curriculum vitae vincent l. pecoraro - labic...

Curriculum Vitae

Vincent L. Pecoraro

Business: Department of Chemistry Home: 3462 Miller Rd

University of Michigan Ann Arbor, MI 48103

Ann Arbor, MI 48109 (734) 663-3809

(734) 763-1519

Skype: vlpec1

ORCID ID: 0000-0002-1540-5735

Personal: Born August 31, 1956

Freeport, New York

Marital Status: Married (Peggy Carver)

American Citizen

Education:

8/84 National Institutes of Health, Postdoctoral Fellow,

University of Wisconsin, Madison

(Advisor: W.W. Cleland)

9/81 Ph.D., Chemistry, University of California, Berkeley

(Advisor: K.N. Raymond)

6/77 B.S., Biochemistry, University of California, Los Angeles

(Advisor: W.F. Libby)

Professional Experience:

Present John T. Groves Collegiate Professor, Department of Chemistry and Senior

Research Scientist, Biophysics Research Division, University of Michigan, Ann Arbor

Membership in Institutes and Interdisciplinary Programs (U of M)

Center for Molecular Genetics (Exec. Comm., 1987-90),

Molecular Biophysics Training Program (PI, 1989-90),

Cellular Biotechnology Training Program

Chemistry Biology Interface Training Program (Director, 2004-2012)

Chemical Biology Ph.D. Program (Program Committee, 2004-)

Blaise Pascal International Chair for Research, University of Paris-11 (2011-12)

1992-2005 Professor, Department of Chemistry

4/1998 Professeur Visité, Université de Paris-Sud (11), Orsay, France

1-8/98 Visiting Professor, Wilhelms Westfalische Universität, Münster, Germany

8-12/97 Visiting Research Scientist, Merck Central Research, Rahway

1989-92 Associate Professor, Department of Chemistry,

University of Michigan, Ann Arbor

1-6/1991 Visiting Associate Professor of Chemistry,

University of North Carolina, Chapel Hill

1984-9 Assistant Professor, Department of Chemistry,


Professional Societies:

American Association for the Advancement of Science (Fellow 2001-)

American Chemical Society

American Society of Biochemists and Molecular Biologists

Society of Biological Inorganic Chemistry

Sigma Xi

Alpha Chi Sigma (Chemistry Fraternity)

Honors, Awards and Fellowships:

National Institutes of Health Postdoctoral Fellow (1981-1984)

Horace H. Rackham Foundation Fellow (1985)

Eli Lilly Foundation Fellow (1985)

G.D. Searle Biomedical Research Scholar (1986-1989)

Alfred P. Sloan Fellow (1989-1990)

LS&A Award for Excellence in Undergraduate Instruction (1991)

Faculty Recognition Award, University of Michigan (1993)

ACS Akron Section Award for Excellence in Chemistry (1995)

Frontier’s Lecturer, Texas A & M University (1996)

Mary Kapp Lecturer, Virginia Commonwealth University (1997)

Karcher Lecturer, University of Oklahoma (1999)

PittCon Lecturer, Duquesne University (2004)

Alexander Von Humboldt Award for Senior US Scientists (1998-99)

Chair, Metals in Biology Gordon Conference, (2000)

Fellow, American Association for the Advancement of Science (2000)

US Young Investigator for IUPAC Assembly (2001)

Margaret and Herman Sokol Faculty Award in the Sciences (2004-5)

Distinguished Faculty Achievement Award, University of Michigan (2008)

La Chaire Internationale des Recherche Blaise Pascal (2010-2012)

Taiwan National Lecturer (2010)

ACS Fellow (2010-)

Vanadis Award (2010)

ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry (2016)

2016 Luigi Sacconi Memorial Lecture, University of Florence, Florence, Italy

2017 Kenneth N. Raymond Lecturer, University of California, Berkeley

Research Interests:

Present Synthetic models for the active site structure and chemical mechanism of manganese

enzymes. Biological chemistry of vanadium. Development of the chemistry of

metallacrowns. De Novo metallopeptide design.

8/84 The use of cobalt(III) and chromium(III) nucleotides to elucidate

the mechanism of phosphoryl transfer in kinases. Stability, structure

and metal ion exchange kinetics of M(II) nucleotide phosphorothioates.

8/81 Determination of the metal binding residues in transferrin.

Stability of Fe(III), Ga(III) and In(III) complexes of multidentate

catecholate chelating agents. Mechanism of iron transport to

bacteria by siderophores.

Research Group (Winter, 2019)

1 postdoctoral, 4 graduate, 3 undergraduate, 1 Rotation, 1 Visiting Scholars

Ph.D. Theses

Xinhua Li, 1989 "Preparation of Synthetic Models for the Oxygen Evolving Complex and

Vanadium Bromperoxidase".

David James Detlefsen, 1990 "Binding and Structural Studies of Modified Electron

Transfer Proteins of Bacterial Respiration."

Linda Maxine Briggs, 1990 "Cloning, Expression and Copper Based Regulation of

Plastocyanin from Synechocystis 6803"

Myoung Soo Lah, 1990 "Development of Metallacrowns and Preparation of Magnetic

Chains"

Erlund John Larson, 1991 "Synthetic Models for the Oxygen Evolving Complex and

Manganese Catalase"

Salman Mustafa Saadeh, 1992 "Manganese Complexes with an All Oxygen Coordination

Environment as Models for Mn Ligninase"

Brian R. Gibney, 1994 "12-Metallacrown-4: A Structural and Functional Analogue of 12-

crown-4"

Andrew Gelasco, 1995 “Low Valent Manganese Complexes as Functional Models for the

Mn Catalases and the Alternate Catalase Reaction of the Oxygen Evolving Complex”

Gregg Dieckmann, 1995, “Use of Metal Binding De Novo Designed -Helical peptides in

the Study of Metalloprotein Structures”

Ann B. Stemmler, 1996, “Synthetic Strategies for Expanding the Scope of Metallacrowns”

Brent Hamstra, 1997, “Models of Vanadium Haloperoxidases”

Neil Law, 1999, “Models for the Reactivity of Mn di-2-oxo cores in the Oxygen Evolving

Complex”

Aaron Small, 2000, “Test of the Immiscibility Concept for the Induction of Smectic

Layering in Nematic Liquid Crystals” (Co-advisor with Prof C. Pugh)

Jeffrey J. Bodwin, 2001, “Designing Solids Using Metallacrowns”

Tom Smith II, 2001, "Spectroscopic and Reactivity Models for Vanadium

Haloperoxidases"

Wen-Yuan Hsieh, 2002, "Synthesis and Reactivity of High Valent Manganese Complexes"

Annabel Van Noord, 2003, “Molecular Recognition by Chiral 15-Metallacrown-5

Metallamacrocycles”

Manolis Matzepetakis, 2004, “De Novo Design of Heavy Metal Binding Proteins”

Joslyn Yudenfreund Kravitz, 2005, “Computational Studies of Vanadium Haloperoxidases”

(co-advisor with Prof. H. Carlson)

Curtis Zaleski, 2005, “Characterization of Metallacrowns as Single Molecule Magnets”

Debdip Ghosh, 2006, “Thermodynamics and Kinetics of Heavy Metal Binding to de Novo

Designed Peptides,”

Choongsun Lim, 2008, “Metallacrowns as Hosts”

Curtis Schneider, 2008, “Synthetic and Computational Models for Biomimetic Chiral

Sulfoxidations,”

Saumen Chakraborty, 2010, “Structural and Spectroscopic Analysis of Cd binding de

novo Designed Peptides”

Joseph Jankolovits, 2012, “Assembly, Solution Thermodynamics and Luminescent

Properties of Metallacrowns”

Thadeus Boron, III, 2012, “Metallacrown Molecular Magnets”

Melissa Zastrow, 2013, “De Novo Design Zn Hydrolases”

Fangting Yu, 2014, “De Novo design Cu Nitrite Reductases”

David Chow, Jefferson Plegaria and Alison Tebo April 2015, Leela Ruckthong, 2015,

Catherine Mocny, 2016, Jacob Lutter, 2018.

Grant History

Present (Direct Costs only)

1. NIH (De Novo Peptide design) (2014-19) $1,250,000 (est)

2. NSF (metallacrowns) (2017-20) $362,000

3. Le Studium Consortium (metallacrowns) (2018-19) $8,000

Submitted (Direct Costs Only)

4. NIH (Renewal of 1) (2019-24) $1,400,000 (est)

Funded Group Proposals:

1. Governor's Research Excellence and Economic Development Funds to Chemical Biosciences $950,000

(≈$300,000 to chemistry)

2. NSF Equipment Proposal X-ray Diffractometer Proposal (≈$250,000)

3. NSF Raman Spectrometer $110,000.

4. Molecular Biophysics Training Program $257,000.

5. NIH BRSG Ultracentrifuge Rotors Proposal $8,500

6. NIH Major Equipment Grant: A 500 Mhz NMR Spectrometer, $ 400,000.

Previous Funding (Direct Costs only):

1. Rackham Grant and Fellowship (1985) $ 10,000

2. NIH (gentimycin, subaccount) (1998-03) $ 80,000

3. Biomedical Research Support Grant (1985) $ 6,000

4. Lilly Fellowship (1985) $ 5,000

5. ACS/PRF Type G (1985-7) $ 15,000

6. Program for Protein Structure (1986) $ 8,000

7. Biomedical Research Support Grant (1987) $ 8,000

8. Program for Protein Structure (1987) $ 12,000

9. Research Mentor Program (OVPR) (1987) $ 10,000

10. USDA* (1987) $ 50,000

11. NSF (1985-6) $ 104,000

12. G.D. Searle/Chicago Comm. Trust (1986-9) $ 162,162

13. NIH (BRSG) (1989-90) $ 6,300

14. NIH (Mn Chemistry yrs 1-18) (1988-06) $ 2,300,000

15. Alfred P. Sloan Fellowship (1989-91) $ 25,000

16. NIH (V Chemistry) (1989-98) $ 1,240,000

17. NATO Collaborative Research (1993-5) $ 5,300

18. NIH (De Novo Peptide design) (2003-14) $2,000,000

19. NSF (metallacrowns) (2001-17) $2,720,000

20. NIH (CBI training program) (2004-14) $1,200,000 (est)

21. Blaise Pascal Chair (2011-12) $298,000

22. Italy/USA Bilateral grant (2013-2019) $10,000

*USDA "Modelling the Active Center of the Oxygen Evolving Complex of Photosystem II," USDA,

funded, $105,000 (total costs) 1987-9. Second year required to be returned due to NIH funding.

Meetings Attended and Invited Lectures

(since appointed to Faculty at U of M)

Gordon Conferences

1984 Enz., Coenzymes, Metabolic Pathways (1 poster)

1986-9 Metals in Biology (1 poster/meeting)

1988 Photosynthesis (1 poster, 1 Lecture)

1991 Metals in Biology (1 poster)

1991 Photosynthesis (1 Lecture)

1992 Metals in Biology (1 Lecture)

1993-4 Metals in Biology (1 poster/meeting)

1994 Photosynthesis (1 Lecture)

1995 Metals in Biology (1 Lecture)

1996 Metals in Biology (1 Poster)

1996 Student GRC: Metals in Biology (Session Chair)

1997 Metals in Biology (1 poster)

1999 Metals in Biology (invited lecture, MEETING VICE-CHAIR)

2000 Metals in Biology (MEETING CHAIR)

2001 Inorganic Reaction Mechanisms (1 invited lecture)

2002 Inorganic Chemistry (1 invited lecture)

2003 Metals in Biology (“Thursday night” lecture)

2004 Environmental Bioinorganic Chemistry (1 invited lecture)

2005 Metals in Biology

2008 Renewable Energy: Solar Fuels (1 invited lecture)

2010 Metals in Biology

2010 Metals in Medicine

2011 Metals in Biology (Session Chair)

2012 Metals in Biology (1 Invited Lecture)

2014 MIB; Graduate Research Symposium (session chair and lecturer)

2014 Biology and Chemistry of Peptides (1 invited lecture)

ACS National Meetings

4/85 Miami (1 poster)

8/85 Chicago (3 posters,1 symposium organized)

4/86 New York (1 poster,1 symposium organized)

8/86 Anaheim (1 poster, 1 symposium organized)

4/87 Denver (1 poster, 1 symposium organized)

9/87 New Orleans (1 poster, 1 symposium organized)

6/88 Toronto (7 posters, coauthor 1 talk)

9/88 Los Angeles (1 invited talk, 1 symposium organized)

8/90 Washington (2 talks (students), 1 poster)

8/91 New York (1 symposium talk)

4/92 San Francisco (2 posters)

3/93 Co-Organizer symposium on Mechanistic Bioinorganic Chemistry, Denver (1 invited

presentation, 2 posters)

3/94 Organizer From Siderophores to Stereognostics Symposium in honor of KN Raymond for

Bader Award (1 talk, 2 posters)

12/95 Pacific Basin Meeting, Honolulu (1 symposium talk)

11/97 Chemical Congress of North America, Cancun, Mexico (1 invited lecture on

Vanadium Chemistry)

8/98 Oxygen Activation Session, Boston ACS, 1 invited lecture

4/01 Metallopeptide Design, San Diego ACS, 1 invited lecture

4/02 Finite and Infinite Polygonal Assemblies, Orlando ACS, 1 invited lecture

9/06 Biological Chemistry of Vanadium, 1 invited lecture

3/07 Biomimetics for practical function (1 invited lecture)

4/08 Celebrating Bioinorganic, Supramolecular, Lanthanide and Actinide Chemistry with Ken

Raymond (1 invited Lecture)

4/08 Metals in Health and Disease (1 invited Lecture)

12/10 Molecular Modeling of Bioinorganic Chemistry (1 keynote lecture) Honolulu, Hawaii

8/11 Fifty Years of Inorganic Chemistry (1 invited lecture), Denver, Colorado

8/13 Molecular Magnetism (1 invited lecture) Indianapolis, Indiana

3/14 Supramolecular Chemistry (1 invited lecture) Dallas, Texas

8/15 De Novo Enzyme Design (1 invited Lecture) Boston, MA

8/15 Design of Electron Transfer Proteins (1 invited Lecture) Boston, MA

3/16 ACS Award Lecture for Distinguished Service in the Advancement of Inorganic Chemistry,

A Short History of Metallacrowns, San Diego, CA

4/17 ACS Celebration of 60 years of Inorganic Chemistry, invited speaker, ACS National

Meeting, San Francisco

8/18 ACS Biochemistry, (1 invited lecture) ACS National Meeting, Boston

3/19 Symposium Honoring Debbie Crans for ACS Award for Service to Inorg. Chem., Orlando,

FL. (1 invited lecture)

ACS Regional Meeting

6/87 Columbus (1 invited symposium talk)

6/94 Chair, Inorganic Division, ACS Central Regional Meeting in Ann Arbor

6/94 Ann Arbor (1 invited symposium talk)

5/97 Midland (1 invited symposium talk)

5/00 Cincinnati (1 invited symposium talk)

11/04 South East Regional Meeting, Raleigh, NC (1 invited symposium talk)

6/08 Central Regional Meeting (1 invited Symposium Talk)

10/17 Rocky Mountain Regional Meeting (1 invited symposium presentation)

6/19 Central Regional Meeting (1 invited Symposium Talk)

Misc. Conferences

4/85 II Int. Conf. Bioinorg. Chem. (1 poster)

4/85 FASEB Nat. Meeting (1 poster)

8/86 VII Int. Cong. Photosynthesis (1 poster, 1 short talk)

10/86 Midwest Photosynthesis Conference (1 poster)

4/87,88 Searle Scholar's Meeting (1 poster)

6/87 III Int. Conf. Bioinorg. Chem. (1 poster)

10/87 Inorg. Discussion Weekend, Univ. Windsor (3 posters)

10/87 Midwest Photosynthesis Conference (1 poster)

4/89 Searle Scholars Meeting [Chicago, IL (1 invited talk)]

6/89 Int. Conf. Coord. Chemistry [Brisbane, Australia

(1 invited poster, session chairman)]

6/89 Marine Bioinog. Chem. Meeting [Heron Island, Australia

(1 invited talk)]

7/89 IV Int. Conf. Bioinorg. Chem. [Boston, MA (1 invited

talk, 1 poster)]

8/89 VIII Int. Cong. Photosynthesis [Stockholm, Sweden (1

poster)]

9/89 Metal Ion Biosensors [Chapel Hill, N.C. (1 poster)]

2/90 The Inorganic/Molecular Biology Interface, UCLA

Symposium Series [Taos, N.M. (1 invited talk)]

4/91 North Carolina ACS Sectional Meeting (1 talk)

7/91 NSF Workshop at University of Georgia, Athens (invited talk on Manganese

Biochemistry)

3/92 The Inorganic Chemistry/Molecular Biology Interface, Keystone Symposium Series

on Cellular and Molecular Biology [Meeting Chairman (with S. Lippard and M.

