c10g-e067a shimadzu's total solutions for the hydrocarbon … · 2021. 1. 31. · c1-c14...

Shimadzu's Total Solutions for the H

ydrocarbon Processing Industry

C10G-E067A

www.shimadzu.com/an/

Analytical and Testing Instruments for the HPI Market

Shimadzu's Total Solutions for theHydrocarbon Processing Industry

© Shimadzu Corporation, 2019

For Research Use Only. Not for use in diagnostic procedures. This publication may contain references to products that are not available in your country. Please contact us to check the availability of these products in your country.Company names, products/service names and logos used in this publication are trademarks and trade names of Shimadzu Corporation, its subsidiaries or its affiliates, whether or not they are used with trademark symbol “TM” or “®”.Third-party trademarks and trade names may be used in this publication to refer to either the entities or their products/services, whether or not they are used with trademark symbol “TM” or “®”.Shimadzu disclaims any proprietary interest in trademarks and trade names other than its own.

The contents of this publication are provided to you “as is” without warranty of any kind, and are subject to change without notice. Shimadzu does not assume any responsibility or liability for any damage, whether direct or indirect, relating to the use of this publication.

World Map of Shimadzu Sales, Service,Manufacturing, and R&D Facilities

Sales and Service

Manufacturing

R&D

Shimadzu's Total Solutionsfor the Hydrocarbon Processing Industry(Petrochemical, Chemical)

The Hydrocarbon Processing Industry (HPI), encompassing petroleum refining, gas

processing, petrochemical and chemical, is a foundational field for all industry. In the

HPI market, many kinds of analytical and measuring instruments are used for quality

control purposes and process management.

With a wide range of products, from GC and Elemental Analyzers to an On-line Water

Quality Analyzer, Shimadzu offers total support for laboratories in the HPI market.

From Upstream to Downstream, our rugged, high-quality products are perfectly suited

to meet the demands of your laboratory and contribute to your business success.

For more information about Shimadzu's solutions for the HPI market, visit our website at:https://www.shimadzu.com/an/industry/petrochemicalchemical/index.html

Developing, Extracting

Transporting, Storage

Exploration, Finding

Manufacturing, Refining

Supply, Trading

Upstream

Downstream

Shimadzu Customized GC Analyzers

Simulated Distillation AnalyzerTransformer Oil Gas Analyzer (TOGA)

Various Applications in the HPI Market

• Support third-party detectors, including a pulsed flame photometric detector (PFPD) and a pulsed discharge helium ionization detector (PDHID).

• Support third-party software for detailed hydrocarbon analysis (DHA) and Chrom Merge.

• Support liquefied petroleum gas (LPG) sampling devices and vaporizers.

• Complete application manual and methods

• Best-in-Class Sensitivity• Unmatched Stability performance • Excellent Maintainability• Automation Functions

Nexis GC-2030

Trace Sulfur Analysis GC System

• Comprehensive gasoline measurements determining bulk PIONA and specific oxygenate and BTEX compound content.

• Provides a lot of information in a fast, robust measurement.• Relatively simple instrumentation, setup, and analysis

procedures.

VUV PIONA+ Analysis GC System

Trace Moisture Analysis GC System

• Easily analyzes both liquid and gas samples

• Uses a variety of WatercolTM GC columns depending on the matrices

• Uses a simple, high-sensitivity, and very stable low-cost Barrier Ionization Discharge (BID) Detector

Analysis of Water in LPGNote: With baseline subtraction

uV BID

Water 25 ppm,

RT= 14.3 min, S/N=350+LPG(Main)

2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 min

0

2500

5000

7500

10000

12500

15000

Natural Gas Analyzers

ASTM D1945/D1946

GPA 2261, GPA 2177

GPA 2286, GPA 2186

ISO 6975Applicable Methods

Analysis

Features

C1-C6+ Hydrocarbons, Non Condensable gases O2, N2, CO, CO2 and H2S

Optional Hydrogen

Extended NGA C1-C14+

NGL, Dual Oven NGA

High Speed NGA

Analysis time 10 min.

UOP 539, ASTM D7833,

D 2163

C1-C6+ Hydrocarbons

saturates and unsaturates

H2S, Non Condensable gases O2, N2, CO, CO2 and H2

LPG Sampling

Vaporizer

Analysis time less than

6 min.

