carbon-13 12 c is not nmr-active (no magnetic spin (i = 0)) 13 c has a magnetic spin (i = 1/2, odd...
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Carbon-13 12C is not NMR-active (no magnetic spin (I = 0))
13C has a magnetic spin (I = 1/2 , odd mass) 13C signals are 6000 times weaker than 1H because:
1. Natural abundance of 13C is small (1.08% )
2. Magnetic moment of 13C is small The gyromagnetic constant of 13C is one-fourth of that of 1H The chemical shift range is larger than for protons
0 - 200 ppm The number of different signals indicates the number of
different kinds of carbon PULSED FT-NMR is required
13C g = 6.72 1H g = 26.75
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Coupling Constants
However, 13C does couple to hydrogen atoms (I = 1/2)
13C - 13C coupling NO! not probable
very common13C – 1H coupling YES!
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Coupling to attached Protons
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Decoupling the Proton Spins
Off-resonance decoupling
Proton-Decoupled Spectra
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Ethylphenylacetate
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Some Instruments Show The Multiplicities of The Peaks on The Decoupled Spectra
s = singlet t = tripletd = doublet q = quartetCODE :
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Hydrogen and Carbon Chemical Shifts
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Correlation chart for 13C Chemical Shifts (ppm)
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Approximate Chemical Shift Ranges (ppm) for Selected Types of Carbon.
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1-Propanol
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2,2-Dimethylbutane
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Bromocyclohexane
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Cyclohexanol
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Cyclohexene
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Cyclohexanone
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Toluene
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Cl
Cla
a
b
b
c
c
1,2-Dichlorobenzene
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1,3-Dichlorobenzene
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Estimation of Carbon Chemical shifts in Substituted Benzene