cheminform abstract: stereoselective synthesis of isoxazolinobenzoxepanes via intramolecular nitrile...

ChemInform 2012, 43, issue 09 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Multi-membered O,S-heterocycles R 0691 DOI: 10.1002/chin.201209188 Stereoselective Synthesis of Isoxazolinobenzoxepanes via Intramolecular Nitrile Oxide Cycloaddition. — Optimized conditions are developed to generate nitrile ox- ides from indole-tethered nitroalkanes of type (III). The cycloaddition proceeds with excellent trans-selectivity. — (RAMACHANDIRAN, K.; KARTHIKEYAN, K.; NANDHAKUMAR, T.; MURALIDHARAN, D.; PERUMAL*, P. T.; Synthesis 2011, 20, 3277-3286, http://dx.doi.org/10.1055/s-0030-1260201 ; Org. Chem. Div., Central Leather Res. Inst., Adyar, Chennai 600 020, India; Eng.) — Mais 09- 188

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Page 1: ChemInform Abstract: Stereoselective Synthesis of Isoxazolinobenzoxepanes via Intramolecular Nitrile Oxide Cycloaddition

Multi-membered O,S-heterocyclesR 0691 DOI: 10.1002/chin.201209188

Stereoselective Synthesis of Isoxazolinobenzoxepanes via Intramolecular Nitrile Oxide Cycloaddition. — Optimized conditions are developed to generate nitrile ox-ides from indole-tethered nitroalkanes of type (III). The cycloaddition proceeds with excellent trans-selectivity. — (RAMACHANDIRAN, K.; KARTHIKEYAN, K.; NANDHAKUMAR, T.; MURALIDHARAN, D.; PERUMAL*, P. T.; Synthesis 2011, 20, 3277-3286, http://dx.doi.org/10.1055/s-0030-1260201 ; Org. Chem. Div., Central Leather Res. Inst., Adyar, Chennai 600 020, India; Eng.) — Mais

09- 188

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