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34
Lecture Presentation Chapter 4 General, Organic, and Biological Chemistry: Structures of Life, 5/e Karen C. Timberlake © 2016 Pearson Education, Inc. 4.1 – Elements and Symbols 4.2 – The Periodic Table 4.3 – The Atom 4.4 – Atomic Number and Mass Number 4.5 – Isotopes and Atomic Mass 4.6 – Electron Energy Levels 4.7 – Electron Configurations 4.8 – Trends in Periodic Properties Goal : Given its name, write its correct symbol; from the symbol. Write the correct name. General, Organic, and Biological Chemistry: Structures of Life, 5/e Karen C. Timberlake © 2016 Pearson Education, Inc. Elements: are pure substances from which all other things are built. are listed on the periodic table.

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Lect

ure

Pres

enta

tion

Chap

ter

4

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

es

Goa

l : G

iven

its

nam

e, w

rite

its

corr

ect

sym

bol;

fro

m t

he

sym

bol.

Wri

te t

he c

orre

ct n

ame.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Elem

ents

:

are

pure

sub

stan

ces

from

whi

ch a

ll ot

her

thin

gs a

re b

uilt

.

are

liste

d on

the

pe

riod

ic t

able

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Elem

ent

nam

es c

ome

from

pla

nets

, m

ytho

logi

cal f

igur

es,

min

eral

s, c

olor

s, g

eogr

aphi

c lo

cati

ons,

and

fam

ous

peop

le.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Chem

ical

sym

bols

•re

pres

ent

the

nam

es o

f th

eel

emen

ts.

•co

nsis

t of

one

to

two

lett

ers

and

star

t w

ith

a ca

pita

l let

ter.

One

-Let

ter

Sym

bols

Two-

Lett

er S

ymbo

lsC

carb

on

Coco

balt

Nni

trog

enCa

calc

ium

Ffl

uori

ne

Alal

umin

um

O

oxyg

en

M

gm

agne

sium

Carb

on,

C

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Wri

te t

he c

orre

ct c

hem

ical

sym

bols

for

eac

h of

the

fol

low

ing

elem

ents

:

A. i

odin

e

B. i

ron

C. m

agne

sium

D. z

inc

E. n

itro

gen

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Giv

e th

e na

mes

of

the

elem

ents

wit

h th

e fo

llow

ing

sym

bols

:

A. P

B. A

l

C. M

n

D. H

E. K

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Mer

cury

(H

g)Is

a s

ilver

y, s

hiny

ele

men

t th

at is

liqu

id a

t ro

om

tem

pera

ture

.

Can

ente

r th

e bo

dy b

y:m

ercu

ry v

apor

inha

lati

onco

ntac

t w

ith

the

skin

inge

stio

n of

wat

er o

r fo

od c

onta

min

ated

wit

h m

ercu

ry

Onc

e m

ercu

ry h

as e

nter

ed t

he b

ody,

it d

estr

oys

prot

eins

, di

srup

ts c

ell f

unct

ion.

Lon

g-te

rm e

xpos

ure

can Da

mag

e th

e br

ain

and

kidn

eys

Caus

e m

enta

l ret

arda

tion

Decr

ease

phy

sica

l dev

elop

men

t

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Mer

cury

con

tam

inat

ion

com

es f

rom

•in

dust

rial

was

tes.

•fi

sh a

nd s

eafo

od.

•ba

tter

ies.

•co

mpa

ct f

luor

esce

nt b

ulbs

.

Fish

abs

orb

mer

cury

.Bi

g fi

sh e

at lo

ts o

f sm

all f

ish,

end

up

wit

h m

ore

mer

cury

.G

ener

al, O

rgan

ic, a

nd B

iolo

gica

l Che

mis

try: S

truct

ures

of L

ife, 5

/eKa

ren

C. T

imbe

rlake

© 2

016

Pear

son

Educ

atio

n, In

c.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

es

Goa

l : U

se t

he p

erio

dic

tabl

e to

iden

tify

the

gro

up a

nd

the

peri

od o

f an

ele

men

t; id

enti

fy t

he e

lem

ent

as a

m

etal

, a

nonm

etal

, or

a m

etal

loid

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Th

e P

erio

dic

Tab

le

The

peri

odic

tab

le

orga

nize

s 11

8 el

emen

ts

into

gro

ups

wit

h si

mila

r pr

oper

ties

and

pl

aces

the

m in

ord

er o

f in

crea

sing

ato

mic

m

ass.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gro

up

s an

d P

erio

ds

In t

he p

erio

dic

tabl

e,

elem

ents

are

arr

ange

d ac

cord

ing

to p

rope

rtie

s.

Vert

ical

col

umns

re

pres

ent

grou

psof

el

emen

ts

and

hori

zont

al r

ows

repr

esen

t pe

riod

s.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gro

up

s an

d P

erio

ds

Gro

up n

umbe

rs a

re w

ritt

en a

t th

e to

p of

eac

h ve

rtic

al c

olum

n (1

-18)

.

Peri

ods

are

num

bere

d 1-

7

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Met

als,

Non

met

als,

an

d M

etal

loid

s

The

heav

y zi

gzag

line

sep

arat

es m

etal

s an

d no

nmet

als.

•M

etal

sar

e lo

cate

d to

the

left

.•N

onm

etal

sar

e lo

cate

d to

the

rig

ht.

•M

etal

loid

sar

e lo

cate

d al

ong

the

heav

y zi

gzag

line

.

Met

als

Solid

at

room

tem

pEx

cept

ion:

mer

cury

Shin

y!Du

ctile

(sh

aped

into

w

ires

)M

alle

able

(ha

mm

ered

fl

at in

to s

heet

s)G

ood

cond

ucto

rsH

igh

mel

ting

poi

nts

Non

met

als

Dull

(not

shi

ny

)

brit

tle

Not

duc

tile

Not

mal

leab

le

Poor

con

duct

ors

Low

mel

ting

poi

nts

Low

den

siti

es (

man

y ar

e ga

sses

at

room

tem

p.)