Karin)]

1/93 Enzyme Mechanisms Meeting [Key Largo, Fl]

6/94 NATO Advanced Study Institute on Bioinorganic

Chemistry [Rhodes, Greece, Primary lecturer, 2 lectures]

7/94 Int. Conf. Coord. Chemistry, Kyoto, Japan [invited lecture]

7/94 Macrocycle Satellite Conference, Fukuoka, Japan [invited lecture]

11/94 ESF Advanced Course in Oxygenic Photosynthesis, Gif-sur-

Yvette, France [invited speaker]

8/95 NSF Workshop at University of Georgia, Athens (invited talk on Manganese

Biochemistry)

8/95 Xth Int. Cong. Photosynthesis [Montpelier, France (1 poster)]

9/95 VII Int. Conf. Bioinorg. Chem. ICBIC [Lübeck, Germany (1 invited talk)]

6/96 Cu, Fe and Mn in Biology [Minneapolis (1 inv. talk)]

8/96 Int. Conf. Coord. Chem., ICCC, Vancouver, Canada (1 inv. lecture)

10/96 ESF Advanced Course in Photosynthesis, Sitges, Spain [invited speaker]

12/96 Symposium on Bioorganic and Bioinorganic Chemistry,

Graduiertenkolleg “Hochreactive Mehrfachbindungssysteme”,

Universität Münster, Germany [1 inv. lecture]

5/97 ESF Conference on Bioinorganic Chemistry, Tomar, Portugal [1 inv. lecture]

6/97 Canadian Chemical Society, Plenary Lecturer, Windsor, Canada

6/97 5th International Symposium on Metallomesogens, Neuchâtel,

Switzerland [1 invited lecture]

7/97 VIII Int. Conf. Bioinorg. Chem. ICBIC [Yokohama, Japan (1 invited lecture)]

5/98 European Network on Photosynthesis, Sigtuna, Sweden (1 inv. lecture)

6/98 Italian Society of Inorganic Chemistry, Maratea, Italy (plenary)

8/98 Int. Conf. Coord. Chem., ICCC, Florence, Italy (1 inv. lecture)

8/98 XIth Int. Cong. Photosynthesis, Budapest, Hungary (1 invited talk)

4/99 5th International Symposium on Applied Bioinorganic Chemistry, Corfu, Greece (1

plenary lecture)

6/99 International Conference on Metallomesogens, Rotenburg an der Fulda, Germany

(1 invited lecture)

8/99 GDCh/IUPAC, Biological Chemistry of Vanadium, Berlin, (1 invited lecture)

2/00 European TMR Network on Photosynthesis, Dublin, Ireland (1 invited lecture)

7/00 Int. Conf. Coord. Chem., ICCC, Edinburgh, Scotland (1 invited talk)

7/00 European BioInorganic Chemistry Conference, EUROBIC, Toulouse, France (1

invited talk)

11/00 Symposium on Electron Transfer Processes, Graduiertenkolleg “Hochreactive

Mehrfachbindungssysteme”, Universität Münster, Germany [1 inv. lecture]

3/01 Cost D-8 Working Group “Metals in Biology,” Dublin, Ireland (1 invited lecture)

5/01 et:pt:HAT:pcet: 40 years of Tunneling in Biology, Univ. Penn., (1 invited talk)

6/01 Physical Approaches to Biological Problems, A Symposium in Tribute to Gerald

Babcock, Michigan State University, (1 invited lecture)

8/01 International Conference on Bioinorganic Chemistry (ICBIC) Florence, Italy

(plenary lecturer)

1/02 PacifiKen 2002, A Conference in Honor of Kenneth N. Raymond, Berkeley,

California (Conference Organizer, 1 Lecture)

3/02 9th workshop DBMS IBS : Metals in Biology, Autrans, France (1 lecture)

9/02 ESF conference on "The Inorganic Side of Molecular Architecture" San Feliu de

Guixois, Spain (1 invited lecture).

4/03 5th International Symposium on Applied Bioinorganic Chemistry, Guanajuato,

Mexico, (1 plenary lecture)

7/03 11th international Conference on Bioinorganic Chemistry (ICBIC), Cairns, Australia,

(1 invited lecture)

8/03 5th International Conference on F-Group Elements, Geneve, Switzerland (1 Invited

Lecture)

9/03 COST D-21 Metals in Biology Working Group, Evaluator, (1 Plenary Lecture)

Thessaloniki, Greece

11/03 314th WE-Heraeus-Seminar "Water Oxidation in Photosynthesis" Bad Honnef,

Germany (1 invited lecture)

9/04 European BioInorganic Chemistry Conference, EUROBIC, Garmesch, Germany (1

invited talk)

9/04 4th International Symposium on Chemistry and Biological Chemistry of

Vanadium, Szeged, Hungary (Plenary lecture)

6/05 28th Annual Brazilian Society of Chemistry Meeting, Poços de Caldas, Brazil (1

Plenary lecture)

7/05 Santa Maria Workshop on Chemistry, Supramolecular Chemistry, Havana, Cuba (1

Plenary lecture, VISA DENIED BY US TREASURY)

7/05 1st Conference on Biomolecular Design, Chicago (Plenary Lecture)

9/05 Sonderforschungsbereich, "Metal Mediated Reactions Modelled after Nature,”

Friedrich-Schiller-University and the Max Planck Institute of Chemical Ecology,

Jena, Germany (1 invited lecture)

9/05 Xth International Conference on Bioinorganic Chemistry “Challenge for New

Generation”, Szklarska Poręba, Poland (1 invited lecture)

11/05 Annual Symposium at the Institute for Metals in Biology Grenoble (1 plenary

lecture).

5/06 COST D-21 Metals in Biology Working Group, Evaluator, (1 Plenary Lecture)

Leuvain, Belgium.

8/06 Int. Conf. Coord. Chem., ICCC, Capetown, South Africa (1 invited talk)

4/07 Royal Society Discussion Meeting: How Nature Uses Sunlight to Split Water (1

invited talk)

7/07 ICBIC, Vienna, Austria, (1 invited talk)

9/07 Int. Conference on Chirality at the Nanoscale, Sitges, Spain (1 talk)

3/08 Zing Conference on Coordination Chemistry, Cancun (1 talk)

7/08 Int. Symposium on Macrocyclic and Supramolecular Chemistry, Las Vegas, (1

invited talk)

7/08 6th International Symposium on Chemistry and Biological Chemistry of Vanadium,

Lisbon, Portugal (1 invited talk)

7/08 10th Int. Symposium on Activation of Dioxygen and Homogeneous Catalytic

Oxidation (1 Plenary Lecture)

8/08 4th EuChemMS Conference on Nitrogen Ligands in Coordination Chemistry,

Metal-Organic Chemistry, Bioinorganic Cheistry and Homogeneous Catalysis (1

Plenary Lecture)

9/08 9th EUROBIC, Wroclaw, Poland, (1 Invited Lecture)

9/08 3rd Int.Meeting of the Institute of Metals in Biology, Grenoble, France (1 invited

Lecture)

3/09 Zing Conference on Coordination Chemistry, Antigua (1 Plenary)

7/09 ICBIC, Nagoya, Japan (1 invited talk)

9/09 International Symposium on Applied Bioinorganic Chemistry, Debrecen, Hungary,

(1 Plenary lecture)

11/09 Molecular Science for Solar Fuels (1 invited Lecture) Sigtuna, Sweden

6/10 10th EUROBIC, Thessaloniki, Greece, (1 Plenary Lecture)

9/10 XIth International Conference on Bioinorganic Chemistry, Kudowa, Poland (1

invited lecture)

9/10 Chem.Comm. Conference, Osaka, Japan and Seoul, South Korea (1 plenary

lecture)

10/10 7th International Symposium on Chemistry and Biological Chemistry of Vanadium,

Toyama, Japan (Vanadis Award Address)

11/10 AsBIC, Kaohshiung, Taiwan (1 Keynote lecture)

6/11 Int. Symp. on Thermodynamics of Metal Complexes, Giardini Naxos, Italy (1

plenary lecture)

7/11 Int. Symp. Macrocyclic and Supramolecular Chemistry, Bristol, England (1 poster)

8/11 ICBIC, Vancouver, Canada (1 lecture)

9/11 Int. Conf on Nligands Granada, Spain (1 keynote lecture)

11/11 European Conference on Molecular Magnetism, Paris, France (1 Plenary)

12/11 International Symposium on Applied Bioinorganic Chemistry, Barcelona, Spain (1

lecture)

8/12 PacifiKen II, Portland, OR (invited lecture)

8/12 International Conference on f-elements, Udine, Italy (plenary lecturer)

9/12 11th EUROBIC, Granada, Spain, (1 keynote lecture)

9/12 ICCC Valencia, Spain (1 keynote lecture)

11/12 AsBIC VI, Hong Kong, (1 keynote lecture)

3/13 Metals in Biology and Medicine, Punta del Este, (1 Plenary lecture)

4/13 Argentinian Chemical Society, Rosario, (1 Plenary Lecutre)

7/13 ICBIC 16 (1 keynote lecture), Grenoble, France

8/13 12th International Symposium on Bioinorganic Chemistry, Wroclaw, Poland

(Plenary Lecture)

9/13 Italian Chemical Society, Parma, Italy (Plenary lecture)

6/14 International Conference on Chemistry and Biology of Vanadium (keynote

lecture) Padua, Italy

8/14 Brazilian Chemical Society National Meeting, Minas Gerais, Brazil (1 Plenary

lecture)

8/14 EUROBIC 12, Zurich, Switzerland (1 Session Lecture)

1/15 Foldamers, Bordeaux, France, (1 Plenary Lecture)

6/15 International Symposium on Applied Bioinorganic Chemistry, Galway, IR

7/15 ACCC5, Hong Kong, China

7/15 ICBIC 17, Beijing, China (Invited Lecturer)

9/15 12th International Symposium on Bioinorganic Chemistry, Karpacz, Poland (Invited

lecturer)

9/15 Sardinian Summer School on Medicinal Inorganic Chemistry, Sardinia, Italy

10/16 9th Conference on Metals in Toxicology and Oncology, Lexington, KY (Keynote)

6/17 ISABC (1 plenary lecture) Biomedical Applications of Near IR Lumiphores,

Toulouse, France

6/17 FrenchBIC (1 plenary lecture) Designing Metalloprotein Redox Catalysts

7/17 ICBIC 18, (1 Plenary Lecture) The Art of Metalloprotein Design, Florianopolis,

Brazil

8/17 Lecturer, Sardinian Summer School on Medicinal Inorganic Chemistry, Sardinia,

Italy (3 Lectures)

9/17 1st International Conference on Metallacrowns and Metallacryptates, invited

speaker, Parma, Italy

5/18 CuBIC (Keynote Lecture) Marseille, France

8/18 EuroBIC (Keynote Lecture) Birmingham, England

9/18 Copper in Medicine and Biology, Sorrento, Italy

6/19 International Conference on Biological Inorganic Chemistry, (1 invited lecture)

Interlaken, Switzerland.

University and Industrial Lectures

Lecture Titles: MN= Understanding Photosynthesis Using Modeling Chemistry

V= From Ozone Holes to Diabetes: Understanding the Biological

Chemistry of Vanadium

MC= Metallacrowns

MP= De Novo Designed Metallopeptides

O=Other

11/84 O University of Michigan (Inorg. Chemistry)

4/86 MN Wayne State University (Inorg. Chemistry)

10/87 MN University of Massachusetts, Amherst (Inorg. Chem.)

10/87 MN Middlebury College, Vermont (Dept. Colloquium)

10/87 MN University of Vermont, Burlington (Inorg. Chem.)

10/87 MN Concordia University, Montreal (Biochemistry)

11/87 MN Indiana University, Bloomington (Inorg. Chem.)

1/88 MN Bowling Green State University (Dept. Colloquium)

10/88 MN University of Maryland, College Park (Biochem)

10/88 MN Johns-Hopkins University (Inorg. Chem.) 10

10/88 MN Michigan State University (Inorg. Chem.)

11/88 MN Rutgers University (Inorg. Chem.)

11/88 MN Emory University (Inorg. Chem.)

11/88 MN University of South Carolina, Columbia (Biochem)

11/88 MN University of Georgia, Athens (Inorg. Chem.)

11/88 MN North Carolina State University, Raleigh (Biochem)

11/88 MN University of Michigan, Ann Arbor (Inorg. Chem.)

11/88 MN University of Wisconsin, Madison (Abbott Lecturer)

12/88 MN University of Michigan, Dearborn (Dept Colloquium)

1/89 MN University of California, San Diego (Inorg. Chem.) 20

2/89 MN University of California, Santa Barbara (Inorg. Chem.)

2/89 MN University of California, Davis (Inorg. Chem.)

2/89 MN University of California, Berkeley (Inorg. Chem.)

2/89 MN Iowa State University (Inorg. Chem.)

2/89 MN University of Iowa (Inorg. Chem.)

2/89 MN University of Kentucky, Lexington (Colloquium)

2/89 MN Univ. of North Carolina, Chapel Hill (Inorg. Chem.)

3/89 MN University of Notre Dame (Inorg. Chem.)

4/89 MN Kent State University (Inorg. Chem.)

11/89 O University of Michigan, Ann Arbor (MCCTA Meeting) 30

1/90 MN University of Michigan, Ann Arbor (Chem. Eng.)

2/90 MN Arizona State University, Tempe (Center for the Study of

Early Reactions in Photosynthesis)

3/90 MN University of Windsor (Colloquium)

4/90 MN Northwestern University (Colloquium)

5/90 MN Carnegie-Mellon University (Inorganic)

5/90 MC Monsanto Corporation (Catalysis Division)

5/90 MC University of Missouri, St. Louis (Colloquium)

10/90 MN Kalamazoo College (Colloquium)

1/91 MC University of North Carolina, Chapel Hill (Colloquium)

2/91 MC Duke University (Colloquium) 40

10/91 MN University of Utah (Colloquium)

10/91 MN Colorado State University (Inorganic)

10/91 MN University of Wyoming (Colloquium)

11/91 MN Princeton University (Colloquium)

11/91 MC University of California, Santa Barbara (Colloquium)

University and Industrial Lectures (continued)

11/91 MN University of California, Riverside (Colloquium)

11/91 MC Salutar Inc. (A division of NYCOMED medical imaging)

11/91 MN Stanford University (Inorganic)

11/92 MN Ohio State University (Inorganic)

12/92 MN University of Michigan, Ann Arbor (Pharmacy) 50

2/93 MN University of Rochester (Colloquium)

3/93 MN Bucknell University (Dow Lecturer)

3/93 MN Penn State University (Inorganic)

3/93 MN University of Michigan, Ann Arbor (Inorganic)

4/93 MC University of Minnesota (Inorganic)

4/93 MN North Dakota State University (Colloquium)

9/93 MC Michigan State University (Colloquium)

9/93 MN Purdue University (Colloquium)

10/93 MN North Carolina State University (Colloquium)

11/93 MC University of Michigan, Ann Arbor (Inorganic) 60

12/93 D Univ. Michigan, Ann Arbor (Protein Structure & Design)

2/94 MC Case Western Reserve University (Colloquium)

3/94 MC Bowling Green State University (Colloquium)

4/94 MC University of New Mexico, Albuquerque (Inorganic)

4/94 MN Arizona State University (Photosynthesis Center)

9/94 MC Massachusetts Institute of Technology (Inorganic)

9/94 MP Boston College (Colloquium)

11/94 MC Oakland University (Colloquium)

11/94 MN University of Paris-South, Orsay (Materials Research)

1/95 MC Columbia University (Colloquium) 70

5/95 MN University of Pennsylvania (Inorganic)

5/95 MC DuPont Central Research (Catalysis Group)

7/95 MC DuPont/Merck (Radioimaging Group)

10/95 MN Aristotle University of Thessaloniki (Colloquium)

10/95 MN Demokritos Institute (Materials/Chemistry)

10/95 MN University of Crete (Colloquium)

10/95 MC George Washington University (Colloquium)

11/95 MC Akron University (Akron Section Award Address)

2/96 MN Yale University

2/96 MC SUNY, Stony Brook 80

4/96 MN University of Nebraska (Yearly Bioinorganic Retreat)

4/96 MC Texas A&M University (Frontiers Lecturer)

9/96 MC Wayne State University (Inorganic Chemistry)

9/96 MC Eastern Michigan University (Colloquium)

10/96 MN Université de Paris-Sud, Orsay (Inorganic)

11/96 MP New College of South Florida (Colloquium)

12/96 MN University of Münster (Westfalisch Research Program)

4/97 MC EPIX Medical

4/97 MC Virginia Commonwealth University (Kapp Lecturer)

4/97 V Merck Pharmaceuticals

9/97 MN University of California, Davis 90

9/97 MC University of California, Berkeley

9/97 MP Stanford University

10/97 MC University of Illinois, Champagne-Urbana

10/97 MC University of Chicago (Colloquium)

10/97 MC University of Pennsylvania

10/97 MP Lucent Technologies


10/97 MC Princeton University

11/97 MC New College of South Florida (Colloquium)

12/97 V Columbia University (Inorganic Group)

1/98 MC/MPWestfälische Wilhelms-Universität, Münster (2 seminars) 100-1

2/98 MN University of Washington, Seattle

2/98 MC Frie University of Berlin, Germany

3/98 D Slater Institute, Amsterdam

3/98 MC Gorsaleus University, Leiden

4/98 MC/MN/MP Université de Paris-Sud, Orsay (3 seminars)

5/98 MN University of Mainz, Mainz

5/98 MC Max-Planck Institute, Mülheim 110

5/98 MC University of Marburg

5/98 MC University of Bielefeld

6/98 MN University of Basel

6/98 MN University of Berne

6/98 MC University of Freibourg

6/98 MC University of Neuchâtel

6/98 MC University of Lausanne

6/98 MC University of Geneve

6/98 MN Atomic Energy Institute, Grenoble

6/98 MC University of Grenoble 120

7/98 MN University of Toulouse

7/98 MC University of Bordeaux

10/98 MC University of British Columbia

10/98 MC Simon Frasier University, Vancouver

11/98 MC University of Victoria

11/98 V New College of the University of South Florida

11/98 MC University of South Florida

2/99 MP Wayne State University (Biochemistry)

4/99 MC University of Oklahoma (Karcher Lecture Series)

5/99 V Universite de Paris, Sud 130

5/99 MN CNRS, Saclay

6/99 MC Erlangen University

6/99 MC University of Darmstadt

6/99 MC University of Dortmund

6/99 MP University of Basel

8/99 V Westfälische Wilhelms-Universität, Münster

10/99 MN New College of the University of South Florida

10/99 MP University of South Florida

10/99 MC University of Florida, Gainesville

2/00 MP Haverford College 140

2/00 MN Johnson Institute, University of Pennsylvania

4/00 MC Southwest Texas State University

4/00 MC University of Texas, Austin

4/00 MC University of Texas, Dallas

4/00 MC Texas Tech University

5/00 MN Universite de Paris, Sud

5/00 MP Universite de Strasbourg

5/00 MC Universite de Strasbourg


10/00 MC Pennsylvania State University

2/01 MP University of Michigan, Biophysics 150

4/01 MN Texas A & M University

11/01 MC Indiana University

4/02 MP Massachusetts Institute of Technology

5/02 MP Universite de Paris-Sud, Orsay

7/02 MN University of Sao Paolo, Brazil

7/02 MN University of Florianopolis, Brazil

10/02 MP University of Cincinnati

11/02 MP University of Michigan-Dearborn

12/02 MC Bowling Green State University

1/03 MN University of Puerto Rico

1/03 MC Michigan State University 160

3/03 MP Arizona State University

3/03 MC University of New Mexico

3/03 MP University of California, Irvine

4/03 MP Carnegie Mellon University

4/03 MC University of Pittsburgh

4/03 MN University of Wisconsin-Madison

1/04 MN Université de Geneve

1/04 MP EPF-Lausanne (Colloquium)

