conforms to ansi z400.1-2004 standard (united states,...
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Brite WashMaterial Safety Data Sheet
Product and company identification1 .Common name Brite Wash
Mild soap.SupplierMaterial uses
ManufacturerIn case of emergency :
:
::
:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
No known significant effects or critical hazards.
Irritating to eyes.
May be harmful if swallowed.
No known significant effects or critical hazards.EyesSkinInhalationIngestion
Physical state Liquid. (Clear.)
See toxicological information (section 11)
:
:
::::
Medical conditionsaggravated by over-exposure
Repeated or prolonged exposure is not known to aggravate any medical condition.:
Odor : Bouquet.
2 .
Emergency overview : WARNING !CAUSES EYE IRRITATION.MAY BE HARMFUL IF SWALLOWED.Do not ingest. Avoid contact with skin and clothing. Wash thoroughly after handling.
Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
:Potential chronic healtheffects
Color : Gold.Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.
Date of issue : 10/30/2006 Page: 1/6
Brite Wash
Composition/information on ingredients
Sodium Dodecylbenzene Sulfonate 25155-30-0 5 - 10
Name CAS number %Canada
Mexico
Name CAS number %Sodium DodecylbenzeneSulfonate
Notregulated.
- 1 0 0 25155-30-0 5 - 10
IDLH H F R SpecialClassification
UN number
3 .
%Name CAS numberUnited States
Sodium Dodecylbenzene Sulfonate 25155-30-0 5 - 10
First aid measures4 .Eye contact
Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.
Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
Wash with soap and water. Get medical attention if symptoms occur.
Non-flammable.
Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting measuresFlammability of the productExtinguishing media
No specific hazard.Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
5 .
None known.Suitable :Not suitable :
Use suitable protective equipment.
For small spills, add absorbent (soil may be used in the absence of other suitablematerials), scoop up material and place in a sealable, liquid-proof container for disposal.For large spills, dike spilled material or otherwise contain material to ensure runoff doesnot reach a waterway. Place spilled material in an appropriate container for disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Date of issue : 10/30/2006 Page: 2/6
Brite Wash
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly afterhandling.
Handling and storageHandling
Storage
:
:
7 .
Exposure controls/personal protection
Personal protection
Consult local authorities for acceptable exposure limits.
8 .
Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol airborne levels.
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
HMIS Code/Personalprotective equipment
: A
No special protective clothing is required.
Not required under normal conditions of uses.Not required under normal conditions of uses.
Safety glasses.
Eyes
:
SkinRespiratory
:::
Hands
100°C (212°F)
Liquid. (Clear.)
12.8 [Basic.]
May start to solidify at 0°C (32°F) based on data for: Water.1.06 (Water = 1)
The highest known value is 0.62 (Air = 1) (Water).The highest known value is 2.3 kPa (17.5 mm Hg) (at 20°C) (Water).
Bouquet.Gold.
Boiling/condensation pointMelting/freezing point
0.36 (Water) compared with Butyl acetate.
Physical and chemical propertiesPhysical state
pH
Relative densityVapor pressureVapor densityEvaporation rate
OdorColor
::::::::::
9 .
Easily soluble in cold water, hot water, methanol, acetone.Solubility :
The product is stable.Reactive with oxidizing materials and acids.
Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
None known.Conditions of reactivity :
Date of issue : 10/30/2006 Page: 3/6
Brite Wash
Toxicological informationToxicity data
Product/ingredient name Test Result Route SpeciesSodium Dodecylbenzene Sulfonate LD50
LD50438 mg/kg1330 mg/kg
OralOral
RatMouse
11 .
Eyes : Irritating to eyes.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : May be harmful if swallowed.
Acute Effects
Potential chronic healtheffects
: Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
These products are carbon oxides and water, sulfur oxides. Some metallic oxides.The products of degradation are less toxic than the product itself.
Ecological information
Toxicity of the products ofbiodegradation
Products of degradation
Ecotoxicity dataSpecies Period ResultProduct/ingredient name
Sodium Dodecylbenzene Sulfonate Daphnia magna (EC50)Lepomis macrochirus (LC50)Oncorhynchus mykiss (LC50)Lepomis macrochirus (LC50)
48 hour(s)96 hour(s)96 hour(s)96 hour(s)
5.88 mg/l1.18 mg/l1.68 mg/l6.5 mg/l
::
Environmental precautions : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .
IATA :DOT/ TDGIMDG/ Not regulated.
NAERG : Not applicable.Regulatory information
UN/
Regulatory information
Clean Water Act (CWA) 307: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Sodium Dodecylbenzene SulfonateSARA 311/312 MSDS distribution - chemical inventory - hazard identification: SodiumDodecylbenzene Sulfonate: Immediate (acute) health hazard
United States
15 .
HCS ClassificationTSCA : All components listed.Irritating material
U.S. Federal regulations ::
Date of issue : 10/30/2006 Page: 4/6
Brite Wash
Clean Water Act (CWA) 311: Sodium Dodecylbenzene SulfonateClean Air Act (CAA) 112 accidental release prevention: No products were found.Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
International lists :
Canada
Mexico
01 0Health
FlammabilityReactivity
Special
Classification :
WHMIS (Canada) Class D-2B: Material causing other toxic effects (Toxic).:
DSL : All components listed.
Pennsylvania RTK: Sodium Dodecylbenzene Sulfonate: (environmental hazard, genericenvironmental hazard); Diethanolamine: (environmental hazard, generic environmentalhazard)Massachusetts RTK: Sodium Dodecylbenzene Sulfonate; DiethanolamineNew Jersey: Sodium Dodecylbenzene Sulfonate; DiethanolamineCalifornia prop. 65: No products were found.
HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
State regulations :
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Other information
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
CAUSES EYE IRRITATION.MAY BE HARMFUL IF SWALLOWED.
Label requirements (U.S.A.) :
:
:
16 .
00
1
HMIS RATING
Physical Hazard
Health 1
0Fire hazard
Personal protection A0
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 10/30/2006 Page: 5/6
Brite Wash
ReferencesReferences
Date of issueVersion :
:
:
10/30/20061
: ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
Date of issue : 10/30/2006 Page: 6/6
Buff MagicMaterial Safety Data Sheet
Product and company identification1 .Common name
Rubbing compound for fiberglass and metal polish.SupplierMaterial uses
ManufacturerIn case of emergency :
:
::
:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Buff Magic
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.EyesSkinInhalationIngestion
Physical state Solid. (Paste.)
See toxicological information (section 11)
:
:
::::
Odor : Ammoniacal. (Slight.)
Hazard status :
2 .
Emergency overview : No specific hazard.USE WITH CARE.Follow good industrial hygiene practice.
Potential chronic healtheffects
Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light].Mutagenic effects: Not available.Teratogenic effects: Not available.
:
Color : White or a pale pink in color.This material is classified as not hazardous under OSHA regulations in the United States,the WHMIS in Canada and the NOM-018-STPS-2000 in Mexico.
Composition/information on ingredients
Distillates (Petroleum), Hydrotreated Light 64742-47-8 10 - 30
Name CAS number %Canada
3 .
%Name CAS numberUnited States
Distillates (Petroleum), Hydrotreated Light 64742-47-8 10 - 30
Date of issue : 10/30/2006 Page: 1/6
Buff Magic
Mexico
Name CAS number %Distillates (Petroleum),Hydrotreated Light
Notregulated.
- 0 1 0 64742-47-8 10 - 30
IDLH H F R SpecialClassification
UN number
First aid measures4 .Eye contact
Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.
Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
Wash with soap and water. Get medical attention if symptoms occur.
May be combustible at high temperature.
Use dry chemical powder.
Fire-fighting measuresFlammability of the productExtinguishing media
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
5 .
Do not use water jet.Suitable :Not suitable :
Immediately contact emergency personnel. Eliminate all ignition sources. Keepunnecessary personnel away. Use suitable protective equipment. Do not touch or walkthrough spilled material.
If emergency personnel are unavailable, carefully scoop up spilled materials and use anon-sparking or explosion-proof means to transfer material to an appropriate container fordisposal by incineration. Avoid creating dusty conditions and prevent wind dispersal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Keep container in a cool, well-ventilated area. Keep container tightly closed and sealeduntil ready for use. Avoid all possible sources of ignition (spark or flame).
Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources.
Handling and storageHandlingStorage
::
7 .
Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.
Exposure controls/personal protection
Product name Exposure limitsUnited States
8 .
Date of issue : 10/30/2006 Page: 2/6
Buff Magic
Personal protection
Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.
Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.
Canada
Mexico
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits. The engineering controls also need to keep gas, vapor or dust concentrationsbelow any lower explosive limits. Use explosion-proof ventilation equipment.