Silv

er(M

etal

)

Anti

mon

y(m

etal

loid

)

Sulf

ur(n

onm

etal

)

Met

allo

ids

have

a c

ombi

nati

on o

f m

etal

and

non

met

al p

rope

rtie

s.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ch

arac

teri

stic

s of

Met

allo

ids

Met

allo

ids,

loca

ted

alon

g th

e he

avy

zigz

ag li

ne o

n th

e pe

riod

ic

tabl

eex

hibi

t pr

oper

ties

of

met

als

and

nonm

etal

s.•

are

bett

er c

ondu

ctor

s th

an

nonm

etal

s bu

t no

t as

goo

d as

m

etal

s.•

are

used

as

sem

icon

duct

ors

and

insu

lato

rs,

beca

use

they

ca

n be

mod

ifie

d to

fun

ctio

n as

co

nduc

tors

or

insu

lato

rs.

Silv

er(M

etal

)

Anti

mon

y(m

etal

loid

)

Sulf

ur(n

onm

etal

)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Iden

tify

eac

h of

the

fol

low

ing

elem

ents

as

a m

etal

, a

nonm

etal

, or

a m

etal

loid

:A.

sodi

umB.

chlo

rine

C.si

licon

D.

iron

E.ca

rbon

Stu

dy

Ch

eck

List

all

of t

he e

lem

ents

tha

t m

atch

the

de

scri

ptio

n.

A.m

etal

s in

Gro

up 1

4

Sn,

Pb,

C, S

i, G

e

B.no

nmet

als

in G

roup

15

Bi,

N,

P, A

s, S

b

C.m

etal

loid

s in

Gro

up 1

4

C, S

i, G

e, S

n, P

b

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gro

up

Nam

es

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Alk

ali M

etal

s

Gro

up 1

,th

e al

kali

met

als,

incl

udes

the

fo

llow

ing:

•lit

hium

(Li

) •so

dium

(N

a)•po

tass

ium

(K)

•ru

bidi

um (

Rb)

•ce

sium

(Cs

)•Fr

anci

um (

Fr)

Soft

Shin

y

Goo

d co

nduc

tors

Low

mel

ting

po

ints

Reac

t vi

goro

usly

wit

h w

ater

!

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Alk

alin

e E

arth

Met

als

Gro

up 2

elem

ents

,th

e al

kalin

e ea

rth

met

als,

are

shi

ny b

ut n

ot a

s re

acti

ve a

s G

roup

1A

met

als.

The

y in

clud

e th

e fo

llow

ing:

•be

rylli

um (

Be)

•m

agne

sium

(M

g)•ca

lciu

m (

Ca)

•st

ront

ium

(Sr

)•ba

rium

(Ba

)•ra

dium

(Ra

)

Stro

ntiu

m g

ives

the

red

col

or in

fi

rew

orks

. G

ener

al, O

rgan

ic, a

nd B

iolo

gica

l Che

mis

try: S

truct

ures

of L

ife, 5

/eKa

ren

C. T

imbe

rlake

© 2

016

Pear

son

Educ

atio

n, In

c.

Hal

ogen

s

Gro

up 1

7,th

e ha

loge

ns,

incl

udes

the

fol

low

ing:

•fl

uori

ne (

F)•ch

lori

ne (

Cl)

•br

omin

e (B

r)•io

dine

(I)

•as

tati

ne (

At)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Nob

le G

ases

Gro

up 1

8,th

e no

ble

gase

s, in

clud

e:

Hel

ium

(H

e)

Neo

n (N

e)

Argo

n (A

r)

Kryp

ton

(Kr)

Xeno

n (X

e)

Rado

n (R

n)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Iden

tify

the

ele

men

t de

scri

bed

by e

ach

of t

he f

ollo

win

g gr

oups

and

per

iods

:

1. G

roup

17,

Per

iod

4

2. G

roup

2,

Peri

od 3

3. G

roup

15,

Per

iod

2

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

FY

I: E

lem

ents

Ess

enti

al t

o H

ealt

h

Of

all t

he e

lem

ents

, 23

are

ess

enti

al f

or t

he w

ell-

bein

g an

d su

rviv

al o

f th

e hu

man

bod

y.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

es

Goa

l : D

escr

ibe

the

elec

tric

al c

harg

e an

d lo

cati

on in

an

atom

for

a p

roto

n, a

neu

tron

, an

d an

ele

ctro

n

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

An a

tom

is th

e sm

alle

st

parti

cle

of a

n el

emen

t tha

t re

tain

s th

e ch

arac

teris

tics

of th

at e

lem

ent.

Alum

inum

foil

cont

ains

at

oms

of a

lum

inum

.

The

Ato

m

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Atom

s co

ntai

n th

e fo

llow

ing

suba

tom

ic p

artic

les:

•Pr

oton

s

•N

eutr

ons

•El

ectr

ons

Ato

ms

are

mad

e of

sub

atom

ic p

artic

les

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Atom

s co

ntai

n th

e fo

llow

ing

suba

tom

ic p

artic

les:

Ato

ms

are

mad

e of

sub

atom

ic p

artic

les

•pr

oton

sha

ve a

pos

itive

(+) c

harg

e

•ne

utro

nsha

ve n

o ch

arge

(neu

tral)

•el

ectr

ons

have

a n

egat

ive

(-) c

harg

e

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

An a

tom

cons

ists

of

a nu

cleu

s, lo

cate

d in

the

cent

er o

f the

ato

m, t

hat c

onta

ins

prot

ons

and

neut

rons

and

repr

esen

ts m

ost o

f the

mas

s of

an

atom

.el

ectr

ons

that

occ

upy

a la

rge,

em

pty

spac

e ar

ound

the

nucl

eus.

Stru

ctur

e of

the

Ato

m

Prot

ons –

posi

tive

char

geN

eutro

ns –

neut

ral

Elec

trons

–ne

gativ

e ch

arge

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stru

ctur

e of

the

Ato

m

In a

n at

om, t

he p

roto

ns a

nd n

eutro

ns th

at m

ake

up a

lmos

t all

the

mas

s ar

e pa

cked

into

the

tiny

volu

me

of th

e nu

cleu

s. T

he ra

pidl

y m

ovin

g el

ectro

ns

(neg

ativ

e ch

arge

) sur

roun

d th

e nu

cleu

s an

d ac

coun

t for

the

larg

e vo

lum

e of

the

atom

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

In D

alto

ns

atom

ic th

eory

, ato

ms

•ar

e tin

y pa

rticl

es o

f mat

ter.

