cheminform abstract: room-temperature synthesis of bismuth clusters in ionic liquids and crystal...
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BismuthI 5400 Room-Temperature Synthesis of Bismuth Clusters in Ionic Liquids and Crystal
Growth of Bi5(AlCl4)3. — Dark-red crystals of Bi5(AlCl4)3 are prepared by reaction of BiCl3 and Bi metal in a [bmim]Cl/AlCl3 (1:1.3) ionic liquid at 298 K and characterized by XRD and Raman spectroscopy. The compound crystallizes in the rhombohedral space group R3c with Z = 6. The use of ionic liquids for the preparation of Bi polyca-tions is fast, convenient, environmentally friendly and avoids the use of toxic organic and inorganic substances. — (AHMED, E.; KOEHLER, D.; RUCK*, M.; Z. Anorg. Allg. Chem. 635 (2009) 2, 297-300; Inst. Anorg. Chem., TU Dresden, D-01069 Dresden, Germany; Eng.) — W. Pewestorf
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ChemInform 2009, 40, issue 16 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim