cheminform abstract: synthesis of 1-phosphono-2-aza-1,3-dienes and their conversion into...

1999 organo-phosphorus compounds, acyclic C derivatives organo-phosphorus compounds, acyclic C derivatives S 0082 29 - 165 Synthesis of 1-Phosphono-2-aza-1,3-dienes and Their Conversion into 1-Vinyl-2-phosphonoaziridines. — 1,4-Dehydrochlorination of N-(phosphonomethyl)-α-chloroimines (IV) gives good yields of the new title compounds (V). They react smoothly with diazomethane to give 1-vinyl- 2-phosphonoaziridines, potential building blocks for further azaheterocyclic phosphonates. — (STEVENS, CHRISTIAN; GALLANT, MARC; DE KIMPE, NORBERT; Tetrahedron Lett. 40 (1999) 17, 3457-3460; Dep. Org. Chem., Fac. Agric. Appl. Biol. Sci., Univ. Gent, B-9000 Gent, Belg.; EN) 1

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Page 1: ChemInform Abstract: Synthesis of 1-Phosphono-2-aza-1,3-dienes and Their Conversion into 1-Vinyl-2-phosphonoaziridines

1999 organo-phosphorus compounds, acyclic C derivatives

organo-phosphorus compounds, acyclic C derivativesS 0082

29 - 165Synthesis of 1-Phosphono-2-aza-1,3-dienes and Their Conversioninto 1-Vinyl-2-phosphonoaziridines. — 1,4-Dehydrochlorination ofN-(phosphonomethyl)-α-chloroimines (IV) gives good yields of the new titlecompounds (V). They react smoothly with diazomethane to give 1-vinyl-2-phosphonoaziridines, potential building blocks for further azaheterocyclicphosphonates. — (STEVENS, CHRISTIAN; GALLANT, MARC; DE KIMPE,NORBERT; Tetrahedron Lett. 40 (1999) 17, 3457-3460; Dep. Org. Chem., Fac.Agric. Appl. Biol. Sci., Univ. Gent, B-9000 Gent, Belg.; EN)

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