•of

an

elem

ent a

re s

imila

r to

each

oth

er a

nd d

iffer

ent

from

thos

e of

oth

er e

lem

ents

.•

of tw

o or

mor

e di

ffere

nt e

lem

ents

com

bine

to fo

rm

com

poun

ds.

•ar

e re

arra

nged

to fo

rm n

ew c

ombi

natio

ns in

a

chem

ical

reac

tion.

Atom

s ar

e ne

ver c

reat

ed o

r des

troye

d du

ring

a ch

emic

al

reac

tion.

Dal

ton’

s A

tom

ic T

heor

y

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Beca

use

the

mas

s of

sub

atom

ic p

artic

les

are

so s

mal

l,

•che

mis

ts u

se a

ver

y sm

all u

nit o

f mas

s ca

lled

the

atom

ic

mas

s un

it (a

mu)

.

•1 a

mu

has

a m

ass

equa

l to

1/12

of t

he m

ass

of th

e ca

rbon

- 12

atom

that

con

tain

s si

x pr

oton

s an

d si

x ne

utro

ns.

•1 a

mu

= 1

Dal

ton

(Da)

in b

iolo

gy.

•1am

u=

1.66

x 1

0-27

kg•E

lect

rons

hav

e su

ch a

sm

all m

ass

that

they

are

not

incl

uded

in

the

mas

s of

an

atom

.

Mas

s of

the

Ato

m

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

If a

pro

ton

has

a m

ass

of 1

.67

x 10

-27

kg,

wha

t is

its

mas

s in

am

u?

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Prot

ons

and

neut

rons

hav

e a

very

sm

all m

ass.

El

ectro

ns a

re 1

800

times

sm

alle

r tha

n pr

oton

s an

d ne

utro

ns.

Suba

tom

ic P

artic

les

in th

e A

tom

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Whi

ch o

f the

follo

win

g su

bato

mic

par

ticle

s fit

s ea

ch o

f the

de

scrip

tions

bel

ow?

prot

ons,

neu

trons

, or e

lect

rons

A. f

ound

out

side

the

nucl

eus

B. h

ave

a po

sitiv

e ch

arge

C.

have

mas

s bu

t no

char

ge

Stud

y C

heck

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

es

Goa

l : G

iven

the

ato

mic

num

ber

and

the

mas

s nu

mbe

r of

an

ato

m,

stat

e th

e nu

mbe

r of

pro

tons

, ne

utro

ns,

and

elec

tron

s.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Nu

mb

er

Each

ele

men

t is

ass

igne

d an

ato

mic

num

ber.

The

atom

ic n

umbe

r is

equ

al t

o th

e nu

mbe

r of

pr

oton

s in

an

atom

(an

d is

alw

ays

a w

hole

num

ber)

.•

The

sam

e fo

r al

l ato

ms

of a

n el

emen

t•

Appe

ars

abov

e th

e sy

mbo

l of

an e

lem

ent

in t

he

peri

odic

tab

le.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Nu

mbe

r -e

xam

ple

s

Atom

ic n

umbe

r =

num

ber

of p

roto

ns

the

atom

ic n

umbe

r of

H is

1;

ever

y H

ato

m h

as o

ne p

roto

n.

the

atom

ic n

umbe

r of

C is

6;

ever

y C

atom

has

six

pro

tons

.

the

atom

ic n

umbe

r of

Cu

is 2

9; e

very

Cu

atom

has

29

prot

ons.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Nu

mbe

r -e

xam

ple

All a

tom

s of

lith

ium

(le

ft)

cont

ain

thre

e pr

oton

s, a

nd a

ll at

oms

of c

arbo

n (r

ight

) co

ntai

n si

x pr

oton

s.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

ms

are

Neu

tral

For

neut

ral a

tom

s, t

he n

et c

harg

e is

zer

o.

num

ber

of p

roto

ns =

num

ber

of e

lect

rons

Alum

inum

has

13

prot

ons

and

13 e

lect

rons

. Th

e ne

t (o

vera

ll)ch

arge

is z

ero.

13 p

roto

ns (

13+)

+

13

elec

tron

s (1

3–)

= 0

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Use

the

per

iodi

c ta

ble

to f

ill in

the

ato

mic

num

ber,

num

ber

of p

roto

ns,

and

num

ber

of e

lect

rons

for

eac

h of

the

fol

low

ing

elem

ents

:El

emen

tA

tom

ic

Num

ber

Prot

ons

Elec

tron

s

N Zn S

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Mas

s N

um

ber

The

mas

s nu

mbe

r

•re

pres

ents

the

num

ber

of p

arti

cles

in t

he n

ucle

us.

•is

equ

al t

o th

e nu

mbe

r of

pro

tons

+ t

he n

umbe

r of

neu

tron

s.

•is

alw

ays

a w

hole

num

ber.

•do

es n

ot a

ppea

r in

the

per

iodi

c ta

ble.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Tip

s

Num

ber

of p

roto

ns =

ato

mic

num

ber

Num

ber

of p

roto

ns +

neu

tron

s =

mas

s nu

mbe

r

Num

ber

ofne

utro

ns =

mas

s nu

mbe

r –

atom

ic n

umbe

r

Char

ge o

f at

om =

Num

ber

of e

lect

rons

+ N

umbe

r of

pro

tons

Num

ber

of e

lect

rons

= c

harg

e –

num

ber

of p

roto

ns

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

An a

tom

of

lead

(Pb

) ha

s a

mas

s nu

mbe

r of

207

.

A. H

ow m

any

prot

ons

are

in t

he n

ucle

us?

B. H

ow m

any

neut

rons

are

in t

he n

ucle

us?

C. H

ow m

any

elec

tron

s ar

e in

the

ato

m?