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.
Product name Exposure limits
Product name Exposure limits
Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
HMIS Code/Personalprotective equipment
: A
A respirator is not needed under normal and intended conditions of use.Lab coat.
Disposable vinyl gloves.
Safety glasses.
Eyes
:
SkinRespiratory
:::
Hands
Solid. (Paste.)
8.5 (Conc. (% w/w): 1) [Basic.]1.09 (Water = 1)
Ammoniacal. (Slight.)White or a pale pink in color.
>1 compared with Butyl acetate.
Physical and chemical propertiesPhysical state
pHRelative densityEvaporation rate
OdorColor
:
:::::
Flash point : Closed cup: 104.44°C (220°F). (Setaflash.)
9 .
Very slightly soluble in cold water, hot water.Solubility :
Date of issue : 10/30/2006 Page: 3/6
Buff Magic
The product is stable.Reactive with oxidizing materials.
Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
Flammable in the presence of the following materials or conditions: open flames, sparksand static discharge.Slightly flammable in the presence of the following materials or conditions: heat.
Conditions of reactivity :
Toxicological information11 .
Eyes : No known significant effects or critical hazards.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : No known significant effects or critical hazards.
Acute Effects
Potential chronic healtheffects
: Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light].Mutagenic effects: Not available.Teratogenic effects: Not available.
Not available.
Ecological information
Products of degradation
Ecotoxicity data Species Period ResultProduct/ingredient name
Distillates (Petroleum), Hydrotreated Light Oncorhynchus mykiss (LC50 96 hour(s) 2.9 mg/l
:Environmental precautions : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .
IATA :DOT/ TDGIMDG/ Not regulated.
Regulatory informationUN/
Date of issue : 10/30/2006 Page: 4/6
Buff Magic
Regulatory information
Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: AmmoniaClean Air Act (CAA) 112 accidental release prevention: No products were found.Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
International lists
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Distillates (Petroleum), Hydrotreated LightSARA 311/312 MSDS distribution - chemical inventory - hazard identification: Distillates(Petroleum), Hydrotreated Light: Delayed (chronic) health hazard
:
Canada
United States
Mexico
15 .
10 0Health
FlammabilityReactivity
Special
Classification :
HCS Classification Not regulated.TSCA : All components listed.U.S. Federal regulations :
:
WHMIS (Canada) Not regulated.:DSL : All components listed.
Not available.California prop. 65: No products were found.
HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
State regulations :
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Other information
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
USE WITH CARE.Label requirements (U.S.A.) :
:
:
16 .
01
0
HMIS RATING
Physical Hazard
Health 0
1Fire hazard
Personal protection A0
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 10/30/2006 Page: 5/6
Buff Magic
ReferencesReferences
Date of issueVersion :
:
:
10/30/20061
: ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
Date of issue : 10/30/2006 Page: 6/6
Pro PolishMaterial Safety Data Sheet
Product and company identification1 .Common name Pro Polish
Pro Polish is a fiberglass/gel coat cleaner, sealant/polish with UV inhibitors .SupplierMaterial uses
ManufacturerIn case of emergency :
:
::
:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
Irritating to respiratory system.
Severely irritating to eyes.
No known significant effects or critical hazards.
Irritating to skin.EyesSkinInhalationIngestion
Physical state Liquid.
See toxicological information (section 11)
:
:
::::
Medical conditionsaggravated by over-exposure
Repeated skin exposure can produce local skin destruction or dermatitis. Repeated orprolonged contact with spray or mist may produce chronic eye irritation and severe skinirritation.
:
2 .
Emergency overview : WARNING !CAUSES SEVERE EYE IRRITATION.CAUSES RESPIRATORY TRACT AND SKIN IRRITATION.Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep containerclosed. Use only with adequate ventilation. Wash thoroughly after handling.
Potential chronic healtheffects
Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light]. Classified None. by NIOSH [Diethanolamine]. Classified3 (Not classifiable for humans.) by IARC [Diethanolamine]. Classified None. by OSHA[Isopropyl alcohol]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3(Not classifiable for humans.) by IARC [Isopropyl alcohol]. Classified None. by OSHA,None. by NIOSH [Methanol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.
:
Hazard status : This material is classified hazardous under OSHA regulations in the United States, theWHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.
Date of issue : 10/30/2006 Page: 1/8
Pro Polish
Composition/information on ingredients
Solvent naphtha (petroleum), heavy aliphatic 64742-96-7 5 - 10Solvent naphtha (petroleum), medium aliphatic 64742-88-7 5 - 10Distillates (Petroleum), Hydrotreated Light 64742-47-8 1 - 51-Tetradecene 1120-36-1 1 - 5Diethanolamine 111-42-2 1 - 5Methanol 67-56-1 0.1 - 0.5
Name CAS number %Canada
Mexico
Name CAS number %Solvent naphtha (petroleum),heavy aliphatic
Notregulated.
- 1 2 0 64742-96-7 5 - 10
Solvent naphtha (petroleum),medium aliphatic
UN1223 - 1 1 0 64742-88-7 5 - 10
1-Tetradecene Notregulated.
- 2 1 0 1120-36-1 1 - 5
Diethanolamine Notregulated.
- 1 1 0 111-42-2 1 - 5
Distillates (Petroleum),Hydrotreated Light
Notregulated.
- 0 1 0 64742-47-8 1 - 5
IDLH H F R SpecialClassification
UN number
3 .
%Name CAS numberUnited States
Solvent naphtha (petroleum), heavy aliphatic 64742-96-7 5 - 10Solvent naphtha (petroleum), medium aliphatic 64742-88-7 5 - 10Distillates (Petroleum), Hydrotreated Light 64742-47-8 1 - 51-Tetradecene 1120-36-1 1 - 5Diethanolamine 111-42-2 1 - 5
First aid measures4 .Eye contact
Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.
Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
Wash with soap and water. Get medical attention if symptoms occur.
CombustibleThese products are carbon oxides, nitrogen oxides. Some metallic oxides.
Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting measuresFlammability of the productProducts of combustionExtinguishing media
::
5 .
None known.Suitable :Not suitable :
Date of issue : 10/30/2006 Page: 2/8
Pro Polish
Combustible liquid and vapor. Vapor may cause flash fire. Vapors may accumulate inlow or confined areas or travel a considerable distance to a source of ignition and flashback. Runoff to sewer may create fire or explosion hazard.
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
Immediately contact emergency personnel. Keep unnecessary personnel away. Usesuitable protective equipment.
If emergency personnel are unavailable, contain spilled material. For small spills, addabsorbent (soil may be used in the absence of other suitable materials), scoop upmaterial and place in a sealable, liquid-proof container for disposal. For large spills, dikespilled material or otherwise contain material to ensure runoff does not reach a waterway.Place spilled material in an appropriate container for disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Avoid contact with eyes, skin and clothing. Keep container closed. Use only withadequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling.
Handling and storageHandling
Storage
:
:
7 .
Solvent naphtha (petroleum), heavy aliphatic ACGIH TLV (United States). TWA: 10 mg/m3 8 hour(s).
Solvent naphtha (petroleum), medium aliphatic Manufacturer (United States). TWA: 100 ppm 8 hour(s). Form: All forms.
Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.
Diethanolamine ACGIH TLV (United States, 1/2005). Skin TWA: 2 mg/m3 8 hour(s). Form: All forms. TWA: 0.46 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). TWA: 15 mg/m3 10 hour(s). Form: All forms. TWA: 3 ppm 10 hour(s). Form: All forms.OSHA PEL 1989 (United States, 3/1989). TWA: 15 mg/m3 8 hour(s). Form: All forms. TWA: 3 ppm 8 hour(s). Form: All forms.
Exposure controls/personal protection
Product name Exposure limits
Solvent naphtha (petroleum), heavy aliphatic ACGIH TLV (United States). TWA: 10 mg/m3 8 hour(s).
Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.
Diethanolamine ACGIH TLV (United States, 1/2005). Skin TWA: 2 mg/m3 8 hour(s). Form: All forms. TWA: 0.46 ppm 8 hour(s). Form: All forms.
Methanol ACGIH TLV (United States, 1/2005). Skin STEL: 328 mg/m3 15 minute(s). Form: All forms. STEL: 250 ppm 15 minute(s). Form: All forms. TWA: 262 mg/m3 8 hour(s). Form: All forms.
United States
Canada
8 .
Product name Exposure limits
Date of issue : 10/30/2006 Page: 3/8
Pro Polish
Personal protection
TWA: 200 ppm 8 hour(s). Form: All forms.
Solvent naphtha (petroleum), heavy aliphatic ACGIH TLV (United States). TWA: 10 mg/m3 8 hour(s).
Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.
Diethanolamine ACGIH TLV (United States, 1/2005). Skin TWA: 2 mg/m3 8 hour(s). Form: All forms. TWA: 0.46 ppm 8 hour(s). Form: All forms.
Mexico
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits.
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.
Product name Exposure limits
Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
HMIS Code/Personalprotective equipment
: B
Natural rubber (latex).A respirator is not needed under normal and intended conditions of use.Lab coat.Safety glasses.
Eyes
:
SkinRespiratory
:::
Hands
Weighted average: 129.57°C (265.2°F)
Liquid.
Basic.
Weighted average: -2.27°C (27.9°F)1.09 (Water = 1)
Weighted average: 1.54 (Air = 1)Weighted average: 1.96 kPa (14.7 mm Hg) (at 20°C)
Boiling/condensation pointMelting/freezing point
>1 compared with Water = 1Kinematic (40C): The highest known value is 1 to 2 cSt (Solvent naphtha (petroleum),medium aliphatic)
Physical and chemical propertiesPhysical state
pH
Relative densityVapor pressureVapor densityEvaporation rateViscosity
:
::::::::
Flash point : Closed cup: 104.44°C (220°F). (Setaflash.)The lowest known value is 229°C (444.2°F) (Solvent naphtha (petroleum), mediumaliphatic).
:Auto-ignition temperature
Flammable limits : The greatest known range is Lower: 1% Upper: 6% (Solvent naphtha (petroleum),medium aliphatic)
9 .
Easily soluble in methanol, acetone.Partially soluble in cold water, hot water.
Solubility :
Date of issue : 10/30/2006 Page: 4/8
Pro Polish
The product is stable.Reactive with oxidizing materials and acids.
Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
Flammable in the presence of the following materials or conditions: open flames, sparksand static discharge.Slightly flammable in the presence of the following materials or conditions: heat.
Conditions of reactivity :
Toxicological informationToxicity data
Product/ingredient name Test Result Route SpeciesSolvent naphtha (petroleum), mediumaliphatic
LD50LD50
>5000 mg/kg>2000 mg/kg
OralDermal
RatRabbit
Diethanolamine LD50LD50LD50
2200 mg/kg3300 mg/kg12200 mg/kg
OralOralDermal
RabbitMouseRabbit
11 .
Eyes : Severely irritating to eyes.Skin : Irritating to skin.Inhalation : Irritating to respiratory system.Ingestion : No known significant effects or critical hazards.
Acute Effects
Potential chronic healtheffects
: Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light]. Classified None. by NIOSH [Diethanolamine]. Classified3 (Not classifiable for humans.) by IARC [Diethanolamine]. Classified None. by OSHA[Isopropyl alcohol]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3(Not classifiable for humans.) by IARC [Isopropyl alcohol]. Classified None. by OSHA,None. by NIOSH [Methanol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.
These products are carbon oxides and waterThe product itself and its products of degradation are not toxic.
Ecological information
Toxicity of the products ofbiodegradation
Products of degradation
Ecotoxicity dataSpecies Period ResultProduct/ingredient name
Distillates (Petroleum), Hydrotreated Light Oncorhynchus mykiss (LC50) 96 hour(s) 2.9 mg/lDiethanolamine Pimephales promelas (LC50)
Daphnia magna (LC50)Pimephales promelas (LC50)Daphnia magna (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)
96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)
100 mg/l100 mg/l>100 mg/l>100 mg/l1370 mg/l1480 mg/l
::
Environmental precautions : No known significant effects or critical hazards.
12 .
Date of issue : 10/30/2006 Page: 5/8
Pro Polish
The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .
IATA :DOT/ TDGIMDG/ Not regulated.
Regulatory informationUN/
Regulatory information
Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean Air Act (CAA) 112 accidental release prevention: MethanolClean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Diethanolamine; Isopar MSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Diethanolamine: Immediate (acute) health hazard; Isopar M: Delayed (chronic) healthhazard
SARA 313
Canada
United States
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
Silica crystalline, quartz Yes. No. No. No.
Ingredient name Cancer Reproductive No significant risklevel
Maximumacceptable dosagelevel
15 .
Diethanolamine 111-42-2 1 - 5
Diethanolamine 111-42-2 1 - 5
Form R - ReportingrequirementsSupplier notification
:
:
HCS Classification Irritating materialU.S. Federal regulations TSCA 8(a) PAIR: Decamethylcyclopentasiloxane; Trade secret
TSCA 8(b) inventory: All components listed.::
Rhode Island RTK hazardous substances: MethanolPennsylvania RTK: Diethanolamine: (environmental hazard, generic environmentalhazard); Methanol: (environmental hazard, generic environmental hazard); Silicacrystalline, quartz: (generic environmental hazard); Isopropyl alcohol: (environmentalhazard, generic environmental hazard)Florida: MethanolMinnesota: MethanolMassachusetts RTK: Diethanolamine; Methanol; Silica crystalline, quartz; IsopropylalcoholNew Jersey: Diethanolamine; Methanol; Silica crystalline, quartz; Isopropyl alcoholNew Jersey spill list: MethanolWARNING: This product contains a chemical known to the State of California to causecancer.
State regulations :
Date of issue : 10/30/2006 Page: 6/8
Pro Polish
International lists :
Mexico
11 0Health
FlammabilityReactivity
Special
Classification :
WHMIS (Canada)
CEPA DSL: All components listed.
CEPA NDSL: C10-16 Alkenes
Canadian NPRI: Methanol
Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).
:
HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Other information
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
CAUSES SEVERE EYE IRRITATION.CAUSES RESPIRATORY TRACT AND SKIN IRRITATION.
Label requirements (U.S.A.) :
:
:
16 .
01
1
ReferencesReferences
Date of issueVersion :
:
:
10/30/20061
:
HMIS RATING
Physical Hazard
Health 1
1Fire hazard
Personal protection B0
ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 10/30/2006 Page: 7/8
Pro Polish
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
Date of issue : 10/30/2006 Page: 8/8
Serious ShineMaterial Safety Data Sheet
Product and company identification1 .Common name Serious Shine
Cleaner and polish for fiberglass, glass, mirror, and most painted and solid surfaces.SupplierMaterial uses
ManufacturerIn case of emergency :
:
::
:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
Irritating to respiratory system.
Irritating to eyes.
No known significant effects or critical hazards.
Irritating to skin.EyesSkinInhalationIngestion
Physical state Liquid. (Aerosol.)
See toxicological information (section 11)
:
:
::::
Medical conditionsaggravated by over-exposure
Repeated skin exposure can produce local skin destruction or dermatitis. Repeated orprolonged contact with spray or mist may produce chronic eye irritation and severe skinirritation. Repeated or prolonged exposure to the substance can produce target organdamage.
:
Odor : Petroleum. (Slight.)
2 .
Emergency overview : WARNING !CONTENTS UNDER PRESSURE.CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.CONTAINS MATERIAL WHICH CAUSES DAMAGE TO TARGET ORGANS.Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep away fromheat, sparks and flame. Do not puncture or incinerate container. Keep container closed.Use only with adequate ventilation. Wash thoroughly after handling.
Potential chronic healtheffects
Carcinogenic effects: Classified None. by OSHA [Isopropyl alcohol]. Classified A4 (Notclassifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC[Isopropyl alcohol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.
:
Hazard status : This material is classified hazardous under OSHA regulations in the United States, theWHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.
Date of issue : 10/30/2006 Page: 1/8
Serious Shine
Composition/information on ingredients
Stoddard Solvent 8052-41-3 5 - 10Propane 74-98-6 5 - 10Isopropyl alcohol 67-63-0 1 - 5n-Butane 106-97-8 1 - 5
Name CAS number %Canada
Mexico
Name CAS number %Stoddard Solvent UN1268 20000 mg/m3 1 2 0 8052-41-3 5 - 10Propane UN1978 2100 ppm 1 4 0 74-98-6 5 - 10Isopropyl alcohol UN1219 2000 ppm 1 2 0 67-63-0 1 - 5n-Butane UN1011 - 0 4 0 106-97-8 1 - 5
IDLH H F R SpecialClassification
UN number
3 .
%Name CAS numberUnited States
Stoddard Solvent 8052-41-3 5 - 10Propane 74-98-6 5 - 10Isopropyl alcohol 67-63-0 1 - 5n-Butane 106-97-8 1 - 5
First aid measures4 .Eye contact
Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.
Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
Wash with soap and water. Get medical attention if symptoms occur.
Non-flammable.These products are carbon oxides.
Use dry chemical, carbon dioxide, water spray (fog) or foam.
Fire-fighting measuresFlammability of the productProducts of combustionExtinguishing media
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
::
:
5 .
Do not use water jet.Suitable :Not suitable :
Date of issue : 10/30/2006 Page: 2/8
Serious Shine
Immediately contact emergency personnel. Eliminate all ignition sources. Keepunnecessary personnel away. Use suitable protective equipment. Do not touch or walkthrough spilled material.
If emergency personnel are unavailable, contain spilled material. For small spills, addabsorbent (soil may be used in the absence of other suitable materials) and use a non-sparking or explosion-proof means to transfer material to a sealable, appropriatecontainer for disposal. For large spills, dike spilled material or otherwise contain materialto ensure runoff does not reach a waterway. Place spilled material in an appropriatecontainer for disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Store in a segregated and approved area. Keep container in a cool, well-ventilated area.Keep container tightly closed and sealed until ready for use. Avoid all possible sources ofignition (spark or flame).
Avoid contact with eyes, skin and clothing. Keep container closed. Use only withadequate ventilation. Avoid breathing vapor or mist. Keep away from heat, sparks andflame. To avoid fire or explosion, dissipate static electricity during transfer by groundingand bonding containers and equipment before transferring material. Do not puncture orincinerate container. Wash thoroughly after handling.
Handling and storageHandling
Storage
:
:
7 .
Stoddard Solvent ACGIH TLV (United States, 1/2005). TWA: 525 mg/m3 8 hour(s). Form: All forms. TWA: 100 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). CEIL: 1800 mg/m3 15 minute(s). Form: All forms. TWA: 350 mg/m3 10 hour(s). Form: All forms.OSHA PEL (United States, 8/1997). TWA: 2900 mg/m3 8 hour(s). Form: All forms. TWA: 500 ppm 8 hour(s). Form: All forms.
Propane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). TWA: 1800 mg/m3 10 hour(s). Form: All forms. TWA: 1000 ppm 10 hour(s). Form: All forms.OSHA PEL (United States, 8/1997). TWA: 1800 mg/m3 8 hour(s). Form: All forms. TWA: 1000 ppm 8 hour(s). Form: All forms.
Isopropyl alcohol ACGIH TLV (United States, 1/2005). STEL: 400 ppm 15 minute(s). Form: All forms. TWA: 200 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). STEL: 1225 mg/m3 15 minute(s). Form: All forms. STEL: 500 ppm 15 minute(s). Form: All forms. TWA: 980 mg/m3 10 hour(s). Form: All forms. TWA: 400 ppm 10 hour(s). Form: All forms.OSHA PEL (United States, 8/1997). TWA: 980 mg/m3 8 hour(s). Form: All forms. TWA: 400 ppm 8 hour(s). Form: All forms.
n-Butane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.
Exposure controls/personal protection
Product name Exposure limitsUnited States
8 .
Date of issue : 10/30/2006 Page: 3/8
Serious Shine
NIOSH REL (United States, 12/2001). TWA: 1900 mg/m3 10 hour(s). Form: All forms. TWA: 800 ppm 10 hour(s). Form: All forms.OSHA PEL 1989 (United States, 3/1989). TWA: 1900 mg/m3 8 hour(s). Form: All forms
Personal protection
Stoddard Solvent ACGIH TLV (United States, 1/2005). TWA: 525 mg/m3 8 hour(s). Form: All forms. TWA: 100 ppm 8 hour(s). Form: All forms.
Propane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.
Isopropyl alcohol ACGIH TLV (United States, 1/2005). STEL: 400 ppm 15 minute(s). Form: All forms. TWA: 200 ppm 8 hour(s). Form: All forms.
n-Butane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms
Stoddard Solvent NOM-010-STPS (Mexico, 9/2000). CCT: 1050 mg/m3 15 minute(s). Form: All forms. CCT: 200 ppm 15 minute(s). Form: All forms. CPT: 523 mg/m3 8 hour(s). Form: All forms. CPT: 100 ppm 8 hour(s). Form: All forms.
Propane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.Simple asphyxiant.
Isopropyl alcohol NOM-010-STPS (Mexico, 9/2000). Skin CCT: 1225 mg/m3 15 minute(s). Form: All forms. CCT: 500 ppm 15 minute(s). Form: All forms. CPT: 980 mg/m3 8 hour(s). Form: All forms. CPT: 400 ppm 8 hour(s). Form: All forms.
n-Butane NOM-010-STPS (Mexico, 9/2000). CPT: 1900 mg/m3 8 hour(s). Form: All forms CPT: 800 ppm 8 hour(s). Form: All forms
Canada
Mexico
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits. The engineering controls also need to keep gas, vapor or dust concentrationsbelow any lower explosive limits. Use explosion-proof ventilation equipment.
Product name Exposure limits
Product name Exposure limits
HMIS Code/Personalprotective equipment
: B
Natural rubber (latex).
Lab coat.A respirator is not needed under normal and intended conditions of product use.
Safety glasses.
Eyes
:
SkinRespiratory
:::
Hands
Date of issue : 10/30/2006 Page: 4/8
Serious Shine
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
Weighted average: 105.03°C (221.1°F)
Liquid. (Aerosol.)
95.89% (w/w)
Neutral.
Weighted average: -2.03°C (28.3°F)0.916 (Water = 1)
Weighted average: 0.65 (Air = 1)Weighted average: 2.35 kPa (17.63 mm Hg) (at 20°C)
Petroleum. (Slight.)
Boiling/condensation pointMelting/freezing point
Weighted average: 0.39 compared with Butyl acetate.
Physical and chemical propertiesPhysical state
pH
Relative densityVapor pressureVapor densityVolatilityEvaporation rate
Odor
1795 (g/l).VOC
:
::::::::::
The lowest known value is 232.22°C (450°F) (Stoddard Solvent).:Auto-ignition temperature
9 .
Miscible in water.Solubility :
The product is stable.Reactive with oxidizing materials and acids.
Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
May be combustible at high temperature.Conditions of reactivity :
Toxicological informationToxicity data
Product/ingredient name Test Result Route SpeciesIsopropyl alcohol LD50
LD50LD50LD50LC50
5045 mg/kg6410 mg/kg3600 mg/kg12800 mg/kg16000 ppm (8 hour(s))
OralOralOralDermalInhalation
RatRabbitMouseRabbitRat
n-Butane LC50 658 mg/l (4 hour(s)) Inhalation Rat
11 .
Eyes : Irritating to eyes.Skin : Irritating to skin.Inhalation : Irritating to respiratory system.Ingestion : No known significant effects or critical hazards.
Acute Effects
Potential chronic healtheffects
: Carcinogenic effects: Classified None. by OSHA [Isopropyl alcohol]. Classified A4 (Notclassifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC[Isopropyl alcohol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.
Target organs : Contains material which causes damage to the following organs: kidneys, the nervoussystem, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
Date of issue : 10/30/2006 Page: 5/8
Serious Shine
These products are carbon oxides and water.The product itself and its products of degradation are not toxic.
Ecological information
Toxicity of the products ofbiodegradation
Products of degradation
Ecotoxicity dataSpecies Period ResultProduct/ingredient name
Isopropyl alcohol Pimephales promelas (EC50)Lepomis macrochirus (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)
48 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)
10000 mg/l>1400 mg/l6550 mg/l9640 mg/l10400 mg/l11130 mg/l
::
Environmental precautions : No known significant effects or critical hazards.
12 .
Do not puncture or incinerate container. Disposal of this product, solutions and anyby-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional and local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .NAERG : 126Regulatoryinformation
-
DOT Classification
TDG Classification 2.2
2
ORM-D -
UN1950AEROSOLS -
UN numberProper shipping name Class PG Label
-
UN / IMDG / IATAClassification
UN1950AEROSOLS 2.2 -
2
-
Additionalinformation
UN DOT TDGIMDGForbidden
IATA-
Regulatory information
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Stoddard Solvent; Propane; Isopropylalcohol; n-ButaneSARA 311/312 MSDS distribution - chemical inventory - hazard identification: StoddardSolvent: Fire hazard, Immediate (acute) health hazard; Propane: Fire hazard, Suddenrelease of pressure; Isopropyl alcohol: Fire hazard, Immediate (acute) health hazard,Delayed (chronic) health hazard; n-Butane: Fire hazard, Sudden release of pressure
United States
15 .
HCS Classification
TSCA : All components listed.
Compressed gasIrritating materialTarget organ effects
U.S. Federal regulations :
:
Date of issue : 10/30/2006 Page: 6/8
Serious Shine
Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean Air Act (CAA) 112 accidental release prevention: Propane; n-ButaneClean Air Act (CAA) 112 regulated flammable substances: Propane; n-ButaneClean Air Act (CAA) 112 regulated toxic substances: No products were found.
