O12.47 12.47 19.97 1.7257 2.978 4.2459 Na2O.2B2O3.4H2O16.32 16.32 25.1 2.1201 4.4949 6.1546 Na2O.2B2O3.4H2O25.81 25.81 41.55 3.5718 12.758 18.285 Na2O.2B2O3.4H2O9.42 9.42 23.63 1.5067 2.2701 5.0698 Na2O.2B2O3.5H2O (m)9.34 9.34 21.04 1.4712 2.1645 4.341 Na2O.2B2O3.5H2O (m)10.5 10.5 19.71 1.558 2.4274 4.0567 Na2O.2B2O3.5H2O (m)12.8 12.8 21.84 1.7776 3.1597 4.7998 Na2O.2B2O3.5H2O (m)15.54 15.54 25.58 2.0636 4.2583 6.2404 Na2O.2B2O3.5H2O (m)20.22 20.22 32.81 2.6354 6.9456 10.034 Na2O.2B2O3.5H2O (m)24.03 24.03 40.16 3.2904 10.827 16.109 Na2O.2B2O3.5H2O (m)8.9 8.9 43 1.7278 2.9853 12.841 Na2O.5B2O3.10H2O + 2Na2O.5.1B2O3.7H2O (m)9.6 9.6 44.52 1.8374 3.376 13.938 Na2O.5B2O3.10H2O + 2Na2O.5B2O3.5H2O (m)

27.56 27.56 39.6 3.6797 13.54 17.321 Na2O.B2O3.4H2O24.86 24.86 32.11 3.0531 9.3213 10.719 Na2O.B2O3.4H2O23.19 23.19 26.33 2.7225 7.4119 7.4922 Na2O.B2O3.4H2O23.03 23.03 24.2 2.6536 7.0413 6.5873 Na2O.B2O3.4H2O

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2Na2O.9B2O3.11H2O + 2Na2O.5.1B2O3.7H2O2Na2O.9B2O3.11H2O + 2Na2O.5B2O3.5H2O (m)

2Na2O.5.1B2O3.7H2O + 2Na2O.9B2O3.11H2O

2Na2O.5.1B2O3.7H2O + Na2O.2B2O3.5H2O (m)2Na2O.9B2O3.11H2O + 2Na2O.5B2O3.5H2O (m)

2Na2O.5B2O3.5H2O + Na2O.2B2O3.5H2O (m)

Na2O.5B2O3.10H2O + 2Na2O.5.1B2O3.7H2O (m)Na2O.5B2O3.10H2O + 2Na2O.5B2O3.5H2O (m)

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PT. TTNA2OIN^0.5B2O3IN solid NA2OIN1 75 0 1.56031 BOH3PPT 02 75 0.4472136 2.31064 BOH3PPT 0.23 75 0.63245553 3.07558 BOH3PPT 0.44 75 0.77459667 3.85488 BOH3PPT 0.65 75 0.89442719 4.6497 BOH3PPT 0.86 75 1 5.46106 BOH3PPT 17 75 1.04880885 5.87322 BOH3PPT 1.18 75 1.09544512 6.33675 BOH3PPT 1.29 75 1.14017543 6.82901 BOH3PPT 1.31 75 1.07238053 6.04169 NA2B10O.10H2 1.152 75 1.09544512 6.10804 NA2B10O.10H2 1.23 75 1.13137085 6.24633 NA2B10O.10H2 1.284 75 1.14017543 6.28566 NA2B10O.10H2 1.35 75 1.18321596 6.50384 NA2B10O.10H2 1.46 75 1.26491106 7.01675 NA2B10O.10H2 1.67 75 1.30384048 7.30033 NA2B10O.10H2 1.78 75 1.34164079 7.56418 NA2B10O.10H2 1.89 75 1.41421356 8.03187 NA2B10O.10H2 210 75 1.44913767 8.26572 NA2B10O.10H2 2.1

1 75 1.36132656 8 NA4B102O.7H2 1.85322 75 1.32650669 7.5 NA4B102O.7H2 1.75963 75 1.28630479 7 NA4B102O.7H2 1.65464 75 1.24513453 6.5 NA4B102O.7H2 1.55045 75 1.20356969 6 NA4B102O.7H2 1.44866 75 1.16164538 5.5 NA4B102O.7H2 1.34947 75 1.11945969 5 NA4B102O.7H2 1.25328 75 1.07724185 4.5 NA4B102O.7H2 1.16059 75 1.03555782 4 NA4B102O.7H2 1.072410 75 0.99595432 3.5 NA4B102O.7H2 0.991911 75 0.96344901 3 NA4B102O.7H2 0.928212 75 0.95908446 2.9 NA4B102O.7H2 0.919813 75 0.95616578 2.8 NA4B102O.7H2 0.914314 75 0.95546638 2.7 NA4B102O.7H2 0.912915 75 0.95858698 2.6 NA4B102O.7H2 0.918916 75 0.9702108 2.5 NA4B102O.7H2 0.941317 75 0.97238778 2.49 NA4B102O.7H2 0.945518 75 0.97491487 2.48 NA4B102O.7H2 0.950519 75 0.97789672 2.47 NA4B102O.7H2 0.956320 75 0.98150242 2.46 NA4B102O.7H2 0.963321 75 0.98603854 2.45 NA4B102O.7H2 0.972322 75 0.99220058 2.44 NA4B102O.7H2 0.984523 75 1.00263652 2.43 NA4B102O.7H2 1.00531 75 1 2.43184 NA4B102O.7H2 12 75 1.04880885 2.44325 NA4B102O.7H2 1.13 75 1.09544512 2.59183 NA4B102O.7H2 1.24 75 1.13137085 2.75062 NA4B102O.7H2 1.28

1 75 1.08166538 2.49803 NA2B4O7.4H2O 1.172 75 1.09544512 2.36252 NA2B4O7.4H2O 1.23 75 1.13137085 2.30198 NA2B4O7.4H2O 1.284 75 1.14017543 2.30168 NA2B4O7.4H2O 1.35 75 1.18321596 2.33354 NA2B4O7.4H2O 1.4

0 0.5 1 1.5 2 2.5 3 3.5 40

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BOH3PPTNA2B10O.10H2ONA4B102O.7H2O

m^0.5 (Na2O)

m B

2O3

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6 75 1.26491106 2.47144 NA2B4O7.4H2O 1.67 75 1.30384048 2.5566 NA2B4O7.4H2O 1.78 75 1.34164079 2.64737 NA2B4O7.4H2O 1.89 75 1.41421356 2.83912 NA2B4O7.4H2O 210 75 1.44913767 2.9382 NA2B4O7.4H2O 2.111 75 1.4832397 3.03864 NA2B4O7.4H2O 2.212 75 1.51657509 3.14011 NA2B4O7.4H2O 2.313 75 1.54919334 3.24234 NA2B4O7.4H2O 2.414 75 1.58113883 3.34517 NA2B4O7.4H2O 2.515 75 1.61245155 3.44847 NA2B4O7.4H2O 2.616 75 1.64316767 3.55217 NA2B4O7.4H2O 2.717 75 1.67332005 3.65618 NA2B4O7.4H2O 2.818 75 1.70293864 3.7605 NA2B4O7.4H2O 2.919 75 1.73205081 3.86507 NA2B4O7.4H2O 320 75 1.84390889 4.28592 NA2B4O7.4H2O 3.421 75 1.94935887 4.71114 NA2B4O7.4H2O 3.822 75 2 4.92569 NA2B4O7.4H2O 423 75 2.0976177 5.35947 NA2B4O7.4H2O 4.424 75 2.19089023 5.80086 NA2B4O7.4H2O 4.825 75 2.23606798 6.02499 NA2B4O7.4H2O 526 75 2.32379001 6.48151 NA2B4O7.4H2O 5.427 75 2.34520788 6.59761 NA2B4O7.4H2O 5.528 75 2.36643191 6.71457 NA2B4O7.4H2O 5.629 75 2.38746728 6.83245 NA2B4O7.4H2O 5.730 75 2.40831892 6.95131 NA2B4O7.4H2O 5.831 75 2.44948974 7.19213 NA2B4O7.4H2O 632 75 2.52982213 7.68772 NA2B4O7.4H2O 6.433 75 2.60768096 8.2048 NA2B4O7.4H2O 6.834 75 2.64575131 8.47238 NA2B4O7.4H2O 735 75 2.7202941 9.0271 NA2B4O7.4H2O 7.436 75 2.79284801 9.60885 NA2B4O7.4H2O 7.837 75 2.82842712 9.90987 NA2B4O7.4H2O 838 75 2.89827535 10.5316 NA2B4O7.4H2O 8.439 75 2.91547595 10.691 NA2B4O7.4H2O 8.540 75 2.93257566 10.852 NA2B4O7.4H2O 8.641 75 2.94957624 11.0145 NA2B4O7.4H2O 8.742 75 2.96647939 11.1785 NA2B4O7.4H2O 8.843 75 2.98328678 11.344 NA2B4O7.4H2O 8.9

21 75 2.31718148 1.8 NA2B2O4.4H2O 5.369320 75 2.22708329 1.9 NA2B2O4.4H2O 4.959919 75 2.17249166 2 NA2B2O4.4H2O 4.719718 75 2.13475994 2.1 NA2B2O4.4H2O 4.557217 75 2.10755071 2.2 NA2B2O4.4H2O 4.441816 75 2.08774759 2.3 NA2B2O4.4H2O 4.358715 75 2.07352357 2.4 NA2B2O4.4H2O 4.299514 75 2.07235615 2.41 NA2B2O4.4H2O 4.294713 75 2.07123393 2.42 NA2B2O4.4H2O 4.2912 75 2.07015217 2.43 NA2B2O4.4H2O 4.285511 75 2.06911334 2.44 NA2B2O4.4H2O 4.281210 75 2.06811267 2.45 NA2B2O4.4H2O 4.27719 75 2.06715263 2.46 NA2B2O4.4H2O 4.27318 75 2.06622845 2.47 NA2B2O4.4H2O 4.26937 75 2.06534259 2.48 NA2B2O4.4H2O 4.2656

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6 75 2.0644951 2.49 NA2B2O4.4H2O 4.26215 75 2.0636836 2.5 NA2B2O4.4H2O 4.25884 75 2.05739398 2.6 NA2B2O4.4H2O 4.23293 75 2.05404479 2.7 NA2B2O4.4H2O 4.21912 75 2.05316098 2.8 NA2B2O4.4H2O 4.21551 75 2.05416893 2.89 NA2B2O4.4H2O 4.21961 75 2.05426386 2.89471 NA2B2O4.4H2O 4.222 75 2.0976177 3.55763 NA2B2O4.4H2O 4.43 75 2.14476106 3.97971 NA2B2O4.4H2O 4.64 75 2.19089023 4.33599 NA2B2O4.4H2O 4.85 75 2.23606798 4.65997 NA2B2O4.4H2O 56 75 2.28035085 4.96407 NA2B2O4.4H2O 5.27 75 2.32379001 5.25485 NA2B2O4.4H2O 5.48 75 2.36643191 5.54006 NA2B2O4.4H2O 5.69 75 2.40831892 5.91197 NA2B2O4.4H2O 5.810 75 2.44948974 6.38507 NA2B2O4.4H2O 611 75 2.48997992 6.78217 NA2B2O4.4H2O 6.212 75 2.52982213 7.15169 NA2B2O4.4H2O 6.413 75 2.56904652 7.50681 NA2B2O4.4H2O 6.614 75 2.60768096 7.85284 NA2B2O4.4H2O 6.815 75 2.64575131 8.19252 NA2B2O4.4H2O 716 75 2.68328157 8.5275 NA2B2O4.4H2O 7.217 75 2.7202941 8.85887 NA2B2O4.4H2O 7.418 75 2.75680975 9.18738 NA2B2O4.4H2O 7.619 75 2.79284801 9.51363 NA2B2O4.4H2O 7.820 75 2.82842712 9.83808 NA2B2O4.4H2O 821 75 2.86356421 10.1611 NA2B2O4.4H2O 8.222 75 2.89827535 10.4831 NA2B2O4.4H2O 8.423 75 2.91547595 10.6437 NA2B2O4.4H2O 8.524 75 2.93257566 10.8042 NA2B2O4.4H2O 8.625 75 2.96647939 11.1249 NA2B2O4.4H2O 8.826 75 2.98328678 11.2851 NA2B2O4.4H2O 8.927 75 3 11.4453 NA2B2O4.4H2O 928 75 3.03315018 11.7658 NA2B2O4.4H2O 9.229 75 3.06594194 12.0867 NA2B2O4.4H2O 9.430 75 3.09838668 12.4081 NA2B2O4.4H2O 9.631 75 3.13049517 12.7304 NA2B2O4.4H2O 9.832 75 3.16227766 13.0538 NA2B2O4.4H2O 1033 75 3.19374388 13.3788 NA2B2O4.4H2O 10.234 75 3.2249031 13.7057 NA2B2O4.4H2O 10.435 75 3.25576412 14.0349 NA2B2O4.4H2O 10.636 75 3.28633535 14.3667 NA2B2O4.4H2O 10.837 75 3.31662479 14.7017 NA2B2O4.4H2O 1138 75 3.34664011 15.0403 NA2B2O4.4H2O 11.239 75 3.3763886 15.3832 NA2B2O4.4H2O 11.440 75 3.40587727 15.7308 NA2B2O4.4H2O 11.641 75 3.43511281 16.0838 NA2B2O4.4H2O 11.842 75 3.46410162 16.4427 NA2B2O4.4H2O 1243 75 3.49284984 16.808 NA2B2O4.4H2O 12.244 75 3.52136337 17.1797 NA2B2O4.4H2O 12.445 75 3.54964787 17.5575 NA2B2O4.4H2O 12.646 75 3.57770876 17.9404 NA2B2O4.4H2O 12.847 75 3.60555128 18.326 NA2B2O4.4H2O 1348 75 3.63318042 18.7112 NA2B2O4.4H2O 13.2

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49 75 3.66060104 19.0919 NA2B2O4.4H2O 13.450 75 3.68781778 19.4641 NA2B2O4.4H2O 13.651 75 3.71483512 19.8244 NA2B2O4.4H2O 13.852 75 3.74165739 20.1706 NA2B2O4.4H2O 1453 75 3.80788655 20.9713 NA2B2O4.4H2O 14.554 75 3.87298335 21.6866 NA2B2O4.4H2O 1555 75 3.93700394 22.3313 NA2B2O4.4H2O 15.556 75 4 22.9177 NA2B2O4.4H2O 1657 75 4.0620192 23.4532 NA2B2O4.4H2O 16.558 75 4.12310563 23.9395 NA2B2O4.4H2O 1759 75 4.18330013 24.3681 NA2B2O4.4H2O 17.5

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t/C wt% Na2O wt% Na2O wt% B2O3 m Na2O^0.5m Na2O m B2O375 1.53 1.53 16.45 0.54860536 0.301 2.880975 3.92 3.92 26.48 0.95326276 0.9087 5.46575 4.41 4.41 28.34 1.028602 1.058 6.053275 3.92 3.92 26.48 0.95326276 0.9087 5.46575 4.49 4.49 25.89 1.02007094 1.0405 5.341775 6.1 6.1 28.09 1.22290631 1.4955 6.131175 6.98 6.98 29.96 1.33636454 1.7859 6.824475 6.84 6.84 32.67 1.35070489 1.8244 7.757975 7.86 7.86 35.15 1.49171604 2.2252 8.859475 6.1 6.1 28.09 1.22290631 1.4955 6.131175 4.69 4.69 17.15 0.98393942 0.9681 3.151875 4.58 4.58 14.29 0.95436876 0.9108 2.530175 4.84 4.84 13.48 0.97777523 0.956 2.370675 5.66 5.66 13.84 1.06508554 1.1344 2.469675 6.52 6.52 14.75 1.15592029 1.3362 2.691175 5.4 5.4 19.16 1.07465795 1.1549 3.648175 5.3 5.3 16.26 1.04410303 1.0902 2.977675 5.85 5.85 15.42 1.09491907 1.1988 2.813375 6.53 6.53 15.72 1.16407404 1.3551 2.904275 10.59 10.59 37.77 1.81898483 3.3087 10.50675 11.54 11.54 39.73 1.9546946 3.8208 11.71175 12.74 12.74 46.9 2.25674947 5.0929 16.69275 6.58 6.58 19.4 1.1976023 1.4343 3.764775 5.66 5.66 13.84 1.06508554 1.1344 2.469675 5.63 5.63 12.67 1.0544291 1.1118 2.227675 6.27 6.27 11.69 1.11044016 1.2331 2.046875 7.91 7.91 12.78 1.26852339 1.6092 2.314675 11.39 11.39 16.71 1.59871714 2.5559 3.338375 15.44 15.44 21.93 1.99437424 3.9775 5.029675 18.72 18.72 26.73 2.35304243 5.5368 7.038575 24.41 24.41 36.75 3.18433311 10.14 13.59175 14.13 14.13 50.36 2.53378616 6.4201 20.37175 9.23 9.23 29.78 1.56259254 2.4417 7.013775 7.41 7.41 21.27 1.29472535 1.6763 4.283975 7.15 7.15 13.41 1.20505708 1.4522 2.424875 9.4 9.4 15.24 1.41862528 2.0125 2.904875 14.53 14.53 21.64 1.91643723 3.6727 4.869875 19.55 19.55 29.2 2.48085088 6.1546 8.18475 22.4 22.4 34.48 2.89506852 8.3814 11.48675 25.53 25.53 40.92 3.50391336 12.277 17.51975 24.41 24.41 36.75 3.18433311 10.14 13.59175 22.96 22.96 32.22 2.87490984 8.2651 10.32675 21 21 26.42 2.53847897 6.4439 7.217675 19.91 19.91 22.53 2.36237834 5.5808 5.622475 19.82 19.82 22.16 2.34767068 5.5116 5.486275 19.7 19.7 20.55 2.30641988 5.3196 4.9403

0 0.5 1 1.5 2 2.5 3 3.5 40

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BOH3PPTNA2B10O.10H2ONA4B102O.7H2O

m^0.5 (Na2O)

m B

2O3

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solid refH3BO3 1967NHH3BO3 + 2Na2O.9B2O3.11H2O 1967NHH3BO3 + Na2O.5B2O3.10H2O (m) 1967NHH3BO3 + 2Na2O.9B2O3.11H2O 1967NH2Na2O.9B2O3.11H2O 1967NH2Na2O.9B2O3.11H2O + 2Na2O.5.1B2O3.7H2O 1967NH2Na2O.9B2O3.11H2O + 2Na2O.5B2O3.5H2O ( 1967NHNa2O.5B2O3.10H2O + 2Na2O.5.1B2O3.7H2O (1967NHNa2O.5B2O3.10H2O + 2Na2O.5B2O3.5H2O (m1967NH2Na2O.5.1B2O3.7H2O + 2Na2O.9B2O3.11H2O1967NH2Na2O.5.1B2O3.7H2O 1967NH2Na2O.5.1B2O3.7H2O 1967NH2Na2O.5.1B2O3.7H2O 1967NH2Na2O.5.1B2O3.7H2O + Na2O.2B2O3.4H2O 1967NH2Na2O.5.1B2O3.7H2O + Na2O.2B2O3.5H2O 1967NH2Na2O.5B2O3.5H2O (m) 1967NH2Na2O.5B2O3.5H2O (m) 1967NH2Na2O.5B2O3.5H2O + Na2O.2B2O3.4H2O (m)1967NH2Na2O.5B2O3.5H2O + Na2O.2B2O3.5H2O (m)1967NH2Na2O.9B2O3.11H2O + Na2O.2B2O3.4H2O (m1967NH2Na2O.9B2O3.11H2O + Na2O.2B2O3.5H2O (m1967NHNa2O.5B2O3.10H2O + Na2O.2B2O3.4H2O (m)1967NHNa2O.2B2O3.4H2O (m) 1967NHNa2O.2B2O3.4H2O + 2Na2O.5.1B2O3.7H2O 1967NHNa2O.2B2O3.4H2O 1967NHNa2O.2B2O3.4H2O 1967NHNa2O.2B2O3.4H2O 1967NHNa2O.2B2O3.4H2O 1967NHNa2O.2B2O3.4H2O 1967NHNa2O.2B2O3.4H2O 1967NHNa2O.2B2O3.4H2O +Na2O.B2O3.4H2O 1967NHNa2O.5B2O3.10H2O + Na2O.2B2O3.5H2O (m)1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O (m) 1967NHNa2O.2B2O3.5H2O +Na2O.B2O3.4H2O (m) 1967NHNa2O.2B2O3.4H2O +Na2O.B2O3.4H2O 1967NHNa2O.B2O3.4H2O 1967NHNa2O.B2O3.4H2O 1967NHNa2O.B2O3.4H2O 1967NHNa2O.B2O3.4H2O 1967NHNa2O.B2O3.4H2O 1967NH

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PT. TTm^0.5 (NA2OIN) B2O3IN SOLID NA2OIN1 60 0 1.10584 BOH3PPT 02 60 0.31622776602 1.46806 BOH3PPT 0.13 60 0.4472135955 1.83405 BOH3PPT 0.24 60 0.54772255751 2.20308 BOH3PPT 0.35 60 0.63245553203 2.57539 BOH3PPT 0.46 60 0.70710678119 2.95124 BOH3PPT 0.57 60 0.77459666924 3.33087 BOH3PPT 0.68 60 0.83666002653 3.71454 BOH3PPT 0.79 60 0.894427191 4.10249 BOH3PPT 0.8

10 60 0.94868329805 4.49495 BOH3PPT 0.911 60 1 4.89213 BOH3PPT 11 60 0.77459666924 3.71595 NA2B10O.10H2O 0.62 60 0.77459666924 8.46697 NA2B10O.10H2O 0.63 60 0.83666002653 6.7943 NA2B10O.10H2O 0.74 60 0.894427191 5.12162 NA2B10O.10H2O 0.85 60 0.90553851381 4.78709 NA2B10O.10H2O 0.826 60 0.91651513899 4.45256 NA2B10O.10H2O 0.847 60 0.92736184955 3.62553 NA2B10O.10H2O 0.868 60 0.93273790531 4.32745 NA2B10O.10H2O 0.879 60 0.93808315196 4.34381 NA2B10O.10H2O 0.88

10 60 0.94868329805 4.37824 NA2B10O.10H2O 0.911 60 1 4.5774 NA2B10O.10H2O 112 60 1.09544511501 5.06163 NA2B10O.10H2O 1.213 60 1.18321595662 5.61254 NA2B10O.10H2O 1.414 60 1.26491106407 6.20892 NA2B10O.10H2O 1.615 60 1.3416407865 6.84555 NA2B10O.10H2O 1.816 60 1.41421356237 7.52464 NA2B10O.10H2O 217 60 1.48323969742 8.25382 NA2B10O.10H2O 2.218 60 1.54919333848 9.04735 NA2B10O.10H2O 2.419 60 1.61245154966 9.93157 NA2B10O.10H2O 2.620 60 1.67332005307 10.9639 NA2B10O.10H2O 2.821 60 1.73205080757 12.3494 NA2B10O.10H2O 310 60 0.93301875651 2.07 NA4B102O.7H2O 0.8705249 60 0.91554300827 2.08 NA4B102O.7H2O 0.8382198 60 0.90889383318 2.09 NA4B102O.7H2O 0.8260887 60 0.90430802274 2.1 NA4B102O.7H2O 0.8177736 60 0.88636617715 2.2 NA4B102O.7H2O 0.7856455 60 0.88412781881 2.4 NA4B102O.7H2O 0.7816824 60 0.89344501789 2.6 NA4B102O.7H2O 0.7982443 60 0.90718190017 2.8 NA4B102O.7H2O 0.8229792 60 0.92311158589 3 NA4B102O.7H2O 0.8521351 60 0.94024411724 3.2 NA4B102O.7H2O 0.8840592 60 0.95806523786 3.4 NA4B102O.7H2O 0.9178893 60 0.97628479451 3.6 NA4B102O.7H2O 0.9531324 60 0.99472910885 3.8 NA4B102O.7H2O 0.9894865 60 1.01329166581 4 NA4B102O.7H2O 1.026766 60 1.03190115806 4.2 NA4B102O.7H2O 1.064827 60 1.05051415983 4.4 NA4B102O.7H2O 1.103588 60 1.06910242727 4.6 NA4B102O.7H2O 1.142989 60 1.08764424331 4.8 NA4B102O.7H2O 1.18297

10 60 1.10612838315 5 NA4B102O.7H2O 1.2235211 60 1.12454435217 5.2 NA4B102O.7H2O 1.264612 60 1.14288669605 5.4 NA4B102O.7H2O 1.30619

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

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14

t=60C

BOH3PPTNA2B10O.10H2ONA4B102O.7H2ONA2B4O7.5H2ONA2B4O7.4H2ONA2B4O7.10H2ONA2B2O4.4H2ONA2B2O4.1H2ONA4B2O5.1H2ONAOH.1H2O

m^0.5 (Na2O)

m B

2O3

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13 60 1.1611545978 5.6 NA4B102O.7H2O 1.3482814 60 1.17934303746 5.8 NA4B102O.7H2O 1.3908515 60 1.19745146039 6 NA4B102O.7H2O 1.4338956 60 2.02957877403 13 NA2B4O7.5H2O 4.1191955 60 2.01115141151 12.8 NA2B4O7.5H2O 4.0447354 60 1.99282211951 12.6 NA2B4O7.5H2O 3.9713453 60 1.97457590383 12.4 NA2B4O7.5H2O 3.8989552 60 1.95640231036 12.2 NA2B4O7.5H2O 3.8275151 60 1.93829048391 12 NA2B4O7.5H2O 3.7569750 60 1.92022394527 11.8 NA2B4O7.5H2O 3.6872649 60 1.90219609925 11.6 NA2B4O7.5H2O 3.6183548 60 1.88419478823 11.4 NA2B4O7.5H2O 3.5501947 60 1.86621274243 11.2 NA2B4O7.5H2O 3.4827546 60 1.84823699779 11 NA2B4O7.5H2O 3.4159845 60 1.83026500813 10.8 NA2B4O7.5H2O 3.3498744 60 1.81228584942 10.6 NA2B4O7.5H2O 3.2843843 60 1.79429094631 10.4 NA2B4O7.5H2O 3.2194842 60 1.77627137566 10.2 NA2B4O7.5H2O 3.1551441 60 1.75822353528 10 NA2B4O7.5H2O 3.0913540 60 1.74013792557 9.8 NA2B4O7.5H2O 3.0280839 60 1.72201045293 9.6 NA2B4O7.5H2O 2.9653238 60 1.70383097753 9.4 NA2B4O7.5H2O 2.9030437 60 1.68559485049 9.2 NA2B4O7.5H2O 2.8412336 60 1.66729721406 9 NA2B4O7.5H2O 2.7798835 60 1.64892995606 8.8 NA2B4O7.5H2O 2.7189734 60 1.63048765711 8.6 NA2B4O7.5H2O 2.6584933 60 1.61196463981 8.4 NA2B4O7.5H2O 2.5984332 60 1.59335808907 8.2 NA2B4O7.5H2O 2.5387931 60 1.57465551788 8 NA2B4O7.5H2O 2.4795430 60 1.5558566772 7.8 NA2B4O7.5H2O 2.4206929 60 1.53695478138 7.6 NA2B4O7.5H2O 2.3622328 60 1.51794598059 7.4 NA2B4O7.5H2O 2.3041627 60 1.49882287146 7.2 NA2B4O7.5H2O 2.2464726 60 1.47958102178 7 NA2B4O7.5H2O 2.1891625 60 1.46021573749 6.8 NA2B4O7.5H2O 2.1322324 60 1.4407220412 6.6 NA2B4O7.5H2O 2.0756823 60 1.4210946485 6.4 NA2B4O7.5H2O 2.0195122 60 1.4013350777 6.2 NA2B4O7.5H2O 1.9637421 60 1.38143403751 6 NA2B4O7.5H2O 1.9083620 60 1.36138899658 5.8 NA2B4O7.5H2O 1.8533819 60 1.34120468237 5.6 NA2B4O7.5H2O 1.7988318 60 1.32087471018 5.4 NA2B4O7.5H2O 1.7447117 60 1.30039993848 5.2 NA2B4O7.5H2O 1.6910416 60 1.27978904512 5 NA2B4O7.5H2O 1.6378615 60 1.25904725884 4.8 NA2B4O7.5H2O 1.585214 60 1.23818819248 4.6 NA2B4O7.5H2O 1.5331113 60 1.21722224758 4.4 NA2B4O7.5H2O 1.4816312 60 1.19618142437 4.2 NA2B4O7.5H2O 1.4308511 60 1.17509999575 4 NA2B4O7.5H2O 1.3808610 60 1.15403206195 3.8 NA2B4O7.5H2O 1.331799 60 1.13306222248 3.6 NA2B4O7.5H2O 1.283838 60 1.1123039153 3.4 NA2B4O7.5H2O 1.237227 60 1.09194322197 3.2 NA2B4O7.5H2O 1.192346 60 1.07226396004 3 NA2B4O7.5H2O 1.14975

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

2

4

6

8

10

12

14

t=60C

BOH3PPT

NA2B10O.10H2O

NA4B102O.7H2O

NA2B4O7.5H2O

NA2B4O7.4H2O

NA2B4O7.10H2O

NA2B2O4.4H2O

NA2B2O4.1H2O

NA4B2O5.1H2O

NAOH.1H2O

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5 60 1.05375993471 2.8 NA2B4O7.5H2O 1.110414 60 1.03733311911 2.6 NA2B4O7.5H2O 1.076063 60 1.02495365749 2.4 NA2B4O7.5H2O 1.050532 60 1.02270230273 2.2 NA2B4O7.5H2O 1.045921 60 1.02532433893 2.16 NA2B4O7.5H2O 1.05129

10 60 1.0246950766 2.16731 NA2B4O7.5H2O 1.059 60 1.0295630141 2.12564 NA2B4O7.5H2O 1.068 60 1.03440804328 2.10201 NA2B4O7.5H2O 1.077 60 1.03923048454 2.08644 NA2B4O7.5H2O 1.086 60 1.04403065089 2.0757 NA2B4O7.5H2O 1.095 60 1.04880884817 2.06824 NA2B4O7.5H2O 1.14 60 1.09544511501 2.07189 NA2B4O7.5H2O 1.23 60 1.1401754251 2.12948 NA2B4O7.5H2O 1.32 60 1.18321595662 2.20684 NA2B4O7.5H2O 1.41 60 1.22474487139 2.29418 NA2B4O7.5H2O 1.51 60 1.22474487139 2.29418 NA2B4O7.5H2O 1.52 60 1.26491106407 2.38726 NA2B4O7.5H2O 1.63 60 1.3416407865 2.58277 NA2B4O7.5H2O 1.84 60 1.41421356237 2.78471 NA2B4O7.5H2O 25 60 1.48323969742 2.98983 NA2B4O7.5H2O 2.26 60 1.61245154966 3.40519 NA2B4O7.5H2O 2.67 60 1.73205080757 3.82563 NA2B4O7.5H2O 38 60 1.84390889146 4.25147 NA2B4O7.5H2O 3.49 60 1.8973665961 4.46677 NA2B4O7.5H2O 3.6

10 60 1.94935886896 4.6839 NA2B4O7.5H2O 3.811 60 2 4.90306 NA2B4O7.5H2O 412 60 2.04939015319 5.12449 NA2B4O7.5H2O 4.213 60 2.09761769634 5.34846 NA2B4O7.5H2O 4.414 60 2.14476105895 5.5753 NA2B4O7.5H2O 4.615 60 2.19089023002 5.80535 NA2B4O7.5H2O 4.816 60 2.2360679775 6.03904 NA2B4O7.5H2O 517 60 2.2803508502 6.27681 NA2B4O7.5H2O 5.218 60 2.32379000772 6.51919 NA2B4O7.5H2O 5.419 60 2.36643191324 6.76671 NA2B4O7.5H2O 5.620 60 2.40831891576 7.01996 NA2B4O7.5H2O 5.821 60 2.44948974278 7.29835 NA2B4O7.5H2O 622 60 2.4899799196 7.41159 NA2B4O7.5H2O 6.223 60 2.52982212813 7.58002 NA2B4O7.5H2O 6.424 60 2.56904651573 7.74846 NA2B4O7.5H2O 6.625 60 2.60768096208 7.9169 NA2B4O7.5H2O 6.826 60 2.64575131106 8.08534 NA2B4O7.5H2O 727 60 2.683281573 8.25377 NA2B4O7.5H2O 7.228 60 2.72029410175 8.42221 NA2B4O7.5H2O 7.429 60 2.75680975042 8.59065 NA2B4O7.5H2O 7.630 60 2.79284800875 8.75908 NA2B4O7.5H2O 7.831 60 2.82842712475 8.92752 NA2B4O7.5H2O 849 60 1.78416647205 11 NA2B4O7.4H2O 3.1832548 60 1.76686728421 10.8 NA2B4O7.4H2O 3.1218247 60 1.74954851319 10.6 NA2B4O7.4H2O 3.0609246 60 1.73220091213 10.4 NA2B4O7.4H2O 3.0005245 60 1.71481194304 10.2 NA2B4O7.4H2O 2.9405844 60 1.69738328023 10 NA2B4O7.4H2O 2.8811143 60 1.67989880648 9.8 NA2B4O7.4H2O 2.8220642 60 1.66235976852 9.6 NA2B4O7.4H2O 2.76344

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

2

4

6

8

10

12

14

t=60C

BOH3PPT

NA2B10O.10H2O

NA4B102O.7H2O

NA2B4O7.5H2O

NA2B4O7.4H2O

NA2B4O7.10H2O

NA2B2O4.4H2O

NA2B2O4.1H2O

NA4B2O5.1H2O

NAOH.1H2O

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41 60 1.64475530095 9.4 NA2B4O7.4H2O 2.7052240 60 1.627077134 9.2 NA2B4O7.4H2O 2.6473839 60 1.60932594585 9 NA2B4O7.4H2O 2.5899338 60 1.5914867263 8.8 NA2B4O7.4H2O 2.5328337 60 1.57355965886 8.6 NA2B4O7.4H2O 2.4760936 60 1.55553849197 8.4 NA2B4O7.4H2O 2.419735 60 1.5374134122 8.2 NA2B4O7.4H2O 2.3636434 60 1.51918070025 8 NA2B4O7.4H2O 2.3079133 60 1.50083310198 7.8 NA2B4O7.4H2O 2.252532 60 1.48236635148 7.6 NA2B4O7.4H2O 2.1974131 60 1.46377252331 7.4 NA2B4O7.4H2O 2.1426330 60 1.44504325195 7.2 NA2B4O7.4H2O 2.0881529 60 1.42617670714 7 NA2B4O7.4H2O 2.0339828 60 1.4071638142 6.8 NA2B4O7.4H2O 1.9801127 60 1.38799855908 6.6 NA2B4O7.4H2O 1.9265426 60 1.3686745413 6.4 NA2B4O7.4H2O 1.8732725 60 1.34918493914 6.2 NA2B4O7.4H2O 1.820324 60 1.32952247066 6 NA2B4O7.4H2O 1.7676323 60 1.30967935007 5.8 NA2B4O7.4H2O 1.7152622 60 1.28965111561 5.6 NA2B4O7.4H2O 1.663221 60 1.26943294427 5.4 NA2B4O7.4H2O 1.6114620 60 1.24901961554 5.2 NA2B4O7.4H2O 1.5600519 60 1.22840140019 5 NA2B4O7.4H2O 1.5089718 60 1.20758022508 4.8 NA2B4O7.4H2O 1.4582517 60 1.18654540579 4.6 NA2B4O7.4H2O 1.4078916 60 1.16530682655 4.4 NA2B4O7.4H2O 1.3579415 60 1.14385750861 4.2 NA2B4O7.4H2O 1.3084114 60 1.12221210116 4 NA2B4O7.4H2O 1.2593613 60 1.10038175194 3.8 NA2B4O7.4H2O 1.2108412 60 1.07838768539 3.6 NA2B4O7.4H2O 1.1629211 60 1.05627174534 3.4 NA2B4O7.4H2O 1.1157110 60 1.03409380619 3.2 NA2B4O7.4H2O 1.069359 60 1.01194367432 3 NA2B4O7.4H2O 1.024038 60 0.9899767674 2.8 NA2B4O7.4H2O 0.9800547 60 0.96843223821 2.6 NA2B4O7.4H2O 0.9378616 60 0.94771989533 2.4 NA2B4O7.4H2O 0.8981735 60 0.92859086793 2.2 NA2B4O7.4H2O 0.8622814 60 0.91260013149 2 NA2B4O7.4H2O 0.8328393 60 0.90391426585 1.8 NA2B4O7.4H2O 0.8170612 60 0.90672432415 1.7 NA2B4O7.4H2O 0.8221491 60 0.93324380523 1.6 NA2B4O7.4H2O 0.870944

17 60 0.94868329805 1.59179 NA2B4O7.4H2O 0.916 60 0.97467943448 1.60103 NA2B4O7.4H2O 0.9515 60 1 1.62544 NA2B4O7.4H2O 114 60 1.00498756211 1.63147 NA2B4O7.4H2O 1.0113 60 1.00995049384 1.63779 NA2B4O7.4H2O 1.0212 60 1.01488915651 1.64439 NA2B4O7.4H2O 1.0311 60 1.01980390272 1.65124 NA2B4O7.4H2O 1.0410 60 1.0246950766 1.65832 NA2B4O7.4H2O 1.059 60 1.0295630141 1.66561 NA2B4O7.4H2O 1.068 60 1.03440804328 1.67309 NA2B4O7.4H2O 1.077 60 1.03923048454 1.68075 NA2B4O7.4H2O 1.086 60 1.04403065089 1.68858 NA2B4O7.4H2O 1.095 60 1.04880884817 1.69657 NA2B4O7.4H2O 1.1

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4 60 1.09544511501 1.78293 NA2B4O7.4H2O 1.23 60 1.1401754251 1.87701 NA2B4O7.4H2O 1.32 60 1.18321595662 1.97536 NA2B4O7.4H2O 1.41 60 1.22474487139 2.07612 NA2B4O7.4H2O 1.5

16 60 1.26491106407 2.17822 NA2B4O7.4H2O 1.617 60 1.26491106407 2.17822 NA2B4O7.4H2O 1.618 60 1.3416407865 2.38418 NA2B4O7.4H2O 1.819 60 1.41421356237 2.59065 NA2B4O7.4H2O 220 60 1.48323969742 2.79678 NA2B4O7.4H2O 2.221 60 1.61245154966 3.20764 NA2B4O7.4H2O 2.622 60 1.73205080757 3.61767 NA2B4O7.4H2O 323 60 1.84390889146 4.02839 NA2B4O7.4H2O 3.424 60 1.8973665961 4.23441 NA2B4O7.4H2O 3.625 60 1.94935886896 4.44103 NA2B4O7.4H2O 3.826 60 2 4.64839 NA2B4O7.4H2O 427 60 2.04939015319 4.85661 NA2B4O7.4H2O 4.228 60 2.09761769634 5.06584 NA2B4O7.4H2O 4.429 60 2.14476105895 5.27624 NA2B4O7.4H2O 4.630 60 2.19089023002 5.488 NA2B4O7.4H2O 4.831 60 2.2360679775 5.70133 NA2B4O7.4H2O 532 60 2.2803508502 5.91652 NA2B4O7.4H2O 5.233 60 2.32379000772 6.2083 NA2B4O7.4H2O 5.434 60 2.36643191324 6.28583 NA2B4O7.4H2O 5.635 60 2.40831891576 6.46926 NA2B4O7.4H2O 5.836 60 2.44948974278 6.65269 NA2B4O7.4H2O 637 60 2.4899799196 6.83611 NA2B4O7.4H2O 6.238 60 2.52982212813 7.01954 NA2B4O7.4H2O 6.439 60 2.56904651573 7.20297 NA2B4O7.4H2O 6.640 60 2.60768096208 7.3864 NA2B4O7.4H2O 6.841 60 2.64575131106 7.56983 NA2B4O7.4H2O 742 60 2.683281573 7.75326 NA2B4O7.4H2O 7.243 60 2.72029410175 7.93669 NA2B4O7.4H2O 7.444 60 2.75680975042 8.12011 NA2B4O7.4H2O 7.645 60 2.79284800875 8.30354 NA2B4O7.4H2O 7.846 60 2.82842712475 8.48697 NA2B4O7.4H2O 816 60 0.97467943448 1.60103 NA2B4O7.4H2O 0.9517 60 0.94868329805 1.59179 NA2B4O7.4H2O 0.943 60 1.7303872399 10 NA2B4O7.10H2O 2.9942442 60 1.71328047908 9.8 NA2B4O7.10H2O 2.9353341 60 1.69601297165 9.6 NA2B4O7.10H2O 2.8764640 60 1.67857975682 9.4 NA2B4O7.10H2O 2.8176339 60 1.66098163747 9.2 NA2B4O7.10H2O 2.7588638 60 1.64321635824 9 NA2B4O7.10H2O 2.7001637 60 1.62528459046 8.8 NA2B4O7.10H2O 2.6415536 60 1.60718387249 8.6 NA2B4O7.10H2O 2.5830435 60 1.58891157715 8.4 NA2B4O7.10H2O 2.5246434 60 1.57046489932 8.2 NA2B4O7.10H2O 2.4663633 60 1.5518472863 8 NA2B4O7.10H2O 2.4082332 60 1.53304598757 7.8 NA2B4O7.10H2O 2.3502331 60 1.5140673697 7.6 NA2B4O7.10H2O 2.292430 60 1.49490467924 7.4 NA2B4O7.10H2O 2.2347429 60 1.4755541332 7.2 NA2B4O7.10H2O 2.1772628 60 1.45601167578 7 NA2B4O7.10H2O 2.1199727 60 1.43627643579 6.8 NA2B4O7.10H2O 2.06289

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26 60 1.41634035458 6.6 NA2B4O7.10H2O 2.0060225 60 1.39619840997 6.4 NA2B4O7.10H2O 1.9493724 60 1.37584882891 6.2 NA2B4O7.10H2O 1.8929623 60 1.35528594769 6 NA2B4O7.10H2O 1.836822 60 1.33450739975 5.8 NA2B4O7.10H2O 1.7809121 60 1.31350295013 5.6 NA2B4O7.10H2O 1.7252920 60 1.29227319093 5.4 NA2B4O7.10H2O 1.6699719 60 1.27081076483 5.2 NA2B4O7.10H2O 1.6149618 60 1.24911168436 5 NA2B4O7.10H2O 1.5602817 60 1.22717154465 4.8 NA2B4O7.10H2O 1.5059516 60 1.20498962651 4.6 NA2B4O7.10H2O 1.45215 60 1.18256500878 4.4 NA2B4O7.10H2O 1.3984614 60 1.15990085783 4.2 NA2B4O7.10H2O 1.3453713 60 1.13700043975 4 NA2B4O7.10H2O 1.2927712 60 1.11387611519 3.8 NA2B4O7.10H2O 1.2407211 60 1.09055031979 3.6 NA2B4O7.10H2O 1.189310 60 1.06705201373 3.4 NA2B4O7.10H2O 1.13869 60 1.0434366296 3.2 NA2B4O7.10H2O 1.088768 60 1.01978429092 3 NA2B4O7.10H2O 1.039967 60 0.99622236474 2.8 NA2B4O7.10H2O 0.9924596 60 0.97296659758 2.6 NA2B4O7.10H2O 0.9466645 60 0.9503772935 2.4 NA2B4O7.10H2O 0.9032174 60 0.92911140344 2.2 NA2B4O7.10H2O 0.8632483 60 0.910520181 2 NA2B4O7.10H2O 0.8290472 60 0.89809353633 1.8 NA2B4O7.10H2O 0.8065721 60 0.8976107174 1.7 NA2B4O7.10H2O 0.805705 PT. TT

18 60 0.89721792225 1.71499 NA2B4O7.10H2O 0.805 0.8972179 6017 60 0.8977750275 1.69546 NA2B4O7.10H2O 0.806 0.897775 6016 60 0.89833178726 1.68332 NA2B4O7.10H2O 0.807 0.8983318 6015 60 0.89888820217 1.67402 NA2B4O7.10H2O 0.808 0.8988882 6014 60 0.89944427287 1.66635 NA2B4O7.10H2O 0.809 0.8994443 6013 60 0.9 1.65978 NA2B4O7.10H2O 0.81 0.9 6012 60 0.90553851381 1.62022 NA2B4O7.10H2O 0.82 0.9055385 6011 60 0.91104335791 1.59964 NA2B4O7.10H2O 0.83 0.9110434 6010 60 0.91651513899 1.58698 NA2B4O7.10H2O 0.84 0.9165151 609 60 0.92195444573 1.57894 NA2B4O7.10H2O 0.85 0.9219544 60

17 60 0.94868329805 1.57234 NA2B4O7.10H2O 0.9 0.9486833 607 60 0.97467943448 1.59163 NA2B4O7.10H2O 0.95 0.9746794 60

15 60 1 1.62293 NA2B4O7.10H2O 1 1 6014 60 1.00498756211 1.63013 NA2B4O7.10H2O 1.01 1.0488088 6013 60 1.00995049384 1.63757 NA2B4O7.10H2O 1.02 1.0954451 6012 60 1.01488915651 1.64524 NA2B4O7.10H2O 1.03 1.1401754 6011 60 1.01980390272 1.65313 NA2B4O7.10H2O 1.04 1.183216 6010 60 1.0246950766 1.6612 NA2B4O7.10H2O 1.05 1.2247449 609 60 1.0295630141 1.66945 NA2B4O7.10H2O 1.068 60 1.03440804328 1.67786 NA2B4O7.10H2O 1.077 60 1.03923048454 1.68643 NA2B4O7.10H2O 1.086 60 1.04403065089 1.69514 NA2B4O7.10H2O 1.095 60 1.04880884817 1.70398 NA2B4O7.10H2O 1.14 60 1.09544511501 1.79797 NA2B4O7.10H2O 1.23 60 1.1401754251 1.89865 NA2B4O7.10H2O 1.32 60 1.18321595662 2.00307 NA2B4O7.10H2O 1.41 60 1.22474487139 2.10967 NA2B4O7.10H2O 1.5

19 60 1.26491106407 2.21755 NA2B4O7.10H2O 1.6

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20 60 1.3416407865 2.4353 NA2B4O7.10H2O 1.821 60 1.41421356237 2.65431 NA2B4O7.10H2O 222 60 1.48323969742 2.87406 NA2B4O7.10H2O 2.223 60 1.61245154966 3.31633 NA2B4O7.10H2O 2.624 60 1.73205080757 3.76453 NA2B4O7.10H2O 325 60 1.84390889146 4.2217 NA2B4O7.10H2O 3.426 60 1.8973665961 4.45461 NA2B4O7.10H2O 3.627 60 1.94935886896 4.69095 NA2B4O7.10H2O 3.828 60 2 4.93112 NA2B4O7.10H2O 429 60 2.04939015319 5.17557 NA2B4O7.10H2O 4.230 60 2.09761769634 5.42476 NA2B4O7.10H2O 4.431 60 2.14476105895 5.67913 NA2B4O7.10H2O 4.632 60 2.19089023002 5.93912 NA2B4O7.10H2O 4.833 60 2.2360679775 6.20514 NA2B4O7.10H2O 534 60 2.2803508502 6.47751 NA2B4O7.10H2O 5.235 60 2.32379000772 6.75649 NA2B4O7.10H2O 5.436 60 2.36643191324 7.04219 NA2B4O7.10H2O 5.637 60 2.40831891576 7.3346 NA2B4O7.10H2O 5.838 60 2.44948974278 7.63359 NA2B4O7.10H2O 639 60 2.4899799196 7.93885 NA2B4O7.10H2O 6.240 60 2.52982212813 8.24997 NA2B4O7.10H2O 6.441 60 2.56904651573 8.56644 NA2B4O7.10H2O 6.642 60 2.60768096208 8.88766 NA2B4O7.10H2O 6.843 60 2.64575131106 9.21298 NA2B4O7.10H2O 744 60 2.683281573 9.54171 NA2B4O7.10H2O 7.245 60 2.72029410175 9.87313 NA2B4O7.10H2O 7.446 60 2.75680975042 10.2065 NA2B4O7.10H2O 7.647 60 2.79284800875 10.5411 NA2B4O7.10H2O 7.848 60 2.82842712475 10.8761 NA2B4O7.10H2O 81 60 2.60355910246 8 NA2B2O4.4H2O 6.778522 60 2.60242002759 7.99 NA2B2O4.4H2O 6.772593 60 2.58078476437 7.8 NA2B2O4.4H2O 6.660454 60 2.56941238418 7.7 NA2B2O4.4H2O 6.601885 60 2.55805394783 7.6 NA2B2O4.4H2O 6.543646 60 2.54671749513 7.5 NA2B2O4.4H2O 6.485777 60 2.49060835942 7 NA2B2O4.4H2O 6.203138 60 2.43657341363 6.5 NA2B2O4.4H2O 5.936899 60 2.38806197575 6 NA2B2O4.4H2O 5.70284

10 60 2.34606479024 5.5 NA2B2O4.4H2O 5.5040211 60 2.26915182392 5 NA2B2O4.4H2O 5.1490512 60 2.19123024806 4.5 NA2B2O4.4H2O 4.8014913 60 2.11737573425 4 NA2B2O4.4H2O 4.4832814 60 2.05123377507 3.5 NA2B2O4.4H2O 4.2075615 60 1.99934239189 3 NA2B2O4.4H2O 3.9973716 60 1.97481644717 2.5 NA2B2O4.4H2O 3.899917 60 2.00901717265 2 NA2B2O4.4H2O 4.0361518 60 2.09713137404 1.7 NA2B2O4.4H2O 4.3979619 60 2.15409609813 1.6 NA2B2O4.4H2O 4.6401320 60 2.24671983122 1.5 NA2B2O4.4H2O 5.0477521 60 2.25997123876 1.49 NA2B2O4.4H2O 5.1074722 60 2.27454610857 1.48 NA2B2O4.4H2O 5.1735623 60 2.29080335254 1.47 NA2B2O4.4H2O 5.2477824 60 2.30930725543 1.46 NA2B2O4.4H2O 5.332925 60 2.33105555489 1.45 NA2B2O4.4H2O 5.43382