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

An a

tom

of

tita

nium

(Ti

) ha

s a

mas

s nu

mbe

r of

44.

A. H

ow m

any

prot

ons

are

in t

he n

ucle

us?

B. H

ow m

any

neut

rons

are

in t

he n

ucle

us?

C. H

ow m

any

elec

tron

s ar

e in

the

ato

m?

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

esG

oal :

Det

erm

ine

the

num

ber

or p

roto

ns,

elec

tron

s, a

nd

neut

rons

in o

ne o

r m

ore

of t

he is

otop

es o

f an

ele

men

t;

calc

ulat

e th

e at

omic

mas

s of

an

elem

ent

usin

g th

e pe

rcen

t ab

unda

nce

and

mas

s of

its

natu

rally

occ

urri

ng is

otop

es.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Isot

opes

Isot

opes

•ar

e at

oms

of t

he s

ame

elem

ent.

•ha

ve t

he s

ame

num

ber

of p

roto

ns b

ut d

iffe

rent

num

bers

of

neu

tron

s.•

(dif

fere

nt m

ass

num

bers

)

•ca

n be

dis

ting

uish

ed b

y th

eir

atom

ic s

ymbo

ls.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Sym

bols

: Su

bato

mic

Par

ticl

es

Giv

en t

he a

tom

ic s

ymbo

ls,

dete

rmin

e th

e nu

mbe

r of

pr

oton

s, n

eutr

ons,

and

ele

ctro

ns.

816O

P31 15

3065Zn

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Nat

ural

ly o

ccur

ring

car

bon

cons

ists

of

thre

e is

otop

es:

12C,

13

C, a

nd 1

4 C.

Stat

e th

e nu

mbe

r of

pro

tons

, ne

utro

ns,

and

elec

tron

s in

eac

h of

the

thr

ee is

otop

es.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Wri

te t

he a

tom

ic s

ymbo

ls f

or a

tom

s w

ith

the

follo

win

g su

bato

mic

par

ticl

es:

A. 8

pro

tons

8

neu

tron

s

8 e

lect

rons

B. 1

7 pr

oton

s 2

0 ne

utro

ns

17 e

lect

rons

C. 4

7 pr

oton

s 6

0 ne

utro

ns

47 e

lect

rons

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

1.W

hich

of

the

pair

s be

low

are

isot

opes

of

the

sam

e el

emen

t?

815X

715X

612X

614X

715X

816X

2.W

hich

of

the

pair

s be

low

hav

e th

e sa

me

num

ber

of n

eutr

ons?

AB

C

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Nat

ura

lly

Occ

urr

ing

Isot

opes

Mos

t el

emen

ts h

ave

seve

ral

isot

opes

tha

t oc

cur

in n

atur

e (v

s. m

ade

in a

lab.

)

Thes

e is

otop

es a

re c

alle

d “n

atur

ally

occ

urri

ng.”

Chlo

rine

has

3 is

otop

es:

35Cl

36 C

l 37 C

l

Onl

y 35

Cl a

nd 3

7 Cl h

appe

n na

tura

lly.

36Cl

has

to

be m

ade

in a

lab.

So c

hlor

ine

has

2 na

tura

lly o

ccur

ring

isot

opes

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Mas

s

Ato

mic

mas

sis

the

wei

ghte

d av

erag

e of

all

natu

rally

occ

urri

ng

isot

opes

of

that

ele

men

t.

num

ber

on t

he p

erio

dic

tabl

e be

low

the

che

mic

al

sym

bol.

Chlo

rine

, w

ith

two

natu

rally

occ

urri

ng

isot

opes

, ha

s an

ato

mic

mas

s of

35.

45

amu.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Isot

opes

of

Mag

nes

ium

Mag

nesi

um,

wit

h th

ree

natu

rally

occ

urri

ng

isot

opes

, ha

s an

ato

mic

m

ass

of 2

4.31

am

u.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Isot

opes

of

Mag

nes

ium

Mag

nesi

um’s

ato

mic

mas

s: 2

4.31

am

u.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Mas

s of

Som

e E

lem

ents

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Cal

cula

tin

g A

tom

ic M

ass

To c

alcu

late

ato

mic

mas

s,

use

the

expe

rim

enta

l per

cent

abu

ndan

ce o

f ea

ch is

otop

e of

th

e el

emen

t.

mul

tipl

y th

e pe

rcen

t ab

unda

nce

(div

ided

by

100)

by

the

atom

ic m

ass

of t

hat

isot

ope.

sum

the

tot

al m

ass

of a

ll is

otop

es.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Cal

cula

tin

g A

tom

ic M

ass

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Gal

lium

is a

n el

emen

t fo

und

in la

sers

use

d in

CD

play

ers.

In

a sa

mpl

e of

gal

lium

, th

ere

is

60.1

0% o

f 69

Ga

atom

s (a

tom

ic m

ass

68.9

26)

39.9

0% o

f 71

Ga

atom

s (a

tom

ic m

ass

70.9

25)

Wha

t is

the

ato

mic

mas

s of

gal

lium

?

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

esG

oal:

Des

crib

e th

e en

ergy

leve

ls,

subl

evel

s, a

nd

orbi

tals

for

the

ele

ctro

ns in

an

atom

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

mag

net

ic R

adia

tion

We

expe

rien

ce e

lect

rom

agne

tic

radi

atio

n in

dif

fere

nt

form

s, s

uch

as li

ght,

the

col

ors

of a

rai

nbow

, or

X-r

ays.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

mag

net

ic R

adia

tion

Ligh

t an

d ot

her

elec

trom

agne

tic

radi

atio

n co

nsis

ts o

f en

ergy

part

icle

s th

at m

ove

as w

aves

of e

nerg

y.•

The

dist

ance

bet

wee

n th

e pe

aks

of w

aves

is c

alle

d th

e w

avel

engt

h.•

Hig

h-en

ergy

rad

iati

on h

as s

hort

er w

avel

engt

hs.

•Lo

w-e

nerg

y ra

diat

ion

has

long

er w

avel

engt

hs.

