cheminform abstract: competition studies in alkyne electrophilic cyclization reactions

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ChemInform 2009, 40, issue 24 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Ring closure reactions O 0130 Competition Studies in Alkyne Electrophilic Cyclization Reactions. — The out- come concerning the ring closure of diarylalkynes is dependent on several factors. The nucleophilicity of competing functional groups, steric nature of substituents, polariza- tion of the alkyne bond, and cationic nature of the intermediates play an important role. — (MEHTA, S.; WALDO, J. P.; LAROCK*, R. C.; J. Org. Chem. 74 (2009) 3, 1141-1147; Dep. Chem., Iowa State Univ., Ames, IA 50011, USA; Eng.) — Jannicke 24- 026

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www.cheminform.wiley-vch.de

Ring closure reactionsO 0130 Competition Studies in Alkyne Electrophilic Cyclization Reactions. — The out-

come concerning the ring closure of diarylalkynes is dependent on several factors. The nucleophilicity of competing functional groups, steric nature of substituents, polariza-tion of the alkyne bond, and cationic nature of the intermediates play an important role. — (MEHTA, S.; WALDO, J. P.; LAROCK*, R. C.; J. Org. Chem. 74 (2009) 3, 1141-1147; Dep. Chem., Iowa State Univ., Ames, IA 50011, USA; Eng.) — Jannicke

24- 026

ChemInform 2009, 40, issue 24 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

www.cheminform.wiley-vch.de

ChemInform 2009, 40, issue 24 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim