cinetica chimica
DESCRIPTION
Cinetica e termodinamica Velocità di reazione Ordine di reazione Reazioni del 1° ordine Meccanismi di reazione Teoria delle collisioni Catalisi. Cinetica chimica. Aspetto cinetico e termodinamico di una reazione. D G° e K eq ci dicono se una reazione avviene spontaneamente - PowerPoint PPT PresentationTRANSCRIPT
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Cinetica chimicaCinetica e termodinamicaVelocit di reazioneOrdine di reazioneReazioni del 1 ordineMeccanismi di reazioneTeoria delle collisioniCatalisi
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Aspetto cinetico e termodinamico di una reazioneDG e Keq ci dicono se una reazione avviene spontaneamente
indispensabile per sapere anche quanto impiega una reazione a raggiungere il proprio stato di equilibrio
Spontaneit e velocit non hanno nessuna correlazione tra loro
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EsempioN2O42NO2 Allequilibrio N2O4 dissociato del 35% Quale la concentrazione delle due specie durante la reazione? E come la scala in funzione del tempo, cosa viene fuori?
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Velocit di ReazioneLa velocit di una reazione riferita alla variazione nel tempo della concentrazione di ciascuno dei reagenti o dei prodottiN2O42NO2
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Velocit di ReazioneLa velocit di una reazione riferita alla variazione nel tempo della concentrazione di ciascuno dei reagenti o dei prodottiN2O42NO2dt-d[N2O4]Vreaz=
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Reazione del 1 ordineN2O42NO2La velocit iniziale dipende SOLO dalla concentrazione del reagente =[N2O4]k
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Reazione del 1 ordineN2O52NO2 +1/2 O2La velocit iniziale dipende SOLO dalla concentrazione del reagente
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Cinetica del 1 ordineN2O52NO2 + O2
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Cinetica del 1 ordinee -ktIn una cinetica del 1 ordine, la variazione della concentrazione segue sempre un andamento ESPONENZIALE.La funzione esponenziale Ae(-kt) ha un andamento ben preciso peculiare
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Cinetica del 1 ordineN2O52NO2 + O2
Grafico1
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Foglio4
Figure 2E
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