Ligh

t is

pur

e en

ergy

!Al

l ele

ctro

mag

neti

c ra

diat

ion

trav

els

at t

he s

peed

of

light

! (3

x 1

08m

/s!)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

mag

net

ic S

pec

tru

m

The

Elec

trom

agne

tic

Spec

trum

abo

ve s

how

s al

l typ

es

elec

trom

agne

tic

wav

es.

Man

y of

whi

ch w

e us

e ev

ery

day!

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

A ra

inbo

w a

ppea

rs w

hen

sunl

ight

ref

lect

s th

roug

h a

rain

drop

and

is s

epar

ated

into

its

diff

eren

t EM

rad

iati

on.

The

sam

e th

ing

happ

ens

whe

n yo

u sh

ine

sunl

ight

thr

ough

a g

lass

pri

sm!

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Sp

ectr

um

They

fou

nd t

hat

each

ele

men

t ha

d it

’s o

wn

“fin

gerp

rint

” ba

sed

on

whi

ch li

ght

it p

rodu

ced.

We

now

cal

l it

an e

lem

ent’

s at

omic

spe

ctru

m

Scie

ntis

ts f

ound

tha

t w

hen

they

use

d a

diff

eren

t lig

ht s

ourc

e th

an t

he s

un,

they

did

n’t

alw

ays

get

a fu

ll ra

inbo

w!

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

The

lines

of

colo

r in

an

atom

ic s

pect

rum

are

ca

used

by

the

beha

vior

of

that

ele

men

t’s

elec

tron

s.

Elec

tron

s oc

cupy

spe

cifi

c ar

eas

arou

nd t

he a

tom

th

ey a

re a

par

t of

.

Each

ele

ctro

n ha

s a

spec

ific

ene

rgy

leve

l w

hich

cor

resp

onds

to

the

“rin

g” t

he e

lect

ron

resi

des

in.

Bohr

mod

el a

nd b

ookc

ase

exam

ple

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

ns

and

En

ergy

Lev

els

•El

ectr

ons

wit

h th

e sa

me

ener

gy a

re g

roup

ed in

the

sa

me

ener

gy le

vel.

•En

ergy

leve

ls a

re a

ssig

ned

valu

es c

alle

d pr

inci

pal

quan

tum

num

bers

(n)

, (n

= 1

, n

= 2,

…).

An e

lect

ron

can

have

onl

y th

e en

ergy

of

one

of t

he e

nerg

y le

vels

in a

n at

om.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

n E

ner

gy L

evel

s

In a

n at

om,

each

ele

ctro

n ha

s a

spec

ific

ene

rgy,

kn

own

as it

s en

ergy

leve

l, w

hich

is a

ssig

ned

prin

cipa

l qua

ntum

num

bers

(n)

= (

n=

1, n

= 2,

…).

incr

ease

s in

ene

rgy

as t

he v

alue

of

nin

crea

ses

and

elec

tron

s ar

e fa

rthe

r aw

ay f

rom

the

nuc

leus

.

The

ener

gy o

f an

ele

ctro

n is

qua

ntiz

ed—

elec

tron

s ca

n ha

ve o

nly

spec

ific

ene

rgy

valu

es.

Bohr

mod

el

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ch

ange

s in

Ele

ctro

n E

ner

gy L

evel

Elec

tron

s m

ove

to a

hi

gher

ene

rgy

leve

l w

hen

they

abs

orb

ener

gy.

Whe

n el

ectr

ons

fall

back

to

a lo

wer

ene

rgy

leve

l, li

ght

is e

mit

ted.

The

ener

gy e

mit

ted

or

abso

rbed

is e

qual

to

the

diff

eren

ces

betw

een

the

two

ener

gy le

vels

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Su

blev

els

It is

the

arr

ange

men

t of

ele

ctro

ns

that

det

erm

ines

the

phy

sica

l and

ch

emic

al p

rope

rtie

s of

an

elem

ent.

•Ea

ch e

nerg

y le

vel c

onsi

sts

of o

ne o

r m

ore

subl

evel

s.

Book

shel

f w

ith

subl

evel

s

•The

num

ber

of s

uble

vels

in a

n en

ergy

leve

l is

equa

l to

the

prin

cipa

l qua

ntum

num

ber

n of

th

at e

nerg

y le

vel.

•The

sub

leve

ls a

re id

enti

fied

as

s, p

, d,

and

f.

•The

ord

er o

f su

blev

els

in a

n en

ergy

leve

l is

s<

p<

d<

f

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Su

blev

els

Up

to 2

ele

ctro

ns c

an f

it in

eac

h “b

ox”

(orb

ital

)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

sO

rbit

als

The

loca

tion

of

an e

lect

ron

is d

escr

ibed

in t

erm

s of

pr

obab

ility

.

•O

rbit

als

are

a th

ree-

dim

ensi

onal

vol

ume

in

whi

ch e

lect

rons

hav

e th

e hi

ghes

t pr

obab

ility

of

bein

g fo

und.

•Th

e s

orbi

tals

are

sp

here

s.

(a)

The

elec

tron

clo

ud o

f an

s o

rbit

al

repr

esen

ts t

he h

ighe

st p

roba

bilit

y of

fi

ndin

g an

s e

lect

ron.

(b)

The

s o

rbit

als

are

show

n as

sph

eres

. Th

e si

zes

of t

he

s or

bita

ls in

crea

se b

ecau

se t

hey

cont

ain

elec

tron

s at

hig

her

ener

gy

leve

ls.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

pO

rbit

als

Ther

e ar

e th

ree

por

bita

ls,

star

ting

wit

hn

= 2.

•Ea

ch p

orbi

tal h

as t

wo

lobe

s, li

ke a

bal

loon

tie

d in

the

mid

dle,

and

can

ho

ld a

max

imum

of

two

elec

tron

s.

•Th

e th

ree

por

bita

ls a

re

arra

nged

per

pend

icul

ar t

o ea

ch o

ther

alo

ng t

he x

, y,

an

d z

axes

aro

und

the

nucl

eus.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

pO

rbit

als

A p

orbi

tal h

as t

wo

regi

ons

of h

igh

prob

abili

ty,

whi

ch g

ives

a “

dum

bbel

l” s

hape

. (a

) Ea

ch p

orb

ital

is a

ligne

d al

ong

a di

ffer

ent

axis

fro

m t

he o

ther

p o

rbit

als.

