cooperative research centre for coal in sustainable ... · ¾feasibility of pulverised coal...
TRANSCRIPT
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Oxy-fuel combustion in GHG Context – Status of Research, Technology and Assessment
R GuptaCRC for Coal in Sustainable Developement
Uni of Newcastle Australiafor
Advanced Coal WorkshopBrigham Young University, Provo,Utah
15-16th March 2005
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OVERVIEW
Introduction
Laboratory investigations
Pilot scale studies
Economic assessments
Australian scene
Summary & technical challenges
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Technologies for capture of CO2
A concentrated stream of CO2 is needed for sequestration. Three ways to to produce sequestration ready stream:
Post-combustion capture - CO2 capture using MEA type solvents
IGCC - Carbon is removal before combustion
Oxy-Fuel – using oxygen for the combustion
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General flow sheet for oxy-fuel with (RFG)
Driver 1, sequestration ready CO2
Driver 2, reduced gas clean up costs,compared to air firing
Driver 3, reduced NOxemissions, compared to air firing
Furnace Heat Extraction
Gas Cleanup
Coal + O2
Hot RFG Cold RFG
Stack
Compression / Sequestration
CO2
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Issues in Oxy-Firing
Combustion IssuesKinetics
Ash related issuesAsh formation and deposits
Pollutant issuesSOx, NOx, Hg, Fine particles
Heat transfer issuesFlame emissivity
Technology issuesASU, Economic feasibility, Retrofit
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Laboratory Scale Tests
The following investigations were done in different laboratory studies:
Effect of lower diffusivity on flame speed was demonstrated in micro-gravity testsThe mechanisms of reduced NOx in oxy-RFG were investigated by Char oxidation has been investigated in oxygen enriched environment.Desulphurisation was found to improve in oxy-RFG caseChar reactivity has been investigated in different environments – Particle temp was found to be slightly lower in CO2 environmentTrace elements behaviour was investigated by thermodynamic equilibrium calcs.
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Pilot Scale Studies
•Argonne National Laboratory•IFRF•IHI/CCUJ•CANMET •Air Liquide
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Argonne National Lab/EERC - 1988
The earliest study of coal oxy-fuel combustion in a pilot-scale furnace was carried out by EERC for ANL in their 3 MWt pilot facility to test performance
Summary
Recycle ratios estimated: For a wet recycle ratio of 0.76 and for a dry recycle 0.73 matched the overall heat transfer performance
Oxy-fuel combustion had a similar in-furnace gas temperature profile as the normal air-fired combustion.
It was found that oxy-fuel combustion had lower NOx (50%) and SOxemissions, and a high carbon burnout compared to air firing.
Conclusion “Oxy-Firing may be applied successfully as a retrofit to a wide range of utility boiler and furnace systems”
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IFRF Study 1993-95IFRF…..Recycled flue gas (RFG) demonstration with primary
consideration to retrofitting an existing pf boiler. 2.5 MW (2mX2mX6.2m)
Summary
Similar to those from ANL/EERC tests
Lower NOx, SOx, Technical feasibility
Recycle ratio depended on coal used
Air leakage resulted in max CO2 concentration to 91%
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IHI Study - 1995
IHI…..Recycled flue gas (RFG) demonstration in 1.2 MWt(1.3mX7.5m) test furnace with primary consideration to reduce NOX and SOX pf boiler. SOx FGD better.
SOXNOX
Almost 99% CO2 was recovered from Flue gas
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CANMET Study 1999IFRF…..Recycled flue gas (RFG) demonstration with primary
consideration to retrofitting an existing pf boiler. 0.3 MW (0.6mX6.7m)
Summary
Technical feasibility, low NOx, low SOx,
Investigated the effect of oxygen purity recycle and different oxygen concentration in burner
Decrease in SOx by higher retention in ash
Slight increase in N2 (>3%) increased NOx emissions
Wet and dry recycle
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Air Liquide Study - 2002
Objective mainly multi-pollutant control, including staged combustion in 1.5MWt. For retrofitting existing pf boiler
100
47
31
63
29 24
0
20
40
60
80
100
120
Air-case Oxy-case1 Oxy-case2
Unstaged Staged US regulation
100
78
120
52
0
20
40
60
80
100
120
140
Air-case Oxy-case1
Unstaged Staged
(a) NOx emissions, normalised assuming the baseline value in air-case is 100. Dash line is US regulation 65 mg/MJ
(b) Unburnt carbon in ash, normalised assuming the baseline value in air-case is 100.
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Conclusions from Pilot Scale Studies
The pilot-scale studies have demonstrated:
Feasibility of pulverised coal oxy-fuel combustion No major technical barriers in pilot-scale studies. Oxy-fuel combustion technology suitable for retrofit Oxy-fuel combustion achieves clean coal combustion,
lowering NOx, Increasing SOx removalpossibly lower mercury emissions and increased CO2 concentration for sequestration.
