combustion || spontaneous ignition temperature data

Appendix G: Spontaneous ignitiontemperature data

The greatest compilations of spontaneous ignition (autoignition) temperature arethose of Mullins [AGARDOgraph No. 4 (1955)] and Zabetakis [US Bur, MinesBulletin 627 (1965)]. These data have been collated and are given with permissionin this appendix. The largest compilation is that of Mullins, and consequently hisgeneral format of presenting the data is followed. There have been many methodsof measuring ignition temperatures, and the results from different measurementshave not necessarily been self-consistent. Mullins lists the various results, a refer-ence to the technique used, and the reporting investigators. Since various techniqueshave not been discussed in the text, these references have been omitted from the datawhich are reproduced here, and only the reported ignition temperatures arepresented.

All temperatures are reported in degrees centigrade. The delay period, whereknown, is in milliseconds and follows the temperature in parentheses. If no delaytime appears, then the spontaneous ignition time was either not specifiable, not spec-ified or determined by the manner shown in Figure 1 of Chapter 7, and probably al-ways in excess of 1000 ms. All data are for atmospheric pressure with the exceptionof the vitiated air data for acetylene and hydrogen, which are for 0.9 atm. When therewas a significant difference between the values reported by Mullins and Zabetakis,the values given by Zabetakis were added to the reorganized Mullins compilation.This value is designated by the letter z following the temperature. When the originalMullins listing reported two or more values within 2 degrees of each other, then onlyone value has been presented. If there are large differences between the reportedvalues, the reader is urged to refer to Mullins and Zabetakis for the method and orig-inal source. Additional data are available in the Ignition Handbook by Babrauskas(Fire Science Publishers, Issaquah, WA 2003) and from Kuchta [US Bur. MinesBulletin 680 (1985)].

705

Table G1 Spontaneous Ignition Temperature Data

Fuel Oxygen Air Vitiated Air

Acetal 174 230 768 (20), 957 (1)

Acetaldehyde 140, 159 185, 275, 175z 869 (20), 1088 (1)

Acetanilide 546

Acetic acid 570, 490 599, 550, 566, 465z

Acetic anhydride 361 392, 401

Acetone 568, 485 700, 727, 561, 538, 569, 465z 871 (20), 1046 (1)

Acetone cyanohydrin 688

Acetonitrile 1000 (20), 1059 (10)

Acetonylacetone 493, 340z 816 (20), 996 (1)

Acetophenone 570z

Acetylchloride 390z

Acetylene 296 305, 335 623 (20), 826 (1)

Acetyl oxide (see Acetic anhydride)

Acrolein 278, 235z 712 (10), 859 (1)

Acrylaldehyde (see Acrolein)

Acrylonitrile 460 481

Adipic acid 420z

Aldol 277, 248

Allyl alcohol 348 389 767 (20), 979 (1)

Allylamine 374

Allyl bromide 295

Allyl chloride 404 487, 392

Allyl ether 200 749 (10), 927 (1)

Aminobenzene (see Aniline)

o-Aminodiphenyl 450z

706

AppendixG:Spontaneousignitio

ntemperature

data

2-Aminoethanol (see Monoethanolamine)

Aminoethylethanolamine 369

Ammonia 651

n-Amyl acetate 399, 360z, 378

i-Amyl acetate 379, 360z

n-Amyl alcohol 390, 332 409, 427, 327, 300z 806 (20), 990 (1)

i-Amyl alcohol 518, 343, 353, 350z 818 (20), 1013 (1)

s-Amyl alcohol 343–385

t-Amyl alcohol 437 814 (20), 995 (1)

Amyl benzene 255

n-Amyl chloride 259

t-Amyl chloride 343

n-Amylene 273

n-Amyl ether 170z

i-Amyl ether 428

Amylmethyl ketone 311

Amyl nitrate 195z 524 (20), 798 (1)

Amyl nitrite 210z 496 (20), 910 (1)

i-Amyl nitrite 437 (10), 918 (1)

n-Amyl propionate 380z

Aniline 530 770, 628, 530, 617, 593 (6000) 907 (20), 1065 (2)

o-Anisidine 787 (20), 1039 (1)

Anisole 560 744 (20), 1025 (1)

Anthracene 580 472, 540z

Antifebrin (see Acetanilide)

Banana oil (see i-Amyl acetate)

Benzaldehyde 168 180, 192 744 (20), 936 (1)

Continued


ntemperature

data

707

Table G1 Spontaneous Ignition Temperature Datadcont’d


Benzene 662, 690, 566 740, 656, 580, 645, 592 (42000), 560z 814 (20), 1000 (1)

Benzene carbonal (see Benzaldehyde)

Benzoic acid 475, 556 573

Benzyl acetate 588, 461 767 (20), 1019 (1)

Benzyl alcohol 373 502, 436 807 (20), 1007 (1)

Benzyl benzoate 480z

Benzyl cellosolve (see Ethyleneglycolmonobenzylether)

Benzyl chloride 627, 585z

Benzyl ethanoate (see Benzyl acetate)

Benzylethyl ether 496

Bicyclohexyl 245z

Biphenyl 577 (36000), 540z

2-Biphenylamine 450z

Bromobenzene 688, 565z 858 (20), 1046 (1)

1-Bromobutane (see n-Butyl bromide)

Bromoethane (see Ethyl bromide)

1,3-Butadiene 335 418

n-Butaldehyde (see n-Butyraldehyde)

n-Butane 283 408, 430 (6000), 405z

i-Butane 319 462, 543, 477 (18000)

1,3-Butandiol 395z

2,3-Butanedione (see Diacetyl)

1-Butanol (see n-Butyl alcohol))

2-Butanol (see s-Butyl alcohol)

2-Butanone (see Methylethyl ketone)

708


ntemperature

data

2-Butenal (see Crotonaldehyde)

1-Butene 310z 384

2-Butene 435, 325z

2-Butanol (see s-Butyl alcohol)

2-Butoxyethanol (see Ethylene glycol monobutylether)

n-Butyl acetate 423 793 (20), 1040 (1)

n-Butyl alcohol 385, 328 450, 503, 367, 359 (18000) 809 (20), 993 (1)

i-Butyl alcohol 364 542, 441, 414 794 (20), 1010 (1)

s-Butyl alcohol 377 414, 405z 833 (20), 990 (1)

t-Butyl alcohol 460 478, 483, 480z

n-Butylamine 312

i-Butylamine 374

t-Butylamine 380z

n-Butylbenzene 412, 444 (6000)

i-Butylbenzene 428, 456 (12000)

s-Butylbenzene 443, 420z, 447 (18000)

t-Butylbenzene 448, 477 (72000) 779 (20), 1000 (1)

2-Butylbiphenyl 433 (12000)

n-Butyl bromide 483, 316, 265z

Butyl carbinol (see i-Amyl alcohol)

Butyl carbitol 228

Butyl carbitol acetate 299

Butyl cellosolve (see Ethyleneglycolmonobutyl ether)

n-Butyl chloride 460

a-Butylene (see 1-Butene)

b-Butylene (see 2-Butene)

g-Butylene (see 2-Methylpropene)

Continued


ntemperature

data

709



i-Butylene (see 2-Methylpropene)

b-Butylene glycol 377

n-Butyl ether 194

n-Butyl formate 308 322

Butyl lactate 382

i-Butylmethyl ketone 459

n-Butyl nitrite 400 (4), 490 (1)

Butylphthalate 403 813 (20), 1021 (1)

n-Butyl propionate 426

n-Butylstearate 355z

n-Butyraldehyde 206 408, 230

i-Butyraldehyde 254

n-Butyric acid 552, 450z

Camphor 466

Carbon disulfide 107 149, 120, 125, 90z 610 (20), 842 (1)

