coating presentation tp bangkok - 23 jan 2014

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22/01/2014 1 Coating Overview Audrey BERGERON Bangkok – January 23 rd 2014 1 2 About the instructor Title Coating specialist Region / Entity Asia Pacific / TPS Business segment Subsea – Onshore Offshore Education Meng./ Chemical Engineering Contact [email protected]

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Corrosion protection by coating methodologies.

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  • 22/01/2014

    1

    Coating Overview

    Audrey BERGERON Bangkok January 23rd 2014

    1

    2

    About the instructor

    Title Coating specialist

    Region / Entity Asia Pacific / TPS

    Business segment Subsea Onshore Offshore

    Education Meng./ Chemical Engineering

    Contact [email protected]

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    3

    About Technip Singapore

    Shallow to deep water (3000 m)

    S-laying Rigidd pipes (4 to 60 ) Piggy-backed pipeline

    installation Pipe-in-pipe, CRA

    OFFSHORE PIPELINE INSTALLATION

    Lifting up to 1200 tons Installation of

    platform, subsea structures, skids, modules, etc.

    OFFSHORESTRUCTUREINSTALLATION,HEAVY LIFTING

    4

    About Technip Singapore

    Spools Risers Buckle Initiator Structures PLEM Manifolds Skids Crossing Structures Installation Aids

    FABRICATION SERVICES

    Full-time divers Saturation to 300m Pipelines, platform, SCM

    de-commissioning / removal

    DIVING, IMR, DECOMMIS-SIONING

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    About Technip Singapore

    G1201 - 3rd Generation DP Pipelay Vessel incl. 1200MT Pedestal Crane

    Summary

    1. HSE moment

    2. Reason for coating

    3. Corrosion prevention - Generality

    4. Surface preparation

    5. Painting & coating

    6. Pipe & field joint coating

    7. Coating qualification process and requirement

    6

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    3LPP/PE:CS:

    CUI: CWC: FBE: FJC:

    GSPU: HP/HT:

    HSS: MLPP/PE:

    PE:PFP:

    PP:PU:

    SPU:SS:

    TSA:

    Three Layer PolyPropylene / PolyEthyleneCarbon SteelCorrosion Under InsulationConcrete Weight CoatingFusion-Bonded EpoxyField Joint CoatingGlass Syntactic PolyUrethaneHigh Pressure/ High TemperatureHeat Shrinkable SleevesMulti-Layer PolyPropylene / PolyEthylenePolyEthylenePassive Fire ProtectionPolyPropylenePolyUrethaneSyntactic PolyUrethaneStainless SteelThermal Spray Aluminum

    Abbreviations

    8

    Summary

    1. HSE moment2. Reason for coating

    3. Corrosion prevention - Generality

    4. Surface preparation

    5. Painting & coating

    6. Pipe & field joint coating

    7. Coating qualification process and requirement

    8

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    1. HSE moment

    Find the difference:

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    1. HSE moment

    10

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    Summary

    1. HSE moment

    2. Reason for coating3. Corrosion prevention - Generality

    4. Surface preparation

    5. Painting & coating

    6. Pipe & field joint coating

    7. Coating qualification process and requirement

    11

    2. Reason for coating

    Why do we need coating? What kind of coating?

    Corrosion protection

    Anti corrosion paint

    Passive Fire Protection (PFP)

    Intumescent Epoxy Cementitious coating

    Fouling release

    Anti fouling paint

    12

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    2. Reason for coating

    Mechanical protection

    Polyolefin coatings

    Negative buoyancy

    Concrete weight coating

    Prevent CUI(corrosion under insulation)

    Metallizing (Thermal spray aluminum)

    13

    2. Reason for coating

    Anti slip

    Paint + natural aggregate

    Insulation

    PU foam

    Aesthetic aspect Polyurethane, Acrylic

    14

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    Summary

    1. HSE moment

    2. Reason for coating

    3. Corrosion prevention - Generality4. Surface preparation

    5. Painting & coating

    6. Pipe & field joint coating

    7. Coating qualification process and requirement

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    3. Introduction to corrosion

    According to NACE: Corrosion is a deterioration of a material because of reaction with its environment.

    Liquid water is in contact with metal AND

    corrosive agent is present in the waterCORROSION =

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    3. Introduction to corrosion

    Corrosion impact:

    o Safety: unsafe corroded structures / equipment

    o Cost: For the US, the annual cost of corrosion worldwide is around 3% of GDP (US$ 250 Billion)

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    3. Introduction to corrosion

    Different types of corrosion Uniform corrosion

    o Uniform loss of mass for external surfaces. Concerns mainly carbon steel and cast iron.

    o Solution: corrosion allowance (3 to 6 mm), painting, cathodic protection.