2/04 MP Columbia University (Colloquium)

3/04 MN UC San Diego 170

4/04 MN Leiden University

5/04 MC Université de Paris-Sud

9/04 MN Duquesne University (PittCon Lecture)

9/04 V Duquesne University

2/05 MP University of Szeged

2/05 MP University of Debrecen

2/05 MN University of Veszprem

2/05 MN University of Budapest

4/05 MN New College of South Florida

4/05 MC University of South Florida, Tampa 180

4/05 MN University of Michigan, Ann Arbor (Sokol Award Lecture)

9/05 V Unilever Corporation, Port Sunlight, England

10/05 MP University of Utah

10/05 MC Wayne State University

1/06 MP Charles University, Prague

1/06 MP University of Brno

2/06 MC Joseph Fourier University, Grenoble

3/06 MP University of Vienna

4/06 MP University of Goetingen

4/06 MC University of Dortmund 190

5/06 MP University of Zurich

5/06 MC University of Erlangen

5/06 MN University of Jena

5/06 MC University of Dresden

5/06 V University of Paris, XI

1/07 MP University of Oregon

3/07 MP Concordia University (Merck-Frost Lecturer)

3/07 MP Wayne State University


1/08 MP Ohio State University

3/08 MP SUNY Buffalo 200

3/08 MP University of Rochester

4/09 MP Juniata College (Distinguished Visiting Scientist Series, 3 lectures)

5/09 MP University of Milan

5/09 MC University of Parma

5/09 MC University of Ferrara

1/10 MP UCSD

2/10 MP Arizona State University

10/10 MC Ulsan National Institute of Technology (UNIST), South Korea

11/10 MP Taiwan National University

12/10 MP California Institute of Technology 210

4/11 MP Universidad Autonoma de Barcelona

5/11 MP Universite de Paris V (Rene Descartes)

5/11 MP Universite de Paris XI (Orsay)

6/11 MP University of Parma

6/11 MP University of Pavia

6/11 MP University of Milan

6/11 MP Universite de Marseille

10/11 MP Universie de Paris VII

12/11 MC Universite de Toulouse

12/11 MP Universite de Toulouse 220

4/12 MP University of Calgary

5/12 MP Ecole Normal Superiore (Paris)

6/12 MC Universite d’Orleans

6/12 MP CEA-Grenoble

10/12 MC UC Davis

11/12 MC Blaise Pascal Closing Symposium, Université de Paris, Sud

11/12 MP Ecole Normal Superiore (Paris)

4/13 MC Johns Hopkins

4/13 MP University of Maryland (Pharmacy)

3/14 MP Bryn Mawr College

3/14 MC Wayne State University (Chemistry) 230

4/14 MP Brown University

10/14 MP Wayne State University (Pharmacy)

12/14 MP Rice University

1/15 MP Duke University (Chemistry)

1/15 MC NCSU (Chemistry)

4/15 MnV ExxonMobil/BASF summit on antioxidants

10/15 MP Florida International University

10/15 MP University of Miami

2/16 MP Luigi Sacconi Memorial Lecture 2015/2016, University of Florence

2/16 MP University of Siena, Siena, Italy 240

5/16 MP Max Planck Institute, Tuebingen, Germany

10/16 MP University of Houston

10/16 MP University of Wisconsin, Madison

5/17 MP 2017 Kenneth N. Raymond Honorary Lecture, UC, Berkeley

7/17 MP Pacific Northwest National Laboratories (PNNL), Richland, WA

9/17 MC Ecole Normale Superieure, Paris

9/17 MP University of Parma, Parma, Italy, Parma


12/17 MP Universitè Aix-Marseille, France

8/18 MP 2018 Haworth Lecture, University of Birmingham, Birmingham, England

3/19 MP Miami University (Ohio) 250

Teaching

Courses Taught: Chemistry 120 (Freshman Seminar) W’09,10

Chemistry 123 (General Chemistry) W'85

Chemistry 124 (General Chemistry) F'84

Chemistry 125 (General Chemistry Laboratory) W'89,90

Chemistry 302 (Soph. Inorganic Chem.) F'90, F'92, F’95, W’96, F’98, W03

Chemistry 303 (Soph. Bioinorganic Chem) W13-17

Chemistry 312 (Sophomore Synthesis Laboratory) F'94, W'95

Chemistry 399 (Undergraduate Research) W'85-W'04

Chemistry 403/402 (Sr. Inorg. Chem.) W'88, F'88, W’99, F’00-10, F12

Chemistry 413 (Inorg. Synthetic Lab) W'87

Chemistry 419 (Jr./Sr. Writing Requirement) W'88

Chemistry 485 (Jr./Sr. Adv. Independent Laboratory) F'94

Chemistry 507 (Graduate Inorg. Chem.) F'85, F86, F87, F94, F13-17

Chemistry 525 (Graduate Chemical Biology) F’00, F01

Chemistry 526 (Graduate Chemical Biology) W99, W02, W04

Chemistry 548 (Graduate CBI Core Course) F13

Chemistry 616 (Graduate Physical Inorganic) W’98, W14, W15

Biophysics 801 (Biophysics Student Seminar) F'89

Chemistry 710 (Special Topics: Bioinorganic) F'89,W94

Chemistry 711 (Chemistry Biology Interface Core Course) F’ 96, W13

Chemistry 802 (Inorg. Seminar) W'85, W'87, F'92

Chemistry 990 (Graduate Research)

Chemistry 21 (2nd term gen chem) UNC, Chapel Hill W91

Guest Lecturer: Biological Chemistry 608 (Graduate Biochem, 3 Lectures) W'85

Chemistry 450 (Biochemistry) F01, F03

Bioinorganic Chemistry, Université de Paris (11), (1 lecture) F04

Miscellaneous Teaching Duties:

Participant in Chemistry TA training workshop 1984-1988

Inteflex Policy Committee Member

Eli Lilly Postdoctoral Teaching Fellow (developed undergrad lecture/laboratory course in Inorg.

Chemistry suitable for chemistry and biochemistry majors. This course evolved into the

present Chemistry 302)

1988-9 Departmental Curriculum Committee

1986-7 Graduate Counselor

1985-6 Undergraduate Counselor

1989 Chair, Feasibility Study for Undergraduate Biochemistry Major

1990 First Presentation of 2nd Year Inorganic Chemistry Course for new

Undergraduate Chemistry major.

1999 First Presentation of Senior Year Inorganic Chemistry Course for revised

Undergraduate Chemistry major

Professional Service

International/National:

Associate Editor, Inorganic Chemistry (1994- )

NIH Study Sections:

CBI (Chemistry/Biology Interface Training Grant) 6/93

BMT (Metallobiochemistry), 7/93-6/96. 5/02

NSF Panels:

Chemistry in Poland (report on Chemistry in Poland, May 1994)

Chemistry of Life Processes 2017

American Chemical Society:

Younger Chemist's Committee 1985-1988 (ACS)

Presidential Panel on Professionalism in Chemistry (Subcommittee Chairman; 9/88)

Membership Affairs Committee (Secretary) 1990-5

Huron Valley ACS Chairman (1990-3) Councilor (1990-6)

Society of Biological Inorganic Chemists

Council Member, 1999-2003

Correspondent Reviewer: NIH, NSF, USDA, SSRL, PRF and NCI

Editorial Advisory Boards:

ACS Books (1/92-12/96); Reaction Times (4/92-3/94, Chair 4/94-3/95); ACSess

(3/94-4-95), J. Biol. Inorg. Chem. (96-99)

External Reviewer: Cooperative Opportunities for Science and Technology (COST D8,

Inorganic Chemistry) (for European Union), 2001

External Reviewer: Cooperative Opportunities for Science and Technology (COST D21,

Inorganic Chemistry) (for European Union), 2003

Visiting Committee Carnegie-Mellon University, 1999, 2005

Advisory Board, ACS Petroleum Research Fund (2001-7); chair Inorganic Chemistry

Committee (2003-4); Program Committee (2004-07); Chair, Committee on Gender

and Underrepresented Minority Equity in the Sciences (2007-08)

Metals in Biology Gordon Research Conference Steering Committee (2000-)

Advisory Subcommittee, IUPAC Division of Systematic Nomenclature and

Structure Representation (2001-)

Faculty of 1000 (2004-)

Scientific Advisory Board, Center for Environmentally Beneficial Catalysis,

University of Kansas (2008-)

Review Panel, DFG, Clusters of Excellence and Graduate Schools, Berlin, Germany,

Dec 2010.

University: Executive Committee, Center for Molecular Genetics 1987-91

Executive Committee, Biophysics Research Division 1995-6, 98-99

Program Committee, Chemistry Biology Interface Training Program

1999-2000

Program Committee, Molecular Biophysics Training Program 1988-90

Acting P. I., Molecular Biophysics Training Program, 1989-90

Faculty Participant, Cellular Biotechnology Training Program 1991-.

Pew and Searle Scholars Selection Committee 1993-4

Research Policy Committee 1993-6

Inteflex Policy Committee 1987-90, 1993-6

Undergraduate Biochemistry Concentration Program 1992-3

OVPR Panel for Research Excellence and VCM 1995-

OVRR Panel to Evaluate the Future of the UM/Ford Nuclear Reactor

(Chairman) 1996-97

Director, Chemical Biology Interface Training Program (2004-)

Program Committee, Chemical Biology IDP (2004-)

Graduate Teaching Awards Selection Committee, Rackham Graduate School 2010-11

LS&A: Ad hoc Chemical Biosciences Committee 1987

Natural Sciences Promotions and Tenure Committee 1993-6

Interdepartmental Concentration Program Board 2009-11

Departmental (Standing or Ad hoc):

Curriculum Committee (1988-9, 2013)

Chemical Biology Cluster Coordinator (1998-99, 04)

Executive Committee (1989-90, 93-4, 98-00, 2003-7, 2010, 2017)

Fajan's Award Committee (1984-5)

Graduate Committee (1986-7, 1996(Chair), 2002-4 (Chair), 05, 09, 12

Graduate Student Recruiting Committee (1986-7)

Undergraduate Awards Committee (1985-6)

Undergraduate Counselor (1985-6)

New Equipment Committee (1986-8)

Recruiting and Admission Committee (1989, 98, 99, 00, 01, 02)

Technical Services Liaison Committee (1989-90, 96)

Faculty Search Committees (1987-90,94, 98(2), 99(2), 00, 01, 04 (chair), 08, 09,10,13-17)

Faculty Awards Committee (00, 02(chair), 13-15 (Chair))

Departmental Staff/Services Committee (1985-6)

Development Officer (1991-3) and Development Committee (1990-3, 02, 13)

Tenure Review Committees (1990, 92, 93 (3), 94, 95 (2), 98(2), 01, 02 (3), many more)

Long Range Planning Committee (01, Co-chair)

Chemistry ADVANCE Program for Increasing Numbers of Women in

Chemistry (02-04)

Lecturer Evaluation Committee 2017

Vincent L. Pecoraro Page 1

Publication List

As of February 14, 2019: 19757 citations, h-index=84 (Google Scholar).

1. Raymond, K.N.; Pecoraro, V.L. "Coordination Chemistry: Ferric ion

Sequestering Agents," McGraw-Hill Yearbook of Science and Technology

(1981), McGraw-Hill, New York, p. 150.

2. Harris, W.R.; Carrano, C.J.; Pecoraro, V.L.; Raymond, K.N. "Siderophilin Metal Coordination. 1.

Complexation of Thorium by Transferin: Structure-Function Implications," J. Amer. Chem. Soc. 1981,

103, 2231.

3. Tufano, T.P.; Pecoraro, V.L.; Raymond, K.N. "Ferric Ion Sequestering Agents. 8. Kinetics of Iron

Release From Ferritin to Catechoylamides,"Biochim. Biophys. Acta 1981, 668, 420.

4. Pecoraro, V.L.; Weitl, F.L.; Raymond, K.N. "Ferric Iron Sequestering Agents. 7. Synthesis, Iron-

Exchange Kinetics and Stability Constants of N-Substituted, Sulfonated Catechoylamide Analogues

of Enterobactin," J. Amer. Chem. Soc. 1981, 103, 5133.

5. Pecoraro, V.L.; Harris, W.R.; Carrano, C.J.; Raymond, K.N. "Siderophilin Metal Coordination. 2.

Difference Ultraviolet Spectroscopy of Di-, Tri- and Tetravalent Metal Ions With Ethylene-bis-(o-

hydroxyphenylglycine)," Biochemistry 1981, 20, 7033.

6. Raymond, K.N.; Pecoraro, V.L.; Weitl, F.L. "Development of Iron Chelators for Clinical Use," Martell,

A.E.; Anderson, W.F.; Badman, D.G., eds., (1981) Elsevier/North Holland, New York, 165.

7. Pecoraro, V.L.; Wong, G.B.; Raymond, K.N. "Stability Constants of Catechoylamide Sequestering

Agents with Ga(III) and In(III)," Inorg. Chem. 1982, 21, 2209.

8. Raymond, K.N.; Pecoraro, V.L.; Harris, W.R.; Carrano, C.J. "Actinide Coordination and Discrimination

by Human Transferrin," Environmental Migration of Long-Lived Radionuclides, (1982) International

Atomic Energy Agency, Vienna, 571.

9. Raymond, K.N.; Pecoraro, V.L.; Kappel, M.J.; Harris, W.R.; Carrano, C.J. "Specific Sequestering Agents

for the Actinides," Actinides in Perspective, 1982, N.E. Edelstein, ed., Pergamon Press, Oxford, 491.

10. Pecoraro, V.L.; Rawlings, J.; Cleland, W.W. "The Use of M3+(NH3)3H2OATP Complexes as Inhibitors

of Hexokinase," Fed. Proc., Fed. Am. Soc. Exp.

Biol. 1982, 41, 907.

11. Raymond, K.N.; Chung, T.D.Y.; Pecoraro, V.L.; Carrano, C.J. "Metal Binding Sites of Transferrin," The

Biochemistry and Physiology of Iron (1982) P. Saltman and J. Hegenauer, eds. Elsevier/North

Holland, New York, 649.

12. Harris, W.R.; Pecoraro, V.L. "Thermodynamic Binding Constants for Gallium Transferrin," Biochemistry

1983, 22, 292.

13. Heidinger, S.; Braun, V.; Pecoraro, V.L.; Raymond, K.N. "Iron Supply of Escherichia coli with Synthetic

Analogues of Enterochelin," J. Bactiol. 1983, 153, 109.

Vincent L. Pecoraro Publications Page 2

14. Pecoraro, V.L.; Wong, G.B.; Kent, T.A.; Raymond, K.N. "Coordination Chemistry of Microbial Iron

Transport Compounds. 22. pH Dependent Mössbauer Spectroscopy of Ferric Enterobactin and

Synthetic Analogues."J. Amer. Chem. Soc. 1983, 105, 4617.

15. Pecoraro; Harris, W.R.; Wong, G.B.; Carrano, C.J.; Raymond, K.N. "Coordination Chemistry of

Microbial Iron Transport Compounds. 23. Fourier Transform Infrared Spectroscopy of Ferric

Enterobactin and Synthetic Analogues," J. Amer. Chem. Soc. 1983, 105, 4623.

16. Pecoraro, V.L.; Rawlings, J.; Cleland, W.W. "The Use of Chromium (III) and Cobalt(III) Complexes of

ADP to Elucidate the Catalytic Mechanism of Creatine Kinase," Inorg. Chim. Acta, Bioinorg. Let. 1983,

79, 241.

17. Riley, P.E.; Pecoraro, V.L.; Carrano, C.J.; Raymond, K.N. "Siderophilin Metal Coordination. 3. Crystal

Structures of Co(III), Ga(III) and Cu(II) Ethylene-bis-(o-hydroxyphenylglycine)," Inorg. Chem. 1983, 22,

3096.

18. Pecoraro, V.L.; Rawlings, J.; Cleland, W.W. "Investigation of the Substrate Specificity of Creatine

Kinase using Co(III) and Cr(III) Complexes of ADP," Biochemistry 1984, 23, 153.

19. Pecoraro, V.L.; Bonadies, J.; Marese, C.A.; Carrano, C.J. "The Stepwise Metal-Assisted Oxidative

Decarboxylation of Vanadium(V) EHPG: Isolation of a Possible Intermediate," J. Amer. Chem. Soc.

1984, 106, 3360.

20. Pecoraro, V.L.; Hermes, J.D.; Cleland, W.W. "Stability Constants of Mg(II)

and Cd(II) Adenine Nucleotides and Thionucleotides and Rate Constants

for Formation and Dissociation of MgATP and MgADP," Biochemistry 1984, 23, 5202.

21. Carrano, C.J.; Spartalian, K.; Appa Rao, G.V.N.; Pecoraro, V.L.; Sundaralingham, M. "The Fe(III)

Complex of N-[2-((o-hydroxyphenyl)glycino)ethyl] salicylidenim-ine. A Model Complex for the

Fe(III) Binding Site in Transferrins," J. Amer. Chem. Soc. 1985, 107, 1651.

22. Pecoraro, V.L.; Rendina, A.R.; Cleland, W.W. "Determination of the Screw Sense Specificity of Bovine

Liver Fructokinase," Biochemistry 1985, 24, 1619.

23. Pecoraro, V.L.; Zylstra, G.; Olsen, R.H. "Isolation of the DNA Sequence Coding for Pseudomonas

aeruginosa Azurin," Rev. Port. Quimica 1985, 27, 170.

24. Kappel, M.J.; Pecoraro, V.L.; Raymond, K.N. "Lipophilic Enterobactin Analogues. Iron Exchange

Kinetics and Complexation of Ga(III) and Fe(III) by Terminally N-Substituted Catechoylamide

Ligands," Inorg. Chem. 1985, 24, 2447.

25. Riley, P.E.; Pecoraro, V.L.; Carrano, C.J.; Bonadies, J.A.; Raymond, K.N."Crystal Structures of Vanadyl

Ethylene-bis-(o-hydroxyphenyglycine) Complexes," Inorg. Chem. 1986, 25, 154.

26. Pecoraro, V.L.; Butler, W.M. "Structure of N,N'-Ethylene-bis-(Salicylideniminato) Manganese(III)

Chloride," Acta Cryst., 1986, C42., 1151.

27. Speckhard, D.; Pecoraro, V.L.; Knight, W.B.; Cleland, W.W. "Synthesis, Purification and

Characterization of the Four Screw Sense Diastereomers of Co(III)(NH3)3ATP," J. Amer. Chem. Soc.,

1986, 108, 4167.


28. Bonadies, J. ; Pecoraro, V.L.; Carrano, C.J. "The Acid Promoted Disproportionation of a Vanadium(IV)

Phenolate: Implications for Vanadium Uptake in Tunicates," J. Chem. Soc., Chem. Comm., 1986, 1218.

29. Kessissoglou, D.P.; Butler, W.M.; Pecoraro, V.L. "Structural and Spectroscopic Characterization of the

Mn(IV) Schiff's Base Complex Mn(SALADHP)2," J. Chem. Soc., Chem. Comm., 1986, 1253.

30. Pecoraro, V.L.; Kessissoglou, D.P.; Li, X.; Butler, W.M. "Models for the Active Sites of

Manganoenzymes," Prog. Photosyn. Res. 1987, 1, 795.

31. Kessissoglou, D.P.; Butler, W.M.; Pecoraro, V.L. "Characterization of Mono- and Binuclear

Manganese(II) Schiff's Base Complexes With Metal Disulfide Bonds," Inorg. Chem. 1987, 26, 495.

32. Bonadies, J.; Butler, W.M.; Pecoraro, V.L.; Carrano, C.J. "Novel Reactivity Patterns of N,N'-Ethylene-

bis-(salicylideniminato)oxovanadium(IV) in Strongly Acidic Media," Inorg. Chem. 1987, 26, 1218.

33. Kessissoglou, D.P.; Li., X.; Butler, W.M.; Pecoraro, V.L. "Mononuclear Mn(IV) Complexes of Hydroxyl

Rich Schiff Base Ligands," Inorg. Chem. 1987 26, 2487.

34. Cusky, S.; Pecoraro, V.L.; Olsen, R.H. "Initial Catabolism of Biogenic Amines by Pseudomonas

aeruginosa PAO: Pathway Description, Mapping of Mutations and Cloning of the Essential Genes," J.

Bact. 1987, 169, 2398.

35. Pecoraro, V.L.; Li, X.; Baker, M.J.; Butler, W.M.; Bonadies, J.A. "Manganese Complexes of Relevance to

Enzymes Containing Multinuclear Manganese Centers," Recueil Trav. Chim. 1987, 106, 221.

36. Kessissoglou, D.P.; Li., X.; Kirk, M.; Bender, C.J.; Pecoraro, V.L. "Isolation of a Mixed Valence Trinuclear

Manganese Complex Potentially Relevant to Photosynthetic Oxygen Evolution," Inorg. Chem., 1988,

27, 1

37. Pecoraro, V.L. "Structural Proposals for the Manganese Centers of the Oxygen Evolving Complex: An

Inorganic Chemist's Perspective," Photochem. Photobiol. 1988, 48, 249.

38. Li, X.; Lah, M.S.; Pecoraro, V.L. "Vanadium Complexes of the Tridentate Schiff Base Ligand N-

(salicylideneaminato)-N'-(2-hydroxyethyl)ethylenediamine: Acid-Base and Redox Conversion

Between Vanadium(IV) and Vanadium(V) Iminophenolates," Inorg. Chem. 1988, 27, 4657.

39. Kessissoglou, D.P.; Bender, C.; Kirk, M.L.; Lah, M.S.; Pecoraro, V.L. "A Bent Mixed Valence Mn(III/II/III)

Complex: A New Class of Trinuclear, Acetate Bridged Schiff Base Compounds Exhibiting a g=2

Multiline ESR Signal," J. Chem. Soc., Chem. Comm., 1989, 84.

40. Pecoraro, V.L. "Structural Characterization of [VO(salicylhydroximate)(CH3OH)]3: Applications to the

Biological Chemistry of Vanadium(V)," Inorg. Chim. Acta., 1989, 155, 171.

41. Waggoner, C.; Pecoraro, V.L.; Yocum, C.F. "Monovalent Cations (Na+, K+ Cs+) Inhibit Calcium

Activation of Photosynthetic Oxygen Evolution," FEBS Lett., 1989, 244, 237.

42. Bonadies, J.A.; Lah, M.S.; Kirk, M.L.; Kessissoglou, D.P.; Hatfield, W.; Pecoraro, V.L. "Structurally Diverse

Manganese(III) Schiff Base Complexes: Chains, Dimers and Cages," Inorg. Chem., 1989, 28, 2037.


43. Bonadies, J.A.; Maroney, M.L.; Pecoraro, V.L. "Structurally Diverse Manganese(III) Schiff Base

Complexes: Solution Speciation via 1H NMR Spectroscopy and Electrochemistry," Inorg. Chem.,

1989, 28, 2044.

44. Penner-Hahn, J.E.; Fronko, R.; Pecoraro, V.L.; Bowlby, N.F.; Betts, S.D.; Yocum, C.F. "XAS of Mn in the

Photosynthetic Oxygen Evolving Complex," Physica B, 1989, 158, 107.

45. Pichersky, E.; Detlefsen, D.; Pecoraro, V.L. "Pre-plastocyanin from Lycopersicon esculentum," Nucl.

Acids Res., 1989, 17, 6414.

46. Li, X.; Lah, M.S.; Pecoraro, V.L. "Structural Characterization of the Manganese(IV) Schiff-Base Complex

MnIV(5-Cl-SALAHP)2," Acta Cryst, 1989, C45, 1517.

47. Lah, M.S.; Pecoraro, V.L. "Isolation and Characterization of Mn(II)[Mn(III)4(salicyl-

hydroximate)4(Acetate)2(DMF)6]: An Inorganic Analogue of M2+(12-Crown-4)," J. Amer. Chem.

Soc., 1989, 111, 7258.

48. Li, X.; Pecoraro, V.L. "Stepwise, Metal Assisted Decarboxylation Promoted by Manganese: Reactivity

Relationship Between Manganese and Vanadium," Inorg. Chem., 1989, 28, 3403.

49. Lah, M.S.; Kirk, M.L.; Hatfield, W.; Pecoraro, V.L. "The Tetranuclear Cluster Fe(III)-

[Fe(III)(Salicylhydroximate)(Acetate)(CH3OH)]3 is an Analogue of M3+(9-Crown-3)," J. Chem. Soc.,

Chem. Comm., 1989, 1606.

50. Pecoraro, V.L.; Kessissoglou, D.P.; Li, X.; Lah, M. S.; Saadeh, S.; Bender, C.; Bonadies, J. A.; Larson, E.

"Evaluation of Structural Possibilities for the Mn Centers of the OEC," Curr Resrch. Photosyn., M.

Baltscheffsky, ed., Klueer Academia Publishers, Dordercht, 1990, 1, 709.

51. Penner-Hahn, J.E.; Fronko, R.; Pecoraro, V.L.; Bowlby, N.F.; Betts, S.D.; Yocum, C.F. "Structural

Characterization of the Manganese Sites in the Photosynthetic Oxygen-Evolving Complex Using X-

ray absorption Spectroscopy," J. Amer. Chem. Soc., 1990, 112, 2549.

52. Carrano, C.J.; Nunn, C.; Quan, R.; Bonadies, J.A.; Pecoraro, V.L. "Monomeric and Dimeric

Vanadium(IV) and (V) Complexes of N-(hydroxyalkyl)salicylidene-amines: Structures,

Magnetochemistry and Reactivity,"Inorg. Chem, 1990, 29, 944.

53. Lah, M.S.; Pecoraro, V.L.; Kirk, M.L.; Hatfield, W. "Transition Metal Encapsulation by "Metallocrown"

Ethers," Biosensor Technology, R. Buck, W. Hatfield, E. Bowden, M. Umana, eds. Marcel-Dekker, New

York, 1990, 201.

54. Detlefsen, D.; Thanabal, V.; Pecoraro, V.L.; Wagner, G. "Sequential 1H NMR Assignments of Iron(II)

Cytochrome c551 from Pseudomonas aeruginosa," Biochemistry, 1990, 29, 9377.

55. Pecoraro, V.L. "Photosynthesis" The 1991 McGraw-Hill Yearbook of Science and Technology, Sybyl

Parker, Ed. McGraw-Hill, New York, 340, 1990.

56. Briggs, L.M.; Pecoraro, V.L.; McIntosh, L. "Copper-Induced Expression, Cloning and Regulatory

Studies of the Plastocyanin Gene from the Cyanobacterium Synechocystis sp. PCC 6803," Plant Mol.

Biol., 1990, 15, 633.


57. Pecoraro, V.L.; Lah, M.S. "Development of Metallacrown Ethers: A New Class of Metal

Clusters,"Comments Inorg. Chem., 1990, 11, 59.

58. Saadeh, S.; Lah, M.S.; Pecoraro, V.L. "Manganese Complexes of -Hydroxy Acids," Inorg. Chem.

1991, 30, 9.

59. Speckhard, D.C.; Rawlings, J.; Pecoraro, V.L.; Cleland, W.W. "Triammine-chromium(III) Complexes of

Tripolyphosphate and Adenosine Tri- and Diphosphate," J. Inorg. Biochem., 1991, 41, 105.

60. Detlefsen, D.; Thanabal, V.; Pecoraro, V.L.; Wagner, G. "Solution Structure of Fe(II) Cytochrome c551

from Pseudomonas aeruginosa as Determined by 2D 1H-NMR," Biochemistry, 1991, 30, 9040.

61. Lah, M.S.; Pecoraro, V. L. "A Functional Analogy Between Crown and Metallacrown Ethers," Inorg.

Chem, 1991, 30, 878.

62. Larson, E.; Pecoraro, V.L. "The Peroxide Dependent 2-O Bond Formation of [Mn(IV)SALPN(O)]2" J.

Amer. Chem. Soc., 1991, 113, 3810.

63. Kirk, M.L.; Lah, M.S.; Kessissoglou, D.P.; Rapodopolou, C.; Hatfield, W.; Pecoraro, V.L. "Cationic

Control of Spin Dimensionality in Infinite Chains of

(Cation)2[Mn(III)(Salicylate)2][Mn(III)(Salicylate)2(CH3OH)2]," Inorg. Chem., 1991, 30, 3900.

64. Larson, E.; Pecoraro, V.L. "Catalytic Disproportionation of Hydrogen Peroxide by a bis-2-O-Mn(IV)

Dimer," J. Amer. Chem. Soc, 1991, 113, 7809.

65. Kirk, M.L.; Hatfield, W.; Lah, M.S.; Kessissoglou, D.P.; Pecoraro, V.L.; Morgan, L.W.; Pedersen, J.D.

"Effects of Alternation in Some Quasi-One Dimensional Magnetic Materials," J. Appl. Phys., 1991, 69,

6013.

66. Pecoraro, V.L. "Vanadium", The McGraw-Hill Encyclopedia of Science and Technology 1991, Sybyl

Parker, Ed. McGraw-Hill, New York, Vol. 19, 149.

67. Larson, E.; Lah, M. S.; Li, X.; Bonadies, J. A.; Pecoraro, V. L. "Manganese-Manganese Separations in

Oxide and Alkoxide Bridged Complexes: Correlation of Structure With Ligand Type and

Number,"Inorg. Chem., 1992, 31, 373.

68. Larson, E.; Pecoraro, V.L. "Introduction to Manganese Enzymes," Chapter 1 in Manganese Redox

Enzymes, V.L. Pecoraro, ed, Verlag-Chemie, 1992, 1.

69. Pecoraro, V.L. "Structurally Diverse Manganese Complexes: From Voodoo to Oxygenic

Photosynthesis," Chapter 10 in Manganese Redox Enzymes, V.L. Pecoraro, ed, Verlag-Chemie, 1992,

197.

70. Pecoraro, V.L., ed. Manganese Redox Enzymes, Verlag-Chemie, New York, 1992.

71. Larson, E.L.; Riggs, P.; Penner-Hahn, J.E.; Pecoraro, V.L. "Structural Characterization of Protonated

[Mn(IV)(2-O)]2 Cores," J. Chem. Soc., Chem. Comm., 1992, 102.


72. Cornman, C.R.; Kampf, J.; Pecoraro, V.L. "Structural and Spectroscopic Characterization of

Vanadium(V)O-Imidazole Complexes,"Inorg. Chem. 1992, 31, 1981.

73. Cornman, C.R.; Kampf, J.; Lah, M.S.; Pecoraro, V.L. "Modelling Vanadium Bromoperoxidase:

Synthesis, Structure and Reactivity of Vanadium(IV)-Imidazole Complexes," Inorg. Chem., 1992, 31,

2035.

74. Larson, E.L.; Haddy, A.; Kirk, M.L.; Sands, R.; Hatfield, W.; Pecoraro, V.L. "The Asymmetric Mixed Valent

Dimer {[Mn(2-OH-SALPN)]2(THF)}ClO4 Shows a Temperature Dependent Interconversion Between

g=2 Multiline and Low Field EPR Signals," J. Amer. Chem. Soc., 1992, 114, 6263.

75. Kessissoglou, D.P.; Kirk, M.; Lah, M.S.; Li, X. Raptopoulou, C.; Hatfield, W.M.; Pecoraro, V.L. "Structural

and Magnetic Characterization of Trinuclear Mixed Valence, Manganese Acetates," Inorg. Chem.

1992, 31, 5424.

76. Cornman, C.R.; Colpas, G.J.; Hoeschele, J.D.; Kampf, J.; Pecoraro, V.L. "Implications for the

Spectroscopic Assignment of Vanadium Biomolecules: Structural and Spectroscopic Characterization

of Monooxovanadium(V) Complexes Containing Catecholate and Hydroximate Based Non-Innocent

Ligands," J. Amer. Chem. Soc. 1992, 114, 9925.

77. Saadeh, S. M.; Trojan, K. L.; Kampf, J.; Hatfield, W. E.; Pecoraro,V. L. "Magnetic Characterization of

S=2 Chains of Composition [(Cat)2{[Mn(III)-(Malonate)2(CH3OH)2][Mn(III)(Malonate)2]}]n and

{(Cat)2[Mn(III)(Malonate)2-(CH3OH)][Mn(III)(Malonate)2]}n," Inorg. Chem., 1993, 32, 3034.

78. Lah, M.S.; Gibney, B.; Tierney, D.; Penner-Hahn, J.E.; Pecoraro, V.L. "The Fused Metallacrown Anion

Na2{[Na0.5[Ga(salicylhydroximate)]4]2(2-OH)4}- is An Inorganic Analogue of a Cryptate," J. Amer.

Chem. Soc. 1993, 115, 5857.

79. Root, C.; Hoeschele, J.D.; Cornman, C.R.; Kampf, J.; Pecoraro, V.L. "Structural and Spectroscopic

Characterization of Dioxovanadium(V) Complexes With Asymmetric Schiff Base Ligands," Inorg.

Chem., 1993, 32, 3855.

80. Gelasco, A.; Pecoraro, V.L. "[Mn(III)(2-OHSalpn)]2 Is An Efficient Functional Model For the

Manganese Catalases" J. Amer. Chem. Soc., 1993, 115, 7928.

81. Gibney, B.; Stemmler, A.J.; Pilotek, S.; Kampf, J.; Pecoraro, V.L. "Generalizing the Metallacrown

Analogy: Ligand Variation and Solution Stability of the V(V)O 9-Metallacrown-3 Structure Type,"

Inorg. Chem., 1993, 32, 6008.

82. Baldwin, M.J.; Gelasco, A.; Pecoraro, V. L. "The Effect of Protonation on [Mn(IV)(2-O)]2 Complexes,"

Photosyn. Resrch., 1993, 38, 303.

83. Baldwin, M.; Kampf, J.; Pecoraro, V.L. "The Linear Mn(II) Complex Mn3(5-NO2-SALIMH)2(OAc)4

Provides an Alternative Structure Type for the Carboxylate Shift in Proteins" J. Chem. Soc., Chem

Comm., 1993, 1741.


84. Hoeschele, J.D.; Roy, A.; Pecoraro, V.L.; Carver, P.L. "In Vitro Analysis of the Interaction Between

Sucralfate and Ketoconazole," Antimicrob. Agents Chemother., 1994, 38, 319.

85. Kessissoglou, D.P.; Kampf, J.; Pecoraro, V.L. "Compositional and Geometrical Isomers of 15-

Metallacrown-5 Complexes," Polyhedron, 1994, 13, 1379.

86. Colpas, G. J.; Hamstra, B.; Pecoraro, V.L. "VO(O2)(HEIDA) is an Efficient Mimic for the Vanadium

Bromoperoxidases," J. Amer. Chem. Soc., 1994, 116, 3627.

87. Pecoraro, V.L.; Baldwin, M.J.; Gelasco, A. "Manganese Complexes with Dioxygen and its Reduced

Forms," Chem Reviews,, 1994, 94, 807.

88. Colpas, G. J.; Hamstra, B.; Kampf, J.; Pecoraro, V.L. "The Preparation of VO3+ and VO2+ Complexes

Using Hydrolytically Stable, Asymmetric Ligands Derived from Schiff Base Precursors," Inorg. Chem.,

1994, 33, 4669.

89. Gibney, B.P.; Kampf, J.; Kessissoglou, D.P.; Pecoraro, V.L. "Copper 12-Metallacrown-4 Complexes,"

Inorg. Chem., 1994, 33, 4840.

90. Baldwin, M.J.; Stemmler, T.; Riggs-Gelasco, P.J.; Kirk, M.J.; Penner-Hahn, J.E.; Pecoraro, V.L. " Structural

and Magnetic Effects of Succesive Protonations of Oxo Bridges in High Valent Manganese Dimers,"

J. Amer. Chem. Soc., 1994, 116, 11349.

91. Stemmler, A.J.; Kampf, J.W.; Pecoraro, V.L. "Preparation of the First Inverse 12- Metallacrown-4,"

Inorg. Chem, 1995, 34, 2271.

92. Utschig, L.M.; Wright, J.G.; Dieckmann, G.; Pecoraro, V.L.; O'Halloran, T.V. "199Hg NMR Spectroscopy

of Mercury Substituted Blue Copper Proteins," Inorg. Chem., 1995, 34, 2497.

93. Dieckmann, G.; Heilman, S.; DeGrado, W.; Pecoraro, V.L. "DeNovo Design of Metallopeptides," in An

Inorganic Perspective of Life, D.P. Kessissoglou, D. Coucouvanis and M. Kanatzidas, eds., Elsevier,

Amsterdam, 1995, 275.

94. Baldwin, M.; Gelasco, A.; Pecoraro, V.L. "Modelling the Reactivity of the Oxygen Evolving Complex" in

An Inorganic Perspective of Life, D.P. Kessissoglou, D. Coucouvanis and M. Kanatzidas, eds., Elsevier,


95. Stemmler, A.J.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. "Characterization of a Nickel Hydroxamate That

Serves As a Model for the Hydroxamate Inhibited Urease," J. Amer. Chem. Soc. 1995, 117, 6368.

96. Gibney, B.; Pecoraro, V.L."Theoretical Considerations for the Binding of Metals in Biological Fluids,"

in Handbook on Metal-Ligand Interactions in Biological Fluids, Volume 1, G. Berthon, Ed.,


97. Pecoraro, V.L.; Gibney, B. "Structural Aspects of Metal Ion Interactions with Synthetic Carrier

Ligands," in Handbook on Metal-Ligand Interactions in Biological Fluids, Volume 1, G. Berthon, Ed.,

Amsterdam 1995, 597.


98. Gelasco, A.; Baldwin, M.; Pecoraro, V.L. "A Modelling Approach For Understanding the Mechanism of

Manganese Enzymes" in Mechanistic Bioinorganic Chemistry, H.H. Thorp and V.L. Pecoraro, eds.,

Adv. Chem Series, ACS Books, Washington, D.C. 1995, 265.

99. Baldwin, M.J.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. "Structural and Magnetic Studies of Mn(II)

Complexes of the Imidazole Containing Ligand 5-NO2-salimH [5-NO2-salimH2= 4-(2-(5-

nitrosalicylideneamino)ethyl)imidazole] With Varying Nuclearity" Inorg. Chem, 1995, 34, 5252.

100. Law, N.A.; Machonkin, T.E.; McGorman, J.P.; Larson, E.J.; Kampf, J.W.; Pecoraro, V.L. "A Structurally

Characterized DiChloro-Mn(IV) Complex Capable of Chlorinating Alkenes," J. Chem. Soc., Chem

Comm. 1995, 2015.

101. Gelasco, A.; Ascenas, A.; Pecoraro,V.L. "The Tetranuclear Complex [Mn(II)(picpn)]4 Efficiently

Disproportionates Hydrogen Peroxide," Inorg. Chem., 1996, 35, 1419.

102. Colpas, G.C.; Hamstra, B.J.; Kampf, J.W.; Pecoraro, V.L. “Functional Models for Vanadium

Haloperoxidase,” J. Amer. Chem. Soc., 1996, 118, 3469.

103. Caudle, M. T.; Riggs-Gelasco; P.; Gelasco, A.K.; Penner-Hahn, J.E.; Pecoraro, V.L. “Homolytic Cleavage

of tert-butyl hydroperoxide by Mn2(2-OHsalpn)2 to Form the One-Electron Oxidized Compound

Mn2(2-OHsalpn)2 OH having a Terminal Hydroxo Ligand,” Inorg. Chem., 1996, 35, 3577.

104. Pecoraro, V.L.; Stemmler, A.J.; Gibney, B.P.; Bodwin, J.; Kampf, J. W.; Wang, H. “Metallacrowns: A New

Class of Molecular Recognition Agents,” in Prog. Inorg. Chem. Vol. 45, Chapter 2, K. Karlin, ed.

Pergamon Press, 1996, 83.

105. Gibney, B.; Wang, H.; Kampf, J. W.; Pecoraro,V.L. "Structural Evaluation and Solution Integrity of Alkali

Halide Salts of Manganese 12-Metallacrown-4," Inorg. Chem., 1996 35, 6184-6193.

106. Baldwin, M.J.; Pecoraro, V.L. “Energetics of the Proton-Coupled Electron Transfer in High-Valent

Systems: Models for Water Oxidation by the Oxygen Evolving Complex of Photosystem II” J. Amer.

Chem. Soc., 1996, 118, 11325.

107. Stemmler, A.J.; Barwinski, A.; Baldwin, M.J.; Young, Jr., V.; Pecoraro, V.L. “Facile Preparation of a Chiral,

Face Differentiated 15-Metallacrown-5,” J. Amer. Chem. Soc, 1996, 118, 11962.

108. Stemmler, A.J.; Kampf, J.W.; Pecoraro, V.L. “A Planar 15-Metallacrown-5 that Selectively Binds the

Uranyl Cation,” Angew. Chem., 1996, 35 (23), 2841.

109. Pecoraro, V.L.; Baldwin, M.J.; Caudle, M.T.; Law, N.A.; Kampf, J.W.; Rasmussen, P.G. “A Modelling

Approach for Understanding Water Oxidation in Photosynthesis,” Photosynthesis: From Light to

Biosphere., Vol. II, Proceedings of the Xth International Photosynthesis Congress, Paul Mathis, ed.,

Dordrecht: Kluwer Academic Publishers, 1995, 377.

110. Slebodnick, C.; Hamstra, B.J.; Pecoraro, V.L. “Modelling the Biological Chemistry of Vanadium:

Structural and Reactivity Studies Elucidating Biological Function,” Structure and Bonding, P. Sadler,

Ed., 1997, 51.


111. Rompel, A.; Andrews, J.C.; Cinco, R.M.; Wemple, M.W.; Christou, G.; Law, N.A.; Pecoraro, V.L.; Sauer, K.

Yachandra, V.K.; Klein, M.P. “Chlorine K-Edge X-ray Absorption Spectroscopy as a Probe of Chlorine-

Metal Bonding: Manganese-Chloride Model Systems with Relevance to the Oxygen Evolving

Complex in Photosystem II,” J. Amer. Chem. Soc. 1997, 119, 4465.

112. Caudle, M.T.; Pecoraro, V.L. “Hydrogen Atom Abstraction of Bound Substrate is a Viable Mechanism

for Cluster Oxidation in the Oxygen Evolving Complex of Photosystem II,” J. Amer. Chem. Soc., 1997,

119, 3415.

113. Gelasco, A.; Kirk, M.L.; Kampf, J.W.; Pecoraro, V.L. "The [Mn2(2-OHsalpn)2]2-,1-,0,1+ System: Synthesis,

Structure, Spectroscopy and Magnetic Characterization of the First Dinuclear Manganese Series

Containing Four Distinct Oxidation States" Inorg. Chem., 1997, 36, 1829.

114. Hamstra, B.J.; Houseman A.L.P.; LoBruto, R.; Colpas, G.C.; Kampf, J.W.; Frasch, W.D.; Pecoraro, V.L.

“Structural and Solution Characterization of Mononuclear V(IV) Complexes that Help to Elucidate

the Active Site Structures of Vanadium Haloperoxidases,” Inorg. Chem., 1997, 36, 4866.

115. Randall, D.W.; Gelasco, A.; Caudle, M.T.; Pecoraro, V.L.; Britt, R.D. “1H ESE-ENDOR and ESEEM

Characterization of Water and Methanol Ligation to a Dinuclear Mn(III)Mn(IV) Cluster,” J. Amer.

Chem. Soc., 1997, 119, 4481.

116. Dieckmann, G.; McCrory, D.; Tierney, D.; Utschig, L. M.; Singer, C.P.; O’Halloran, T.V.; Penner-Hahn, J.E.;

DeGrado, W.; Pecoraro, V.L.; "Conversion of a Three Helix Bundle to a Two Helix Bundle Initiated by

the Complexation of Hg(II)," J. Amer. Chem. Soc., 1997, 119, 6195.

117. Caudle, M.T.; Kampf, J. W.; Rasmussen, P. G.; Pecoraro, V. L. “The First Binuclear Mn(IV) Complex

Containing a Bridging Imidazolate Ligand Exhibits Unique EPR Spectral Features” J. Amer. Chem.

Soc, 1997, 119, 9297.

118. Priuska, E. M.; Clark-Baldwin, K.; Pecoraro, V.L. , Schacht, J. "1H NMR studies of Iron-Gentamicin

Complexes and the Implications for Aminoglycoside Toxicity." Inorg. Chem. Acta. (Special Issue

dedicated to Ivano Bertini), 1998, 273, 85.

119. Gelasco, A.; Pecoraro, V.L. "The [Mn2(2-OHsalpn)2]2-,1-,0 System: An Efficient Functional Model for the

Reactivity and Inactivation of the Manganese Catalases" Inorg.. Chem., 1998, 37, 3301.

120. Slebodnick, C.; Pecoraro, V.L. “Solvent Effects on 51V NMR Chemical Shifts: Characterization of

Vanadate and Peroxovanadate Complexes in Mixed Water Acetonitrile Solvent,” Inorg. Chem. Acta,

1998, 283, 37 (Special Issue dedicated to Osamu Yamauchi).

121. LoBruto, R.; Hamstra, B.J.; Colpas, G.C.; Frasch, W.D.; Pecoraro, V.L. “ESEEM Spectroscopy Reveals and

Distinguishes Equatorial and Axial Nitrogen Ligands Bound to VO in Proteins Containing the

Vanadyl Ion,” J. Amer. Chem. Soc., 1998, 120, 4410-4416.

122. Pecoraro, V.L.; Baldwin, M.J.; Caudle, M.T.; Hsieh, W.-Y.; Law, N.A. “A Proposal for Water Oxidation in

Photosystem II,” Pure & Appl. Chem, 1998, 70, 925.

123. Grant, C.V.; Ball, J.A.; Hamstra, B. J. ; Pecoraro, V.L.; Britt, R. D. “51V ESE-ENDOR Studies of

Oxovanadium(IV) Complexes: Investigation of the Nuclear Quadrupole Interaction,” J. Phys. Chem.,

B 1998, 102, 8145-8150.


124. Halfen, J.A.; Bodwin, J.J.; Pecoraro, V.L. “Preparation and Characterization of Chiral Copper 12-

Metallacrown-4 Complexes: Inorganic Analogues of Tetraphenylporphyrinatocopper(II)” Inorg. Chem.,

1998, 37, 5416.

125. Dieckmann, G.; McRorie, D.; Lear, J.D.; Sharp, K.A.; DeGrado, W.; Pecoraro, V.L."The Role of

Protonation and Chelation Preferences in Defining the Properties of Mercury Binding Coiled-Coils,"

J. Mol. Biol., 1998, 280, 897.

126. Pecoraro, V.L.; “A Modelling Approach for Understanding Photosynthetic Water Oxidation” Photosyn

Resch., in G. Garab (ed.) Photosynthesis:Mechanisms and Effects, Kluwer Academic Publishers,

Dordrecht 1998, 1247-1252.

127. Pecoraro, V.L.; Slebodnick, C.; Hamstra, B.J. "Synthetic Models for Vanadium Haloperoxidases", in

Vanadium Compounds: Chemistry, Biochemistry, and Therapeutic Applications, A.S. Tracey & D.C. Crans,

eds, 1998, 157.

128. Hamstra, B.J.; Colpas, G.C.; Pecoraro, V.L. “Reactivity of dioxovanadium(V) complexes with hydrogen

peroxide: Implications for vanadium haloperoxidase” Inorg. Chem., 1998, 37, 949-955.

129. Baldwin, M.P.; Law, N.A.; Stemmler, T.L.; Kampf, J.W.; Penner-Hahn, J.E.; Pecoraro, V.L. “Reactivity of

[MnIV(salpn)]2(-O,-OCH3)+ and [MnIV(salpn)]2(-O,-OCH3)

+: Effects of Proton Lability and

Hydrogen Bonding,” Inorg. Chem., 1999, 38, 4801-4809.

130. Law, N.A.; Caudle, M.T.; Pecoraro, V.L. “Manganese Redox Enzymes and Model Systems: Properties ,

Structures, and Reactivity” Adv. Inorg. Chem., Geoffery B. Sykes, ed., 1999, 46 305-440.

131. Stemmler, A.J.; Kampf, J.W.; Kirk, M.L.; Atasi, B.H.; Pecoraro, V.L. “The Preparation, Characterization

and Magnetism of Copper 15-Metallacrown-5 Lanthanide Complexes,” Inorg. Chem., 1999, 38,

2807-2817.

132. Yocum, C.F.; Pecoraro, V.L. “Recent Advances in the Understanding of the Biological Chemistry of

Manganese,” Current Opinions in Biology, 1999, 3, 182-187.

133. Pecoraro, V.L.; Hsieh, W-Y “The Use of Model Complexes to Elucidate the Structure and Function of

Manganese Redox Enzymes”, Chapter 14 in "Metal Ions in Biological Systems", Vol 37, Astrid Sigel

and Helmut Sigel, eds., Marcel-Dekker, Inc., Basel, Switzerland, 2000, 429-504.

134. Slebodnick, C.A.; Law, N.A.; Pecoraro, V.L. “A Comparison of Manganese and Vanadium Peroxidase,

Haloperoxidase and Catalase Activities” B. Meunier, ed., Imperial College Press, London, 2000, 215-

267.

135. Law, N.A.; Kampf, J.W.; Pecoraro, V.L. “Correlation of Mn-O-Mn Bridging Angle and the Heisenberg

Exchange Parameter, J, For an Isostructural Series of MnIV2(2-O)2 dimers,” Inorg. Chim. Acta, 2000

,297, 252-264. (honoring Professor S. Lippard).

136. Smith, T.A.; Root, C.; Kampf, J.W.; Rasmussen, P.; Pecoraro, V.L. “Reevaluation of the additivity

relationship for vanadyl imidazole complexes: Correlation of the EPR hyperfine constant with ring

orientation,” J. Amer. Chem. Soc., 2000, 122, 767-775.


137. Gibney, B.R.; Pecoraro, V.L. “The Preparation of Manganese and Copper 12-Metallacrown-4 Complexes:

Mn(II)(Acetate)2[Mn(III)(salicylhydroximate)]4 and (Tetramemthylammonium)2[Cu(II)5(napthoyl-

hydroximate) 4]” Inorg. Synth., 2002, 33, 70-4.

138. Stemmler, A.J.; Pecoraro, V.L. “The Preparation of Uranyl and Europium 15-Metallacrown-5:

UO2(NO3)3[Cu(II)(picolinate)]5 and Eu(NO3)3[Cu(II)(picolinate)]5” Inorg. Synth., 2002, 33, 67-70.

139. Pecoraro, V.L.; Bodwin, J.B.; Cutland, A. “Formation of Chiral Solids Via a Molecular Building Block

Approach,” J. Solid State Chem., 2000, 152, 68-77.

140. Bodwin, J.J.; Pecoraro, V.L. “Preparation of a Chiral, 2-Dimensional Porous Network Using

Metallacrown and Copper Benzoate Building Blocks” Inorg. Chem., 2000, 39, 3434-5.

141. Cutland, A.; Malkani, R.; Kampf, J.; Pecoraro, V.L. “Lanthanide 15-MC-5 Complexes Form

Nitrate Selective Cavities,” Angew. Chem. 2000, 39, 2689-2691.

142. Caudle, M.T.; Pecoraro, V.L, “Mechanism for the Reduction of the Mixed-Valent Mn(III)Mn(IV)[2-

Ohsalpn]+ Complex by Tertiary Amines,” Inorg. Chem., 2000, 39, 5831-5837.

143. Farrer, B.T.; McClure, C.; Penner-Hahn, J.E.; Pecoraro, V.L. “Arsenic(III)-Thiol Interactions Stabilize Three-

Helix Bundles in Aqueous Solution” Inorg. Chem., 2000, 39, 5422-5423.

144. Peloquin, J.M.; Campbell, K.A.; Randall, D.W.; Evanchik, M.A.; Pecoraro, V.L.; Armstrong, W.A.; Britt, R.W.

“55Mn ENDOR of the S2-state Multiline EPR Signal of Photosystem II: Implications on the Structure of

the Tetranuclear Cluster,” J. Amer. Chem. Soc., 2000, 122, 10926-10942.

145. Psomas, G. Stemmler, A.J.; Dendrinou-Samara, C.; Bodwin, J.J.; Schneider, M.; Alexiou, M.; Kampf, J.J.;

Kessissoglou, D. P.; Pecoraro, V.L. “The Preparation of Site Differentiated Mixed Ligand and Mixed

Ligand/Mixed Metal Metallacrowns ” Inorg. Chem., 2001, 40, 1562-1570.

146. Bodwin, J.J.; Cutland, A. D. ; Pecoraro, V.L. “The Development of Chiral Metallacrowns Into Anion

Recognition Agents and Porous Materials,” Coord. Chem. Rev., 2001, 216-217, 489-512.

147. Cutland, A.; Halfen, J.A.; Kampf, J.; Pecoraro, V.L. “Chiral 15-Metallacrown-5 Complexes Differentially

Bind Carboxylate Anions ,” J. Amer. Chem. Soc., 2001, 123, 6211-6212.

148. Farrer, B. T.; Pecoraro, V.L. "Thermodynamic Model for the Stabilization of Trigonal Hg(II) in a

Designed Three Helix Bundle," Biochemistry, 2001, 40, 14696-14705.