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26 60 2.39696891928 1.43 NA2B2O4.4H2O 5.745461 60 2.34520787991 1.44445 NA2B2O4.4H2O 5.52 60 2.44948974278 1.42384 NA2B2O4.4H2O 63 60 2.5495097568 1.4328 NA2B2O4.4H2O 6.54 60 2.64575131106 1.46453 NA2B2O4.4H2O 75 60 2.73861278753 1.51536 NA2B2O4.4H2O 7.56 60 2.82842712475 1.5833 NA2B2O4.4H2O 87 60 2.91547594742 1.66723 NA2B2O4.4H2O 8.58 60 3 1.76663 NA2B2O4.4H2O 99 60 3.08220700148 1.88131 NA2B2O4.4H2O 9.5

10 60 3.16227766017 2.0113 NA2B2O4.4H2O 101 60 3.16227766017 1.92865 NA2B2O4.1H2O 102 60 3.2403703492 1.71924 NA2B2O4.1H2O 10.53 60 3.31662479036 1.54476 NA2B2O4.1H2O 114 60 3.39116499156 1.3964 NA2B2O4.1H2O 11.55 60 3.46410161514 1.26837 NA2B2O4.1H2O 126 60 3.53553390593 1.15663 NA2B2O4.1H2O 12.57 60 3.60555127546 1.05823 NA2B2O4.1H2O 138 60 3.67423461417 0.970944 NA2B2O4.1H2O 13.59 60 3.74165738677 0.893038 NA2B2O4.1H2O 14

10 60 3.80788655293 0.823147 NA2B2O4.1H2O 14.511 60 3.87298334621 0.76017 NA2B2O4.1H2O 1512 60 3.93700393701 0.703202 NA2B2O4.1H2O 15.513 60 4 0.651497 NA2B2O4.1H2O 1614 60 4.06201920232 0.604425 NA2B2O4.1H2O 16.515 60 4.12310562562 0.561458 NA2B2O4.1H2O 171 60 3.74165738677 1.49142 NA4B2O5.1H2O 142 60 3.76828873628 1.20664 NA4B2O5.1H2O 14.23 60 3.80788655293 0.917138 NA4B2O5.1H2O 14.54 60 3.87298334621 0.616648 NA4B2O5.1H2O 155 60 3.93700393701 0.432289 NA4B2O5.1H2O 15.56 60 4 0.310962 NA4B2O5.1H2O 167 60 4.06201920232 0.227822 NA4B2O5.1H2O 16.58 60 4.12310562562 0.1693 NA4B2O5.1H2O 179 60 4.18330013267 0.127293 NA4B2O5.1H2O 17.5

10 60 4.24264068712 0.096679 NA4B2O5.1H2O 1811 60 4.30116263352 0.074085 NA4B2O5.1H2O 18.512 60 4.35889894354 0.057232 NA4B2O5.1H2O 1913 60 4.41588043316 0.044543 NA4B2O5.1H2O 19.514 60 4.472135955 0.034906 NA4B2O5.1H2O 201 60 3.94674549471 0 NAOH.1H2O 15.57682 60 3.97585210993 0.2 NAOH.1H2O 15.80743 60 4.02225061377 0.5 NAOH.1H2O 16.17854 60 4.11128933548 1 NAOH.1H2O 16.9027

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ref t/C wt% Na2O wt% B2O3 m Na2O^0.51967NH 60 0 7.22 01967NH 60 1.04 11.9 0.439017221967NH 60 2.08 16.5 0.642007841967NH 60 3.36 21.77 0.850922361967NH 60 3.58 22.6 0.884562871967NH 60 5.61 26.13 1.15152271967NH 60 4.21 23.1 0.96666931967NH 60 3.36 21.77 0.850922361967NH 60 3.97 22.62 0.934096741967NH 60 7.09 29.9 1.347387741967NH 60 11.85 41.84 2.031870381967NH 60 10.25 37.92 1.786263581967NH 60 4.3 23.68 0.981480971967NH 60 3.58 22.6 0.884562871967NH 60 3.97 22.62 0.934096741967NH 60 4.13 22.74 0.954556091967NH 60 5.4 24.83 1.117472211967NH 60 9.18 33.29 1.604531941967NH 60 7.55 26 1.353942431967NH 60 4.63 11.58 0.944210041967NH 60 3.94 11.83 0.868738211967NH 60 4.36 17.8 0.950639911967NH 60 5.4 24.83 1.117472211967NH 60 5.61 26.13 1.15152271967NH 60 5.4 16.07 1.053302941967NH 60 11.85 41.84 2.031870381967NH 60 6.96 21.63 1.254005141967NH 60 8.11 26.48 1.414368471967NH 60 6.14 18.25 1.144639641967NH 60 5.52 15.72 1.06338591967NH 60 5.01 12.45 0.989602641967NH 60 4.94 11.14 0.974551851967NH 60 5.28 10.02 1.002881151967NH 60 5.72 10.23 1.047860261967NH 60 6.05 10.57 1.081984291967NH 60 7.77 12.27 1.252126861967NH 60 4.95 11.89 0.979985331967NH 60 10.98 39.57 1.892745561967NH 60 6.71 21.01 1.223844961967NH 60 7.56 24.68 1.341678351967NH 60 7.88 26.31 1.389925031967NH 60 9.52 33.51 1.641986491967NH 60 5.59 15.83 1.071332071967NH 60 5.11 12.71 1.001616791967NH 60 5.03 11.32 0.984975061967NH 60 5.4 10.22 1.016134821967NH 60 5.7 10.3 1.0463381967NH 60 5.89 10.36 1.065220351967NH 60 6.69 10.94 1.144729141967NH 60 8.47 12.73 1.316900041967NH 60 12 16.92 1.650407271967NH 60 15.65 21.83 2.009656821967NH 60 18.83 26.45 2.35627692

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

2

4

6

8

10

12

14

t=60C

BOH3PPTNA2B10O.10H2ONA4B102O.7H2ONA2B4O7.5H2ONA2B4O7.4H2ONA2B4O7.10H2ONA2B2O4.4H2ONA2B2O4.1H2ONA4B2O5.1H2ONAOH.1H2O

m^0.5 (Na2O)

m B

2O3

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1967NH 60 21.56 31.42 2.71992721967NH 60 4.63 11.58 0.944210041967NH 60 4.52 10.23 0.924903111967NH 60 4.96 9.29 0.96604641967NH 60 6.27 9.98 1.099045261967NH 60 8.22 11.94 1.288842531967NH 60 13.43 18.2 1.780243591967NH 60 16.66 22.52 2.102270061967NH 60 20.66 28.58 2.562586691967NH 60 19.46 24.64 2.369952971967NH 60 18.14 20.55 2.184878031967NH 60 18.03 18.48 2.140520611967NH 60 18.39 16.53 2.13521351967NH 60 19.45 13.14 2.157604571967NH 60 21.77 9.52 2.260962991967NH 60 28.49 6.31 2.65519634

Linke and Seidell 60 49.25 0 3.95693857Linke and Seidell 60 48.44 0.81 3.92426438Linke and Seidell 60 49.28 1.53 4.02041748Linke and Seidell 60 47.38 2.24 3.89531569Linke and Seidell 60 44.74 3.78 3.74457846Linke and Seidell 60 42.94 5.67 3.67168931Linke and Seidell 60 40.14 5.41 3.44876781Linke and Seidell 60 38.7 5.56 3.3469268Linke and Seidell 60 35.76 6.29 3.15534062Linke and Seidell 60 34.93 6.8 3.10993275Linke and Seidell 60 33.12 7.47 2.99909071Linke and Seidell 60 31.88 9.85 2.97105616Linke and Seidell 60 29.56 11.83 2.85259797Linke and Seidell 60 28.07 14.65 2.81186144Linke and Seidell 60 33.12 7.47 2.99909071Linke and Seidell 60 28.64 6.51 2.66935129Linke and Seidell 60 22.06 10.29 2.29373408Linke and Seidell 60 18.72 17.33 2.17323586Linke and Seidell 60 18.32 19.17 2.17451396Linke and Seidell 60 19.29 22.78 2.31786727Linke and Seidell 60 20.3 25.5 2.45823043Linke and Seidell 60 22.21 32.17 2.80266282Linke and Seidell 60 19.43 27.09 2.42111219Linke and Seidell 60 16.13 23.05 2.06856032Linke and Seidell 60 13.51 19.1 1.79847399Linke and Seidell 60 11.58 16.62 1.6131185Linke and Seidell 60 6.95 11.5 1.17261281Linke and Seidell 60 5.65 14.89 1.07108554Linke and Seidell 60 6.84 20.4 1.23156098Linke and Seidell 60 8.42 28.05 1.46231465Linke and Seidell 60 11.29 41.47 1.96365976Linke and Seidell 60 8.29 33.57 1.51674987Linke and Seidell 60 6.29 28.77 1.25009608Linke and Seidell 60 3.22 21.94 0.83317314Linke and Seidell 60 3.4 22.59 0.86093125Linke and Seidell 60 1.39 13.92 0.51459498Linke and Seidell 60 0 7.39 0

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

2

4

6

8

10

12

14

t=60C

BOH3PPT

NA2B10O.10H2O

NA4B102O.7H2O

NA2B4O7.5H2O

NA2B4O7.4H2O

NA2B4O7.10H2O

NA2B2O4.4H2O

NA2B2O4.1H2O

NA4B2O5.1H2O

NAOH.1H2O

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0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50

2

4

6

8

10

12

14

t=60C

BOH3PPT

NA2B10O.10H2O

NA4B102O.7H2O

NA2B4O7.5H2O

NA2B4O7.4H2O

NA2B4O7.10H2O

NA2B2O4.4H2O

NA2B2O4.1H2O

NA4B2O5.1H2O

NAOH.1H2O

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NA2OIN B2O3IN0.805 1.714990.806 1.695460.807 1.683320.808 1.674020.809 1.666350.81 1.659780.82 1.620220.83 1.599640.84 1.586980.85 1.578940.9 1.57234

0.95 1.591631 1.62293

1.1 1.797511.2 2.000661.3 2.203811.4 2.406961.5 2.61012

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m Na2O m B2O3 solid0 1.1178 H3BO3

0.1927 1.9634 H3BO30.4122 2.9109 H3BO30.7241 4.1767 H3BO3 + Na2O.5B2O3.10H2O0.7825 4.3976 H3BO3 + 2Na2O.9B2O3.11H2O (m)1.326 5.4986 Na2O.5B2O3.10H2O + 2Na2O.5.1B2O3.7H2O (m)0.9344 4.5647 Na2O.5B2O3.10H2O (m)0.7241 4.1767 Na2O.5B2O3.10H2O + H3BO30.8725 4.426 Na2O.5B2O3.10H2O + 2Na2O.9B2O3.11H2O1.8155 6.8162 Na2O.5B2O3.10H2O (m)4.1285 12.978 Na2O.5B2O3.10H2O + Na2O.2B2O3.10H2O (m)3.1907 10.509 Na2O.5B2O3.10H2O + Na2O.2B2O3.4H2O (m)0.9633 4.7229 Na2O.5B2O3.4H2O (m)0.7825 4.3976 2Na2O.9B2O3.11H2O + H3BO3 (m)0.8725 4.426 2Na2O.9B2O3.11H2O + Na2O.5B2O3.10H2O0.9112 4.4666 2Na2O.9B2O3.11H2O1.2487 5.1119 2Na2O.9B2O3.11H2O + 2Na2O.5.1B2O3.7H2O2.5745 8.3119 2Na2O.9B2O3.11H2O + Na2O.2B2O3.4H2O (m)1.8332 5.6203 Na2O.2B2O3.4H2O (m)0.8915 1.9852 2Na2O.5.1B2O3.7H2O + Na2O.2B2O3.4H2O0.7547 2.0174 2Na2O.5.1B2O3.7H2O0.9037 3.2847 2Na2O.5.1B2O3.7H2O1.2487 5.1119 2Na2O.5.1B2O3.7H2O + 2Na2O.9B2O3.11H2O1.326 5.4986 2Na2O.5.1B2O3.7H2O + Na2O.5B2O3.10H2O (m)1.1094 2.9394 Na2O.2B2O3.4H2O (m)4.1285 12.978 Na2O.2B2O3.10H2O + Na2O.5B2O3.10H2O (m)1.5725 4.3509 Na2O.2B2O3.10H2O (m)2.0004 5.815 Na2O.2B2O3.10H2O (m)1.3102 3.4671 Na2O.2B2O3.10H2O (m)1.1308 2.867 Na2O.2B2O3.10H2O0.9793 2.1666 Na2O.2B2O3.10H2O (m)0.9498 1.9068 Na2O.2B2O3.10H2O (m)1.0058 1.6993 Na2O.2B2O3.10H2O (m)1.098 1.7483 Na2O.2B2O3.10H2O (m)1.1707 1.8209 Na2O.2B2O3.10H2O (m)1.5678 2.2042 Na2O.2B2O3.10H2O (m)0.9604 2.0537 Na2O.2B2O3.10H2O + 2Na2O.5.2B2O3.7H2O (m)3.5825 11.494 Na2O.5B2O3.10H2O + Na2O.2B2O3.5H2O (m)1.4978 4.1753 Na2O.2B2O3.5H2O (m)1.8001 5.2318 Na2O.2B2O3.5H2O (m)1.9319 5.7426 Na2O.2B2O3.5H2O (m)2.6961 8.449 Na2O.2B2O3.5H2O (m)1.1478 2.8937 Na2O.2B2O3.5H2O (m)1.0032 2.2216 Na2O.2B2O3.5H2O (m)0.9702 1.9438 Na2O.2B2O3.5H2O (m)1.0325 1.7398 Na2O.2B2O3.5H2O (m)1.0948 1.7613 Na2O.2B2O3.5H2O (m)1.1347 1.7769 Na2O.2B2O3.5H2O (m)1.3104 1.9078 Na2O.2B2O3.5H2O (m)1.7342 2.3205 Na2O.2B2O3.5H2O (m)2.7238 3.4193 Na2O.2B2O3.5H2O (m)4.0387 5.0155 Na2O.2B2O3.5H2O (m)5.552 6.9432 Na2O.2B2O3.5H2O (m)

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7.398 9.5985 Na2O.2B2O3.5H2O + Na2O.B2O3.4H2O (m)0.8915 1.9852 Na2O.2B2O3.4H2O + 2Na2O.5.1B2O3.7H2O0.8554 1.7237 Na2O.2B2O3.4H2O0.9332 1.5562 Na2O.2B2O3.4H2O1.2079 1.7117 Na2O.2B2O3.4H2O1.6611 2.1481 Na2O.2B2O3.4H2O3.1693 3.8237 Na2O.2B2O3.4H2O4.4195 5.3186 Na2O.2B2O3.4H2O6.5669 8.0876 Na2O.2B2O3.4H2O + Na2O.B2O3.4H2O5.6167 6.3315 Na2O.B2O3.4H2O4.7737 4.8146 Na2O.B2O3.4H2O4.5818 4.181 Na2O.B2O3.4H2O4.5591 3.6484 Na2O.B2O3.4H2O4.6553 2.7999 Na2O.B2O3.4H2O5.112 1.9902 Na2O.B2O3.4H2O7.0501 1.3901 Na2O.B2O3.4H2O

15.657 0 NaOH.H2O15.4 0.2293 NaOH.H2O

16.164 0.4468 NaOH.H2O + 2Na2O.B2O3.H2O15.173 0.6387 2Na2O.B2O3.H2O14.022 1.0547 2Na2O.B2O3.H2O13.481 1.5848 2Na2O.B2O3.H2O + Na2O.B2O3.H2O11.894 1.4272 Na2O.B2O3.H2O11.202 1.4328 Na2O.B2O3.H2O9.9562 1.5591 Na2O.B2O3.H2O9.6717 1.6763 Na2O.B2O3.H2O8.9945 1.8061 Na2O.B2O3.H2O + Na2O.B2O3.4H2O8.8272 2.4281 Na2O.B2O3.H2O (unstable)8.1373 2.8993 Na2O.B2O3.H2O (unstable)7.9066 3.6738 Na2O.B2O3.H2O (unstable)8.9945 1.8061 Na2O.B2O3.H2O + Na2O.B2O3.4H2O7.1254 1.4419 Na2O.B2O3.4H2O5.2612 2.1849 Na2O.B2O3.4H2O4.723 3.8926 Na2O.B2O3.4H2O4.7285 4.4051 Na2O.B2O3.4H2O5.3725 5.6484 Na2O.B2O3.4H2O6.0429 6.758 Na2O.B2O3.4H2O7.8549 10.129 Na2O.B2O3.4H2O + Na2O.2B2O3.5H2O5.8618 7.2761 Na2O.2B2O3.5H2O4.2789 5.4438 Na2O.2B2O3.5H2O3.2345 4.0711 Na2O.2B2O3.5H2O2.6022 3.3249 Na2O.2B2O3.5H2O1.375 2.0256 Na2O.2B2O3.5H2O1.1472 2.6917 Na2O.2B2O3.5H2O1.5167 4.0273 Na2O.2B2O3.5H2O2.1384 6.3421 Na2O.2B2O3.5H2O3.856 12.61 Na2O.2B2O3.5H2O + Na2O.5B2O3.10H2O2.3005 8.2938 Na2O.5B2O3.10H2O1.5627 6.3636 Na2O.5B2O3.10H2O0.6942 4.211 Na2O.5B2O3.10H2O0.7412 4.3843 Na2O.5B2O3.10H2O + H3BO30.2648 2.3609 H3BO3

0 1.1462 H3BO3

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PT. TTNA2OIN^0.5 B2O3IN solid NA2OIN1 30 0 0.521641 BOH3PPT 02 30 0.31622777 0.862424 BOH3PPT 0.13 30 0.4472136 1.20432 BOH3PPT 0.24 30 0.54772256 1.54742 BOH3PPT 0.35 30 0.63245553 1.89249 BOH3PPT 0.46 30 0.70710678 2.24034 BOH3PPT 0.57 30 0.77459667 2.59173 BOH3PPT 0.68 30 0.83666003 2.94737 BOH3PPT 0.79 30 0.89442719 3.30791 BOH3PPT 0.8

10 30 0.9486833 3.67392 BOH3PPT 0.911 30 1 4.04596 BOH3PPT 11 30 0.67082039 2.05677 NA2B10O.10H2O 0.452 30 0.77459667 2.37844 NA2B10O.10H2O 0.63 30 0.83666003 2.61905 NA2B10O.10H2O 0.74 30 0.89442719 2.87033 NA2B10O.10H2O 0.85 30 0.9486833 3.1294 NA2B10O.10H2O 0.96 30 1 3.39528 NA2B10O.10H2O 17 30 1.09544512 3.94761 NA2B10O.10H2O 1.28 30 1.18321596 4.53151 NA2B10O.10H2O 1.49 30 1.26491106 5.15595 NA2B10O.10H2O 1.6

10 30 1.34164079 5.83553 NA2B10O.10H2O 1.811 30 1.41421356 6.59557 NA2B10O.10H2O 212 30 1.4832397 7.48874 NA2B10O.10H2O 2.213 30 1.54919334 8.68387 NA2B10O.10H2O 2.41 30 0.8220298 2.6 NA4B102O.7H2O 0.6757332 30 0.79910888 2.4 NA4B102O.7H2O 0.6385753 30 0.77668333 2.2 NA4B102O.7H2O 0.6032374 30 0.76581656 2.1 NA4B102O.7H2O 0.5864755 30 0.76474832 2.09 NA4B102O.7H2O 0.584846 30 0.76368449 2.08 NA4B102O.7H2O 0.5832147 30 0.76262442 2.07 NA4B102O.7H2O 0.5815968 30 0.76156812 2.06 NA4B102O.7H2O 0.5799869 30 0.76051627 2.05 NA4B102O.7H2O 0.578385

10 30 0.75533039 2 NA4B102O.7H2O 0.57052411 30 0.74541063 1.9 NA4B102O.7H2O 0.55563712 30 0.73635997 1.8 NA4B102O.7H2O 0.54222613 30 0.72870502 1.7 NA4B102O.7H2O 0.53101114 30 0.72348946 1.6 NA4B102O.7H2O 0.52343715 30 0.72335814 1.5 NA4B102O.7H2O 0.52324716 30 0.74444476 1.4 NA4B102O.7H2O 0.5541981 30 0.80322911 2.6 NA2B4O7.10H2O 0.6451772 30 0.77447143 2.4 NA2B4O7.10H2O 0.5998063 30 0.74488724 2.2 NA2B4O7.10H2O 0.5548574 30 0.72975886 2.1 NA2B4O7.10H2O 0.5325485 30 0.71438995 2 NA2B4O7.10H2O 0.5103536 30 0.69876749 1.9 NA2B4O7.10H2O 0.4882767 30 0.68287847 1.8 NA2B4O7.10H2O 0.4663238 30 0.66670908 1.7 NA2B4O7.10H2O 0.4445019 30 0.65024534 1.6 NA2B4O7.10H2O 0.422819

10 30 0.63347533 1.5 NA2B4O7.10H2O 0.40129111 30 0.61638949 1.4 NA2B4O7.10H2O 0.37993612 30 0.59898164 1.3 NA2B4O7.10H2O 0.35877913 30 0.58125726 1.2 NA2B4O7.10H2O 0.33786

0 0.5 1 1.5 2 2.5 3 3.5 40.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

t=30CBOH3PPTNA2B10O.10H2ONA2B4O7.10H2ONA2B2O4.8H2O

m^0.5-Na2O

m-B

2O3

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14 30 0.56323796 1.1 NA2B4O7.10H2O 0.31723715 30 0.54497706 1 NA2B4O7.10H2O 0.29716 30 0.52658238 0.9 NA2B4O7.10H2O 0.27728917 30 0.5082706 0.8 NA2B4O7.10H2O 0.25833918 30 0.49047222 0.7 NA2B4O7.10H2O 0.24056319 30 0.47409598 0.6 NA2B4O7.10H2O 0.22476720 30 0.46135453 0.5 NA2B4O7.10H2O 0.21284821 30 0.46018366 0.4 NA2B4O7.10H2O 0.21176922 30 0.46185604 0.39 NA2B4O7.10H2O 0.21331123 30 0.46431778 0.38 NA2B4O7.10H2O 0.21559124 30 0.46799038 0.37 NA2B4O7.10H2O 0.21901525 30 0.47386179 0.36 NA2B4O7.10H2O 0.22454526 30 0.48642677 0.35 NA2B4O7.10H2O 0.2366111 30 0.47958315 0.354098 NA2B4O7.10H2O 0.232 30 0.63245553 0.449329 NA2B4O7.10H2O 0.43 30 0.89442719 0.873192 NA2B4O7.10H2O 0.84 30 1 1.10407 NA2B4O7.10H2O 15 30 1.09544512 1.3291 NA2B4O7.10H2O 1.26 30 1.18321596 1.5451 NA2B4O7.10H2O 1.47 30 1.26491106 1.75451 NA2B4O7.10H2O 1.68 30 1.34164079 1.95999 NA2B4O7.10H2O 1.89 30 1.41421356 2.16332 NA2B4O7.10H2O 2

10 30 1.4832397 2.36553 NA2B4O7.10H2O 2.211 30 1.61245155 2.76845 NA2B4O7.10H2O 2.612 30 1.67332005 2.96954 NA2B4O7.10H2O 2.813 30 1.73205081 3.17049 NA2B4O7.10H2O 314 30 1.84390889 3.5721 NA2B4O7.10H2O 3.415 30 1.8973666 3.77285 NA2B4O7.10H2O 3.616 30 1.94935887 3.97365 NA2B4O7.10H2O 3.817 30 2 4.17459 NA2B4O7.10H2O 418 30 2.04939015 4.37577 NA2B4O7.10H2O 4.219 30 2.0976177 4.57736 NA2B4O7.10H2O 4.420 30 2.14476106 4.77952 NA2B4O7.10H2O 4.621 30 2.19089023 4.98249 NA2B4O7.10H2O 4.822 30 2.23606798 5.18656 NA2B4O7.10H2O 523 30 2.28035085 5.3921 NA2B4O7.10H2O 5.224 30 2.32379001 5.59959 NA2B4O7.10H2O 5.425 30 2.36643191 5.80965 NA2B4O7.10H2O 5.626 30 2.40831892 6.02308 NA2B4O7.10H2O 5.827 30 2.44948974 6.24096 NA2B4O7.10H2O 628 30 2.48997992 6.46472 NA2B4O7.10H2O 6.229 30 2.52982213 6.69633 NA2B4O7.10H2O 6.430 30 2.56904652 6.93852 NA2B4O7.10H2O 6.631 30 2.60768096 7.19506 NA2B4O7.10H2O 6.832 30 2.64575131 7.47108 NA2B4O7.10H2O 733 30 2.68328157 7.77305 NA2B4O7.10H2O 7.234 30 2.7202941 8.10798 NA2B4O7.10H2O 7.435 30 2.75680975 8.48108 NA2B4O7.10H2O 7.636 30 2.79284801 8.89233 NA2B4O7.10H2O 7.837 30 2.82842712 9.33393 NA2B4O7.10H2O 81 30 1.62319438 2.8 NA2B2O4.8H2O 2.634762 30 1.56211395 2.4 NA2B2O4.8H2O 2.44023 30 1.53038884 2.2 NA2B2O4.8H2O 2.342094 30 1.51534485 2.1 NA2B2O4.8H2O 2.29627

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5 30 1.50140934 2 NA2B2O4.8H2O 2.254236 30 1.488909 1.9 NA2B2O4.8H2O 2.216857 30 1.47823205 1.8 NA2B2O4.8H2O 2.185178 30 1.46985714 1.7 NA2B2O4.8H2O 2.160489 30 1.46440432 1.6 NA2B2O4.8H2O 2.14448

10 30 1.46269272 1.5 NA2B2O4.8H2O 2.1394711 30 1.46584106 1.4 NA2B2O4.8H2O 2.1486912 30 1.47547281 1.3 NA2B2O4.8H2O 2.1770213 30 1.49410843 1.2 NA2B2O4.8H2O 2.2323614 30 1.5262372 1.1 NA2B2O4.8H2O 2.329415 30 1.58201454 1 NA2B2O4.8H2O 2.5027716 30 1.70811592 0.9 NA2B2O4.8H2O 2.917661 30 1.70293864 0.902122 NA2B2O4.8H2O 2.92 30 1.73205081 0.89183 NA2B2O4.8H2O 33 30 1.84390889 0.884464 NA2B2O4.8H2O 3.44 30 1.8973666 0.896657 NA2B2O4.8H2O 3.65 30 1.92353841 0.906099 NA2B2O4.8H2O 3.76 30 1.94935887 0.91764 NA2B2O4.8H2O 3.87 30 1.97484177 0.931212 NA2B2O4.8H2O 3.98 30 2 0.946766 NA2B2O4.8H2O 49 30 2.0976177 1.02832 NA2B2O4.8H2O 4.4

10 30 2.14476106 1.08063 NA2B2O4.8H2O 4.611 30 2.19089023 1.14076 NA2B2O4.8H2O 4.812 30 2.23606798 1.20887 NA2B2O4.8H2O 51 30 1.8973666 0.90512 NA2B2O4.4H2O 3.62 30 1.92353841 0.873569 NA2B2O4.4H2O 3.73 30 1.94935887 0.846212 NA2B2O4.4H2O 3.84 30 1.97484177 0.822313 NA2B2O4.4H2O 3.95 30 2 0.801322 NA2B2O4.4H2O 46 30 2.0976177 0.73917 NA2B2O4.4H2O 4.47 30 2.14476106 0.717857 NA2B2O4.4H2O 4.68 30 2.19089023 0.701403 NA2B2O4.4H2O 4.89 30 2.23606798 0.689008 NA2B2O4.4H2O 5

10 30 2.28035085 0.680083 NA2B2O4.4H2O 5.211 30 2.32379001 0.674181 NA2B2O4.4H2O 5.412 30 2.36643191 0.670963 NA2B2O4.4H2O 5.613 30 2.40831892 0.670165 NA2B2O4.4H2O 5.814 30 2.44948974 0.671582 NA2B2O4.4H2O 615 30 2.48997992 0.675054 NA2B2O4.4H2O 6.216 30 2.52982213 0.680456 NA2B2O4.4H2O 6.417 30 2.56904652 0.687693 NA2B2O4.4H2O 6.618 30 2.60768096 0.696691 NA2B2O4.4H2O 6.819 30 2.64575131 0.707395 NA2B2O4.4H2O 720 30 2.68328157 0.719769 NA2B2O4.4H2O 7.221 30 2.7202941 0.733785 NA2B2O4.4H2O 7.422 30 2.75680975 0.749432 NA2B2O4.4H2O 7.623 30 2.79284801 0.766704 NA2B2O4.4H2O 7.824 30 2.82842712 0.785606 NA2B2O4.4H2O 825 30 2.86356421 0.80615 NA2B2O4.4H2O 8.226 30 2.89827535 0.828355 NA2B2O4.4H2O 8.427 30 2.93257566 0.852244 NA2B2O4.4H2O 8.628 30 2.96647939 0.877848 NA2B2O4.4H2O 8.829 30 3 0.905199 NA2B2O4.4H2O 930 30 3.03315018 0.934337 NA2B2O4.4H2O 9.2

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31 30 3.06594194 0.965303 NA2B2O4.4H2O 9.432 30 3.09838668 0.998142 NA2B2O4.4H2O 9.633 30 3.13049517 1.0329 NA2B2O4.4H2O 9.834 30 3.16227766 1.06964 NA2B2O4.4H2O 1035 30 3.19374388 1.1084 NA2B2O4.4H2O 10.236 30 3.2249031 1.14925 NA2B2O4.4H2O 10.437 30 3.25576412 1.19224 NA2B2O4.4H2O 10.638 30 3.28633535 1.23743 NA2B2O4.4H2O 10.839 30 3.31662479 1.28489 NA2B2O4.4H2O 1140 30 3.34664011 1.33467 NA2B2O4.4H2O 11.241 30 3.3763886 1.38685 NA2B2O4.4H2O 11.442 30 3.40587727 1.44148 NA2B2O4.4H2O 11.643 30 3.43511281 1.49864 NA2B2O4.4H2O 11.844 30 3.46410162 1.55839 NA2B2O4.4H2O 1245 30 3.49284984 1.6208 NA2B2O4.4H2O 12.246 30 3.52136337 1.68594 NA2B2O4.4H2O 12.447 30 3.54964787 1.75387 NA2B2O4.4H2O 12.648 30 3.57770876 1.82467 NA2B2O4.4H2O 12.849 30 3.60555128 1.89841 NA2B2O4.4H2O 1350 30 3.63318042 1.97514 NA2B2O4.4H2O 13.251 30 3.66060104 2.05495 NA2B2O4.4H2O 13.452 30 3.68781778 2.1379 NA2B2O4.4H2O 13.653 30 3.71483512 2.22405 NA2B2O4.4H2O 13.854 30 3.74165739 2.31348 NA2B2O4.4H2O 141 30 3.40170545 0 NAOH.1H2O 11.57162 30 3.42150552 0.2 NAOH.1H2O 11.70673 30 3.45114474 0.5 NAOH.1H2O 11.91044 30 3.50049996 1 NAOH.1H2O 12.25355 30 3.54985915 1.5 NAOH.1H2O 12.60156 30 3.59937495 2 NAOH.1H2O 12.9555

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ref t/C wt% Na2O wt% Na2O wt% B2O31967NH 30 0.517 0.517 5.831967NH 30 1.237 1.237 8.81967NH 30 1.83 1.83 11.221967NH 30 1.83 1.83 11.221967NH 30 2.12 2.12 11.751967NH 30 2.91 2.91 13.61967NH 30 3.46 3.46 15.081967NH 30 5.14 5.14 23.161967NH 30 3.46 3.46 15.081967NH 30 2.33 2.33 9.71967NH 30 1.59 1.59 6.041967NH 30 1.27 1.27 3.941967NH 30 1.17 1.17 2.631967NH 30 1.36 1.36 2.321967NH 30 1.97 1.97 2.661967NH 30 3.24 3.24 3.951967NH 30 4.63 4.63 5.491967NH 30 8.2 8.2 9.591967NH 30 11.48 11.48 13.461967NH 30 11.48 11.48 13.461967NH 30 11.07 11.07 12.371967NH 30 11.18 11.18 11.421967NH 30 11.47 11.47 10.7

1906D 30 42 42 01906D 30 40.85 40.85 2.711906D 30 41.37 41.37 5.11906D 30 38.85 38.85 5.551906D 30 34.44 34.44 3.731906D 30 29.39 29.39 2.511906D 30 28.61 28.61 2.381906D 30 27.78 27.78 2.441906D 30 26.13 26.13 2.751906D 30 25.08 25.08 2.981906D 30 23 23 3.821906D 30 21.58 21.58 4.631906D 30 16.61 16.61 13.691906D 30 21.58 21.58 4.631906D 30 20.58 20.58 4.691906D 30 18.31 18.31 4.971906D 30 15.32 15.32 6.211906D 30 13.25 13.25 8.181906D 30 12.39 12.39 9.121906D 30 8.85 8.85 10.491906D 30 5.81 5.81 6.941906D 30 4 4 4.761906D 30 1.88 1.88 2.411906D 30 1.38 1.38 5.161906D 30 1.84 1.84 7.361906D 30 2.02 2.02 7.791906D 30 2.4 2.4 9.481906D 30 4.08 4.08 17.21906D 30 4.08 4.08 17.2

0 0.5 1 1.5 2 2.5 3 3.5 40.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

t=30CBOH3PPTNA2B10O.10H2ONA2B4O7.10H2ONA2B2O4.8H2O

m^0.5-Na2O

m-B

2O3

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1906D 30 3.79 3.79 15.841906D 30 3.47 3.47 13.31906D 30 2.26 2.26 12.141906D 30 1.99 1.99 11.841906D 30 1.99 1.99 11.841906D 30 1.86 1.86 11.181906D 30 1.81 1.81 11.181906D 30 0.64 0.64 6.111906D 30 0 0 3.54

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m Na2O^0.5m Na2O m B2O3 solid0.2984411 0.0891 0.8942 H3BO30.47100672 0.2218 1.4051 H3BO30.58272676 0.3396 1.8535 H3BO3 + Na2O.5B2O3.10H2O0.58272676 0.3396 1.8535 Na2O.5B2O3.10H2O + H3BO30.63018044 0.3971 1.9596 Na2O.5B2O3.10H2O0.74990021 0.5624 2.3398 Na2O.5B2O3.10H2O0.8278279 0.6853 2.6591 Na2O.5B2O3.10H2O + Na2O.2B2O3.10H2O1.07546479 1.1566 4.6398 H3BO3 + Na2O.2B2O3.10H2O (metastable)0.8278279 0.6853 2.6591 Na2O.2B2O3.10H2O + Na2O.5B2O3.10H2O0.65370962 0.4273 1.5839 Na2O.2B2O3.10H2O0.52699598 0.2777 0.9393 Na2O.2B2O3.10H2O0.46493775 0.2162 0.5971 Na2O.2B2O3.10H2O0.4429754 0.1962 0.3927 Na2O.2B2O3.10H2O0.4772934 0.2278 0.346 Na2O.2B2O3.10H2O0.57729984 0.3333 0.4006 Na2O.2B2O3.10H2O0.75049764 0.5632 0.6113 Na2O.2B2O3.10H2O0.91166058 0.8311 0.8774 Na2O.2B2O3.10H2O1.26858279 1.6093 1.6756 Na2O.2B2O3.10H2O1.57087229 2.4676 2.5758 Na2O.2B2O3.10H2O + Na2O.B2O3.8H2O1.57087229 2.4676 2.5758 Na2O.B2O3.8H2O + Na2O.2B2O3.10H2O1.52737987 2.3329 2.3208 Na2O.B2O3.8H2O1.52659781 2.3305 2.1194 Na2O.B2O3.8H2O1.54199302 2.3777 1.9748 Na2O.B2O3.8H2O

3.41810077 11.683 0 NaOH.H2O3.41724992 11.678 0.6897 NaOH.H2O3.53116778 12.469 1.3685 NaOH.H2O3.35762608 11.274 1.4338 Na2O.B2O3.4H2O2.99782421 8.9869 0.8665 Na2O.B2O3.4H2O2.6387634 6.9631 0.5294 Na2O.B2O3.4H2O2.58628946 6.6889 0.4954 Na2O.B2O3.4H2O2.5343982 6.4232 0.5023 Na2O.B2O3.4H2O2.43471452 5.9278 0.5554 Na2O.B2O3.4H2O2.37166183 5.6248 0.595 Na2O.B2O3.4H2O2.25186282 5.0709 0.7498 Na2O.B2O3.4H2O2.17220685 4.7185 0.9013 Na2O.B2O3.4H2O + Na2O.B2O3.8H2O1.96084218 3.8449 2.8213 Na2O.B2O3.4H2O2.17220685 4.7185 0.9013 Na2O.B2O3.8H2O + Na2O.B2O3.4H2O2.10789711 4.4432 0.9015 Na2O.B2O3.8H2O1.96229406 3.8506 0.9305 Na2O.B2O3.8H2O1.77480961 3.1499 1.1368 Na2O.B2O3.8H2O1.64950553 2.7209 1.4955 Na2O.B2O3.8H2O1.59588908 2.5469 1.669 Na2O.B2O3.8H2O1.3305057 1.7702 1.8681 Na2O.2B2O3.10H2O1.03652448 1.0744 1.1425 Na2O.2B2O3.10H2O0.84103016 0.7073 0.7494 Na2O.2B2O3.10H2O0.56295604 0.3169 0.3617 Na2O.2B2O3.10H2O0.48809108 0.2382 0.7931 Na2O.2B2O3.10H2O0.5717948 0.3269 1.1643 Na2O.2B2O3.10H2O0.60113319 0.3614 1.2407 Na2O.2B2O3.10H2O0.66289171 0.4394 1.5453 Na2O.2B2O3.10H2O0.91445377 0.8362 3.1385 Na2O.2B2O3.10H2O + Na2O.5B2O.10H2O0.91445377 0.8362 3.1385 Na2O.5B2O.10H2O + Na2O.2B2O3.10H2O

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0.87226176 0.7608 2.831 Na2O.5B2O.10H2O0.82016079 0.6727 2.2954 Na2O.5B2O.10H2O0.65266684 0.426 2.0372 Na2O.5B2O.10H2O0.6104115 0.3726 1.9737 Na2O.5B2O.10H2O + H3BO30.6104115 0.3726 1.9737 H3BO3 + Na2O.5B2O.10H2O0.58745002 0.3451 1.8467 H3BO30.57933387 0.3356 1.8457 H3BO30.33276664 0.1107 0.9412 H3BO3

0 0 0.5272 H3BO3

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t/C m-HCl m-H3BO3 solid ref PT.26 0 0.944384 H3BO3 1902H26 0.1356 0.933658 H3BO3 1902H26 0.2716 0.908797 H3BO3 1902H26 0.4079 0.880638 H3BO3 1902H26 1.3724 0.680924 H3BO3 1902H26 2.3112 0.579931 H3BO3 1902H26 4.8009 0.342289 H3BO3 1902H26 6.9527 0.391666 H3BO3 1902H26 8.4285 0.38928 H3BO3 1902H26 10.879 0.407028 H3BO3 1902H26 12.104 0.430184 H3BO3 1902H25 0 0.931309 H3BO3 1921KA25 0.0687 0.917278 H3BO3 1921KA25 0.1356 0.893467 H3BO3 1921KA25 0.2851 0.874229 H3BO3 1921KA25 0.64 0.812709 H3BO3 1921KA25 1.2101 0.742966 H3BO3 1921KA25 1.9205 0.668222 H3BO3 1921KA25 2.8275 0.586783 H3BO3 1921KA25 3.4085 0.542577 H3BO3 1921KA25 4.843 0.467883 H3BO3 1921KA25 5.8645 0.422224 H3BO3 1921KA25 8.4224 0.410342 H3BO3 1921KA25 11.91 0.444101 H3BO3 1921KA25 15.657 0.499372 H3BO3 1921KA25 1.4495 0.704664 H3BO3 1910H25 0.7341 0.806433 H3BO3 1910H25 0 0.937814 H3BO3 1910H18 0 0.759772 H3BO3Linke&Seidell18 0 0.744845 H3BO3Linke&Seidell18 0.5191 0.680021 H3BO3Linke&Seidell18 0.6238 0.669024 H3BO3Linke&Seidell18 1.0456 0.622114 H3BO3Linke&Seidell18 1.2587 0.606078 H3BO3Linke&Seidell18 1.5808 0.575715 H3BO3Linke&Seidell

0 2 4 6 8 10 12 14 16 18 200.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.01921KA-25C1910H-25C1902H-26C18C-1965LS25C-MSE18C-MSE

m-HCl

m-H

3BO

3

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PT. TTHCLIN BOH3IN solid1 25 0 0.933017 BOH3PPT2 25 0.5 0.834151 BOH3PPT3 25 1 0.740942 BOH3PPT4 25 1.5 0.662818 BOH3PPT5 25 2 0.601679 BOH3PPT6 25 2.5 0.555681 BOH3PPT7 25 3 0.521803 BOH3PPT8 25 3.5 0.497086 BOH3PPT9 25 4 0.479077 BOH3PPT

10 25 4.5 0.465895 BOH3PPT11 25 5 0.456159 BOH3PPT12 25 5.5 0.448887 BOH3PPT13 25 6 0.443385 BOH3PPT14 25 6.5 0.439177 BOH3PPT15 25 7 0.435932 BOH3PPT16 25 7.5 0.433427 BOH3PPT17 25 8 0.43151 BOH3PPT18 25 8.5 0.430079 BOH3PPT19 25 9 0.429064 BOH3PPT20 25 9.5 0.42842 BOH3PPT21 25 10 0.428115 BOH3PPT22 25 10.5 0.428127 BOH3PPT23 25 11 0.428449 BOH3PPT24 25 11.5 0.429066 BOH3PPT25 25 12 0.429975 BOH3PPT26 25 12.5 0.431175 BOH3PPT27 25 13 0.432666 BOH3PPT28 25 13.5 0.434451 BOH3PPT29 25 14 0.436535 BOH3PPT30 25 14.5 0.438928 BOH3PPT31 25 15 0.44164 BOH3PPT32 25 15.5 0.444683 BOH3PPT33 25 16 0.448075 BOH3PPT34 25 16.5 0.451829 BOH3PPT35 25 17 0.455963 BOH3PPT36 25 17.5 0.460492 BOH3PPT37 25 18 0.465432 BOH3PPT38 25 18.1 0.46647 BOH3PPT39 25 18.2 0.467526 BOH3PPT40 25 18.3 0.468599 BOH3PPT41 25 18.4 0.46969 BOH3PPT42 25 18.5 0.470798 BOH3PPT43 25 19 0.476605 BOH3PPT

1 18 0 0.761329 BOH3PPT2 18 0.5 0.671533 BOH3PPT3 18 1 0.592604 BOH3PPT4 18 1.5 0.531201 BOH3PPT5 18 2 0.486869 BOH3PPT6 18 2.5 0.456475 BOH3PPT7 18 3 0.436535 BOH3PPT8 18 3.5 0.424078 BOH3PPT9 18 4 0.416834 BOH3PPT

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10 18 4.5 0.413162 BOH3PPT11 18 5 0.411917 BOH3PPT12 18 5.5 0.412319 BOH3PPT13 18 6 0.413846 BOH3PPT14 18 6.5 0.416157 BOH3PPT15 18 7 0.419033 BOH3PPT16 18 7.5 0.422339 BOH3PPT17 18 8 0.425993 BOH3PPT18 18 8.5 0.42995 BOH3PPT19 18 9 0.43419 BOH3PPT20 18 9.5 0.438705 BOH3PPT21 18 10 0.443498 BOH3PPT22 18 10.5 0.448577 BOH3PPT23 18 11 0.453953 BOH3PPT24 18 11.5 0.459639 BOH3PPT25 18 12 0.465649 BOH3PPT26 18 12.5 0.471994 BOH3PPT27 18 13 0.478689 BOH3PPT28 18 13.5 0.485744 BOH3PPT29 18 14 0.493166 BOH3PPT30 18 14.5 0.500963 BOH3PPT31 18 15 0.509136 BOH3PPT32 18 15.5 0.517683 BOH3PPT33 18 16 0.5266 BOH3PPT34 18 16.5 0.535881 BOH3PPT35 18 17 0.545528 BOH3PPT36 18 17.5 0.55555 BOH3PPT37 18 18 0.565969 BOH3PPT38 18 18.1 0.568104 BOH3PPT39 18 18.2 0.570255 BOH3PPT40 18 18.3 0.572425 BOH3PPT41 18 18.4 0.574613 BOH3PPT42 18 18.5 0.576819 BOH3PPT43 18 19 0.588143 BOH3PPT44 18 19.5 0.599993 BOH3PPT45 18 20 0.612423 BOH3PPT46 18 20.1 0.614984 BOH3PPT47 18 20.2 0.617571 BOH3PPT

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t/C m LiCl m H3BO3 solid ref PT. TT LICLIN25 0 0.934036 H3BO3 1971GK 1 25 025 0.852637 0.743801 H3BO3 1971GK 2 25 0.525 2.852674 0.568387 H3BO3 1971GK 3 25 125 6.095087 0.396282 H3BO3 1971GK 4 25 1.525 8.580439 0.422585 H3BO3 1971GK 5 25 225 10.00247 0.470005 H3BO3 1971GK 6 25 2.525 12.47928 0.621058 H3BO3 1971GK 7 25 325 13.66491 0.751981 H3BO3 1971GK 8 25 3.525 16.10734 1.128075 H3BO3 1971GK 9 25 425 20.97036 2.050539H3BO3 + LiCl.H2O 1971GK 10 25 4.525 18.97011 0.732818 LiCl.H2O 1971GK 11 25 525 19.05318 0 LiCl.H2O 1971GK 12 25 5.525 4.116407 0.555494 H3BO3 1910H 13 25 625 2.402643 0.691703 H3BO3 1910H 14 25 6.525 1.087913 0.808013 H3BO3 1910H 15 25 725 0.746624 0.854937 H3BO3 1910H 16 25 7.525 0 0.937814 H3BO3 1910H 17 25 825 0 0.941067 H3BO3 Linke&Seidell 18 25 8.525 0.494555 0.880141 H3BO3 Linke&Seidell 19 25 925 0.995093 0.827309 H3BO3 Linke&Seidell 20 25 9.525 1.502392 0.763946 H3BO3 Linke&Seidell 21 25 1025 2.017357 0.704202 H3BO3 Linke&Seidell 22 25 10.525 2.545709 0.653686 H3BO3 Linke&Seidell 23 25 1125 3.898278 0.534086 H3BO3 Linke&Seidell 24 25 11.5

23.85 0 0.89693 H3BO3 Linke&Seidell (1924L) 25 25 1223.85 0.701199 0.798884 H3BO3 Linke&Seidell (1924L) 26 25 12.523.85 1.416098 0.710589 H3BO3 Linke&Seidell (1924L) 27 25 1323.85 2.897383 0.584241 H3BO3 Linke&Seidell (1924L) 28 25 13.523.85 4.653845 0.488236 H3BO3 Linke&Seidell (1924L) 29 25 14

20 0 0.759943 H3BO3 Linke&Seidell 30 25 14.520 1.367228 0.58896 H3BO3 Linke&Seidell 31 25 15

17.85 0 0.744725 H3BO3 Linke&Seidell (1924L) 32 25 15.517.85 0.696737 0.664348 H3BO3 Linke&Seidell (1924L) 33 25 1617.85 1.408102 0.59376 H3BO3 Linke&Seidell (1924L) 34 25 16.517.85 2.882976 0.483943 H3BO3 Linke&Seidell (1924L) 35 25 1717.85 6.090412 0.355796 H3BO3 Linke&Seidell (1924L) 36 25 17.5

12 0 0.621542 H3BO3 Linke&Seidell (1924L) 37 25 1812 0.692726 0.546312 H3BO3 Linke&Seidell (1924L) 38 25 18.512 1.400711 0.488155 H3BO3 Linke&Seidell (1924L) 39 25 1912 2.869819 0.394975 H3BO3 Linke&Seidell (1924L) 40 25 19.512 4.539371 0.323043 H3BO3 Linke&Seidell (1924L) 41 25 20

42 25 20.143 25 20.244 25 20.345 25 20.4

1 25 19.89852 25 20.0453 25 20.1764 25 20.29135 25 20.31256 25 20.33157 25 20.3315

0 5 10 15 200.0

0.5

1.0

1.5

2.0

2.525C-1971GK25C-1910H25C-1965LS25C-H3BO3PPT25C-1971GK25C-LiCl.H2O17.85C-1924L17.85C-H3BO3PPT

m-LiCl

m-H

3BO

3

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8 25 20.33159 25 20.331510 25 20.331511 25 20.331512 25 20.3315

1 12 02 12 0.53 12 14 12 1.55 12 26 12 2.57 12 38 12 3.59 12 410 12 4.511 12 512 12 5.513 12 6

1 17.85 02 17.85 0.53 17.85 14 17.85 1.55 17.85 26 17.85 2.57 17.85 38 17.85 3.59 17.85 410 17.85 4.511 17.85 512 17.85 5.513 17.85 614 17.85 6.515 17.85 716 17.85 7.517 17.85 8

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BOH3IN solid0.933017 BOH3PPT0.913721 BOH3PPT0.847711 BOH3PPT0.767451 BOH3PPT0.690255 BOH3PPT0.62308 BOH3PPT0.567461 BOH3PPT0.522684 BOH3PPT0.487348 BOH3PPT0.459997 BOH3PPT0.43935 BOH3PPT0.42435 BOH3PPT0.414157 BOH3PPT0.408114 BOH3PPT0.405715 BOH3PPT0.406583 BOH3PPT0.41043 BOH3PPT0.417061 BOH3PPT0.426342 BOH3PPT0.438197 BOH3PPT0.452596 BOH3PPT0.469554 BOH3PPT0.489123 BOH3PPT0.511388 BOH3PPT0.536467 BOH3PPT0.564505 BOH3PPT0.595676 BOH3PPT0.630177 BOH3PPT0.668228 BOH3PPT0.71007 BOH3PPT0.755966 BOH3PPT0.806208 BOH3PPT0.861127 BOH3PPT0.92112 BOH3PPT0.986689 BOH3PPT1.05852 BOH3PPT1.13759 BOH3PPT1.2254 BOH3PPT1.32436 BOH3PPT1.43876 BOH3PPT1.57734 BOH3PPT1.60946 BOH3PPT1.64368 BOH3PPT1.68039 BOH3PPT1.68922 BOH3PPT

