chapter 19 chemical bonds lesson 3 part 2. binary ionic compounds binary ionic compounds....
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Chapter 19Chapter 19
Chemical BondsChemical Bonds
Lesson 3 Part 2Lesson 3 Part 2
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Binary Ionic CompoundsBinary Ionic Compounds
• Binary ionic compounds. – composed of two elements.
• Before you can write a formula, – you must have all the needed
information at your fingertips.
– elements are involved and what number of electrons they lose, gain, or share
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Binary Ionic CompoundsBinary Ionic Compounds
• Oxidation number – how many electrons an atom has
gained, or shared to become stable.– ionic compounds the oxidation number
is the same as the charge on the ion.
• For example – sodium ion has a charge of 1+ and an
oxidation number of 1+.
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Oxidation NumbersOxidation Numbers
• The elements – more than one oxidation
number.
• Naming compounds – oxidation number is
expressed in the name with a roman numeral
– the oxidation number of iron in iron (III) oxide is 3++..
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Compounds Are NeutralCompounds Are Neutral
• Writing formulas – the individual ions in a compound carry
charges, the compound itself is neutral.– must have the right number of positive
ions and the right number of negative ions so the charges balance.
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Compounds Are NeutralCompounds Are Neutral
• Calcium fluoride – calcium ion has a charge of 2+ and a
fluoride ion has a charge of 1 −.
– two fluoride ions for every calcium ion
• C2+ F1- Cris-cross and drop– charges cancel and the compound is
neutral with the formula CaF2.
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Writing FormulasWriting Formulas
1. Write the symbol of the element which has the positive oxidation number or charge
2. Write the symbol of the element or polyatomic ion with the negative oxidation number.
3. The charge (without the sign) of one ion becomes the subscript of the other ion.
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Naming FormulasNaming Formulas
1. Write the name of the positive ion.
2. Check to see if the positive ion is capable of forming more than one oxidation number. If it is, determine the oxidation number of the ion from the formula of the compound.
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Writing Names Writing Names
3. Write the charge of the positive ion using roman numerals in parentheses after the ion’s name. If the ion has only one possible oxidation number, proceed to step 4
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Writing NamesWriting Names
4.4. Write the root name of the negative ion. The root is the first part of the element’s name.
5. Add the ending -ide to the root. The table lists several elements and their -ide counterparts.
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Writing Names Writing Names
• Subscripts – do not become part of the name for
ionic compounds– can be used to help determine the
charges of the metals that have more than one positive charge
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Examples of naming for multiple charges
Element Cation Preferred Name
Other Name
copper Cu+ copper (I) cuprous
Cu2+ copper (II) cupric
iron Fe2+ Iron (II) Ferrous
Fe3+ Iron (III) Ferric
Lead Pb2+ Lead (II) Plumbous
Pb4+ Lead (IV) plumbic
Mercury Hg22+ Mercury (I) Mercurous
Hg2+ Mercury (II) Mercuric
Tin Sn2+ Tin (II) Stannous
Sn4+ Tin (IV) Stannic
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