    Galvanic corrosiono Creation of an electric current between 2 materials with

    different potential. o Common cases: aluminum/stainless steel, carbon

    steel/stainless steel. o Solution: isolation joints, cathodic protection, coating

    Erosion corrosiono Erosion (abrasion): removal of metal by mechanical

    action of liquids (or solids). Erosion-corrosion :removal of corrosion products by mechanical action of liquids ( or solids).

    o Solution: improve flow by design of the piece, change for better material, corrosion allowance

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    3. Introduction to corrosion

    Different types of corrosion

    Pitting corrosiono High chloride concentration leads to passivation layer

    breakdown. o Affects stainless steel, aluminum, titaniumo Solution: increase molybdenum content in SS (CRA),

    coating

    Chloride stress corrosion crackingo Combined action of seawater and mechanical stresso 316 Austenitic stainless steels subject to CSCC if

    chloride concentration > 50 ppm and temperature > 50

    o Solution: coating, change material grade (316 SS to 22Cr or 25Cr)

    20

    3. Introduction to corrosion

    Corrosion preventionCorrosion prevention

    Design

    Coating

    Chemical treatment

    Cathodicprotection

    Material selection

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    3. Introduction to corrosion

    How to prevent corrosion?

    Design: avoid water retention, moisture / salts entrapment

    Inhibitors: chemical added into a fluid to decrease corrosion rate Material selection. Examples:

    o SS 304L very sensitive to CSCC in offshore environment. SS 316L, 22Cr duplex or Inconel 625 are preferred.

    o Carbon Steel can be selected for offshore structures, provided it is protected by coating and cathodic protection.

    Cathodic protection: protection of the surface by another sacrificial metal (Zn, Al, Mg, ) who has a more electronegative potential.

    Protective coating

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    Summary

    1. HSE moment

    2. Reason for coating

    3. Corrosion prevention - Generality

    4. Surface preparation5. Painting & coating

    6. Pipe & field joint coating

    7. Coating qualification process and requirement

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    Clean the surface from contaminant

    Create roughness for coating adhesion.

    4. Surface preparation

    objectives

    Surface preparation: The key step to the coating success

    dustgrease

    mill scale

    oil

    Soluble salts

    Former coating

    contaminants

    Long term stability to the coating

    Did you know? 75% of premature coating failures are caused by inadequate or improper surface preparation

    23

    Substrate: carbon steel, stainless steel, Aluminum, galvanized steel

    Degree of cleanliness required (paint system type and thickness)

    Geometry of the piece (area difficult to access with machines)

    Place where surface is prepared (on site, applicators plant)

    Selection of the method depends on:

    4. Surface preparation

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    1. Prior to commencement

    check for fabrication or welding defaults: rough edges, cuts and welds shall be rounded to a 2mm radius to improve coating coverage and adhesion on the surface.

    remove weld spatters.

    4. Surface preparation

    2. Solvent cleaning.Degrease and remove oil, grease, soluble contaminants with solventcleaning (fresh water, emulsion cleaners, detergents, organic solvents,petroleum based solvents, alkaline cleaners). Does not removeChlorides, mill scale or other inorganic materials.

    3. Abrasive blasting or other method

    Remove chlorides and sulfates, create desired surface profile forprimer adhesion, create a uniform aspect.

    25

    steel shot or grit (carbon steel surfaces),

    aluminum oxide or garnet sand (stainless steel or carbon

    steel surfaces).

    Projection of abrasive particles to remove rust and other contaminant and create a rough surface

    Abrasive blast cleaning

    4. Surface preparation

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    4. Surface preparation

    Abrasive blasting equipment

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    Surface preparation: other methods

    Power tool cleaning (hand or mechanical). Example: rotary wire brush.

    Water jetting. Only to remove previous coating, does not create roughness.

    Pickling. Dipping of steel in an acid bath

    4. Surface preparation

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    4. Surface preparation

    Substrate Type of system Cleanliness (ISO 8501-1 or SSPC)

    Profile surface (ISO 8503)

    Carbon steel external surfaces

    Typical paint system with DFT > 200m

    Sa 2 eq. to SSPC SP10 50-75 m

    Carbon steel internal surfaces

    Internal coating (lining)

    Sa 3 eq. to SSPC SP5 or Sa 2 eq. to SSPC SP10

    50-75 m

    Stainless steel, Galvanized steel

    Typical paint system Sweep blasting eq. to SSPC SP7 20-40 m

    - Carbon steel - Stainless steel

    TSA - Sa 3 eq. to SSPC SP5- Sweep blasting eq. to SSPC SP7

    70-120 m

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    Summary

    1. HSE moment

    2. Reason for coating

    3. Corrosion prevention - Generality

    4. Surface preparation

    5. Painting & coating6. Pipe & field joint coating

    7. Coating qualification process and requirement

    30

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    5.1 Corrosion protection coatings

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    Definition Application Selection Protection mode Specification

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    5.1. Corrosion protection coatings - Definition

    PAINT= A+B

    Binder (polymer)

    Pigments + fillers

    Solvent

    Additives

    Reactive + solvent

    Component A

    Component B

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    5.1. Corrosion protection coatings - Definition

    2 component- thermoset coatings Excellent adhesion, chemical and water resistance Shall be top-coated by UV-resistant topcoat

    EPOXY

    2 component Resistant to UV, good gloss and color retentionPOLYURETHANE

    2 component min. zinc content 85% Very high substrate adhesion good chemical resistance Max thickness 80 m, subject to mud-cracking -careful with

    repairs INORGANIC ZINC

    Cure at ambient temp. or with help of heat For heat resistance up to 600 , or foul releaseSILICONES

    2 component coatings Very good for immersion service Suitable up to 230

    PHENOLIC EPOXIES

    2 component used as linings very resistant to chemicals and temp.