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Economic Assessments
•Air Liquide•CANMET•IHI/CCUJ •Vattenfall•CCSD
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Economic Assessments
Technology has been demonstrated only at pilot-scale, not at a practical scale, but demonstrations are planned
Many assessments of practical systems have been made
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Assessment Basis
Comparisons have been made comparing oxy-fuel with alternative technologies, based on
$ / t CO2 avoided, COE, compared with pf, PF SC, USC, IGCC, NGCC etc
Reduction in mass of NOX emissions compared to pf
Reduction of capital and operating cost of gas cleanup compared to pf
In comparing with IGCC, we compare a technology with new process with one not demonstrated at large scale Uses standard unit operations, there are no substantial technical obstacles.
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A1 - Air Liquide/ ICCT
Three cases:Case 1: Retrofit: FGD, SCR,
ESP, Hg
Case 2: Retrofit: FGD, ESP, Hg
Case 3: New (compact design): FGD, ESP, Hg
Economics: Capital + operating cost (operating cost= 0.22 x capital cost)
Balance between ASU cost with reduced cost of back end gas clean up
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A 2 CANMET – 400 MWe retrofit
Considers complete substitution of air by O2/CO2, ie no allowance for dual oxidant option
Supplementary (lost) energy generated from natural gas to maintain original plant output
Oxyfuel, at US$25/ton of CO2 avoided, is ~70% of amine case…… but both are expensive, increasing electricity price by 20-30%.
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A3 - IHI /CCUJ A new plant – 1000MWe
Total costOperatingcost
Fixed cost-5
0
5
10
15 Oxy-Firing systemPCF+amine absorption
Economy (billion yen/year)
PCF(non-CO2recovery)
PCF+amine
absorption
Oxy-Firingsystem
0
10
20
30
40
50
ASU and CO2 comp. powerStation service powerNet thermal efficiency
Thermal Efficiency (%)
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A4 – EU/Vattenfall – Lignite Fired
Energy flow diagram for lignite fired plant with O2/CO2 combustion
Energy input Fuel
2026 MW 100 %
Cooling 1084 MW – 53,5 %
Auxilliaries 45 MW – 2,2 %
Air separation 137 MW - 6,8 %
CO2 compression 71 MW - 3,5 %
Net electricity output689 MW – 34,0 %
Original electricity output
865 MW – 42,7 %
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Identified Impacts for Retrofit
ASU + CO2 compression reduces overall efficiency by ~ 9%
Reduces sent out electricity by ~ 18 - 20%
Air leakage, for reduced pressure operation, increases impacts
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CO2 avoidance cost, transport and storage excluded
0
5
10
15
20
25
30
35
40
45
O2/CO2 Lippendorf2001
IEA GHG 2000,PC+postcomb
IEA GHG 2003,IGCC+precomb
IEA GHG 2020,IGCC+precomb
IEA GHG 2000,NGCC+postcomb
IEA GHG 2000,IRCC+precomb
EUR/
ton
CO
2
Lignite Hard coal Natural gas
Rate of return: 7%; Depreciation time 25 years; Operational time 7500 h/year
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Assessment 4
Report "Systems assessment of future electricity generation options for Australia“, BHPBilliton Group, November 2003
CCSD Australia Compares technology options for sequestration ready CO2for new plants
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A5 – CCSD Australia new plant - COE
0
10
20
30
40
50
60
70
SC
NGCC
USCO2 U
SC-100%
CCS
DFC-C
C
IGCC
O2-IG
CC-25% M
EA-CCS
O2-IG
CC-75% M
EA-CCS
O2-IG
CC-75% S
X-CCS
Cos
t (A
UD
$/M
Wh)
CO2 disposalCarbon taxOtherFuelCapital service
0
2
4
6
8
10
12
14
16
18
O2-IG
CC-H2
Cos
t (A
UD
$/G
J)
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Cost of CO2 abatement relative to USC
Technology Cost of CO2 abatement ($/t CO2)
IGCC 182
DCF-CCGT 105
IGCC-25% CCS 86
IGCC-75% MEA-CCS 64
O2-USC-100% CCS 29
NGCC 25
USC 9
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Conclusions from assessments
The assessment studies have shown that
CCS (includes pipelining) reduces efficiency by 6-10%, and increase generation costs by around A$20/MWh.
IGCC generation costs, with or without sequestration, are predicted to be significantly higher than most other technology combinations, for carbon taxes below A$50/t CO2.