0 LICL.1H2O0.5 LICL.1H2O1 LICL.1H2O

1.5 LICL.1H2O1.6 LICL.1H2O1.7 LICL.1H2O1.8 LICL.1H2O

0 5 10 15 200.0

0.5

1.0

1.5

2.0

2.525C-1971GK25C-1910H25C-1965LS25C-H3BO3PPT25C-1971GK25C-LiCl.H2O17.85C-1924L17.85C-H3BO3PPT

m-LiCl

m-H

3BO

3

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1.9 LICL.1H2O2 LICL.1H2O

2.1 LICL.1H2O2.2 LICL.1H2O2.3 LICL.1H2O

0.634524 BOH3PPT0.602381 BOH3PPT0.543099 BOH3PPT0.482122 BOH3PPT0.429143 BOH3PPT0.386412 BOH3PPT0.353342 BOH3PPT0.32855 BOH3PPT0.310627 BOH3PPT0.298372 BOH3PPT0.290832 BOH3PPT0.287285 BOH3PPT0.287193 BOH3PPT

0.757942 BOH3PPT0.731691 BOH3PPT0.669185 BOH3PPT0.599685 BOH3PPT0.536375 BOH3PPT0.483455 BOH3PPT0.441143 BOH3PPT0.408278 BOH3PPT0.383415 BOH3PPT0.365225 BOH3PPT0.352605 BOH3PPT0.344687 BOH3PPT0.340802 BOH3PPT0.34045 BOH3PPT0.343263 BOH3PPT0.348985 BOH3PPT0.357443 BOH3PPT

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T m-NaCl m-BOH3 expm-BOH3 cal ref12 0 0.62154 0.634519 1924L12 0.4129 0.62276 0.67223 1924L12 0.83174 0.62381 0.675563 1924L12 1.68969 0.62867 0.628696 1924L12 3.49898 0.63353 0.497729 1924L

17.85 0 0.74473 0.757936 1924L17.85 0.83691 0.74443 0.819315 1924L17.85 1.70038 0.74477 0.778221 1924L17.85 2.5943 0.74467 0.705819 1924L17.85 3.52247 0.74511 0.635906 1924L23.85 0 0.89693 0.902889 1924L23.85 0.41833 0.89041 0.963821 1924L23.85 0.84279 0.88767 0.985067 1924L23.85 1.71223 0.87998 0.953431 1924L23.85 3.54896 0.88103 0.804517 1924L

25 3.26857 0.91164 0.86187 1910H25 1.63414 0.88695 0.994877 1910H25 0.87273 0.90359 1.0194 1910H25 0 0.93728 0.933011 1910H25 0 0.93403 0.933011 1979S25 0.95165 0.91748 1.0199 1979S25 2.00877 0.91516 0.967446 1979S25 3.1911 0.91893 0.868021 1979S25 4.52424 0.93223 0.778445 1979S25 6.04703 0.97394 0.720536 1979S25 6.24757 0.97996 0.716127 1979S

0 1.073530.09 0.684 1.074 1.16997 1993DBBD30.09 1.54 1.064 1.16874 1993DBBD30.09 2.396 1.051 1.10795 1993DBBD

30 3.251 1.05 1.03264 1993DBBD30.1 4.106 1.057 0.974102 1993DBBD30.09 4.991 1.074 0.926718 1993DBBD30.1 5.852 1.099 0.898829 1993DBBD30.06 6.203 1.108 0.890555 1993DBBD

0 1.407440.19 0.684 1.41 1.52327 1993DBBD40.17 1.54 1.395 1.5425 1993DBBD40.14 2.396 1.371 1.496 1993DBBD40.09 3.251 1.37 1.43036 1993DBBD40.09 4.106 1.375 1.37476 1993DBBD40.14 4.969 1.396 1.34056 1993DBBD40.14 5.814 1.423 1.32837 1993DBBD40.19 6.259 1.446 1.33462 1993DBBD

0 1.826350.23 0.684 1.845 1.94347 1993DBBD50.18 1.54 1.815 1.96708 1993DBBD50.08 2.396 1.79 1.92983 1993DBBD50.03 3.251 1.785 1.87946 1993DBBD50.08 4.106 1.792 1.84558 1993DBBD50.13 4.975 1.815 1.83988 1993DBBD50.13 5.839 1.861 1.87311 1993DBBD50.23 6.38 1.895 1.92956 1993DBBD

0 1 2 3 4 5 6 70

1

2

3

4

5

6

712C-1924L18C-1924L24C-1924L25C-1910H25C-1979S30C-1993DBBD

m-NaCl

m-H

3BO

3

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0 2.352360.23 0.684 2.352 2.4508 1993DBBD60.18 1.54 2.322 2.45714 1993DBBD60.12 2.396 2.297 2.41738 1993DBBD60.03 3.25 2.295 2.37147 1993DBBD59.98 4.106 2.285 2.34918 1993DBBD60.08 4.989 2.337 2.37833 1993DBBD60.13 5.863 2.376 2.47856 1993DBBD60.13 6.484 2.435 2.63701 1993DBBD

0 3.014370.46 0.677 3.045 3.09514 1993DBBD70.31 1.553 2.985 3.05687 1993DBBD70.06 2.414 2.94 2.98208 1993DBBD70.06 3.273 2.923 2.93045 1993DBBD69.96 4.161 2.949 2.90218 1993DBBD70.06 4.982 3.01 2.93302 1993DBBD70.06 5.827 3.027 3.02911 1993DBBD70.12 6.651 3.225 3.26721 1993DBBD

0 3.851379.58 0.729 3.84 3.81652 1993DBBD80.18 1.591 3.787 3.80241 1993DBBD80.18 2.659 3.771 3.70323 1993DBBD80.18 3.438 3.761 3.64917 1993DBBD80.18 4.736 3.835 3.62441 1993DBBD80.18 6.162 3.987 3.73367 1993DBBD80.45 6.788 4.096 3.87313 1993DBBD

0 4.917289.61 0.721 4.822 4.84061 1993DBBD90.16 1.55 4.8 4.82571 1993DBBD89.86 2.646 4.772 4.6898 1993DBBD89.76 3.43 4.763 4.63022 1993DBBD89.76 4.752 4.877 4.61404 1993DBBD89.76 5.431 4.962 4.64095 1993DBBD89.96 6.155 5.097 4.72527 1993DBBD90.44 6.953 5.246 4.89334 1993DBBD

0 6.2896100.17 0.708 6.107 6.29452 1993DBBD100.06 1.581 6.074 6.23193 1993DBBD99.76 2.632 6.039 6.15229 1993DBBD99.76 3.431 6.074 6.16077 1993DBBD99.66 4.713 6.207 6.21514 1993DBBD99.76 5.395 6.359 6.30612 1993DBBD99.96 6.078 6.508 6.44263 1993DBBD

100.34 7.149 6.797 6.72375 1993DBBD35 6.29673 1.32617 1.08932 1929T75 6.58762 3.59037 3.48292 1929T

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0 1 2 3 4 5 6 70

1

2

3

4

5

6

712C-1924L18C-1924L24C-1924L25C-1910H25C-1979S30C-1993DBBD

m-NaCl

m-H

3BO

3

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PTSSC_BOH3PPT CALCSC_BOH3PPT EXP BOH3IN CALCBOH3IN EXP T ACETACIDINBOH3IN ref1 0.999638 1 0 0 26 0 0.9595 seidell (1903H)2 0.855563 1 0 0 26 0.9099 0.8307 seidell (1903H)3 0.789091 1 0 0 26 1.9053 0.7772 seidell (1903H)4 0.601475 1 0 0 26 4.1734 0.608 seidell (1903H)5 0.432369 1 0 0 26 6.9287 0.4486 seidell (1903H)6 1.01343 1 0 0 30 0 1.0885 seidell7 0.971812 1 0 0 30 1.7889 1.0723 seidell8 0.995249 1 0 0 30 4.2734 1.1359 seidell9 0.910433 1 0 0 30 9.1843 1.0882 seidell10 0.933512 1 0 0 30 16.6964 1.1807 seidell11 0.87792 1 0 0 30 29.0669 1.1905 seidell12 1.04339 1 0 0 30 72.5648 1.7589 seidell13 1.20975 1 0 0 30 129.429 2.5919 seidell14 0.899942 X'-ACETACID 0 0 30 382.153 3.7513 seidell15 0 0 0.959858 0.9595 26 0 0 seidell (1903H)16 0 0.126994386767 0.97549 0.8307 26 0.9099 0 seidell (1903H)17 0 0.1821678138962 0.991754 0.7772 26 1.9053 0 seidell (1903H)18 0 0.2644367837398 1.02443 0.608 26 4.1734 0 seidell (1903H)19 0 0.33312132131 1.05795 0.4486 26 6.9287 0 seidell (1903H)20 0 0 1.07355 1.0885 30 0 0 seidell21 0 0.1766947636874 1.10455 1.0723 30 1.7889 0 seidell22 0 0.2673622576429 1.14153 1.1359 30 4.2734 0 seidell23 0 0.3767848031773 1.19951 1.0882 30 9.1843 0 seidell24 0 0.4808687793921 1.26828 1.1807 30 16.6964 0 seidell25 0 0.5862408053647 1.36313 1.1905 30 29.0669 0 seidell26 0 0.7527189567552 1.68262 1.7589 30 72.5648 0 seidell27 0 0.8365708342965 2.12379 2.5919 30 129.429 0 seidell28 0 0.9344352568955 4.18473 3.7513 30 382.153 0 seidell29 0 0 0.933017 0.95 25 0 0 1979S30 0 0.0998677520764 0.942517 0.8023 25 0.5592 0 1979S31 0 0.1852305277943 0.965696 1.0852 25 1.9722 0 1979S32 0 0 1.13439 1 32 0 0 1979S33 0 0.1038515712792 1.1452 1.1059 32 0.6052 0 1979S34 0 0.1330992758958 1.15234 1.1998 32 1.0011 0 1979S35 0 0.1863017621846 1.16926 1.4495 32 1.9959 0 1979S36 0 0 1.40737 1.4 40 0 0 1979S37 0 0.1239834605135 1.42374 1.3617 40 0.8666 0 1979S38 0 0.169782411724 1.43811 1.6002 40 1.6476 0 1979S39 0 0.2040457164387 1.45127 1.8513 40 2.4115 0 1979S40 0 0 2.35226 2.35 60 0 0 1979S41 0 0.1154911922202 2.36801 2.0273 60 0.7504 0 1979S42 0 0.1633466263248 2.38432 2.2936 60 1.5217 0 1979S43 0 0.2080895593387 2.40358 2.6056 60 2.5124 0 1979S44 0 0.2313253441535 2.41491 2.8822 60 3.1383 0 1979S45 0 0.2651809068976 2.43287 3.2393 60 4.1987 0 1979S46 0 0 3.8513 3.8513 80 0 0 1979S47 0 0.1228723472914 3.8715 3.0589 80 0.8509 0 1979S48 0 0.1356138997914 3.87611 3.2632 80 1.04 0 1979S49 0 0.178752881239 3.89445 3.5913 80 1.8322 0 1979S50 0 0.210997336306 3.91049 3.9251 80 2.5864 0 1979S51 0 0.2317399963117 3.9217 4.2303 80 3.1502 0 1979S52 0 0.2612711555072 3.93871 4.6254 80 4.0668 0 1979S53 0 0 6.28959 5 100 0 0 1979S

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54 0 0.0882197661311 6.302 4.9796 100 0.4354 0 1979S55 0 0.1982278521118 6.35228 5.8801 100 2.2704 0 1979S56 0 0.2536397131562 6.38648 6.5596 100 3.8166 0 1979S57 0 0.2688844022249 6.39649 6.9261 100 4.326 0 1979S58 0 0.2993325865586 6.41715 7.5152 100 5.4631 0 1979S

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0.0 0.2 0.4 0.6 0.8 1.00.00.51.01.52.02.53.03.54.04.5

solubility of H3BO3 in acetic acid-water

1909D1903H

X'-HAc (H3BO3-free)

m-H

3BO

3

0.0 0.2 0.4 0.6 0.8 1.00.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0solubility of H3BO3 in acetic acid-water

30C-1909D26C-1903H25C32C40C60C80C100C

X'̂ 0.5-HAc (H3BO3-free)m

-H3B

O3

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0.0 0.2 0.4 0.6 0.8 1.00.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0solubility of H3BO3 in acetic acid-water

30C-1909D26C-1903H25C32C40C60C80C100C

X'̂ 0.5-HAc (H3BO3-free)

m-H

3BO

3

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H2O+H3BO3+C4H6O5

0 050 100

100 0

Burgess, Stanley Grove; Hunter, HaroldInvestigations on the dependence of rotatory power on chemical constitution. Part XXXIV. Borotartaric acidJournal of the Chemical Society 1929, 2838-2852

t w% w%C H3BO3 tartaric acid

0 1.9 0 1.9 00 6.8 33.1 23.35 33.10 10 55.8 37.9 55.80 11.1 62.3 42.25 62.30 6.4 58.6 35.7 58.60 0 53.5 26.75 53.5

25 5.1 0 5.1 025 5.3 2.8 6.7 2.825 5.8 9.5 10.55 9.525 6.2 14.9 13.65 14.925 7.3 24.6 19.6 24.625 8.8 31.3 24.45 31.325 9.6 39.4 29.3 39.425 10.5 49.1 35.05 49.125 13 65.1 45.55 65.125 10.7 63.7 42.55 63.725 9.9 63.3 41.55 63.325 7.8 61.6 38.6 61.625 4.2 60.4 34.4 60.4

0 10 20 30 40 50 60 70 80 90 1000

10

20

30

40

50

60

70

80

90

100H2O+H3BO3+C4H6O5

Column H Column H Column H

Column H Column H Column H

Column H Column H Column H

w% H3BO3

w%

mal

ic a

cid

(tarta

ric a

cid)

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25 0 59.6 29.8 59.650 9.5 0 9.5 050 9.5 4.4 11.7 4.450 9.6 14.3 16.75 14.350 9.8 15.2 17.4 15.250 10 19.6 19.8 19.650 10 25.1 22.55 25.150 10.2 28.6 24.5 28.650 10.7 37.8 29.6 37.850 12.8 51.2 38.4 51.250 14.8 60.1 44.85 60.150 15.8 65 48.3 6550 16.5 67.3 50.15 67.350 12.4 66.9 45.85 66.950 9.3 66.7 42.65 66.750 5.8 66.2 38.9 66.250 0 66.1 33.05 66.1

MSE

t w% w%C H3BO3 malic acid

0 2.5766994 0 2.5766994 00 2.5949937 0.1304264 2.6602069 0.13042640 2.6152876 0.2604317 2.7455035 0.26043170 2.6767698 0.6479352 3.0007373 0.64793520 2.7799258 1.2854901 3.4226708 1.28549010 2.8831307 1.9128665 3.8395639 1.91286650 2.9860122 2.530281 4.2511526 2.5302810 3.0883633 3.1379407 4.6573337 3.13794070 3.1900701 3.7360574 5.0580988 3.73605740 3.3912513 4.9044713 5.8434869 4.90447130 3.589183 6.0371124 6.6077392 6.03711240 3.7836954 7.1355076 7.3514492 7.13550760 3.9747041 8.2010499 8.0752291 8.20104990 4.1621971 9.2351412 8.7797676 9.23514120 4.346193 10.239055 9.4657204 10.2390550 4.5267229 11.214027 10.133736 11.2140270 4.7038453 12.161255 10.784473 12.1612550 4.8776072 13.081792 11.418503 13.0817920 5.0480822 13.976755 12.036459 13.9767550 5.2153252 14.847086 12.638868 14.8470860 5.3794151 15.693784 13.226307 15.6937840 5.5404131 16.517735 13.79928 16.5177350 5.6983748 17.319773 14.358261 17.3197730 5.8533842 18.10076 14.903764 18.100760 6.0055034 18.861492 15.436249 18.8614920 6.1547935 19.602694 15.95614 19.6026940 6.5160228 21.374794 17.20342 21.3747940 6.8608781 23.03949 18.380623 23.039490 7.1902068 24.605919 19.493166 24.6059190 7.5048369 26.082332 20.546003 26.0823320 7.8055107 27.476028 21.543525 27.4760280 8.0929515 28.793647 22.489775 28.793647

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0 8.3678363 30.041195 23.388434 30.0411950 8.6307933 31.223984 24.242785 31.2239840 8.8824282 32.346914 25.055885 32.3469140 9.1233129 33.41437 25.830498 33.414370 9.3539839 34.430309 26.569138 34.4303090 9.574984 35.398481 27.274225 35.3984810 9.7867763 36.322094 27.947823 36.3220940 9.9898411 37.204183 28.591933 37.2041830 10.184621 38.047527 29.208385 38.0475270 10.371518 38.854544 29.79879 38.8545440 10.550967 39.627709 30.364822 39.6277090 10.723329 40.369066 30.907862 40.3690660 10.888967 41.080566 31.42925 41.0805660 11.048203 41.763919 31.930162 41.7639190 11.201381 42.420912 32.411837 42.4209120 11.348792 43.05297 32.875277 43.052970 11.490727 43.661549 33.321502 43.6615490 11.627442 44.247859 33.751372 44.2478590 11.759228 44.813285 34.165871 44.8132850 11.8863 45.358822 34.565711 45.3588220 12.008879 45.885482 34.95162 45.8854820 12.127226 46.394418 35.324435 46.3944180 12.2415 46.886353 35.684676 46.8863530 12.351898 47.362154 36.032975 47.3621540 12.458618 47.822669 36.369953 47.8226690 12.561816 48.268576 36.696104 48.2685760 12.661669 48.700628 37.011983 48.7006280 12.758335 49.119496 37.318083 49.1194960 12.851936 49.525679 37.614776 49.5256790 12.942634 49.919859 37.902564 49.9198590 13.115766 50.674031 38.452781 50.6740310 13.278691 51.386049 38.971716 51.3860490 13.432241 52.059237 39.46186 52.0592370 13.577237 52.696906 39.92569 52.6969060 13.714293 53.301665 40.365126 53.3016650 13.844093 53.876099 40.782143 53.8760990 13.967153 54.422394 41.17835 54.4223940 14.083993 54.942585 41.555286 54.9425850 14.195063 55.438532 41.914329 55.4385320 14.300778 55.91191 42.256733 55.911910 14.401525 56.364244 42.583647 56.3642440 14.497623 56.796863 42.896055 56.7968630 14.589409 57.211051 43.194935 57.2110510 14.677155 57.607951 43.48113 57.6079510 14.761122 57.988651 43.755448 57.9886510 14.841559 58.354154 44.018636 58.3541540 14.918668 58.705285 44.271311 58.7052850 14.992666 59.042937 44.514135 59.0429370 15.132038 59.680701 44.972389 59.6807010 15.261005 60.272905 45.397457 60.2729050 15.380689 60.824304 45.79284 60.8243040 15.49206 61.338945 46.161533 61.3389450 15.595966 61.820368 46.50615 61.8203680 15.693129 62.271735 46.828996 62.271735

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0 15.784209 62.695754 47.132086 62.6957540 15.869741 63.094816 47.417149 63.0948160 15.950253 63.471124 47.685815 63.4711240 16.02613 63.826464 47.939362 63.8264640 16.097802 64.162628 48.179116 64.1626280 16.165604 64.481097 48.406152 64.4810970 16.229836 64.783247 48.62146 64.7832470 16.290772 65.070273 48.825908 65.0702730 16.348671 65.343293 49.020318 65.3432930 16.403763 65.603318 49.205423 65.6033180 16.456223 65.851212 49.381829 65.8512120 16.506255 66.087882 49.550196 66.0878820 16.554025 66.314015 49.711033 66.3140150 16.599684 66.530325 49.864846 66.5303250 16.643361 66.737419 50.012071 66.7374190 16.685192 66.93584 50.153112 66.935840 16.725283 67.126208 50.288387 67.1262080 16.763745 67.308941 50.418216 67.3089410 16.800674 67.484461 50.542904 67.4844610 16.836174 67.653264 50.662806 67.6532640 16.870311 67.815715 50.778169 67.8157150 16.903161 67.972094 50.889208 67.9720940 16.934812 68.122828 50.996226 68.1228280 16.965312 68.268141 51.099382 68.2681410 16.99474 68.408375 51.198927 68.4083750 17.023129 68.543738 51.294998 68.5437380 17.050551 68.674537 51.387819 68.6745370 17.077046 68.800972 51.477532 68.8009720 17.102662 68.923229 51.564276 68.9232290 17.127449 69.04155 51.648224 69.041550 17.151447 69.156132 51.729513 69.1561320 17.174675 69.26712 51.808235 69.267120 17.197197 69.374688 51.88454 69.3746880 17.219025 69.478994 51.958522 69.4789940 17.40548 70.370918 52.590939 70.3709180 17.548335 71.055221 53.075946 71.0552210 17.661305 71.596842 53.459726 71.5968420 17.752891 72.036146 53.770964 72.0361460 0 45.469422 22.734711 45.4694220 0.0336709 45.501237 22.784289 45.5012370 0.0672604 45.523681 22.829101 45.5236810 0.1675994 45.572507 22.953853 45.5725070 0.3334484 45.641437 23.154167 45.6414370 0.4975887 45.708092 23.351635 45.7080920 0.6600377 45.774564 23.54732 45.7745640 0.8208052 45.841454 23.741532 45.8414540 0.9799074 45.90893 23.934372 45.908930 1.2931603 46.045779 24.31605 46.0457790 1.599896 46.185406 24.692599 46.1854060 1.9002167 46.327693 25.064063 46.3276930 2.1942259 46.472673 25.430563 46.4726730 2.4820238 46.620167 25.792107 46.6201670 2.7637073 46.770139 26.148777 46.7701390 3.0393753 46.922425 26.500588 46.922425

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0 3.309131 47.076897 26.84758 47.0768970 3.5730719 47.233513 27.189829 47.2335130 3.8313006 47.392065 27.527333 47.3920650 4.0838987 47.552522 27.86016 47.5525220 4.3309913 47.714757 28.18837 47.7147570 4.5726637 47.878699 28.512013 47.8786990 4.8090034 48.04416 28.831084 48.044160 5.0401034 48.211041 29.145624 48.2110410 5.2660778 48.37936 29.455758 48.379360 5.4870091 48.548887 29.761452 48.5488870 6.0178912 48.977721 30.506752 48.9777210 6.5193078 49.412427 31.225521 49.4124270 6.9926476 49.851508 31.918402 49.8515080 7.4393311 50.29384 32.586251 50.293840 7.860698 50.737965 33.229681 50.7379650 8.2580897 51.182741 33.84946 51.1827410 8.6327553 51.627025 34.446268 51.6270250 8.985961 52.069693 35.020807 52.0696930 9.3189389 52.509863 35.57387 52.5098630 9.6328195 52.946542 36.10609 52.9465420 9.9287364 53.378897 36.618185 53.3788970 10.207788 53.806227 37.110901 53.8062270 10.470974 54.227867 37.584908 54.2278670 10.719286 54.643156 38.040865 54.6431560 10.953676 55.051733 38.479542 55.0517330 11.174985 55.453039 38.901504 55.4530390 11.384093 55.8468 39.307493 55.84680 11.581763 56.232675 39.6981 56.2326750 11.768748 56.610488 40.073992 56.6104880 11.945752 56.980086 40.435795 56.9800860 12.113395 57.341244 40.784017 57.3412440 12.272325 57.694038 41.119344 57.6940380 12.423091 58.03835 41.442266 58.038350 12.566244 58.374277 41.753382 58.3742770 12.702273 58.701849 42.053198 58.7018490 12.83162 59.021051 42.342146 59.0210510 12.954734 59.332074 42.620771 59.3320740 13.072004 59.634995 42.889502 59.6349950 13.183825 59.930042 43.148846 59.9300420 13.290502 60.217221 43.399112 60.2172210 13.392387 60.496827 43.6408 60.4968270 13.489758 60.768956 43.874236 60.7689560 13.582901 61.033824 44.099814 61.0338240 13.672073 61.291631 44.317889 61.2916310 13.757509 61.542551 44.528784 61.5425510 13.839416 61.786707 44.732769 61.7867070 13.993513 62.255792 45.121408 62.2557920 14.135812 62.700284 45.485954 62.7002840 14.267593 63.121663 45.828425 63.1216630 14.389978 63.521418 46.150687 63.5214180 14.503918 63.900839 46.454337 63.9008390 14.610262 64.261254 46.740889 64.2612540 14.709749 64.603879 47.011689 64.6038790 14.803017 64.929811 47.267922 64.929811

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0 14.890637 65.240119 47.510696 65.2401190 14.973118 65.535833 47.741035 65.5358330 15.050893 65.817804 47.959795 65.8178040 15.124369 66.086938 48.167837 66.0869380 15.193895 66.344031 48.365911 66.3440310 15.259793 66.589835 48.554711 66.5898350 15.322334 66.824989 48.734828 66.8249890 15.381774 67.050146 48.906847 67.0501460 15.438346 67.26591 49.071301 67.265910 15.492261 67.472849 49.228685 67.4728490 15.592831 67.862176 49.523919 67.8621760 15.684779 68.22176 49.79566 68.221760 15.76918 68.554751 50.046556 68.5547510 15.846958 68.863985 50.27895 68.8639850 15.918865 69.151816 50.494773 69.1518160 15.98555 69.420331 50.695715 69.4203310 16.047578 69.671417 50.883286 69.6714170 16.105422 69.906663 51.058754 69.9066630 16.159492 70.127477 51.223231 70.1274770 16.210159 70.335166 51.377742 70.3351660 16.422212 71.2119 52.028161 71.21190 16.583686 71.886725 52.527049 71.8867250 16.710848 72.421917 52.921807 72.4219170 16.813624 72.856605 53.241927 72.8566050 16.898431 73.216576 53.506719 73.2165760 16.969628 73.5196 53.729428 73.5196

25 5.4542988 0 5.4542988 025 5.4699585 0.1265755 5.5332462 0.126575525 5.4893476 0.2527422 5.6157187 0.252742225 5.5480722 0.6287985 5.8624715 0.628798525 5.6462607 1.247509 6.2700152 1.24750925 5.7441247 1.856346 6.6722977 1.85634625 5.8413497 2.4555145 7.0691069 2.455514525 5.9378247 3.0452318 7.4604406 3.045231825 6.0334689 3.6257129 7.8463254 3.625712925 6.2219597 4.7597365 8.601828 4.759736525 6.4066461 5.8591621 9.3362272 5.859162125 6.5874034 6.9254976 10.050152 6.925497625 6.7642962 7.9601138 10.744353 7.960113825 6.9373233 8.9644139 11.41953 8.964413925 7.1065779 9.9396196 12.076388 9.939619625 7.2721311 10.886931 12.715597 10.88693125 7.4340226 11.807501 13.337773 11.80750125 7.5924335 12.702437 13.943652 12.70243725 7.7473859 13.572711 14.533742 13.57271125 7.898991 14.419328 15.108655 14.41932825 8.0473263 15.24322 15.668936 15.2432225 8.1925214 16.045244 16.215144 16.04524425 8.3346421 16.82622 16.747752 16.8262225 8.4737491 17.587003 17.267251 17.58700325 8.6099644 18.328311 17.77412 18.32831125 8.7433355 19.050832 18.268752 19.05083225 9.0649209 20.779547 19.454694 20.77954725 9.3704276 22.405127 20.572991 22.405127

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25 9.6609296 23.936337 21.629098 23.93633725 9.9373907 25.381044 22.627913 25.38104425 10.200697 26.746285 23.573839 26.74628525 10.45166 28.038355 24.470837 28.03835525 10.69105 29.262952 25.322526 29.26295225 10.919535 30.425036 26.132053 30.42503625 11.137784 31.529449 26.902508 31.52944925 11.346395 32.580241 27.636515 32.58024125 11.545905 33.581207 28.336509 33.58120725 11.736874 34.535815 29.004782 34.53581525 11.91974 35.447294 29.643387 35.44729425 12.094969 36.318391 30.254164 36.31839125 12.26299 37.151749 30.838865 37.15174925 12.424208 37.949894 31.399155 37.94989425 12.578973 38.714872 31.936409 38.71487225 12.727634 39.448832 32.452051 39.44883225 12.87052 40.153603 32.947322 40.15360325 13.007933 40.830864 33.423365 40.83086425 13.140135 41.482246 33.881258 41.48224625 13.267425 42.109142 34.321997 42.10914225 13.390057 42.713125 34.74662 42.71312525 13.508202 43.295113 35.155759 43.29511325 13.622172 43.856659 35.550501 43.85665925 13.732107 44.398508 35.931361 44.39850825 13.838252 44.921947 36.299226 44.92194725 13.94074 45.427726 36.654603 45.42772625 14.039791 45.916797 36.99819 45.91679725 14.135534 46.389993 37.33053 46.38999325 14.228138 46.848037 37.652157 46.84803725 14.317728 47.291685 37.96357 47.29168525 14.404476 47.721646 38.265299 47.72164625 14.488494 48.138524 38.557756 48.13852425 14.569893 48.542829 38.841307 48.54282925 14.648814 48.935287 39.116457 48.93528725 14.799586 49.686366 39.642769 49.68636625 14.94162 50.395648 40.139444 50.39564825 15.075626 51.066472 40.608862 51.06647225 15.202248 51.70196 41.053228 51.7019625 15.322061 52.304832 41.474477 52.30483225 15.435624 52.877605 41.874426 52.87760525 15.543351 53.422413 42.254557 53.42241325 15.645721 53.941307 42.616375 53.94130725 15.743096 54.436078 42.961135 54.43607825 15.835828 54.908366 43.290011 54.90836625 15.924247 55.35974 43.604117 55.3597425 16.008636 55.791495 43.904384 55.79149525 16.089271 56.204943 44.191743 56.20494325 16.166399 56.601193 44.466995 56.60119325 16.240247 56.981336 44.730915 56.98133625 16.310979 57.346255 44.984107 57.34625525 16.378846 57.696963 45.227328 57.69696325 16.443978 58.034187 45.461072 58.03418725 16.566717 58.671276 45.902355 58.67127625 16.680357 59.26301 46.311862 59.26301

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50 0.5701023 68.529958 34.835081 68.52995850 0.7572301 68.405893 34.960177 68.40589350 0.9428931 68.284141 35.084964 68.28414150 1.1270829 68.164662 35.209414 68.16466250 1.3097759 68.04785 35.333701 68.0478550 1.4909865 67.933177 35.457575 67.93317750 1.6706916 67.821008 35.581196 67.82100850 1.848893 67.711168 35.704477 67.71116850 2.0255886 67.603545 35.827361 67.60354550 2.2007588 67.498308 35.949913 67.49830850 2.3744046 67.395402 36.072106 67.39540250 2.5465278 67.294774 36.193915 67.29477450 2.7171158 67.196442 36.315337 67.19644250 2.8861682 67.100374 36.436355 67.10037450 3.053681 67.006523 36.556942 67.00652350 3.2196607 66.914961 36.677141 66.91496150 3.3840822 66.825569 36.796867 66.82556950 3.546962 66.738397 36.91616 66.73839750 3.9473889 66.53012 37.212449 66.5301250 4.33811 66.335353 37.505786 66.33535350 4.7191093 66.153947 37.796083 66.15394750 5.090398 65.985672 38.083234 65.98567250 5.4519912 65.830323 38.367153 65.83032350 5.8039021 65.687665 38.647734 65.68766550 6.1461699 65.557383 38.924861 65.55738350 6.4788666 65.439296 39.198515 65.43929650 6.8020342 65.333051 39.46856 65.33305150 7.1157725 65.238393 39.734969 65.23839350 7.4201555 65.154903 39.997607 65.15490350 7.7152935 65.082378 40.256482 65.08237850 8.0012902 65.020318 40.511449 65.02031850 8.2782941 64.968433 40.762511 64.96843350 8.546429 64.926321 41.00959 64.92632150 8.8058546 64.893612 41.252661 64.89361250 9.0567261 64.86988 41.491666 64.8698850 9.2992113 64.854766 41.726594 64.85476650 9.5334929 64.847802 41.957394 64.84780250 9.7597589 64.848628 42.184073 64.84862850 9.9781826 64.856808 42.406587 64.85680850 10.188988 64.871972 42.624974 64.87197250 10.392356 64.893685 42.839198 64.89368550 10.588507 64.921577 43.049295 64.92157750 10.77763 64.955216 43.255238 64.95521650 10.959957 64.994253 43.457084 64.99425350 11.135683 65.038331 43.654849 65.03833150 11.305021 65.087038 43.84854 65.08703850 11.4682 65.140076 44.038238 65.14007650 11.625406 65.197086 44.223949 65.19708650 11.77686 65.257739 44.40573 65.25773950 11.922757 65.321732 44.583623 65.32173250 12.063309 65.388739 44.757678 65.38873950 12.198703 65.458509 44.927957 65.45850950 12.329142 65.530768 45.094526 65.53076850 12.454824 65.605272 45.25746 65.605272

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50 12.692609 65.759943 45.572581 65.75994350 12.913474 65.920796 45.873872 65.92079650 13.118767 66.086224 46.161879 66.08622450 13.309724 66.254861 46.437154 66.25486150 13.487519 66.425528 46.700283 66.42552850 13.653217 66.597193 46.951814 66.59719350 13.807825 66.768976 47.192313 66.76897650 13.952234 66.940153 47.42231 66.94015350 14.087288 67.110095 47.642336 67.11009550 14.213751 67.278268 47.852884 67.27826850 14.332312 67.44429 48.054457 67.4442950 14.443631 67.607837 48.247549 67.60783750 14.548266 67.768586 48.432559 67.76858650 14.646757 67.926388 48.609951 67.92638850 14.739579 68.081056 48.780108 68.08105650 14.827173 68.232485 48.943415 68.23248550 14.909931 68.380579 49.100221 68.38057950 14.988216 68.525281 49.250856 68.52528150 15.132697 68.804606 49.535 68.80460650 15.262916 69.07047 49.798151 69.0704750 15.3808 69.32314 50.04237 69.3231450 15.487986 69.563161 50.269566 69.56316150 15.585813 69.790985 50.481306 69.79098550 15.675446 70.007273 50.679082 70.00727350 15.757856 70.212629 50.86417 70.21262950 15.833879 70.40768 51.037719 70.4076850 15.904215 70.593 51.200715 70.59350 15.969481 70.769188 51.354075 70.76918850 16.236045 71.531648 52.001869 71.53164850 16.432152 72.136911 52.500608 72.13691150 16.582646 72.626646 52.895969 72.62664650 16.701924 73.030026 53.216937 73.03002650 16.798859 73.367448 53.482583 73.36744850 16.879257 73.653634 53.706074 73.653634

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0 10 20 30 40 50 60 70 80 90 1000

10

20

30

40

50

60

70

80

90

100H2O+H3BO3+C4H6O5

Column H Column H Column H

Column H Column H Column H

Column H Column H Column H

w% H3BO3

w%

mal

ic a

cid

(tarta

ric a

cid)

Page 238: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

Reburn, William T.; Gale, William A.The system lithium oxide – boric oxide – waterThe Journal of Physical Chemistry 1955, 59 (1), 19-24

wt% tLiBO2 C

0.88 0 LiBO2.8H2O1.42 10 LiBO2.8H2O2.51 20 LiBO2.8H2O4.63 30 LiBO2.8H2O5.97 34 LiBO2.8H2O6.41 35 LiBO2.8H2O6.84 36 LiBO2.8H2O7.2 36.9 LiBO2.8H2O+LiBO2.2H2O9.4 40 LiBO2.8H2O (metastable)7.2 36.9 LiBO2.2H2O+LiBO2.8H2O

7.26 37 LiBO2.2H2O7.33 38 LiBO2.2H2O7.34 39 LiBO2.2H2O7.4 40 LiBO2.2H2O

7.84 50 LiBO2.2H2O8.43 60 LiBO2.2H2O

0 5 10 15 20 25 30 350

50

100

150

200

250

300

350 Column B Column B

Column B Column B

Column B Column B

Bouaziz Column B

Column E Column B

Column B

w% LiBO2

t/C

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9.48 70 LiBO2.2H2O10.58 80 LiBO2.2H2O

13.4 101.2 LiBO2.2H2O

cited from Seidell

wt% tLiBO2 C

0.89 0 LiBO2.8H2O2.203 18 LiBO2.8H2O3.344 25 LiBO2.8H2O

9.42 38.8 LiBO2.8H2O14.7 44.8 LiBO2.8H2O

cited from Seidell

wt% tLiBO2 C

4.65 30 LiBO2.8H2O34.1 42 LiBO2.8H2O

29.97 46 LiBO2.8H2O25.67 47.1 LiBO2.8H2O

Menzel, HeinrichZur Kenntnis der Borsäuren und borsauren Alkalisalze. II. Die Alkaliborate in wäßriger LösungZeitschrift für anorganische und allgemeine Chemie 1927, 164 (1), 22-62

wt% tLiBO2 C0.1832401 -0.13 ice0.3312274 -0.23 ice0.4265182 -0.291 ice0.5240885 -0.356 ice0.5929622 -0.402 ice0.6980566 -0.468 ice0.7799152 -0.515 ice0.8547931 -0.557 ice

Menzel, HeinrichZur Kenntnis der Borsäuren und borsauren Alkalisalze. III. Die Alkalimono- und –polyborate in festem ZustandZeitschrift für anorganische und allgemeine Chemie 1927, 166 (1), 63-98

wt% tLiBO2 C2.2039922 18 LiBO2.8H2O3.3420513 25 LiBO2.8H2O

Byers, W. A.; Lindsay, W. T.; Kunig, R. H.Solubility of lithium monoborate in high-temperature water,Journal of Solution Chemistry 2000, 29 (6), 541-559

w% tLiBO2 C1.7162462 270

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1.5525812 2801.3883703 2901.2284643 3001.072908 310

0.9217448 3200.7701189 3300.6327671 3400.5048852 3500.4013555 360

cited from Bouaziz

w% tLiBO2 C2.6020453 2752.8515348 245

w% t mLiBO2 C LiBO230.303053 63 8.739405828.948462 64 8.189573627.893714 65 7.775753527.009559 66 7.438078826.238707 67 7.1502822 31.678878 67 9.320175125.54986 68 6.8981443 30.357232 68 8.7618419

24.923659 69 6.6729517 29.32797 69 8.341491424.347287 70 6.468973 28.464528 70 7.998191823.811651 71 6.2821779 27.710942 71 7.705272423.310097 72 6.1096335 27.036687 72 7.448317722.837591 73 5.9491344 26.422898 73 7.218501422.390191 74 5.7989646 25.857059 74 7.010009121.964726 75 5.6577547 25.330412 75 6.818797221.558672 76 5.5244154 24.836452 76 6.641888221.169921 77 5.3980456 24.370333 77 6.477069420.79674 78 5.2779038 23.928208 78 6.3226013

20.437658 79 5.1633652 23.507023 79 6.177110220.091398 80 5.0538912 23.104378 80 6.039513419.756898 81 4.9490326 22.718253 81 5.908908619.433216 82 4.848394 22.346919 82 5.78453219.119529 83 4.7516318 21.989011 83 5.665773318.815137 84 4.6584515 21.643323 84 5.552099118.519382 85 4.5685823 21.308799 85 5.443046818.231721 86 4.4817958 20.984535 86 5.338220617.951636 87 4.3978802 20.669756 87 5.237280417.678692 88 4.3166531 20.363811 88 5.139937717.412488 89 4.2379489 20.066064 89 5.045918917.152618 90 4.1616053 19.775995 90 4.954995516.898807 91 4.0875026 19.493135 91 4.866962916.650732 92 4.0155111 19.217034 92 4.781628416.408077 93 3.9455055 18.947333 93 4.698833416.170655 94 3.8774018 18.683664 94 4.618421115.938171 95 3.8110876 18.425725 95 4.5402592

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15.710455 96 3.7464877 18.173221 96 4.464221515.487309 97 3.6835223 17.925919 97 4.390203715.268514 98 3.6221066 17.68355 98 4.318093915.053961 99 3.5621888 17.445915 99 4.247803914.843424 100 3.5036859 17.212807 100 4.179244914.636801 101 3.4465514 16.984046 101 4.112338614.43395 102 3.3907282 16.759454 102 4.0470095

14.234745 103 3.3361656 16.538877 103 3.983190314.039038 104 3.2828071 16.322164 104 3.920816913.846753 105 3.2306178 16.109211 105 3.859839713.65778 106 3.1795537 15.89984 106 3.800189113.47198 107 3.1295646 15.693971 107 3.741825

13.289288 108 3.0806207 15.49146 108 3.684690613.109619 109 3.0326872 15.292224 109 3.628746512.932911 110 2.9857368 15.096159 110 3.573949312.759023 111 2.9397215 14.90319 111 3.520263812.587945 112 2.8946282 14.713176 112 3.467637912.419555 113 2.8504153 14.526113 113 3.416057912.253815 114 2.8070642 14.341852 114 3.365470812.090633 115 2.7645419 14.160366 115 3.315857711.929966 116 2.7228286 13.98157 116 3.267184811.771755 117 2.6819016 13.805397 117 3.219423411.61592 118 2.6417325 13.631754 118 3.1725385

11.462432 119 2.6023066 13.460637 119 3.126519911.311236 120 2.5636027 13.291966 120 3.081336611.162272 121 2.5255992 13.12566 121 3.036958911.015488 122 2.4882762 12.961688 122 2.993369810.870853 123 2.4516199 12.799989 123 2.950545710.728323 124 2.4156132 12.640532 124 2.908470410.587814 125 2.3802297 12.483262 125 2.867122410.449333 126 2.3454654 12.328139 126 2.826484210.312819 127 2.3113 12.175091 127 2.786530310.178237 128 2.2777197 12.024139 128 2.747259710.04555 129 2.2447105 11.875179 129 2.7086393

9.9146936 130 2.2122521 11.728184 130 2.67065629.7856832 131 2.1803437 11.58313 131 2.63329839.6584737 132 2.14897 11.440004 132 2.59655719.5329938 133 2.1181093 11.298719 133 2.56040479.4092324 134 2.087755 11.159294 134 2.52484079.2871539 135 2.0578946 11.021647 135 2.48983989.1667444 136 2.028521 10.885805 136 2.45540399.0479516 137 1.9996181 10.751679 137 2.42150578.9307771 138 1.9711828 10.619258 138 2.38813838.8151574 139 1.9431964 10.488524 139 2.35529288.7011079 140 1.9156595 10.359463 140 2.32296198.5885662 141 1.888554 10.232008 141 2.29112428.4774856 142 1.8618659 10.106145 142 2.25977298.3679116 143 1.8356031 9.9818494 143 2.2288988.2597554 144 1.8097416 9.8591306 144 2.19849848.1530466 145 1.7842859 9.7379225 145 2.16855418.047731 146 1.7592205 9.6181916 146 2.1390536

7.9437447 147 1.7345277 9.4999329 147 2.10999257.8411422 148 1.7102182 9.3831613 148 2.08137127.7398572 149 1.6862738 9.2678091 149 2.0531702

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7.6398889 150 1.6626922 9.1538597 150 2.02538247.5411961 151 1.6394615 9.0412978 151 1.99800147.4437657 152 1.6165766 8.9301036 152 1.97101957.3476034 153 1.5940367 8.8202498 153 1.94442757.2526563 154 1.5718275 8.7117313 154 1.91822167.158932 155 1.5499489 8.6045263 155 1.892394

7.0663905 156 1.5283897 8.498582 156 1.86692956.974991 157 1.5071386 8.3939233 157 1.8418319

6.8847957 158 1.4862085 8.2905233 158 1.81709246.7956974 159 1.4655726 8.1883433 159 1.79269956.7077389 160 1.4452394 8.087398 160 1.76865466.6208947 161 1.4252014 7.9876476 161 1.74494626.5350923 162 1.4054403 7.8890564 162 1.72156376.4504145 163 1.3859738 7.7916585 163 1.69851346.3667762 164 1.3667808 7.6953904 164 1.67577826.2841967 165 1.3478644 7.6002749 165 1.65336186.2026478 166 1.3292168 7.5062557 166 1.6312496.1221306 167 1.3108368 7.4133576 167 1.60944416.042644 168 1.2927231 7.321559 168 1.5879401

5.9641494 169 1.2748654 7.2308466 169 1.56673245.8866618 170 1.257266 7.1412212 170 1.54581955.8101607 171 1.2399191 7.0526372 171 1.52518935.7345985 172 1.2228128 6.9651283 172 1.5048485.6599867 173 1.2059485 6.8786547 173 1.48478495.5863039 174 1.1893203 6.7931813 174 1.46499045.5135292 175 1.1729225 6.7087456 175 1.44547195.4416798 176 1.156758 6.6252851 176 1.42621355.3707284 177 1.1408196 6.5428316 177 1.40722135.3006372 178 1.1250979 6.46134 178 1.38848355.2314492 179 1.1096015 6.3808188 179 1.37000095.1631055 180 1.0943165 6.3012309 180 1.35176375.0955961 181 1.0792397 6.222569 181 1.33376915.0289424 182 1.064375 6.1448308 182 1.31601554.963085 183 1.0497084 6.0679995 183 1.29849794.898061 184 1.0352473 5.9920732 184 1.2812147

4.8338491 185 1.0209862 5.9170397 185 1.26416214.7704049 186 1.0069145 5.842853 186 1.24732884.7077568 187 0.9930377 5.7695476 187 1.2307214

4.64587 188 0.9793475 5.6970963 188 1.21433294.5847321 189 0.9658404 5.6254875 189 1.19815974.5243629 190 0.9525201 5.5546934 190 1.18219464.4647281 191 0.9393783 5.4847334 191 1.16644114.4058279 192 0.9264146 5.4155716 192 1.15089034.3476428 193 0.9136239 5.347211 193 1.13554194.2901707 194 0.9010052 5.2796388 194 1.12039244.2333936 195 0.888554 5.2128553 195 1.10544084.1773182 196 0.8762711 5.146848 196 1.09068384.1219245 197 0.8641517 5.0815901 197 1.07611444.0672062 198 0.8521938 5.0170815 198 1.0617324.0131526 199 0.8403945 4.9533111 199 1.04753343.9597594 200 0.8287525 4.8902761 200 1.03351723.9070179 201 0.8172652 4.8279443 201 1.01967573.8549163 202 0.8059297 4.7663648 202 1.0060193.8034426 203 0.7947428 4.7054504 203 0.9925272

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3.7525992 204 0.7837047 4.6452594 204 0.97921253.7023686 205 0.772811 4.5857526 205 0.96606573.6527546 206 0.7620623 4.526928 206 0.95308573.6037376 207 0.7514537 4.4687796 207 0.94027073.5553158 208 0.7409846 4.4112796 208 0.92761383.5074791 209 0.7306522 4.3544518 209 0.91511993.460224 210 0.7204556 4.2982607 210 0.9027805

3.4135407 211 0.7103921 4.2427103 211 0.89059613.367424 212 0.7004603 4.1877951 212 0.8785649

3.3218601 213 0.6906569 4.1335021 213 0.86668363.2768517 214 0.680982 4.0798302 214 0.85495143.2323901 215 0.6714335 4.0267706 215 0.84336593.1884594 216 0.6620077 3.9743072 216 0.83192323.1450648 217 0.6527053 3.9224456 217 0.82062413.1021947 218 0.6435235 3.8711704 218 0.80946473.0598409 219 0.6344602 3.8204807 219 0.79844443.0180025 220 0.625515 3.7703629 220 0.78755992.976671 221 0.6166858 3.7208175 221 0.7768108

2.9358406 222 0.607971 3.6718376 222 0.76619532.895502 223 0.5993683 3.6234115 223 0.7557104

2.8556601 224 0.5908786 3.5755396 224 0.74535582.8163002 225 0.5824985 3.5282107 225 0.73512882.7774167 226 0.5742264 3.4814222 226 0.72502852.739011 227 0.5660625 3.4351692 227 0.7150533

2.7010739 228 0.5580045 3.3894452 228 0.70520162.6635992 229 0.5500509 3.3442397 229 0.69547082.6265829 230 0.5422006 3.2995497 230 0.685862.5900213 231 0.5344525 3.2553743 231 0.67636852.5539077 232 0.5268052 3.2117031 232 0.66699382.5182358 233 0.5192569 3.1685321 233 0.65773492.4830038 234 0.5118071 3.1258585 234 0.64859072.448159 235 0.5044445 3.0836732 235 0.6395591

2.4137901 236 0.4971876 3.0419702 236 0.63063852.3799005 237 0.490037 3.0007465 237 0.62182792.3463781 238 0.4829686 2.9599983 238 0.61312632.3132704 239 0.4759925 2.9197194 239 0.60453212.280575 240 0.4691079 2.879906 240 0.5960442

2.2482859 241 0.4623133 2.8405518 241 0.58766112.2163984 242 0.4556077 2.8016506 242 0.57938112.1849106 243 0.4489904 2.763199 243 0.57120342.1538161 244 0.44246 2.725195 244 0.56312722.1231099 245 0.4360152 2.6876327 245 0.5551512.0927957 246 0.4296566 2.6505054 246 0.54727332.0628564 247 0.4233805 2.6138042 247 0.53949192.0333002 248 0.4171885 2.5775352 248 0.53180792.0041145 249 0.4110777 2.5416945 249 0.52422021.9752985 250 0.405048 2.5062652 250 0.51672511.9468541 251 0.3990995 2.4712508 251 0.50932321.9187671 252 0.3932291 2.4366499 252 0.50201381.8910431 253 0.3874379 2.4024508 253 0.49479451.8636698 254 0.3817231 2.3686592 254 0.48766611.8366527 255 0.3760858 2.3352607 255 0.48062561.809982 256 0.3705239 2.3022592 256 0.4736734

1.7836542 257 0.3650364 2.2696476 257 0.466808

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1.7576703 258 0.3596235 2.2374214 258 0.46002821.732025 259 0.3542839 2.2055764 259 0.453333