    High thickness (2 x 1000 m)VINYL ESTER

    2 component short pot life (45 min at 20 ) - Glass flake reinforcedExcellent resistance to abrasion, water and moisture good for salt and fresh water environment and walkways

    POLYESTER

    Major paint used for corrosion protection purpose

    Spray application : Air spray vs Airless spray

    - Spray pattern easily adjusted - High quality of finishes (automotive)

    - Overspray causes high loss of coating- Add solvent to improve atomization but leads to low thickness

    Air spray

    Airless spray

    - Less overspray- Heavier film built- Better production rates

    -Little control of coating quantity- Speed makes it difficult for small pieces

    5.1. Corrosion protection coatings Application

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    Brush application

    Brush is only for o Small areas not easily

    accessible by sprayo Repairs and touch-upo Stripe coats, corner, edges,

    welds, bolting, flangeso When environmental conditions

    prohibit the use of spray

    Roller application Do not use roller unless specific client approval

    - Helps coating to have a good adhesion on substrate (for primers and underwater coatings)- Good penetration into surfaces that cannot be properly cleaned

    - Slow application (can be an advantage in some cases)- Low DFT achieved

    5.1. Corrosion protection coatings Application

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    36 Steel

    Finish coat (polyurethane)

    Intermediate coat (Epoxy based)

    Zinc rich primer (inorganic zinc, zinc rich epoxy)Primer with inibitors (zinc phosphate)

    1 Barrier

    2 Galvanic

    3 Inhibition

    Impermeability to water vapor, oxygen and salts (Chloride), thick film, electric resistance pigmented epoxies (high solid content, mica flakes)

    1. Barrier effect

    Primer contains a metallic pigment with a more electronegative potential inorganic zinc silicates and zinc rich organic primers (epoxies)

    2. Galvanic effect

    Isolation of the substrate surface by addition of a metallic compound chemically bonded to the surface zinc phosphate pigment

    3. Inhibition

    5.1. Corrosion protection coatings Protection mode

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    Selection of coating depends on:

    Atmospheric corrosivity of environment (marine C5M, industrial C5I, high C4, )

    Substrate (carbon steel, stainless steel, galvanized steel, aluminum, CRA, )

    Equipment operating temperature

    Durability of the coating / installation

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    2

    3

    4

    5.1. Corrosion protection coatings - Selection

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    5.1. Corrosion protection coatings Specification

    Frequently encountered coating systems Onshore offshore systems

    Substrate System DFT (m)CS operating below 120 (Uninsulated)

    Zinc rich primer (epoxy or inorganic zinc)Epoxy high build Polyurethane topcoat

    50-75150-20050

    CS operating between 120 and 450 (Uninsulated)

    Inorganic zinc primerAl pigmented siliconeAl pigmented silicone

    50-752525

    SS operating below 120 (Uninsulated)

    Epoxy primer, zinc freeEpoxy high build Polyurethane topcoat

    50150-20050

    SS operating between 120 and 600 (Uninsulated)

    Al pigmented siliconeAl pigmented silicone

    2525

    Insulated CS and SS operating below 200

    Epoxy phenolicEpoxy phenolic

    100100

    Insulated CS and SS operating between 200 and 600

    TSASealer (silicone)

    25040

    Bulk items (any substrate, any temperature, valves, piping, )

    Universal coating, inorganic copolymer (compatible with PU topcoat for color marking)

    As per manufacturer

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    Frequently encountered coating systems Onshore offshore systemsInternal coatings (Carbon steel surfaces)

    Application System DFT (m)Potable water below 60 Solvent free epoxy

    Solvent free epoxy300300

    Crude oil, diesel, condensate, below 60 : bottom up to 1m + roof and upper 1m of wall

    Abrasion resistant epoxyAbrasion resistant epoxy

    150-180150-180

    methanol, MEG below 80 Inorganic zinc primer 60

    Process vessel below 120 Solvent free epoxy Novolac 300-600

    5.1. Corrosion protection coatings Specification

    Galvanized surfaces

    Substrate System DFT (m)Galvanized steel operating below 120 Epoxy primer, zinc free

    High build epoxyPolyurethane

    5010050

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    Frequently encountered coating systems Subsea systems

    Substrate System DFT (m)

    CS and SS in splash zone operating below 100

    Abrasion resistant epoxy (glass flakes)Abrasion resistant epoxy (glass flakes)

    300300

    CS and SS immersed operating below 100

    Abrasion resistant epoxy or high build epoxyAbrasion resistant epoxy or high build epoxy