(b)

All

thre

e p

orbi

tals

are

sho

wn

arou

nd t

he n

ucle

us.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

d O

rbit

als

Ther

e ar

e fi

ve d

orbi

tals

, st

arti

ng w

ith

n =

3.

•Fo

ur o

f th

e fi

ve d

orbi

tal

has

four

lobe

s, in

the

sh

ape

of a

4-l

eaf

clov

er.

•Th

e on

ly d

iffe

renc

e be

twee

n th

em is

the

ir

loca

tion

. Sh

ape

is

iden

tica

l.

•Th

e 5t

hd

orbi

tal l

ooks

lik

e a

por

bita

l wit

h a

donu

t ar

ound

its

mid

dle.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

dO

rbit

als

Each

of

the

dsu

blev

els

cont

ains

fiv

e d

orbi

tals

.

Four

of

the

five

d

orbi

tals

con

sist

of

four

lobe

s th

at a

re

alig

ned

alon

g or

be

twee

n di

ffer

ent

axes

. O

ne d

orb

ital

co

nsis

ts o

f tw

o lo

bes

and

a do

ughn

ut-

shap

ed r

ing

arou

nd

its

cent

er.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Su

blev

els

Up

to 2

ele

ctro

ns c

an f

it in

eac

h “b

ox”

(orb

ital

)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Each

orb

ital

can

hol

d to

tw

o el

ectr

ons.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Orb

ital

Cap

acit

y an

d E

lect

ron

Sp

in

elec

tron

s in

the

sam

e or

bita

l rep

el e

ach

othe

r.

elec

tron

s in

the

sam

e or

bita

l mus

t ha

ve

thei

r m

agne

tic

spin

s ca

ncel

(th

ey m

ust

spin

in o

ppos

ite

dire

ctio

ns).

We

can

repr

esen

t m

agne

tic

spin

s w

ith

ar

row

s

Sum

mar

y: E

ach

orbi

tal c

an h

ave

up t

o 2

elec

tron

s w

ith

one

“spi

n up

” an

d th

e ot

her

“spi

n do

wn”

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

The

Paul

i exc

lusi

on p

rinc

iple

sta

tes

that

each

orb

ital

can

hol

d a

max

imum

of

two

elec

tron

s.

elec

tron

s in

the

sam

e or

bita

l rep

el e

ach

othe

r.

elec

tron

s in

the

sam

e or

bita

l mus

t ha

ve t

heir

m

agne

tic

spin

s ca

ncel

(th

ey m

ust

spin

in

oppo

site

dir

ecti

ons)

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Nu

mb

er o

f E

lect

ron

s in

Su

ble

vels

Ther

e is

a m

axim

um n

umbe

r of

ele

ctro

ns t

hat

can

fill

each

sub

leve

l.

Each

ssu

blev

el h

as o

ne o

rbit

al a

nd c

an h

old

a m

axim

um o

f tw

o el

ectr

ons.

Each

psu

blev

el h

as t

hree

orb

ital

s an

d ca

n ho

ld a

m

axim

um o

f si

x el

ectr

ons.

Each

dsu

blev

el h

as f

ive

orbi

tals

and

can

hol

d a

max

imum

of

10 e

lect

rons

.

Each

fsu

blev

el c

an h

as 7

orb

ital

s an

d ca

n ho

ld a

m

axim

um o

f 14

ele

ctro

ns.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Nu

mb

er o

f E

lect

ron

s in

Su

ble

vels

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

esG

oal:

Dra

w t

he o

rbit

al d

iagr

am a

nd w

rite

the

ele

ctro

n co

nfig

urat

ion

for

an e

lem

ent.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

An o

rbit

al d

iagr

amsh

ows

the

plac

emen

t of

ele

ctro

ns in

the

or

bita

ls in

ord

er o

f in

crea

sing

ene

rgy.

This

is m

uch

easi

er t

han

tryi

ng t

o dr

aw a

ll th

e or

bita

l sh

apes

.

Ther

eis

1s

orbi

tal,

so

ther

eis

1bo

x.

Ther

e ar

e 3

por

bita

ls,

so

ther

e ar

e 3

boxe

s re

pres

enti

ng it

.

Etc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Orb

ital

Dia

gram

s –

H a

nd

He

We

fill

an o

rbit

al d

iagr

am w

ith

the

num

ber

of e

lect

rons

an

atom

has

.

Elem

ent

Atom

ic #

# of

elec

tron

s

Hyd

roge

n(H

)

Hel

ium

(He)

Begi

n at

the

bot

tom

of

the

char

t, p

utti

ng t

wo

elec

tron

s in

eac

h or

bita

l (bo

x).

Hyd

roge

nH

eliu

m

Use

an

arro

w t

o re

pres

ent

an

elec

tron

.

If t

here

are

tw

o el

ectr

ons

in o

ne

orbi

tal,

mak

e on

e “u

p” a

nd o

ne

“dow

n”

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Orb

ital

dia

gram

s ca

n al

so b

e w

ritt

en o

n on

e lin

e to

sav

e sp

ace.

Th

eyar

ew

ritt

en in

the

orde

rof

low

est

ener

gyto

high

est.

Hyd

roge

nH

eliu

m

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Fina

lly,

orbi

tal d

iagr

ams

can

also

be

wri

tten

usi

ng t

he o

rbit

al

nam

es a

nd n

umbe

r of

ele

ctro

ns a

s:

We

call

this

for

mat

the

ele

ctro

n co

nfig

urat

ion

of t

hat

atom

or

elem

ent.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

n C

onfi

gura

tion

s

Chem

ists

use

a n

otat

ion

calle

d el

ectr

on c

onfi

gura

tion

to

•in

dica

te t

he p

lace

men

t of

ele

ctro

ns in

an

atom

.