1.7067097 260 0.3490158 2.1741135 260 0.44672241.6817277 261 0.3438197 2.1430254 261 0.44019471.657077 262 0.338695 2.1123081 262 0.433749

1.6327495 263 0.3336401 2.0819574 263 0.42738411.608742 264 0.3286542 2.0519704 264 0.4210994

1.5850535 265 0.3237369 2.0223465 265 0.41489461.5616819 266 0.3188876 1.9930803 266 0.40876841.5386207 267 0.3141051 1.9641626 267 0.40271871.5158718 268 0.3093895 1.9356013 268 0.39674711.4934305 269 0.3047397 1.907387 269 0.39085151.4712873 270 0.3001539 1.8795146 270 0.38503061.4494494 271 0.2956332 1.851986 271 0.37928481.4279093 272 0.2911762 1.8247919 272 0.3736121.4066655 273 0.2867824 1.7979374 273 0.36801311.3857109 274 0.2824503 1.7714117 274 0.36248571.3650509 275 0.2781809 1.7452149 275 0.35702981.3446764 276 0.2739722 1.7193439 276 0.35164461.3245851 277 0.2698238 1.6937976 277 0.34632981.3047794 278 0.2657359 1.6685686 278 0.34108371.2852511 279 0.2617069 1.6436577 279 0.33590641.2660011 280 0.2577369 1.6190611 280 0.3307971.2470258 281 0.2538251 1.5947735 281 0.32575431.2283226 282 0.2499708 1.5707991 282 0.3207791.2098879 283 0.2461733 1.5471295 283 0.31586941.1917233 284 0.2424328 1.5237624 284 0.31102481.1737493 285 0.2387329 1.5006974 285 0.30624521.1561912 286 0.2351199 1.4779319 286 0.30152981.1388123 287 0.2315451 1.4554623 287 0.29687781.1216961 288 0.2280255 1.4332849 288 0.29228841.1048358 289 0.2245598 1.4113988 289 0.28776131.0882332 290 0.2211481 1.389803 290 0.28329621.0718814 291 0.2177892 1.3684912 291 0.27889171.0557794 292 0.2144826 1.347466 292 0.27454841.0399275 293 0.2112284 1.3267244 293 0.27026541.0243205 294 0.2080255 1.3062606 294 0.26604161.0089585 295 0.2048739 1.2860703 295 0.26187590.9938399 296 0.2017732 1.266161 296 0.25776990.9789608 297 0.1987225 1.2465177 297 0.25372030.9642991 298 0.1957173 1.2271492 298 0.2497290.9498974 299 0.1927663 1.2080511 299 0.2457950.9356031 300 0.1898381 1.1892762 300 0.2419290.9226395 301 0.1871832 1.1731522 301 0.238610.9089227 302 0.1843749 1.15479 302 0.23483170.8954409 303 0.1816154 1.1366652 303 0.23110350.8821524 304 0.1788962 1.1187776 304 0.22742550.8690759 305 0.1762211 1.1011297 305 0.22379810.8562115 306 0.17359 1.0837194 306 0.22022080.8435593 307 0.1710031 1.066543 307 0.21669280.8311177 308 0.1684598 1.0496051 308 0.2132150.8188825 309 0.1659594 1.0328976 309 0.20978560.8068597 310 0.163503 1.0164253 310 0.20640570.7950447 311 0.1610896 1.0001836 311 0.2030741

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0.7834365 312 0.158719 0.9841745 312 0.19979140.7720349 313 0.1563911 0.9683963 313 0.1965570.7608405 314 0.1541061 0.9528471 314 0.19337060.7498512 315 0.1518634 0.9375319 315 0.19023320.7390646 316 0.1496626 0.9224424 316 0.18714290.7284819 317 0.1475039 0.9075813 317 0.18410030.7180113 318 0.1453684 0.8929434 318 0.18110430.707835 319 0.1432935 0.8785366 319 0.1781564

0.6978609 320 0.1412601 0.8643553 320 0.17525550.6880877 321 0.1392681 0.8503976 321 0.17240120.6785143 322 0.1373172 0.8366622 322 0.16959310.6691389 323 0.1354071 0.823156 323 0.16683270.6599618 324 0.1335376 0.8098679 324 0.16411750.6509845 325 0.1317093 0.7968075 325 0.16144960.6422037 326 0.1299212 0.783965 326 0.15882690.6336207 327 0.1281738 0.7713443 327 0.15625020.6252308 328 0.1264659 0.7589454 328 0.15371930.6170377 329 0.1247984 0.7467654 329 0.15123380.6090404 330 0.123171 0.734808 330 0.14879430.601237 331 0.1215833 0.7230693 331 0.1463999

0.5936248 332 0.1200348 0.7115476 332 0.14405040.5862075 333 0.1185261 0.7002445 333 0.1417460.5789807 334 0.1170564 0.6891617 334 0.1394870.5719469 335 0.1156261 0.6782962 335 0.13727280.5651063 336 0.1142354 0.6676502 336 0.13510380.5584567 337 0.1128836 0.6572182 337 0.13297880.5519986 338 0.111571 0.6470053 338 0.13089890.5457314 339 0.1102973 0.6370063 339 0.1288630.5396575 340 0.109063 0.6272267 340 0.12687220.5337738 341 0.1078676 0.6176687 341 0.12492680.5280826 342 0.1067114 0.6083219 342 0.12302480.5225837 343 0.1055943 0.5991937 343 0.12116760.5172782 344 0.1045167 0.5902824 344 0.11935490.5121652 345 0.1034783 0.5815895 345 0.11758690.5072504 346 0.1024803 0.5731174 346 0.11586410.5025324 347 0.1015223 0.5648622 347 0.11418570.4980113 348 0.1006043 0.5567784 348 0.11254250.4936943 349 0.0997279 0.5489684 349 0.11095510.4896072 350 0.0988983 0.541478 350 0.1094330.4873565 351 0.0984414 0.5361174 351 0.10834370.4836891 352 0.097697 0.5289782 352 0.10689330.4802981 353 0.0970088 0.5221406 353 0.10550430.4771879 354 0.0963776 0.5155552 354 0.10416680.474354 355 0.0958025 0.5092667 355 0.1028897

0.4717814 356 0.0952805 0.5032868 356 0.10167540.4694532 357 0.094808 0.4976221 357 0.10052530.4673527 358 0.0943818 0.4922761 358 0.099440.4654595 359 0.0939977 0.4872528 359 0.09842030.4637565 360 0.0936522 0.4825507 360 0.0974665.2063245 -10 1.10397985.259391 -9 1.115857

5.3114545 -8 1.12752275.3625504 -7 1.1389845.4126879 -6 1.1502424

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5.4618128 -5 1.1612855.5099479 -4 1.17211625.5570695 -3 1.18273015.6032251 -2 1.19313665.6483627 -1 1.20332355.6924883 0 1.21329145.7357471 1 1.22307265.7780668 2 1.23265015.8195611 3 1.24204925.8602453 4 1.25127285.9002556 5 1.26035145.9396122 6 1.26928925.9783671 7 1.27809776.0166138 8 1.28679786.0544161 9 1.29540386.0917907 10 1.30391926.1288486 11 1.31236926.1655744 12 1.320756.2020957 13 1.32909066.2383911 14 1.33738616.2745596 15 1.3456596.3106347 16 1.35391696.3466621 17 1.36217026.382714 18 1.3704355

6.4187744 19 1.37870916.454964 20 1.38701886.491252 21 1.3953575

6.5277578 22 1.40375286.5644731 23 1.41220296.6014445 24 1.42071876.6387202 25 1.42931146.6763401 26 1.43799036.7143784 27 1.44677296.7528097 28 1.45565366.7917268 29 1.46465396.8311562 30 1.47378046.8711391 31 1.48304296.9117052 32 1.49244876.9529107 33 1.50201116.9947714 34 1.51173427.0373412 35 1.5216317.0806466 36 1.53170817.1247617 37 1.54198337.1696895 38 1.55245787.2154853 39 1.56314527.2621792 40 1.574053

7.30982 41 1.58519337.3584688 42 1.59658127.4081032 43 1.60821217.4588193 44 1.62010937.5106403 45 1.63227937.5636119 46 1.64473357.6177664 47 1.65748077.6731442 48 1.6705312

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7.7297718 49 1.68389257.7877353 50 1.69758597.8470264 51 1.71161097.9077186 52 1.72598597.9698613 53 1.74072428.0334698 54 1.75583078.0985766 55 1.77131478.1652789 56 1.78720098.2335545 57 1.80348588.3034981 58 1.82019368.3751128 59 1.83732718.4484828 60 1.85490838.523624 61 1.8729432

8.6005935 62 1.89144768.6794109 63 1.91042868.7601617 64 1.92990928.8428453 65 1.94989198.9275521 66 1.97040129.0142883 67 1.99144139.1031114 68 2.01302949.1940901 69 2.0351851

9.28723 70 2.05791329.3825996 71 2.08123379.4802341 72 2.1051599.5801728 73 2.12970259.6824833 74 2.15488479.7871736 75 2.18071189.8943218 76 2.207207410.003966 77 2.234385610.116161 78 2.262264610.230923 79 2.290853610.348289 80 2.320166910.468334 81 2.350229110.591075 82 2.381049710.716562 83 2.412647210.844839 84 2.445039510.975963 85 2.478247211.109955 86 2.512282311.246834 87 2.547156911.386671 88 2.582896611.529505 89 2.619518511.675355 90 2.657036111.824261 91 2.695467911.976279 92 2.73483712.13143 93 2.77515812.28972 94 2.8164418

12.451221 95 2.858716812.615957 96 2.901999512.783936 97 2.946302812.955236 98 2.99165813.129821 99 3.038067113.307733 100 3.085552813.489019 101 3.1341413.673708 102 3.1838493

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13.861812 103 3.234696614.053323 104 3.286693614.248309 105 3.339872714.446752 106 3.394243414.648668 107 3.449825314.854083 108 3.506640815.063018 109 3.564711915.275453 110 3.624049615.491407 111 3.684675715.710897 112 3.746612915.933944 113 3.809885116.160489 114 3.874494416.390596 115 3.940477716.624232 116 4.007845916.861413 117 4.076623617.102092 118 4.146817817.346311 119 4.218462117.594042 120 4.291570817.845272 121 4.366162418.099971 122 4.44225118.358156 123 4.519865618.619762 124 4.59901118.884826 125 4.679723119.153276 126 4.762005819.425131 127 4.845890919.700332 128 4.931386819.978867 129 5.018517320.260703 130 5.10730020.4519264 -10 0.09125240.4806449 -9 0.09707920.5110213 -8 0.1032460.5431477 -7 0.10977220.5771173 -6 0.11667750.6130228 -5 0.12398140.6509734 -4 0.1317070.6910706 -3 0.13987610.7334295 -2 0.1485130.7781672 -1 0.15764310.8253919 0 0.16728960.8754122 1 0.17751720.9282362 2 0.18832930.9840301 3 0.19976181.0429561 4 0.21185011.1051928 5 0.22463311.1709379 6 0.23815431.2403923 7 0.25245791.3137771 8 0.26759281.3913226 9 0.28361031.4732827 10 0.3005671.559924 11 0.318523

1.6515341 12 0.33754311.7484251 13 0.35769821.8509265 14 0.37906371.9594043 15 0.4017236

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2.0742437 16 0.42576712.1958718 17 0.45129352.3247444 18 0.47840972.4613605 19 0.50723342.6062706 20 0.53789532.7600841 21 0.57054122.9234257 22 0.60532263.0970331 23 0.64241853.2817258 24 0.68202933.4783761 25 0.72437123.6879826 26 0.76969323.9116284 27 0.81826894.1505645 28 0.8704164.4062085 29 0.92649834.680138 30 0.9869259

4.9741366 31 1.05216825.2903457 32 1.12279145.6311014 33 1.19942675.9992619 34 1.28284996.3980925 35 1.37396326.8314956 36 1.4738597.3041997 37 1.58387857.8219549 38 1.70567818.3918604 39 1.84133779.0229962 40 1.99355599.7271106 41 2.165886910.520027 42 2.363198911.424001 43 2.592456212.472133 44 2.864202213.717985 45 3.19579815.259683 46 3.619634317.321843 47 4.21126520.788282 48 5.275194137.410188 49 12.01421840.153234 50 13.486185

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0 5 10 15 20 25 30 350

50

100

150

200

250

300

350 Column B Column B

Column B Column B

Column B Column B

Bouaziz Column B

Column E Column B

Column B

w% LiBO2

t/C

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Page 252: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

Reburn, William T.; Gale, William A.The system lithium oxide – boric oxide – waterThe Journal of Physical Chemistry 1955, 59 (1), 19-24

wt% tLi2B4O7 C

2.2 02.55 102.81 203.01 303.26 403.76 604.35 805.17 100

Zhang, Ai-Yun; Yao, Yao; Li, Li-Juan; Song, Peng-ShengIsopiestic determination of the osmotic coefficients and Pitzer model representation for Li2B4O7(aq) at T=298.15 KThe Journal of Chemical Thermodynamics 2005, 37 (2), 101-109

wt% tLi2B4O7 C2.9095729 25

Sang, Shi-hua; Yin, Hui-an; Tang, Ming-lin; Lei, Ning-FeiSolubility investigations in the system K2B4O7 + Li2B4O7 + H2O and Na2B4O7 + Li2B4O7 + H2O at T=288 K

0 1 2 3 4 5 6-100

102030405060708090

100110120

Column B Zhang et al. 2005

Sang et al. 2004 Column B

Column B

w% Li2B4O7

t/C

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Journal of the Chemical Engineering Data 2004, 49 (6), 1586-1589

wt% tLi2B4O7 C

2.55 14.85

Menzel, HeinrichZur Kenntnis der Borsäuren und borsauren Alkalisalze. II. Die Alkaliborate in wäßriger LösungZeitschrift für anorganische und allgemeine Chemie 1927, 164 (1), 22-62

w% tLi2B4O7 C0.5315712 -0.2880.598456 -0.318

0.8867 -0.4351.4023349 -0.6161.7235244 -0.7211.9646721 -0.8022.3693392 -0.9282.669853 -1.023

3.1147896 -1.1613.3886447 -1.2393.8333051 -1.365

w% t mLi2B4O7 C Li2B4O72.1168147 -10 0.1278752.1295242 -9 0.12865952.143094 -8 0.1294973

2.1574951 -7 0.13038672.1726989 -6 0.1313259

2.18867 -5 0.13231282.2053886 -4 0.13334632.2228216 -3 0.13442442.240945 -2 0.1355455

2.2597324 -1 0.13670812.2791577 0 0.13791072.2991883 1 0.13915132.3197864 2 0.14042752.340915 3 0.1417372

2.3625212 4 0.14307712.3845836 5 0.14444582.4070565 6 0.14584072.4299187 7 0.14726042.4531357 8 0.14870282.4766821 9 0.15016642.5005347 10 0.15164972.5246731 11 0.15315152.5490784 12 0.15467072.5737284 13 0.15620592.5986066 14 0.1577561

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2.6236928 15 0.15932012.6489828 16 0.16089762.6744536 17 0.16248722.7000972 18 0.16408842.7258996 19 0.16570042.7518457 20 0.16732222.7779362 21 0.16895392.8041489 22 0.17059422.8304821 23 0.17224292.8569238 24 0.17389922.8834741 25 0.17556332.9101111 26 0.17723382.9368421 27 0.1789112.9636529 28 0.18059422.9905408 29 0.18228323.0175035 30 0.18397773.0445327 31 0.18567753.0716202 32 0.18738183.098767 33 0.1890908

3.1259651 34 0.19080413.1532215 35 0.19252193.1805209 36 0.19424353.2078661 37 0.19596893.2352556 38 0.1976983.2626834 39 0.19943063.2901553 40 0.20116693.3176562 41 0.20290613.3452016 42 0.20464913.3727803 43 0.20639513.4003927 44 0.20814433.4280382 45 0.20989663.4557217 46 0.21165243.4834403 47 0.21341133.5111972 48 0.21517373.5389823 49 0.21693893.566809 50 0.2187078

3.5946685 51 0.22047973.6225742 52 0.22225573.6505159 53 0.22403493.6785012 54 0.2258183.706532 55 0.227605

3.7346055 56 0.22939583.7627303 57 0.23119093.7909047 58 0.23299023.8191287 59 0.23479373.8474161 60 0.23660243.8757562 61 0.23841553.9041623 62 0.24023383.9326314 63 0.24205733.9611731 64 0.24388663.9897848 65 0.24572144.0184715 66 0.24756214.0472384 67 0.2494094.076087 68 0.2512624

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4.105023 69 0.25312244.134055 70 0.2549898

4.1631756 71 0.2568644.1923994 72 0.2587464.2217258 73 0.26063574.2511567 74 0.26253334.2807053 75 0.26443974.310373 76 0.266355

4.3401549 77 0.26827894.3700605 78 0.27021194.4000939 79 0.27215444.4302647 80 0.2741074.4605773 81 0.27607014.4910272 82 0.27804334.5216277 83 0.28002754.5523818 84 0.2820234.5832861 85 0.28402954.6143563 86 0.28604814.6455875 87 0.28807844.6769901 88 0.29012134.708569 89 0.292177

4.7403187 90 0.29424514.7722515 91 0.29632664.8043709 92 0.29842174.8366806 93 0.30053064.8691843 94 0.30265364.9018806 95 0.30479074.934787 96 0.3069434.967889 97 0.3091095

5.0011941 98 0.31129095.0347238 99 0.31348865.0684554 100 0.3157015.1024186 101 0.31793025.1365947 102 0.3201755.1709918 103 0.3224365.2056176 104 0.32471365.2404539 105 0.32700685.2755556 106 0.32931925.3108754 107 0.33164765.3464155 108 0.33399245.3822191 109 0.33635625.4182411 110 0.3387364

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Isopiestic determination of the osmotic coefficients and Pitzer model representation for Li2B4O7(aq) at T=298.15 K

Solubility investigations in the system K2B4O7 + Li2B4O7 + H2O and Na2B4O7 + Li2B4O7 + H2O at T=288 K

0 1 2 3 4 5 6-100

102030405060708090

100110120

Column B Zhang et al. 2005

Sang et al. 2004 Column B

Column B

w% Li2B4O7

t/C

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Reburn, William T.; Gale, William A.The system lithium oxide – boric oxide – waterThe Journal of Physical Chemistry 1955, 59 (1), 19-24

wt% tLiB5O8 C

19.27 4520.88 5024.34 6027.98 7031.79 80

Menzel, HeinrichZur Kenntnis der Borsäuren und borsauren Alkalisalze. II. Die Alkaliborate in wäßriger LösungZeitschrift für anorganische und allgemeine Chemie 1927, 164 (1), 22-62

w% tLiB5O8 C0.8525564 -0.3811.7053085 -0.6582.471666 -0.887

0 5 10 15 20 25 30 35 40-100

102030405060708090

100

Column B Column B Column B

w% LiB5O8

t/C

Page 258: support.olisystems.comsupport.olisystems.com/Documents/Validation Data Sets... · XLS file · Web view2010-02-11 · Zur Kenntnis der Borsäuren und borsauren Alkalisalze. I. Die

2.9884184 -1.0463.6946775 -1.2574.3682642 -1.4495.3213663 -1.7255.8905235 -1.877

w% t mLiB5O8 C LiB5O86.0791354 -10 0.34249136.2502675 -9 0.35277556.4242103 -8 0.36326716.6009266 -7 0.3739666.7804051 -6 0.38487376.9626309 -5 0.39599147.1475896 -4 0.40732057.3352245 -3 0.41885967.5255455 -2 0.43061197.718525 -1 0.4425778

7.9140994 0 0.45475578.112131 1 0.4671395

8.3127724 2 0.4797418.5160121 3 0.49256218.7218692 4 0.50560658.9303509 5 0.51887739.1414717 6 0.53237819.3552262 7 0.54611159.5715789 8 0.56007799.7906814 9 0.574290110.012365 10 0.588740110.236656 11 0.603432710.463679 12 0.618379310.693276 13 0.633572610.925571 14 0.649024211.160498 15 0.66473311.398092 16 0.680704911.638284 17 0.696938711.881172 18 0.713444712.126619 19 0.730217412.374812 20 0.747273212.625577 21 0.764604312.878963 22 0.782217813.134966 23 0.800117513.393593 24 0.818308213.654861 25 0.836795213.918681 26 0.855576714.185095 27 0.874660114.454076 28 0.89404814.725634 29 0.9137456

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14.999767 30 0.933757715.276478 31 0.954089315.555689 32 0.974739715.837404 33 0.995714116.121669 34 1.017021216.408425 35 1.038661816.697645 36 1.060639416.98941 37 1.0829654

17.283531 38 1.105631217.580172 39 1.12865517.879224 40 1.152034318.180662 41 1.175773118.484542 42 1.19988218.790787 43 1.224360919.099357 44 1.249213219.410296 45 1.274448819.723593 46 1.300073420.039185 47 1.326088920.357057 48 1.352500620.677254 49 1.379319620.999653 50 1.406542721.324366 51 1.434186621.651217 52 1.46224421.980346 53 1.490734522.311597 54 1.519652422.645049 55 1.549012522.980648 56 1.578818523.318339 57 1.609073523.658148 58 1.639788524.000017 59 1.670966924.344016 60 1.702623924.689998 61 1.734755225.038056 62 1.767378525.388128 63 1.800497525.740171 64 1.834118126.094155 65 1.868246826.450122 66 1.90289826.808033 67 1.938078327.167844 68 1.973793927.529573 69 2.010057427.893196 70 2.046877328.258643 71 2.084258128.625985 72 2.122218528.995145 73 2.160762529.366117 74 2.199901529.738906 75 2.239648630.113482 76 2.280013230.489801 77 2.321003830.867943 78 2.362642431.247796 79 2.404930731.62944 80 2.4478915

32.012814 81 2.491532632.397923 82 2.535869632.784759 83 2.5809169

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33.173292 84 2.626686833.563603 85 2.673205233.955606 86 2.720478634.349326 87 2.768527434.744786 88 2.817372235.141975 89 2.8670335.540942 90 2.917526335.941566 91 2.968865236.343981 92 3.021084136.748222 93 3.074208937.15418 94 3.1282472

37.562025 95 3.183244437.971717 96 3.239218738.383228 97 3.296190838.796681 98 3.354203439.212062 99 3.413281139.629388 100 3.473454240.048809 101 3.534773540.470287 102 3.597263940.893923 103 3.660972241.319753 104 3.725937641.747824 105 3.792202142.178266 106 3.859823142.611157 107 3.928851943.046564 108 3.999340343.484613 109 4.071352443.925427 110 4.144954844.369073 111 4.22020844.81569 112 4.297187

45.265513 113 4.375988745.718583 114 4.456679346.175133 115 4.539363746.635264 116 4.624128147.099211 117 4.711088747.567237 118 4.800372948.039534 119 4.892102448.516275 120 4.986401948.997763 121 5.083429749.484305 122 5.183354849.975942 123 5.286300750.473098 124 5.392480650.976149 125 5.502111651.485317 126 5.615390952.000755 127 5.732512852.522647 128 5.853692453.051411 129 5.979215153.587195 130 6.1093219

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0 5 10 15 20 25 30 35 40-100

102030405060708090

100

Column B Column B Column B

w% LiB5O8

t/C

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t/C m Na2O.5B2O3wt% Na2O.5B2O3g Na2O.5B2O3/100gW solid35 0.4584576412 15.824915824916 18.8 Na2O.5B2O3.10H2O

-1.7 0.1419293609 5.5 Na2O.5B2O3.10H2O + ice0 0.1493234407 5.77 Na2O.5B2O3.10H2O5 0.1765209673 6.75 Na2O.5B2O3.10H2O

10 0.2091745423 7.9 Na2O.5B2O3.10H2O15 0.2500443397 9.3 Na2O.5B2O3.10H2O20 0.2876162907 10.55 Na2O.5B2O3.10H2O30 0.3877799419 13.72 Na2O.5B2O3.10H2O40 0.517279737 17.5 Na2O.5B2O3.10H2O50 0.6766286304 21.72 Na2O.5B2O3.10H2O60 0.8964672904 26.88 Na2O.5B2O3.10H2O80 1.5009827218 38.1 Na2O.5B2O3.10H2O85 1.7016408132 41.1 Na2O.5B2O3.10H2O90 1.9395005066 44.3 Na2O.5B2O3.10H2O95 2.2152208585 47.6 Na2O.5B2O3.10H2O

100 2.538139351 51 Na2O.5B2O3.10H2O105 2.944628361 54.7 Na2O.5B2O3.10H2O107 3.1417261307 56.3 Na2O.5B2O3.10H2O

-0.53 0.0336222839 1.36 ice-0.91 0.0671543361 2.68 ice-1.24 0.1000218783 3.94 ice-1.7 0.1501476216 5.8 ice + Na2O.5B2O3.10H2O-1.7 0.1501476216 5.8 Na2O.5B2O3.10H2O + ice

0 0.1556556048 6 Na2O.5B2O3.10H2O13.5 0.2294529374 8.6 Na2O.5B2O3.10H2O20 0.2921956089 10.7 Na2O.5B2O3.10H2O35 0.4610441277 15.9 Na2O.5B2O3.10H2O50 0.7161231768 22.7 Na2O.5B2O3.10H2O

59.6 0.9226697839 27.45 Na2O.5B2O3.10H2O70.8 1.2395319878 33.7 Na2O.5B2O3.10H2O80 1.5460433596 38.8 Na2O.5B2O3.10H2O85 1.7586493542 41.9 Na2O.5B2O3.10H2O90 2.0358991484 45.5 Na2O.5B2O3.10H2O93 2.1887284941 47.3 Na2O.5B2O3.10H2O96 2.3429729264 49 Na2O.5B2O3.10H2O99 2.5280034165 50.9 Na2O.5B2O3.10H2O

100 2.6207409082 51.8 Na2O.5B2O3.10H2O + Na2O.5B2O3.2H2O102 2.8057062233 53.5 Na2O.5B2O3.10H2O (m)

104.5 3.0414055805 55.5 Na2O.5B2O3.10H2O (m)100 2.6207409082 51.8 Na2O.5B2O3.2H2O + Na2O.5B2O3.10H2O103 2.7170075223 52.7 Na2O.5B2O3.2H2O107 2.8975103493 54.3 Na2O.5B2O3.2H2O

107.5 2.9209657991 54.5 Na2O.5B2O3.2H2O108.3 2.9565381681 54.8 Na2O.5B2O3.2H2O109 2.9805165799 55 Na2O.5B2O3.2H2O

109.6 3.0168865198 55.3 boiling point Na2O.5B2O3.2H2O0 0.1634062751 6.28 Na2O.5B2O3.10H2O5 0.1863734313 7.1 Na2O.5B2O3.10H2O

10 0.214936847 8.1 Na2O.5B2O3.10H2O15 0.2500443397 9.3 Na2O.5B2O3.10H2O20 0.2876162907 10.55 Na2O.5B2O3.10H2O25 0.3388493689 12.2 Na2O.5B2O3.10H2O30 0.3887630322 13.75 Na2O.5B2O3.10H2O

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35 0.4507373199 15.6 Na2O.5B2O3.10H2O40 0.5137011847 17.4 Na2O.5B2O3.10H2O45 0.5956178404 19.63 Na2O.5B2O3.10H2O50 0.6798155696 21.8 Na2O.5B2O3.10H2O55 0.7828017005 24.3 Na2O.5B2O3.10H2O60 0.8973797587 26.9 Na2O.5B2O3.10H2O65 1.0130649869 29.35 Na2O.5B2O3.10H2O70 1.160811724 32.25 Na2O.5B2O3.10H2O75 1.3119407031 34.98 Na2O.5B2O3.10H2O80 1.4845043969 37.84 Na2O.5B2O3.10H2O85 1.6785734328 40.77 Na2O.5B2O3.10H2O90 1.9005493947 43.8 Na2O.5B2O3.10H2O95 2.2465145927 47.95 Na2O.5B2O3.10H2O

100 2.4680443675 50.3 Na2O.5B2O3.10H2O

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ref PT. TT1929T 4 103

1967NH 3 1021967NH 2 1011967NH 1 1001967NH 2 1001967NH 1 1001967NH 3 951967NH 4 901967NH 5 851967NH 6 801967NH 7 751967NH 8 701967NH 9 651967NH 10 601967NH 11 551967NH 12 501967NH 13 451967NH 14 40

Linke and Seidell (1935RP) 15 35Linke and Seidell (1935RP) 16 30Linke and Seidell (1935RP) 17 25Linke and Seidell (1935RP)Linke and Seidell (1935RP) 1 99.9074Linke and Seidell (1935RP) 2 100.136Linke and Seidell (1935RP) 3 101.199Linke and Seidell (1935RP) 4 102.144Linke and Seidell (1935RP) 5 102.982Linke and Seidell (1935RP) 6 103.381Linke and Seidell (1935RP) 7 103.381Linke and Seidell (1935RP) 8 103.381Linke and Seidell (1935RP) 9 103.381Linke and Seidell (1935RP) 10 103.381Linke and Seidell (1935RP) 11 103.381Linke and Seidell (1935RP)Linke and Seidell (1935RP) 7 56Linke and Seidell (1935RP) 6 55Linke and Seidell (1935RP) 5 54Linke and Seidell (1935RP) 4 53Linke and Seidell (1935RP) 3 52Linke and Seidell (1935RP) 2 51Linke and Seidell (1935RP) 1 50Linke and Seidell (1935RP) 8 50Linke and Seidell (1935RP) 9 45Linke and Seidell (1935RP) 10 40Linke and Seidell (1935RP) 11 35Linke and Seidell (1935RP) 12 30Linke and Seidell (1939BS) 13 25Linke and Seidell (1939BS) 14 20Linke and Seidell (1939BS) 15 15Linke and Seidell (1939BS) 16 9.99999Linke and Seidell (1939BS) 17 4.99999Linke and Seidell (1939BS) 18 -6.1E-06Linke and Seidell (1939BS) 19 -1.00001

-20 0 20 40 60 80 100 1200.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

1967NH1935RP1939BSNA2B10O.10H2OBOH3PPTICE

T/C

m-N

a2O

.5B

2O3

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Linke and Seidell (1939BS) 20 -1.10001Linke and Seidell (1939BS) 21 -1.19999Linke and Seidell (1939BS) 22 -1.29999Linke and Seidell (1939BS) 23 -1.4Linke and Seidell (1939BS)Linke and Seidell (1939BS) 1 -0.100012Linke and Seidell (1939BS) 2 -0.199988Linke and Seidell (1939BS) 3 -0.4Linke and Seidell (1939BS) 4 -0.600012Linke and Seidell (1939BS) 5 -0.799994Linke and Seidell (1939BS) 6 -1.00001Linke and Seidell (1939BS) 7 -1.19999Linke and Seidell (1939BS) 8 -1.4Linke and Seidell (1939BS)

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NA2B10O16IN solid2.70229 NA2B10O.10H2O

2.584 NA2B10O.10H2O2.48036 NA2B10O.10H2O2.38806 NA2B10O.10H2O2.38807 NA2B10O.10H2O2.38806 NA2B10O.10H2O2.03203 NA2B10O.10H2O1.77273 NA2B10O.10H2O1.56434 NA2B10O.10H2O1.38807 NA2B10O.10H2O1.23446 NA2B10O.10H2O1.09815 NA2B10O.10H2O0.975875 NA2B10O.10H2O0.865504 NA2B10O.10H2O0.770573 NA2B10O.10H2O0.693593 NA2B10O.10H2O0.622737 NA2B10O.10H2O0.557441 NA2B10O.10H2O0.497299 NA2B10O.10H2O0.442004 NA2B10O.10H2O0.391321 NA2B10O.10H2O

2.38 NA2B10O.10H2O2.4 NA2B10O.10H2O2.5 NA2B10O.10H2O2.6 NA2B10O.10H2O2.7 NA2B10O.10H2O2.8 NA2B10O.10H2O2.9 NA2B10O.10H2O3 NA2B10O.10H2O

3.1 NA2B10O.10H2O3.2 NA2B10O.10H2O3.3 NA2B10O.10H2O

0.78009 BOH3PPT0.754082 BOH3PPT0.729065 BOH3PPT0.704988 BOH3PPT0.681799 BOH3PPT0.659455 BOH3PPT0.637912 BOH3PPT0.637912 BOH3PPT0.540956 BOH3PPT0.459208 BOH3PPT0.389769 BOH3PPT0.33046 BOH3PPT0.279596 BOH3PPT0.235839 BOH3PPT0.198109 BOH3PPT0.165524 BOH3PPT0.137351 BOH3PPT0.112836 BOH3PPT0.107602 BOH3PPT

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0.107092 BOH3PPT0.106585 BOH3PPT0.10608 BOH3PPT0.105577 BOH3PPT

0.004144833 ICE0.00990859 ICE0.02362776 ICE0.0383922 ICE0.05358098 ICE0.06911101 ICE0.0849986 ICE0.101417 ICE

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t/C m-Na2B4O7wt% Na2B4O7gNa2B4O7/100gW solid20 0.12424465 2.4390243902 2.5 Na2B4O7.10H2O

23.5 0.1441238 2.8182701652 2.9 Na2B4O7.10H2O28.5 0.18388209 3.5679845709 3.7 Na2B4O7.10H2O35 0.26339867 5.0332383666 5.3 Na2B4O7.10H2O

-0.42 0.05172153 1.03 Na2B4O7.10H2O0 0.05273649 1.05 Na2B4O7.10H2O5 0.06545818 1.3 Na2B4O7.10H2O10 0.08234982 1.63 Na2B4O7.10H2O15 0.10142421 2 Na2B4O7.10H2O20 0.12638505 2.48 Na2B4O7.10H2O25 0.15687586 3.06 Na2B4O7.10H2O30 0.19631172 3.8 Na2B4O7.10H2O35 0.24838495 4.76 Na2B4O7.10H2O40 0.31272464 5.92 Na2B4O7.10H2O45 0.40295564 7.5 Na2B4O7.10H2O50 0.51865797 9.45 Na2B4O7.10H2O55 0.69378781 12.25 Na2B4O7.10H2O60 0.94662594 16 Na2B4O7.10H2O

60.8 0.99276473 16.65 Na2B4O7.10H2O + Na2B4O7.5H2O (m)60 0.9713808 16.35 Na2B4O7.5H2O (m)65 1.0820723 17.88 Na2B4O7.5H2O (m)70 1.20309443 19.49 Na2B4O7.5H2O (m)75 1.33704908 21.2 Na2B4O7.5H2O (m)80 1.51649179 23.38 Na2B4O7.5H2O (m)85 1.71003396 25.6 Na2B4O7.5H2O (m)90 1.93845149 28.06 Na2B4O7.5H2O (m)95 2.24325617 31.1 Na2B4O7.5H2O (m)100 2.63276267 34.63 Na2B4O7.5H2O (m)

102.8 2.88509952 36.73 Na2B4O7.5H2O (m)58 0.82250541 14.2 Na2B4O7.10H2O + Na2B4O7.4H2O60 0.85440951 14.67 Na2B4O7.4H2O65 0.93327378 15.81 Na2B4O7.4H2O70 1.01935118 17.02 Na2B4O7.4H2O75 1.11392808 18.31 Na2B4O7.4H2O80 1.22077957 19.72 Na2B4O7.4H2O85 1.34345846 21.28 Na2B4O7.4H2O90 1.48113046 22.96 Na2B4O7.4H2O95 1.65218075 24.95 Na2B4O7.4H2O100 1.85965752 27.23 Na2B4O7.4H2O0 0.05934373 1.18 Na2B4O7.10H2O5 0.07261051 1.44 Na2B4O7.10H2O10 0.08903526 1.76 Na2B4O7.10H2O15 0.10764147 2.12 Na2B4O7.10H2O20 0.13161618 2.58 Na2B4O7.10H2O25 0.16058048 3.13 Na2B4O7.10H2O30 0.1989982 3.85 Na2B4O7.10H2O35 0.24838495 4.76 Na2B4O7.10H2O40 0.31722039 6 Na2B4O7.10H2O45 0.40760635 7.58 Na2B4O7.10H2O50 0.5247259 9.55 Na2B4O7.10H2O55 0.69378781 12.25 Na2B4O7.10H2O

58.5 0.84418923 14.52 Na2B4O7.10H2O + Na2B4O7.4H2O60 0.86466578 14.82 Na2B4O7.4H2O

-20 0 20 40 60 80 100 1200.01

0.1

1

10 NA2B4O7.10H2O1929T&1967NH1939BSNA2B4O7.4H2O1967NH1939BSNA4B102O.7H2O

T/C

m-N

a2B

4O7

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65 0.93818598 15.88 Na2B4O7.4H2O70 1.02657746 17.12 Na2B4O7.4H2O75 1.12138453 18.41 Na2B4O7.4H2O80 1.23314215 19.88 Na2B4O7.4H2O85 1.35953906 21.48 Na2B4O7.4H2O90 1.51057134 23.31 Na2B4O7.4H2O95 1.70554784 25.55 Na2B4O7.4H2O100 1.95385018 28.22 Na2B4O7.4H2O60.8 0.99276473 16.65 Na2B4O7.10H2O + Na2B4O7.5H2O (metastable)35 0.67705643 11.99 Na2B4O7.5H2O (metastable)45 0.73474341 12.88 Na2B4O7.5H2O (metastable)55 0.88046241 15.05 Na2B4O7.5H2O (metastable)65 1.0820723 17.88 Na2B4O7.5H2O (metastable)70 1.20309443 19.49 Na2B4O7.5H2O (metastable)75 1.34506284 21.3 Na2B4O7.5H2O (metastable)80 1.51649179 23.38 Na2B4O7.5H2O (metastable)85 1.72172611 25.73 Na2B4O7.5H2O (metastable)90 1.96834893 28.37 Na2B4O7.5H2O (metastable)95 2.26214947 31.28 Na2B4O7.5H2O (metastable)100 2.63276267 34.63 Na2B4O7.5H2O (metastable)

102.8 2.88509952 36.73 Na2B4O7.5H2O (metastable)108 3.04599798 38116 3.74913695 43121 4.58749494 48125 5.55942183 52.8126 5.81066107 53.9130 6.58785611 57132 7.45467928 60135 8.49846906 63.1137 9.64723201 66140 11.1136643 69.1t/C m-Na2B2O7 ref solid199 4.81325749 1990UV Na2B2O7.2H2O199 4.91050444 1990UV Na2B2O7.2H2O201 4.75582279 1990UV Na2B2O7.2H2O210 5.09050974 1990UV Na2B2O7.2H2O240 6.12348655 1990UV Na2B2O7.2H2O249 6.27407396 1990UV Na2B2O7.2H2O290 7.51711378 1990UV Na2B2O7.2H2O299 7.48581829 1990UV Na2B2O7.2H2O302 7.54856693 1990UV Na2B2O7.2H2O300 7.33166477 1990UV Na2B2O7.2H2O

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ref PT. TT NA2B4O7IN solid1929T 5 -0.4 0.0559767 NA2B4O7.10H2O1929T 4 -0.299994 0.0562199 NA2B4O7.10H2O1929T 3 -0.199988 0.0564641 NA2B4O7.10H2O1929T 2 -0.100012 0.0567098 NA2B4O7.10H2O

1967NH 1 -6.1E-06 0.0569549 NA2B4O7.10H2O1967NH 6 4.99999 0.0707184 NA2B4O7.10H2O1967NH 7 9.99999 0.087761 NA2B4O7.10H2O1967NH 8 15 0.108958 NA2B4O7.10H2O1967NH 9 20 0.135452 NA2B4O7.10H2O1967NH 10 25 0.168731 NA2B4O7.10H2O1967NH 11 30 0.21071 NA2B4O7.10H2O1967NH 12 35 0.263809 NA2B4O7.10H2O1967NH 13 40 0.330974 NA2B4O7.10H2O1967NH 14 45 0.41564 NA2B4O7.10H2O1967NH 15 50 0.52171 NA2B4O7.10H2O1967NH 16 55 0.653818 NA2B4O7.10H2O1967NH 17 60 0.818214 NA2B4O7.10H2O1967NH 18 61 0.855731 NA2B4O7.10H2O1967NH 19 62 0.895011 NA2B4O7.10H2O1967NH1967NH 4 62.7 0.922028 NA2B4O7.4H2O1967NH 3 62.8 0.924022 NA2B4O7.4H2O1967NH 2 62.9 0.926019 NA2B4O7.4H2O1967NH 1 63 0.928019 NA2B4O7.4H2O1967NH 5 64 0.948187 NA2B4O7.4H2O1967NH 6 65 0.968666 NA2B4O7.4H2O1967NH 7 70 1.07599 NA2B4O7.4H2O1967NH 8 75 1.19231 NA2B4O7.4H2O1967NH 9 80 1.31901 NA2B4O7.4H2O1967NH 10 81 1.34574 NA2B4O7.4H2O1967NH 11 82 1.37298 NA2B4O7.4H2O1967NH 12 83 1.43557 NA2B4O7.4H2O1967NH 13 84 1.5091 NA2B4O7.4H2O1967NH 14 85 1.58519 NA2B4O7.4H2O1967NH 15 90 2.00756 NA2B4O7.4H2O1967NH 16 95 2.50992 NA2B4O7.4H2O1967NH1967NH1967NH 1 82.5 1.3822 NA4B102O.7H2O

Linke and Seidell (1939BS) 2 85 1.41357 NA4B102O.7H2OLinke and Seidell (1939BS) 3 90 1.47795 NA4B102O.7H2OLinke and Seidell (1939BS) 4 95 1.54497 NA4B102O.7H2OLinke and Seidell (1939BS) 5 96 1.55875 NA4B102O.7H2OLinke and Seidell (1939BS)Linke and Seidell (1939BS) 1 96 1.53893 NA4B10O.5H2OLinke and Seidell (1939BS) 2 97 1.50852 NA4B10O.5H2OLinke and Seidell (1939BS) 3 98 1.47922 NA4B10O.5H2OLinke and Seidell (1939BS) 4 99 1.45099 NA4B10O.5H2OLinke and Seidell (1939BS) 5 100 1.42377 NA4B10O.5H2OLinke and Seidell (1939BS) 6 105 1.30122 NA4B10O.5H2OLinke and Seidell (1939BS) 7 110 1.19768 NA4B10O.5H2OLinke and Seidell (1939BS) 8 115 1.10922 NA4B10O.5H2OLinke and Seidell (1939BS) 9 120 1.03284 NA4B10O.5H2O

-20 0 20 40 60 80 100 1200.01

0.1

1

10 NA2B4O7.10H2O1929T&1967NH1939BSNA2B4O7.4H2O1967NH1939BSNA4B102O.7H2O

T/C

m-N

a2B

4O7

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Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)

Linke and SeidellLinke and SeidellLinke and Seidell

Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)Linke and Seidell (1939BS)

1942B1942B1942B1942B1942B1942B1942B1942B1942B1942B

wt% Na2B2O749.249.748.950.655.255.860.260.160.359.6

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t/C m NaBO2wt% NaBO2gNa2B2O4/100gW solid ref20 3.91345 20.4771372 25.75 NaBO2.4H2O 1929T35 5.42563 26.3080324 35.7 NaBO2.4H2O 1929T

-5.77 2.29104 13.1 NaBO2.4H2O 1967NH0 2.57741 14.5 NaBO2.4H2O 1967NH5 2.83044 15.7 NaBO2.4H2O 1967NH

10 3.11281 17 NaBO2.4H2O 1967NH15 3.44982 18.5 NaBO2.4H2O 1967NH20 3.79946 20 NaBO2.4H2O 1967NH25 4.18716 21.6 NaBO2.4H2O 1967NH30 4.69462 23.6 NaBO2.4H2O 1967NH35 5.22937 25.6 NaBO2.4H2O 1967NH40 5.881 27.9 NaBO2.4H2O 1967NH45 6.76436 30.8 NaBO2.4H2O 1967NH50 7.86414 34.1 NaBO2.4H2O 1967NH

53.6 8.88749 36.9 NaBO2.4H2O + NaBO2.2H2O 1967NH55 9.00255 37.2 NaBO2.2H2O 1967NH60 9.43399 38.3 NaBO2.2H2O 1967NH65 9.92256 39.5 NaBO2.2H2O 1967NH70 10.5176 40.9 NaBO2.2H2O 1967NH75 11.096 42.2 NaBO2.2H2O 1967NH80 11.7966 43.7 NaBO2.2H2O 1967NH85 12.637 45.4 NaBO2.2H2O 1967NH90 13.6954 47.4 NaBO2.2H2O 1967NH95 14.9566 49.6 NaBO2.2H2O 1967NH

100 16.7304 52.4 NaBO2.2H2O 1967NH105 19.3427 56 NaBO2.2H2O + NaBO2.0.5H2O 1967NH110 19.1864 55.8 NaBO2.0.5H2O 1967NH115 18.9546 55.5 NaBO2.0.5H2O 1967NH

120.2 18.8018 55.3 NaBO2.0.5H2O 1967NH0 2.49464 14.1 NaBO2.4H2O Linke and Seidell (1939BS)5 2.83044 15.7 NaBO2.4H2O Linke and Seidell (1939BS)

10 3.16369 17.23 NaBO2.4H2O Linke and Seidell (1939BS)15 3.44982 18.5 NaBO2.4H2O Linke and Seidell (1939BS)20 3.85185 20.22 NaBO2.4H2O Linke and Seidell (1939BS)20 3.91413 20.48 NaBO2.4H2O Linke and Seidell25 4.28657 22 NaBO2.4H2O Linke and Seidell (1939BS)30 4.77304 23.9 NaBO2.4H2O Linke and Seidell (1939BS)35 5.40102 26.22 NaBO2.4H2O Linke and Seidell (1939BS)35 5.42338 26.3 NaBO2.4H2O Linke and Seidell40 6.13246 28.75 NaBO2.4H2O Linke and Seidell (1939BS)45 7.08965 31.81 NaBO2.4H2O Linke and Seidell (1939BS)50 8.19065 35.02 NaBO2.4H2O Linke and Seidell (1939BS)54 9.25565 37.85 NaBO2.4H2O + NaBO2.2H2OLinke and Seidell (1939BS)55 9.36234 38.12 NaBO2.2H2O Linke and Seidell (1939BS)60 9.71666 39 NaBO2.2H2O Linke and Seidell (1939BS)65 10.2805 40.35 NaBO2.2H2O Linke and Seidell (1939BS)70 10.9602 41.9 NaBO2.2H2O Linke and Seidell (1939BS)75 11.8446 43.8 NaBO2.2H2O Linke and Seidell (1939BS)80 12.8425 45.8 NaBO2.2H2O Linke and Seidell (1939BS)85 14.0851 48.1 NaBO2.2H2O Linke and Seidell (1939BS)90 15.4121 50.35 NaBO2.2H2O Linke and Seidell (1939BS)95 17.001 52.8 NaBO2.2H2O Linke and Seidell (1939BS)

100 19.0315 55.6 NaBO2.2H2O Linke and Seidell (1939BS)

-20 0 20 40 60 80 100 120 1400

5

10

15

20

25

Na2B2O4.8H2O

NA2B2O4.4H2O

NA2B2O4.1H2O

T/C

m-N

aBO

2

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PT. TT NABO2IN SOLID1 54.5 9.25451 Na2B2O4.8H2O2 54 9.10251 Na2B2O4.8H2O3 53 8.81529 Na2B2O4.8H2O4 52 8.54753 Na2B2O4.8H2O5 51 8.2965 Na2B2O4.8H2O6 50 8.06005 Na2B2O4.8H2O7 45 7.04632 Na2B2O4.8H2O8 40 6.23245 Na2B2O4.8H2O9 35 5.55378 Na2B2O4.8H2O10 30 4.97316 Na2B2O4.8H2O11 25 4.46645 Na2B2O4.8H2O12 20 4.01651 Na2B2O4.8H2O13 15 3.61027 Na2B2O4.8H2O14 9.99999 3.23702 Na2B2O4.8H2O15 4.99999 2.88721 Na2B2O4.8H2O16 -6.1E-06 2.54949 Na2B2O4.8H2O17 -3.00001 2.35257 Na2B2O4.8H2O18 -4.00001 2.28747 Na2B2O4.8H2O19 -4.10001 2.28098 Na2B2O4.8H2O20 -4.19999 2.27449 Na2B2O4.8H2O21 -4.29999 2.268 Na2B2O4.8H2O22 -4.4 2.26151 Na2B2O4.8H2O23 -4.50001 2.25502 Na2B2O4.8H2O24 -4.60001 2.24854 Na2B2O4.8H2O25 -4.69999 2.24206 Na2B2O4.8H2O26 -4.79999 2.23558 Na2B2O4.8H2O27 -4.9 2.22911 Na2B2O4.8H2O

1 54.6 9.26509 NA2B2O4.4H2O2 55 9.29824 NA2B2O4.4H2O3 60 9.74112 NA2B2O4.4H2O4 65 10.2391 NA2B2O4.4H2O5 70 10.7958 NA2B2O4.4H2O6 75 11.4146 NA2B2O4.4H2O7 80 12.0988 NA2B2O4.4H2O8 85 12.8512 NA2B2O4.4H2O9 90 13.6735 NA2B2O4.4H2O10 95 14.5669 NA2B2O4.4H2O11 100 15.5309 NA2B2O4.4H2O12 105 16.5639 NA2B2O4.4H2O13 106 16.7786 NA2B2O4.4H2O14 107 16.996 NA2B2O4.4H2O15 108 17.2161 NA2B2O4.4H2O16 109 17.4388 NA2B2O4.4H2O17 110 17.6643 NA2B2O4.4H2O18 111 17.8926 NA2B2O4.4H2O19 112 18.1235 NA2B2O4.4H2O20 113 18.3573 NA2B2O4.4H2O21 114 18.594 NA2B2O4.4H2O22 115 18.8335 NA2B2O4.4H2O23 115.1 18.8576 NA2B2O4.4H2O24 115.2 18.8818 NA2B2O4.4H2O25 115.3 18.9059 NA2B2O4.4H2O

-20 0 20 40 60 80 100 120 1400

5

10

15

20

25

Na2B2O4.8H2O

NA2B2O4.4H2O

NA2B2O4.1H2O

T/C

m-N

aBO

2

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26 115.4 18.9302 NA2B2O4.4H2O27 115.5 18.9544 NA2B2O4.4H2O