    175175

    5.1. Corrosion protection coatings Specification

    Antiskid surfaces

    Substrate System DFT (m)Carbon steel Epoxy primer

    Ultra high build epoxy + non-skid aggregatesPolyurethane

    50600-300060

    Note: 1. Surface friction coefficient may need to be indicated. 2. Use of Aluminum oxide (and other non-ferrous irregular surfaces) is preferred

    40

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    Checks and Quality Controls

    Before painting applicationo Operator and inspector Qualification certificateso Instrumentation device calibration certificates

    Surface preparationo Environmental conditions (Dew Point, surface TC and Ambient TC measurement),o Abrasive contamination,o Grade of cleanliness + surface roughness,o Chloride content + dust level

    Painting applicationo Wet and dry film thickness,o Visual inspection

    After painting applicationo Curing of inorganic zinc,o Adhesion testo Pinhole detection (only for immersed, underground and internal coatings)

    5.1. Corrosion protection coatings Specification

    5.2 Specific coatings

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    Metallizing Passive Fire Protection Fouling-release coatings

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    Thermal Spray Aluminum Spraying of molten Aluminum wire by flame spray or arc spray Good for immersion and CUI prevention. Applied on Carbon steel or Stainless steel operating up to 600

    - Excellent corrosion protection properties- Excellent resistance to mechanical damages - Very high durability (up to 50 years)- Zero VOC.

    - Porous: need to apply a sealer on top (epoxy or silicone).- Cost effective process - HSE rules must be strictly followed. - Critical surface preparation: high degree of cleanliness required

    5.2 Specific coatings: Metallizing (TSA)

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    5.2 Specific coatings: Metallizing (TSA)

    TSA coating systems

    Substrate System DFT (m)

    CS and SS operating below 120

    TSAEpoxy sealer compatible with TSA

    25040

    CS and SS operating above 120

    TSASilicone sealer compatible with TSA

    25040

    Application examples Bulk valves (all temperatures, CS and SS) Offshore or immersed structures Flare top

    TSA applicators Norimax WASCO MTM Metalization

    44

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    5.2 Specific coatings: Metallizing (TSA)

    Splitter column Turret component

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    5.2 Specific coatings: Metallizing

    Other Thermal Spray Coatings:

    Zinc Al-Zn Stainless steel Inconel Copper Nickel Monel Hastelloy

    Harder material Higher operating temperature gun

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    Steel begins to lose strength as its temperature rises in a fire structural collapse. PFP is designed to protect structures supporting high risk and valuable equipment. Objective: prevent the substrate to rise in temperature during a fire to avoid steel to collapse:

    o Jet fireo Hydrocarbon fire o Cellulosic fire

    0

    200

    400

    600

    800

    1000

    1200

    1400

    0 30 60 90 120 150 180

    Tem

    pera

    ture

    C

    Time (minutes)

    Fire Curves

    Cellulosic

    Hydrocarbon

    Jet Fire

    Jet fire: Release of hydrocarbon fuel under pressure through a relatively small opening such as a crack or hole high levels of turbulence, erosion of the PFP coating.

    Pool fire: Hydrocarbon fuel burning under atmospheric pressure.

    5.2 Specific coatings: PFP

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    - Provides corrosion protection- Low DFT for 2h protection (2-10 mm)- Low density

    - Requires the use of skilled applicators- Cost effective

    Organic coatings: Intumescent epoxyThey are inert at ambient temperature but react when exposed totemperatures above about 200C. The reacted coating forms a thick carbonbased char. Applied with reinforcement mesh

    5.2 Specific coatings: PFP

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    Spray application equipment

    Source: PPG

    Typical Plural Component Pump

    Typical plural component mixing block and spray gun

    5.2 Specific coatings: PFP

    Thickness of PFP is determined by:o Size, shape of steel section to protect (beams, hollow section)o Critical failure temperatureo Duration of protection needed

    Calculation of DFT with Hp/A value.

    Low A

    High Hp

    Fast Heating

    Low Hp

    High A

    Slow Heating

    Source: PPG

    Hp = heated perimeter exposed to fireA = cross-section area of steel element

    The higher Hp/A value, the higher PFP thickness will be required.

    5.2 Specific coatings: PFP

    50

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    5.2 Specific coatings: PFP

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    - Cheap, easy to install and repair- Hard and durable

    - Heavy- Thickness around 25 mm for a 2h fire protection- Poor flexibility- Risk of hidden corrosion in reinforcement by water ingress

    Inorganic coatings: CementitiousLightweight with nominal density around 500 kg/m3.Must be topcoated with a high water vapor permeabilitycoating. Must also be applied with mesh reinforcement.