•sh

ow h

ow e

lect

rons

fill

ene

rgy

leve

ls a

nd s

uble

vels

in o

rder

of

incr

easi

ng e

nerg

y.

•w

rite

an

abbr

evia

ted

form

usi

ng a

nob

le g

as t

o re

pres

ent

all

elec

tron

s pr

eced

ing

it.

Elec

tron

Con

figu

rati

on f

or C

arbo

n

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Per

iod

2: L

i

Elem

ent

Atom

ic #

# of

elec

tron

s

Lith

ium

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Per

iod

2: B

e

Elem

ent

Atom

ic #

# of

elec

tron

s

Bery

llium

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Per

iod

2: B

, C, a

nd

N

Elem

ent

Atom

ic #

# of

elec

tron

s

Boro

n

Carb

on

Nit

roge

n

Plac

e on

e el

ectr

on in

eac

h p

orbi

tal b

efor

e do

ublin

g up

. (s

ame

for

dan

d f

orbi

tals

)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Per

iod

2: O

, F, a

nd

Ne

Elem

ent

Atom

ic #

# of

elec

tron

s

Oxy

gen

Fluo

rine

Neo

n Plac

e on

e el

ectr

on in

eac

h p

orbi

tal b

efor

e do

ublin

g up

. (s

ame

for

dan

d f

orbi

tals

)

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Per

iod

3: S

odiu

m t

o A

rgon

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

n C

onfi

gura

tion

s an

d t

he

Per

iod

ic T

able

The

elec

tron

con

figu

rati

ons

of e

lem

ents

are

rel

ated

to

thei

r po

siti

ons

on t

he p

erio

dic

tabl

e. D

iffe

rent

sec

tion

s or

blo

cks

corr

espo

nd t

o su

blev

els

s, p

, d,

and

f.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Blo

cks

on t

he

Per

iod

ic T

able

1. T

he s

bloc

k co

ntai

ns e

lem

ents

in 1

and

2.

This

mea

ns t

he

fina

l one

or

two

elec

tron

s ar

e in

the

ssu

blev

el.

2. T

he p

bloc

k co

nsis

ts o

f el

emen

ts in

Gro

up 1

3 to

Gro

up 1

8.

Ther

e ar

e si

x p

bloc

k el

emen

ts in

eac

h pe

riod

, be

caus

e th

ree

por

bita

ls c

an h

old

a m

axim

um o

f si

x el

ectr

ons.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Blo

cks

on t

he

Per

iod

ic T

able

3. T

he d

bloc

k, w

hich

con

tain

s tr

ansi

tion

ele

men

ts,

firs

t ap

pear

s af

ter

calc

ium

(at

omic

num

ber

20).

The

re a

re

10 e

lem

ents

in t

he d

bloc

k, b

ecau

se f

ive

dor

bita

ls c

an h

old

a m

axim

um

of 1

0 el

ectr

ons.

4. T

hef

bloc

k, t

he in

ner

tran

siti

on e

lem

ents

, is

the

tw

o ro

ws

of

elem

ents

at

the

bott

om o

f th

e pe

riod

ic t

able

. Th

ere

are

14 e

lem

ents

in

each

fbl

ock,

bec

ause

sev

en f

orb

ital

s ca

n ho

ld a

max

imum

of

14

elec

tron

s.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Wri

tin

g C

onfi

gura

tion

s U

sin

g S

ubl

evel

Blo

cks

STEP

1

Loca

te t

he e

lem

ent

on t

he p

erio

dic

tabl

e.

STEP

2

Wri

te t

he f

illed

sub

leve

ls in

ord

er,

goin

g ac

ross

ea

ch p

erio

d.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Exam

ple:

Chl

orin

e

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ele

ctro

n C

onfi

gura

tion

s: d

an

d f

blo

ck

Begi

nnin

g in

Per

iod

4,

the

4ssu

blev

el f

ills

befo

re t

he 3

dsu

blev

el,

beca

use

the

3dsu

blev

el is

slig

htly

low

er in

ene

rgy

than

the

4s

subl

evel

.th

e 5s

subl

evel

fill

s be

fore

the

4d

subl

evel

.th

e 6s

subl

evel

fill

s be

fore

the

5d

subl

evel

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Use

the

sub

leve

l blo

cks

on t

he p

erio

dic

tabl

e to

wri

te t

he

elec

tron

con

figu

rati

on f

or s

elen

ium

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

d b

lock

Su

blev

el E

xcep

tion

s

For

chro

miu

m (

Cr),

mov

ing

one

of t

he 4

sel

ectr

ons

to t

he 3

dsu

blev

el a

dds

stab

ility

wit

h a

half

-fill

ed d

sub

shel

l, a

nd t

he r

esul

ting

con

figu

rati

on is

4s1

3d5 .

For

copp

er (

Cu),

mov

ing

one

of t

he 4

sel

ectr

ons

to t

he 3

dsu

blev

el a

dds

stab

ility

wit

h a

fille

dd

subs

hell,

and

the

res

ulti

ng c

onfi

gura

tion

is 4

s13d

10.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Use

the

sub

leve

l blo

cks

on t

he p

erio

dic

tabl

e to

wri

te t

he

elec

tron

con

figu

rati

on f

or r

heni

um (

Re).

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Use

the

per

iodi

c ta

ble

to g

ive

the

sym

bol a

nd n

ame

for

the

elem

ent

wit

h th

e el

ectr

on c

onfi

gura

tion

of

1s2 2

s22p

6 3s2

3p6 4

s23d

7 .

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Wri

te t

he e

lect

ron

arra

ngem

ent

for

the

follo

win

g el

emen

ts:

C Si O

1s 2s 2

p

3s 3

p 3

d

4s 4

p 4

d 4

f

5s 5

p 5

d 5

f

6s 6

p 6

d 6

f

7s 7

p 7

d 7

f

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

es

Goa

l: U

se t

he e

lect

ron

conf

igur

atio

ns o

f el

emen

ts t

o ex

plai

n th

e tr

ends

in p

erio

dic

prop

erti

es.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Val

ence

Ele

ctro

ns

•M

ost

prop

erti

es o

f el

emen

ts a

re d

ue t

o th

e be

havi

or o

f th

e el

ectr

ons

in t

he e

lem

ent’

s ou

term

ost

orbi

tals

.•

Vale

nce

elec

tron

s ar

e th

e nu

mbe

r of

ele

ctro

ns in

the

ou

term

ost

ener

gy le

vel.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Val

ence

Ele

ctro

ns

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Usi

ng t

he p

erio

dic

tabl

e, h

ow m

any

vale

nce

elec

tron

s do

ea

ch e

lem

ent

have

?