20 115.6 18.9778 NA2B2O4.1H2O19 115.7 18.9704 NA2B2O4.1H2O18 115.8 18.9628 NA2B2O4.1H2O17 115.9 18.9553 NA2B2O4.1H2O1 116 18.9477 NA2B2O4.1H2O16 116 18.9477 NA2B2O4.1H2O2 117 18.8686 NA2B2O4.1H2O3 118 18.7839 NA2B2O4.1H2O4 119 18.6933 NA2B2O4.1H2O5 120 18.5973 NA2B2O4.1H2O6 121 18.4968 NA2B2O4.1H2O7 122 18.3945 NA2B2O4.1H2O8 123 18.2947 NA2B2O4.1H2O9 124 18.2038 NA2B2O4.1H2O10 125 18.1294 NA2B2O4.1H2O11 126 18.0802 NA2B2O4.1H2O12 127 18.0644 NA2B2O4.1H2O13 128 18.0898 NA2B2O4.1H2O14 129 18.1636 NA2B2O4.1H2O15 130 18.2934 NA2B2O4.1H2O

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Na2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2ONa2B2O4.8H2O

NA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2O

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NA2B2O4.4H2ONA2B2O4.4H2O

NA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2ONA2B2O4.1H2O

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NaNH4+H2O

H2O+NaOH+NaBH4

Banus et al.(1954)

0 10 20 30 40 50-40

-30

-20

-10

0

10

20

30

40

50

60 Banus 1954James and Wallbridge 1970Jensen 1954Merck Index 1989Mikheeva and Breitzis 1960Mikheeva and Breitzis 1960aSaldin et al. 1983Stockmayer et al. 1955Column AColumn AColumn A

w% NaBH4

t/C

0 10 20 30 40 50 600

5

10

15

20

25

30

35

40

45 Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C

w% NaOH

w%

NaB

H4

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Proprietary data: Rohm and Haas, Report by , Table III

t w% w% m mC NaOH NaBH4 NaOH NaBH4

-24.5 0.3174714 20.632149 0.1004089 6.8989434 10.6335465 0.279084 30.228988 0.1004089 11.498239 15.393578

10 0.2746936 31.326605 0.1004089 12.106192 15.93799620 0.2616301 34.592472 0.1004089 14.035781 17.55786625 0.2538574 36.535659 0.1004089 15.27812 18.52168730 0.2460799 38.480013 0.1004089 16.599757 19.48608740 0.2232367 44.190823 0.1004089 21.014023 22.318648

t w% w% m mC NaOH NaBH4 NaOH NaBH4

25 58.5 0 35.243519 0 58.525 48.8 5.6 26.756326 3.2461252 51.625 46.4 11.9 27.819763 7.5431542 52.3525 48.3 12.1 30.494635 8.0766686 54.3525 43.1 14.7 25.535027 9.2076109 50.4525 36.2 16.5 19.13458 9.220721 44.4525 26.4 21.5 12.668865 10.907942 37.1525 20.8 25.3 9.6481949 12.407201 33.4525 14.1 30.8 6.397923 14.775466 29.525 9.7 31.9 4.1526983 14.438428 25.6525 5.2 31.8 2.0636417 13.342237 21.1

James, B. D.; Wallbridge, M. G. H.Metal TetrahydroboratesProgress in Inorganic Chemistry, Vol. 11, p. 99-231John Wiley & Sons Inc. 1970

t w% w% m mC NaOH NaBH4 NaOH NaBH4

0 0 20 0 6.6081834 1025 2.5155455 34.591258 1 14.538003 19.81117460 4.0709637 45.038301 2 23.392969 26.590114

Jensen, E. H.A study on sodium borohydrideCopenhagen 1954

t w% w% m mC NaOH NaBH4 NaOH NaBH4

1.00054 0.2846206 28.555078 0.1 10.60688 NaBH4.2H2O 14.562163.14241 0.2831765 28.917577 0.1 10.79631 NaBH4.2H2O 14.7419656.60161 0.2800933 29.691494 0.1 11.20727 NaBH4.2H2O 15.125849.45035 0.2772316 30.409856 0.1 11.59691 NaBH4.2H2O 15.482159

11.46 0.2750134 30.966661 0.1 11.9045 NaBH4.2H2O 15.75834414.17 0.2716191 31.818684 0.1 12.3849 NaBH4.2H2O 16.180961

21.5 0.2595037 34.859857 0.1 14.2021 NaBH4.2H2O 17.68943230.37 0.2394901 39.88365 0.1 17.6067 NaBH4.2H2O 20.18131535.53 0.2223882 44.176523 0.1 21.0015 NaBH4.2H2O 22.31065

36.4 0.217404 45.427648 0.1 22.0914 NaBH4.2H2O 22.931228

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36.4 0.217404 45.427648 0.1 22.0914 NaBH4 22.93122836.4 0.218178 45.233379 0.1 21.9189 NaBH4 22.834868

38.31 0.2161895 45.73252 0.1 22.3646 NaBH4 23.08244943.88 0.2072658 47.972539 0.1 24.4701 NaBH4 24.19353547.66 0.1948591 51.086827 0.1 27.7178 NaBH4 25.738273

50.058 0.183921 53.832495 0.1 30.944521 NaBH4 27.100168

Budavari, S.; O'Neil, M. J.; Smith, A.; Heckleman, P. E.The Merck IndexMerck & Co., Inc., 1989

t w% w% m mC NaOH NaBH4 NaOH NaBH4

25 0 35.483871 0 14.538003 17.74193560 2.0777746 45.974095 1 23.392969 25.064822

Mikheeva, V. I.; Breitzis, V. B.Izoterma rastvorimosti borogidrida natriya i gidrata okisi natriya v vode pri 0°CDoklady Akademii Nauk SSSR 1960, 131 (6), 1349-1350

t w% w% m mC NaOH NaBH4 NaOH NaBH4

0 0 28.9 0 10.744107 NaBH4.2H2O 14.450 22.5 22.3 10.190956 10.678441 NaBH4.2H2O+ 33.650 44.4 12.3 25.636963 7.5086056 NaBH4+NaOH. 50.55

t w% w% m mC NaOH NaBH4 NaOH NaBH4

0 0.22135 28.3517 0.0774799 10.492019 NaBH4.2H2O 14.39720 0.2305 28.217 0.0805411 10.423849 NaBH4.2H2O 14.3390 0.7182 27.951 0.2517328 10.357676 NaBH4.2H2O 14.69370 1.2985 27.6182 0.4567156 10.269986 NaBH4.2H2O 15.10760 2.1474 27.2198 0.7601128 10.186397 NaBH4.2H2O 15.75730 2.6938 26.9542 0.9573272 10.127263 NaBH4.2H2O 16.17090 3.24925 26.5539 1.1572761 9.9989125 NaBH4.2H2O 16.52620 3.8543 26.2886 1.3794516 9.9471572 NaBH4.2H2O 16.99860 4.4933 25.9562 1.6152385 9.8646784 NaBH4.2H2O 17.47140 5.4687 25.424 1.97848 9.7243824 NaBH4.2H2O 18.18070 6.38545 24.8915 2.3230608 9.5739404 NaBH4.2H2O 18.83120 7.41045 24.4943 2.7208165 9.5080245 NaBH4.2H2O 19.65760 8.41965 23.8951 3.1100795 9.3316167 NaBH4.2H2O 20.36720 9.3273 23.4972 3.4714949 9.2458593 NaBH4.2H2O 21.07590 10.2936 23.0996 3.8638496 9.1670155 NaBH4.2H2O 21.84340 11.4542 22.434 4.3316891 8.9695326 NaBH4.2H2O 22.67120 12.42045 22.0365 4.7378595 8.8870587 NaBH4.2H2O 23.43870 13.42055 21.5719 5.1615247 8.7713548 NaBH4.2H2O 24.20650 14.6464 21.2434 5.7118298 8.7586863 NaBH4.2H2O 25.26810 15.78865 20.8471 6.2297726 8.6964785 NaBH4.2H2O 26.21220 17.0145 20.5186 6.8099 8.6824012 NaBH4.2H2O 27.27380 18.1816 20.1898 7.3760065 8.6594796 NaBH4.2H2O 28.27650 19.0279 20.2628 7.8362292 8.8223912 NaBH4.2H2O 29.15930 19.7321 20.2676 8.2222633 8.9287565 NaBH4.2H2O 29.86590 20.30065 20.5407 8.5795238 9.17781 NaBH4.2H2O 30.5710 20.894 20.8814 8.9719444 9.4797127 NaBH4.2H2O 31.3347

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0 21.4626 21.1546 9.3513022 9.7446256 NaBH4.2H2O 32.03990 21.98815 21.6295 9.7502783 10.140173 NaBH4.2H2O 32.80290 22.3128 22.0358 10.024194 10.466339 NaBH4.2H2O 33.33070 22.4119 22.3058 10.135941 10.665317 NaBH4.2H2O 33.56480 22.4119 22.3058 10.135941 10.665317 NaBH4 33.56480 23.19565 21.5703 10.499561 10.322654 NaBH4 33.98080 23.91155 20.9691 10.846138 10.055827 NaBH4 34.39610 24.5935 20.435 11.18547 9.8260536 NaBH4 34.8110 25.2416 19.968 11.518181 9.6332354 NaBH4 35.22560 25.865 19.4334 11.821809 9.3905458 NaBH4 35.58170 26.72295 18.9005 12.286954 9.1876347 NaBH4 36.17320 27.54705 18.4347 12.74988 9.020646 NaBH4 36.76440 28.439 17.8346 13.234212 8.7744057 NaBH4 37.35630 29.2632 17.3688 13.709209 8.6026244 NaBH4 37.94760 30.20465 16.9037 14.277698 8.4476661 NaBH4 38.65650 31.02885 16.4379 14.767362 8.2709261 NaBH4 39.24780 31.7604 16.0388 15.211789 8.1215101 NaBH4 39.77980 32.76055 15.5741 15.853432 7.9679327 NaBH4 40.54760 33.75165 15.2441 16.544747 7.9001893 NaBH4 41.37370 34.5327 14.98 17.100936 7.8428109 NaBH4 42.02270 35.4651 14.6496 17.774611 7.7623864 NaBH4 42.78990 36.31395 14.2513 18.365918 7.6201622 NaBH4 43.43960 37.4224 13.922 19.229602 7.5632921 NaBH4 44.38340 38.5308 13.5928 20.121393 7.504634 NaBH4 45.32720 39.48795 13.3299 20.924657 7.4677753 NaBH4 46.15290 40.3864 13.0666 21.692767 7.420155 NaBH4 46.91970 41.43625 12.7369 22.606427 7.3465901 NaBH4 47.80470 42.14945 12.6071 23.292049 7.3654886 NaBH4 48.4530 43.3753 12.2786 24.454487 7.3187261 NaBH4 49.51460 43.87865 12.2147 24.985869 7.3535082 NaBH4 49.9860 44.20595 12.1495 25.323411 7.3581809 NaBH4 50.2807

Mikheeva, V. I.; Breitzis, V. B.Politerma rastvorimosti sistemy NaBH4 – H2O i izotermy rastvorimosti sistemy NaBH4 – NaOH – H2O pri 0; 18; 30 i 50°Zh. Neorg. Khim. 1960, 5 (11), 2553-2563

t w% w% m mC NaOH NaBH4 NaOH NaBH4

-2.5 0.3904101 2 0.1 0.5416012 Ice 1.3904101-3.8 0.3860279 3.1 0.1 0.8490115 Ice 1.9360279-5.4 0.3800522 4.6 0.1 1.2796321 Ice 2.6800522-7.9 0.3712879 6.8 0.1 1.9362822 Ice 3.7712879

-10.8 0.362922 8.9 0.1 2.5926703 Ice 4.812922-14.7 0.3529626 11.4 0.1 3.4146547 Ice 6.0529626-18.8 0.3430031 13.9 0.1 4.2843734 Ice 7.2930031-24.9 0.3318485 16.7 0.1 5.3204349 Ice 8.6818485-30.9 0.3218891 19.2 0.1 6.3061679 Ice 9.9218891-34.2 0.3171086 20.4 0.1 6.801313 Ice 10.517109

-35 0.3155151 20.8 0.1 6.9696957 Ice 10.715515-36.9 0.3127264 21.5 0.1 7.2684945 Ice 11.062726-37.5 0.3115313 21.8 0.1 7.3981887 Ice+NaBH4.2H 11.211531-34.5 0.3095394 22.3 0.1 7.6165712 NaBH4.2H2O 11.459539-30.2 0.3055556 23.3 0.1 8.061878 NaBH4.2H2O 11.955556-25.6 0.3031654 23.9 0.1 8.3346796 NaBH4.2H2O 12.253165

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-23.3 0.3019702 24.2 0.1 8.4726999 NaBH4.2H2O 12.40197-18.6 0.2983848 25.1 0.1 8.8933947 NaBH4.2H2O 12.848385

-14 0.2944011 26.1 0.1 9.3728514 NaBH4.2H2O 13.344401-10.2 0.2920108 26.7 0.1 9.6668048 NaBH4.2H2O 13.642011

-4.7 0.2888238 27.5 0.1 10.066311 NaBH4.2H2O 14.0388240 0.2844416 28.6 0.1 10.63025 NaBH4.2H2O 14.584442

36.4 0.2159207 45.8 0.1 22.425486 NaBH4.2H2O+ 23.115921

t w% w% m mC NaOH NaBH4 NaOH NaBH4

0 0 28.9 0 10.744107 NaBH4.2H2O 14.450 1.4 27.8 0.4943861 10.378955 NaBH4.2H2O 15.30 4.6 25.8 1.6524187 9.7983408 NaBH4.2H2O 17.50 6.9 24.9 2.5295089 9.6506607 NaBH4.2H2O 19.350 9.6 23.5 3.5877041 9.2850409 NaBH4.2H2O 21.350 12.3 22.3 4.7021758 9.0129963 NaBH4.2H2O 23.450 17.1 20.8 6.8845571 8.8534759 NaBH4.2H2O 27.50 20 20.6 8.4181187 9.1669076 NaBH4.2H2O 30.30 21 21.1 9.0680149 9.6326542 NaBH4.2H2O 31.550 22.4 22.1 10.090822 10.525467 NaBH4.2H2O 33.450 22.5 22.3 10.190956 10.678441 NaBH4.2H2O+ 33.650 22.9 22 10.390953 10.553904 NaBH4 33.90 26.1 19.9 12.084209 9.7409518 NaBH4 36.050 29 18 13.680237 8.9771548 NaBH4 380 33.4 15.7 16.405905 8.1531221 NaBH4 41.250 38.8 13.6 20.379629 7.5522096 NaBH4 45.60 42.5 12.6 23.665413 7.417649 NaBH4 48.80 43.4 12.5 24.604958 7.4922714 NaBH4 49.650 44.4 12.13 25.536703 7.3758697 NaBH4+NaOH. 50.4650 44.5 11.3 25.171508 6.7576898 NaOH.H2O 50.150 45.1 9.4 24.782016 5.4608284 NaOH.H2O 49.80 46.1 5.8 23.962236 3.1873151 NaOH.H2O 490 46.8 4.4 23.977148 2.3832792 NaOH.H2O 490 47.6 2.4 23.801726 1.2687712 NaOH.H2O 48.80 49.1 0 24.117662 0 NaOH.H2O 49.1

18 0.6 33.3 0.2269453 13.316339 NaBH4.2H2O 17.2518 3 31.2 1.1399003 12.533454 NaBH4.2H2O 18.618 6.4 29.2 2.4846522 11.985028 NaBH4.2H2O 2118 9 28.3 3.5887769 11.930564 NaBH4.2H2O 23.1518 10.8 27.8 4.397713 11.967915 NaBH4.2H2O 24.718 13.2 28 5.6126518 12.587016 NaBH4.2H2O 27.218 14.2 28.3 6.1743607 13.009502 NaBH4.2H2O 28.3518 15.5 28.7 6.944948 13.595331 NaBH4.2H2O 29.8518 16 29 7.2732546 13.937259 NaBH4.2H2O+ 30.518 17.5 27.6 7.9696124 13.288587 NaBH4 31.318 21.9 24 10.120882 11.726166 NaBH4 33.918 26 21.3 12.33486 10.683439 NaBH4 36.6518 29.6 19.5 14.539365 10.126489 NaBH4 39.3518 34.6 16.9 17.836345 9.2105813 NaBH4 43.0518 38.1 15.4 20.485356 8.7540666 NaBH4 45.818 41.5 14.8 23.74314 8.952047 NaBH4 48.918 44.2 14.4 26.692756 9.1939942 NaBH4 51.418 46.1 14 28.886806 9.2746433 NaBH4 53.118 46.8 13.9 29.773151 9.3489821 NaBH4+NaOH. 53.75

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18 47.6 11.9 29.384846 7.766655 NaOH.H2O 53.5518 47.8 10.4 28.59059 6.5765653 NaOH.H2O 5318 48.6 8.4 28.257863 5.1636037 NaOH.H2O 52.818 49.5 4.9 27.140126 2.8403595 NaOH.H2O 51.9518 50.4 2.6 26.810454 1.4622363 NaOH.H2O 51.718 51.4 0 26.442246 0 NaOH.H2O 51.430 0.9 38.1 0.3688792 16.509625 NaBH4.2H2O 19.9530 2.1 37.7 0.8721563 16.55339 NaBH4.2H2O 20.9530 3.4 37 1.4262779 16.409583 NaBH4.2H2O 21.930 4.7 36.5 1.9984442 16.408074 NaBH4.2H2O 22.9530 6.1 36.1 2.6385996 16.509026 NaBH4.2H2O 24.1530 7.4 35.8 3.2572784 16.660068 NaBH4.2H2O 25.330 8.9 35.4 3.9949036 16.79926 NaBH4.2H2O 26.630 9.1 35.4 4.0993963 16.859798 NaBH4.2H2O+ 26.830 11 33.9 4.9912875 16.262607 NaBH4 27.9530 11.8 33.2 5.3640253 15.955759 NaBH4 28.430 15 30.4 6.8686298 14.717126 NaBH4 30.230 19.3 27.3 9.0362357 13.513364 NaBH4 32.9530 25.4 23.2 12.354981 11.930728 NaBH4 3730 31.8 19.8 16.426811 10.813391 NaBH4 41.730 37.2 17.5 20.53129 10.211321 NaBH4 45.9530 40.4 16.6 23.490075 10.204265 NaBH4 48.730 43.7 16 27.111147 10.494385 NaBH4 51.730 45.7 15.4 29.372309 10.464373 NaBH4 53.430 48.5 15 33.221587 10.862767 NaBH4+NaOH. 5630 48.7 13.7 32.382667 9.6310758 NaOH.H2O 55.5530 49.2 11.6 31.379826 7.8219313 NaOH.H2O 5530 50.6 7.9 30.484138 5.0317734 NaOH.H2O 54.5530 51.4 5.5 29.816547 3.3730866 NaOH.H2O 54.1530 52.5 2.3 29.039716 1.3450285 NaOH.H2O 53.6530 53.4 0 28.650146 0 NaOH.H2O 53.450 3.3 42.1 1.5110986 20.381283 NaBH4 24.3550 6.9 38.8 3.1770259 18.887478 NaBH4 26.350 11.8 34.6 5.5041304 17.062921 NaBH4 29.150 16.9 30.8 8.0789796 15.566505 NaBH4 32.350 21 27.9 10.274718 14.431962 NaBH4 34.9550 24 26 12.00087 13.745021 NaBH4 3750 26.6 24.5 13.600168 13.243394 NaBH4 38.8550 29.3 22.9 15.325379 12.663381 NaBH4 40.7550 31.3 21.9 16.721298 12.369164 NaBH4 42.2550 33.1 21.2 18.108534 12.262012 NaBH4 43.750 35.6 20.3 20.182869 12.167449 NaBH4 45.7550 37.7 19.5 22.022625 12.042951 NaBH4 47.4550 39.4 19 23.679601 12.072643 NaBH4 48.950 40 18.3 23.982554 11.599977 NaBH4 49.1550 43.2 18 27.83707 12.262608 NaBH4 52.250 44.5 17.6 29.35569 12.274831 NaBH4 53.350 47.5 17.2 33.642666 12.879406 NaBH4 56.150 48.5 17 35.147476 13.024825 NaBH4 5750 50.4 16.8 38.417419 13.538717 NaBH4 58.850 50.8 16.5 38.840736 13.337618 NaBH4+NaOH. 59.0550 52.6 14 39.374112 11.079589 NaOH.H2O 59.650 54.3 9.7 37.711067 7.1221532 NaOH.H2O 59.1550 56.2 6.1 37.270607 4.2769144 NaOH.H2O 59.25

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50 58.4 2.3 37.152821 1.5469539 NaOH.H2O 59.5550 59.2 0 36.27714 0 NaOH.H2O 59.2

Morton, PaulRohm & Haas 2002 proprietary data

t w% w% m mC NaOH NaBH4 NaOH NaBH4

50 36 20 20.456029 12.014879 4650 21.89781 27.007299 10.715063 13.971588 35.4014650 9.5541401 36.305732 4.4120846 17.72548 27.707006

Saldin, V. I.; Brovkina, O. V.; Ippolitov, E. G.; Popov, A. P.Zhurnal Neorganicheskoi Khimii 1983, 28, 490-494The MBF4-MBH4-H2O systems (M= Na or K) at 0 °CRuss. J. Inorg. Chem. 1983, 28 (2), 273-275

t w% w% m mC NaOH NaBH4 NaOH NaBH4

0 0.2872701 27.89 0.1 10.264285 14.23227

Stockmayer, Walter H.; Rice, Dale W.; Stephenson, Clark C.Thermodynamic properties of sodium borohydride and aqueous borohydride ionThe Journal of the American Chemical Society 1955, 77 (7), 1980-1983

t w% w% m mC NaOH NaBH4 NaOH NaBH4

25 0 36.04891 0 14.9 NaBH4.2H2O 18.02445525 0 36.963963 0 15.5 NaBH4 18.481981

MSE

t w% w% m mC NaOH NaBH4 NaOH NaBH4

-0.359 0.3983771 0 0.0999999 0 0.3983771-0.394 0.3982274 0.037667 0.1 0.01 0.4170609-0.533 0.3976278 0.1880516 0.0999998 0.05 0.4916536-0.71 0.3968821 0.3753971 0.1 0.1 0.5845807

-1.074 0.3953968 0.7479866 0.0999998 0.2000001 0.7693902-1.453 0.3939259 1.1177988 0.1000004 0.2999999 0.9528253-1.845 0.3924604 1.4848677 0.0999995 0.4000004 1.1348943-2.248 0.391009 1.8492185 0.0999996 0.5000001 1.3156183-2.662 0.3895655 2.2108804 0.0999988 0.5999988 1.4950057-3.086 0.388125 2.5699037 0.0999962 0.7000021 1.6730769-3.519 0.3867298 2.926272 0.1000026 0.7999976 1.8498658-3.959 0.3853136 3.2800733 0.1000008 0.9000016 2.0253503-4.406 0.3839202 3.631286 0.1000023 1.0000002 2.1995632-4.858 0.3825278 3.9799566 0.1000014 1.0999986 2.3725061-5.546 0.3804629 4.4982722 0.1000014 1.2500005 2.629599-6.714 0.3770777 5.3497854 0.1000033 1.4999973 3.0519705-7.899 0.3737196 6.1862707 0.0999964 1.7500003 3.466855-9.096 0.3704554 7.008085 0.099999 1.9999992 3.8744979

-10.301 0.3672405 7.8156359 0.0999996 2.250001 4.2750584-11.511 0.3640741 8.6092791 0.0999983 2.5000018 4.6687137

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-12.725 0.3609787 9.3893638 0.1000017 2.7499999 5.0556606-13.941 0.3579099 10.156253 0.0999979 3 5.4360362

-15.16 0.3549116 10.910264 0.0999995 3.2499992 5.8100437-16.383 0.3519617 11.651739 0.1000006 3.500003 6.1778312-17.609 0.3490599 12.380947 0.1000015 3.7499977 6.5395334-18.842 0.3461839 13.098244 0.0999962 4.0000011 6.8953058-20.082 0.3434 13.803868 0.1000041 4.2499984 7.2453342-21.332 0.3406197 14.498148 0.0999998 4.5000016 7.5896936-22.593 0.3379092 15.18132 0.1000031 4.7500016 7.9285694-23.869 0.3352239 15.853656 0.1000011 4.9999982 8.2620517-26.472 0.3299735 17.166882 0.0999954 5.5000039 8.9134146-29.164 0.3249114 18.439715 0.099998 5.9999979 9.5447689-31.971 0.3200152 19.674035 0.1000046 6.4999981 10.157033-34.924 0.3151083 20.871624 0.0999613 7.0000151 10.75092-38.059 0.310541 22.033917 0.0999811 7.5000011 11.327499

-41.42 0.3062034 23.162507 0.1000328 7.9999744 11.887457-45.067 0.3016551 24.259084 0.0999735 8.5000024 12.431197-49.075 0.2975548 25.324623 0.1000219 8.9999812 12.959866-53.554 0.2932431 26.360797 0.0999593 9.5000175 13.473641-58.667 0.2893779 27.368365 0.1000103 9.999974 13.97356-64.681 0.2853007 28.348982 0.0999505 10.500015 14.459792

-72.1 0.2816692 29.303224 0.1000103 10.999974 14.933281-82.125 0.2778244 30.232643 0.0999592 11.500025 15.394146

-100.615 0.2744242 31.137661 0.1000337 11.999978 15.843255-40 0.3123641 21.59062 0.0999996 7.3075663 11.107674-39 0.3116805 21.755953 0.0999915 7.3790819 11.189657-38 0.3109971 21.920643 0.0999827 7.4506202 11.271319

-37.5 0.3107654 22.002678 0.1000134 7.486378 11.312104-37 0.3103141 22.084712 0.0999732 7.5221893 11.35267-36 0.3096308 22.2483 0.0999629 7.5938493 11.433781-35 0.3091677 22.411286 0.1000233 7.6655672 11.514811-34 0.3084853 22.574046 0.1000122 7.7374655 11.595508-33 0.3078027 22.736554 0.1000008 7.8095543 11.67608-32 0.3071198 22.899014 0.0999891 7.8819256 11.756627-31 0.3066572 23.061079 0.1000491 7.9544478 11.837197-30 0.305975 23.223307 0.1000374 8.0273271 11.917628-29 0.3052928 23.38551 0.1000256 8.1005039 11.998048-28 0.3046107 23.547894 0.100014 8.1740731 12.078558-27 0.3039286 23.710459 0.1000027 8.2480382 12.159158-26 0.303247 23.873228 0.0999917 8.3224129 12.239861-25 0.302565 24.03636 0.0999811 8.3972731 12.320745-24 0.3018831 24.199879 0.0999709 8.4726341 12.401823-23 0.3014206 24.363778 0.1000343 8.5485226 12.48331-22 0.3007388 24.528274 0.1000255 8.6249942 12.564876-21 0.3000573 24.693386 0.1000176 8.7020883 12.64675-20 0.2993751 24.859245 0.1000105 8.7798728 12.728998-19 0.2986936 25.025745 0.1000044 8.8583042 12.811566-18 0.2980114 25.193196 0.0999993 8.9375364 12.89461-17 0.2973298 25.361494 0.0999955 9.0175278 12.978077-16 0.2966482 25.530589 0.0999928 9.0982624 13.061943-15 0.2959662 25.700865 0.0999916 9.179933 13.146399-14 0.2952842 25.872348 0.0999919 9.262562 13.231458-13 0.2948212 26.044827 0.1000683 9.3460861 13.317235-12 0.2939201 26.218755 0.0999973 9.4306519 13.403298

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-11 0.2932378 26.394064 0.1000028 9.5163224 13.49027-10 0.2925554 26.570786 0.1000102 9.603098 13.577948-9 0.2916537 26.749131 0.0999445 9.6910669 13.666219-8 0.2911903 26.928905 0.1000315 9.7802347 13.755643-7 0.2902884 27.110692 0.0999702 9.8707902 13.845634-6 0.2896056 27.29412 0.0999867 9.962653 13.936666-5 0.2889226 27.47958 0.1000061 10.056007 14.028713-4 0.2882393 27.667071 0.1000283 10.150871 14.121775-3 0.2875556 27.856774 0.1000535 10.247357 14.215942-2 0.2866531 28.048777 0.1000055 10.345501 14.311042-1 0.2857498 28.243377 0.0999605 10.445509 14.4074380 0.2850654 28.440448 0.0999958 10.547376 14.5052891 0.2843808 28.640817 0.100036 10.651526 14.6047892 0.2834767 28.844438 0.1000031 10.757936 14.7056963 0.2825723 29.051365 0.0999747 10.866701 14.8082554 0.2818868 29.26183 0.1000291 10.978015 14.9128025 0.2809816 29.476379 0.1000112 11.092141 15.0191716 0.2800757 29.695243 0.099999 11.209283 15.1276977 0.2791694 29.918868 0.0999935 11.329731 15.2386048 0.278262 30.147612 0.0999948 11.453738 15.3520689 0.2773539 30.381747 0.1000037 11.581514 15.468227

10 0.2764456 30.621753 0.1000211 11.713394 15.58732211 0.2753172 30.868347 0.099968 11.849814 15.7094912 0.274407 31.12165 0.1000041 11.991006 15.83523213 0.2732765 31.382592 0.0999707 12.137511 15.96457214 0.272145 31.651685 0.0999486 12.289771 16.09798815 0.2712309 31.929354 0.1000195 12.448192 16.23590816 0.2700965 32.216831 0.1000236 12.613541 16.37851217 0.2687423 32.514617 0.099961 12.786271 16.52605118 0.2676046 32.823722 0.099996 12.967238 16.67946619 0.2664649 33.145244 0.1000492 13.157259 16.83908720 0.2648862 33.480671 0.0999576 13.357378 17.00522221 0.2635234 33.831088 0.09997 13.568665 17.17906722 0.2621577 34.198195 0.1000069 13.792442 17.36125523 0.260571 34.584008 0.0999878 14.030296 17.55257524 0.2589802 34.990745 0.0999992 14.284125 17.75435325 0.2571673 35.421261 0.099961 14.556248 17.96779826 0.2553501 35.878626 0.0999626 14.849369 18.19466327 0.2535273 36.366812 0.1000107 15.16692 18.43693328 0.2514798 36.891117 0.1000272 15.513416 18.69703829 0.2489898 37.457868 0.0999339 15.894428 18.97792430 0.2467087 38.075223 0.1000058 16.317505 19.2843231 0.2439815 38.754679 0.0999975 16.792944 19.62132132 0.241024 39.512089 0.1000224 17.335543 19.99706833 0.2376144 40.370884 0.1000276 17.967433 20.42305734 0.233531 41.368274 0.0999808 18.724492 20.91766835 0.2287646 42.569862 0.0999894 19.671517 21.51369536 0.2226464 44.114547 0.1000051 20.948783 22.2799237 0.2133869 46.430983 0.0999906 23.002217 23.428878

-40 0.2658399 33.289685 0.1000306 13.243198 16.910682-39 0.2653868 33.416408 0.1000502 13.318922 16.973591-38 0.2647154 33.543329 0.0999875 13.39501 17.03638

-37.5 0.2644889 33.606782 0.0999974 13.43318 17.06788-37 0.2642624 33.670232 0.1000074 13.471422 17.099379

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-36 0.2638094 33.797125 0.1000274 13.54812 17.162372-35 0.2631382 33.924217 0.0999645 13.62519 17.225247-34 0.2626852 34.051292 0.0999849 13.702591 17.288331-33 0.2622326 34.178391 0.1000054 13.780307 17.351428-32 0.2617797 34.305652 0.1000262 13.858422 17.414606-31 0.2611086 34.433115 0.0999634 13.93692 17.477666-30 0.260656 34.560598 0.0999846 14.015782 17.540955-29 0.2602032 34.688244 0.1000061 14.095053 17.604325-28 0.2597503 34.816088 0.1000279 14.174759 17.667794-27 0.2590792 34.944138 0.0999656 14.25486 17.731148-26 0.2586269 35.072246 0.0999881 14.335362 17.79475-25 0.2579558 35.200698 0.0999261 14.416351 17.858305-24 0.2577213 35.329169 0.100034 14.497771 17.922306-23 0.2570504 35.458062 0.0999726 14.579687 17.986082-22 0.2565979 35.586986 0.0999964 14.661999 18.050091-21 0.2561451 35.716285 0.1000209 14.744883 18.114288-20 0.2556923 35.845794 0.1000457 14.828237 18.178589-19 0.2550212 35.975726 0.0999854 14.912152 18.242884-18 0.2545687 36.105732 0.1000112 14.996507 18.307434-17 0.2541159 36.236122 0.1000375 15.081457 18.372177-16 0.2534449 36.366942 0.0999782 15.166985 18.436916-15 0.252992 36.498012 0.1000057 15.253084 18.501998-14 0.2525388 36.629475 0.1000337 15.339798 18.567276-13 0.252086 36.761239 0.1000625 15.427073 18.632705-12 0.2514149 36.893447 0.100005 15.514955 18.698138-11 0.2509617 37.026087 0.1000351 15.603549 18.764005-10 0.2502903 37.159178 0.0999786 15.692768 18.829879-9 0.2498367 37.292711 0.10001 15.782717 18.896192-8 0.2493833 37.426568 0.1000422 15.873271 18.962667-7 0.2487117 37.561096 0.0999875 15.964614 19.02926-6 0.2482577 37.696081 0.1000214 16.056721 19.096298-5 0.247586 37.83162 0.099968 16.149553 19.163396-4 0.2471319 37.967629 0.1000036 16.243171 19.230946-3 0.2466776 38.104162 0.1000401 16.337565 19.298759-2 0.2460053 38.241438 0.099989 16.432835 19.366724-1 0.2453325 38.379418 0.0999386 16.529023 19.4350410 0.2448774 38.517939 0.0999781 16.626081 19.5038471 0.2444222 38.657057 0.1000187 16.724 19.5729512 0.2437488 38.797157 0.0999713 16.823001 19.6423273 0.2430751 38.938244 0.0999252 16.923159 19.7121974 0.2426187 39.080319 0.0999703 17.024549 19.7827785 0.2419442 39.223653 0.0999274 17.127258 19.8537716 0.2414869 39.368205 0.0999765 17.231395 19.9255897 0.2410294 39.514275 0.1000283 17.337133 19.9981678 0.2403532 39.662178 0.099992 17.444658 20.0714429 0.2398944 39.811622 0.1000491 17.553905 20.145706

10 0.2389998 39.963259 0.0999273 17.665185 20.22062911 0.2385393 40.116752 0.0999907 17.778533 20.29691512 0.2378611 40.272543 0.0999664 17.894111 20.37413313 0.2371817 40.430691 0.0999454 18.012057 20.45252714 0.2367193 40.591325 0.1000205 18.13257 20.53238215 0.2360382 40.75481 0.1000079 18.255829 20.61344316 0.2353563 40.92124 0.0999999 18.382013 20.69597617 0.2346732 41.090802 0.0999967 18.511308 20.780074

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18 0.2339892 41.263563 0.0999985 18.643814 20.86577119 0.2333035 41.440074 0.100006 18.780008 20.95334120 0.2326175 41.620205 0.1000196 18.919848 21.0427221 0.2317122 41.804556 0.0999457 19.063794 21.1339922 0.2310231 41.993102 0.0999725 19.212041 21.22757423 0.2303322 42.186207 0.1000066 19.364879 21.32343624 0.2296401 42.384229 0.1000489 19.522679 21.42175525 0.2287289 42.587532 0.1000046 19.685752 21.52249526 0.2280331 42.796378 0.1000646 19.85456 21.62622227 0.2271181 43.011225 0.1000387 20.02944 21.7327328 0.2259843 43.232596 0.0999271 20.210948 21.84228229 0.2252825 43.460663 0.1000189 20.399599 21.95561430 0.2241447 43.696193 0.0999297 20.595877 22.07224131 0.2232213 43.939513 0.09995 20.800471 22.19297832 0.2222957 44.191406 0.099985 21.014165 22.31799833 0.2213674 44.452468 0.1000356 21.237696 22.44760234 0.2202192 44.723715 0.100005 21.472112 22.58207635 0.2190689 45.005589 0.0999924 21.71818 22.72186336 0.2179154 45.299401 0.1000002 21.977387 22.86761637 0.2167584 45.606189 0.1000304 22.251049 23.01985338 0.2155984 45.927117 0.1000858 22.540669 23.17915739 0.2140021 46.263985 0.0999671 22.848236 23.34599540 0.2126185 46.618182 0.0999799 23.175937 23.5217141 0.2112313 46.991818 0.1000279 23.5264 23.7071442 0.2096241 47.387694 0.1000136 23.903095 23.90347143 0.2080128 47.808575 0.1000453 24.309895 24.112344 0.2061812 48.258414 0.1000265 24.751951 24.33538845 0.2041292 48.742072 0.0999652 25.235854 24.57516546 0.2020725 49.26579 0.0999795 25.770322 24.83496747 0.1997954 49.837995 0.0999805 26.367017 25.11879348 0.1972974 50.470591 0.0999915 27.042744 25.43259349 0.1945781 51.180872 0.1000483 27.822373 25.78501450 0.1912065 51.9963 0.0999845 28.745716 26.18935751 0.1873965 52.963898 0.1000081 29.883015 26.66934552 0.1827161 54.178423 0.1000952 31.378605 27.27192753 0.1756538 55.89504 0.0999712 33.632643 28.123174

0 0 28.610297 0 10.593241 14.3051480 0.028468 28.593315 0.0099716 10.588657 14.3251250 0.1425474 28.52516 0.0499626 10.570219 14.4051270 0.2850654 28.440448 0.0999958 10.547376 14.5052890 0.5691392 28.272405 0.1999694 10.502152 14.7053420 0.8524386 28.106227 0.3000016 10.457636 14.9055520 1.1347482 27.941828 0.4000196 10.413751 15.1056620 1.4160658 27.779328 0.500027 10.370562 15.305730 1.6963929 27.618757 0.6000281 10.328086 15.5057710 1.9757321 27.459937 0.7000262 10.286234 15.70570 2.2540803 27.303018 0.8000252 10.245083 15.9055890 2.5314401 27.148029 0.9000301 10.204653 16.1054550 2.8078148 26.99479 1.0000436 10.164851 16.305210 3.0832004 26.843457 1.1000702 10.125761 16.5049290 3.4939943 26.620109 1.2499831 10.068444 16.8040490 4.1737993 26.257009 1.4999822 9.9763201 17.3023040 4.847017 25.90565 1.7500199 9.8885704 17.7998420 5.5132215 25.566228 1.9999917 9.8052799 18.296335

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0 6.1724324 25.238563 2.2499524 9.7264014 18.7917140 6.8248852 24.922654 2.5000491 9.6520165 19.2862120 7.4697164 24.618879 2.7500013 9.5822532 19.7791560 8.1073535 24.32716 3.0000307 9.5171863 20.2709330 8.7374023 24.047576 3.2500308 9.4568617 20.761190 9.3596423 23.780273 3.499966 9.4013884 21.2497790 9.9743263 23.52509 3.7499857 9.3507818 21.7368720 10.581226 23.282369 4.0000639 9.3052634 22.2224110 11.179718 23.052337 4.2499917 9.2649434 22.7058870 11.77025 22.834782 4.5000037 9.2298496 23.1876420 12.352416 22.629926 4.7499833 9.2001284 23.6673790 12.926184 22.438091 4.9999908 9.1760414 24.145230 14.048054 22.093496 5.5000834 9.1450933 25.0948020 15.134028 21.802655 5.999972 9.1384943 26.0353550 16.183543 21.567025 6.4999455 9.1579217 26.9670560 17.195231 21.388428 6.9999603 9.2052803 27.8894450 18.167618 21.269259 7.4999996 9.2829535 28.8022480 19.099089 21.212551 8.0000832 9.3938867 29.7053640 19.987288 21.222033 8.4999599 9.5415861 30.5983040 20.830724 21.301913 8.9999928 9.7303172 31.481680 21.626383 21.457777 9.4999698 9.9653752 32.3552710 22.371074 21.69699 9.9999647 10.253726 33.2195680 23.060737 22.028287 10.499908 10.603852 34.074880 23.690487 22.463376 10.999955 11.027131 34.9221750 24.253473 23.017583 11.499961 11.538589 35.7622640 24.741276 23.710598 11.999985 12.158268 36.5965750 25.142452 24.569358 12.500089 12.91427 37.4271310 25.441304 25.629569 13.000001 13.845732 38.2560890 25.617442 26.939414 13.500001 15.009173 39.0871490 25.641857 28.56573 13.999981 16.488983 39.9247220 25.474357 30.601089 14.499979 18.414995 40.7749020 25.05449 33.185055 15.00002 21.004841 41.6470170 24.268252 36.586472 15.499962 24.704909 42.5614880 22.647966 41.961993 15.999987 31.341307 43.6289620 0 38.714905 0 16.698037 19.3574520 0.024404 38.695201 0.0099566 16.690818 19.3720050 0.1224481 38.616306 0.0499733 16.661994 19.4306010 0.2448774 38.517939 0.0999781 16.626081 19.5038470 0.4894614 38.32167 0.1999942 16.554424 19.6502960 0.7335347 38.126107 0.2999606 16.483011 19.7965880 0.9775321 37.931197 0.4000584 16.411922 19.943130 1.2208017 37.737204 0.5000206 16.341167 20.0894040 1.4637778 37.543873 0.6000277 16.270683 20.2357140 1.706246 37.351286 0.6999921 16.20047 20.3818890 1.9484172 37.159492 0.8000047 16.130616 20.5281630 2.1900835 36.968275 0.8999767 16.060917 20.6742210 2.4314544 36.777891 1.0000018 15.991606 20.82040 2.6725341 36.588208 1.1000826 15.922591 20.9666380 3.0329276 36.305158 1.2500214 15.819556 21.1855070 3.6315426 35.837138 1.4999697 15.649312 21.5501110 4.2275217 35.373657 1.7499631 15.480806 21.914350 4.8208697 34.914726 2.0000278 15.314042 22.2782330 5.4111584 34.460565 2.2500024 15.149061 22.6414410 5.9986045 34.010939 2.4999974 14.985752 23.004074

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0 6.5829888 33.566024 2.7499405 14.824179 23.3660010 7.1645452 33.125684 2.9999549 14.664307 23.7273870 7.7432574 32.689827 3.2500503 14.506064 24.0881710 8.3187216 32.258772 3.5000732 14.349572 24.4481080 8.8909201 31.832428 3.7500282 14.194764 24.8071340 9.4600792 31.410615 4.0000322 14.041572 25.1653870 10.025786 30.99359 4.2499181 13.890075 25.5225810 10.588661 30.581045 4.4999896 13.74021 25.8791830 11.148094 30.173088 4.7499689 13.591909 26.2346380 11.704286 29.769865 4.9999851 13.445322 26.5892190 12.806523 28.977408 5.4999639 13.157056 27.2952270 13.895223 28.203367 5.9999533 12.875198 27.9969060 14.970206 27.447756 6.4999832 12.599749 28.6940840 16.031254 26.710734 7.0000758 12.330811 29.3866220 17.077785 25.99218 7.5000059 12.068223 30.0738760 18.109981 25.292237 8.0000019 11.812176 30.75610 19.127754 24.610475 8.5000618 11.562418 31.4329920 20.130446 23.947282 8.9999497 11.319142 32.1040870 21.118494 23.302282 9.499964 11.082253 32.7696350 22.091498 22.675749 9.9999997 10.851931 33.4293730 23.04948 22.067349 10.5001 10.628037 34.0831550 23.991839 21.477385 11.000017 10.410745 34.7305320 24.918759 20.905702 11.499916 10.200081 35.371610 25.830562 20.352001 12.00003 9.9959983 36.0065620 26.726495 19.816512 12.49997 9.7986168 36.6347510 27.606856 19.299131 12.999987 9.6080286 37.2564220 28.471386 18.799834 13.499957 9.4242844 37.8713030 29.320137 18.318561 13.999968 9.2474715 38.4794180 30.152943 17.85527 14.499949 9.0776566 39.0805780 30.96979 17.409926 14.999935 8.9149436 39.6747530 31.770709 16.982503 15.500002 8.759456 40.2619610 32.555431 16.572943 15.999975 8.6112476 40.8419020 33.324085 16.181233 16.500006 8.4704803 41.4147020 34.076593 15.807334 17.000067 8.3372663 41.980260 34.812814 15.451141 17.500053 8.2116678 42.5383840 35.532621 15.112743 17.999929 8.0938926 43.0889930 36.236392 14.791945 18.499994 7.9840362 43.6323640 36.923728 14.488824 18.999972 7.8822669 44.168140 37.594846 14.20323 19.500037 7.7886977 44.6964620 38.249399 13.935205 19.999925 7.703493 45.2170020 39.509708 13.451372 20.999936 7.558773 46.2353940 40.704718 13.036713 22.000069 7.4493432 47.2230740 41.83424 12.690418 22.999977 7.376359 48.1794490 42.899037 12.411318 24.00005 7.3409639 49.1046960 43.899495 12.198003 25.0001 7.3441499 49.9984960 44.836428 12.048593 26.000059 7.386696 50.8607250 45.710978 11.960855 26.999924 7.4692126 51.6914050 46.524926 11.931962 28.000008 7.5919774 52.4909070 47.279866 11.958779 29.000075 7.7549733 53.2592550 47.977828 12.037671 29.999941 7.9577969 53.9966640 48.62162 12.164691 31.000108 8.1998413 54.7039650 49.213416 12.3357 31.999904 8.4800719 55.3812660 49.75662 12.546361 33.000108 8.7973701 56.02980 50.253758 12.79229 34.000018 9.1501769 56.649903

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0 50.708111 13.069179 34.999996 9.536949 57.2427010 51.122743 13.372832 36.000054 9.9559561 57.8091590 51.500524 13.699307 37.000006 10.405413 58.3501780 51.844511 14.044841 38.000063 10.883509 58.8669320 52.157269 14.406056 38.999878 11.388436 59.3602970 52.441688 14.779824 39.999932 11.918523 59.83160 52.700131 15.163242 40.999909 12.471935 60.2817520 52.934934 15.553867 41.999967 13.047146 60.7118680 53.148168 15.949513 43.000026 13.64264 61.1229240 53.341819 16.348182 44.000073 14.256917 61.515910 53.517515 16.748245 44.999801 14.888623 61.8916370 53.677278 17.148173 46 15.536593 62.2513650 53.822284 17.546822 47.000093 16.19965 62.5956950 53.95391 17.943091 48.000057 16.876667 62.9254560 54.073398 18.336098 48.999938 17.566667 63.2414470 54.181987 18.725113 50.000107 18.268843 63.5445440 49.228686 0 24.242161 0 49.2286860 49.217325 0.0192048 24.240311 0.01 49.2269270 49.172191 0.0959639 24.233179 0.0499999 49.2201720 49.115937 0.1917785 24.224346 0.1 49.2118260 49.004281 0.3829562 24.207251 0.2000005 49.195760 48.893561 0.5735284 24.190724 0.300001 49.1803260 48.783645 0.7634905 24.174634 0.3999999 49.165390 48.67483 0.9528418 24.159276 0.500001 49.1512510 48.566836 1.1415748 24.144374 0.5999998 49.1376230 48.459916 1.329686 24.130176 0.6999992 49.1247590 48.35392 1.5171769 24.116539 0.8000002 49.1125090 48.248923 1.7040352 24.103534 0.8999994 49.1009410 48.144914 1.8902653 24.091153 1.0000011 49.0900470 48.041715 2.0758581 24.079221 1.0999987 49.0796440 47.88888 2.3530475 24.062604 1.2499977 49.0654040 47.638779 2.8118214 24.037745 1.5000005 49.044690 47.39448 3.2665298 24.01646 1.7500016 49.0277450 47.156148 3.7171174 23.998933 2.0000021 49.0147070 46.923859 4.1635225 23.985253 2.2499977 49.005620 46.6973 4.6057457 23.975157 2.5000013 49.0001730 46.47673 5.0436973 23.968909 2.7499975 48.9985780 46.261879 5.4773845 23.966291 3.0000008 49.0005720 46.052802 5.9067563 23.96738 3.2500058 49.006180 45.849464 6.3317498 23.972162 3.4999938 49.0153390 45.651974 6.752385 23.980812 3.7500072 49.0281670 45.460058 7.1685861 23.993061 3.9999979 49.0443510 45.274006 7.5803458 24.009262 4.2500055 49.0641790 45.093269 7.9876482 24.02889 4.4999894 49.0870930 44.918344 8.3904735 24.052507 4.7500007 49.113580 44.748793 8.788789 24.079697 4.999992 49.1431880 44.426274 9.5718593 24.145485 5.500003 49.2122030 44.125098 10.336753 24.226005 5.9999945 49.2934740 43.844985 11.083433 24.321403 6.5000029 49.3867010 43.585447 11.811834 24.431586 7.0000006 49.4913640 43.345708 12.522071 24.556237 7.5000207 49.6067440 43.125325 13.214101 24.695307 8.0000053 49.7323750 42.92364 13.888107 24.848627 8.5000109 49.8676930 42.739916 14.5442 25.015878 9 50.012016