    5.2 Specific coatings: PFP

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    5.2 Specific coatings: PFP

    PFP systems

    Substrate System DFT (m)

    Fireproofed carbon steel surfaces

    Zinc rich epoxy or inorganic zinc silicateIntumescent PFP epoxyPolyurethane

    50As calculated50

    Fireproofed stainless steel surfaces

    Zinc free epoxy primerIntumescent PFP epoxyPolyurethane

    50As calculated50

    Fireproofed carbon steel surfaces

    Zinc rich epoxy or inorganic zinc silicateHigh build epoxyCementitious PFP

    50150As calculated

    Fireproofed stainless steel surfaces

    Zinc free epoxy primerHigh build epoxyCementitious PFP

    50150As calculated

    Objective: prevent formation of biofouling on vessels and structures (mussels, barnacles, algae, etc.). 2 mechanisms: fouling release coatings and antifouling coatings (biocide release).

    Fouling release coatings: - Silicones- Fluoro-polymer Prevent attachment of micro-organisms on the structure by creating a smooth finish with low surface tension.

    5.2 Specific coatings: Fouling release coatings

    Source: PPG

    TBT-based coatings are prohibited54

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    5.2 Specific coatings: Fouling release coatings

    Fouling release system

    Substrate System DFT (m)

    Any (riser, structure, hull, etc.) Epoxy primerFoul release coat (1 or 2 coats)Finish coat

    50-100200-600100-150

    Note: Fouling release systems depend on each coating manufacturer; all products of the system should be compatible with each other. The proposed system is for example only.

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    5.2 Specific coatings: Shop primers

    Thin film inorganic zinc primer applied on applicators plant for more accurate control of application process.

    Typical application: steel plates for tank storage. Purpose: Protect against corrosion and environment during

    transport and before erection.

    Primer is applied automatically or not at 15-30 m.

    Source: TOTAL GTS presentation

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    5.2 Specific coatings: Shop primers

    Source: TOTAL GTS presentation

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    5.2 Specific coatings: Shop primers

    Source: TOTAL GTS presentation

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    Summary

    1. HSE moment

    2. Reason for coating

    3. Corrosion prevention - Generality

    4. Surface preparation

    5. Painting & coating

    6. Pipe & field joint coating7. Coating qualification process and requirement

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    6.1 Pipe coating

    60

    Selection Properties Standards Systems Subcontractors Futures challlenges

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    6.1. Pipe coating - Selection

    Pipeline protection = Combination of

    Adequate protective coating, Supplementary cathodic protection

    Selection of the coating system depends on: o Pipe material characteristicso Service / design temperatureo Pipeline design thermal profileo Maximum water deptho Specific properties requirement (cathodic disbondment, elongation, strength, )o Laying method

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    Properties for Corrosion protection coating

    Main properties

    o Strong adhesion to the pipeo Corrosion propertieso Strong resistance to cathodic

    disbondment

    o Durability for design life of the pipe

    o Good mechanical strength

    6.1. Pipe coating - Properties

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    Properties for Thermal insulation coating

    Pipes are insulated to prevent hydrate formation, waxing and to satisfy separator arrival temperature.

    Main propertieso Thermal conductivityo Densityo Adhesion to base material

    Properties for Weight coating

    Main propertieso Densityo Compressive strength

    6.1. Pipe coating - Properties

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    Types of pipe coatings

    o Fusion Bonded Epoxy (FBE), Liquid epoxy

    o 3-layer Polyethylene (3LPE) / Polypropylene (3LPP)

    o MLPP Foam / syntactic

    o GSPU, SPU

    o Concrete Weight Coating (CWC)

    Corrosion protection

    Flow assurance

    Negative buoyancy

    6.1. Pipe coating - Properties

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    International standards in pipe coating: ISO 21809

    3LPE/PP: ISO 21809 - 1 FBE: ISO 21809 - 2 CWC: ISO 21809 - 5ISO 21809 replaces DIN (German), NF (French), CSA (Canadian)

    Other standards or specifications AWWA (American Water Works Association): AWWA C213-07 (FBE) DNV-RP-F106 (FBE, 3LPP, 3LPE) NACE RP0394-2002 (FBE) DNV-OS-F101 (CWC)

    NO STANDARD FOR INSULATION COATING

    6.1. Pipe coating - Standards

    Liquid coating- Mainly used for buried pipe operating at elevated temperature, where 3LPE and 3LPP cannot be

    considered.

    - Generally a high built coating applied by airless spray with DFT up to 3000 m.

    - Maximum service temperature can go up to 200 , depending on the type of resin (epoxy, epoxy novolac, phenolic epoxy, vinyl ester).

    - Can be reinforced with glass flakes to improve moisture and mechanical resistance.

    - Can be applied as an internal lining to protect against corrosive fluid. In this case, thickness up to 300 m.

    6.1. Pipe coating - Systems

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    Fusion Bonded Epoxy (FBE)

    Coating system description Single layer fusion bonded epoxy

    Type of protection Corrosion protection

    Typical coating thickness 350-500 m

    Design temperature 90

    Water depth limit Unlimited

    Major characteristics - Excellent long term corrosion resistance to steel, - Cathodic disbondment resistance (reduce cost of

    cathodic protection) - Good chemical resistance.