International lists :
SARA 313
Canada
Mexico
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
11 0Health
FlammabilityReactivity
Special
Classification :
Isopropyl alcohol 67-63-0 1 - 5
Isopropyl alcohol 67-63-0 1 - 5
Form R - ReportingrequirementsSupplier notification
:
:
WHMIS (Canada) Class A: Compressed gas.Class D-2B: Material causing other toxic effects (Toxic).
:
DSL : All components listed.
Pennsylvania RTK: Stoddard Solvent: (generic environmental hazard); Propane: (genericenvironmental hazard); Isopropyl alcohol: (environmental hazard, generic environmentalhazard); n-Butane: (generic environmental hazard)Massachusetts RTK: Stoddard Solvent; Propane; Isopropyl alcohol; n-ButaneNew Jersey: Stoddard Solvent; Propane; Isopropyl alcohol; n-ButaneCalifornia prop. 65: No products were found.
HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
State regulations :
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Other informationCONTENTS UNDER PRESSURE.CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.CONTAINS MATERIAL WHICH CAUSES DAMAGE TO TARGET ORGANS.
Label requirements (U.S.A.) :
16 .
Date of issue : 10/30/2006 Page: 7/8
Serious Shine
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
:
:
01
1
ReferencesReferences
Date of issueVersion :
:
:
10/30/20061
:
HMIS RATING
Physical Hazard
Health * 1
1Fire hazard
Personal protection B0
ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 10/30/2006 Page: 8/8
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
Material Safety Data Sheet
Product and company identification1 .Common name
Serious Marine Cleaner is a concentrate that has been designed to clean a multitude ofsurfaces including fiberglass, vinyl, carpet, rubber, teak and acrylic canvas.
Supplier
Material uses
ManufacturerIn case of emergency :
:
:
:
:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Serious Marine Cleaner (SMC) Concentrate
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
Corrosive to the respiratory system.
Corrosive to eyes.
May be harmful if swallowed. May cause burns to mouth, throat and stomach.
Corrosive to the skin. May cause sensitization by skin contact.EyesSkinInhalationIngestion
Physical state Liquid.
See toxicological information (section 11)
:
:
::::
Medical conditionsaggravated by over-exposure
Repeated skin exposure can produce local skin destruction or dermatitis. Repeated orprolonged exposure to the substance can produce lung damage. Repeated or prolongedcontact with spray or mist may produce chronic eye irritation and severe skin irritation.
:
Odor : Citrus.
2 .
Emergency overview : DANGER !CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.MAY CAUSE ALLERGIC SKIN REACTION.MAY BE HARMFUL IF SWALLOWED.
When used, in diluted water solution, this product is non-hazardous.Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Keepcontainer closed. Use only with adequate ventilation. Wash thoroughly after handling.
Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
:Potential chronic healtheffects
Color : Blue-Green.Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 in Mexico.
Date of issue : 10/30/2006 Page: 1/7
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
Composition/information on ingredients
Ethylene oxide-nonylphenol polymer 9016-45-9 1 - 53-Butoxypropan-2-ol 5131-66-8 1 - 5Tetrasodium EDTA 64-02-8 1 - 5Sodium hydroxide 1310-73-2 1 - 5Sodium Silicate 1344-09-8 1 - 5
Name CAS number %Canada
Mexico
Name CAS number %3-Butoxypropan-2-ol Not
regulated.- 2 2 0 5131-66-8 1 - 5
Ethylene oxide-nonylphenolpolymer
Notregulated.
- 1 1 0 9016-45-9 1 - 5
Sodium Xylene Sulfonate Notregulated.
- 1 0 0 1330-72-7 1 - 5
Tetrasodium EDTA Notregulated.
- 1 0 0 64-02-8 1 - 5
Sodium Silicate Notregulated.
- 1 0 0 1344-09-8 1 - 5
Sodium hydroxide UN1823 10 mg/m3 3 0 0 1310-73-2 1 - 5
IDLH H F R SpecialClassification
UN number
3 .
%Name CAS numberUnited States
Sodium Xylene Sulfonate 1330-72-7 1 - 5Ethylene oxide-nonylphenol polymer 9016-45-9 1 - 53-Butoxypropan-2-ol 5131-66-8 1 - 5Tetrasodium EDTA 64-02-8 1 - 5Sodium hydroxide 1310-73-2 1 - 5Sodium Silicate 1344-09-8 1 - 5
First aid measures4 .Eye contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 20 minutes. Get medical attention immediately.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical attention immediately.Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention immediately.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Getmedical attention immediately.
Date of issue : 10/30/2006 Page: 2/7
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
Non-flammable.
Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting measuresFlammability of the productExtinguishing media
No specific hazard.Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
5 .
None known.Suitable :Not suitable :
Immediately contact emergency personnel. Keep unnecessary personnel away. Usesuitable protective equipment.
If emergency personnel are unavailable, contain spilled material. For small spills, addabsorbent (soil may be used in the absence of other suitable materials), scoop upmaterial and place in a sealable, liquid-proof container for disposal. For large spills, dikespilled material or otherwise contain material to ensure runoff does not reach a waterway.Place spilled material in an appropriate container for disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use onlywith adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handlin
Handling and storageHandling
Storage
:
:
7 .
Sodium hydroxide ACGIH TLV (United States, 1/2005). CEIL: 2 mg/m3 Form: All forms.NIOSH REL (United States, 12/2001). CEIL: 2 mg/m3 Form: All forms.OSHA PEL (United States, 8/1997). TWA: 2 mg/m3 8 hour(s). Form: All forms.
Exposure controls/personal protection
Product name Exposure limits
Sodium hydroxide CSST (Canada, 2001). TWA: 2 mg/m3 8 hour(s).
Sodium hydroxide NOM-010-STPS (Mexico, 9/2000). LMPE-P: 2 mg/m3 Form: All forms
United States
Canada
Mexico
8 .
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits.
Product name Exposure limits
Product name Exposure limits
Date of issue : 10/30/2006 Page: 3/7
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
Personal protection
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
HMIS Code/Personalprotective equipment
: J
Synthetic apron.
Nitrile gloves.Vapor respirator.
Splash goggles.
Eyes
:
SkinRespiratory
:::
Hands
100°C (212°F)
Liquid.
12.8 [Basic.]
Weighted average: -5.93°C (21.3°F)1.07 (Water = 1)
Weighted average: 0.87 (Air = 1)Weighted average: 2.17 kPa (16.28 mm Hg) (at 20°C)
Citrus.Blue-Green.
Boiling/condensation pointMelting/freezing point
<1 (Ethylene oxide-nonylphenol polymer) compared with Ether (anhydrous).
Physical and chemical propertiesPhysical state
pH
Relative densityVapor pressureVapor densityEvaporation rate
OdorColor
::::::::::
9 .
Easily soluble in cold water, hot water, methanol, acetone.Solubility :
The product is stable.Highly reactive or incompatible with the following materials: acids and moisture.Reactive with oxidizing materials.Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
None known.Conditions of reactivity :
Toxicological informationToxicity data
Product/ingredient name Test Result Route SpeciesEthylene oxide-nonylphenol polymer LD50 1310 mg/kg Oral Rat3-Butoxypropan-2-ol LD50
LD503300 mg/kg3100 mg/kg
OralDermal
RatRabbit
Sodium Silicate LD50LD50
1960 mg/kg>4640 mg/kg
OralDermal
RatRabbit
11 .
Eyes : Corrosive to eyes.Acute Effects
Date of issue : 10/30/2006 Page: 4/7
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
Skin : Corrosive to the skin. May cause sensitization by skin contact.Inhalation : Corrosive to the respiratory system.Ingestion : May be harmful if swallowed. May cause burns to mouth, throat and stomach.
Potential chronic healtheffects
: Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
These products are carbon oxides and water, nitrogen oxides. Some metallic oxides.The products of degradation are less toxic than the product itself.
Ecological information
Toxicity of the products ofbiodegradation
Products of degradation
Ecotoxicity dataSpecies Period ResultProduct/ingredient name
Ethylene oxide-nonylphenol polymer Lepomis macrochirus (LC50)Oncorhynchus mykiss (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)
96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)
1.3 mg/l4.7 mg/l7.6 mg/l7.9 mg/l>10 mg/l>1000 mg/l
Tetrasodium EDTA Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)
96 hour(s)96 hour(s)96 hour(s)96 hour(s)
486 mg/l1030 mg/l2070 mg/l3092 mg/l
::
Environmental precautions : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .NAERG : 153Regulatoryinformation
8
8
CORROSIVE
DOT Classification
TDG Classification 8
8
CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. (Sodium hydroxide)
III
UN3267CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. (Sodium hydroxide)
III
UN numberProper shipping name Class PG Label
UN3267
UN / IMDG / IATAClassification
UN3267CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. (Sodium hydroxide)
8 III
8
Date of issue : 10/30/2006 Page: 5/7
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
EXEMPTED:For container of 1 gallon
or less.