A. c

alci

um

B. l

ead

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Lew

is S

ymbo

ls

Lew

is s

ymbo

lsre

pres

ent

the

vale

nce

elec

tron

s as

dot

s pl

aced

on

side

s of

the

sym

bol f

or a

n el

emen

t.•

One

to

four

val

ence

ele

ctro

ns a

re a

rran

ged

as s

ingl

e do

ts.

•Fi

ve t

o ei

ght

vale

nce

elec

tron

s ar

e ar

rang

ed w

ith

at le

ast

one

pair

of

elec

tron

s ar

ound

the

sym

bol f

or t

he e

lem

ent.

HH

eB

SKr

Rem

embe

r, w

ith

vale

nce

elec

tron

s, it

doe

sn’t

mat

ter

whi

ch r

ow (

peri

od)

you

are

in.

Onl

y th

e co

lum

n (g

roup

).G

ener

al, O

rgan

ic, a

nd B

iolo

gica

l Che

mis

try: S

truct

ures

of L

ife, 5

/eKa

ren

C. T

imbe

rlake

© 2

016

Pear

son

Educ

atio

n, In

c.

Stu

dy

Ch

eck

Wri

te t

he e

lect

ron-

dot

(Lew

is)

sym

bol f

or e

ach

of t

he

follo

win

g el

emen

ts:

ClN

C

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

siz

e

•is

det

erm

ined

by

the

atom

’s a

tom

ic r

adiu

s,th

e di

stan

ce

betw

een

the

nucl

eus

and

the

oute

rmos

t el

ectr

ons.

Ato

mic

Siz

e

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ato

mic

Siz

e

The

atom

ic s

ize

incr

ease

s go

ing

dow

n a

grou

p an

dri

ght

to

left

acr

oss

a pe

riod

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Atom

ic s

ize

incr

ease

s to

p to

bot

tom

dow

n a

grou

pBe

caus

eea

chpe

riod

adds

mor

e or

bita

ls w

hich

are

incr

easi

ngly

fart

her

from

the

nucl

eus.

Atom

icsi

zein

crea

ses

from

left

tori

ght

Beca

use

as y

ou r

ight

alo

ng a

per

iod,

you

are

add

ing

mor

epr

oton

s an

d el

ectr

ons

(but

hav

e th

e sa

me

orbi

tals

.) T

his

crea

tes

a st

rong

er

attr

acti

on b

etw

een

the

nucl

eus

(pro

tons

) an

d th

e el

ectr

ons

and

it

suck

s th

e el

ectr

ons

in t

ight

er.

Mak

ing

the

atom

sm

alle

r.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Giv

en t

he e

lem

ents

C,

N,

and

Cl,

A. w

hich

is t

he la

rges

t at

om?

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ion

izat

ion

En

ergy

Ioni

zati

on e

nerg

y is

the

ene

rgy

requ

ired

to

rem

ove

one

of

the

oute

rmos

t (v

alen

ce)

elec

tron

s.

•As

the

dist

ance

fro

m t

he n

ucle

us t

o th

e va

lenc

e el

ectr

ons

incr

ease

s, t

he io

niza

tion

ene

rgy

decr

ease

s.

•The

ioni

zati

on e

nerg

y is

low

for

met

als

and

high

for

the

no

nmet

als.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Ion

izat

ion

En

ergy

Ioni

zati

on e

nerg

y in

crea

ses

up

a gr

oup

and

incr

ease

s go

ing

acro

ss a

per

iod

from

left

to

righ

t.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Stu

dy

Ch

eck

Giv

en t

he e

lem

ents

C,

N,

and

Cl,

B. w

hich

has

the

hig

hest

ioni

zati

on e

nerg

y?

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Met

alli

c C

har

acte

r

An e

lem

ent

wit

h m

etal

lic c

hara

cter

is o

ne t

hat

lose

s va

lenc

e el

ectr

ons

easi

ly (

low

ioni

zati

on e

nerg

y).

Met

allic

cha

ract

er

•is

mor

e pr

eval

ent

in m

etal

s on

the

left

sid

e of

the

pe

riod

ic t

able

.

•is

less

for

non

met

als

on t

he r

ight

sid

e of

the

per

iodi

c ta

ble

that

do

not

lose

ele

ctro

ns e

asily

.

•de

crea

ses

goin

g do

wn

a gr

oup,

as

elec

tron

s ar

e fa

rthe

r aw

ay f

rom

the

nuc

leus

.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Met

alli

c C

har

acte

r

The

met

allic

ch

arac

ter

of t

he s

and

pbl

ock

elem

ents

in

crea

ses

goin

g do

wn

a gr

oup

and

incr

ease

s go

ing

from

rig

ht t

o le

ftac

ross

a p

erio

d.

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Su

mm

ary

: Per

iod

ic T

ren

ds

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

4.1

–El

emen

ts a

nd S

ymbo

ls

4.2

–Th

e Pe

riod

ic T

able

4.3

–Th

e At

om

4.4

–Ato

mic

Num

ber

and

Mas

s N

umbe

r

4.5

–Is

otop

es a

nd A

tom

ic M

ass

4.6

–El

ectr

on E

nerg

y Le

vels

4.7

–El

ectr

on C

onfi

gura

tion

s

4.8

–Tr

ends

in P

erio

dic

Prop

erti

es

Gen

eral

, Org

anic

, and

Bio

logi

cal C

hem

istry

: Stru

ctur

es o

f Life

, 5/e

Kare

n C

. Tim

berla

ke©

201

6 Pe

arso

n Ed

ucat

ion,

Inc.

Con

cep

t M

ap