cheminform abstract: a new stereospecific synthesis of unusual (z)-β-branched baylis—hillman...

1998 addition reactions addition reactions O 0060 36 - 070 A New Stereospeciﬁc Synthesis of Unusual (Z)-β-Branched Baylis– Hillman Adducts. — The novel synthesis of unusual (Z)-β-branched Baylis–Hillman adducts involves formation of anionic β-substituted [α- (alkoxycarbonyl)vinyl]aluminum intermediates and their Bu 2 B-OTf-catalyzed coupling with carbonyl compounds. — (LI, G.; WEI, H.-X.; WILLIS, S.; Tetrahedron Lett. 39 (1998) 26, 4607-4610; Dep. Chem. Biochem., Tex. Tech. Univ., Lubbock, TX 79409, USA; EN) 1

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Page 1: ChemInform Abstract: A New Stereospecific Synthesis of Unusual (Z)-β-Branched Baylis—Hillman Adducts

1998 addition reactions

addition reactionsO 0060

36 - 070A New Stereospecific Synthesis of Unusual (Z)-β-Branched Baylis–Hillman Adducts. — The novel synthesis of unusual (Z)-β-branchedBaylis–Hillman adducts involves formation of anionic β-substituted [α-(alkoxycarbonyl)vinyl]aluminum intermediates and their Bu2B-OTf-catalyzedcoupling with carbonyl compounds. — (LI, G.; WEI, H.-X.; WILLIS, S.;Tetrahedron Lett. 39 (1998) 26, 4607-4610; Dep. Chem. Biochem., Tex. Tech.Univ., Lubbock, TX 79409, USA; EN)

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