EXEMPTED:For container of 1 gallon
or less.
EXEMPTED:For container of 1 gallon
or less.
Additionalinformation
UN DOT TDGIMDGEXEMPTED:
For container of 1 gallon or ess.
IATAEXEMPTED:
For container of 1 gallonor less.
Regulatory information
Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: Sodium hydroxide; Sodium hydroxide; Formaldehyde;AcetaldehydeClean Air Act (CAA) 112 accidental release prevention: Formaldehyde; AcetaldehydeClean Air Act (CAA) 112 regulated flammable substances: AcetaldehydeClean Air Act (CAA) 112 regulated toxic substances: Formaldehyde
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Tetrasodium EDTA; Sodium hydroxideSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Tetrasodium EDTA: Immediate (acute) health hazard; Sodium hydroxide: Immediate(acute) health hazard
Canada
United States
1,4-Dioxane Yes. No. Yes. No.Acetaldehyde Yes. No. 90 µg/day (inhalation) No.Formaldehyde Yes. No. Yes. No.
Ingredient name Cancer Reproductive No significant risklevel
Maximumacceptable dosagelevel
15 .
HCS Classification Corrosive materialSensitizing materialTarget organ effects
U.S. Federal regulations TSCA 8(a) PAIR: Ethylene oxide-nonylphenol polymer; AcetaldehydeTSCA 8(b) inventory: All components listed.TSCA 8(d) H and S data reporting: 3-Butoxypropan-2-ol: 1994
:
:
WHMIS (Canada) Class D-2B: Material causing other toxic effects (Toxic).Class E: Corrosive material
:
Connecticut carcinogen reporting list.: FormaldehydeRhode Island RTK hazardous substances: FormaldehydePennsylvania RTK: Sodium hydroxide: (environmental hazard, generic environmentalhazard); Sodium hydroxide: (environmental hazard, generic environmental hazard); 1,4-Dioxane: (special hazard, environmental hazard, generic environmental hazard);Formaldehyde: (special hazard, environmental hazard, generic environmental hazard);Acetaldehyde: (environmental hazard, generic environmental hazard)Florida: FormaldehydeMinnesota: FormaldehydeMichigan critical material: FormaldehydeMassachusetts RTK: Sodium hydroxide; Glycine, n,n-bis(carboxymethyl)-, trisodium salt;Sodium hydroxide; 1,4-Dioxane; Formaldehyde; AcetaldehydeNew Jersey: Sodium hydroxide; Sodium hydroxide; 1,4-Dioxane; Formaldehyde;AcetaldehydeLouisiana RTK reporting list: FormaldehydeWARNING: This product contains a chemical known to the State of California to causecancer.
State regulations :
Date of issue : 10/30/2006 Page: 6/7
Serious Marine Cleaner (SMC) Concentrate
Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.
International lists :
Mexico
03 0Health
FlammabilityReactivity
Special
Classification :
CEPA DSL: All components listed.
CEPA NDSL: Glycine, n,n'-1,2-ethanediylbis-, disodium salt
HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Other information
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.MAY CAUSE ALLERGIC SKIN REACTION.MAY BE HARMFUL IF SWALLOWED.
When used, in diluted water solution, this product is non-hazardous.
Label requirements (U.S.A.) :
:
:
16 .
00
3
ReferencesReferences
Date of issueVersion :
:
:
10/30/20061
:
HMIS RATING
Physical Hazard
Health 3
0Fire hazard
Personal protection J0
ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 10/30/2006 Page: 7/7
Serious Marine Cleaner (SMC)Material Safety Data Sheet
Product and company identification1 .Common name Serious Marine Cleaner (SMC)
Serious Marine Cleaner is a concentrate that has been designed to clean a multitude ofsurfaces including fiberglass, vinyl, carpet, rubber, teak and acrylic canvas.
Supplier
Material uses
ManufacturerIn case of emergency :
:
:
:
:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
No known significant effects or critical hazards.
Moderately irritating to eyes.
May be harmful if swallowed.
No known significant effects or critical hazards.EyesSkinInhalationIngestion
Physical state Liquid.
See toxicological information (section 11)
:
:
::::
Medical conditionsaggravated by over-exposure
Repeated or prolonged exposure is not known to aggravate any medical condition.:
Odor : Citrus.
2 .
Emergency overview : WARNING!MAY BE HARMFUL IF SWALLOWED.Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use onlywith adequate ventilation. Wash thoroughly after handling
Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
:Potential chronic healtheffects
Color : Blue-Green.Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.
Date of issue : 10/30/2006 Page: 1/6
Serious Marine Cleaner (SMC)
Composition/information on ingredients
Ethylene oxide-nonylphenol polymer 9016-45-9 0.5 - 13-Butoxypropan-2-ol 5131-66-8 0.5 - 1
Name CAS number %Canada
Mexico
Name CAS number %3-Butoxypropan-2-ol Not
regulated.- 2 2 0 5131-66-8 0.5 - 1
Ethylene oxide-nonylphenolpolymer
Notregulated.
- 1 1 0 9016-45-9 0.5 - 1
Sodium Xylene Sulfonate Notregulated.
- 1 0 0 1330-72-7 0.5 - 1
IDLH H F R SpecialClassification
UN number
3 .
%Name CAS numberUnited States
Sodium Xylene Sulfonate 1330-72-7 0.5 - 1Ethylene oxide-nonylphenol polymer 9016-45-9 0.5 - 13-Butoxypropan-2-ol 5131-66-8 0.5 - 1
First aid measures4 .Eye contact
Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.
Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
Wash with soap and water. Get medical attention if symptoms occur.
Non-flammable.
Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting measuresFlammability of the productExtinguishing media
No specific hazard.Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
5 .
None known.Suitable :Not suitable :
Use suitable protective equipment.
For small spills, add absorbent (soil may be used in the absence of other suitablematerials), scoop up material and place in a sealable, liquid-proof container for disposal.For large spills, dike spilled material or otherwise contain material to ensure runoff doesnot reach a waterway. Place spilled material in an appropriate container for disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Date of issue : 10/30/2006 Page: 2/6
Serious Marine Cleaner (SMC)
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use onlywith adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handlin
Handling and storageHandling
Storage
:
:
7 .
Exposure controls/personal protection
Personal protection
Consult local authorities for acceptable exposure limits.
8 .
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits.
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
HMIS Code/Personalprotective equipment
: B
Natural rubber (latex).A respirator is not needed under normal and intended conditions of use.Lab coat.Safety glasses.
Eyes
:
SkinRespiratory
:::
Hands
100°C (212°F)
Liquid.
<11 [Basic.]
Weighted average: -5.93°C (21.3°F)1.07 (Water = 1)
Weighted average: 0.87 (Air = 1)Weighted average: 2.17 kPa (16.28 mm Hg) (at 20°C)
Citrus.Blue-Green.
Boiling/condensation pointMelting/freezing point
<1 (Ethylene oxide-nonylphenol polymer) compared with Ether (anhydrous).
Physical and chemical propertiesPhysical state
pH
Relative densityVapor pressureVapor densityEvaporation rate
OdorColor
::::::::::
9 .
Miscible in water.Solubility :
The product is stable.Reactive with oxidizing materials.
Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
None known.Conditions of reactivity :
Date of issue : 10/30/2006 Page: 3/6
Serious Marine Cleaner (SMC)
Toxicological informationToxicity data
Product/ingredient name Test Result Route SpeciesEthylene oxide-nonylphenol polymer LD50 1310 mg/kg Oral Rat3-Butoxypropan-2-ol LD50
LD503300 mg/kg3100 mg/kg
OralDermal
RatRabbit
11 .
Eyes : Moderately irritating to eyes.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : May be harmful if swallowed.
Acute Effects
Potential chronic healtheffects
: Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
These products are carbon oxides and water.The products of degradation are less toxic than the product itself.
Ecological information
Toxicity of the products ofbiodegradation
Products of degradation
Ecotoxicity dataSpecies Period ResultProduct/ingredient name
Ethylene oxide-nonylphenol polymer Lepomis macrochirus (LC50)Oncorhynchus mykiss (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)
96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)
1.3 mg/l4.7 mg/l7.6 mg/l7.9 mg/l>10 mg/l>1000 mg/l
::
Environmental precautions : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .
IATA :DOT/ TDGIMDG/ Not regulated.
NAERG : Not applicable.Regulatory information
UN/
Date of issue : 10/30/2006 Page: 4/6
Serious Marine Cleaner (SMC)
Regulatory information
Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: Sodium hydroxide; Sodium hydroxide; Formaldehyde;AcetaldehydeClean Air Act (CAA) 112 accidental release prevention: Formaldehyde; AcetaldehydeClean Air Act (CAA) 112 regulated flammable substances: AcetaldehydeClean Air Act (CAA) 112 regulated toxic substances: Formaldehyde
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: No products were found.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No productswere found.
Canada
United States
1,4-Dioxane Yes. No. Yes. No.Acetaldehyde Yes. No. 90 µg/day (inhalation) No.Formaldehyde Yes. No. Yes. No.
Ingredient name Cancer Reproductive No significant risklevel
Maximumacceptable dosagelevel
15 .
HCS Classification Non hazardous.U.S. Federal regulations TSCA 8(a) PAIR: Ethylene oxide-nonylphenol polymer; Acetaldehyde
TSCA 8(b) inventory: All components listed.TSCA 8(d) H and S data reporting: 3-Butoxypropan-2-ol: 1994
::
WHMIS (Canada)CEPA DSL: All components listed.
CEPA NDSL: Glycine, n,n'-1,2-ethanediylbis-, disodium salt
Not controlled under WHMIS (Canada).:
Connecticut carcinogen reporting list.: FormaldehydeRhode Island RTK hazardous substances: FormaldehydePennsylvania RTK: Sodium hydroxide: (environmental hazard, generic environmentalhazard); Sodium hydroxide: (environmental hazard, generic environmental hazard); 1,4-Dioxane: (special hazard, environmental hazard, generic environmental hazard);Formaldehyde: (special hazard, environmental hazard, generic environmental hazard);Acetaldehyde: (environmental hazard, generic environmental hazard)Florida: FormaldehydeMinnesota: FormaldehydeMichigan critical material: FormaldehydeMassachusetts RTK: Sodium hydroxide; Glycine, n,n-bis(carboxymethyl)-, trisodium salt;Sodium hydroxide; 1,4-Dioxane; Formaldehyde; AcetaldehydeNew Jersey: Sodium hydroxide; Sodium hydroxide; 1,4-Dioxane; Formaldehyde;AcetaldehydeLouisiana RTK reporting list: FormaldehydeWARNING: This product contains a chemical known to the State of California to causecancer.
State regulations :
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Date of issue : 10/30/2006 Page: 5/6
Serious Marine Cleaner (SMC)
International lists :
Mexico
01 0Health
FlammabilityReactivity
Special
Classification : HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
Other information
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
MAY BE HARMFUL IF SWALLOWED.Label requirements (U.S.A.) :
:
:
16 .
00
1
ReferencesReferences
Date of issueVersion :
:
:
10/30/20061
:
HMIS RATING
Physical Hazard
Health 1
0Fire hazard
Personal protection B0
ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 10/30/2006 Page: 6/6
Snap-StickMaterial Safety Data Sheet
Product and company identification1 .Common name
To lubricate and protect snaps and zippers.SupplierMaterial uses
ManufacturerIn case of emergency :
:
::
:CHEMTREC, U.S. Domestic: (800) 424-9300CHEMTREC, International: (703) 527-3887
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 11/30/2006
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Contact the supplier.
Snap-Stick
Dermal contact. Eye contact. Inhalation. Ingestion.
Hazards identification
Routes of entryPotential acute health effects
No known significant effects or critical hazards.
Slightly irritating to the eyes.
No known significant effects or critical hazards.
No known significant effects or critical hazards.EyesSkinInhalationIngestion
Physical state Solid.
See toxicological information (section 11)
:
:
::::
Medical conditionsaggravated by over-exposure
Repeated exposure of the eyes to a low level of dust can produce eye irritation.:
Odor : Odorless.
Hazard status :
2 .
Emergency overview : No specific hazard.USE WITH CARE.Follow good industrial hygiene practice.
Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
:Potential chronic healtheffects
Color : White.This material is classified as not hazardous under OSHA regulations in the United States,the WHMIS in Canada and the NOM-018-STPS-2000 in Mexico.
Composition/information on ingredients
Mineral Oil 8042-47-5 5 - 10
Name CAS number %Canada
3 .
%Name CAS numberUnited States
Mineral Oil 8042-47-5 5 - 10
Date of issue : 11/30/2006 Page: 1/5
Snap-Stick
Mexico
Name CAS number %Mineral Oil Not
regulated.- 0 1 0 8042-47-5 5 - 10
IDLH H F R SpecialClassification
UN number
First aid measures4 .Eye contact
Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.
Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.
Skin contact
Inhalation
Ingestion
Notes to physician
:
:
:
:
: No specific antidote. Medical staff must contact Poison Control Center.
Wash with soap and water. Get medical attention if symptoms occur.
May be combustible at high temperature.
Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting measuresFlammability of the productExtinguishing media
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
5 .
None known.Suitable :Not suitable :
Immediately contact emergency personnel. Keep unnecessary personnel away. Usesuitable protective equipment.
If emergency personnel are unavailable, vacuum or carefully scoop up spilled materialand place in an appropriate container for disposal by incineration. Avoid creating dustyconditions and prevent wind dispersal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.
Personal precautions :
Methods for cleaning up :
6 .
Keep container tightly closed. Keep container in a cool, well-ventilated area.Wash thoroughly after handling.
Handling and storageHandlingStorage
::
7 .
Mineral Oil ACGIH TLV (United States). STEL: 10 mg/m3 15 minute(s). Form: Mist TLV: 5 mg/m3 Form: Mist
Exposure controls/personal protection
Product name Exposure limitsUnited States
8 .
Date of issue : 11/30/2006 Page: 2/5
Snap-Stick
Personal protection
Mineral Oil ACGIH TLV (Canada). STEL: 10 mg/m3 15 minute(s). Form: Mist TLV: 5 mg/m3 Form: Mist
Mineral Oil ACGIH TLV (United States). STEL: 10 mg/m3 15 minute(s). Form: Mist TLV: 5 mg/m3 Form: Mist
Canada
Mexico
Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol airborne levels. If this product contains ingredients with exposure limits, useprocess enclosures, local exhaust ventilation or other engineering controls to keep workerexposure below any recommended or statutory limits.
Hygiene measures :
Personal protection in caseof a large spill
: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.
Product name Exposure limits
Product name Exposure limits
Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.
HMIS Code/Personalprotective equipment
: A
A respirator is not needed under normal and intended conditions of use.Lab coat.
Disposable vinyl gloves.
Safety glasses.
Eyes
:
SkinRespiratory
:::
Hands
Solid.
40 to 50°C (104 to 122°F)Weighted average: 0.83 (Water = 1)
The highest known value is >1 (Air = 1) (Paraffin wax).The highest known value is <1e-005 kPa (<0.0001 mm Hg) (at 20°C) (Paraffin wax).
Odorless.White.
Melting/freezing point
<1 (Paraffin wax) compared with Ether (anhydrous).
Physical and chemical propertiesPhysical state
Relative densityVapor pressureVapor density
Evaporation rate
OdorColor
:
::::::
:
Flash point : The lowest known value is Closed cup: 232°C (449.6°F). (Paraffin wax)
9 .
Insoluble in cold water, hot water.Solubility :
Date of issue : 11/30/2006 Page: 3/5
Snap-Stick
The product is stable.Reactive with oxidizing materials.
Will not occur.
Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization
::
:
10 .
Not available.Conditions of reactivity :
Toxicological information11 .
Eyes : Slightly irritating to the eyes.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : No known significant effects or critical hazards.
Acute Effects
Potential chronic healtheffects
: Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.
Not available.
Ecological information
Products of degradation :Environmental precautions : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.
Waste disposal
Disposal considerations:
13 .
Transport information14 .
IATA :DOT/ TDGIMDG/ Not regulated.
Regulatory informationUN/
Regulatory information
Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean Air Act (CAA) 112 accidental release prevention: No products were found.Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: No products were found.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No productswere found.
United States
15 .
HCS Classification Not regulated.TSCA : All components listed.U.S. Federal regulations :
:
Not available.State regulations :
Date of issue : 11/30/2006 Page: 4/5
Snap-Stick
International lists :
Canada
Mexico
00 0Health
FlammabilityReactivity
Special
Classification :
WHMIS (Canada) Not regulated.:DSL : All components listed.
California prop. 65: No products were found.
HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.
Other information
Hazardous MaterialInformation System (U.S.A.)
National Fire ProtectionAssociation (U.S.A.)