Carbon monoxide 588 609, 651 758 (20), 848 (1)

Castor oil 449

Cellosolve (see Ethyleneglycolmonoethyl ether)

Cetane 235

Cetene 748 (20), 1036 (1)

o-Chloroaniline 885 (20), 1084 (2)

m-Chloroaniline 846 (20), 1080 (2)

Chlorobenzene 674, 640z

Chloroethane (see Ethyl chloride)

2-Chloro-2-methyl chloride 318 343

710


ntemperature

data

3-Chloro-(trifluoromethyl) benzene 654

Creosote oil 336

o-Cresol 599

m-Cresol 626 836 (20), 1100 (2)

Crotonaldehyde 232 703 (20), 924 (1)

Cumene 467 (6000), 425z 802 (20), 985 (1)

Pseudo-cumene 770 (20), 1025 (2)

Cyanogen 850

Cyclohexadiene 360

Cyclohexane 325, 296 259, 270 (102000), 245z 798 (20), 980 (1)

Cyclohexanol 350 300z 814 (20), 1030 (1)

Cyclohexanone 550 557, 453 816 (20), 1046 (1)

Cyclohexylamine 293

Cyclohexyl acetate 335z

Cyclohexene 325 781 (20), 972 (1)

Cyclopentadiene 510

Cyclopentane 385 (6000)

Cyclopentanone 540

Cyclopropane 454 498

p-Cymene 466, 494, 445, 435z 807 (20), 1050 (1)

Decahydronaphthalene 280 262, 272 (18000), 250z

trans-Decahydronaphthalene 814 (20), 1002 (1)

Decalin (see Decahydronaphthalene)

n-Decane 202 463, 425, 250, 210z, 232 (54000), 236

1-Decanol 291

1-Decene 244 (78000)

n-Decyl alcohol 793 (20), 960 (1)

Continued


ntemperature

data

711



Diacetone alcohol 603 805 (20), 1065 (1)

Diacetyl 748 (20), 930 (1)

1,2-Diacetylethane (see Acetonylacetone)

Diallyl 330

Diallyl ether (see Allyl ether)

Dibutyl ether (see n-Butyl ether)

Dibutyl phthalate (see Butyl phthalate)

Di-n-butyl tartrate 284

o-Dichlorobenzene 648

1,2-Dichloro-n-butane 250 276

Dichloro-1-(chlorotetrafluoroethyl)-4-(trifluoromethyl) benzene

591

1,2-Dichloroethane (see Ethylene dichloride)

Dichloroethylene 441, 458 738 (20), 1079 (1)

2,20-Dichloroethyl ether 369 766 (20), 953 (1)

Dichloromethane (see Methylene chloride)

1,2-Dichloropropane (see Propylene dichloride)

Dicyclopentadiene 510

Di-n-decyl ether 217

Diesel fuel (41 cetane) 233z




Diethanolamine 662 823 (20), 1000 (2)

1,1-Diethoxyethane (see Acetal)

712


ntemperature

data

Diethylamine 312 754 (20), 977 (1)

Diethylaniline 630z 762 (20), 965 (1)

1,2-Diethylbenzene 404 (6000)

1,3-Diethylbenzene 455 (12000)

1,4-Diethylbenzene 430, 451 (12000)

Diethyl cellosolve (see Ethyleneglycoldiethyl ether)

Dimethyl cyclohexane 240z

1,4-Diethylene dioxide (see Dioxane)

Diethyl ether (see Ethylether)

Diethylene glycol 229

Diethyleneglycolbenzoate-2-ethylhexoate 340

Diethylene oxide (see Dioxane)

Diethylene triamine 399

Diethyl ketone 608, 450z

3,3-Diethylpentane 322, 290z

Diethyl peroxide 189

Diethyl sulfate 436

Dihexyl (see Dodecane)

