cheminform abstract: preparation and structures of salts with the anions of if-2, cif-4, if- 4,...
TRANSCRIPT
1997 structure
structure (solids and liquids)D 2000
24 - 014Preparation and Structures of Salts with the Anions of IF-2, CIF-4,IF- 4, TeF-7, and AsF-4. — Single crystal structures are presentedfor the title anions precipitated as 1,1,3,3,5,5-hexamethylpiperidinium (pip+)salts. Precise structural data for these ions are obtained for the first timeand confirm the expected geometries. The pip+ cation has the advantage ofyielding good crystallinity, avoiding crystal twinning, and resulting in weakcation-anion interactions. pip+ IF-2 crystallizes in the monoclinic space groupP21/c with Z = 4; pip+ClF-4 is tetragonal, I41cd, Z = 16; (pip+)2IF-4H2F-3is monoclinic, P21/n, Z = 4; pip+AsF-4 is also monoclinic, P21/c, Z = 4; andpip+TeF-7 belongs to the triclinic space group P1 with Z = 2. — (ZHANG,X.; SEPPELT, K.; Z. Anorg. Allg. Chem. 623 (1997) 4, 491-500; Inst. Anorg.Anal. Chem., FU Berlin, D-14195 Berlin, Germany; EN)
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