O2-USC with sequestration gives overall better economics than for IGCC
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Australian Initiatives – Coal21
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Japan-Australia Oxy-Fired PF Feasibility Study - 2004
Retrofit with oxygen plant, CO2 compression and sequestration (including combustion and heat transfer evaluation)
Stage 1 – Detailed engineering feasibility study on the technical requirements and costs to convert an existing PF boiler (Callide A 30 MWe Unit owned by CS Energy) to oxy-firing. Completed Mar 06
Stage 2 – Establishment of an oxy-fired PF demonstration plant capable of producing up to 200,000 tpa of CO2 for sequestration
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Study items for feasibility study
IDFFFBoiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Air
IDFFFBoiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Air
IDFFFBoiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Air
IDFFFBoiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Air
IDFFFBoiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Air
Boiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Boiler
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
WB
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
AH
Coal Bunker
Mill
GMF
O2Pre-
heater
ASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
AH
Coal Bunker
Mill
Coal Bunker
Coal Bunker
Mill
GMF
O2Pre-
heater
ASUASU CO2recovery
unit
High performancedust removal
①
②
Further study:① Additional cooling equipment② Matching with CO2 recovery unit③ Heat/Mass balance
Air
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Fundamental Research at University of Newcastle
•Heat transfer – radiative
•Combustion –burnout and excess air
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Radiative Heat TransferCase-I: Air-Firing
15% (CO2 + H2O)
Furnace wall
Dust burden = 5 g/m3
Case-II: Oxy-Firing
90% (CO2 + H2O)
Furnace wall
Dust burden = 5 -15 g/m3
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3-gray gas model Article: T.F.Smith et al (1982)
[ ]PSkI
ii
ieTa −
=
−= ∑ 1)(0
,εε
Total emissivity of gray gases:
1
1,,,
−
=∑= j
J
jjii Tba εε
Optimized values for:
i = 3 (no. of gray gases)
j = 4 (polynomial order)Where,
[ ] ithPSk ktcoefficienabsorptionwithemissivitygasgrayie i ,1 =− −
gasabsorbingofLengthPathpressurePartialPS )*(=
factorsweightingemissivitygasgrayia thi =,ε
tscoefficienpolynomialetemperaturgasemissivityb ji =,,ε
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WBM Vs WSGGM Model for BL @ 1600 °C
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Absorption Spectra
CH4s
N2O
O2 and O3
CO2
H2O
Atmosphere
From Fleagle and Businger (1980), An Introduction to Atmospheric Physics
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Experiments: Astro DTF
drop tube furnace
pulverized coal
filter
Burn coal in varying oxygen concentrations in DTF at 1400 °C,
Measure carbon burnout from combustion residue to determine reactivity (conversion)
cyclone
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Devolatilisation CRC 272 SEM
Combustion in 4.6% O2 in CO2,
76.2% carbon in sample
Combustion in 3% O2 in N2
82.8% carbon in sample
High VM (35%)Coal
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Devolatilisation CRC 299 SEM
Char formed in CO2 Char formed in N2
Low VM (24%)Coal
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Experimental Results for Combustion
Conversion of Fixed CarbonCRC 272, zeropoint determined by V*
0
20
40
60
80
100
0 10 20 30 40
O2 Concentration (%)
Bur
nout
(%)
N2CO2
Conversion of Fixed CarbonCRC 299, Zeropoint determined by V*
0.010.020.030.040.050.060.070.080.090.0
100.0
0 5 10 15 20 25 30 35
Oxygen %C
onve
rsio
n (%
)
N2CO2
CRC 272 CRC 299
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Future Challanges
Technological developments needed in
New Boilers - less or nil recycleAir Separation – new technology – scale upCO2 – clean-up – tolerance for SOx, NOx – removal of SCR
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Challenge 1: Boiler design
Design of next generation oxyfuel boiler, combustion considerations
Reduced recycle rate or complete removal of recycle
Optimisation of combustion for reduced formation of NOx, to eliminate catalytic reactors
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Challenge 2: O2 Production
At present cryogenic air separation only technology for large scale oxygen production; issues:
Scale-up
Optimal integration in power plant
Oxygen purity optimisation: where to remove the non-condensables?
Emerging technologies?
High temperature oxygen separation with ceramic materials, e.g. oxygen transfer membranes: Scale-up and cost? Integration into power plant
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Challenge 3: CO2 Processing
NOx control needed?
Flue gas desulphurisation needed?
Flue gas condensing
Design of CO2 compression train depending on CO2 impurity level:
Dehydration &Removal of non-condensableRequirements on CO2 purity from transport, storage environmental perspective is generally unexploredBehaviour of CO2 with impurities at high pressures (supercritical) is not well known (solubility etc.)
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SUMMARY
All pilot scale tests demonstrate technical feasibility
All assessment studies demonstrate economic feasibility
Fundamental research in radiative transfer and combustion kinetics in new environment
Technological innovations needed in new boiler design, large scale ASU or Chemical Looping and compression of CO2 with some level of impurities
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Acknowledgements
Project supported by CCSD
UN: Terry Wall, Raj Gupta, Bart Buhre, Liza Elliott, Sameer Khare
CSIRO: Lou Wibberley
IHI, Tokyo: Keiji Makino, Takashi Kiga, Yamada
Australian generators: Chris Spero (CS Energy), Howard Morrison (Tarong), Peter Coombes (Delta), Andy Wearmouth (Western Power)