149. Smith II, T.S.; LoBrutto, R.; Pecoraro, V.L. “Paramagnetic Spectroscopy of Vanadyl Complexes:

Applications to Biological Systems,” Coord. Chem. Reviews, 2002, 228, 1-18.

150. Kessissoglou, D.P.; Bodwin, J.J.; Kampf, J.J.; Dendrinou-Samarab, C.; Pecoraro, V.L. "Pseudohalide

complexation by manganese 12-metallacrowns-4 complexes" Inorg. Chim. Acta, 2002, 331, 73-80

(Special issue in honor of Geoffrey Sykes).

151. Farrer, B.T.; Pecoraro, V.L. “Bioinorganic Chemistry,” in The Academic Press Encyclopedia of Science

and Technology, 3rd edition, Academic Press, New York, 2002 117-139.


152. Matzapetakis, M.; Farrer, B. T.; Wang, T.-C.; Hemmingsen, L.; Penner-Hahn, J. E.; Pecoraro, V.L. "Heavy

Metal Complexation by de Novo Designed Peptides: Comparison of Peptide Aggregation

Preferences in the Presence of Cadmium(II), Mercury(II) and Arsenic(III) " J. Amer. Chem. Soc., 2002,

124, 8042-8054.

153. Triller, M.U.; Hseih, W.-Y.; Pecoraro, V.L.; Rompel, A.; Krebs, B. "Preparation of Highly Efficient

Manganese Catalase Mimics," Inorg. Chem., 2002, 41, 5544-5554.

154. Rajendiran, T.M.; Kampf, J. W.; Pecoraro, V.L. "A Structurally Characterized Monomeric Mn(IV)

Complex in a Discrete N2O4 Coordination Environment, " Inorg. Chim Acta (issue in honor of

Helmut Sigel) 2002, 339, 497-502.

155. Cutland-Van Noord, A.D. ; Kampf, J.W.; Pecoraro, V.L. “Preparation of Resolved Four-Fold

Symmetric Amphiphilic Helices Using Chiral Metallacrown Building Blocks,” Angew. Chem.,

2002, 41, 4667-4670.

156. Smith, T.S.; Pecoraro, V.L. "Oxidation of Organic Sulfides By Vanadium Haloperoxidase Model

Complexes," Inorg. Chem., 2002, 41, 6754-6760.

157. Farrer, Brian T.; Pecoraro, Vincent L. “Heavy Metal Complexation by de Novo Peptide Design,” Curr.

Opin. Drug Discovery & Development, 2002, 5, 937-943.

158. Pecoraro, V.L., "Protagonists in Chemistry: Kenneth N. Raymond" Inorg. Chim. Acta, 2002, 341, XI-XIII.

159. Hseih, W.-Y.; Pecoraro, V.L. “Oxidation of m-Chlorobenzoic acid by Mn(V)=O complexes,” Inorg. Chim

Acta, (special issue honoring K.N. Raymond) 2002, 341, 113-117.

160. Rajendiran, T.M.; Setyawati, I.; Caudle, M.T.; Kampf, J. W.; Pecoraro, V.L. "The First Ferromagnetically

Coupled Mn(III/IV) Complex," J. Chem. Soc., Chem. Comm., 2003, 824-825.

161. Farrer, Brian T.; Pecoraro, Vincent L. “Kinetics of Hg(II) Encapsulation by a Weakly Associated Three-

Stranded Coiled Coil,” Proc. Natl. Acad. Sci., 2003, 100, 3760-3765.

162. Rajendiran, T.M.; Caudle, M.T.; Setyawati, I.; Kampf, J.W.; Pecoraro, V.L. “Evaluating Hydrogen Bond

Interactions in Enzymes Containing Mn(III)-Histidine Complexation Using Manganese Imidazole

Complexes," J. Biol. Inorg. Chem., 2003, 8, 283-293.

163. Alexiou, M.; Zaleski, C.; Yoder, D.; Kampf, J.W.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

"Models For the Lower S States of Photosystem II: A Trinuclear Mixed-Valent MnII/MnIV/MnII

Complex,” Inorg. Chem, 2003, 42(7); 2185-2187.

164. Lesniak, W.; Harris, W.R.; Yudenfreund-Kravitz, J.; Schacht, J.; Pecoraro, V.L. “The Solution Chemistry

of Copper(II)-Gentamicin Complexes: Relevance to Metal,” Inorg. Chem., 2003, 42, 1420-1429.

165. Johnson, J.A.; Kampf, J. W.; Pecoraro, V.L. “The Preparation of a New Type of Helicate: A Double-

Metallahelicate Containing 28 Copper Atoms,” Angew. Chem., Int. Ed., 2003, 42, 546-549.


166. Dendrinou-Samara, C.; Alexiou, M.; Zaleski, C. M.; Kampf, J. W.; Kirk, M. L.; Kessissoglou, D. P.;

Pecoraro, V. L. "Synthesis and Magnetic Properties of a Metallacryptate that Behaves as a Single-

Molecule Magnet " Angew. Chem., Int. Ed., 2003, 42, 3763-3766. (highlighted in Dec 13, 2004

C&ENews)

167. Triller, M. U.; Pursche, D.; Hsieh, W.-Y.; Pecoraro, V. L.; Rompel, A.; Krebs, B. “Catalytic Oxidation of

3,5-Di-tert-butylcatechol by a series of Mononuclear Manganese Complexes: Synthesis, Structure

and Kinetic Investigations,” Inorg. Chem., 2003, 42, 6274-6283.

168. Alexiou, M.; Zaleski, C. M.; Dendrinou-Samara, C.; Kampf, J. W.; Kessissoglou, D. P.; Pecoraro, V. L.

"Trinuclear Mixed Valent MnIIMnIVMnII Complexes- Structure and Magnetic Behavior," Z. Anorg. Allg.

Chem., 2003, 2348-2355.

169. Dendrinou-Samara, C.; Zaleski, C.M.; Evagorou, A.; Kampf, J.W.; Pecoraro, V.L.; Kessissoglou, D.

P. "A Cationic 24-MC-8 Manganese Cluster with Ring Metals Possessing Three Oxidation

States [MnII4MnIII

6MnIV2(4-O)2(3-O)4(3-OH)4(3-OCH3)2(pko)12](OH)(ClO4)3," J. Chem. Soc.,

Chem. Comm., 2003, 2668-9.

170. Lesniak, W.; McLaren, J.; Harris, W. R.; Pecoraro, V. L.; Schacht, J. "An Isocratic Separation for

Underivatized Gentamicin Components and 1H NMR Assignment," Carbohydrate Res. 2003,

338, 2853-2862.

171. Hsieh, W.-Y.; Campbell, K.; Britt, R.D.; Yoder, D.; Penner-Hahn, J. E.; Pecoraro, V. L. "The First

Spectroscopic Model for the S1 state Multiline Signal of the OEC," Biochim. Biophys. Acta:

Bioenergetics, 2004, 1655, 149-157.

172. Wu, A.J.; Penner-Hahn; J.E.; Pecoraro, V.L. "Structural, Spectroscopic and Reactivity Models for

the Manganese Catalases," Chem. Rev., 2004, 104, 903-938.

173. Zampella, G.; Kravitz, J.Y.; Webster, C.E.; Fantucci, P.; Hall, M.B.; Carlson, H.A.; Pecoraro, V.L.; De

Gioia, L. "Quantum Mechanical Models of the Resting State of the Vanadium-Dependent

Haloperoxidases” Inorg. Chem., 2004; 43, 4127-4136.

174. Zaleski, C.M.; Depperman, E.C.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. “Synthesis, Structure and

Magnetic Properties of a Novel Lanthanide-Transition Metal Complex:

Dy6Mn6(salicylhydroximate)16,” Angew. Chem. 2004, 43, 3912-14 (highlighted in Dec 13, 2004

C&ENews)

175. Glatzel, P.; Bergmann, U.; Yano, J.; Visser, H.; Robblee, J. H.; Gu, W.; de Groot, M. F.; Christou,

G.; Pecoraro, V. L.; Cramer, S. P.; Yachandra, V. K. “The Electronic Structure of Mn in Oxides,

Coordination Complexes, and the Oxygen-Evolving Complex of Photosystem II Studied by

Resonant Inelastic X-ray Scattering” J. Amer. Chem. Soc. 2004; 126, 9946-9959.

176. Weng, T.C.; Hsieh, W.-Y.; Uffelman, E. S.; Gordon-Wylie, S. W.; Collins, T.; Pecoraro, V.L.;

Penner-Hahn, J.E. "XANES Evidence Against a Manganyl Species in the S3 state of the Oxygen

Evolving Complex," J. Amer. Chem. Soc., 2004; 126, 8070-8071.


177. Lee, K.-H.; Matzapetakis, M.; Mitra, S.; Marsh, E.N.G.; Pecoraro, V.L. “Control of Metal

Coordination Number Through Subtle Sequence Modifications of Designed Peptides” J.

Amer. Chem. Soc. 2004; 126, 9178-9179.

178. Bren, K.; Pecoraro, V.L.; Gray, H.B. “Metalloprotein Folding” Inorg. Chem. 2004, 43, 7894-7896.

179. Ghosh, D.; Pecoraro, V.L. “Understanding Metalloprotein Folding Using De Novo Peptide

Design,” Inorg. Chem., 2004, 43, 7902-7915.

180. Lesniak, W.; Pecoraro, V. L.; Schacht, J. “Ternary Complexes of Gentamicin with Iron and Lipid

Catalyze Formation of Reactive Oxygen Species,” Chem. Res. Toxicol. 2005, 18, 357-364

181. Zampella, G.; Fantucci, P.; Pecoraro, V.L.; De Gioia, L. “DFT studies on the cofactor of vanadium

haloperoxidases: protonation state of the catalytically active peroxo species,” J. Amer. Chem.

Soc., 2005; 126, 953-60.

182. Ghosh, D.; Pecoraro, V.L. “Probing Metal-Protein Interactions Using a De Novo Design

Approach” Curr. Opin. Chem. Biol., 2005, 9, 97-103.

183. Kravitz, J. Y.; Pecoraro, V.L. “Synthetic and Computational Modeling of the Vanadium

Dependent Haloperoxidases” Pure Appl. Chem., 2005, 77, 1595-1605.

184. Afrati T.; Dendrinou-Samara C.; Zaleski, C.J.; Kampf, J.W.; Pecoraro, V.L.; Kessissoglou, D.P.

“Synthesis and Structure of [18-MCCuII(N)pko-6]6+: A new Member of Anion Encapsulating

Metallamacrocycles” Inorg. Chem. Comm., 2005, 8, 1173-1176.

185. Angaridis, P.; Kampf, J.W.; Pecoraro, V.L. “Multinuclear Fe(III) Complexes with Polydentate

Ligands of the Family of Dicarboxyimidazoles: Nuclearity- and Topology-Controlled Syntheses

and Magneto-Structural Correlations” Inorg. Chem., 2005, 44, 3626-3635.

186. Zaleski, C.J.; Depperman, E.; Kessissoglou, D.P.; Kirk, M.L.; Pecoraro, V.L. “Metallacryptate

Single-Molecule Magnets: The Effect of Lower Molecular Symmetry” J. Amer. Chem. Soc.,

2005, 127, 12862-12872.

187. Kravitz, J. Y.; Pecoraro, V.L.; Carlson, H. “Quantum Mechanics/Molecular Mechanics

Calculations of the Vanadium Dependent Chloroperoxidase” J. Chem.Theor.and Comput.

2005, 1, 1265-1274.

188. Scarpellini, M.; Wu, A.J.; Kampf, J.W.; Pecoraro, V.L. “Corroborative Models of the Co(II)

Inhibited Fe/Mn SODs,” Inorg. Chem., 2005, 44, 5001-5010.

189. Ghosh, D.; Lee, K.-H.; Pecoraro, V.L. “Free Energy Relationship of Metal Binding to Three

Stranded Coiled Coils,” Biochemistry, 2005, 44, 10732-10740.

190. Hsieh, W.Y.; Zaleski, C. M.; Pecoraro, V.L. Liu, S. “Mn(II) Complexes of Monoanionic Bidentate

Chelators: The x-ray Crystal Structures of Mn(DHA)2(CH3OH)2 (DHA=Dehydroacetic Acid) and

[Mn(ema)2(H2O)]2 2H2O (Hema= 2-Ethyl-3-Hydroxy-4-Pyrone), Inorg. Chim. Acta, 2006, 359 (1): 228-

236.


191. Matzapetakis, M.; Pecoraro, V.L. “Site selective metal binding by designed -helical peptides”

J. Amer. Chem. Soc, 2005, 127 (51): 18229-18233.

192. Lee, K.-H.; Cabello, C.; Hemmingsen, L.; Marsh, E.N.G.; Pecoraro, V.L. ”Using Non-Natural

Amino Acids to Control Metal Coordination Number in Three Stranded Coiled-Coils" Angew.

Chem. Int. Ed. 2006, 45, 2864-2868.

193. Matzapetakis, M.; Ghosh, D.P.; Weng, T.-C.; Penner-Hahn, J.E.; Pecoraro, V.L. “The Binding of

Pb(II) and Bi(III) to de novo designed peptides,” JBIC, 2006, 11(7), 876-890.

194. Zampella, G.; Fantucci, P.; Pecoraro, V.L.; De Gioia, L. “Insight into the Catalytic Mechanism

of Vanadium Haloperoxidases. DFT Investigation of Vanadium Cofactor Reactivity,” Inorg.

Chem., 2006, 45, 7133-7143.

195. Zaleski, C.J.; Depperman, E.; Kampf, J.W.; Kirk, M.L.; Pecoraro, V.L. “Using LnIII[15-MCCuII(N)S-

pheHA-5]3+ Complexes to Construct Chiral Single-Molecule Magnets and Chains of Single-

Molecule Magnets” Inorg. Chem., 2006, 45, 10022-10024.

196. Iranzo, O.; Ghosh, D.; Pecoraro, V. L. “Assessing the integrity of designed homomeric

parallel 3-stranded coiled coils in the presence of metal ions,” Inorg. Chem., 2006, 45, 9959-

9973.

197. Schneider, C.J.; Zampella, G.; Greco, C.; Pecoraro, V. L.; De Gioia, L. “Mechanistic Analysis of

Nucleophilic Substrate Oxidation by Functional Models of Vanadium Dependent

Haloperoxidases: A Density Functional Theory Study” Eur. J. Inorg. Chem., 2007, 515-523

[Cover Article].

198. Mezei, G.; Kampf, J.W.; Pan, S.; Poeppelmeier, K.; Watkins, B.; Pecoraro, V.L. “Metallacrown-

Based Molecular Capsules: Selective Encapsulation of Three Isonicotinate Anions,” Chem.

Comm., 2007, 1148-1150.

199. Mezei, G.; Kampf, J.W.; Pecoraro, V. L., “Temperature-, molar ratio- and counterion-effect on

the crystal growth of bipyridinium-bis-alkylcarboxylic acid/crown ether pseudorotaxanes”

New Journal of Chemistry, 2007, 31, 439-446.

200. Zaleski, C.J.; Cutland-Van Noord, A.D.; Kampf, J.W.; Pecoraro, V.L. “Controlling the Polymorph

of LnIII(NO3)3-x(OH)x[15-MCCuII(N)S-pheHA-5] Complexes Through Solvent Type and LnIII Ion

Choice” Crystal Growth and Design 2007, 7, 1098-1105.

201. Zaleski, C.J.; Kampf, J.W.; Mallah, T.; Kirk, M.L.; Pecoraro, V.L. “Using the Metallacrown Analogy

to Prepare Mixed d-f Element Clusters: LnIII4MnIII

6” Inorg. Chem., 2007, 46, 1954-1956.

202. Afrati, T.; Zaleski, C.; Dendrinou-Samara, C.; Mezei, G.; Kampf, J. W.; Pecoraro, V. L.;

Kessissoglou, D. P. “Di-2-Pyridyl Ketone Oxime in Copper Chemistry: di-, tri-, penta- and

hexanuclear Clusters” Dalton.Trans, 2007, 2658-2668.

203. Lim, C.S.; Van Noord, A.C.; Kampf, J.W.; Pecoraro, V.L. “Assessing Guest Selectivity Within

Metallacrown Host Capsules” Eur. J Inorg. Chem., 2007, 1347-1350.


204. Iranzo, O.; Cabello, C.; Pecoraro, V.L. “Heterochromia in Designed Metallopeptides: Geometry-

Selective Binding of Cd(II) in a De Novo Peptide” Angew. Chem., 2007, 46, 6688-6691 [Cover

Article].

205. Touw, D.S. ; Stuckey, J.A.; Nordman, C.E.; Pecoraro, V.L. “Identifying important structural

characteristics of arsenic resistance proteins by using designed three-stranded coiled coils”

Proc. Natl. Acad. Sci. (USA), 2007, 104, 11969-11974.

206. Schneider, C.J.; Pecoraro, V.L. “Understanding the Mechanism of Vanadium Dependent

Haloperoxidases and Related Biomimetic Catalysis,” ACS Symposium Series, 2007, 974,

Chapter 12, 148-162.

207. Gätjens, J.; Sjodin, M.; Pecoraro, V.L.; Un. S. “The relationship between the manganese(II) zero-

field interaction and Mn(II)/Mn(III) redox potential of Mn(4'-X-terpy)2 complexes” J. Amer.

Chem. Soc., 2007, 129, 13825-.

208. Iranzo, O.; Thulstrup, P.W.; Ryu, S.-B.; Hemmingsen, L.; Pecoraro, V.L. “The Application of 199Hg

NMR and 199mHg PAC Spectroscopies to Define the Biological Chemistry of Hg(II): A Case

Study Using Designed Two and Three Stranded Coiled Coils,” Chem: Eur. J. 2007, 13, 9178-

9190 [Frontispiece].

209. Mezei, G.; Zaleski, C.; Pecoraro, V.L. “Structural and Functional Evolution of Metallacrowns,”

Chem. Rev., 2007, 107, 4933-5003.