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0 42.57374 15.182519 25.197122 9.4999989 50.1650 42.424089 15.803346 25.391764 9.9999991 50.3257610 42.290306 16.406882 25.599572 10.499981 50.4937470 42.171915 16.993406 25.820562 11.000017 50.6686180 42.067613 17.56323 26.053717 11.499972 50.8492280 41.977186 18.116698 26.299371 12.000012 51.0355350 41.899558 18.654095 26.556703 12.499985 51.2266060 41.834111 19.175853 26.825536 12.999994 51.4220380 41.780035 19.682371 27.105392 13.500035 51.621220 41.736457 20.173984 27.39562 13.999992 51.8234490 41.702902 20.651137 27.696148 14.499988 52.028470 41.678481 21.114279 28.006313 14.999987 52.2356210 41.662806 21.563744 28.326026 15.500006 52.4446780 41.654878 22.000067 28.654447 16.000028 52.6549110 41.654206 22.423554 28.991251 16.499968 52.8659830 41.660282 22.834743 29.336243 17.000003 53.0776540 41.672413 23.234009 29.68879 17.500021 53.2894170 41.690258 23.621696 30.048738 18.000034 53.5011060 41.712991 23.998303 30.415273 18.49999 53.7121420 41.740503 24.364168 30.788556 19.00001 53.9225870 41.771956 24.719732 31.167628 19.49994 54.1318220 41.807408 25.06535 31.552913 20.000026 54.3400830 41.88782 25.728159 32.339142 21.000036 54.75190 41.978752 26.355444 33.144426 21.99996 55.1564740 42.078187 26.949784 33.967129 22.999992 55.5530780 42.183881 27.513619 34.804834 24.000005 55.9406910 42.294128 28.049195 35.655709 24.999998 56.3187250 42.407674 28.558517 36.518416 26.000022 56.6869320 42.523197 29.043505 37.391266 27.000006 57.0449490 42.639854 29.505835 38.2732 27.999969 57.3927710 42.756724 29.947188 39.162961 28.999982 57.7303180 42.873329 30.368862 40.059742 29.999917 58.057760 42.989083 30.772311 40.962733 30.999982 58.3752390 43.103623 31.158591 41.871073 31.999905 58.6829190 43.216672 31.52889 42.784368 32.999933 58.9811170 43.327922 31.88417 43.701815 33.999875 59.2700070 43.437319 32.225394 44.623367 35.000007 59.5500160 43.544489 32.553434 45.547974 36.000062 59.8212060 43.64971 32.868829 46.475894 36.999955 60.0841250 43.752654 33.172608 47.406634 38.000115 60.3389580 43.853354 33.465224 48.339707 39.000081 60.5859650 43.9518 33.747348 49.275009 40.000025 60.8254740 44.048037 34.01958 50.212547 41.000129 61.0578280 44.142117 34.282315 51.151978 42.000068 61.2832750 44.234138 34.536065 52.093463 43.000063 61.5021710 44.323864 34.781402 53.036183 43.999963 61.7145650 44.411698 35.018511 53.980759 44.999725 61.9209530 44.497549 35.248044 54.927276 45.999973 62.1215710 44.581443 35.470162 55.875017 46.999939 62.3165240 44.663482 35.685247 56.824215 47.999879 62.5061060 44.74373 35.893645 57.774931 48.999924 62.6905520 44.822195 36.095673 58.726987 50.000037 62.870032

18 0 32.989136 0 13.012711 16.49456818 0.0266559 32.9725 0.0099468 13.008094 16.512906

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18 0.1339245 32.906027 0.0500053 12.989779 16.58693818 0.2676046 32.823722 0.099996 12.967238 16.67946618 0.5344501 32.661275 0.2000204 12.923227 16.86508818 0.8003159 32.501913 0.3000002 12.880706 17.05127218 1.0652063 32.345423 0.399945 12.839556 17.23791818 1.3293356 32.191846 0.4999457 12.799844 17.42525918 1.5927042 32.041014 0.6000109 12.761474 17.61321118 1.8550954 31.893171 0.7000685 12.724553 17.80168118 2.1160727 31.748302 0.799957 12.688992 17.99022418 2.3765073 31.606182 0.9000214 12.654829 18.17959818 2.6355281 31.467039 0.9999324 12.622037 18.36904818 2.8940065 31.330447 1.1000351 12.590535 18.5592318 3.2793478 31.131099 1.2500411 12.545901 18.84489718 3.9159724 30.812849 1.4999945 12.478215 19.32239718 4.5456116 30.512005 1.7499901 12.418942 19.80161418 5.167862 30.228367 1.9999749 12.367984 20.28204618 5.7826943 29.961948 2.2500511 12.32545 20.76366818 6.3892726 29.712939 2.4999832 12.291415 21.24574218 6.9880236 29.481094 2.7500524 12.265939 21.72857118 7.578077 29.266841 3.0000066 12.249254 22.21149818 8.1594587 29.070101 3.2499574 12.241466 22.69450918 8.7321623 28.891086 3.5000201 12.242869 23.17770518 9.2955335 28.730249 3.7500302 12.253789 23.66065818 9.8493738 28.587915 4.000022 12.274585 24.14333118 10.393466 28.464366 4.250021 12.305599 24.62564918 10.927354 28.360458 4.4999803 12.347511 25.10758318 11.45106 28.276585 4.7500594 12.400834 25.58935318 11.963706 28.213678 5.0000208 12.466266 26.07054518 12.954931 28.154346 5.4999623 12.636903 27.03210418 13.897441 28.192081 5.9999714 12.86803 27.99348118 14.78604 28.340659 6.5000236 13.171753 28.95636918 15.613307 28.619951 6.9998885 13.565496 29.92328218 16.369798 29.060151 7.499986 14.076205 30.89987318 17.038778 29.710996 7.9999726 14.74816 31.89427718 17.591991 30.663267 8.5000263 15.663697 32.92362518 17.966205 32.123996 8.9999899 17.013192 34.02820318 17.915975 34.93301 9.4999407 19.583352 35.3824818 0 41.487526 0 18.741794 20.74376318 0.0232713 41.465127 0.0099438 18.731954 20.75583518 0.1170027 41.375433 0.0499983 18.692725 20.80471918 0.2339894 41.263604 0.0999986 18.643846 20.86579118 0.467913 41.041061 0.200008 18.546904 20.98844418 0.7017723 40.819738 0.3000347 18.45084 21.11164118 0.935347 40.59985 0.3999906 18.355745 21.23527218 1.1688574 40.381145 0.4999753 18.26149 21.3594318 1.4023004 40.16371 0.5999942 18.168136 21.48415618 1.6354562 39.947719 0.6999588 18.075741 21.60931618 1.868548 39.732919 0.7999702 17.984178 21.73500718 2.1013537 39.519404 0.8999372 17.893447 21.86105618 2.3340895 39.30717 0.9999611 17.803605 21.98767518 2.5667572 39.096056 1.1000459 17.714526 22.11478518 2.9148729 38.782047 1.2499701 17.582528 22.30589618 3.4943486 38.264756 1.5000636 17.366527 22.62672718 4.0718667 37.75539 1.7500301 17.155426 22.949562

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18 4.6474234 37.253747 1.9999372 16.949022 23.27429718 5.2212281 36.759602 2.2499489 16.747167 23.60102918 5.7930706 36.272828 2.5000347 16.549666 23.92948518 6.3625083 35.793593 2.7500608 16.356479 24.25930518 6.9293212 35.321694 2.9999764 16.167365 24.59016818 7.4939391 34.856932 3.2500415 15.982271 24.92240518 8.0557193 34.399358 3.5000062 15.80103 25.25539818 8.6148698 33.948741 3.7500157 15.62351 25.5892418 9.1711964 33.504973 4.0000211 15.449561 25.92368318 9.7244513 33.068146 4.2499554 15.279168 26.25852418 10.274861 32.637905 4.4999579 15.112119 26.59381418 10.822425 32.214259 4.7500791 14.948408 26.92955518 11.366507 31.797249 5.0000363 14.787891 27.26513218 12.445068 30.982286 5.4999947 14.476016 27.93621118 13.510313 30.192425 5.9999775 14.17597 28.60652518 14.561826 29.426948 6.4999832 13.887121 29.27529918 15.599231 28.685 6.9999764 13.608768 29.94173218 16.622245 27.966308 7.5000073 13.340672 30.60539918 17.630509 27.270043 7.9999833 13.082196 31.2655318 18.623984 26.595805 8.5000283 12.833098 31.92188618 19.602293 25.943131 9.0000304 12.593025 32.57385818 20.565425 25.311469 9.5000626 12.361657 33.22115918 21.512973 24.700519 9.9999673 12.138774 33.86323318 22.445355 24.109538 10.500017 11.924029 34.50012418 23.362144 23.538619 11.000082 11.717495 35.13145318 24.263145 22.987059 11.499999 11.518733 35.75667418 25.148549 22.454724 11.999973 11.327801 36.37591118 26.018388 21.941136 12.500018 11.144483 36.98895618 26.872435 21.446175 13.000029 10.968765 37.59552318 27.710622 20.969557 13.499965 10.800558 38.19540118 28.533306 20.510907 14.000066 10.639799 38.78875918 29.340093 20.070034 14.500047 10.486404 39.3751118 30.131134 19.646765 15.000029 10.340422 39.95451618 30.906458 19.24081 15.500003 10.201792 40.52686318 31.666097 18.852009 15.99999 10.070555 41.09210118 32.410155 18.480123 16.500045 9.94671 41.65021718 33.138496 18.125008 17.000042 9.8302819 42.20118 33.851224 17.786419 17.500015 9.721273 42.74443318 34.54845 17.464195 18.000031 9.6197512 43.28054718 35.230078 17.158142 18.499955 9.5257223 43.80914918 35.896478 16.868031 19.000057 9.4392619 44.33049318 36.547374 16.593731 19.500045 9.3603928 44.84423918 37.182992 16.335031 20.000058 9.2891817 45.35050818 38.40854 15.86361 20.999962 9.1698727 46.34034518 39.574129 15.452154 22.00007 9.081808 47.30020618 40.680155 15.098995 22.999957 9.025329 48.22965318 41.727963 14.802234 23.999988 9.0008118 49.1290818 42.718503 14.559915 25.000011 9.0085233 49.99846118 43.652949 14.370004 25.999992 9.0487189 50.83795118 44.532818 14.230189 27.000057 9.121489 51.64791218 45.359425 14.13822 28.000047 9.2269157 52.42853518 46.134445 14.091603 29.000004 9.3649126 53.18024618 46.859743 14.087724 30.000065 9.535286 53.90360518 47.536903 14.124019 30.99993 9.7377517 54.598912

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18 48.168226 14.197734 32.000098 9.9719545 55.26709318 48.755256 14.306208 32.999948 10.237335 55.9083618 49.300384 14.446669 33.999965 10.533349 56.52371818 49.805541 14.616451 34.999958 10.859314 57.11376618 50.272858 14.812855 35.999949 11.214442 57.67928518 50.70447 15.033326 37.000062 11.597967 58.22113318 51.102203 15.275404 37.999903 12.008981 58.73990518 51.468369 15.53661 38.9999 12.446577 59.23667418 51.804863 15.814685 39.999919 12.909805 59.71220518 52.113655 16.107467 41.000058 13.397716 60.16738918 52.396422 16.412975 42.000007 13.909311 60.6029118 52.655041 16.729244 42.99986 14.443551 61.01966318 52.891381 17.054559 44.00006 14.999592 61.41866118 53.106812 17.387337 45.000109 15.576396 61.8004818 53.302924 17.726062 46.000107 16.173002 62.16595518 53.481135 18.069385 46.999992 16.78847 62.51582818 53.642942 18.416087 48.00015 17.421997 62.85098618 53.789339 18.765035 48.999828 18.072503 63.17185618 53.921818 19.115292 49.999952 18.739439 63.47946418 51.758262 0 26.82429 0 51.75826218 51.747322 0.018248 26.822684 0.01 51.75644618 51.703818 0.0911845 26.816497 0.0500001 51.7494118 51.649449 0.1822299 26.808695 0.1000001 51.74056418 51.541846 0.3638999 26.794044 0.2000004 51.72379618 51.435265 0.5450016 26.780134 0.2999992 51.70776618 51.330064 0.7255311 26.767349 0.4000002 51.69282918 51.225853 0.9054806 26.755272 0.4999999 51.67859418 51.122891 1.0848447 26.744181 0.6000011 51.66531418 51.020937 1.2636175 26.733816 0.7000011 51.65274618 50.920205 1.4417872 26.724405 0.7999994 51.64109918 50.820542 1.6193583 26.715791 0.8999995 51.63022118 50.722163 1.7963192 26.708203 1.0000023 51.62032318 50.624777 1.9726632 26.701326 1.1000014 51.61110918 50.480951 2.236008 26.692769 1.2500001 51.59895518 50.246676 2.6717826 26.682601 1.5000043 51.58256718 50.019384 3.1035239 26.677748 1.7499938 51.57114618 49.799106 3.5312057 26.678299 2.0000009 51.56470918 49.58527 3.954756 26.683649 2.2500015 51.56264818 49.378223 4.3740886 26.694201 2.4999978 51.56526718 49.177838 4.7891704 26.709867 2.750003 51.57242318 48.983801 5.1999513 26.730339 3.000004 51.58377718 48.796193 5.6063847 26.75575 3.2500098 51.59938518 48.614846 6.0084183 26.785957 3.5000076 51.61905518 48.439547 6.406038 26.820776 3.7500009 51.64256618 48.270281 6.7992202 26.860252 3.9999996 51.66989118 48.106838 7.1879436 26.904201 4.249996 51.7008118 47.949254 7.5721829 26.952721 4.4999991 51.73534618 47.797357 7.9519117 27.005668 4.7499952 51.77331318 47.651084 8.3271361 27.063047 5.0000016 51.81465218 47.37444 9.0640719 27.190229 5.5000002 51.90647518 47.118476 9.7829772 27.333806 5.9999896 52.00996518 46.88232 10.483948 27.493324 6.5000035 52.12429418 46.664925 11.167086 27.668089 7.0000162 52.24846818 46.465212 11.83256 27.857373 7.5000044 52.381492

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18 46.282476 12.480579 28.0609 8.000006 52.52276518 46.115581 13.111395 28.277841 8.4999826 52.67127818 45.963913 13.725319 28.508044 9.0000198 52.82657318 45.826257 14.322606 28.750485 9.4999959 52.9875618 45.702194 14.90359 29.005214 10.000011 53.15398918 45.590578 15.468617 29.271277 10.499984 53.32488618 45.490757 16.018091 29.548386 10.999981 53.49980318 45.402135 16.552354 29.836257 11.500015 53.67831218 45.323822 17.071756 30.134161 12.000003 53.859718 45.255095 17.576766 30.441649 12.500007 54.04347918 45.195436 18.067723 30.758438 13.000011 54.22929818 45.144041 18.545043 31.083845 13.499967 54.41656318 45.100555 19.009153 31.417845 13.999994 54.60513218 45.064306 19.460405 31.759834 14.5 54.79450818 45.034712 19.899218 32.10937 14.999991 54.98432118 45.011319 20.326013 32.466184 15.500021 55.17432618 44.993535 20.741145 32.829692 16.000001 55.36410718 44.981037 21.144994 33.199755 16.499985 55.55353418 44.973265 21.538002 33.575865 16.999995 55.74226718 44.969979 21.920438 33.957873 17.499982 55.93019818 44.970656 22.29274 34.345282 17.999975 56.11702618 44.97493 22.655274 34.737778 18.499987 56.30256718 44.98261 23.008324 35.135258 19.00002 56.48677218 44.99311 23.352265 35.536964 19.499968 56.66924218 45.006489 23.687403 35.943268 20.000021 56.85019118 45.040124 24.332518 36.767284 21.000015 57.20638318 45.08145 24.946074 37.605101 21.999948 57.55448718 45.129065 25.530297 38.455484 23.00003 57.89421418 45.181392 26.087186 39.316422 24.000052 58.22498518 45.237069 26.618731 40.186208 25.000028 58.54643418 45.2955 27.126519 41.064268 26.000019 58.8587618 45.355779 27.61216 41.949324 26.999971 59.16185918 45.417003 28.077269 42.840075 27.999946 59.45563718 45.478987 28.522984 43.736283 28.999908 59.74047918 45.541189 28.950665 44.637203 30.000033 60.01652218 45.603048 29.361419 45.541624 31.00004 60.28375718 45.664759 29.756039 46.449911 31.999959 60.54277818 45.725975 30.135631 47.361569 33.000002 60.7937918 45.786336 30.501113 48.275759 34.000045 61.03689318 45.846165 30.852979 49.192923 34.99994 61.27265418 45.905041 31.192271 50.112424 36.000009 61.50117618 45.963091 31.519487 51.034287 37.00007 61.72283518 46.020328 31.835144 51.958282 37.999901 61.937918 46.076885 32.139881 52.884968 38.999944 62.14682518 46.132532 32.434313 53.813678 40.000063 62.34968818 46.187433 32.718736 54.744421 40.999933 62.54680118 46.241771 32.99363 55.677844 41.999936 62.73858618 46.295402 33.259418 56.613292 42.999735 62.92511118 46.348511 33.516613 57.551722 44.000057 63.10681718 46.40121 33.765277 58.49263 45.000024 63.28384818 46.453286 34.006012 59.435753 45.999978 63.45629218 46.505074 34.238974 60.381909 46.999995 63.62456118 46.556383 34.46463 61.330667 48.000158 63.78869818 46.60759 34.682937 62.282579 49.000035 63.949058

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18 46.658558 34.894349 63.237524 49.999911 64.10573225 0 35.586434 0 14.603239 17.79321725 0.025743 35.569714 0.0099934 14.598423 17.810625 0.1287051 35.503361 0.0499917 14.579478 17.88038625 0.2571673 35.421261 0.099961 14.556248 17.96779825 0.5137999 35.25971 0.2000098 14.51131 18.14365525 0.76946 35.102138 0.2999902 14.468557 18.32052925 1.0243651 34.948175 0.4 14.427806 18.49845225 1.2782993 34.797901 0.4999671 14.389064 18.6772525 1.5314738 34.651348 0.5999893 14.352403 18.85714825 1.7836754 34.508464 0.699994 14.317747 19.03790725 2.0349048 34.369254 0.7999943 14.285106 19.21953225 2.285156 34.233623 0.8999991 14.254424 19.40196825 2.5342152 34.101856 0.9999376 14.225843 19.58514325 2.7825146 33.973504 1.0999925 14.199178 19.76926625 3.1526995 33.787863 1.2499827 14.162917 20.04663125 3.764201 33.496581 1.5000481 14.112484 20.51249225 4.3678504 33.22815 1.7499548 14.074592 20.98192525 4.9638551 32.982403 1.999966 14.049355 21.45505725 5.551577 32.759554 2.2499924 14.036966 21.93135425 6.1305443 32.560127 2.5000228 14.037883 22.41060825 6.7001179 32.384568 2.7499668 14.052503 22.89240225 7.2602861 32.233406 3.0000229 14.081458 23.37698925 7.8099611 32.107652 3.2499239 14.125487 23.86378725 8.3493333 32.008057 3.4999888 14.185503 24.35336225 8.877314 31.93612 3.7499885 14.262678 24.84537425 9.3934576 31.893364 4.0000128 14.358425 25.3401425 9.8968365 31.882032 4.2499836 14.474629 25.83785325 10.386782 31.904613 4.4999939 14.613525 26.33908825 10.862193 31.964308 4.7500067 14.777896 26.84434725 11.321893 32.065266 5.0000642 14.971385 27.35452625 12.186526 32.415482 5.499933 15.466802 28.39426725 12.961549 33.028524 6.0000492 16.164328 29.47581125 13.603369 34.072162 6.4999966 17.212222 30.6394525 13.958401 36.187138 7.0000823 19.186347 32.0519725 0 42.832279 0 19.804432 21.4161425 0.0228104 42.807783 0.0099756 19.792522 21.42670225 0.1142631 42.709761 0.0499648 19.744931 21.46914325 0.2287289 42.587532 0.1000046 19.685752 21.52249525 0.457615 42.344653 0.200029 19.568694 21.62994225 0.686441 42.103536 0.2999871 19.453087 21.73820925 0.9154219 41.864098 0.3999828 19.338924 21.84747125 1.1443407 41.626389 0.4999293 19.226162 21.95753525 1.3736318 41.390237 0.600028 19.114798 22.0687525 1.6026414 41.155995 0.6999998 19.004883 22.18063925 1.8315856 40.923455 0.7999475 18.896315 22.29331325 2.0608987 40.692444 0.9000736 18.789089 22.40712125 2.2897092 40.463324 0.9999985 18.683195 22.52137125 2.5186731 40.235785 1.1000226 18.578596 22.63656625 2.8616681 39.89764 1.2499305 18.424021 22.81048825 3.433193 39.342086 1.499982 18.172546 23.10423625 4.0036344 38.796823 1.7499811 17.928571 23.40204625 4.5729756 38.261375 2.0000242 17.691616 23.70366325 5.1407804 37.735812 2.2500203 17.461505 24.008686

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25 5.7068192 37.219901 2.4999584 17.237904 24.31676925 6.2711011 36.713349 2.7499322 17.020517 24.62777525 6.8336005 36.215847 3.000013 16.809035 24.94152425 7.393677 35.727491 3.2499846 16.603281 25.25742225 7.9513219 35.248066 3.4999176 16.403041 25.57535525 8.5067432 34.777162 3.7499761 16.208018 25.89532425 9.0595287 34.31468 4.000026 16.01798 26.21686925 9.6092075 33.860696 4.2499062 15.832819 26.53955625 10.156439 33.414671 4.4999891 15.652286 26.86377525 10.700605 32.97651 4.7500145 15.476113 27.1888625 11.241654 32.546272 5.0000243 15.304309 27.5147925 12.314046 31.708428 5.4999477 14.972802 28.1682625 13.373401 30.899834 5.9999763 14.656639 28.82331825 14.418846 30.119331 6.4999176 14.354672 29.47851125 15.450421 29.365658 7.0000198 14.065956 30.1332525 16.467208 28.638151 7.5000041 13.789772 30.78628325 17.469034 27.935745 7.9999221 13.525325 31.43690725 18.455898 27.257469 8.4998991 13.271949 32.08463225 19.4276 26.602595 8.999944 13.029125 32.72889825 20.383917 25.970348 9.5000071 12.796307 33.36909125 21.324626 25.360161 10.000041 12.573117 34.00470725 22.249585 24.771354 10.499996 12.35912 34.63526225 23.158915 24.203462 11.000019 12.154113 35.26064525 24.052298 23.655835 11.499896 11.95766 35.88021625 24.930313 23.127843 12.000017 11.76955 36.49423425 25.792378 22.61918 12.500013 11.589548 37.10196725 26.638677 22.129435 13.000013 11.417527 37.70339525 27.469207 21.658239 13.50001 11.253346 38.29832725 28.284002 21.205115 13.999979 11.096799 38.88655925 29.083126 20.769746 14.499951 10.947809 39.46799925 29.866765 20.351763 15.000023 10.806284 40.04264625 30.634683 19.950933 15.499993 10.67215 40.6101525 31.387142 19.566853 15.999987 10.545312 41.17056925 32.124152 19.199338 16.499992 10.425788 41.72382125 32.845702 18.848083 16.999926 10.313504 42.26974325 33.552167 18.512772 17.50003 10.20846 42.80855325 34.243334 18.193201 18.000064 10.110619 43.33993525 34.919308 17.889114 18.500038 10.019969 43.86386425 35.580182 17.600283 18.999955 9.9365272 44.38032425 36.226266 17.326431 19.499998 9.8603129 44.88948225 36.857516 17.067319 20.00003 9.7913028 45.39117525 38.075851 16.59248 21.000006 9.6750153 46.37209125 39.236291 16.173808 22.000013 9.5877756 47.32319625 40.339761 15.809513 23.00001 9.5297996 48.24451725 41.387365 15.497663 23.999996 9.5012378 49.13619625 42.380295 15.236272 24.999961 9.5022106 49.99843125 43.319798 15.02342 25.999931 9.5329024 50.83150725 44.207308 14.857011 26.999986 9.5933763 51.63581325 45.044092 14.734993 27.999958 9.6836716 52.41158825 45.831844 14.655169 29.000065 9.8037683 53.15942925 46.571795 14.615399 29.999874 9.9535434 53.87949425 47.266086 14.613409 31.000057 10.132928 54.5727925 47.915959 14.647028 32.000038 10.341663 55.23947325 48.523254 14.71397 32.999938 10.579464 55.880239

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25 49.08991 14.811972 34.000019 10.846019 56.49589625 49.617486 14.938834 34.999951 11.140892 57.08690325 50.107968 15.092321 36.000013 11.463639 57.65412925 50.563055 15.270302 37.000066 11.81374 58.19820625 50.984554 15.470675 38.000148 12.19064 58.71989225 51.374144 15.691403 39.000093 12.593702 59.21984625 51.733677 15.930474 40.000054 13.022264 59.69891425 52.064769 16.18606 40.999923 13.475684 60.15779925 52.36919 16.456367 41.999937 13.953313 60.59737325 52.648538 16.739656 43.00004 14.454386 61.01836625 52.90418 17.034349 43.999855 14.978123 61.42135425 53.137898 17.338909 45.000002 15.523889 61.80735225 53.350917 17.651979 46.000098 16.090919 62.17690625 53.544639 17.972187 47.000137 16.67841 62.53073325 53.720203 18.298356 47.999759 17.285584 62.86938125 53.879235 18.629317 48.999913 17.91189 63.19389425 54.022693 18.964041 50.000071 18.556492 63.50471325 52.952537 0 28.139868 0 52.95253725 52.941802 0.0177962 28.138386 0.01 52.950725 52.899473 0.088927 28.133114 0.0500001 52.94393725 52.846597 0.1777175 28.126481 0.0999998 52.93545625 52.74191 0.3548868 28.114142 0.1999998 52.91935325 52.638382 0.5315014 28.102748 0.3 52.90413325 52.536127 0.7075515 28.092424 0.3999998 52.88990225 52.434899 0.8830324 28.082893 0.4999984 52.87641625 52.335006 1.0579392 28.074506 0.5999998 52.86397625 52.236106 1.232263 28.066872 0.6999986 52.85223825 52.138506 1.4059975 28.060343 0.7999992 52.84150525 52.042011 1.5791396 28.054698 0.9000003 52.83158125 51.94673 1.7516782 28.050059 1.0000011 52.82256925 51.852567 1.9236107 28.046321 1.1000018 52.81437225 51.71337 2.1803609 28.042347 1.2500014 52.8035525 51.486952 2.6051725 28.040224 1.5000003 52.78953825 51.267605 3.0260205 28.043857 1.7499964 52.78061525 51.055145 3.4428613 28.053082 2.0000054 52.77657525 50.849297 3.8556048 28.067597 2.2500044 52.77709925 50.650126 4.2642036 28.087526 2.5000084 52.78222725 50.457459 4.6685857 28.112698 2.7500023 52.79175225 50.271089 5.0687246 28.142927 2.999993 52.80545225 50.091019 5.4646009 28.178282 3.2500023 52.82331925 49.917147 5.8561316 28.218668 3.500001 52.84521325 49.749098 6.2433368 28.263722 3.7500019 52.87076625 49.587035 6.6261678 28.31369 4.0000123 52.90011925 49.430588 7.0046 28.368177 4.2500063 52.93288825 49.279783 7.3786357 28.427295 4.5000091 52.96910125 49.134335 7.7482424 28.490744 4.7499877 53.00845725 48.994262 8.1134771 28.558657 5.0000017 53.05125 48.729496 8.8306758 28.707131 5.4999963 53.14483425 48.484402 9.530311 28.87197 6.0000107 53.24955825 48.257679 10.212466 29.052099 6.499984 53.36391225 48.048712 10.877338 29.247367 7.0000031 53.48738125 47.856216 11.525105 29.456698 7.4999986 53.61876825 47.679152 12.156071 29.679369 7.9999994 53.75718725 47.516956 12.770431 29.915181 8.5000047 53.902171

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25 47.368413 13.368546 30.16313 8.9999963 54.05268625 47.232855 13.950725 30.422872 9.4999951 54.20821725 47.109198 14.517359 30.693502 9.9999753 54.36787725 46.996962 15.06879 30.974893 10.499993 54.53135825 46.895236 15.605411 31.266297 11.000021 54.69794225 46.803227 16.12758 31.567062 11.500008 54.86701725 46.720436 16.635712 31.876987 12.00003 55.03829225 46.646028 17.13018 32.195283 12.500002 55.21111825 46.579501 17.611434 32.521708 13.000014 55.38521825 46.520215 18.079836 32.855689 13.500006 55.56013325 46.467666 18.53581 33.196894 14.000023 55.73557125 46.421267 18.979714 33.544761 14.499998 55.91112425 46.380634 19.411954 33.899084 14.999995 56.08661125 46.345072 19.832962 34.259121 15.499969 56.26155325 46.314483 20.243051 34.62502 15.999991 56.43600925 46.288186 20.642626 34.995977 16.499983 56.60949925 46.265997 21.032038 35.371996 17.000026 56.78201625 46.247319 21.411655 35.752323 17.500019 56.95314625 46.232017 21.781782 36.136965 18.000013 57.12290825 46.219586 22.142798 36.5253 18.499962 57.29098525 46.209983 22.494993 36.917477 18.999958 57.45747925 46.202865 22.838678 37.313079 19.49996 57.62220425 46.198017 23.174196 37.711968 20.000052 57.78511525 46.193903 23.821677 38.517713 20.999973 58.10474125 46.196178 24.439742 39.333368 21.99998 58.41604925 46.203661 25.030316 40.157628 23.000039 58.71881925 46.215134 25.595282 40.988974 24.000115 59.01277525 46.229632 26.13627 41.826031 25.000023 59.29776825 46.246772 26.654763 42.668584 25.999932 59.57415325 46.265722 27.152431 43.515671 27.000117 59.84193725 46.28597 27.63029 44.366073 27.999975 60.10111525 46.307493 28.089652 45.220397 29.000137 60.35231925 46.329815 28.531422 46.077421 30.000023 60.59552625 46.352787 28.956675 46.937158 30.999894 60.83112425 46.376262 29.366411 47.799603 32.000002 61.05946725 46.400185 29.761341 48.664555 33.000165 61.28085525 46.424563 30.142076 49.531873 34.000137 61.49560125 46.449144 30.509481 50.401193 35.000037 61.70388425 46.474258 30.86402 51.273274 35.99993 61.90626825 46.499688 31.20653 52.148016 37.000178 62.10295325 46.525454 31.53723 53.024751 37.999873 62.29406925 46.551906 31.85677 53.90508 38.999995 62.48029125 46.578717 32.165654 54.787951 40.000048 62.66154425 46.605941 32.464296 55.673493 40.99999 62.83808925 46.633984 32.752905 56.562745 41.99991 63.01043725 46.662749 33.031974 57.455672 42.999924 63.17873625 46.692166 33.301901 58.35213 43.999962 63.34311725 46.722409 33.562874 59.252432 44.999809 63.50384625 46.753504 33.815311 60.157027 45.999823 63.66115925 46.785529 34.05944 61.0661 46.999878 63.81524925 46.818621 34.295494 61.980171 48.000063 63.96636825 46.852698 34.523727 62.898899 49.00007 64.11456125 46.88791 34.744299 63.82274 49.999851 64.2600630 0 38.237328 0 16.36453 19.118664

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30 8.9774642 34.908662 3.9999534 16.443907 26.43179530 9.5255257 34.438067 4.2500121 16.244658 26.74455930 10.070656 33.977132 4.4999947 16.051349 27.05922230 10.612886 33.525379 4.7499668 15.863586 27.37557630 11.152205 33.082589 4.9999873 15.681162 27.69349930 12.221422 32.223042 5.5000408 15.331381 28.33294330 13.277441 31.396769 6.0000965 15.000281 28.97582530 14.319384 30.602205 6.5000161 14.686334 29.62048630 15.347057 29.837634 6.9999467 14.388138 30.26587430 16.360218 29.101632 7.4999814 14.104543 30.91103430 17.358232 28.393037 7.9999525 13.834528 31.55475130 18.341117 27.710488 8.4999968 13.577122 32.19636130 19.308431 27.053164 9.0000026 13.331662 32.83501330 20.259938 26.420038 9.4999054 13.097403 33.46995730 21.195939 25.810019 9.9999337 12.873699 34.10094930 22.116397 25.222238 10.500108 12.659997 34.72751630 23.0205 24.656331 10.999988 12.455939 35.34866530 23.909088 24.111251 11.500086 12.26107 35.96471430 24.781524 23.586579 12.000005 12.07505 36.57481430 25.638128 23.081581 12.499922 11.897539 37.17891830 26.47926 22.595558 13.000042 11.728232 37.77703930 27.304343 22.128321 13.49998 11.566993 38.36850330 28.113902 21.679261 14.000056 11.413627 38.95353330 28.907761 21.247895 14.500068 11.267877 39.53170830 29.685985 20.833812 15.000008 11.129594 40.10289130 30.448824 20.436682 15.500023 10.998736 40.66716530 31.196205 20.056064 15.999958 10.875103 41.22423730 31.928401 19.691637 16.499969 10.758665 41.77421930 32.645398 19.343115 16.999976 10.649355 42.31695530 33.347424 19.010108 17.500059 10.547084 42.85247730 34.034277 18.692366 17.999962 10.451771 43.3804630 34.706504 18.38953 18.500045 10.363421 43.90126930 35.36378 18.101404 18.999938 10.28197 44.41448230 36.006615 17.827654 19.499976 10.207434 44.92044230 36.634947 17.56806 20.000005 10.139789 45.41897730 37.848703 17.090225 21.000082 10.025091 46.39381630 39.006011 16.665816 22.000027 9.9377675 47.33891930 40.108171 16.292894 23.000034 9.8778958 48.25461830 41.156269 15.969564 24.000031 9.8455375 49.14105130 42.151536 15.693869 24.999999 9.8407269 49.99847130 43.095238 15.463834 25.999878 9.8634713 50.82715530 43.98901 15.27758 27.000071 9.9139308 51.627830 44.833764 15.133193 28.000004 9.9920371 52.4003630 45.631181 15.028716 28.999981 10.097839 53.14553930 46.382782 14.962137 30.000031 10.23126 53.86385130 47.089998 14.931537 31.000076 10.39224 54.55576630 47.754355 14.934912 32.000053 10.580616 55.22181130 48.37747 14.970292 33.000016 10.796223 55.86261630 48.960911 15.035719 33.999916 11.038832 56.47877130 49.506424 15.129254 34.999974 11.30822 57.07105130 50.015461 15.249024 35.99996 11.604071 57.63997230 50.489765 15.393122 37.000073 11.926047 58.18632630 50.930799 15.559734 38.000075 12.273735 58.71066630 51.340143 15.747111 38.999986 12.646748 59.213699

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30 47.732987 16.319539 33.19875 12.000009 55.89275630 47.648259 16.808389 33.516615 12.499994 56.05245430 47.570459 17.28472 33.841336 12.999992 56.21281930 47.499209 17.748844 34.172655 13.499976 56.3736330 47.433871 18.201239 34.510011 14.000001 56.5344930 47.374053 18.642217 34.853066 14.50002 56.69516130 47.319096 19.072206 35.201102 15.000002 56.85519930 47.268656 19.491581 35.553867 15.499984 57.01444730 47.222538 19.900656 35.911306 15.999995 57.17286630 47.180147 20.299857 36.272734 16.500023 57.33007530 47.141325 20.689401 36.638022 16.999992 57.48602530 47.105566 21.069779 37.006672 17.500013 57.64045630 47.07277 21.441183 37.378607 18.000007 57.79336130 47.042618 21.803972 37.753515 18.500015 57.94460430 47.014697 22.158498 38.130862 19.000012 58.09394630 46.989076 22.504955 38.510891 19.500036 58.24155330 46.965354 22.843651 38.893021 20.000008 58.3871830 46.923153 23.498834 39.663376 21.000004 58.6725730 46.886729 24.126069 40.440371 21.999982 58.94976330 46.855217 24.727123 41.223147 22.999975 59.21877930 46.827514 25.30379 42.010316 23.999987 59.47940930 46.803414 25.857384 42.801916 25.000048 59.73210630 46.781945 26.38942 43.596458 26.000001 59.97665530 46.762899 26.90121 44.394065 27.000132 60.21350430 46.745976 27.393717 45.194132 28.000087 60.44283430 46.730779 27.868139 45.996237 28.999989 60.66484930 46.717311 28.325401 46.800657 29.999966 60.88001230 46.70563 28.766312 47.607739 31.0001 61.08878630 46.695239 29.191746 48.41641 32.000049 61.29111230 46.686396 29.602365 49.22748 33.000023 61.48757930 46.679039 29.998865 50.040981 34.000031 61.67847130 46.672992 30.381963 50.856707 35.000077 61.86397430 46.668501 30.752029 51.675135 35.999969 62.04451630 46.665459 31.109813 52.496527 37.00011 62.22036530 46.663984 31.455598 53.320929 38.000072 62.39178330 46.664115 31.78992 54.148767 39.000085 62.55907530 46.665818 32.113213 54.980054 40.000058 62.72242430 46.669236 32.425802 55.815241 40.99996 62.88213730 46.674394 32.728109 56.654673 41.999927 63.03844930 46.681435 33.020451 57.498964 43.000093 63.19166130 46.690337 33.303077 58.34794 44.000079 63.34187630 46.701225 33.576249 59.202116 44.999918 63.48934930 46.714089 33.840415 60.06208 46.000096 63.63429730 46.728967 34.095713 60.92774 47.00015 63.77682430 46.745947 34.342353 61.799489 48.000034 63.91712330 46.765346 34.580471 62.678621 49.000078 64.05558230 46.78686 34.810433 63.564359 49.999974 64.19207650 0 52.638823 0 29.378239 26.31941250 0.0189267 52.573189 0.0099815 29.3127 26.30552150 0.0950646 52.313959 0.049942 29.055948 26.25204450 0.1912063 51.996249 0.0999843 28.745657 26.18933150 0.3858564 51.381261 0.200011 28.158117 26.07648750 0.5832953 50.791399 0.2999146 27.610222 25.97899550 0.7839461 50.224283 0.4000687 27.097716 25.896088

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50 37.634585 19.595821 22.000042 12.110733 47.43249650 38.700924 19.229736 22.999963 12.082303 48.31579250 39.723588 18.894603 23.999958 12.068974 49.17088950 40.704716 18.587505 24.999931 12.069402 49.99846850 41.646603 18.305645 25.999975 12.082282 50.79942550 42.551329 18.046419 26.999988 12.106318 51.57453850 43.421065 17.807352 28.000026 12.140257 52.32474150 44.257836 17.586069 28.999983 12.182794 53.0508750 45.063812 17.380334 30.000036 12.232706 53.75397850 45.840896 17.188126 31.00014 12.288805 54.43495950 46.590779 17.007519 31.999986 12.349841 55.09453950 47.3155 16.836739 32.999921 12.414751 55.7338750 48.016725 16.674264 33.999966 12.482547 56.35385750 48.695925 16.518638 34.999888 12.552171 56.95524450 49.354706 16.368605 35.999892 12.622776 57.53900850 49.994438 16.223067 36.999978 12.693556 58.10597150 50.61627 16.081097 37.999954 12.763776 58.65681950 51.221456 15.941816 38.999904 12.832758 59.19236450 51.811088 15.804527 39.999867 12.899947 59.71335150 52.386232 15.668674 41.00006 12.96493 60.22056950 52.947572 15.533745 42.000018 13.027173 60.71444450 53.496069 15.399339 43.000041 13.086384 61.19573950 54.032368 15.265165 43.999955 13.142268 61.66495150 54.557281 15.130904 44.999975 13.194563 62.12273350 55.071246 14.996475 45.999871 13.243155 62.56948450 55.574973 14.861686 46.999934 13.287909 63.00581650 56.068875 14.726465 47.999995 13.32872 63.43210850 56.553349 14.590778 48.999947 13.365534 63.84873850 57.028946 14.454628 50.000202 13.39843 64.2562650 59.015073 0 36.000645 0 59.01507350 59.006146 0.0155029 36.000975 0.01 59.01389750 58.970727 0.0774642 36.002685 0.05 59.00945950 58.926654 0.1548022 36.005025 0.0999998 59.00405650 58.838924 0.309101 36.010004 0.1999998 58.99347550 58.752137 0.4628927 36.015961 0.3000007 58.98358350 58.665922 0.6161723 36.022343 0.3999989 58.97400850 58.580639 0.7689426 36.029694 0.5000011 58.9651150 58.496065 0.9211929 36.037675 0.6 58.95666250 58.412135 1.0729277 36.046193 0.6999989 58.94859950 58.329042 1.2241421 36.05554 0.7999992 58.94111350 58.246695 1.3748382 36.065583 0.9000028 58.93411450 58.164872 1.5250067 36.075983 0.9999994 58.92737650 58.084072 1.6746467 36.087496 1.100002 58.92139550 57.963858 1.8981194 36.105454 1.2499989 58.91291850 57.767275 2.2679202 36.138962 1.5000031 58.90123550 57.574827 2.634382 36.176085 1.7500008 58.89201850 57.386538 2.9974925 36.216897 1.9999995 58.88528550 57.202319 3.3572468 36.261307 2.2500059 58.88094350 57.021956 3.713612 36.309 2.4999958 58.87876250 56.84542 4.0666148 36.360004 2.7499959 58.87872850 56.672627 4.4162405 36.414216 2.9999977 58.88074750 56.503536 4.7624843 36.471615 3.2500011 58.88477850 56.337844 5.1053733 36.531788 3.500006 58.8905350 56.175457 5.4449035 36.594618 3.7500009 58.897908

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50 56.016418 5.7810786 36.660215 3.9999921 58.90695750 55.860521 6.1139448 36.728328 4.2499936 58.91749450 55.707709 6.4434939 36.79889 4.4999887 58.92945650 55.557882 6.7697829 36.871826 4.7500073 58.94277450 55.410797 7.0927914 36.946746 4.9999949 58.95719350 55.124969 7.7291573 37.103021 5.5000121 58.98954750 54.849294 8.3528048 37.266575 6.0000015 59.02569650 54.583236 8.9639952 37.436933 6.4999973 59.06523450 54.325894 9.5630451 37.613013 6.9999998 59.10741650 54.076828 10.150209 37.79443 7.5000151 59.15193350 53.83513 10.725796 37.979995 7.9999865 59.19802850 53.600519 11.290158 38.169638 8.5000142 59.24559850 53.372232 11.843557 38.362306 8.9999914 59.2940150 53.149829 12.386381 38.55763 9.4999971 59.34301950 52.93281 12.918919 38.754998 9.9999891 59.39226950 52.720808 13.44151 38.954081 10.500006 59.44156450 52.513365 13.954459 39.154314 11.000017 59.49059550 52.310103 14.458043 39.355234 11.499978 59.53912450 52.110639 14.952669 39.556506 11.999988 59.58697450 51.91485 15.438525 39.758027 12.499988 59.63411350 51.722276 15.915981 39.95924 13.000007 59.68026650 51.532769 16.385266 40.160029 13.500027 59.72540250 51.345926 16.84668 40.359837 14.000009 59.76926650 51.161612 17.300488 40.558599 14.499989 59.81185650 50.979792 17.746884 40.75637 14.999961 59.85323350 50.800152 18.186221 40.952832 15.50001 59.89326250 50.62258 18.61861 41.147764 15.999993 59.93188550 50.446997 19.044326 41.341235 16.500014 59.9691650 50.273162 19.463568 41.532861 16.99999 60.00494650 50.101036 19.876531 41.722691 17.499948 60.03930150 49.93057 20.283391 41.910735 17.999892 60.07226650 49.761628 20.684442 42.09697 18.499955 60.10384950 49.594249 21.079723 42.281421 19.000006 60.13411150 49.428232 21.469428 42.463781 19.500001 60.16294650 49.263548 21.853772 42.644173 20.000046 60.19043450 48.938194 22.606738 42.999144 21.000051 60.24156350 48.617958 23.339704 43.346496 22.000026 60.2878150 48.302635 24.053639 43.686347 22.999918 60.32945450 47.992079 24.749667 44.019289 24.000119 60.36691250 47.686441 25.428142 44.345508 24.999996 60.40051250 47.385569 26.0901 44.665598 26.000002 60.43061950 47.08951 26.7361 44.979963 26.999987 60.4575650 46.798276 27.366731 45.28903 27.999912 60.48164250 46.5121 27.982528 45.5938 28.999958 60.50336450 46.231013 28.583897 45.89458 29.999914 60.52296250 45.954927 29.171452 46.191766 30.999958 60.54065350 45.684065 29.745507 46.486143 32.000056 60.55681850 45.418382 30.306455 46.77793 33.000085 60.5716150 45.158068 30.854511 47.067736 33.999866 60.58532450 44.903065 31.390331 47.356342 35.000047 60.59823150 44.653469 31.913924 47.643767 35.999932 60.61043150 44.409176 32.425859 47.930565 37.000015 60.62210550 44.170375 32.926262 48.217349 38.000145 60.63350650 43.936938 33.415395 48.50403 39.000054 60.644636

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50 43.708828 33.89364 48.791087 40.000012 60.65564850 43.486052 34.361212 49.078821 40.999937 60.66665850 43.268555 34.81844 49.367592 42.000015 60.67777550 43.056426 35.265413 49.65775 43.000016 60.68913250 42.849344 35.702529 49.948941 43.999899 60.70060850 42.64764 36.12991 50.24247 45.000096 60.71259550 42.450776 36.547871 50.537047 45.9999 60.72471250 42.259016 36.95664 50.834032 47.000041 60.73733650 42.072098 37.356432 51.132888 48.000099 60.75031450 41.890058 37.747406 51.434034 49.00014 60.76376150 41.712708 38.129823 51.737315 50.000099 60.77762

0 0 00 100 50

100 0 10068.945658 0 55.508065 0 68.945658

0 51.219208 0 27.754033 25.609604

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0 5 10 15 20 25 30-40

-30

-20

-10

0

10

20

30

40

50

60 Banus 1954James and Wallbridge 1970Jensen 1954Merck Index 1989Mikheeva and Breitzis 1960Mikheeva and Breitzis 1960aSaldin et al. 1983Stockmayer et al. 1955Column AColumn AColumn A

m NaBH4

t/C

0 5 10 15 20 25 30 35 40 450

5

10

15

20

25 Column E Column E

Column E Column E

Column E Column E

Column E Column E

Column E Column E

Column E Column E

Column E

m NaOH

m N

aBH

4

0 10 20 30 40 50-40

-30

-20

-10

0

10

20

30

40

50

60 Banus 1954James and Wallbridge 1970Jensen 1954Merck Index 1989Mikheeva and Breitzis 1960Mikheeva and Breitzis 1960aSaldin et al. 1983Stockmayer et al. 1955Column AColumn AColumn A

w% NaBH4

t/C

0 10 20 30 40 50 600

5

10

15

20

25

30

35

40

45 Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C

w% NaOH

w%

NaB

H4

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Politerma rastvorimosti sistemy NaBH4 – H2O i izotermy rastvorimosti sistemy NaBH4 – NaOH – H2O pri 0; 18; 30 i 50°

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0 5 10 15 20 25 30-40

-30

-20

-10

0

10

20

30

40

50

60 Banus 1954James and Wallbridge 1970Jensen 1954Merck Index 1989Mikheeva and Breitzis 1960Mikheeva and Breitzis 1960aSaldin et al. 1983Stockmayer et al. 1955Column AColumn AColumn A

m NaBH4

t/C

0 5 10 15 20 25 30 35 40 450

5

10

15

20

25 Column E Column E

Column E Column E

Column E Column E

Column E Column E

Column E Column E

Column E Column E

Column E

m NaOH

m N

aBH

4

0 10 20 30 40 50 60 70 80 90 1000

10

20

30

40

50

60

70

80

90

100 H2O+NaOH+NaBH4

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C

w% NaOH

w%

NaB

H4

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0 10 20 30 40 50 60 70 80 90 1000

10

20

30

40

50

60

70

80

90

100 H2O+NaOH+NaBH4

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C Column C

Column C

w% NaOH

w%

NaB

H4

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t/C m-NaClm-Na2O.5B2O3wt% Na2O.5B2O3wt% NaCl solid20 0.1871 0.28338607 10.31 0.97 Na2O.5B2O3.10H2O20 0.5471 0.2289795239 8.34 2.84 Na2O.5B2O3.10H2O20 1.2126 0.1896318894 6.77 6.17 Na2O.5B2O3.10H2O20 1.3978 0.171958283 6.12 7.09 Na2O.5B2O3.10H2O20 3.138 0.1359816621 4.5 14.8 Na2O.5B2O3.10H2O20 5.0021 0.1261912262 3.85 21.75 Na2O.5B2O3.10H2O20 5.9586 0.1199537137 3.52 24.92 Na2O.5B2O3.10H2O + NaCl20 5.9586 0.1199537137 3.52 24.92 NaCl + Na2O.5B2O3.10H2O20 6.0421 0.0509299093 1.52 25.7 NaCl20 6.0944 0.0283519875 0.85 26.04 NaCl35 1.2182 0.3058103972 10.48 5.95 Na2O.5B2O3.10H2O35 1.5143 0.2818856467 9.6 7.35 Na2O.5B2O3.10H2O35 3.0014 0.2243887007 7.26 13.84 Na2O.5B2O3.10H2O35 3.7567 0.2128839243 6.68 16.8 Na2O.5B2O3.10H2O35 5.9197 0.1910315427 5.5 24.29 Na2O.5B2O3.10H2O + NaCl35 5.9197 0.1910315427 5.5 24.29 NaCl + Na2O.5B2O3.10H2O35 6.0374 0.1399678495 4.07 25.02 NaCl35 6.1137 0.0555299114 1.65 25.89 NaCl35 6.1499 0.0328093408 0.98 26.18 NaCl70 1.5578 0.920295668 25.7 6.2 Na2O.5B2O3.10H2O70 1.8123 0.8657134949 24.3 7.25 Na2O.5B2O3.10H2O70 2.3401 0.8140635525 22.7 9.3 Na2O.5B2O3.10H2O70 2.8221 0.7826724613 21.6 11.1 Na2O.5B2O3.10H2O70 3.2385 0.734125341 20.2 12.7 Na2O.5B2O3.10H2O70 3.8369 0.7094122107 19.2 14.8 Na2O.5B2O3.10H2O + Na2O.5B2O3.2H70 3.8369 0.7094122107 19.2 14.8 Na2O.5B2O3.2H2O + Na2O.5B2O3.10H70 4.4759 0.5686431958 15.6 17.5 Na2O.5B2O3.2H2O70 4.648 0.5386768093 14.8 18.2 Na2O.5B2O3.2H2O70 5.2648 0.4891921495 13.3 20.4 Na2O.5B2O3.2H2O70 5.6349 0.4253806301 11.6 21.9 Na2O.5B2O3.2H2O + NaCl70 5.6349 0.4253806301 11.6 21.9 NaCl + Na2O.5B2O3.2H2O70 6.1092 0.1595672914 4.6 25.1 NaCl70 5.9537 0.2780864752 7.8 23.8 NaCl80 0.774 1.3906742803 35.3 2.8 Na2O.5B2O3.10H2O80 1.3247 1.3058333637 33.2 4.8 Na2O.5B2O3.10H2O80 2.362 1.1390592328 29.1 8.6 Na2O.5B2O3.10H2O + Na2O.5B2O3.2H80 2.362 1.1390592328 29.1 8.6 Na2O.5B2O3.2H2O + Na2O.5B2O3.10H80 2.8518 1.0257621996 26.5 10.5 Na2O.5B2O3.2H2O80 3.7127 0.8665481309 22.6 13.8 Na2O.5B2O3.2H2O80 5.053 0.651564633 17.1 18.9 Na2O.5B2O3.2H2O80 5.4552 0.5764663765 15.2 20.5 Na2O.5B2O3.2H2O + NaCl80 5.4552 0.5764663765 15.2 20.5 NaCl + Na2O.5B2O3.2H2O80 5.8437 0.3813515685 10.44 22.8 NaCl80 6.2398 0.145899413 4.2 25.6 NaCl93 0.6691 2.0071939995 44.2 2.1 Na2O.5B2O3.10H2O + Na2O.5B2O3.2H93 0.6691 2.0071939995 44.2 2.1 Na2O.5B2O3.2H2O + Na2O.5B2O3.10H93 0.9679 1.8734534375 42.1 3.1 Na2O.5B2O3.2H2O93 2.1279 1.4124795934 34 7.3 Na2O.5B2O3.2H2O93 3.7526 1.0177481849 25.5 13.4 Na2O.5B2O3.2H2O93 5.2797 0.7485215673 19 19.1 Na2O.5B2O3.2H2O + NaCl93 5.2797 0.7485215673 19 19.1 NaCl + Na2O.5B2O3.2H2O93 5.7124 0.516366017 13.7 21.6 NaCl93 6.3668 0.1984910619 5.6 25.6 NaCl