Di-n-hexyl ether 200

2,20-Dihydroxyethylamine (see Diethanolamine)

Diisobutylenes 470 799 (20), 1064 (1)

Diisooctyladipate 366

Diisopropyl (see 2,3-Dimethylbutane)

Diisopropylbenzene 449

Diisopropyl ether 443, 416, 500 820 (20), 1037 (1)

Dimethylamine 346 402

Dimethylaniline 371 780 (20), 960 (1)

Continued


ntemperature

data

713



2,2-Dimethylbutane 425, 440 (12000)

2,3-Dimethylbutane 298 420, 421 (12000)

2,3-Dimethyl-1-butene 369 (6000)

2,3-Dimethyl-2-butene 407 (6000)

Dimethylchloracetal 232

Dimethyl decalin 235z

2,4-Dimethyl-3-ethylpentane 390 (12000), 510

Dimethyl ether 252 350

trans-Dimethylethylene (see 2-Methyl propene)

Dimethyl formamide 445, 435z

Dimethylglyoxal (see Diacetyl)

3,3-Dimethylheptane 441 (3600)

2,3-Dimethylhexane 438

Dimethylketone (see Acetone)

2,3-Dimethyloctane 231 (72000)

4,5-Dimethyloctane 388

2,3-Dimethylpentane 337, 338 (6000)

o-Dimethylphthalate 556

2,2-Dimethylpropane 450, 456 (3000)

Dimethyl sulfide 206

1,1-Dineopentylethane 500

1,1-Dineopentylethylene 455

Dioctylbenzene phosphonate 314

Di-n-octyl ether 210

Dioctylisooctenephosphonate 320

714


ntemperature

data

1,4-Dioxane 266, 179 775 (20), 933 (1)

Dipentene 237z

Diphenylamine 452, 635z

1,1-Diphenylbutane 462 (6000)

1,1-Diphenylethane 487 (6000)

Diphenylether 620z

Diphenylmethane 517 (18000), 485z

Diphenyloxide 646 (12000)

1,1-Diphenylpropane 466 (6000)

Di-n-propyl ether 189

Divinyl ether 360

n-Dodecane 232, 205z

i-Dodecane 534, 500 827 (20), 1010 (1)

1-Dodecanol 283

n-Eicosane 240

Ethanal (see Acetaldehyde)

Ethane 506z 472, 515 809 (20), 991 (1)

Ethanol (see Ethyl alcohol)

Ethene (see Ethylene)

Ether (see Ethylether)

p-Ethoxyaniline (see p-Phenetidine)

2-Ethoxyethanol (see Ethyleneglycolmonoethylether)

2-Ethoxylethanol acetate(see Ethyleneglycolmonoethyl ether monoacetate)

Ethyl acetate 610, 486 804 (20), 1063 (1)

Ethyl alcohol 425, 375 558, 426, 365z 814 (20), 1030 (1)

Ethylamine (70% aqueous solution) 384

Ethylaniline 479

Continued


ntemperature

data

715



Ethylbenzene 468 460 (18000), 553, 477, 430z 785 (20), 966 (1)

Ethylbenzoate 644

2-Ethylbiphenyl 449 (18000)

Ethyl bromide 588, 511 883 (20), 1055 (2)

2-Ethylbutane 273

2-Ethyl-1-Butanol (see i-Hexyl alcohol)

2-Ethyl-1-Butene 324 (6000)

Ethyl-n-butyrate 351 612, 463

Ethyl caprate 493

Ethyl-n-caproate 582

Ethyl-n-caprylate 571

Ethyl carbonate 782 (20), 1013 (1)

Ethyl chloride 468 516, 494

Ethylcyclobutane 211

Ethylcyclohexane 262, 264 (114000)

