Equations and constants that you may need G = H - TS Greaction = Gº + RT ln Q Gº = -RT ln KeqEº = -Gº/nF Farday's constant = 96,485 J.V-1mol-1, gas constant R = 8.315 J.mol-1K-1 pH = pKa + log [conjugate base]/[weak acid]

amino acid pKaAsp 4.0Glu 4.0His 7.0Cys 8.3Tyr 10.9Lys 10.5Arg 12.5Ser 13.0Thr 13.0

N-term. 9.0C-term. 2.0

G A P

VL I

F YW

K

MT N Q

H

C S D E

R

CHEM 527 Final Handout

Glycogen

Glucose-1-P

Glucose-6-P

Glycogen phosphorylase

phosphoglucomutase

akacomplex II of ETC

Coenzyme-Aas thiolester in succinyl-CoA

FAD and FADH2

Q

QH2 NAD+ and NADH

+

FMN – remove AMP

Coenzymes

-oxidation of fatty acids

ETF – electron transferring flavoprotein

Fatty acid + CoA-SHC16 - palmitoyl

ATPAMP +PPi

To transport fats in mitochondria:acyl-CoA synthetase, which requires 2 ATP equiv. to make acyl-CoA

Acyl carnitine translocase gets acyl-CoAs into the matrix

To transition from glycolysis to the citric acid cycle:

CHEM 527Electron Transport & Oxidative Phosphorylation

RNA DNA

The Genetic Code for Protein Translation