cyanoacrylate adhesive eximcorp india pvt. ltd

SAFETY DATA SHEET CYANOACRYLATE ADHESIVE

Eximcorp India Pvt. Ltd. KHASARA NO. 87/1, 50TH KM, MILESTONE, ROHTAK ROAD, NEAR SARASWATI DHARAM KANTA, NEW DELHI-110041, INDIA This safety data sheet has been prepared in accordance with the requirements of EC Directives 1999/45/EC and 2001/58/EC and provides information relating to the safe handling and use of the product:

1. Product and Company Information

2. Composition / Information on Ingredients Nature - Cyanoacrylate Adhesive Hazardous Components in Product Component Name %WT CAS R Phrases EC No Ethyl Cyanoacrylate 86-99 7085-85-0 Xi R36/37/38 230-391-5 Polymethyl Methacrylate

1-14 9011-12-7 Xi R36/37/38 n/e (polymer)

3. Hazard Identification

Danger Cyanoacrylate – Bonds skin and eyes in seconds. Keep out of the reach of children. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and protective mask,

4. First Aid Measures Inhalation: Remove to fresh air and rest.

If recovery is not rapid call for prompt medical attention.

Eyes: Cyanoacrylates bond eyelids in seconds. Irrigate thoroughly with water for at least 15 minutes. Take care not to wash chemical from one eye to another. If the eyelid is bonded closed, do not force open. Cover with wet pad soaked in warm water. Get prompt medical attention, in case solid particles of cured cyanoacrylate trapped behind the eye cause any abrasive damage. Keep eye covered with wet pad until debonding is complete, usually 1-3 days. (Cyanoacrylate will Cyanoacrylate will bond to eye protein, causing a lachrymatory effect that aids debonding).

Skin: Do not pull bonded skin apart. Remove contaminated clothing. Wash with soap/cleanser and rinse with plenty of water. Any bonded skin should be gently peeled apart with the aid of a blunt object, preferably after soaking in warm, soapy water. If irritation persists, obtain medical attention. In the case of large spills on skin, superficial burns may occur-treat accordingly.

Ingestion: Ensure that breathing passages are not obstructed. Give plenty of water to drink. Do not induce vomiting. The product will polymerize immediately in the mouth, making it almost impossible to swallow. Saliva will separate the solidified product from the mouth over a period of hours. Seek medical attention.

Product Name Cyanoacrylate Adhesive Trade Name 21st Century Supplier Eximcorp India Pvt. Ltd. Address Khasara no. 87/1, 50th km, Milestone, Rohtak Road, Near

Saraswati Dharam Kanta, New Delhi-110041, India Phone Number Tel: 91 98910 38202 Fax Number Fax:91 11 41063444


Eximcorp India Pvt. Ltd. KHASARA NO. 87/1, 50TH KM, MILESTONE, ROHTAK ROAD, NEAR SARASWATI DHARAM KANTA, NEW DELHI-110041, INDIA

5. Fire-Fighting Measures

Suitable Extinguishers:

Alcohol resistant foam. Dry powder. Carbon dioxide. Water spray/fog.

Unsuitable Extinguishers:

Direct water jets.

Hazardous Decomposition:

Toxic fumes are produced in fire (CO, CO2, nitrogen oxides).

Special Procedures: Do not breathe decomposition products and fumes. Use approved self-contained breathing apparatus. Wear fire retardant clothing. Wear eye protection. Use water spray to cool containers. Prevent runoff from fire control from entering waterways. Large fires should only be dealt with by trained personnel.

6. Accidental Release Measures

Exposure Controls: Refer to Section 8 – Personal Protection. Ventilate area. Evacuate

personnel. Use approved self-contained breathing apparatus. Do not allow spill to enter drains and watercourses.

Personal Protection:

Wear suitable respiratory protection in confirmed spaces. Wear polythene gloves. Use eye protection such as goggles to BS EN 166 Chemical Grade

Disposal Considerations:

Absorb in inert material such as sand or absorbent granules (do not use cloths) or polymerize slowly with water and scrape up. Dispose in accordance with local regulations.