Ethylcyclopentane 262

Ethylene 485 490, 543

Ethylene chlorhydrin 400 425

Ethylene dichloride 413

Ethyleneglycol 500 522, 413, 400z

Ethyleneglycol diacetate 635

Ethyleneglycoldiethyl ether 208

Ethyleneglycolmonobenzyl ether 352

Ethyleneglycolmonobutyl ether 244 792 (20), 964 (1)

Ethyleneglycolmonoethyl ether 238, 350z 790 (20), 954 (1)

716


ntemperature

data

Ethyleneglycolmonoethyl ether acetate 379

Ethyleneglycolmonoethyl ether monoacetate 774 (20), 960 (1)

Ethyleneglycolmonomethyl ether 288, 382 780 (20), 933 (1)

Ethylene imine 322

Ethylene oxide 429

Ethyl ether 178, 182 343, 491, 186, 193, 160z 794 (20), 947 (1)

Ethyl formate 577, 455z 768 (20), 956 (1)

Bis(2-Ethylhexyl)-adipate 262

Ethyl lactate 400

Ethyl malonate 541

Ethyl mercaptan 261 299

Ethylmethyl ether (see Methyl ethyl ether)

Ethylmethyl ketone (see Methyl ethyl ketone)

1-Ethylnaphthalene 481 (6000)

Ethyl nitrate 426 (20), 562 (1)

Ethyl nitrite 90 580 (20), 833 (1)

3-Ethyloctane 235

4-Ethyloctane 237 (54000)

Ethyl oleate 353

Ethyl oxalate 742 (10), 880 (1)

Ethyl palmitate 388

Ethyl pelargonate 524

Ethyl propionate 440 602, 476, 440z

Ethylpropyl ketone 575

Ethyl-n-valerianate 590

Formaldehyde (37% solution) 430

Formamide 969 (20), 1032 (10)

Continued


ntemperature

data

717



Formic acid 504

Furan 783 (20), 982 (1)

2-Furancarbonal (see Furfuraldehyde)

Furfuraldehyde 391 696 (20), 880 (1)

Furfuran (see Furan)

Furfuryl alcohol 364 391, 491 775 (20), 944 (1)

Fusel oil (see n-Amyl alcohol)

Gas oil 270 336

Gasoline (100/130) 440z

Gasoline (115/145) 470z

Glycerine 370z

Glycerol 414, 320 500, 523, 393

Glyceryl triacetate 433

Glycol (see Ethylene glycol)

n-Heptane 300, 214, 209z 451, 230, 233, 250, 247 (30000),215z, 223z

806 (20), 950 (1)

n-Heptanoic acid 523

1-Heptene 332, 263 (66000)

a-n-Heptylene (see 1-Heptene)

Hexachlorobutadiene 618 (6000)

Hexachlorodiphenyl oxide 628, 600

n-Hexadecane 230 (66000), 232, 205z

i-Hexadecane 484

1-Hexadecene 240 (78000), 253

Hexahydrobenzene (see cyclohexane)

Hexahydrophenol (see cyclohexanol)

718


ntemperature

data

Hexamethylbenzene 375

Hexamethylene (see cyclohexane)

n-Hexane 296, 225z 487, 520, 248, 261, 225z, 261 (30000) 828 (20), 1015 (1)

i-Hexane 268, 284

2,5-Hexanedione (see Acetonylacetone)

1-Hexene 272 (72000)

Hexone (see i-Butylmethyl ketone)

n-Hexyl alcohol 300 801 (20), 970 (1)

i-Hexyl alcohol 800 (20), 963 (1)

Hexylene 325

n-Hexylether 185z

Hydrazine 270

Hydrocyanic acid 538

Hydrogen 560 572, 400z 610 (20), 700 (1)

Hydrogen sulfide 220 292

Hydroquinone 630

2-Hydroxyethylamine (see Monoethanolamine)

4-Hydroxy-4-Methyl-2-pentanone(see Diacetone alcohol)

a-Hydroxytoluene (see Benzyl alcohol)

m-Hydroxytoluene (see m-Cresol)

