chapter 22 additions and condensations of enolate ions
Post on 21-Dec-2015
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TRANSCRIPT
![Page 1: Chapter 22 Additions and Condensations of Enolate Ions](https://reader033.vdocuments.mx/reader033/viewer/2022061601/56649d545503460f94a315ee/html5/thumbnails/1.jpg)
Chapter 22 Additions and Condensations of Enolate Ions
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Alpha Substitution
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Condensation Reactions
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Base-Catalyzed Keto-Enol Tautomerism
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Acid-Catalyzed Keto-Enol Tautomerism
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Racemization
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Energy Diagram of Enolate Reaction with an Electrophile
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Alpha Halogenation of Ketones
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Mechanism of Haloform Formation
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Bromoform Reaction
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Iodoform Reaction with a Secondary Alcohol
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Mechanism of Acid-Catalyzed a-Halogenation
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Hell-Volhard-Zelinsky Reaction
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Hell-Volhard-Zelinski Reaction: Step 1
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Hell-Volhard-Zelinski Reaction: Step 2
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Alkylation of Enolate Ions
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Mechanism of Enolate Formation
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Alkylation of an Enamine
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Acylation of Enamines
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Aldol Condensation
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Mechanism of Base-Catalyzed Aldol Condensation
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Aldol Condensation of Acetone
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Chapter 23 Carbohydrates and
Nucleic Acids
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Structures of Glucose and Fructose
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Classicfication of Monosaccharides
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D and L Series of Sugars
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Degradation of an Aldose
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The D Family of Aldoses
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Erytho and Threo Diastereomers
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Dissymetric Molecules
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Epimers
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Mechanism of Cyclic Hemiacetal Formation
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Glucose Conformations
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Fructose
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Anomers of Glucose
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Anomers of Fructose
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Mutarotation
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Base-Catalyzed Epimerization of Glucose
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Base-Catalyzed Enediol Rearrangement
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Oxiation of Aldoses Using Bromine Water
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Nitric Acid Oxidation
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Tollens Test
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Nonreducing Sugars
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Aglycones
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Ether Formation
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Ester Formation
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Osazone Formation
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Ruff Degradation
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Kiliani-Fischer Synthesis
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Periodic Acid Cleavage of Carbohydrates
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Disaccharides
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b-Glucosidic Linkage
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a Glucosidic Linkage
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Linkage of Two Anomeric Carbons: Sucrose
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Cellulose
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Amylose
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Amylose Helix
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Amylopectin
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RNA Polymer
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Cytidine, Uridine, Adenosine, and Guanosine
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Common Ribonucleotides
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Phosphate Linkages
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Common Deoxyribonucleosides
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Base Pairing in DNA and RNA
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Strands of DNA
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Double Helix
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Replication
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