    6.1. Pipe coating - Systems

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    FBE coating process

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

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    Three Layer Polypropylene (3LPP)

    Coating system description FBE + PP Adhesive + Solid PP

    Type of protection Corrosion protectionMechanical protection

    Typical coating thickness 2- 4.5 mm

    Design temperature 110 (up to 130 with high temperature FBE)

    Water depth limit Unlimited

    Major characteristics - High film thickness- Good PP flexibility mechanical protection to the

    pipe.- Good impact strength

    6.1. Pipe coating - Systems

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    3LPP coating process

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

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    Three Layer Polyethylene (3LPE)

    Coating system description

    FBE + PE Adhesive + Solid PE

    Type of protection Corrosion protectionMechanical protection

    Typical coating thickness

    2- 4.5 mm

    Design temperature 80

    Water depth limit Unlimited

    Major characteristics - Cheaper than 3LPP, but does not have as good mechanical characteristics as 3LPP.

    3LPE process is the same as 3LPP

    6.1. Pipe coating - Systems

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    Multilayer PP (MLPP) Foam MLPP

    Coating system description

    FBE + PP Adhesive + (Solid PP) + PP Foam + Solid PP

    Type of protection Corrosion protection + Mechanical protection + Thermal insulation

    Typical coating thickness

    Depends on thermal requirements

    Design temperature 120Water depth limit 600 m

    Major characteristics K-value around 0.17 W/m.K, density 600-800 kg/m3

    1. FBE2. 2. PP adhesive3. Solid PP4. PP foam5. Outer PP shield

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

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    Multilayer (MLPP) Glass syntactic MLPP

    Coating system description

    FBE + PP Adhesive + (Solid PP) + GSPP + Solid PP

    Type of protection Corrosion protection + Mechanical protection + Thermal insulation

    Typical coating thickness

    Depends on thermal requirements

    Design temperature 130Water depth limit 3000 m

    Major characteristics K-value around 0.16 W/m.K, density 650-700 kg/m3

    Hydrostatic pressure resistance is reinforced by glass microspheres added into the PP matrix.

    6.1. Pipe coating - Systems

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    Syntactic PU - polymer syntactic (sPU)

    Coating system description

    FBE + sPU

    Type of protection Corrosion protection + Thermal insulation

    Typical coating thickness

    Depends on thermal requirements

    Design temperature 115Water depth limit 300 m

    Major characteristics - K-value around 0.12 W/m.K, density 600-700 kg/m3

    - Thin wall + low polymer mechanical properties decrease compression resistance of the foam.

    6.1. Pipe coating - Systems

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    Syntactic PU - Glass syntactic (GSPU)

    Coating system description

    FBE + GSPU

    Type of protection Corrosion protection + Thermal insulation

    Typical coating thickness

    Depends on thermal requirements

    Design temperature 130Water depth limit 3000 m

    Major characteristics - K-value around 0.16 W/m.K, density 800 kg/m3- Hydrostatic pressure resistance reinforced by glass

    microspheres added into the PU matrix. - Grade of glass influences the collapse pressure and

    theoretical maximum water depth.

    6.1. Pipe coating - Systems

    76

    Injection moulding PU process

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

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    Concrete Weight Coating (CWC)

    Purpose: provide negative buoyancy and mechanical protection to the pipe.

    Mixture of cement, iron ore and wire wrap

    Main properties:o Density (1900-3700 kg/m3): varies iron ore

    quantity. o Compressive strength: depends on cement

    and water content. o Thickness: depends on pipe diameter.o Water absorption: ISO standard recommend

    a maximum of 5% vol.

    Reinforcement o Rigid preformed cageso Wire mesh fabric

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

    77

    78

    Concrete Weight coating

    Type of protection Negative buoyancy + Mechanical protection

    Typical coating thickness Depends on pipe diameter

    Design temperature N/A

    Water depth limit Unlimited

    Major characteristics Density (1900-3700 kg/m3): varies with iron ore quantity.

    6.1. Pipe coating - Systems

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    79

    Concrete Weight Coating (CWC)

    Impingement method

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

    80

    Concrete Weight Coating (CWC)

    Wrap-on method

    Source: Bredero Shaw

    6.1. Pipe coating - Systems

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    81

    6.1. Pipe coating - Systems

    Elastomer coatings (Neoprene, EPDM, butyl rubber, etc.)

    Mainly used for splash zone protection

    Be careful of chamfering can cause failure of

    the bond

    Source: Yadana riser F. Duesso

    82

    APAC Bredero Shaw WASCO Energy

    Americas Bredero Shaw CRC Evans

    EMEA Bredero Shaw Eupec Socotherm Tenaris

    6.1. Pipe coating - Subcontractors

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    83

    Operators - Gap analysis with ISO 21809-1: Microsoft Excel Worksheet

    6.1. Pipe coating - Operators

    84

    Microsoft Excel Worksheet

    Operators - Gap analysis with ISO 21809-1:

    ENI = based on ISO TOTAL SHELL and PETRONAS: more stringent on different tests

    6.1. Pipe coating - Operators

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    85

    HT/HP- R&D programm in different pipe coating applicators and manufacturers

    to test different materials like glass syntactic silicones

    Arctic- Bredero Shaw involved in JIP for new material in arctic conditions

    Flexible weight coating Ultra deep waters thermal insulation

    6.1. Pipe coating Future challenges

    6.2 Field joint coating

    86

    Definition Selection Standards Systems S-Lay installation Subcontractors

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    Field joint definition: Part of pipe left bare for welding prior to installation

    Purpose of FJC: anticorrosion or thermal insulation.

