cheminform abstract: terminal olefin cross-metathesis with acrolein acetals

1999 alkylation, arylation, dealkylation, dearylation, C-acylation, olefination alkylation, arylation, dealkylation, dearylation, C-acylation, olefination O 0280 21 - 064 Terminal Olefin Cross-Metathesis with Acrolein Acetals. — Acrolein acetals undergo cross-metathesis reaction with terminal olefins to give the cor- responding homologation products. Analogous reactions of the ketal (Vb) and the β,γ-unsaturated acetal (IX) do not proceed efficiently. — (O’LEARY, DANIEL J.; BLACKWELL, HELEN E.; WASHENFELDER, REBECCA A.; MIURA, KATSUKIYO; GRUBBS, ROBERT H.; Tetrahedron Lett. 40 (1999) 6, 1091-1094; Arnold and Mabel Beckman Lab. Chem. Synth., Calif. Inst. Technol., Pasadena, CA 91125, USA; EN) 1

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Page 1: ChemInform Abstract: Terminal Olefin Cross-Metathesis with Acrolein Acetals

1999 alkylation, arylation, dealkylation, dearylation, C-acylation, olefination

alkylation, arylation, dealkylation, dearylation, C-acylation, olefinationO 0280

21 - 064Terminal Olefin Cross-Metathesis with Acrolein Acetals. — Acroleinacetals undergo cross-metathesis reaction with terminal olefins to give the cor-responding homologation products. Analogous reactions of the ketal (Vb) andthe β,γ-unsaturated acetal (IX) do not proceed efficiently. — (O’LEARY,DANIEL J.; BLACKWELL, HELEN E.; WASHENFELDER, REBECCA A.;MIURA, KATSUKIYO; GRUBBS, ROBERT H.; Tetrahedron Lett. 40 (1999)6, 1091-1094; Arnold and Mabel Beckman Lab. Chem. Synth., Calif. Inst.Technol., Pasadena, CA 91125, USA; EN)

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