Isophorone 322 462

Isoprene 440

JP-1 228z

JP-3 238z

JP-4 240z

JP-6 230z

Kerosene 270 295, 254, 210z, 249 (66000) 806 (20), 998 (1)

Continued


ntemperature

data

719



Ketohexahydrobenzene (see cyclohexanone)

DL-Limonene 263 (30000)

Linseed oil 438

Mesitylene 621

Mesityl oxide 344 823 (20), 1037 (1)

Methanamide (see Formamide)

Methane 556 632, 537, 540z 961 (20), 1050 (10)

Methanol (see Methyl alcohol)

Methone 506

o-Methoxyaniline (see o-Anisidine)

2-Methoxyethanol (see Ethyleneglycolmonomethylether)

Methyl acetate 654, 502 816 (20), 1028 (2)

Methyl alcohol 555, 500, 461 574, 470, 464, 385z 820 (20), 1040 (1)

Methylamine 400 430

Methylaniline (see Toluidine)

2-Methylbiphenyl 502 (12000)

Methyl bromide 537

2-Methylbutane 294 420, 427 (6000)

2-Methyl-2-Butanol (see t-Amyl alcohol)

3-Methyl-1-Butanol (see i-Amyl alcohol)

3-Methyl-1-Butene 374 (6000)

1-Methyl-2-t-butylcyclohexane 314 (12000)

1-Methyl-3-t-butylcyclohexane (high boiling isomer) 304 (12000)

1-Methyl-3-t-butylcyclohexane (low boiling isomer) 291 (24000)

Methylbutyl ketone 533

720


ntemperature

data

Methyl cellosolve (see Ethyleneglycolmonomethylether)

Methyl chloride 632

Methyl cyanide (see Acetonitrile)

Methylcyclohexane 285 265 (108000), 250z

Methylcyclohexanone 598

Methylcyclopentane 329 323 (6000) 812 (20), 1013 (1)

Methyl cyclopentadiene 445z

2-Methyldecane 231

Methylenedichloride (see Methylene chloride)

1-Methyl-3,5-Diethylbenzene 461 (12000)

Methylene chloride 606 642, 662, 615z 902 (20), 1085 (2)

Methyl ether (see Dimethyl ether)

1-Methyl-2-Ethylbenzene 447 (18000)



Methylethyl ether 190

Methylethyl ketone 514, 505 804 (20), 975 (1)

Methylethylketone peroxide 390z

2-Methyl-3-Ethylpentane 461

Methylformate 236, 449, 465z 797 (20), 1026 (2)

Methylheptenone 534

Methylcyclohexanol 295z

Methylhexyl ketone 572

Methylisopropylcarbinol (see s-Amyl alcohol)

Methyl lactate 385

1-Methylnaphthalene 566, 547 (24000), 553, 530z

Continued


ntemperature

data

721



2-Methylnonane 214 (102000)

2-Methylpropanal (see i-Butyraldehyde)

2-Methyloctane 227 (66000)



2-Methylpentane 275 306, 307 (6000)

3-Methylpentane 304 (12000)

2-Methyl-1-Pentene 306 (6000)

4-Methyl-1-Pentene 304 (12000)

4-Methyl-3-Pentene-2-one (see Mesityl oxide)

2-Methyl-1-Propanol (see i-Butyl alcohol)

a-Methylpropyl alcohol (see s-Butyl alcohol)

2-Methyl Propane (see i-Butane)

2-Methylpropene 465

Methylpropionate 469

Methyl-n-propyl ketone 505 832 (20), 1020 (1)

2-Methylpyridine (see a-Picoline)

Methylsalicylate 454

2-Methyltetrahydrofuran (see Tetrahydrosylvan)

Methylstyrene 495z

Monoethanolamine 780 (20), 1006 (1)

Monoisopropyl bicyclohexyl 230z

2-Monoisopropyl biphenyl 435z

Monoisopropylxylenes 798 (20), 1040 (1)