210. Signorella, S.; Buldt-Karentzopoulos, K.; Rompel, A.; Krebs, B.; Pecoraro, V.L.; Tuchagues, J.-P.

“Reevaluation of the Rates of Mn Catalase Mimics” Inorg. Chem. 2007, 46, 10864-10868.

211. Scarpellini, M.; Gätjens, J.; Karylowski, O.; Kampf, J.W.; Sherman, S.E.; Pecoraro, V.L. ”Modeling

the Resting State of Oxalate Oxidase and Oxalate Decarboxylase Enzymes,” Inorg. Chem.

2008, 47, 3584-3593.

212. Mullins, C.S.; Pecoraro, V.L. “Reflections on Small Molecule Manganese Models that Seek to

Mimic Photosynthetic Water Oxidation Chemistry,” Coord. Chem. Reviews, 2008, 252, 416-

443.

213. Sjodin, M.; Gätjens, J.; Tabares, L.C.; Thuéry, P.; Pecoraro, V.L.; Un, S. ”Tuning the Redox

Properties of Manganese(II) and its Implications to the Electrochemistry of Manganese/Iron

Superoxide Dismutases,” Inorg. Chem., 2008, 47, 2897-2908.

214. Pecoraro, V.L.; Hsieh, W.Y. “In Search of High Valent Intermediates in Schiff Base Containing

Manganese Dimers,” Inorg. Chem. 2008, 47, 1765-1778.

215. Meelich, K.; Zaleski, C.; Pecoraro, V.L. “Using Small Molecule Complexes to Elucidate Features

of Photosynthetic Water Oxidation” Phil. Trans. Royal Soc., 2008, 363, 1271-1281.

216. Schneider, C.J.; Penner-Hahn, J.E.; Pecoraro, V.L. “Elucidating the Protonation Site of

Vanadium Peroxide Complexes and the Implications for Biomimetic Catalysis”J. Amer. Chem.

Soc. 2008, 130, 2712-2713.


217. Zaleski, C.J.; Weng, T-C; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.;

Kampf, J.W.; Penner-Hahn, J.E.; Pecoraro, V.L; Kessissoglou, D.P. “Structural and Physical

Characterization of Tetranuclear [MnII3MnIV] and [MnII

2MnIII2] Valence-Isomers Manganese

Clusters" Inorg. Chem. 2008, 47, 6127-6136. [Cover Article].

218. Peacock, A.F.A.; Stachura, M.; Hemmingsen, L.; Pecoraro, V.L. “Diastereopeptides: A new

approach to controlling metal ion coordination” Proc. Natl. Acad. Sci., 2008, 105, 16566-

16571.

219. Luczkowski, M.; Stachura, M.; Schirf, V.; Demeler, B.; Hemmingsen, L.; Pecoraro, V.L. “Design of

Thiolate Rich Metal Binding Sites within a Peptidic Framework,” Inorg. Chem. 2008, 47, 10875-

10888. DOI: 10.1021/ic8009817

220. Gätjens, J.; Kampf, J.W.; Thuéry, P.; Pecoraro, V.L “Corroborative Cobalt and Zinc Models of -

amino--carboxymuconic--semialdehyde decarboxylase (ACMSD),” Dalton Transactions,

2009 51-62. DOI: 10.1039/b809453e

221. Pecoraro, V.L.; Peacock, A.F.A.; Iranzo, O.; Luczkowski, M. “Understanding the Biological

Chemistry of Hg(II) Using a De Novo Design Strategy,” ACS Symposium Series, E. Long and

M.J. Baldwin, Eds, 2009, 183-197.

222. Gätjens, J.; Kampf, J.W.; Pecoraro, V.L “Preparation of a new 16-MC-4 Structure Type That

Captures Mn(II) in the Central Cavity” Inorg. Chim. Acta, 2009, 362, 878-886 [special issue in

honor of Bernhard Lippert]. DOI:10.1016/j.ica.2008.02.006

223. Iranzo, O.; Jakusch, T.; Lee, K-H; Thulstrup, P.W.; Hemmingsen, L.; Pecoraro, V.L. “The

Correlation of 113Cd NMR and 111mCd PAC Spectroscopies Provides a Powerful Approach for

Characterizing the Structure of Cd(II) Substituted Zn(II) Proteins” Chem: Eur. J. 2009, 15, 3761-

3772.

224. Peacock, A.F.A.; Iranzo, O.; Pecoraro, V.L. “Harnessing natures ability to control metal ion

coordination geometries using de novo designed peptides” Dalton Transactions, 2009, 2271-

2280. [Cover]

225. Lim, C.S.; Kampf, J.W.; Pecoraro, V.L. “Establishing the binding affinity of organic carboxylates

to 15-metallacrown-5 Complexes,” Inorg. Chem., 2009, 48, 5224-5233.

226. Micera, G.; Pecoraro, V.L.; Garribba, E. “Assessing the Dependence of 51V Az Values on the

Aromatic Ring Orientation of VIVO2+ Pyridine Complexes,” Inorg. Chem. 2009, 48, 5790-5796.

http://dx.doi.org/10.1021%2Fic8009817

http://www.rsc.org/Publishing/Journals/DT/article.asp?doi=b809453e

227. Tabares, L.; Gätjens, J.; Hureau, C.; Burrell, M.R.; Bowater, L.; Pecoraro, V.L.; Bornemann,

S.; Un, S. “The pH-dependent Structures of the Manganese Binding Sites in Oxalate

Decarboxylase as Revealed by High-Field Electron Paramagnetic Resonance” J. Phys. Chem.

2009, 113, 9016-9025.

228. Peacock, A.F.A.; Stuckey; J.A.; Pecoraro, V.L. “Chirally Switching Metal Coordination

Environments in Designed Peptides,” Angew. Chem., 2009, 48, 7371-7374.[inside cover]


229. Lim, C.S.; Jankolovits, J.; Kampf, J.W.; Pecoraro, V.L. “Advances in Mesostructured Systems:

Construction of Chiral Nano Channels by Metallacrown Self Assembly” Chem: Asian J., 2010,

5, 46-49. [cover article]

230. Jankolovits, J.; Kampf, J.W.; Maldonado, S.; Pecoraro, V.L. “Voltammetric Characterization of

Redox-Inactive Guest Binding to 15-Metallacrown-5 Hosts Based on Competition with a

Redox Probe” Chem.: Eur. J, 2010, 16, 6786-6796. [cover article]

231. Jankolovits, J.; Lim, C.-S.; Kampf, J.W.; Pecoraro, V.L. “Disruption of the La(III)[15-

Metallacrown-5] Cavity through Bithiophene Dicarboxylate Inclusion” Z. Naturforschung.

2010, 65b, 263-272.

232. Tegoni, M.; Furlotti, M.; Tropiano, M.; Lim, C.S.; Pecoraro, V.L. ‘Thermodynamics of core metal

replacement and self assembly of Ca2+ 15-metallacrown-5” Inorg. Chem, 2010, 49, 5190-5201.

233. Neupane, K.; Pecoraro, V.L. “Probing a Homoleptic PbS3 Coordination Environment in a

Designed Peptide Using Pb-207 NMR: Implications for Understanding the Molecular Basis of

Lead Toxicity,” Angew. Chem., 2010, 49, 8177–8180.

234. Chakraborty, S.; Touw, D.S.; Peacock, A. F. A. ; Stuckey, J.; Pecoraro, V. L. “Structural

Comparisons of Apo- and Metallated Three Stranded Coiled Coils Clarify Metal Binding

Determinants in Thiolate Containing Designed Peptides” J. Amer. Chem. Soc., 2010, 132

(38), 13240–13250.

235. Boron, III, T. T.; Kampf, J.W.; Pecoraro, V.L. “A Mixed 3d-4f 14-Metallacrown-5 Complex that

Displays Single-Molecule Magnetic Behavior through Geometric Control of

Magnetoanisotropy” Inorg. Chem., 2010, 49 (20), 9104–9106.

236. Ellis, P.D.; Lipton, A.S.; Sears, J.A.; Yang, P.; Dupuis, M.; Boron, III, T. T.; Pecoraro, V. L.;

Stich, T.; Britt, R. D. “The 55Mn Solid State NMR Spectroscopy of bis(-oxo)dimanganese(IV)

[Mn2O2(salpn)2]. An Antiferromagnetically Coupled Mn4+ Dimer at Cryogenic

Temperatures” J. Amer. Chem. Soc., 2010, 132 (47), pp 16727–16729.

237. Iranzo, O.; Chakraborty, S.; Hemmingsen, L.; Pecoraro, V.L. “Controlling and Fine Tuning the

Physical Properties of Two Identical Metal Coordination Sites in De Novo Designed Three

Stranded Coiled Coil Peptides” J. Amer. Chem Soc., 2011, 133 (2), pp 239–251.

238. Chakraborty,S.; Kravitz, J.Y.; Thulstrup, P.W.; Hemmingsen, L.; DeGrado, W.F.; Pecoraro,

V.L. “Realization of a Designed Three-Helix Bundle Capable of Binding Heavy Metals in a

Tris(Cysteine) Environment” Angew. Chem. Int. Ed. 2011, 50, 2049 –2053 (inside cover).


239. Jankolovits, J.; Andolina, C.M.; Kampf, J.W.; Raymond, K.N.; Pecoraro, V.L. “Assembly of

NIR Luminescent Lanthanide Host(Host-Guest) Complexes Using a Lanthanide-

Metallacrown Sandwich Motif” Angew. Chem., 2011, 50(41), 9660-9664.

240. Lim, C.S.; Jankolovits, J.; Zhao, P.; Kampf, J.W.; Pecoraro, V.L. “Gd(III)[15-Metallacrown-5]

Recognition of Chiral α-Amino Acid Derivatives,” Inorg. Chem., 2011, 50, 4832-4841.

241. Neupane, K.; Pecoraro, V.L. “Pb-207 NMR Spectroscopy Reveals that Pb(II) Coordinates with

Glutathione (GSH) and Tris Cysteine Zinc Finger Proteins in a PbS3 Coordination” J. Inorg

Biochem., 2011, 105, 1030-1034.

242. Zaleski, C.; Lim, C.S.; van Noord, A.C.; Kampf, J.W.; Pecoraro, V.L. “The Effects of Central

Lathanide Ion Radius on the 15-MCCu(II)N(pheHA)-5 Structure” Inorg. Chem., 2011, 50, 7707-17.

243. Zaleski, C.; S. Tricard; E. C. Depperman; W. Wernsdorfer; T. Mallah; M. L. Kirk; and V. L.

Pecoraro, “Single-molecule magnet behavior of a pentanuclear Mn-based metallacrown

complex: solid state and solution magnetic studies” Inorg. Chem., 2011, 50 (22), pp 11348–

11352.

244. Zastrow, M.L.; Peacock, A.F.A.; Stuckey, J.A.; Pecoraro, V.L. “Hydrolytic Catalysis and

Structural Stabilization in a Designed Metalloprotein” Nature: Chemistry, 2012, 4, 118-123.

245. Zampella, G.; Neupane, K.P.; DeGioia, L.; Pecoraro, V.L. “The Importance of

Stereochemically Active Lone Pairs For Influencing Pb(II) and As(III) Protein Binding” Chem.

Eur. J, 2012, 18, 2040-2050.

246. Chakraborty, S.; Iranzo, O.; Zuiderweg, E.R.P.; Pecoraro, V.L. “An Experimental and

Theoretical Evaluation of Multi-site Cd(II) Exchange in Designed Three-Stranded Coiled

Coils” J. Amer. Chem. Soc., 2012, 134, 6191-6203.

247. Jankolovits, J.; Lim, C.S.; Mezei, G.; Kampf, J.W.; Pecoraro, V.L. “Influencing the Size and

Anion Selectivity of Dimeric Ln3+[15-Metallacrown-5] Compartments through Systematic

Variation of the Host Side Chains and Central Metal” Inorg. Chem., 2012, 51, 4527-4538.

248. Sanna, D.; Pecoraro, V.L.; Micera, G.; Garribba, E. “Application of DFT methods to the Study

of Coordination Environment of VO2+ ion in V-proteins” J. Biol. Inorg. Chem. 2012, 17, 773-790.

249. Grant, J.T.; Jankolovits, J.; Pecoraro, V.L. “Enhanced Guest Affinity and Enantioselectivity

through Variation of the Gd3+[15-Metallacrown-5] Side Chain” Inorg. Chem. 2012, 51, 8034–

8041.


250. Tegoni, M.; Yu, F.; Berseloni, M.; Penner-Hahn, J.E.; Pecoraro, V.L. “Designing functional

type 2 copper centers within alpha-helical coiled coils that have nitrite reductase activity”

Proc. Nat. Acad. Sci. (USA), 2012, 109, 21234–21239.

251. Lim, C.S.; Tegoni, M.; Kampf, J.W.; Pecoraro, V.L. “Clarifying the Mechanism of Cation

Exchange in Ca(II)[15-MCCu(II)Ligand-5] Complexes” Inorg. Chem., 2012, 51, 11533–11540.

252. Jankolovits, J.; Kampf, J.W.; Pecoraro, V.L. “Comparison of Structural Constraints on the

Ln(III)[15-MC-5] Topology using Ni(II), Cu(II), or Zn(II) Ring Metals”, Polyhedron, 2013, 52,

491-499. DOI: 10.1016/j.poly.2012.08.046.

253. Zastrow, M.; Pecoraro, V.L. “Designing functional metalloproteins: from structural to catalytic

metal sites” Coord. Chem. Rev. 2013, 257, 2565-2588.

254. Peacock, A.F.A.; Pecoraro, V.L. “Natural and Artificial Proteins Containing Cadmium”,

Chapter 10 in Cadmium: From Toxicity to Essentiality, Metal Ions in Life Sciences, A. Sigel, H.

Sigel, and R. K. O. Sigel (eds.), 2013, 11, 303–337. DOI: 10.1007/978-94-007-5179-8_10.

255. Zastrow, M.; Pecoraro, V.L. “The Influence of Active Site Location on Catalytic Activity in de

Novo Designed Zinc Metalloenzymes” J. Amer. Chem. Soc., 2013, 135, 5895-5903.

256. Łuczkowski, M.; Zeider, B.A.; Stachura, M.; Chakraborty, S.; Hemmingsen, L.; Huffman, D.L.

Pecoraro, V.L. “Probing the Coordination Environment of the Human Copper Chaperone

HAH1: Characterization of Hg(II) bridged Homodimeric Species in Solution” Chem.: Eur. J.,

2013, 19, 9042-9049.

257. Yu, F.; Pecoraro, V.L. “Use of the Mechanistic Probe 2-methyl-1-phenylpropan-2-yl

hydroperoxide (MPPH) to Discriminate Between the Formation of MnIVMnIV(O.) and

MnIVMnV=O species” Polyhedron, 2013, 64, 99-105. (special issue honoring George Christou).

258. Jankolovits, J.; Kampf, J.W.; Pecoraro, V. L. “Isolation of Elusive Tetranuclear and

Pentanuclear M(II)-Hydroximate Intermediates in the Assembly of Lanthanide [15-

Metallacrown-5] Complexes” Inorg. Chem., 2013, 52, 5063-5076.

259. Lassalle-Kaiser, B.; Boron III, T.T.; Krewald, V.; Kern, J.; Beckwith, M.A.; Delgado-Jaime,

M.U.; Schroeder, H.; Mori, R.A.; Nordlund, D.; Weng, T.-C.; Sokaras, D.; Neese, F.;

Bergmann, U.; Yachandra, V.K; DeBeer, S.; Pecoraro, V.L.; Yano, J. “Experimental and

Computational X-ray Emission Spectroscopy as a Direct Probe of Protonation States in Oxo-

Bridged MnIV-Dimers Relevant to Redox-active Metalloproteins” Inorg. Chem. 2013, 52, 12915-

12922.


260. Glatzel, P.; Schroeder, H.; Pushkar, Y.; Boron, T.T., III; Mukerjee, S.; Christou, G.; Pecoraro,

V.L.; Messinger, J.; Yachandra, V.K.; Bergmann, U.; Yano, J. “Electronic Structural Changes of

Mn in the Oxygen-Evolving Complex of Photosystem II During the Catalytic Cycle”, Inorg.

Chem., 2013, 52, 5642-5644.

261. Krewald, V.; Lassalle-Kaiser, B.; Boron III, T.T.; Pollock, C.J.; Kern, J.; Beckwith, M.A.;

Yachandra, V.K. Pecoraro, V.L.; Yano, J.; Neese, F.; DeBeer, S. “The Protonation States of an

Oxo-Bridged MnIV-Dimer Resolved by Experimental and Computational Mn K Pre-Edge X-

Ray Absorption Spectroscopy” Inorg. Chem., 2013, 52, 12904-12914.

262. Yu, F.; Penner-Hahn, J.E.; Pecoraro, V.L. “de Novo Designed Metallopeptides with Type 2

Copper Centers: Modulation of Reduction Potentials and Nitrite Reductase Activities" J.

Amer. Chem. Soc., 2013, 135, 18096-18107.

263. Yu, F.; Cangelosi, V.; Zastrow, M.L.; Tegoni, M.; Plegaria, J.; Tebo, A.; Mocny, C.; Ruckthong,

L.; Qayyum, H.; Pecoraro, V.L. “Protein design: towards functional metalloenzymes” Chem.

Rev., 2014, 114, 3495−3578.

264. Cangelosi, V.; Pecoraro, V.L. “Binding, Transport and Storage of Lead” Binding, Transport and

Storage of Metal Ions in Biological Cells, W. Maret & A. Wedd, eds; Royal Society of Chemistry:

Cambridge, RSC Metallobiology Series No. 2, 2014, Chapter 28, 830-868.

265. Trivedi, E.R.; Eliseeva, S.V.; Jankolovits, J.; Olmstead, M.; Petoud, S.; Pecoraro, V.L. “Highly

Emitting Near-Infrared Lanthanide “Encapsulated Sandwich” Metallacrown Complexes with

Excitation Shifted Toward Lower Energy” J. Amer. Chem. Soc. 2014, 136, 1526−1534.

