cheminform abstract: zn-mediated rhodium-catalyzed α-trifluoromethylation of ketones via silyl enol...

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2008 Halogen compounds Q 0090 Zn-Mediated Rhodium-Catalyzed α-Trifluoromethylation of Ketones via Silyl Enol Ethers. — The reaction is efficiently improved by addition of diethyl zinc allow- ing mild conditions and higher yields of α-CF3 ketones. — (SATO, K.; YUKI, T.; TARUI, A.; OMOTE, M.; KUMADAKI, I.; ANDO*, A.; Tetrahedron Lett. 49 (2008) 22, 3558-3561; Fac. Pharm. Sci., Setsunan Univ., Hirakata, Osaka 573-01, Japan; Eng.) — Mais 36- 063

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Page 1: ChemInform Abstract: Zn-Mediated Rhodium-Catalyzed α-Trifluoromethylation of Ketones via Silyl Enol Ethers

2008

Halogen compoundsQ 0090 Zn-Mediated Rhodium-Catalyzed α-Trifluoromethylation of Ketones via Silyl

Enol Ethers. — The reaction is efficiently improved by addition of diethyl zinc allow-ing mild conditions and higher yields of α-CF3 ketones. — (SATO, K.; YUKI, T.; TARUI, A.; OMOTE, M.; KUMADAKI, I.; ANDO*, A.; Tetrahedron Lett. 49 (2008) 22, 3558-3561; Fac. Pharm. Sci., Setsunan Univ., Hirakata, Osaka 573-01, Japan; Eng.) — Mais

36- 063

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