Naphthalene 630, 560 587, 568, 526z

722


ntemperature

data

Neatsfoot oil 442

Neohexane (see 2,2-Dimethylbutane)

Nicotine 235 244

Nitrobenzene 556, 482 706 (20), 884 (1)

Nitroethane 415 623 (20), 762 (1)

Nitroglycerol 270

Nitromethane 419 684 (20), 784 (1)

1-Nitropropane 417

2-Nitropropane 428

o-Nitrotoluene 672 (20), 837 (1)

m-Nitrotoluene 711 (20), 911 (1)

n-Nonadecane 237

n-Nonane 285, 234 (66000), 205z

n-Octadecane 235

1-Octadecene 251

Octadecyl alcohol 270

Octahydroanthracene 315

n-Octane 208 458, 218, 240 (54000)

i-Octane (see 2,2,4-Trimethylpentane)

1-Octene 256 (72000)

Octyleneglycol 335

Olive oil 441

Oxalic acid 640

Oxybutyricaldehyde (see Aldol)

Palm oil 343

Paraldehyde 541, 242 846 (20), 1064 (1)

Pentamethylene glycol 335z

Continued


ntemperature

data

723



n-Pentane 300, 258 579, 290, 284 (24000), 260z

i-Pentane (see 2-Methylbutane)

1-Pentene 298 (18000)

1-Pentanol (see n-Amyl alcohol)

2-Pentanone (see Methylpropyl ketone)

g-Pentylene oxide (see Tetrahydrosylvan)

Perfluorodimethylcyclohexae 651 (6000)

p-Phenetidine 822 (20), 1004 (1)

Phenol 574, 500 715

Phenylamine (see Aniline)

Phenylaniline (see Diphenylamine)

Phenylbromide (see Bromobenzene)

Phenyl carbinol (see Benzyl alcohol)

Phenyl chloride (see Chlorobenzene)

n-Phenyldiethylamine (see Diethylaniline)

Phenylethane (see Ethylbenzene)

Phenylethylene (see Styrene)

Phenylmethyl ether (see Anisole)

Phenylmethyl ketone (see Acetophenone)

Phosphorus (yellow) 30

Phosphorus (red) 260

Phosphorus sesquisulfide 100

Phthalic anhydride 584, 570z

a-Picoline 538, 500z 846 (20), 1037 (2)

Picric acid 300

724


ntemperature

data

Pinene 275 263 (60000) 797 (20), 1039 (1)

1,2-Propandiol 410z

Propane 468 493, 450z, 466, 504 (6000)

1-Propanol (see n-Propyl alcohol)

2-Propanol (see i-Propyl alcohol)

2-Propanone (see Acetone)

Propenal (see Acrolein)

Propene 423z 458

Propen-1-ol (see Allyl alcohol)

Propene oxide (see Propylene oxide)

Propionaldehyde 419

n-Propionic acid 596

n-Propyl acetate 388 662, 450 828 (20), 1060 (2)

i-Propyl acetate 448 572, 460, 476

n-Propyl alcohol 445, 370, 328 505, 540, 439, 433 811 (20), 1007 (1)

i-Propyl alcohol 512 590, 620, 456 811 (20), 1050 (1)

n-Propylamine 318

i-Propylamine 402

n-Propylbenzene 456 (12000)

i-Propylbenzene (see Cumene)

2-Propylbiphenyl 452 (18000), 440z

Propyl bromide 255 490

Propyl chloride 520

i-Propyl chloride 593

Propylcyclopentane 285

Propylene (see Propene)

Propylene aldehyde (see Crotonaldehyde)

Continued


ntemperature

data

725



Propylene dichloride 557 790 (20), 1012 (2)