266. Azar, M.R.; Boron, III, T.T.; Lutter, J.C.; Daly, C.; Zegalia, K.A; Nimthong, R.; Ferrence, G.M.;

Zeller, M.; Kampf, J.W.; Pecoraro, V.L.; Zaleski, C.M. “Controllable Formation of

Heterotrimetallic Coordination Compounds - Systematically Incorporating Lanthanide and

Alkali Metal Ions into the Manganese 12-Metallacrown-4 Framework” Inorg. Chem., 2014, 53,

1729−1742.

267. Zastrow, M. L.; Pecoraro, V.L. “Designing hydrolytic zinc metalloenzymes” Biochemistry

2014, 53, 957−978.

268. Deb, A.; Boron, III, T.T.; Itou, M.; Sakurai, Y.; Mallah, T.; Pecoraro, V.L.; Penner-Hahn, J.E.

“Understanding Spin Structure in Metallacrown Single-Molecule Magnets”J. Amer. Chem.

Soc. 2014, 136, 4889-4892.


269. Jankolovits, J.; Kampf, J.W.; Pecoraro, V.L. “Solvent Dependent Assembly of Lanthanide

Metallacrowns Using Building Blocks with Incompatible Symmetry Preferences” Inorg.

Chem., 2014, 53, 7534-7546.

270. Cangelosi, V.; Deb. A.; Penner-Hahn, J.E.; Pecoraro, V.L. “A de novo designed metalloenzyme

for the hydration of CO2” Angew. Chem. 2014, 53, 7900-7903.

271. Oyala, P.H.; Stich, T.A.; Stull, J.A.; Yu, F.; Pecoraro, V.L.; Britt, R. D. “Pulse EPR Studies of 13C-methanol bound to the Mn4CaO5 cluster in the S2 state of PSII,“ Biochemistry, 2014, 53 (50),

7914–7928.

272. Plegaria, J.; Pecoraro, V.L. “Sculpting Metal Binding Environments in De Novo Designed

Three-Helix Bundles”, Israel J. Chem., 2015, 55, 85-95.

273. Chow, C.Y.; Trivedi, E.R.; Pecoraro, V.L.; Zaleski, C.M. “Heterometallic Mixed 3d-4f

Metallacrowns: Structural versatility, luminescence, and molecular magnetism” Comm. Inorg.

Chem., 2014, 35, 214-253.

274. Tebo, A.; Pecoraro, V.L. “Designing Catalytic and Electron Centers in De Novo Designed

Proetins,” Current Opinion in Chemical Biology, 2015, 25, 65-70.

275. Jankolovits, J.; Kampf, J.W.; Pecoraro, V.L. “Assembly of Zinc Metallacrowns with an α-

Amino Hydroxamic Acid Ligand” Chinese Chemistry Letters, 2015, 26, 444-448.

276. Plegaria, J. P.; Dzul, S.; Zuiderweg, E.R.P.; Stemmler, T.J.; Pecoraro, V.L. “Solution Structure

and Stability of a De Novo Designed Peptide that Sequesters Toxic Heavy Metals”

Biochemistry 2015, 54, 2858−2873.

277. Ross, M.R; White, A.M.; Yu, F.; King, J.T.; Pecoraro, V.L.; Kubarych, K.J. “Histidine

Orientation Modulates the Structure and Dynamics of a de Novo designed Metalloenzyme” J.

Amer. Chem. Soc. 2015, 137, 10164-10176.

278. Chow, C.Y.; Campbell, V.E.; Guillot, R.; Kampf, J.W.; Wernsdorfer, W.; Mallah, T.; Pecoraro,

V.L. “Assessing the Role of Super-Exchange Coupling in a Dinuclear Dysprosium(III) Single-

Molecule Magnet” Chemical Sciences, 2015, 6, 4148-4159.

279. Mocny, C.S.; Pecoraro, V.L. “De Novo Protein Design as a Methodology for Synthetic

Bioinorganic Chemistry” Accts. Chem. Resrch. 2015, 48, 2388-2396.


280. Plegaria, J.S.; Duca, M.; Tard, C.; Deb, A.; Penner-Hahn, J.E.; Pecoraro, V.L. “De Novo Design

of Copper Metallopeptides Inspired by Native Cupredoxins,” Inorg. Chem. 2015, 54, 9470-

9482.

281. Plegaria, J.S.; Herrero, C.; Quaranta, A.; Pecoraro, V.L. “Electron Transfer Activity of a de

Novo Designed Copper Center in a Three-Helix Bundle Fold,” Biochim. Biophys. Acta-

Bioenergetics 2015, 522-530.

282. Tebo, A.G.; Hemmingsen, L.; Pecoraro, V.L. “Variable primary coordination environments of

Cd(II) Binding to Three Helix Bundles Provide a Pathway for Rapid Metal Exchange”

Metallomics 2015, 7, 1555-1561.

283. Plegaria, J.S.; Pecoraro, V.L. “de Novo Design of Metalloproteins and Metalloenzymes in a

Three Helix Bundle,” in Computational Design of Ligand Binding Proteins. L. B. Stoddard.

New York, NY, Springer New York: 2016, 187-196.

284. Chow, C. Y.; Eliseeva, S. V.; Trivedi, E. R.; Nguyen, T.; Kampf, J.W.; Petoud, S.; Pecoraro, V.L.

“Ga3+/Ln3+ Metallacrowns: A Promising Family of Highly Luminescent Lanthanide

Complexes that Covers Visible and Near-Infrared Domains” J. Amer. Chem. Soc., 2016, 138,

5100-5109.

285. Atzeri, C.; Marchiò, L.; Chow, C.Y.; Kampf, J.W.; Pecoraro, V.L.; Tegoni, M. “Design of 2D

Porous Coordination Polymers Based on Metallacrown Units”, Chem: Eur. J. 2016, 6482–6486.

286. Chow, C.Y.; Guillot, R.; Riviere, E.; Kampf, J.W.; Mallah, T.; Pecoraro, V.L. “Fe(III) Based 9-

Metallacrown-3 Complexes Exhibit Magnetocoolant Properties” Inorg. Chem., 2016, 55, 10238-

10247.

287. Cangelosi, V; Ruckthong, L.; Pecoraro, V.L. “Lead(II) Binding in Natural and Artificial

Proteins,” Chapter 9 in Metals in Life Sciences, Volume 17, H. Sigel, A. Sigel & R. Sigel, eds,

2017 .

288. Ruckthong, L.; Stuckey, J. A.; Pecoraro, V.L. “Methods for Solving Highly Symmetric de Novo

Designed Metalloproteins: Crystallographic Examination of a Novel Three Stranded Coiled

Coil structure containing D-amino Acids” Methods in Enzymology, Academic Press, Vol 580,

2016, 135-148.

289. Ruckthong, L.; Zastrow, M.L.; Stuckey, J. A.; Pecoraro, V.L. “A Crystallographic Examination

of Predisposition Versus Preorganization in de Novo Designed Metalloproteins” J. Amer.

Chem. Soc., 2016, 138, 11979-11988.


290. Pecoraro, V.L. “Preface: Peptide, Protein and Enzyme Design” Methods in Enzymology

Academic Press, Vol 580, 2016, xvii.

291. Boron, III, T.T.; Lutter, J.; Daly, C.I.; Chow, C.Y.; Davis, A.H.; Nimthong, R.; Zeller, M.;

Kampf, J.W.; Zaleski, C.M.; Pecoraro, V.L. “The nature of the bridging anion controls the

single-molecule magnetic properties of DyX4M 12-Metallacrown-4 complexes,” Inorg. Chem.,

2016, 55, 10597-10607.

292. Nguyen, T.N.; Pecoraro, V.L. “Metallacrowns: From Discovery to Potential Applications in

Biomolecular Imaging” in Comprehensive Supramolecular Chemistry II, Elsevier, 2017, 5, 195-

212.

293. Stachura, M.; Chakraborty, S.; Gottberg, A.; Ruckthong, L.; Pecoraro, V.L.; Hemmingsen, L.

“Remote Mutation Affects Nanosecond Water Exchange Dynamics at Protein Metal Site,” J.

Amer. Chem Soc., 2017, 139, 79-82.

294. Tebo, A.G.; Quaranta, A.; Herrero, C.; Pecoraro, V.L.; Aukuloo, A. “Intramolecular

photogeneration of a tyrosine radical in a designed protein” ChemPhotoChem, 2017, 1, 89-92.

295. Sgarlata, C.; Giuffridi, A.; Trivedi, E.; Pecoraro, V.L.; Arena, G. “Anion encapsulation drives

the formation of dimeric Gd3+[15-Metallacrown-5] complexes in aqueous solution” Inorg.

Chem., 2017, 56, 4771-4774.

296. Ruckthong, L.; Peacock, A.F.A.; Pascoe, C.E.; Hemmingsen, L.; Stuckey, J. A.; Pecoraro, V.L.

“D-Cysteine Ligands Control Metal Geometries Within de Novo Designed Three-Stranded

Coiled Coils,” Chem. Eur. J. 2017, 23, 8232-8243. DOI: 10.1002/chem.201700660.

297. Martinìc, I.; Eliseeva, S. V.; Nguyen, T.; Pecoraro, V.L.; Petoud, S. “Near-Infrared Optical

Imaging of Necrotic Cells by Photostable Lanthanide-Based Metallacrowns,” J. Amer. Chem.

Soc., 2017, 139 (25), pp 8388–8391 DOI: 10.1021/jacs.7b01587.

298. Martinìc, I.; Eliseeva, S. V.; Nguyen, T.N.; Kampf, J.W.; Pecoraro, V.L.; Petoud, S. “Near-Infrared

Optical Imaging Agents for in vitro Cell Fixation,” Chem. Sci., 2017, 8(9): 6042–6050.

299. Ruckthong, L.; Deb, A.; Hemmingsen, L.; Penner-Hahn, J.E.; Pecoraro, V.L. “Incorporation of

Second Coordination Sphere D-Amino Acids Alter Cd(II) Geometries in Designed Thiolate-rich

Proteins” JBIC 2018, 23, 123-135. (doi: 10.1007/s00775-017-1515-7).

300. Nguyen, T.N.; Chow, C.Y.; Eliseeva, S.V.; Kampf, J.W.; Trivedi, E.R.; Martinic, I Petoud, S.;

Pecoraro, V.L. “One-step Assembly of Visible and Near-infrared Emitting Metallacrown Dimers

Using a Bifunctional Linker” Chem. Eur. J., 2018, 24, 1031-1035. (10.1002/chem.201703911).


301. Lutter, J.; Zaleski, C.; Pecoraro, V.L. “Metallacrowns: Supramolecular Constructs with Potential

in Extended Solids, Solution-State Dynamics, Molecular Magnetism, and Imaging

Applications” Adv. Inorg. Chem., 2018; Vol. 71, pp 177 – 246.

302. Cabral, A.D.S.; Jakolevska, J.; Deb, A.; Penner-Hahn, J.E.; Pecoraro, V.L.; Freisinger, E. “Further

insights into the metal ion binding abilities and the metalation pathway of a plant

metallothionein from Musa acuminata” JBIC, 2018; 23(1): 91-107. (doi: 10.1007/s00775-017-

1513-9).

303. Rajczak, E.; Pecoraro, V.L.; Juskowiak, B. “Sm(III)[12-MC Ga(III)shi-4] as a luminescent probe

for G-quadruplex structure” Metallomics, 2017, 9, 1735-44.

304. Koebke, K.; Yu, F.; Salerno, E.; Van Stappen, C.; Tebo, A.G.; Penner-Hahn, J.E.; Pecoraro, V.L.

“Modifying the Sterics In the Second Coordination Sphere of Designed Peptides Leads to

Enhancement of Nitrite Reductase Actvity,” Angew. Chem., 2018, 57, 3954-.

305. Tebo, A.G.; Pinter, T.; Garcia-Serres, R.; Speelman, A.L.; Tard, C.; Sénéque, O.; Blondin, G.;

LaTour, J.-M.; Penner-Hahn, J.E.; Lehnert, N.; Pecoraro, V.L. “Development of a rubredoxin-

type center embedded in a de novo designed three helix bundle“ Biochemistry, 2018, 57,

2308-2316.

306. Koebke, K.; Pecoraro, V.L. “Development of de Novo Copper Nitrite Reductases: Where We

Are and Where We Need To Go,” ACS Catal., 2018, 8, pp 8046–8057.

307. Lutter, J. C.; Eliseeva, S.V.; Kampf, J.W.; Petoud, S.; Pecoraro, V.L. “The

Ln(III)[3.3.1]Metallacryptate Exhibits Slow Magnetic Relaxation and Vis/NIR Luminescence”

Chem Eur. J., 2018, 24, 10773-10783. May 16. doi: 10.1002/chem.201801355.

308. Koebke, K.; Ruckthong, L.; Meagher, J.; Matthieu, E.; Harland, J.; Deb, A.; Lehnert, N.; Policar, C.;

Tard, C.; Penner-Hahn, J.E.; Stucky, J.; Pecoraro, V.L. “Clarifying the Copper Coordination

Environment in a de Novo Designed Red Copper Protein” Inorg. Chem. 2018, 57, 12291–

12302.

309. Marzaroli, V.; Spigolon, G.; Lococciolo, G.; Quaretti, M.; Salviati, C.; Kampf, J.W.; Licini, G.;

Marchiò, L.; Pecoraro, V.L.; Tegoni, M. “Three-dimensional porous architectures based on

MnII/III three-blades paddlewheel metallacryptates” ACS Crystal Growth and Design, in press.

310. Lutter, J.C.; Lopez-Bermudez, B.A.; Nguyen, T.N.; Kampf, J.W.; Pecoraro, V.L. “Functionalization

of Luminescent Lanthanide-Gallium Metallacrowns using Copper-Catalyzed Alkyne-Azide

Cycloaddition and Thiol-Maleimide Michael Addition” J. Inorg. Biochem., 2019, 192,119-125.

311. Ruckthong, L.; Stuckey, J.A.; Pecoraro, V.L. “How Outer Coordination Sphere Modifications

Can Impact Metal Structures in Proteins: A Crystallographic Analysis” Chem. Eur J.

312. Tolbert, A.; Mocny, C.S.; Ruckthong, L.; Neupane, K.S.; Stuckey, J.A.; Prabhakar, R.; Pecoraro,

V.L. “Metal Dependent Assembly of Heterotrimeric Three Stranded Coiled Coils” submitted

to Nature: Chemistry.

313. Lutter, J.C.; Eliseeva, S.V.; Collet, G.; Martinić, I.; Kampf, J.W.; Carichner, A.; Sobilo, J.;

Lerondel, S.; Petoud, S.; Pecoraro, V.L. “Iodinated bis[Yb(III) (12-MC-4)] Complexes:

Toward Bimodal Near Infrared and X-Ray Contrast Imaging Agents” submitted to J. Amer.

Chem. Soc.

314. Koebke, K.; Pecoraro, V.L. “Non-coded Amino Acids in de novo Metalloprotein Design:

Controlling Coordination Number and Catalysis” submitted to Accts. Chem. Resch.

315. Koebke, K.; Yu, F.; Van Stappen, C.; Pinter, T.B.J; Deb, A.; Penner-Hahn, J.E.; Pecoraro,

V.L. “Methylated Histidines Alter Tautomeric Preferences that Influence the Rates of Copper

Nitrite Reductase Catalysis in Designed Proteins” submitted J. Amer. Chem. Soc.

Patents

Application Number: PCT/US2014/054335

Publication Date: 12.03.2015 International Filling Date: 05.09.2014

Metallacrown complexes and methods of making the same

Inventors: Evan R. Trivedi, Vincent L. Pecoraro, Svetlana V. Eliseeva, Stephane Petoud, Joseph

Jankolovits, Alexandra Foucault-Collet, Ivana Martinic

Centre National De La Recherche Scientifique


Application Number PCT/EP2016/058587

Publication Date: 20.10.2016 International Filling Date: 18.04.2016

Ln(III) And Ga(III) Metallacrown Complexes

Evan R. Trivedi, Vincent L. Pecoraro, Svetlana V. Eliseeva, Stephane Petoud, Chun Y. Chow, Tu Ngoc

Nguyen, Jacob Charles Lutter, Ivana Martinic



Application Number: PCT/EP2016/069296

Publication Date: 23.02.2017 International Filing Date: 12.08.2016

Selective Near-Infrared Optical Imaging of Necrotic Cells And Simultaneous Cell Fixing And Counter

Staining with Metallacrown Complexes

Evan R. Trivedi, Vincent L. Pecoraro, Svetlana V. Eliseeva, Stephane Petoud, Chun Y. Chow, Tu Ngoc

Nguyen, Jacob Charles Lutter, Ivana Martinic



http://www.freshpatents.com/Evan-R-Trivedi-Farmington-Hills-invdxt.php

http://www.freshpatents.com/Vincent-L-Pecoraro-Ann-Arbor-invdxp.php

http://www.freshpatents.com/Svetlana-V-Eliseeva-Orleans-invdxe.php

http://www.freshpatents.com/Stephane-Petoud-Paris-invdxp.php

http://www.freshpatents.com/Joseph-Jankolovits-Oakland-invdxj.php

http://www.freshpatents.com/Joseph-Jankolovits-Oakland-invdxj.php

http://www.freshpatents.com/Alexandra-Foucaultcollet-San-Diego-invdxf.php

http://www.freshpatents.com/Ivana-Martinic-Orleans-invdxm.php









Books

1. Manganese Redox Enzymes, V.L. Pecoraro, ed., Verlag-Chemie, New York, 1992.

2. Mechanistic Bioinorganic Chemistry, H.H. Thorp and V.L. Pecoraro, eds., Advances in Chemistry Series

246, ACS Books, Washington. D.C., 1995.

3. Comprehensive Inorganic Chemistry, Bioinorganic Chemistry, Volume ed, Elsevier, 2012.

4. Methods in Enzymology “Peptide, Protein and Enzyme Design”, Vol. 580, Elsevier, 2016.

5. Metals in Biology and Medicine, Valensin, G.; Pecoraro, V.L.; Carver, P.L.; Kozlowski, H., Royal Society

of Chemistry, to be published in 2018.

curriculum vitae vincent l. pecoraro - labic...

Documents