HealthSpecial
ReactivityFlammability
USE WITH CARE.Label requirements (U.S.A.) :
:
:
16 .
00
0
ReferencesReferences
Date of issueVersion :
:
:
11/30/20061
:
HMIS RATING
Physical Hazard
Health 0
0Fire hazard
Personal protection A0
ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Date of issue : 11/30/2006 Page: 5/5
Serious Pad Cleaner
Not available.
Solid.
GHS product identifier
Other means of identification
Product type
Emergency telephone number (with hours of operation)
Section 1. Identification:
:
:
:
Supplier's details :
Identified uses
Serious Pad Cleaner
SAFETY DATA SHEETConforms to HazCom 2012/United States
Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]
CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887
Not available.
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 1BSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Classification of the substance or mixture
:
Signal word : Danger
Hazard statements : Causes severe skin burns and eye damage.May cause respiratory irritation.
Hazard pictograms :
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Use only outdoors or in a well-ventilated area. Avoid breathing dust. Wash hands thoroughly after handling.
GHS label elements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Serious Pad Cleaner
Section 2. Hazards identificationResponse : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED:Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or physician.
Storage : Store locked up.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
: None known.
Section 3. Composition/information on ingredients
Sodium carbonate 30 - 60 497-19-8Disodium metasilicate 10 - 30 6834-92-0Trisodium orthophosphate 10 - 30 7601-54-9Benzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts 1 - 5 68081-81-2Alcohols, C9-11, ethoxylated 1 - 5 68439-46-3Undecan-1-ol, ethoxylated 1 - 5 34398-01-1
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of identification
: Not available.
CAS number : Not applicable.
Substance/mixture
Product code : Not available.
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
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Serious Pad Cleaner
Section 4. First aid measures
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes.Chemical burns must be treated promptly by a physician. Wash clothing before reuse.Clean shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : May cause respiratory irritation.
May cause burns to mouth, throat and stomach.:Ingestion
Skin contact : Causes severe burns.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing
Adverse symptoms may include the following:stomach pains
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Serious Pad Cleaner
Section 5. Fire-fighting measures
No special measures are required.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidephosphorus oxidesmetal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Small spill
Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.
:
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Serious Pad Cleaner
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Sodium carbonate OSHA PEL (United States). TWA: 15 mg/m³ 8 hours.
Trisodium orthophosphate AIHA WEEL (United States, 10/2011). STEL: 5 mg/m³ 15 minutes.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Eye/face protection :
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Appropriate engineering controls
: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
5/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com
Serious Pad Cleaner
Section 8. Exposure controls/personal protectionHand protection
Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Solid.
Not available.
Not available.
Not available.
Not available.
Not available.
Citrus.Odor
pH
Orange.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >93.333°C (>200°F)
Not available.
11.9 [Conc. (% w/w): 1%]
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Not available.
Decomposition temperature : Not available.
6/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com
Serious Pad Cleaner
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials: oxidizing materials and acids.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Carcinogenicity
Specific target organ toxicity (single exposure)
Disodium metasilicate Category 3 Not applicable. Respiratory tract irritationTrisodium orthophosphate Category 3 Not applicable. Respiratory tract irritationBenzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts Category 3 Not applicable. Respiratory tract irritation
Name Category Route of exposure
Target organs
Information on toxicological effects
Acute toxicity
Sodium carbonate LD50 Oral Rat 4090 mg/kg -Disodium metasilicate LD50 Oral Rat 1153 mg/kg -Alcohols, C9-11, ethoxylated LD50 Dermal Rabbit >2 g/kg -
LD50 Oral Rat 1378 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Sodium carbonate Eyes - Severe irritant Rabbit - 50 mg -Skin - Mild irritant Rabbit - 24 hours 500 mg -Eyes - Mild irritant Rabbit - 0.5 minutes 100
mg-
Eyes - Moderate irritant Rabbit - 24 hours 100 mg -Disodium metasilicate Skin - Moderate irritant Guinea pig - 24 hours 250 mg -
Skin - Severe irritant Human - 24 hours 250 mg -Skin - Severe irritant Rabbit - 24 hours 250 mg -
Product/ingredient name Result Score Exposure Observation
Sensitization
Species
There is no data available.
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
Aspiration hazard
: Not available.
There is no data available.
There is no data available.
There is no data available.
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Serious Pad Cleaner
Section 11. Toxicological information
Inhalation : May cause respiratory irritation.
May cause burns to mouth, throat and stomach.:Ingestion
Skin contact : Causes severe burns.
Causes serious eye damage.:Eye contact
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing
Adverse symptoms may include the following:stomach pains
Adverse symptoms may include the following:pain or irritationrednessblistering may occur
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 2884.3 mg/kg
Route ATE value
Acute toxicity estimates
Potential acute health effects
Potential immediate effects
: No known significant effects or critical hazards.
Short term exposure
Potential delayed effects : No known significant effects or critical hazards.
Potential immediate effects
: No known significant effects or critical hazards.
Long term exposure
Potential delayed effects : No known significant effects or critical hazards.
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Serious Pad Cleaner
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Toxicity
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Sodium carbonate Acute EC50 242000 µg/l Fresh water Algae - Navicula seminulum 96 hoursAcute LC50 176000 µg/l Fresh water Crustaceans - Amphipoda 48 hoursAcute LC50 265000 µg/l Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 300000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours
Disodium metasilicate Acute EC50 33.53 mg/L Fresh water Crustaceans - Ceriodaphnia dubia -Neonate
48 hours
Acute LC50 2320 ppm Fresh water Fish - Gambusia affinis - Adult 96 hoursChronic NOEC 160 mg/L Fresh water Algae - Pseudokirchneriella subcapitata 72 hours
Trisodium orthophosphate Acute LC50 151 ppm Fresh water Fish - Gambusia affinis - Adult 96 hoursAlcohols, C9-11, ethoxylated Acute EC50 5.36 mg/L Fresh water Crustaceans - Ceriodaphnia dubia -
Neonate48 hours
Acute EC50 2686 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hoursAcute LC50 8500 µg/l Fresh water Fish - Pimephales promelas 96 hours
Undecan-1-ol, ethoxylated Acute EC50 6700 µg/l Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 7100 µg/l Fresh water Fish - Pimephales promelas 96 hours
There is no data available.
There is no data available.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
CORROSIVE SOLID, BASIC,INORGANIC N.O.S. (Disodium metasilicate)
CORROSIVE SOLID, BASIC,INORGANIC N.O.S. (Disodium metasilicate)
CORROSIVE SOLID, BASIC,INORGANIC N.O.S. (Disodium metasilicate)
UN3262UN3262 UN3262
DOT Classification IMDG IATA
UN number
UN proper shipping name
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Serious Pad Cleaner
Section 14. Transport information8
III
8
III
8
III
Reportable quantity25000 lbs / 11350 kgPackage sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity)transportation requirements.
- -
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No. No. No.
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
AERG : 154
Section 15. Regulatory informationU.S. Federal regulations
Clean Water Act (CWA) 311: Trisodium orthophosphate
:
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
: Not listed
Clean Air Act Section 602 Class I Substances
: Not listed
Clean Air Act Section 602 Class II Substances
: Not listed
DEA List I Chemicals (Precursor Chemicals)
: Not listed
DEA List II Chemicals (Essential Chemicals)
: Not listed
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
SARA 311/312
Classification : Immediate (acute) health hazard
Composition/information on ingredients
No products were found.
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Serious Pad Cleaner
Section 15. Regulatory information
None of the components are listed.
No products were found.
Massachusetts :
California Prop. 65
New York : The following components are listed: Trisodium orthophosphate
New Jersey : The following components are listed: Trisodium orthophosphate
Pennsylvania : The following components are listed: Trisodium orthophosphate
State regulations
Sodium carbonate 30 - 60 No. No. No. Yes. No.Disodium metasilicate 10 - 30 No. No. No. Yes. No.Trisodium orthophosphate 10 - 30 No. No. No. Yes. No.Benzenesulfonic acid, mono-C10-16-alkyl derivs.,sodium salts
1 - 5 No. No. No. Yes. No.
Alcohols, C9-11, ethoxylated 1 - 5 No. No. No. Yes. No.Undecan-1-ol, ethoxylated 1 - 5 No. No. No. Yes. No.
Name % Fire hazard
Sudden release of pressure
Reactive Immediate (acute)health hazard
Delayed (chronic)health hazard
Section 16. Other informationHistory
Prepared by :
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
Date of issue mm/dd/yyyy
Version :
:
1
03/15/2014
KMK Regulatory Services Inc.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Revised Section(s) : Not applicable.
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