Propylene glycol 392 421

Propylene oxide 748 (10), 870 (1)

i-Propyl ether (see Diisopropyl ether)

n-Propyl formate 455

n-Propyl nitrate 175z

i-Propyl formate 485

4-i-Propylheptane 288

p-i-Propyltoluene (see p-Cymene)

Pseudocumene (see pseudo-Cumene)

Pulegone 426

Pyridine 482, 574 745 (20), 1014 (1)

Pyrogallol 510

Quinoline 480

Quinone 575

Rapeseed oil 446

Rosin oil 342

Salicylicaldehyde 772 (20), 1015 (1)

Soya bean oil 445

Stearic acid 250 395

Styrene 450 490 777 (20), 1065 (1)

Sugar 378 385

Sulfur 232

Tannic acid 527

Tartaric acid 428

726


ntemperature

data

p-Terphenyl 535z

Tetraaryl salicylate 577 (6000)

n-Tetradecane 232, 200z

1-Tetradecene 239 (66000), 255

1,2,3,4-Tetrahydrobenzene (see Cyclohexene)

Tetrahydrofurfuryl alcohol 273 282 793 (20), 980 (1)

Tetrahydronaphthalene 420 423 (6000), 385z 819 (20), 1030 (1)

Tetrahydrosylvan 794 (20), 1025 (1)

Tetraisobutylene 415

n-Tetradecane 200z

Tetralin (see Tetrahydronaphthalene)

Tetramethylbenzene 791 (20), 1030 (1)

Tetramethylene glycol 390z

2,2,3,3-Tetramethylpentane 430, 452 (42000), 516

2,3,3,4-Tetramethylpentane 437 (24000), 514

Toluene 552, 640, 516 810, 633, 552, 540, 480z, 568 (48000),635

830 (20), 1057 (1)

o-Toluidine 537, 482 832 (20), 1040 (3)

m-Toluidine 580 846 (10), 1062 (2)

p-Toluidine 482

Tributyl citrate 368

Trichloroethane 500z

Trichloroethylene 419 463, 420z 771 (10), 950 (1)

Trichloro-1-(pentafluoroethyl)-4-(trifluoromethyl)benzene

568

Tricresyl phosphate 600

Triethylene glycol 244 371

Continued


ntemperature

data

727



Triethylenetetramine 338

Triisobutylenes 413 789 (20), 1060 (1)

1,2,3-Trimethylbenzene 479 (24000), 510



2,2,3-Trimethylbutane 454 (18000), 420z

2,3,3-Trimethyl-1-butene 383 (12000)

Trimethylene glycol 400z

2,5,5-Trimethylheptane 485

2,2,3-Trimethylpentane 436 (24000)

2,2,4-Trimethylpentane 283 561, 434, 447 (12000), 515, 415z 786 (20), 996 (2)

2,3,3-Trimethylpentane 430 (12000)

2,3,4-Trimethyl-1-pentene 257 (12000)

2,4,4-Trimethyl-1-pentene (cf. Diisobutylenes) 420 (12000)

2,4,4-Trimethyl-2-pentene (cf. Diisobutylenes) 308 (30000)

3,4,4-Trimethyl-2-pentene 330 (24000)

2,4,6-Trimethyl-1,3,5-trioxane (see Paraldehyde)

728


ntemperature

data

Trinitrophenol (see Picric acid)

Trioxane 424, 414

Tritolyl phosphate (see Tricresyl phosphate)

Tung oil 457

Turkey red oil 445

Turpentine 252, 255 780 (20), 996 (1)

Vinyl acetate 427

Vinylcyclohexene 269

Vinyl ether (see Divinyl ether)

Vinylethyl ether 201

Vinyl-2-ethylhexyl ether 201

Vinylisopropyl ether 272

o-Xylene 496, 465z, 501 (30000), 551

m-Xylene 563 (54000), 652, 530z

p-Xylene 618, 564 (42000), 657, 530z

Zinc stearate 421


ntemperature

data

729

combustion || spontaneous ignition temperature data

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