    Field joint is the weak point in a pipe coating system. Welded joints are highly sensitive to corrosion.

    pipe

    3LPP coating

    Cut back length shall be predetermined and mainly depends on type of FJC.

    Properties shall be the same as the parent coating (pipe coating).

    FJC are mostly applied in field application shall be easy, fast and reliable.

    FJC = FBE, HSS, Polyolefin tapes, IMPP, IMPU, PE, PP, liquid resins

    FJC

    6.2. Field joint coatings - Definition

    87

    density, thermal conductivity (if thermal insulation), coating breakdown factor

    Line pipe working conditions

    mechanical protection expected (impact strength, abrasion, compressive strength, flexibility, water absorption, curing time)

    Pipe laying environment

    Parent coating

    Parent coating FJC possibilities

    FBE FBEHeat Shrinkable SleevesLiquid coating

    Polyethylene HSSLiquid coatingPE flame spray

    Polypropylene PP flame spray / tapesIMPUIMPPLiquid coating

    Concrete coating HSS + HDPUF

    6.2. Field joint coatings - Selection

    88

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    6.2. Field joint coatings - Standards

    International standards in field joint coating: ISO 21809

    ISO 21809 - 3

    Other standards or specifications DNV-RP-F102 NACE RP0303 - HSS EN 12068 tapes and HSS

    NO STANDARD FOR INSULATION COATING

    89

    FBECoating system description

    FBE

    Type of protection Corrosion protection

    Typical coating thickness

    350-500 m

    Design temperature 90, modified epoxies can withstand higher temperaturesWater depth limit Unlimited

    Major characteristics - The most widely used coating - Good chemical resistance- Very good corrosion protection - Very common and easy to find subcontractors- Low impact resistance

    Overlap on parent coating

    50 mm

    6.2. Field joint coatings - Systems

    90

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    Heat Shrink Sleeves: 2-layers (mastic HSS)

    Coating system description

    Mastic adhesive + Polyolefin backing on St3 steel

    Type of protection Corrosion protection

    Typical coating thickness

    2 mm

    Design temperature Up to 100 (depending on product: PE or PP)Water depth limit 3000 m

    Major characteristics Manual application with gas torch

    Example of HSS system PE: - KLNN Canusa- WPC 100M (Berry Plastic)PP: - GTS PP 100

    Overlap on parent coating

    100 mm

    6.2. Field joint coatings - Systems

    91

    Heat Shrink Sleeves: 3-layers (hot-melt HSS)

    Coating system description

    Liquid epoxy + hot-melt adhesive + Polyolefin backing on Sa 21/2 steel

    Type of protection Corrosion protectionTypical coating thickness 2 mm

    Design temperature > 100 (depending on product: PE or PP)Water depth limit 3000 mMajor characteristics Manual application with gas torch

    Example of HSS system PE: - GTS 80 (Canusa)- HTLP80 (Berry Plastic)PP: - GTS PP (Canusa)

    Overlap on parent coating

    100 mm

    6.2. Field joint coatings - Systems

    92

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    PP tape wrapCoating system description

    FBE + Adhesive PP + PP tape

    Type of protection Corrosion protectionTypical coating thickness

    3 mm

    Design temperature 110Water depth limit 3000 mMajor characteristics - Applied in spiral or wrapped by hand or by wrapster

    with the determined overlap (50% recommended). - Only compatible with 3LPP pipeline coating

    Example of tape wrap system

    FBE: Scotchkote 226N (3M)Adhesive: Hifax EP 510/60m (Basell)PP tape: Hifax EP 510/60 (Basell)

    Overlap on parent coating

    70 mm

    6.2. Field joint coatings - Systems

    93

    Flame spray PPCoating system description

    FBE + Adhesive PP + PP powder

    Type of protection Corrosion protectionTypical coating thickness

    3 mm

    Design temperature 110Water depth limit 3000 mMajor characteristics Similar to tape wrap

    Overlap on parent coating

    70 mm

    6.2. Field joint coatings - Systems

    94

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    Injection moulded polyurethane (IMPU)Coating system description

    FBE + Solid PU or PU primer + Solid PU

    Type of protection Corrosion protection + thermal insulationTypical coating thickness

    +4 mm

    Design temperature Up to 130Water depth limit 3000 mExample of system FBE: Scotchkote 226N (3M)

    Solid PU: Hyperlast FJ302 (DOW)

    Overlap on parent coating

    70 mm

    6.2. Field joint coatings - Systems

    95

    Injection moulded polypropylene (IMPP)Coating system description

    FBE + PP adhesive + Moulded PP

    Type of protection Corrosion protection + thermal insulationTypical coating thickness

    4-10 mm

    Design temperature Up to 110 (130 with high temp. FBE)Water depth limit 3000 mExample of system FBE: Scotchkote 226N (3M)

    Adhesive: BB 127E (Borealis) or Hifax EP5 10/60 (Basell)Solid PP: EA 165E (Borealis) or CA 197 (Basell)

    Overlap on parent coating

    70 mm

    6.2. Field joint coatings - Systems

    96

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    6.2. Field joint coatings S-lay installation

    S-lay: Firing line is horizontal Pipeline is support by a stinger to avoid high bending stress.