100 1.1257 1.9848040177 43.3 3.5 Na2O.5B2O3.2H2O100 1.3383 1.9118295787 42.1 4.2 Na2O.5B2O3.2H2O100 2.4953 1.5112114593 35.1 8.26 Na2O.5B2O3.2H2O100 3.3694 1.2568834706 30.1 11.5 Na2O.5B2O3.2H2O100 3.8316 1.1838695226 28.4 13.1 Na2O.5B2O3.2H2O100 4.3718 1.0645684508 25.8 15.1 Na2O.5B2O3.2H2O100 4.7619 1.0335532156 24.9 16.35 Na2O.5B2O3.2H2O

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t/C m-NaBO2m-NaClwt% NaBO2 wt% NaCl solid ref20 3.847074 0 20.2 0 NaBO2.4H2O 1976STG20 3.433544 1.1133 17.5 5.04 NaBO2.4H2O 1976STG20 3.135999 2.1668 15.48 9.5 NaBO2.4H2O 1976STG20 2.983114 3.6066 13.95 14.98 NaBO2.4H2O 1976STG20 2.982195 3.6347 13.93 15.08 NaBO2.4H2O + NaBO2.NaCl.2H2O1976STG20 2.979172 3.6483 13.91 15.13 NaBO2.4H2O + NaBO2.NaCl.2H2O1976STG20 2.97745 3.6537 13.9 15.15 NaBO2.NaCl.2H2O 1976STG20 2.338623 4.3017 10.95 17.89 NaBO2.NaCl.2H2O 1976STG20 1.613741 5.1686 7.54 21.45 NaBO2.NaCl.2H2O 1976STG20 1.206691 5.7909 5.6 23.87 NaBO2.NaCl.2H2O 1976STG20 1.195578 5.7965 5.55 23.9 NaBO2.NaCl.2H2O + NaCl 1976STG20 1.190297 5.8266 5.52 24 NaBO2.NaCl.2H2O + NaCl 1976STG20 1.188176 5.8738 5.5 24.15 NaCl 1976STG20 0.701145 6.0209 3.3 25.17 NaCl 1976STG20 0 6.1344 0 26.39 NaCl 1976STG

0 1 2 3 4 5 6 70.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

t=20C

NaBO2.4H2ONaBO2.NaCl.2H2ONaCl

m-NaCl

m-N

aBO

2

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PT. TT NACLIN NABO2IN solid1 20 0 4.00405 NA2B2O4.8H2O2 20 0.25 3.85824 NA2B2O4.8H2O3 20 0.5 3.72059 NA2B2O4.8H2O4 20 0.75 3.59854 NA2B2O4.8H2O5 20 1 3.49252 NA2B2O4.8H2O6 20 1.25 3.40157 NA2B2O4.8H2O7 20 1.5 3.32456 NA2B2O4.8H2O8 20 1.75 3.26041 NA2B2O4.8H2O9 20 2 3.20821 NA2B2O4.8H2O10 20 2.25 3.16719 NA2B2O4.8H2O11 20 2.5 3.13667 NA2B2O4.8H2O12 20 2.75 3.11614 NA2B2O4.8H2O13 20 3 3.10516 NA2B2O4.8H2O14 20 3.25 3.10348 NA2B2O4.8H2O15 20 3.5 3.11087 NA2B2O4.8H2O16 20 3.75 3.21509 NA2B2O4.8H2O17 20 4 3.47066 NA2B2O4.8H2O

9 20 3 5.05289 NA2BO2CL.2H2O8 20 3.1 4.75875 NA2BO2CL.2H2O7 20 3.2 4.4646 NA2BO2CL.2H2O6 20 3.3 4.17046 NA2BO2CL.2H2O5 20 3.4 3.87631 NA2BO2CL.2H2O4 20 3.5 3.58216 NA2BO2CL.2H2O3 20 3.6 3.28802 NA2BO2CL.2H2O2 20 3.7 3.0601 NA2BO2CL.2H2O1 20 3.75 2.99135 NA2BO2CL.2H2O2 20 3.8 2.92384 NA2BO2CL.2H2O3 20 3.9 2.79251 NA2BO2CL.2H2O4 20 4 2.66606 NA2BO2CL.2H2O5 20 4.1 2.54441 NA2BO2CL.2H2O6 20 4.2 2.4275 NA2BO2CL.2H2O7 20 4.3 2.31524 NA2BO2CL.2H2O8 20 4.4 2.20755 NA2BO2CL.2H2O9 20 4.5 2.10434 NA2BO2CL.2H2O10 20 4.6 2.00549 NA2BO2CL.2H2O11 20 4.7 1.91091 NA2BO2CL.2H2O12 20 4.8 1.82047 NA2BO2CL.2H2O13 20 4.9 1.73407 NA2BO2CL.2H2O14 20 5 1.65157 NA2BO2CL.2H2O15 20 5.1 1.57286 NA2BO2CL.2H2O16 20 5.2 1.49781 NA2BO2CL.2H2O17 20 5.3 1.42628 NA2BO2CL.2H2O18 20 5.4 1.35816 NA2BO2CL.2H2O19 20 5.5 1.29331 NA2BO2CL.2H2O20 20 5.6 1.2316 NA2BO2CL.2H2O21 20 5.7 1.1729 NA2BO2CL.2H2O22 20 5.8 1.1286 NA2BO2CL.2H2O23 20 5.9 1.1286 NA2BO2CL.2H2O24 20 6 1.1286 NA2BO2CL.2H2O

1 20 6.1197 0 NACLPPT2 20 6.04482 0.25 NACLPPT

0 1 2 3 4 5 6 70.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

t=20C

NaBO2.4H2ONaBO2.NaCl.2H2ONaCl

m-NaCl

m-N

aBO

2

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3 20 5.9697 0.5 NACLPPT4 20 5.89418 0.75 NACLPPT5 20 5.81822 1 NACLPPT6 20 5.87916 1.25 NACLPPT7 20 6.0855 1.5 NACLPPT8 20 6.29183 1.75 NACLPPT9 20 6.49817 2 NACLPPT

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t/Cm^0.5 NaHCOOm Na2B4O7m NaHCOO solid phase ref wt% NaHCOO15 0 0.1014242 0 Na2B4O7.10H2O 1967NH 015 0 0.1076415 0 Na2B4O7.10H2O Linke and Seidell (1939BS) 015 0 0.1066493 0 Na2B4O7.10H2O 1986BKS 015 0.9916897891 0.1112839 0.9834486 Na2B4O7.10H2O 1986BKS 6.1415 1.4741135793 0.110781 2.1730108 Na2B4O7.10H2O 1986BKS 12.6315 1.832153996 0.1156864 3.3567883 Na2B4O7.10H2O 1986BKS 18.2415 1.9694312649 0.1077553 3.8786595 Na2B4O7.10H2O 1986BKS 20.5215 2.1865827127 0.1027428 4.781144 Na2B4O7.10H2O 1986BKS 24.1615 2.2567774442 0.0991945 5.0930444 Na2B4O7.10H2O 1986BKS 25.3515 2.5030462358 0.0858825 6.2652405 Na2B4O7.10H2O 1986BKS 29.5215 2.6228476358 0.0816514 6.8793297 Na2B4O7.10H2O 1986BKS 31.5215 2.8472709152 0.0720747 8.1069517 Na2B4O7.10H2O 1986BKS 35.2115 3.0158807615 0.0714974 9.0955368 Na2B4O7.10H2O 1986BKS 37.8815 3.1039536475 0.0680758 9.6345282 Na2B4O7.10H2O 1986BKS 39.2615 3.1490745567 0.0618636 9.9166706 Na2B4O7.10H2O 1986BKS 39.9815 3.1903259052 0.0548152 10.178179 Na2B4O7.10H2O + NaHC 1986BKS 40.6415 3.1803342531 0.0399829 10.114526 NaHCOO 1986BKS 40.5615 3.2510851712 0 10.569555 NaHCOO 1986BKS 41.82

25 0 0.1568759 0 Na2B4O7.10H2O 1967NH25 0 0.1605805 0 Na2B4O7.10H2O Linke and Seidell (1939BS)25 0 0.1622 0 Na2B4O7.10H2O 2003AM

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.00.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0.16

0.18

15C-Literature15C-Na2B4O7.10H2O15C-Na2B2O4.8H2O15C-NaCOOH.3H2O

m0.5 NaCOOH

m N

a2B

4O7

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wt% Na2B4O7-CORR NACOOHIN^0.5 PT. TT NACOOHIN NA2B4O7IN2 0 1 15 0 0.108665

2.12 0.0316227766017 2 15 0.001 0.1084382.10087 0.1 3 15 0.01 0.1064712.05569 0.22360679775 4 15 0.05 0.099480661.90509 0.3162277660168 5 15 0.1 0.094654551.85991 0.4472135955 6 15 0.2 0.094023891.68672 0.5477225575052 7 15 0.3 0.097960791.53612 0.6324555320337 8 15 0.4 0.1024341.46082 0.7071067811865 9 15 0.5 0.1065081.19727 0.7745966692415 10 15 0.6 0.1100491.10691 0.8366600265341 11 15 0.7 0.1130820.92619 0.8944271909999 12 15 0.8 0.1156540.88101 0.9486832980505 13 15 0.9 0.1178090.82077 1 14 15 1 0.1195840.73794 1.0488088481702 15 15 1.1 0.1210130.64758 1.0954451150103 16 15 1.2 0.1221270.47439 1.1401754250991 17 15 1.3 0.122958

0 1.1832159566199 18 15 1.4 0.1235331.2247448713916 19 15 1.5 0.1238791.2649110640674 20 15 1.6 0.124021.3038404810405 21 15 1.7 0.1239811.3416407864999 22 15 1.8 0.1237831.378404875209 23 15 1.9 0.1234441.4142135623731 24 15 2 0.1229831.4832396974191 25 15 2.2 0.1217561.549193338483 26 15 2.4 0.120211.6124515496597 27 15 2.6 0.1184311.6733200530682 28 15 2.8 0.1164891.7320508075689 29 15 3 0.1144371.7888543819998 30 15 3.2 0.1123191.8439088914586 31 15 3.4 0.1101681.897366596101 32 15 3.6 0.1080091.9493588689618 33 15 3.8 0.105864

2 34 15 4 0.1037472.0493901531919 35 15 4.2 0.101672.0976176963403 36 15 4.4 0.09964172.1447610589527 37 15 4.6 0.097668952.1908902300207 38 15 4.8 0.09575622.2360679774998 39 15 5 0.093906592.2803508501983 40 15 5.2 0.092122152.3237900077245 41 15 5.4 0.0904042.3664319132398 42 15 5.6 0.088752572.4083189157585 43 15 5.8 0.08716772.4494897427832 44 15 6 0.085648852.4899799195977 45 15 6.2 0.084195172.5298221281347 46 15 6.4 0.082805532.569046515733 47 15 6.6 0.081478692.6076809620811 48 15 6.8 0.080213232.6457513110646 49 15 7 0.079007722.6832815729997 50 15 7.2 0.077860632.7202941017471 51 15 7.4 0.076770452.756809750418 52 15 7.6 0.075735662.7928480087538 53 15 7.8 0.07475476

0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.00.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0.16

0.18

15C-Literature15C-Na2B4O7.10H2O15C-Na2B2O4.8H2O15C-NaCOOH.3H2O

m0.5 NaCOOH

m N

a2B

4O7

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2.8284271247462 54 15 8 0.073826292.8635642126553 55 15 8.2 0.072948852.8982753492379 56 15 8.4 0.072121052.932575659723 57 15 8.6 0.071341612.9664793948383 58 15 8.8 0.07060927

3 59 15 9 0.069922853.0331501776206 60 15 9.2 0.069281243.0659419433512 61 15 9.4 0.068683393.0983866769659 62 15 9.6 0.068128343.1304951684997 63 15 9.8 0.069049033.1622776601684 64 15 10 0.07037565

3.1144823004795 1 15 9.7 0.067340823.1304951684997 2 15 9.8 0.06621373.1464265445105 3 15 9.9 0.065122923.1622776601684 4 15 10 0.064067023.1937438845343 5 15 10.2 0.062054273.2249030993194 6 15 10.4 0.060165043.2557641192199 7 15 10.6 0.058478633.286335345031 8 15 10.8 0.056998763.3166247903554 9 15 11 0.055518853.3466401061363 10 15 11.2 0.054038943.3763886032268 11 15 11.4 0.052559033.4058772731853 12 15 11.6 0.051079123.4351128074635 13 15 11.8 0.04959923.4641016151378 14 15 12 0.0481193

3.247691487811 1 15 10.5475 03.2479070183735 2 15 10.5489 0.0053.2477992548801 3 15 10.5482 0.013.2473835621928 4 15 10.5455 0.023.2468754210779 5 15 10.5422 0.033.246336396617 6 15 10.5387 0.043.2457664734235 7 15 10.535 0.053.2451964501398 8 15 10.5313 0.063.2448112425841 9 15 10.5288 0.073.2436245158773 10 15 10.5211 0.083.2424527752922 11 15 10.5135 0.093.2412806111165 12 15 10.5059 0.1

0 1 25 0 0.1682650.0316227766017 2 25 0.001 0.168013

0.1 3 25 0.01 0.1657910.22360679775 4 25 0.05 0.156942

0.3162277660168 5 25 0.1 0.1482130.4472135955 6 25 0.2 0.137519

0.5477225575052 7 25 0.3 0.1330090.6324555320337 8 25 0.4 0.1316960.7071067811865 9 25 0.5 0.1318380.7745966692415 10 25 0.6 0.1325830.8366600265341 11 25 0.7 0.1335250.8944271909999 12 25 0.8 0.1344680.9486832980505 13 25 0.9 0.135316

1 14 25 1 0.136019

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1.0488088481702 15 25 1.1 0.1365581.0954451150103 16 25 1.2 0.1369261.1401754250991 17 25 1.3 0.1371241.1832159566199 18 25 1.4 0.137161.2247448713916 19 25 1.5 0.1370451.2649110640674 20 25 1.6 0.136791.3038404810405 21 25 1.7 0.1364071.3416407864999 22 25 1.8 0.135911.378404875209 23 25 1.9 0.1353111.4142135623731 24 25 2 0.134621.4832396974191 25 25 2.2 0.133011.549193338483 26 25 2.4 0.1311581.6124515496597 27 25 2.6 0.129131.6733200530682 28 25 2.8 0.126981.7320508075689 29 25 3 0.1247521.7888543819998 30 25 3.2 0.1224821.8439088914586 31 25 3.4 0.1201981.897366596101 32 25 3.6 0.1179221.9493588689618 33 25 3.8 0.11567

2 34 25 4 0.1134572.0493901531919 35 25 4.2 0.1112932.0976176963403 36 25 4.4 0.1091862.1447610589527 37 25 4.6 0.107142.1908902300207 38 25 4.8 0.1051612.2360679774998 39 25 5 0.103252.2803508501983 40 25 5.2 0.1014112.3237900077245 41 25 5.4 0.099642412.3664319132398 42 25 5.6 0.097946132.4083189157585 43 25 5.8 0.096321492.4494897427832 44 25 6 0.094767912.4899799195977 45 25 6.2 0.093284512.5298221281347 46 25 6.4 0.091870192.569046515733 47 25 6.6 0.09052372.6076809620811 48 25 6.8 0.089243692.6457513110646 49 25 7 0.088028752.6832815729997 50 25 7.2 0.086877452.7202941017471 51 25 7.4 0.085788322.756809750418 52 25 7.6 0.084759942.7928480087538 53 25 7.8 0.083790882.8284271247462 54 25 8 0.082879782.8460498941515 55 25 8.1 0.082445562.8635642126553 56 25 8.2 0.082025342.8809720581776 57 25 8.3 0.081618972.8827070610799 58 25 8.31 0.08157912.8844410203712 59 25 8.32 0.081539352.8861739379324 60 25 8.33 0.081499742.8879058156387 61 25 8.34 0.081460272.88963665536 62 25 8.35 0.08142094

2.8913664589602 63 25 8.36 0.08138174

2.8827070610799 1 25 8.31 0.086959652.8844410203712 2 25 8.32 0.08152854

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2.8861739379324 3 25 8.33 0.081427862.8879058156387 4 25 8.34 0.081327392.88963665536 5 25 8.35 0.08122715

2.8913664589602 6 25 8.36 0.081127142.8930952282979 7 25 8.37 0.081027352.894822965226 8 25 8.38 0.080927792.896549671592 9 25 8.39 0.080828462.8982753492379 10 25 8.4 0.080729342.932575659723 11 25 8.6 0.078793212.9664793948383 12 25 8.8 0.07694209

3 13 25 9 0.075171923.0331501776206 14 25 9.2 0.073478833.0659419433512 15 25 9.4 0.071859183.0983866769659 16 25 9.6 0.070309513.1304951684997 17 25 9.8 0.068826553.1622776601684 18 25 10 0.067407183.1937438845343 19 25 10.2 0.066048473.2249030993194 20 25 10.4 0.064747623.2557641192199 21 25 10.6 0.0635023.286335345031 22 25 10.8 0.06230913.3166247903554 23 25 11 0.061166543.3466401061363 24 25 11.2 0.060072083.3763886032268 25 25 11.4 0.059023573.3911649915626 26 25 11.5 0.059056353.4058772731853 27 25 11.6 0.059375573.4205262752974 28 25 11.7 0.05969873.4351128074635 29 25 11.8 0.060025753.4641016151378 30 25 12 0.060691933.4928498393146 31 25 12.2 0.061374553.5213633723318 32 25 12.4 0.062074213.5496478698598 33 25 12.6 0.06279153.5777087639997 34 25 12.8 0.063526943.605551275464 35 25 13 0.06428111

3.7947331922021 1 25 14.4 0.033942023.7815340802378 2 25 14.3 0.034196183.7682887362834 3 25 14.2 0.034450343.7549966711037 4 25 14.1 0.034808143.7416573867739 5 25 14 0.03540413.7282703764614 6 25 13.9 0.036017023.7148351242013 7 25 13.8 0.036647523.7013511046643 8 25 13.7 0.037296253.6878177829172 9 25 13.6 0.037963863.6742346141748 10 25 13.5 0.038651083.6606010435446 11 25 13.4 0.039358623.6469165057621 12 25 13.3 0.040087273.633180424917 13 25 13.2 0.040837843.6193922141708 14 25 13.1 0.041611173.605551275464 15 25 13 0.042408153.5916569992136 16 25 12.9 0.043229723.5777087639997 17 25 12.8 0.044076863.5637059362411 18 25 12.7 0.04495063.5496478698598 19 25 12.6 0.045852033.5355339059327 20 25 12.5 0.04678228

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3.5213633723318 21 25 12.4 0.047742573.50713558335 22 25 12.3 0.04873415

3.4928498393146 23 25 12.2 0.049758363.4785054261852 24 25 12.1 0.050816613.4641016151378 25 25 12 0.05191043.4496376621321 26 25 11.9 0.053041283.4351128074635 27 25 11.8 0.054210933.4205262752974 28 25 11.7 0.055421113.4058772731853 29 25 11.6 0.056673683.3911649915626 30 25 11.5 0.057970613.3896902513357 31 25 11.49 0.058102823.3882148692195 32 25 11.48 0.05823553.3867388443752 33 25 11.47 0.058368653.3852621759622 34 25 11.46 0.058502283.3837848631377 35 25 11.45 0.058636373.3823069050576 36 25 11.44 0.058770943.3808283008754 37 25 11.43 0.063994133.3793490497432 38 25 11.42 0.076079223.3778691508109 39 25 11.41 0.08816431

3.7617017425628 1 25 14.1504 03.7616884506828 2 25 14.1503 0.0053.761356138416 3 25 14.1478 0.013.7605318772748 4 25 14.1416 0.023.759601042664 5 25 14.1346 0.033.7595212461163 6 25 14.134 0.043.760186165604 7 25 14.139 0.05

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solidNA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2O

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NA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2O

NA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2ONA2B2O4.8H2O

NACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2ONACOOH.3H2O

NA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2O

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NA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2ONA2B4O7.10H2O

NA2B4O7.4H2ONA2B4O7.4H2O

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NA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2ONA2B4O7.4H2O

NA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2O

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NA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2ONA2B2O4.4H2O

NACOOH.2H2ONACOOH.2H2ONACOOH.2H2ONACOOH.2H2ONACOOH.2H2ONACOOH.2H2ONACOOH.2H2O

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1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 1262. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 1203. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 924. Nikolaev, A.V. and Chelishcheva, A.G. Dokl. Akad. Nauk SSSR 1940, 28(2), 1245. Mandelbaum, Z. anorg. Chem. 1909, 62, 370-3826. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-22337. Sborgi, U. Atti Accad. Linc. 1913, 22(5), 641, 716-718

; t CaO B2O3; deg C m m Phase ; pH;; 1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 126 *; *

25 0.021245953 0 ; CH *25 0.022326789 0.0053233 ; CH *25 0.025910754 0.0089242 ; CH *25 0.033980966 0.0146942 ; CH+1:1:6 *

;25 0.033980966 0.0146942 ; CH+1:1:625 0.03487905 0.0155603 ; 1:1:625 0.031294178 0.0149804 ; 1:1:6

0 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.050

0.1

0.2

0.3

0.4

0.5

Solubility in the CaO-B2O3-H2O system at 25 C

Kurnakova (1947) - Ca(OH)2Rza-Zade (1963) - Ca(OH)2Nikolaev (1940) - Ca(OH)2Nikolski (1975) - Ca(OH)2Kurnakova (1947) - 1:1:6Rza-Zade (1963) - 1:1:6Nikolaev (1940) - 1:1:6Nikolski (1975) - 1:1:6Kurnakova (1947) - 2:3:13Rza-Zade (1963) - 2:3:13Nikolaev (1940) - 2:3:13Nikolski (1975) - 2:3:13Kurnakova (1947) - 1:3:4

m CaO

m B

2O3

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; 25 0.016083988 0.0181379 ; 1:1:6+2:3:13;; 2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 120 *; *

25 0.021424705 0 ; CH *25 0.022506531 0.0058991 ; CH *25 0.036335498 0.0245103 ; CH+1:1:6 11.14 *

;; 25 0.036335498 0.0245103 ; CH+1:1:6 11.14; 25 0.025222513 0.0246394 ; 1:1:6 11.05; 25 0.012155392 0.0249098 ; 1:1:6 10.48

25 0.013224877 0.0207294 ; 1:1:6+2:3:13 9.35;; 4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-130*; *

25 0.021245953 0 ; CH *25 0.033980966 0.0146942 ; CH+1:1:6 *

;25 0.033980966 0.0146942 ; CH+1:1:625 0.031294178 0.0149804 ; 1:1:625 0.016083988 0.0181379 ; 1:1:6+2:3:13

;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233 *; *

25 0.021156578 0 ; CH *25 0.026802348 0.0071964 ; CH *25 0.035237845 0.0157049 ; CH+1:1:6 *

;25 0.035237845 0.0157049 ; CH+1:1:625 0.026819144 0.0162021 ; 1:1:625 0.020913166 0.0169895 ; 1:1:625 0.017872351 0.0177073 ; 1:1:625 0.016084149 0.018282 ; 1:1:6+2:3:13

;; 5. Mandelbaum, Z. anorg. Chem. 1909, 62, 370-382;

30 0.020258991 0.020259 ; 1:1:650 0.028183184 0.0281832 ; 1:1:670 0.036524565 0.0365246 ; 1:1:6

; 90 0.028663944 0.0286639 ; 1:1:6 ????;; 1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 126;; 25 0.016083988 0.0181379 ; 1:1:6+2:3:13

25 0.017337223 0.0190041 ; 2:3:1325 0.005901425 0.036012 ; 2:3:1325 0.006082269 0.040635 ; 2:3:1325 0.006088254 0.0548103 ; 2:3:1325 0.006637784 0.0812124 ; 2:3:1325 0.0088163 0.1217402 ; 2:3:1325 0.011369888 0.1639794 ; 2:3:13

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25 0.009547461 0.1385734 ; 2:3:13+1:3:4;; 2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 120;

25 0.013224877 0.0207294 ; 1:1:6+2:3:13 9.3525 0.011619474 0.0257745 ; 2:3:13 9.3225 0.007153888 0.0363034 ; 2:3:13 8.0525 0.006443281 0.0475755 ; 2:3:13 7.9125 0.006814373 0.0751121 ; 2:3:13 7.7725 0.00753956 0.0896505 ; 2:3:13 7.6225 0.007735504 0.1202715 ; 2:3:13 7.2125 0.009917461 0.1525076 ; 2:3:13+1:3:4 6.55

;; 4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-130;

25 0.016083988 0.0181379 ; 1:1:6+2:3:1325 0.006088254 0.0548103 ; 2:3:1325 0.009547461 0.1385734 ; 2:3:13+1:3:4

; ;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

25 0.016084149 0.018282 ; 1:1:6+2:3:1325 0.011687627 0.0215926 ; 2:3:1325 0.009347642 0.0251943 ; 2:3:1325 0.007829722 0.0287983 ; 2:3:1325 0.006883649 0.0324045 ; 2:3:1325 0.006330772 0.0360129 ; 2:3:1325 0.006045296 0.0378177 ; 2:3:13

;; 1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 126;

25 0.009547461 0.1385734 ; 2:3:13+1:3:425 0.007956496 0.195327 ; 1:3:425 0.008343112 0.2387189 ; 1:3:425 0.008752861 0.3172685 ; 1:3:425 0.009335523 0.3730383 ; 1:3:425 0.01070245 0.4907912 ; 1:3:4+BH

;; 2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 120;

25 0.009917461 0.1525076 ; 2:3:13+1:3:4 6.5525 0.008690918 0.2133699 ; 1:3:4 6.4225 0.007615223 0.2347003 ; 1:3:4 6.325 0.007827498 0.2925242 ; 1:3:4 625 0.008227682 0.3568477 ; 1:3:4 5.5525 0.011268968 0.5074265 ; 1:3:4+BH 5.13

;; 4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-130;

25 0.009547461 0.1385734 ; 2:3:13+1:3:425 0.007956415 0.1951794 ; 1:3:4

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25 0.010702228 0.4904837 ; 1:3:4+BH; ;; 1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 126;

25 0.01070245 0.4907912 ; 1:3:4+BH; 25 0.014199168 0.4782913 ; BH

25 0.005343429 0.4734533 ; BH25 0 0.4702469 ; BH

;; 2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 120;

25 0.011268968 0.5074265 ; 1:3:4+BH 5.1325 0.004426035 0.4872389 ; BH 5.0425 0 0.4779108 ; BH

;; 4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-130;

25 0.010702228 0.4904837 ; 1:3:4+BH25 0 0.4702469 ; BH

;; 3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 92;

45 0.019101209 0 ; CH45 0.023414892 0.0145414 ; CH45 0.028797286 0.0203146 ; CH45 0.03759071 0.0243676 ; CH+1:1:445 0.02147631 0.0345982 ; 1:1:4

; 45 0.02772938 0.0239211 ; 1:1:445 0.019684247 0.0343058 ; 1:1:445 0.01717691 0.0345899 ; 1:1:445 0.011448861 0.0361677 ; 1:1:4+2:3:9

;; 3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 92;

45 0.011448861 0.0361677 ; 1:1:4+2:3:945 0.009133023 0.0533716 ; 2:3:945 0.009509516 0.0809348 ; 2:3:945 0.010781436 0.1013183 ; 2:3:945 0.013173565 0.1613496 ; 2:3:945 0.014443215 0.1668022 ; 2:3:9+1:3:4

;; 3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 92;

45 0.014443215 0.1668022 ; 2:3:9+1:3:445 0.014815545 0.177553 ; 1:3:445 0.015234319 0.2322765 ; 1:3:445 0.016403563 0.3038999 ; 1:3:445 0.016679759 0.3868246 ; 1:3:445 0.016743436 0.4431379 ; 1:3:445 0.01867277 0.6617987 ; 1:3:445 0.01926449 0.8336857 ; 1:3:4+BH

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45 0.019657215 0.8449793 ; 1:3:4+BH;; 3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 92;

45 0.01926449 0.8336857 ; 1:3:4+BH45 0.019657215 0.8449793 ; 1:3:4+BH45 0.017326267 0.7918668 ; BH45 0.016373383 0.7822279 ; BH45 0 0.7655576 ; BH

;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

80 0.011527239 0 ; CH80 0.01912035 0.0143938 ; CH80 0.030786418 0.0288353 ; CH+1:1:4

;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

80 0.030786418 0.0288353 ; CH+1:1:480 0.027921584 0.0306365 ; 1:1:480 0.026848082 0.0317182 ; 1:1:480 0.025881447 0.032439 ; 1:1:480 0.024378963 0.0342426 ; 1:1:480 0.023682456 0.0357588 ; 1:1:4+2:3:9

; ;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

80 0.023682456 0.0357588 ; 1:1:4+2:3:980 0.021483856 0.0396578 ; 2:3:980 0.020521121 0.0432715 ; 2:3:980 0.020113851 0.0468882 ; 2:3:9

; ;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

95 0.009636486 0.0025874 ; CH+2:1:195 0.009815136 0.0027312 ; CH+2:1:195 0.008029843 0.0028747 ; CH+2:1:195 0.008922404 0.0027311 ; CH+2:1:195 0.006958779 0.0028745 ; 2:1:195 0.003032707 0.0031613 ; 2:1:195 0.001248912 0.0063234 ; 2:1:195 0.003033344 0.0061802 ; 2:1:195 0.007678954 0.0143846 ; 2:1:195 0.010361291 0.0172676 ; 2:1:195 0.013045509 0.0201526 ; 2:1:195 0.014477765 0.0215959 ; 2:1:195 0.013582715 0.020874 ; 2:1:1+1:1:2

; ;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

95 0.013582715 0.020874 ; 2:1:1+1:1:2

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95 0.013404935 0.0220272 ; 2:1:1+2:3:9; ;; 6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-2233;

95 0.013404935 0.0220272 ; 2:1:1+2:3:9

; ; 7. Sborgi, U. Atti Accad. Linc. 1913, 22(5), 641, 716-718;; 30 0.028914032 0.6386021 ; BH wrong; 30 0.025532502 0.6273496 ; BH points; 30 0.048020522 0.7068245 ; BH; 30 0.028914032 0.6386021 ; BH; 30 0.037933866 0.0184487 ; CH; 30 0.034660447 0.0140891 ; CH; 30 0.024972757 0.0046188 ; CH; 30 0.022554086 0.0020138 ; CH

t H3BO3 Ca(OH)2 B2O3 CaOdeg C m m m m pH Phase

1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 12625 0 0.021254088 0 0.021246 CH25 0.010653987 0.022342204 0.0053233 0.0223268 CH25 0.017865311 0.02593537 0.0089242 0.0259108 CH25 0.029429843 0.034028823 0.0146942 0.033981 CH+1:1:6

25 0.029429843 0.034028823 0.0146942 0.033981 CH+1:1:625 0.031166414 0.034930375 0.0155603 0.0348791 1:1:625 0.030001997 0.031337217 0.0149804 0.0312942 1:1:625 0.036321865 0.016104441 0.0181379 0.016084 1:1:6+2:3:13

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2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 12025 0 0.021432977 0 0.0214247 CH25 0.011806767 0.022522844 0.0058991 0.0225065 CH25 0.049117798 0.036407559 0.0245103 0.0363355 11.14 CH+1:1:6

25 0.049117798 0.036407559 0.0245103 0.0363355 11.14 CH+1:1:625 0.049366936 0.025267643 0.0246394 0.0252225 11.05 1:1:625 0.049897744 0.012174448 0.0249098 0.0121554 10.48 1:1:625 0.041515216 0.013242869 0.0207294 0.0132249 9.35 1:1:6+2:3:13

4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-13025 0 0.021254088 0 0.021246 CH25 0.029429843 0.034028823 0.0146942 0.033981 CH+1:1:6

25 0.029429843 0.034028823 0.0146942 0.033981 CH+1:1:625 0.030001997 0.031337217 0.0149804 0.0312942 1:1:625 0.036321865 0.016104441 0.0181379 0.016084 1:1:6+2:3:13

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223325 0 0.021164645 0 0.0211566 CH25 0.014405383 0.026825735 0.0071964 0.0268023 CH25 0.031456388 0.035290201 0.0157049 0.0352378 CH+1:1:6

25 0.031456388 0.035290201 0.0157049 0.0352378 CH+1:1:625 0.03244824 0.026855636 0.0162021 0.0268191 1:1:625 0.034023042 0.020940283 0.0169895 0.0209132 1:1:625 0.035459864 0.017895239 0.0177073 0.0178724 1:1:625 0.036610786 0.016104728 0.018282 0.0160841 1:1:6+2:3:13

1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 12625 0.036321865 0.016104441 0.0181379 0.016084 1:1:6+2:3:1325 0.03805908 0.017360476 0.0190041 0.0173372 2:3:1325 0.072172167 0.005913563 0.036012 0.0059014 2:3:1325 0.081457815 0.006096325 0.040635 0.0060823 2:3:1325 0.109958315 0.006107014 0.0548103 0.0060883 2:3:1325 0.163160381 0.006667848 0.0812124 0.0066378 2:3:1325 0.2451322 0.008876111 0.1217402 0.0088163 2:3:1325 0.330959612 0.011473925 0.1639794 0.0113699 2:3:1325 0.279286499 0.009621172 0.1385734 0.0095475 2:3:13+1:3:4

2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 12025 0.041515216 0.013242869 0.0207294 0.0132249 9.35 1:1:6+2:3:1325 0.051631772 0.011638122 0.0257745 0.0116195 9.32 2:3:1325 0.072758904 0.007168877 0.0363034 0.0071539 8.05 2:3:1325 0.095407304 0.006460643 0.0475755 0.0064433 7.91 2:3:1325 0.150855178 0.006842992 0.0751121 0.0068144 7.77 2:3:1325 0.180198644 0.007577303 0.0896505 0.0075396 7.62 2:3:1325 0.242150765 0.007787208 0.1202715 0.0077355 7.21 2:3:1325 0.307605619 0.010001686 0.1525076 0.0099175 6.55 2:3:13+1:3:4

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4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-13025 0.036321865 0.016104441 0.0181379 0.016084 1:1:6+2:3:1325 0.109958315 0.006107014 0.0548103 0.0060883 2:3:1325 0.279286499 0.009621172 0.1385734 0.0095475 2:3:13+1:3:4

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223325 0.036610786 0.016104728 0.018282 0.0160841 1:1:6+2:3:1325 0.04324471 0.01170375 0.0215926 0.0116876 2:3:1325 0.050465887 0.009361967 0.0251943 0.0093476 2:3:1325 0.057694513 0.007843035 0.0287983 0.0078297 2:3:1325 0.064930716 0.006896583 0.0324045 0.0068836 2:3:1325 0.072174467 0.006343842 0.0360129 0.0063308 2:3:1325 0.075798493 0.006058338 0.0378177 0.0060453 2:3:13

1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 12625 0.279286499 0.009621172 0.1385734 0.0095475 2:3:13+1:3:425 0.394879295 0.008042551 0.195327 0.0079565 1:3:425 0.483751736 0.008453448 0.2387189 0.0083431 1:3:425 0.645710961 0.008906995 0.3172685 0.0087529 1:3:425 0.761558662 0.009529247 0.3730383 0.0093355 1:3:425 1.008528281 0.010996249 0.4907912 0.0107024 1:3:4+BH

2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 12025 0.307605619 0.010001686 0.1525076 0.0099175 6.55 2:3:13+1:3:425 0.431786707 0.008793702 0.2133699 0.0086909 6.42 1:3:425 0.475497373 0.007714132 0.2347003 0.0076152 6.3 1:3:425 0.594531698 0.007954376 0.2925242 0.0078275 6 1:3:425 0.727840496 0.008390752 0.3568477 0.0082277 5.55 1:3:425 1.043687377 0.011589146 0.5074265 0.011269 5.13 1:3:4+BH

4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-13025 0.279286499 0.009621172 0.1385734 0.0095475 2:3:13+1:3:425 0.394577645 0.008042404 0.1951794 0.0079564 1:3:425 1.007879354 0.010995833 0.4904837 0.0107022 1:3:4+BH

1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 12625 1.008528281 0.010996249 0.4907912 0.0107024 1:3:4+BH25 0.982224142 0.014579781 0.4782913 0.0141992 BH25 0.971868606 0.00548429 0.4734533 0.0053434 BH25 0.965019676 0 0.4702469 0 BH

2. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 12025 1.043687377 0.011589146 0.5074265 0.011269 5.13 1:3:4+BH25 1.000914929 0.004546112 0.4872389 0.004426 5.04 BH25 0.981164234 0 0.4779108 0 BH

4. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-13025 1.007879354 0.010995833 0.4904837 0.0107022 1:3:4+BH25 0.965019676 0 0.4702469 0 BH

3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 92

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45 0 0.019107784 0 0.0191012 CH45 0.029117998 0.023443205 0.0145414 0.0234149 CH45 0.040695084 0.028843919 0.0203146 0.0287973 CH45 0.04883254 0.037665822 0.0243676 0.0375907 CH+1:1:445 0.069353012 0.021524887 0.0345982 0.0214763 1:1:445 0.04792809 0.027779171 0.0239211 0.0277294 1:1:445 0.068763474 0.01972782 0.0343058 0.0196842 1:1:445 0.069330898 0.017214419 0.0345899 0.0171769 1:1:445 0.072491987 0.011473655 0.0361677 0.0114489 1:1:4+2:3:9

3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 9245 0.072491987 0.011473655 0.0361677 0.0114489 1:1:4+2:3:945 0.107069742 0.009160955 0.0533716 0.009133 2:3:945 0.162608641 0.009552939 0.0809348 0.0095095 2:3:945 0.203792106 0.010842917 0.1013183 0.0107814 2:3:945 0.32561595 0.013292636 0.1613496 0.0131736 2:3:945 0.3367276 0.014578433 0.1668022 0.0144432 2:3:9+1:3:4

3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 9245 0.3367276 0.014578433 0.1668022 0.0144432 2:3:9+1:3:445 0.358643316 0.014963125 0.177553 0.0148155 1:3:445 0.470589826 0.015432285 0.2322765 0.0152343 1:3:445 0.618134969 0.016682496 0.3038999 0.0164036 1:3:445 0.790411397 0.017041148 0.3868246 0.0166798 1:3:445 0.908303389 0.017159581 0.4431379 0.0167434 1:3:445 1.373174367 0.019372183 0.6617987 0.0186728 1:3:445 1.746678291 0.020180786 0.8336857 0.0192645 1:3:4+BH45 1.771485706 0.020605519 0.8449793 0.0196572 1:3:4+BH

3. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 9245 1.746678291 0.020180786 0.8336857 0.0192645 1:3:4+BH45 1.771485706 0.020605519 0.8449793 0.0196572 1:3:4+BH45 1.655083211 0.018106842 0.7918668 0.0173263 BH45 1.634018045 0.017101411 0.7822279 0.0163734 BH45 1.597199852 0 0.7655576 0 BH

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223380 0 0.011529633 0 0.0115272 CH80 0.028820016 0.019141834 0.0143938 0.0191203 CH80 0.057792812 0.03085161 0.0288353 0.0307864 CH+1:1:4

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223380 0.057792812 0.03085161 0.0288353 0.0307864 CH+1:1:480 0.06140552 0.027981992 0.0306365 0.0279216 1:1:480 0.063576224 0.026907222 0.0317182 0.0268481 1:1:480 0.06502228 0.025939017 0.032439 0.0258814 1:1:480 0.068642298 0.024434916 0.0342426 0.024379 1:1:480 0.071686745 0.023738462 0.0357588 0.0236825 1:1:4+2:3:9

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223380 0.071686745 0.023738462 0.0357588 0.0236825 1:1:4+2:3:9

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80 0.07951672 0.021538356 0.0396578 0.0214839 2:3:980 0.086778069 0.02057685 0.0432715 0.0205211 2:3:980 0.094048749 0.020172279 0.0468882 0.0201139 2:3:9

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223395 0.005176403 0.009639507 0.0025874 0.0096365 CH+2:1:195 0.00546415 0.009818321 0.0027312 0.0098151 CH+2:1:195 0.005751078 0.008032252 0.0028747 0.0080298 CH+2:1:195 0.005463789 0.008925156 0.0027311 0.0089224 CH+2:1:195 0.005750622 0.006960733 0.0028745 0.0069588 2:1:195 0.006324069 0.003033391 0.0031613 0.0030327 2:1:195 0.012651413 0.001249367 0.0063234 0.0012489 2:1:195 0.012365296 0.003034524 0.0061802 0.0030333 2:1:195 0.028795589 0.007685993 0.0143846 0.007679 2:1:195 0.034573887 0.010372907 0.0172676 0.0103613 2:1:195 0.040358602 0.013062806 0.0201526 0.0130455 2:1:195 0.043253657 0.014498469 0.0215959 0.0144778 2:1:195 0.04180537 0.013601387 0.020874 0.0135827 2:1:1+1:1:2

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223395 0.04180537 0.013601387 0.020874 0.0135827 2:1:1+1:1:295 0.04411758 0.013424158 0.0220272 0.0134049 2:1:1+2:3:9

6. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-223395 0.04411758 0.013424158 0.0220272 0.0134049 2:1:1+2:3:9

1. Kurnakova, Izv. SFChA AN SSSR 1947, 15, 1262. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1963, 3, 1203. Rza-Zade, P.F.; Ganf, K.L. Azerb. Khim. Zh. 1964, 6, 924. Nikolaev, A.V; Chelishcheva, A.G. Compt. Rend. Akad. Sci. USSR 1940, 28, 127-1305. Mandelbaum, Z. anorg. Chem. 1909, 62, 370-3826. Nikolskii, B.A.; Plyschevskii, Yu.S. Zh. Neorg. Khim. 1975, 20(8), 2231-22337. Sborgi, U. Atti Accad. Linc. 1913, 22(5), 641, 716-718

t H3BO3 Ca(OH)2 B2O3 CaOdeg C m m m m pH Phase

25 0 0.021254088 0 0.021246 Ca(OH)225 0.010653987 0.022342204 0.0053233 0.0223268 Ca(OH)225 0.017865311 0.02593537 0.0089242 0.0259108 Ca(OH)225 0.029429843 0.034028823 0.0146942 0.033981 Ca(OH)2+CaO.B2O3.6H2O25 0.031166414 0.034930375 0.0155603 0.0348791 CaO.B2O3.6H2O25 0.030001997 0.031337217 0.0149804 0.0312942 CaO.B2O3.6H2O

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25 0.036321865 0.016104441 0.0181379 0.016084 CaO.B2O3.6H2O+2CaO.3B2O3.13H2O25 0.03805908 0.017360476 0.0190041 0.0173372 2CaO.3B2O3.13H2O25 0.072172167 0.005913563 0.036012 0.0059014 2CaO.3B2O3.13H2O25 0.081457815 0.006096325 0.040635 0.0060823 2CaO.3B2O3.13H2O25 0.109958315 0.006107014 0.0548103 0.0060883 2CaO.3B2O3.13H2O25 0.163160381 0.006667848 0.0812124 0.0066378 2CaO.3B2O3.13H2O25 0.2451322 0.008876111 0.1217402 0.0088163 2CaO.3B2O3.13H2O25 0.330959612 0.011473925 0.1639794 0.0113699 2CaO.3B2O3.13H2O25 0.279286499 0.009621172 0.1385734 0.0095475 2CaO.3B2O3.13H2O+CaO.3B2O3.4H2O25 0.394879295 0.008042551 0.195327 0.0079565 CaO.3B2O3.4H2O25 0.483751736 0.008453448 0.2387189 0.0083431 CaO.3B2O3.4H2O25 0.645710961 0.008906995 0.3172685 0.0087529 CaO.3B2O3.4H2O25 0.761558662 0.009529247 0.3730383 0.0093355 CaO.3B2O3.4H2O25 1.008528281 0.010996249 0.4907912 0.0107024 CaO.3B2O3.4H2O+H3BO325 0.982224142 0.014579781 0.4782913 0.0141992 H3BO325 0.971868606 0.00548429 0.4734533 0.0053434 H3BO325 0.965019676 0 0.4702469 0 H3BO325 0 0.021432977 0 0.0214247 Ca(OH)225 0.011806767 0.022522844 0.0058991 0.0225065 Ca(OH)225 0.049117798 0.036407559 0.0245103 0.0363355 11.14 Ca(OH)2+CaO.B2O3.6H2O25 0.049366936 0.025267643 0.0246394 0.0252225 11.05 CaO.B2O3.6H2O25 0.049897744 0.012174448 0.0249098 0.0121554 10.48 CaO.B2O3.6H2O25 0.041515216 0.013242869 0.0207294 0.0132249 9.35 CaO.B2O3.6H2O+2CaO.3B2O3.13H2O25 0.051631772 0.011638122 0.0257745 0.0116195 9.32 2CaO.3B2O3.13H2O25 0.072758904 0.007168877 0.0363034 0.0071539 8.05 2CaO.3B2O3.13H2O25 0.095407304 0.006460643 0.0475755 0.0064433 7.91 2CaO.3B2O3.13H2O25 0.150855178 0.006842992 0.0751121 0.0068144 7.77 2CaO.3B2O3.13H2O25 0.180198644 0.007577303 0.0896505 0.0075396 7.62 2CaO.3B2O3.13H2O25 0.242150765 0.007787208 0.1202715 0.0077355 7.21 2CaO.3B2O3.13H2O25 0.307605619 0.010001686 0.1525076 0.0099175 6.55 2CaO.3B2O3.13H2O+CaO.3B2O3.4H2O25 0.431786707 0.008793702 0.2133699 0.0086909 6.42 CaO.3B2O3.4H2O25 0.475497373 0.007714132 0.2347003 0.0076152 6.3 CaO.3B2O3.4H2O25 0.594531698 0.007954376 0.2925242 0.0078275 6 CaO.3B2O3.4H2O25 0.727840496 0.008390752 0.3568477 0.0082277 5.55 CaO.3B2O3.4H2O25 1.043687377 0.011589146 0.5074265 0.011269 5.13 CaO.3B2O3.4H2O+H3BO325 1.000914929 0.004546112 0.4872389 0.004426 5.04 H3BO325 0.981164234 0 0.4779108 0 H3BO325 0 0.021254088 0 0.021246 Ca(OH)225 0.029429843 0.034028823 0.0146942 0.033981 Ca(OH)2+CaO.B2O3.6H2O25 0.030001997 0.031337217 0.0149804 0.0312942 CaO.B2O3.6H2O25 0.036321865 0.016104441 0.0181379 0.016084 CaO.B2O3.6H2O+2CaO.3B2O3.13H2O25 0.109958315 0.006107014 0.0548103 0.0060883 2CaO.3B2O3.13H2O25 0.279286499 0.009621172 0.1385734 0.0095475 2CaO.3B2O3.13H2O+CaO.3B2O3.4H2O25 0.394577645 0.008042404 0.1951794 0.0079564 CaO.3B2O3.4H2O25 1.007879354 0.010995833 0.4904837 0.0107022 CaO.3B2O3.4H2O+H3BO325 0.965019676 0 0.4702469 0 H3BO325 0 0.021164645 0 0.0211566 Ca(OH)225 0.014405383 0.026825735 0.0071964 0.0268023 Ca(OH)225 0.031456388 0.035290201 0.0157049 0.0352378 Ca(OH)2+CaO.B2O3.6H2O25 0.03244824 0.026855636 0.0162021 0.0268191 CaO.B2O3.6H2O25 0.034023042 0.020940283 0.0169895 0.0209132 CaO.B2O3.6H2O

