cheminform abstract: synthesis and characterization of fluorescent polyoxometalate nano-/microrods

ChemInform 2010, 41, issue 31 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Tungsten I 5700 DOI: 10.1002/chin.201031019 Synthesis and Characterization of Fluorescent Polyoxometalate Nano-/Micro- rods. — Crystalline rods of K4H[Eu(α-SiW11O39)(H2O)2]·17H2O are prepared from an aqueous solution of K8[α-SiW11O39] and Eu(NO3)3 (pH 1, 80 °C, 15 min). The samples are characterized by FTIR, UV/VIS, and ESEM-FEG. Their average ratio of diameter to length is 1:20. They exhibit a regular profile and intense fluorescence, and thus may be used as potential one-dimensional fluorescent materials. — (SHEN, Y.; PENG*, J.; CHEN, C.; CHEN, D.; ZHANG, H.; MENG, C.; Z. Naturforsch., B: Chem. Sci. 65 (2010) 5, 603-606; Key Lab. Polyoxometalates Sci. Min. Educ., Northeast Norm. Univ., Changchun 130024, Peop. Rep. China; Eng.) — W. Pewestorf 31- 019

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Page 1: ChemInform Abstract: Synthesis and Characterization of Fluorescent Polyoxometalate Nano-/Microrods

www.cheminform.wiley-vch.de

TungstenI 5700 DOI: 10.1002/chin.201031019

Synthesis and Characterization of Fluorescent Polyoxometalate Nano-/Micro-rods. — Crystalline rods of K4H[Eu(α-SiW11O39)(H2O)2]·17H2O are prepared from an aqueous solution of K8[α-SiW11O39] and Eu(NO3)3 (pH 1, 80 °C, 15 min). The samples are characterized by FTIR, UV/VIS, and ESEM-FEG. Their average ratio of diameter to length is 1:20. They exhibit a regular profile and intense fluorescence, and thus may be used as potential one-dimensional fluorescent materials. — (SHEN, Y.; PENG*, J.; CHEN, C.; CHEN, D.; ZHANG, H.; MENG, C.; Z. Naturforsch., B: Chem. Sci. 65 (2010) 5, 603-606; Key Lab. Polyoxometalates Sci. Min. Educ., Northeast Norm. Univ., Changchun 130024, Peop. Rep. China; Eng.) — W. Pewestorf

31- 019

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