    97

    6.2. Field joint coatings S-lay installation

    98

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    6.2. Field joint coatings Subcontractors

    BrederoShaw

    Canusa CPS

    PIH

    OJS

    FBE, IMPU, IMPP

    HSS, liquid epoxy, tape wrap

    FBE, flame spray PP & PE, HSS, IMPU, IMPP, PU foam infill

    HDPUF, HSS

    99

    100

    Summary

    1. HSE moment

    2. Reason for coating

    3. Corrosion prevention - Generality

    4. Surface preparation

    5. Painting & coating

    6. Pipe & field joint coating

    7. Coating qualification process and requirement

    100

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    7. Coating qualification

    101

    Painting Pipe and field joint coatings

    7. Coating qualification - Painting

    Norsok M501 rev.6

    CS surfaces operating < 120

    Ballast water tanks/ seawater filled vessels

    Anti-slip for walkways, escape routes, lay down areas

    Intumescent epoxy + cementitiousPFP

    Splash zone and immersed surfaces

    1

    3B

    4

    5

    7

    102

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    7. Coating qualification - Painting

    Norsok M501 rev.6

    Test (acc. to ISO 20340) Assessment method Acceptance criteriaSeawater immersion- 4200h- For system 3B, 7A, 7B, 7C and 1 when used in tidal or splash zone

    ISO 4624- pull-off testISO 4628-3,4,5,6

    5MPaNo defect

    Ageing- 4200h- For system 1, 3B, 4, 5A, 5B, 7A

    ISO 4624- pull-off testISO 4628

    5MPaNo defect

    Cathodic disbonding- 4 weeks- For system 3B, 7A, 7B, 7C, 1 whenused in splash or tidal zone

    ISO 15711 Max. 20 mm

    103

    7. Coating qualification

    Shell systems that need to be qualified as per DEP

    TSA (DEP 30.48.40.31)

    DFT checking

    Ballast water tanks/ seawater filled vessels

    Anti-slip for walkways, escape routes, lay down areas

    Intumescent epoxy + cementitiousPFP

    Splash zone and immersed surfaces

    104

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    7. Coating qualification

    Test Assessment method

    Measurement Acceptance criteria

    Visual examination ISO 14918 100% surface Uniform appearance, no defect or blisters

    Coating thickness ISO 2808 Min. 5 Min. 250 m

    Coating adhesion ISO 4624 Min. 3 > 7 MPa

    Overall quality Bend test (DEP) Min. 3 Minor cracks

    Sealer Visual inspection 100% surface No open pores at the surface

    Shell systems that need to be qualified as per DEP - TSA

    Check every step of the ITP. The process leads to qualification of:

    o operators (blasters, sprayers),o equipment,o subcontractor coating procedure.

    Example of PQT done for Prelude FLNGMicrosoft Word

    7 - 2003 DocumenAdobe Acrobat

    Document

    105

    7. Coating qualification Pipe & FJC

    Qualification of 3LPE and 3LPP as per ISO 21809-1: Adobe Acrobat Document

    Properties 3LPE 3LPP

    Continuity Zero defect Zero defect

    Impact strength > 7 J/mm > 10 J/mm

    Indentation at 23 Indentation at max temp.

    < 0.2 mm< 0.4 mm

    < 0.1 mm< 0.4 mm

    Elongation at break > 400 % > 400 %

    Peel strength at 23 Peel strength at max. Temp.

    > 15 N/mm> 3 N/mm

    > 25 N/mm> 4 N/mm

    Cathodic disbondment 23 , 28 dCathodic disbondment 65 , 24 hCathodic disbondment max. temp., 28 d

    < 7 mm< 7 mm< 15 mm

    < 7 mm< 7 mm< 15 mm

    Hot water immersion test (80 , 48h) Average < 2 mm and max. < 3 mm

    Average < 2 mm and max. < 3 mm

    Flexibilitty No cracking at 2 angle No cracking at 2 angle

    Curing of epoxy As per manufacturer As per manufacturer

    106

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    Sources

    Bibliography:

    [1] NACE CIP 1 Manual

    [2] Encyclopedie de la peinture: formuler, fabriquer, appliquer, tome 1

    [3] ISO 8501-1

    [4] ISO 21809-1 to 5

    [5] PPG PFP and Fouling release coating presentation

    Websites:

    [6] www.nace.com

    [7] http://www.corrosion-doctors.org/Seawater/Fouling.htm

    [8] www.brederoshaw.com

    107

    Thank you

    108