7. Handling and Storage

Handling: Avoid skin and eye contact. Avoid inhalation of vapour. Ensure

adequate ventilation – Local Exhaust Ventilation may be required. Wear eye protection and gloves. Ambient Relative Humidity should be >40% to minimize discomfort.

Storage: Store in tightly closed labeled containers. Store in a cool, dry, well-ventilated area.

8. Exposure Controls / Personal Protection

Occupational Exposure Limit:

OES for ethyl cyanoacrylate is 0.3 ppm = 1.5mg/m3 (STEL 15 min. TWA, as stated in EH40/2000) Wear polythene gloves. Wear suitable overalls or apron if usage is large and change if contaminated. Wear suitable eye protection such as BS En 166 Use in well-ventilated areas – Use mechanical ventilation if necessary to maintain vapour level below TLV. If excessive inhalation in a poorly ventilated areas is likely then use a respirator with filter type P After contact with skin wash off immediately



9. Physical & Chemical Properties

Appearance: Clear and almost colourless liquid ( black RT grades, 2 white RT) Odour: Sharp, Pungent pH: n/e Boiling point/range: >150° C Melting point/range: n/e Flash point: >85° C (C.O.C.) Flammability: NON-FLAMMABLE Auto flammability: n/e Explosive properties: None Oxidizing properties: None Vapour pressure: ~ 0.2 mm Relative density: 1.04 – 1.10 depending on grade Solubility: polymerizes in water ( Note – soluble in acetone) Vapour Density: n/e Viscosity: Various – from 3cP (water-thin) to gel Evaporation rate (Bu Ac =1): n/e (n/e=not established)

10. Stability and Reactivity

Stable at normal temperatures. Will polymerizes rapidly on contact with water. Material to avoid: strong oxidizing agents, water, alkalis, amines, alcohols. Conditions to avoid: high temperature, moisture & direct sunlight. No hazardous decomposition products when stored and handled correctly.

11. Toxicological Information

Oral: LD50 oral-rat>5000mg/kg. Considered to have relatively low toxicity. Products is almost impossible to swallow, due to polymerization in mouth.

Skin: LD50 skin-rabbit >2000mg/kg. Inhalation: see section 8 for OES

Acute effects: eye watering, irritation of nasal cavities and respiratory tract and irritation and redness at the site of skin contact. Repeated skin contact may possibly cause dermatitis in sensitive individuals. Prolonged and repeated over-exposure to high concentrations of vapours may lead to sensitizing.

12. Ecological Information

Ecotoxicity: No specific data available, but expected to be very low. Persistence: No specific data available Bio-accumulative potential: No specific data available Mobillity: No specific data available, but expected to be very low.

13. Disposal Considerations

Polymerize adhesive by adding slowly to water (~10:1, adhesive: water). Add water to contaminated packaging and then dispose of. Do not discharge into drains or watercourses Dispose of in accordance with local regulations



X

14. Transport Information

Not classified as hazardous for transport

15. Regulatory Information

a) Risk & Safety Danger – cyanoacrylate. Bonds skin and eyes in seconds. Keep out of the reach of children

R36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN S24/25 Avoid contact with skin and eyes S26 In case of contact with eyes, rinse immediately with plenty of water

and seek medical advice S37 Wear suitable gloves. b) Other Regulations Health & Safety at Work etc. Act 1974 Control of Substances Hazardous to Health Regulations 1994 Environmental Protection Act 1990 Special Waste Regulations 1996

This Safety Data Sheet is compiled with reference to The Chemicals (Hazard Information and Packaging for Supply) regulations 1994 (CHIP2), which implement the Council Directives 67/548/EEC (The Dangerous Substances Directive) and 88/379/EEC (The Dangerous Preparations Directive), and subsequent amending regulations, up to and including The Chemicals (hazard Information and Packaging for Supply) Regulations 2000 (CHIP2000), which implements the 26th ATP of 67/548/EEC/

16. Other Information

The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Eximcorp India Pvt Ltd nor its distributor companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). This safety data sheet was prepared in accordance with Commission Directive 2001/59/EC adapting to technical progress for the 28th time Council Directive 67/548/EEC and Commission Directive 1999/45/EC

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cyanoacrylate adhesive eximcorp india pvt. ltd

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