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25 0.035459864 0.017895239 0.0177073 0.0178724 CaO.B2O3.6H2O25 0.036610786 0.016104728 0.018282 0.0160841 CaO.B2O3.6H2O+2CaO.3B2O3.13H2O25 0.04324471 0.01170375 0.0215926 0.0116876 2CaO.3B2O3.13H2O25 0.050465887 0.009361967 0.0251943 0.0093476 2CaO.3B2O3.13H2O25 0.057694513 0.007843035 0.0287983 0.0078297 2CaO.3B2O3.13H2O25 0.064930716 0.006896583 0.0324045 0.0068836 2CaO.3B2O3.13H2O25 0.072174467 0.006343842 0.0360129 0.0063308 2CaO.3B2O3.13H2O25 0.075798493 0.006058338 0.0378177 0.0060453 2CaO.3B2O3.13H2O45 0 0.019107784 0 0.0191012 Ca(OH)245 0.029117998 0.023443205 0.0145414 0.0234149 Ca(OH)245 0.040695084 0.028843919 0.0203146 0.0287973 Ca(OH)245 0.04883254 0.037665822 0.0243676 0.0375907 Ca(OH)2+CaO.B2O3.4H2O45 0.069353012 0.021524887 0.0345982 0.0214763 CaO.B2O3.4H2O45 0.04792809 0.027779171 0.0239211 0.0277294 CaO.B2O3.4H2O45 0.068763474 0.01972782 0.0343058 0.0196842 CaO.B2O3.4H2O45 0.069330898 0.017214419 0.0345899 0.0171769 CaO.B2O3.4H2O45 0.072491987 0.011473655 0.0361677 0.0114489 CaO.B2O3.4H2O+2CaO.3B2O3.9H2O45 0.107069742 0.009160955 0.0533716 0.009133 2CaO.3B2O3.9H2O45 0.162608641 0.009552939 0.0809348 0.0095095 2CaO.3B2O3.9H2O45 0.203792106 0.010842917 0.1013183 0.0107814 2CaO.3B2O3.9H2O45 0.32561595 0.013292636 0.1613496 0.0131736 2CaO.3B2O3.9H2O45 0.3367276 0.014578433 0.1668022 0.0144432 2CaO.3B2O3.9H2O+CaO.3B2O3.4H2O45 0.358643316 0.014963125 0.177553 0.0148155 CaO.3B2O3.4H2O45 0.470589826 0.015432285 0.2322765 0.0152343 CaO.3B2O3.4H2O45 0.618134969 0.016682496 0.3038999 0.0164036 CaO.3B2O3.4H2O45 0.790411397 0.017041148 0.3868246 0.0166798 CaO.3B2O3.4H2O45 0.908303389 0.017159581 0.4431379 0.0167434 CaO.3B2O3.4H2O45 1.373174367 0.019372183 0.6617987 0.0186728 CaO.3B2O3.4H2O45 1.746678291 0.020180786 0.8336857 0.0192645 CaO.3B2O3.4H2O+H3BO345 1.771485706 0.020605519 0.8449793 0.0196572 CaO.3B2O3.4H2O+H3BO345 1.655083211 0.018106842 0.7918668 0.0173263 H3BO345 1.634018045 0.017101411 0.7822279 0.0163734 H3BO345 1.597199852 0 0.7655576 0 H3BO380 0 0.011529633 0 0.0115272 Ca(OH)280 0.028820016 0.019141834 0.0143938 0.0191203 Ca(OH)280 0.057792812 0.03085161 0.0288353 0.0307864 Ca(OH)2+CaO.B2O3.4H2O80 0.06140552 0.027981992 0.0306365 0.0279216 CaO.B2O3.4H2O80 0.063576224 0.026907222 0.0317182 0.0268481 CaO.B2O3.4H2O80 0.06502228 0.025939017 0.032439 0.0258814 CaO.B2O3.4H2O80 0.068642298 0.024434916 0.0342426 0.024379 CaO.B2O3.4H2O80 0.071686745 0.023738462 0.0357588 0.0236825 CaO.B2O3.4H2O+2CaO.3B2O3.9H2O80 0.07951672 0.021538356 0.0396578 0.0214839 2CaO.3B2O3.9H2O80 0.086778069 0.02057685 0.0432715 0.0205211 2CaO.3B2O3.9H2O80 0.094048749 0.020172279 0.0468882 0.0201139 2CaO.3B2O3.9H2O95 0 0.008743584 0 0.0087422 Ca(OH)295 0.007190723 0.010355382 0.003594 0.0103514 Ca(OH)2+2CaO.B2O3.H2O95 0.005176403 0.009639507 0.0025874 0.0096365 Ca(OH)2+2CaO.B2O3.H2O95 0.00546415 0.009818321 0.0027312 0.0098151 Ca(OH)2+2CaO.B2O3.H2O95 0.005751078 0.008032252 0.0028747 0.0080298 Ca(OH)2+2CaO.B2O3.H2O95 0.005463789 0.008925156 0.0027311 0.0089224 Ca(OH)2+2CaO.B2O3.H2O95 0.005750622 0.006960733 0.0028745 0.0069588 2CaO.B2O3.H2O

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95 0.006324069 0.003033391 0.0031613 0.0030327 2CaO.B2O3.H2O95 0.012651413 0.001249367 0.0063234 0.0012489 2CaO.B2O3.H2O95 0.012365296 0.003034524 0.0061802 0.0030333 2CaO.B2O3.H2O95 0.028795589 0.007685993 0.0143846 0.007679 2CaO.B2O3.H2O95 0.034573887 0.010372907 0.0172676 0.0103613 2CaO.B2O3.H2O95 0.040358602 0.013062806 0.0201526 0.0130455 2CaO.B2O3.H2O95 0.043253657 0.014498469 0.0215959 0.0144778 2CaO.B2O3.H2O95 0.04180537 0.013601387 0.020874 0.0135827 2CaO.B2O3.H2O+CaO.B2O3.2H2O95 0.04411758 0.013424158 0.0220272 0.0134049 CaO.B2O3.2H2O+2CaO.3B2O3.9H2O30 0.060143551 0.02479977 0.0052521 0.0247059 CaO.B2O3.4H2O50 0.059515761 0.024558388 0.00518 0.0244664 CaO.B2O3.4H2O70 0.076700772 0.031406904 0.0069101 0.0312561 CaO.B2O3.4H2O90 0.058693924 0.024797556 0.0045324 0.0247047 CaO.B2O3.4H2O30 0.046507108 0.02029603 0.0029486 0.0202346 CaO.B2O3.6H2O50 0.065762992 0.02825669 0.0046052 0.028137 CaO.B2O3.6H2O70 0.093031658 0.036665561 0.0097942 0.0364568 CaO.B2O3.6H2O90 0.077041047 0.028757951 0.0097179 0.0286262 CaO.B2O3.6H2O

t H3BO3 Ca(OH)2 B2O3 CaOdeg C m m m m pH Phase

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0 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.050

0.1

0.2

0.3

0.4

0.5

Solubility in the CaO-B2O3-H2O system at 25 C

Kurnakova (1947) - Ca(OH)2Rza-Zade (1963) - Ca(OH)2Nikolaev (1940) - Ca(OH)2Nikolski (1975) - Ca(OH)2Kurnakova (1947) - 1:1:6Rza-Zade (1963) - 1:1:6Nikolaev (1940) - 1:1:6Nikolski (1975) - 1:1:6Kurnakova (1947) - 2:3:13Rza-Zade (1963) - 2:3:13Nikolaev (1940) - 2:3:13Nikolski (1975) - 2:3:13Kurnakova (1947) - 1:3:4

m CaO

m B

2O3

0 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.050

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1 Solubility in the CaO-B2O3-H2O system at 45 C

Rza-Zade (1964) - Ca(OH)2Rza-Zade (1964) - 1:1:4Rza-Zade (1964) - 2:3:9Rza-Zade (1964) - 1:3:4Rza-Zade (1964) - BHCa(OH)2PPTH3BO3PPTCaB2O4.4H2OCaB6O10.4H2OCaB6O10.4H2OCa2B6O11.9H2OCa2B6O11.9H2O

m CaO

m B

2O3

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Comments Refs1

11 days 116 days 1145 days 136 days 130 days 1

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CaO.B2O3.6H2O+2CaO.3B2O3.13H2O 84 days 115 days 133 days 124 days 141 days 123 days 129 days 1150 days 1

2CaO.3B2O3.13H2O+CaO.3B2O3.4H2O 84 days 148 days 112 days 128 days 131 days 1116 days 118 days 111 days 114 days 1up to 6 2months 2up to 6 2months 2up to 6 2

CaO.B2O3.6H2O+2CaO.3B2O3.13H2O months 2up to 6 2months 2up to 6 2months 2up to 6 2months 2

2CaO.3B2O3.13H2O+CaO.3B2O3.4H2O up to 6 2months 2up to 6 2months 2up to 6 2months 2up to 6 2months 23 months 43 months 43 months 4

CaO.B2O3.6H2O+2CaO.3B2O3.13H2O 3 months 43 months 4

2CaO.3B2O3.13H2O+CaO.3B2O3.4H2O 3 months 43 months 43 months 43 months 4

66666

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6CaO.B2O3.6H2O+2CaO.3B2O3.13H2O 6

666666

27 days 333

173 days 3159 days 3

3129 days 3130 days 3

CaO.B2O3.4H2O+2CaO.3B2O3.9H2O 3115 days 3145 days 3204 days 3133 days 3

2CaO.3B2O3.9H2O+CaO.3B2O3.4H2O 187 days 3192 days 3124 days 3109 days 3116 days 3115 days 3

3162 days 320 days 320 days 320 days 35 days 3

6666666

CaO.B2O3.4H2O+2CaO.3B2O3.9H2O 6666

4 days 64 days 64 days 64 days 64 days 64 days 64 days 6

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4 days 64 days 64 days 64 days 64 days 64 days 6

nCaB2O4 4 days 62CaO.B2O3.H2O+CaO.B2O3.2H2O 4 days 6CaO.B2O3.2H2O+2CaO.3B2O3.9H2O 4 days 6

0.0024663 amorphous 50.0024424 amorphous 50.0031186 amorphous 50.0024663 amorphous 50.0020208 crystalline 50.0028084 crystalline 50.0036358 crystalline 50.0028561 crystalline 5

Comments Refs

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Calculated data:Ca(OH)2PPT CaB2O4.6H2O CaB6O11.13H2O

t / C CaO B2O3 CaO B2O3 CaO25 0.0210777 0 0.016 0.0261179 0.006125 0.0218775 0.001 0.017 0.0365769 0.006225 0.0226907 0.002 0.018 0.0448916 0.006325 0.0235162 0.003 0.0187 0.0501405 0.006425 0.0243533 0.004 0.01871 0.0502131 0.006525 0.025201 0.005 0.01872 0.0502856 0.006625 0.0260586 0.006 0.01873 0.050358 0.006725 0.0269253 0.007 0.01874 0.0504304 0.006825 0.0278004 0.008 0.01875 0.0505028 0.006925 0.0286833 0.009 0.01876 0.050575 0.00725 0.0295733 0.01 0.01877 0.0506472 0.00825 0.03047 0.011 0.01878 0.0152222 0.00925 0.0313728 0.012 0.01879 0.0152214 0.0125 0.0322812 0.013 0.0188 0.0152205 0.01125 0.0331948 0.014 0.019 0.0152031 0.01225 0.0341131 0.015 0.02 0.015122 0.01325 0.0350359 0.016 0.021 0.0150473 0.01425 0.0359628 0.017 0.022 0.0149769 0.01525 0.0368934 0.018 0.023 0.0149097 0.016

0 0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.050

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1 Solubility in the CaO-B2O3-H2O system at 45 C

Rza-Zade (1964) - Ca(OH)2Rza-Zade (1964) - 1:1:4Rza-Zade (1964) - 2:3:9Rza-Zade (1964) - 1:3:4Rza-Zade (1964) - BHCa(OH)2PPTH3BO3PPTCaB2O4.4H2OCaB6O10.4H2OCaB6O10.4H2OCa2B6O11.9H2OCa2B6O11.9H2O

m CaO

m B

2O3

0 0.005 0.01 0.015 0.02 0.025 0.03 0.0350

0.005

0.01

0.015

0.02

0.025

0.03

0.035

0.04

0.045

0.05Solubility in the CaO-B2O3-H2O system at 80-95 C (Nikolski (1975))

80C - Ca(OH)280C - 1:1:480C - 2:3:995C - Ca(OH)2+1:1:195C - 2:1:195C - 2:1:1+1:1:2

m CaO

m B

2O3

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25 0.0378275 0.019 0.024 0.014845 0.01725 0.0387648 0.02 0.025 0.0147824 0.01825 0.039705 0.021 0.026 0.0147217 0.01925 0.040648 0.022 0.027 0.0146627 0.0225 0.0415935 0.023 0.028 0.014605 0.02125 0.0425413 0.024 0.029 0.0145488 0.02225 0.0434913 0.025 0.03 0.0144937 0.02325 0.0444433 0.026 0.031 0.0144398 0.02425 0.0453972 0.027 0.032 0.0143869 0.02525 0.0463527 0.028 0.033 0.0143349 0.02625 0.0473099 0.029 0.034 0.0142839 0.02725 0.0482685 0.03 0.035 0.0142337 0.02825 0.036 0.0141843 0.02925 0.037 0.0141356 0.0325 0.038 0.014087625 0.039 0.0140403

t / C CaO B2O3 CaO B2O3 CaO45 0.0174983 0 0.0391861 0.019 0.00945 0.0181751 0.001 0.0326413 0.02 0.0145 0.0188688 0.002 0.0231423 0.022 0.01145 0.0195783 0.003 0.022084 0.024 0.01245 0.0203026 0.004 0.0220048 0.026 0.01345 0.0210404 0.005 0.0220624 0.028 0.01445 0.0217909 0.006 0.0221135 0.029 0.01545 0.0225531 0.007 0.0221743 0.03 0.01645 0.0233259 0.008 0.0223184 0.032 0.01745 0.0241086 0.009 0.01845 0.0249003 0.01 0.01945 0.0257003 0.011 0.0245 0.0265079 0.012 0.02145 0.0273225 0.013 0.02245 0.0281436 0.014 0.02345 0.0289704 0.015 0.023245 0.0298027 0.016 0.023545 0.0306399 0.017 0.023745 0.0314816 0.018 0.02445 0.0323275 0.019 0.02545 0.0331772 0.02 0.02645 0.0340304 0.02145 0.0348868 0.02245 0.0357461 0.02345 0.0366082 0.02445 0.0374728 0.02545 0.0383396 0.02645 0.0392086 0.02745 0.0400795 0.02845 0.0409521 0.02945 0.0418264 0.034545

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454545454545454545

t / C CaOIN B2O3IN CAOIN B2O3IN CAOIN80 0.0121566 0 0.031 0.019748 0.02010580 0.0127489 0.001 0.03 0.0200619 0.020249380 0.0133667 0.002 0.029 0.020398 0.020358380 0.0140073 0.003 0.028 0.0207665 0.020505680 0.0146685 0.004 0.027 0.0211852 0.020700680 0.0153478 0.005 0.026 0.0216873 0.020956780 0.0160429 0.006 0.025 0.0223459 0.02180 0.0167518 0.007 0.024 0.0233603 0.02280 0.0174724 0.008 0.0231814 0.025 0.02380 0.018203 0.009 0.023 0.025658 0.023280 0.018942 0.01 0.0229259 0.026 0.023580 0.0196879 0.011 0.0228 0.0267483 0.023780 0.0204392 0.012 0.0227668 0.027 0.02480 0.0211949 0.013 0.0226695 0.028 0.02580 0.0219539 0.014 0.0226 0.029 0.02680 0.022715 0.015 0.022614 0.029421980 0.0234775 0.016 0.0225882 0.0380 0.0242405 0.017 0.0225844 0.03180 0.0250032 0.018 0.0225976 0.03280 0.0257649 0.019 0.0226241 0.03380 0.026525 0.02 0.0226616 0.03480 0.0272828 0.021 0.0227082 0.03580 0.0280377 0.022 0.0227624 0.03680 0.0287892 0.023 0.0228234 0.03780 0.0295367 0.024 0.0228901 0.03880 0.0228901 0.03880 0.022962 0.03980 0.0230386 0.0480 0.0231194 0.041

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CaB6O11.13H2O CaB6O10.4H2O B(OH)3PPTB2O3 CaO B2O3 CaO B2O3 CaO B2O3

0.0329283 0.0062658 0.028 0.0100396 0.11 0 0.4550310.0295014 0.0062203 0.029 0.0096166 0.12 0.001 0.4580960.0273386 0.0061814 0.03 0.0093165 0.13 0.002 0.4614020.0257149 0.0061211 0.032 0.0090987 0.14 0.003 0.4647180.0244097 0.0060804 0.034 0.0089386 0.15 0.004 0.4680360.0233203 0.0060558 0.036 0.0088202 0.16 0.005 0.4713550.022389 0.0060449 0.038 0.008733 0.17 0.006 0.474674

0.0215796 0.0060458 0.04 0.0086694 0.18 0.007 0.4779930.0208677 0.0060569 0.042 0.0086242 0.19 0.008 0.4813130.0202358 0.006077 0.044 0.0085936 0.2 0.009 0.4846320.0164595 0.006105 0.046 0.0085652 0.22 0.01 0.4879520.0149221 0.0061403 0.048 0.0085788 0.25 0.011 0.4912710.0143589 0.0061819 0.05 0.0086128 0.27 0.012 0.4945910.0143167 0.0063105 0.055 0.0086888 0.3 0.013 0.497910.0145829 0.0064686 0.06 0.0087518 0.32 0.014 0.501230.0150432 0.0066509 0.065 0.0088598 0.35 0.015 0.5045490.0156309 0.0068538 0.07 0.0089391 0.37 0.016 0.5078690.0163043 0.0070742 0.075 0.009 0.382296 0.017 0.5111880.0170364 0.00731 0.08 0.0090667 0.4 0.018 0.514508

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0.0178087 0.0075593 0.085 0.0090889 0.405 0.019 0.5178270.0186081 0.0078207 0.09 0.0091 0.405274 0.2 1.116360.0194254 0.0080931 0.095 0.0091113 0.410.0202535 0.0083754 0.1 0.0091339 0.4150.0210871 0.0089665 0.11 0.0091385 0.4160.0219221 0.009589 0.12 0.009143 0.4170.0227552 0.0102389 0.13 0.0091476 0.4180.0235838 0.0109132 0.14 0.0091522 0.4190.0244057 0.0116097 0.15 0.0095 0.4887380.0252192 0.0123264 0.16 0.01 0.5821130.0260228 0.0130619 0.170.0268155 0.0138149 0.180.02759630.0283644

B2O3 CaO B2O3 CaO B2O3 CaO B2O3 CaO B2O30.0296364 0.0091644 0.028 0.0208249 0.11 0.02 0.114406 0 0.7691040.0230051 0.0089681 0.03 0.0191596 0.12 0.021 0.109173 0.001 0.77220.0201739 0.0088177 0.032 0.0180486 0.13 0.022 0.105032 0.002 0.775720.0187969 0.0087025 0.034 0.0172656 0.14 0.023 0.101685 0.003 0.7792790.0181829 0.0086152 0.036 0.0166947 0.15 0.024 0.09894 0.004 0.7828480.0180225 0.0085509 0.038 0.0162692 0.16 0.025 0.0966647 0.005 0.7864220.0181502 0.0085056 0.04 0.0159476 0.17 0.006 0.7899970.0184677 0.0084765 0.042 0.0157028 0.18 0.007 0.7935750.0189125 0.0084614 0.044 0.0155159 0.19 0.008 0.7971550.0194427 0.0084585 0.046 0.015374 0.2 0.009 0.8007350.0200289 0.0084664 0.048 0.0151891 0.22 0.01 0.8043150.0206502 0.0084839 0.05 0.0150762 0.25 0.011 0.8078970.0212909 0.0085636 0.055 0.0150717 0.27 0.012 0.811480.0219394 0.0086858 0.06 0.0151334 0.3 0.013 0.8150630.0225869 0.0088425 0.065 0.0152074 0.32 0.014 0.8186460.0227156 0.009028 0.07 0.0153536 0.35 0.015 0.822230.022908 0.0092379 0.075 0.0154693 0.37 0.016 0.825815

0.0230357 0.009469 0.08 0.0156639 0.4 0.017 0.82940.0232264 0.0097187 0.085 0.0158053 0.42 0.018 0.8329850.023853 0.0099849 0.09 0.0159546 0.44 0.019 0.836572

0.0244626 0.0102659 0.095 0.0161108 0.46 0.02 0.8401580.0105603 0.1 0.0162732 0.48 0.021 0.8437460.0111847 0.11 0.0164412 0.5 0.022 0.8473330.0118507 0.12 0.0166144 0.52 0.023 0.8509220.0125527 0.13 0.0175477 0.62 0.024 0.854510.0132865 0.14 0.0177464 0.64 0.025 0.85810.0140489 0.15 0.0179489 0.66

0.014837 0.16 0.018155 0.680.0156488 0.17 0.0183648 0.70.0164825 0.18 0.018578 0.720.0173365 0.19 0.0187948 0.740.0182097 0.2 0.0190151 0.760.0191008 0.21 0.0192389 0.78

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0.020009 0.22 0.0194661 0.80.0209334 0.23 0.0196968 0.820.0218733 0.24 0.0199309 0.84

0.022828 0.25 0.0201685 0.860.023797 0.26 0.0190151 0.76

0.0247798 0.27 0.0192389 0.780.0257757 0.28 0.0194661 0.80.0267845 0.29 0.0196968 0.820.0278057 0.3 0.0199309 0.84

0.0201685 0.86

B2O3IN0.055

0.050.0480.0460.0440.042

0.04171030.03712570.03462910.03426540.03378140.03349490.03311230.03216040.0315642

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1. Kurnakova, A.G. Izv. SFKhA AN SSSR 1947, 15, 129-1332. Rza-Zade, P.F.; Bagirov, G.; Sedelnikov, G.S. Azerb. Khim. Zh. 1964, 2, 1193. Rza-Zade, P.F.; Abduragimova, R.A.; Sedelnikov, G.S.; Afuzova, A. Study in the area of inorganic and physical chemistry, Akad. Nauk Azerb. SSR 1966, 714. Nikolaev, A.V. and Chelishcheva, A.G. Dokl. Akad. Nauk SSSR 1940, 28(2), 1245. D'Ans, J. and Behrendt, K.H. Kali und Steinsalz 1957, 2, 132-125

1. Mg(OH)2 - MH2. 2MgO.3B2O3.15H2O - 2:3:153. MgO.2B2O3.9H2O - 1:2:94. MgO.3B2O3.7.5H2O - 1:3:7.55. MgO.B2O3.3H2O - 1:1:36. H3BO3 - BH

Experimental data: Calculated data:Mg(OH)2

t MgO B2O3 Phase Refs t/C MGO B2O3deg C m m 25 0.0001522 0

25 0.00074436 0 MH 1 25 0.0002222 0.000125 0.01416461 0.0143866 MH 1 25 0.0002986 0.000225 0.02488959 0.0309803 MH+2:3:15 1 25 0.0003783 0.000325 0.00099249 0 MH 4 25 0.0004597 0.000425 0.02488959 0.0309803 MH+2:3:15 4 25 0.000542 0.000525 0.00029774 0 MH 5 25 0.0006246 0.000625 0.00124073 0.0012929 MH 5 25 0.0007073 0.000725 0.00670385 0.0064685 MH 5 25 0.0007899 0.0008

0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.080

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1 1 - MH 4 - MH5 - MH 2 - MH1 - 2:3:15 4 - 2:3:152 - 2:3:15 5 - 2:3:152 - 1:2:9 -metast. 1 - 1:2:94 - 1:2:9 5 - 1:2:8.5-metast.5 - 1:3:7.5-metast. 5 - 1:3:7.5

m MgO

m B

2O3

0 0.02 0.04 0.06 0.08 0.1 0.120

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1 5 - BH - 35C5 - 1:3:7.55 - 2:3:155 - MH

m MgO

m B

2O3

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25 0.01192619 0.0133774 MH 5 25 0.0008724 0.000925 0.02313919 0.0269362 MH 5 25 0.0009548 0.00125 0.02613276 0.0295378 MH+2:3:15 5 25 0.0017651 0.00225 0.00071955 0 MH 2 25 0.0025536 0.00325 0.00571429 0.0161095 MH 2 25 0.0033248 0.00425 0.02916793 0.0518135 MH+2:3:15 2 25 0.0040823 0.00525 0.02488959 0.0309803 2:3:15 1 25 0.0048284 0.00625 0.01965765 0.0302519 2:3:15 1 25 0.0055648 0.00725 0.01593221 0.0387684 2:3:15 1 25 0.0062926 0.00825 0.01444785 0.0488882 2:3:15 1 25 0.0070125 0.00925 0.01496393 0.0658398 2:3:15 1 25 0.0077254 0.0125 0.02022936 0.0828478 2:3:15 1 25 0.014536 0.0225 0.02310166 0.1599106 2:3:15 1 25 0.0208622 0.0325 0.03000204 0.2145607 2:3:15+1:2:9 1 25 0.0267738 0.0425 0.02488959 0.0309803 MH+2:3:15 4 25 0.032339 0.0525 0.01498155 0.0828303 2:3:15 4 25 0.0376281 0.0625 0.03000204 0.2145607 2:3:15+1:2:9 4 25 0.0427032 0.0725 0.02916793 0.0518135 MH+2:3:15 2 25 0.0476133 0.0825 0.02493286 0.0560058 2:3:15 2 25 0.0523959 0.0925 0.00246696 0.0608792 2:3:15 2 25 0.0570789 0.125 0.00220628 0.149356 2:3:15 225 0.02180069 0.1304186 2:3:15 2 35 0.0001379 025 0.02894387 0.1901509 2:3:15 2 35 0.0002039 0.000125 0.03968334 0.2461295 2:3:15 2 35 0.000275 0.000225 0.04454159 0.2616758 2:3:15 2 35 0.0003481 0.000325 0.04250137 0.2574789 2:3:15 2 35 0.000422 0.000425 0.05487346 0.311651 2:3:15 2 35 0.0004959 0.000525 0.05744919 0.3192009 2:3:15+1:2:7.5 2 35 0.0005696 0.000625 0.02613276 0.0295378 MH+2:3:15 5 35 0.0006429 0.000725 0.02090453 0.0314085 2:3:15 5 35 0.0007158 0.000825 0.01520797 0.0606206 2:3:15 5 35 0.0007882 0.000925 0.01497507 0.0765812 2:3:15 5 35 0.0008602 0.00125 0.0180394 0.1305453 2:3:15 5 35 0.0015562 0.00225 0.02159809 0.1628411 2:3:15 5 35 0.0022194 0.00325 0.02235672 0.1657876 2:3:15 5 35 0.0028594 0.00425 0.02515072 0.1820076 2:3:15 5 35 0.0034819 0.00525 0.03156479 0.2368301 2:3:15 5 35 0.0040902 0.00625 0.03745772 0.2666737 2:3:15 5 35 0.0046868 0.00725 0.04030383 0.2876301 2:3:15 5 35 0.0052731 0.00825 0.04106553 0.2876389 2:3:15 5 35 0.0058505 0.00925 0.05744919 0.3192009 2:3:15+1:3:7.5 2 35 0.0064199 0.0125 0.07275635 0.3215049 1:2:9 2ms 35 0.0117831 0.0225 0.07075385 0.3294626 1:2:9 2ms 35 0.0167151 0.0325 0.07048633 0.3268974 1:2:9 2ms 35 0.0213456 0.0425 0.06777899 0.3484355 1:2:9 2ms 35 0.0257593 0.0525 0.07293133 0.3568238 1:2:9 2ms 35 0.0300181 0.0625 0.03000204 0.2145607 2:3:15+1:2:9 1 35 0.034166 0.0725 0.03284911 0.2457642 1:2:9 1 35 0.0382341 0.0825 0.04008269 0.2996119 1:2:9 1 35 0.0422443 0.0925 0.04061166 0.3071186 1:2:9 1 35 0.0462117 0.125 0.05137633 0.4039789 1:2:9 1

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25 0.05375928 0.4253487 1:2:9+1:3:7.5 1 45 0.000124 025 0.03000204 0.2145607 2:3:15+1:2:9 4 45 0.0001839 0.000125 0.05265163 0.4024784 1:2:9 4 45 0.0002467 0.000225 0.05375928 0.4253487 1:2:9+1:3:7.5 4 45 0.0003102 0.000325 0.03799723 0.1821017 1:2:8.5 5ms 45 0.0003735 0.000425 0.04085267 0.211691 1:2:8.5 5ms 45 0.0004361 0.000525 0.04550656 0.2458894 1:2:8.5 5ms 45 0.000498 0.000625 0.04730373 0.2533547 1:2:8.5 5ms 45 0.0005591 0.000725 0.04991477 0.2757717 1:2:8.5 5ms 45 0.0006195 0.000825 0.05691105 0.3118269 1:2:8.5+1:3:7. 5ms 45 0.0006792 0.000925 0.0559154 0.3178275 1:3:7.5 5ms 45 0.0007381 0.00125 0.0550092 0.3479546 1:3:7.5 5ms 45 0.0012981 0.00225 0.06119971 0.5501459 1:3:7.5+2:3:15 5ms 45 0.0018199 0.00325 0.06149697 0.5594708 1:3:7.5 5ms 45 0.0023167 0.00425 0.05451552 0.3524791 1:3:7.5 5 45 0.0027951 0.00525 0.05634831 0.4314995 1:3:7.5 5 45 0.0032592 0.00625 0.0640553 0.6125582 1:3:7.5 5 45 0.0037117 0.00725 0.07241814 0.7295309 BH+1:3:7.5 5 45 0.0041544 0.00825 0.05375928 0.4253487 1:2:9+1:3:7.5 1 45 0.0045888 0.00925 0.05380369 0.4375663 1:3:7.5 1 45 0.0050158 0.0125 0.05633586 0.4959228 1:3:7.5 1 45 0.009012 0.0225 0.06023325 0.5672162 1:3:7.5 1 45 0.0127086 0.0325 0.06495755 0.6408085 1:3:7.5 1 45 0.016243 0.0425 0.07079282 0.7183608 BH+1:3:7.5 1 45 0.0196839 0.0525 0.05375928 0.4253487 1:2:9+1:3:7.5 4 45 0.0230713 0.0625 0.05407721 0.4421576 1:3:7.5 4 45 0.0264294 0.0725 0.07080028 0.7199489 BH+1:3:7.5 4 45 0.029773 0.0825 0.06101847 0.443352 1:3:7.5 2 45 0.0331112 0.0925 0.0594906 0.5111004 1:3:7.5 2 45 0.0364499 0.125 0.07207696 0.7130011 1:3:7.5 225 0.07299255 0.7398913 BH+1:3:7.5 2 70 9.339E-05 025 0.04200188 0.6217172 BH 2 70 0.00013 0.000125 0.02214549 0.5310186 BH 2 70 0.0001657 0.000225 0.01568099 0.5092755 BH 2 70 0.0002002 0.000325 0.01335274 0.4942967 BH 2 70 0.0002334 0.000425 0.00563559 0.462849 BH 2 70 0.0002657 0.000525 0 0.4638153 BH 2 70 0.000297 0.000625 0.07079282 0.7183608 BH+1:3:7.5 1 70 0.0003274 0.000725 0.06975966 0.721507 BH 1 70 0.0003571 0.000825 0.04750366 0.6365917 BH 1 70 0.0003862 0.000925 0.02839104 0.5618307 BH 1 70 0.0004146 0.00125 0.0115586 0.4996446 BH 1 70 0.0006757 0.00225 0 0.4702469 BH 1 70 0.0009094 0.00325 0.07080028 0.7199489 BH+1:3:7.5 4 70 0.0011266 0.00425 0 0.4702469 BH 7 70 0.0013325 0.00525 0.0750879 0.7391574 BH 5ms 70 0.00153 0.00625 0.07241814 0.7295309 BH+1:3:7.5 5 70 0.0017209 0.00725 0.05139686 0.6341806 BH 5 70 0.0019065 0.00825 0.02574309 0.5246049 BH 5 70 0.0020877 0.00925 0.01282762 0.4812273 BH 5 70 0.0022654 0.0125 0 0.4610606 BH 5 70 0.003931 0.02

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35 0 0.5907127 BH 5 70 0.005528 0.0335 0.03306665 0.6903687 BH 5 70 0.0071416 0.0435 0.06542311 0.8705293 BH 5 70 0.0088067 0.0535 0.09917349 0.9712816 BH+1:3:7.5 5 70 0.0105383 0.0635 0.07937407 0.7059127 1:3:7.5 5 70 0.0123416 0.0735 0.07280854 0.5410916 1:3:7.5 5 70 0.0142167 0.0835 0.07171086 0.4746795 1:3:7.5 5 70 0.016161 0.0935 0.07324978 0.4211024 1:3:7.5 5 70 0.0181708 0.135 0.074442 0.4028311 2:3:15+1:3:7.5 535 0.06917593 0.3738826 2:3:15 5 83 8E-05 035 0.05801882 0.3344174 2:3:15 5 83 0.0001048 0.000135 0.03840897 0.2428434 2:3:15 5 83 0.0001284 0.000235 0.0294344 0.1835139 2:3:15 5 83 0.0001509 0.000335 0.02176793 0.1086396 2:3:15 5 83 0.0001726 0.000435 0.02098916 0.0896885 2:3:15 5 83 0.0001934 0.000535 0.02440208 0.0373362 2:3:15 5 83 0.0002136 0.000635 0.02689344 0.0366172 MH+2:3:15 5 83 0.0002331 0.000735 0.01416816 0.0179878 MH 5 83 0.0002522 0.000835 0.00039699 0 MH 5 83 0.0002708 0.000945 0.00794212 0 MH 3 83 0.0002889 0.00145 0.01118058 0.013521 MH+1:1:3 3 83 0.0004542 0.00245 0.011267 0.1246589 1:1:3 3 83 0.0006008 0.00345 0.02000902 0.1042551 1:1:3 3 83 0.0007363 0.00445 0.02508715 0.145238 1:1:3 3 83 0.0008642 0.00545 0.03017781 0.1776214 1:1:3 3 83 0.0009865 0.00645 0.03580913 0.2146109 2:3:15+1:1:3 3 83 0.0011044 0.00745 0.04719126 0.2971485 2:3:15 3 83 0.0012188 0.00845 0.0493345 0.3297814 2:3:15 3 83 0.0013304 0.00945 0.0688987 0.3693315 2:3:15 3 83 0.0014397 0.0145 0.08357215 0.4289146 2:3:15 3 83 0.0024637 0.0245 0.10079545 0.5401477 1:3:7.5+2:3:15 3 83 0.0034528 0.0345 0.09833387 0.5602994 1:3:7.5 3 83 0.0044665 0.0445 0.09587613 0.5820624 1:3:7.5 3 83 0.0055318 0.0545 0.09603661 0.6070794 1:3:7.5 3 83 0.0066623 0.0645 0.09664874 0.6212013 1:3:7.5 3 83 0.0078644 0.0745 0.09759475 0.6463705 1:3:7.5 3 83 0.0091405 0.0845 0.10377952 0.7863831 1:3:7.5 3 83 0.0104904 0.0945 0.11702136 0.9654039 1:3:7.5 3 83 0.0119122 0.145 0.14886822 1.3925827 BH+1:3:7.5 345 0.08873623 1.1519875 BH 345 0.03469577 0.9491284 BH 345 0 0.7569571 BH 370 0 1.4032925 BH 370 0.11200175 1.7815234 BH 370 0.21733696 2.286637 BH+1:3:7.5 370 0.32145719 2.5234815 1:3:7.5 370 0.30365402 2.5277023 1:3:7.5 370 0.33455971 2.7358428 1:3:7.5 370 0.27580889 2.2841949 1:3:7.5 370 0.23259633 1.3434108 1:3:7.5 370 0.22719864 1.3517791 1:3:7.5 3

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70 0.21776138 1.268574 1:3:7.5 370 0.22215738 1.1920365 1:3:7.5 370 0.21589549 1.1934355 1:1:3+1:3:7.5 370 0.21732229 1.1393705 1:1:3 370 0.19208417 1.1213986 1:1:3 370 0.20352685 1.0833384 1:1:3 370 0.11274237 0.7498505 1:1:3 370 0.08888214 0.718883 1:1:3 370 0.08965551 0.6288734 1:1:3 370 0.06656515 0.5922975 1:1:3 370 0.06700154 0.5161983 1:1:3 370 0.06332536 0.5022287 1:1:3 370 0.05385374 0.4513352 1:1:3 370 0.01873749 0.0888071 1:1:3 370 0.00947277 0.0623457 1:1:3 370 0.00347569 0.0067552 1:1:3 370 0.00422039 0.0060365 MH+1:1:3 370 0.00243173 0 MH 383 0.0092013 0.0277865 ? 583 0.00821777 0.048008 ? 583 0.01200832 0.112391 1:1:3 583 0.01051555 0.1246551 ? 583 0.01152261 0.1310963 ? 583 0.01407812 0.1819265 1:1:3 583 0.0158744 0.2144387 1:1:3 583 0.04016121 0.4220667 1:1:3 583 0.08035401 0.6443501 1:1:3 583 0.09008008 0.6998737 1:1:3 583 0.10777187 0.7913233 1:1:3 583 0.14779044 0.9946069 1:1:3 583 0.15226504 1.0129679 1:1:3 583 0.17898255 1.1376252 1:1:3 583 0.20080046 1.2079982 1:1:3 583 0.26181645 1.4901352 1:1:3 583 0.33222612 1.7295672 1:1:3+1:3:7.5 583 0.33359909 1.6860459 1:3:7.5* 5ms83 0.38002423 1.5220238 1:3:7.5* 5ms83 0.35845308 1.5402932 1:3:7.5* 5ms83 0.34200989 1.5749725 1:3:7.5* 5ms83 0.34072094 1.6071426 1:3:7.5* 5ms83 0.3317312 1.7331781 1:3:7.5 583 0.35979336 2.28014 1:3:7.5 583 0.45316252 3.2084961 1:3:7.5 583 0.55838888 3.9988349 1:3:7.5 583 0.54884864 4.0092211 BH+1:3:7.5 583 0.3262578 3.1492089 BH 583 0.13718115 2.3825649 BH 583 0 1.8683478 BH 5

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3. Rza-Zade, P.F.; Abduragimova, R.A.; Sedelnikov, G.S.; Afuzova, A. Study in the area of inorganic and physical chemistry, Akad. Nauk Azerb. SSR 1966, 71

2MgO.3B2O3.15H2O MgO.3B2O3.7.5H2O MgO.B2O3.3H2Ot/C MGO B2O3 t/C MGO B2O3 t/C MGO B2O3

25 0.06 0.056282 25 0.0631138 0.3 25 0.0524208 0.0625 0.055 0.052428 25 0.0575787 0.4 25 0.054288 0.0725 0.05 0.04845 25 0.0584354 0.5 25 0.0565573 0.0825 0.045 0.04437 25 0.0606603 0.6 25 0.0590241 0.0925 0.04 0.040233 25 0.0634787 0.7 25 0.0616184 0.125 0.035 0.036123 25 0.0666637 0.8 25 0.0906098 0.225 0.03 0.032214 25 0.0701297 0.9 25 0.121822 0.325 0.025 0.028907 25 0.0738404 1 25 0.153839 0.425 0.02 0.027393 25 0.0777796 1.1 25 0.186184 0.5

0 0.02 0.04 0.06 0.08 0.1 0.120

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1 5 - BH - 35C5 - 1:3:7.55 - 2:3:155 - MH

m MgO

m B

2O3

0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16

-0.2

-1.66533453693773E-16

0.2

0.4

0.6

0.8

1

1.2

1.43 - MH - 45C 3 - 1:1:33 - 2:3:15 3 - 1:3:7.53 - BH 45C - M(OH)2 - calc.45C - 2:3:15 - calc. 45C - 1:3:7.5 - calc.45C - B(OH)3 - calc.

m MgO

m B

2O3

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25 0.015 0.034602 25 0.0819408 1.2 25 0.218629 0.625 0.0181987 0.028 25 0.251051 0.725 0.0171384 0.029 35 0.0801696 0.4 25 0.283379 0.825 0.0164917 0.03 35 0.0768672 0.5 25 0.315574 0.925 0.0142853 0.04 35 0.0782862 0.6 25 0.34761 125 0.0139265 0.05 35 0.0810976 0.7 25 0.411161 1.225 0.0141187 0.06 35 0.0845845 0.8 25 0.505138 1.525 0.0145964 0.07 35 0.0885038 0.9 25 0.582252 1.7525 0.0152542 0.08 35 0.0927543 1 25 0.658351 225 0.0160385 0.09 35 0.0972882 1.1 25 0.718554 2.225 0.0169178 0.1 35 0.102081 1.225 0.0284016 0.2 35 0.107122 1.325 0.0422367 0.3 35 0.0349119 0.0425 0.0572941 0.4 45 0.105912 0.5 35 0.0359381 0.0525 0.0731772 0.5 45 0.102243 0.6 35 0.0375325 0.0625 0.0896737 0.6 45 0.103799 0.7 35 0.0393778 0.0725 0.106648 0.7 45 0.107052 0.8 35 0.0413853 0.08

45 0.111152 0.9 35 0.0435112 0.0945 0.115789 1 35 0.0457293 0.1

35 0.1 0.083435 45 0.120824 1.1 35 0.0706918 0.235 0.095 0.080489 45 0.126191 1.2 35 0.0980615 0.335 0.09 0.077454 45 0.13185 1.3 35 0.126454 0.435 0.085 0.074323 35 0.155348 0.535 0.08 0.07109 83 0.282757 1.2 35 0.184487 0.635 0.075 0.067747 83 0.291001 1.5 35 0.213728 0.735 0.07 0.064291 83 0.309026 1.75 35 0.242985 0.835 0.065 0.06072 83 0.330694 2 35 0.272205 0.935 0.06 0.057035 83 0.354609 2.25 35 0.301353 135 0.055 0.053248 83 0.380219 2.5 35 0.330409 1.135 0.05 0.049381 83 0.407255 2.75 35 0.359358 1.235 0.045 0.045481 83 0.435561 3 35 0.388193 1.335 0.04 0.041636 83 0.465035 3.25 35 0.445499 1.535 0.035 0.038017 83 0.495601 3.5 35 0.516443 1.7535 0.03 0.034993 83 0.527201 3.75 35 0.586638 235 0.025 0.033524 83 0.559785 4 35 0.586638 235 0.02 0.037496 83 0.593307 4.2535 0.0191493 0.04 83 0.627729 4.5 45 0.0236638 0.0335 0.0177786 0.05 83 0.699123 5 45 0.0243777 0.0435 0.017563 0.06 83 0.773694 5.5 45 0.0255361 0.0535 0.0178196 0.07 45 0.0269225 0.0635 0.0183449 0.08 70 0.202586 1 45 0.0284676 0.0735 0.0190476 0.09 70 0.209918 1.2 45 0.0301342 0.0835 0.0198786 0.1 70 0.222278 1.4 45 0.031899 0.0935 0.03157 0.2 70 0.236948 1.6 45 0.262102 135 0.0459969 0.3 70 0.253123 1.8 45 0.28871 1.135 0.0617307 0.4 70 0.270473 2 45 0.315281 1.235 0.06993 0.45 70 0.288838 2.2 45 0.341799 1.335 0.0783031 0.5 70 0.308125 2.435 0.086825 0.55 70 0.328273 2.635 0.095476 0.6 70 0.349239 2.8 70 0.00951611 0.0235 0.10424 0.65 70 0.370988 3 70 0.00981504 0.03

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35 0.113104 0.7 70 0.393492 3.2 70 0.0103069 0.0435 0.131088 0.8 70 0.0109243 0.05

70 0.0116422 0.0645 0.1 0.084316 70 0.012446 0.0745 0.095 0.081366 70 0.013325 0.0845 0.09 0.078332 70 0.0142711 0.0945 0.085 0.075212 70 0.0152778 0.145 0.08 0.071999 70 0.0277973 0.245 0.075 0.068693 70 0.043248 0.345 0.07 0.065293 70 0.0604856 0.445 0.065 0.061805 70 0.0789177 0.545 0.06 0.058242 70 0.098188 0.645 0.055 0.054633 70 0.118065 0.745 0.05 0.051029 70 0.138391 0.845 0.045 0.047526 70 0.159054 0.945 0.04 0.044309 70 0.179973 145 0.035 0.041755 70 0.222354 1.245 0.03 0.040785 70 0.286741 1.545 0.025 0.044686 70 0.340771 1.7545 0.0232905 0.0545 0.0221608 0.0645 0.0219943 0.07 83 0.00635689 0.0145 0.0222765 0.08 83 0.00615601 0.0245 0.0228272 0.09 83 0.0063571 0.0345 0.0235602 0.1 83 0.00667075 0.0445 0.0352795 0.2 83 0.0070635 0.0545 0.0502446 0.3 83 0.00752241 0.0645 0.0666292 0.4 83 0.00803977 0.0745 0.0751656 0.45 83 0.00861001 0.0845 0.0838769 0.5 83 0.00922877 0.0945 0.0927351 0.55 83 0.00989248 0.145 0.101719 0.6 83 0.0184955 0.245 0.11081 0.65 83 0.0297326 0.345 0.119996 0.7 83 0.0428216 0.445 0.138607 0.8 83 0.0572888 0.545 0.157479 0.9 83 0.0728083 0.645 0.17656 1 83 0.0891452 0.745 0.195811 1.1 83 0.106125 0.8

83 0.123618 0.983 0.0523859 0.1 83 0.141524 183 0.0572265 0.2 83 0.17828 1.283 0.0727177 0.3 83 0.235036 1.583 0.0907179 0.4 83 0.283282 1.7583 0.109926 0.5 83 0.332071 283 0.129839 0.6 83 0.381222 2.2583 0.150203 0.7 83 0.430615 2.583 0.170872 0.8 83 0.48017 2.7583 0.191751 0.9 83 0.52983 383 0.212781 1 83 0.579558 3.2583 0.233918 1.1 83 0.629326 3.583 0.255134 1.2 83 0.679113 3.75

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83 0.728905 470 0.2 0.13698 83 0.778691 4.2570 0.18 0.128198 83 0.828462 4.570 0.16 0.119083 83 0.702142 570 0.14 0.109553 83 0.777121 5.570 0.12 0.09951170 0.1 0.08888170 0.08 0.07780570 0.07 0.07241170 0.06 0.06776770 0.05 0.06570170 0.04 0.076924

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B(OH)3t/C MGO B2O3

25 0 0.45503125 0.005 0.47113525 0.01 0.48750825 0.015 0.50387625 0.02 0.52023825 0.025 0.53659325 0.03 0.55294225 0.04 0.5856225 0.045 0.601948

0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16

-0.2

-1.66533453693773E-16

0.2

0.4

0.6

0.8

1

1.2

1.43 - MH - 45C 3 - 1:1:33 - 2:3:15 3 - 1:3:7.53 - BH 45C - M(OH)2 - calc.45C - 2:3:15 - calc. 45C - 1:3:7.5 - calc.45C - B(OH)3 - calc.

m MgO

m B

2O3

0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.40

0.5

1

1.5

2

2.5

3 70C - ref. 3 - BH 70C - ref. 3 - 1:3:7.570C - ref. 3 - 1:1:3 70C - ref. 3 - MH70C - MH - calc. 70C - 1:3:7.5 - calc.70C -1:1:3 - calc. 70C - B(OH)3 - calc.

m MgO

m B

2O3

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25 0.05 0.61826825 0.055 0.63458125 0.06 0.65088625 0.065 0.66718325 0.07 0.68347325 0.075 0.69975525 0.08 0.71602825 0.085 0.73229525 0.09 0.748552

35 0 0.59567735 0.01 0.62894435 0.015 0.64577935 0.02 0.66261435 0.025 0.67944835 0.03 0.69628135 0.035 0.71311435 0.04 0.72994535 0.045 0.74677635 0.05 0.76360635 0.055 0.78043435 0.06 0.79726135 0.065 0.81408835 0.07 0.83091335 0.075 0.84773735 0.08 0.86455935 0.085 0.8813835 0.09 0.898235 0.095 0.91501935 0.1 0.93183735 0.15 1.0999535 0.12 0.999095

45 0 0.76910345 0.01 0.80324945 0.015 0.82061545 0.02 0.83798445 0.025 0.85535745 0.03 0.87273445 0.035 0.89011445 0.04 0.90749745 0.045 0.92488445 0.05 0.94227445 0.055 0.95966845 0.06 0.97706545 0.065 0.99446645 0.07 1.0118745 0.075 1.0292845 0.08 1.0466945 0.085 1.0641145 0.09 1.08152

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45 0.095 1.0989545 0.1 1.1163745 0.15 1.2908445 0.12 1.1861245 0.125 1.2035645 0.13 1.2210145 0.135 1.2384645 0.14 1.2559245 0.145 1.2733845 0.15 1.29084

70 0 1.3936270 0.005 1.4114970 0.01 1.4305470 0.02 1.4687570 0.03 1.5070270 0.04 1.5453470 0.05 1.583770 0.06 1.6221170 0.07 1.6605770 0.08 1.6990870 0.09 1.7376370 0.1 1.7762470 0.15 1.9700870 0.2 2.1652770 0.25 2.3618670 0.3 2.5599170 0.35 2.7594870 0.4 2.960670 0.45 3.1633570 0.5 3.36778

83 0 1.8633483 0.005 1.8819683 0.01 1.9021783 0.02 1.9428283 0.03 1.9835683 0.04 2.0243783 0.05 2.0652483 0.06 2.1061883 0.07 2.1471883 0.08 2.1882583 0.09 2.2293983 0.1 2.270683 0.15 2.4777183 0.2 2.6866683 0.25 2.897583 0.3 3.110383 0.35 3.3251283 0.4 3.5420383 0.45 3.76107

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83 0.5 3.9823283 0.55 4.2058383 0.6 4.4316683 0.65 4.6598883 0.7 4.89055

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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.90

0.5

1

1.5

2

2.5

3

3.5

4

4.5

5

5 - 1:1:3 - 83C5 - 1:3:7.55 - BH5 - 1:3:7.5 metast.83C - MH - calc.83C - 1:3:7.5 - calc.83C - 1:1:3 - calc.83C - B(OH)3 - calc.

m MgO

m B

2O3

0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.40

0.5

1

1.5

2

2.5

3 70C - ref. 3 - BH 70C - ref. 3 - 1:3:7.570C - ref. 3 - 1:1:3 70C - ref. 3 - MH70C - MH - calc. 70C - 1:3:7.5 - calc.70C -1:1:3 - calc. 70C - B(OH)3 - calc.

m MgO

m B

2O3

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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.90

0.5

1

1.5

2

2.5

3

3.5

4

4.5

5

5 - 1:1:3 - 83C5 - 1:3:7.55 - BH5 - 1:3:7.5 metast.83C - MH - calc.83C - 1:3:7.5 - calc.83C - 1:1:3 - calc.83C - B(OH)3 - calc.

m MgO

m B

2O3