ASTM D1946

ASTM E1746

O2, N2, CO, CO2

Impurities in Chlorine

Special Hastelloy

Material for Chlorine Analyzer

ASTM D3612C

TOGA with Head Space

H2, O2, N2, CO, CO2, C1, C2's, C3's

High Sensitivity

Extension up to C4

ASTM

D6228

Trace Sulfur

PFPD for Sulfur

Refinery Gas Analyzer (RGA)

Process and Custom Gas Analyzers

Petrochemicals analyzer

TOGA/DGA Analyzer SimulatedDistillation

ASTM D7096, D7213, D3710, D2887, D6417, D6352, D7500, D5307, D7169, IP 480, ISO3924

Boiling Point Distribution

C1-C110 (As per method)

Fast Simdist

Correlations with D86 and D1160, Integrated Shimadzu Software

ASTM D5134, D6729, D6730, D6733, D8071

C1-C14 Hydrocarbons

PIONA Report

Tuned D6730 column

Fast DHA

Front End PIONA

Room Temperature

Database

VUV PIONA+

ASTM D4815,D7423

UOP 960

C1-C4 Alcohols

Use of N2 Carrier for D4815

ASTM D6228

ASTM D5504

ASTM D5623

ASTM D7011

Trace Sulfur Analysis Individual components

Use of FPD, PFPD or SCD Detectors

ASTM D3606, 5580

Aromatics

Combination model for D3606, D5580. D4815

DHA Analyzers Oxygenates Analyzers Aromatics AnalyzersSulfur Analyzers

Product Lineup

4Shimadzu's Total Solutions for the Hydrocarbon Processing Industry

Analytical and Testing Instruments for the HPI Market 5

Rel

ativ

e R

esp

on

se F

acto

r

1.3

1.2

1.1

1.0

0.9

0.8

0.70 50 100 150 200 250 300 350 400

Analysis time (Hours) (Day 16)

1-Butanethiol b.p. 98℃Methyl disulfide b.p. 109℃Diethyl disulfide b.p. 152℃3-Methylbenzothiophene b.p. 273℃

Excellent Long-Term StabilityVUV Chromatogram of Gasoline Sample

* The VUV detector VGA-100 is a product of VUV ANALYTICS, INC.

Sulfur Chemiluminescence Detection Gas Chromatograph System

SCD-2030

Aromatics AnalysisHPLC

Features

SwitchingValve

Configuration

SuperPerformance

andExpandability

PreciseSample

Injection

Furan AnalysisHPLC

Features

FullyIntegrated

System

NetworkConnectivity

HighSensitivityDetector

Applicable Methods ASTM D5837 Custom Methods

Analysis Subjects Components in transformer oil

15.0

12.5

10.0

7.5

5.0

2.5

0.0

PDA Ch1 Absorbance (220nm+/- 4nm) (+)mAV

Chromatogram View

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 min

Furf

ury

alc

oh

ol/6

.452

/5.1

02

/7.2

33

/8.4

14

/9.3

78

Time Inten. 0.015Max Intensity : 7,116

0.000

15.0

12.5

10.0

7.5

5.0

2.5

0.0

PDA Ch2 Absorbance (282nm+/- 4nm) (+)mAV

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 min

/7.2

33/7

.233

/8.4

14/8

.414

Time Inten. 0.029

Max Intensity : 14,654

2.044

5-h

ydro

xym

eth

yl-2

-fu

rald

ehyd

e/5.

102

5-h

ydro

xym

eth

yl-2

-fu

rald

ehyd

e/9.

388

2-fu

rald

ehyd

e/7.

233

2-fu

rald

ehyd

e/8.

414

Furan Chromatogram

200

190

180

170

160

150

140

130

120

110

100

90

80

70

60

50

40

30

20

10

00.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5

Applicable Methods ASTM D 6591, D6379, IP 391, IP 436, IP 548, IP590 Custom Methods

Analysis Subjects Aromatics in fuels Poly-aromatics in diesel

FAME in jet fuel

Aromatics Ref. Std. ASTMD6591

Non-Aromatics

Mono-Aromatics Di-Aromatics

Tri-Aromatics

LC / MS / MS

Features

VOCs AnalysisGC-MS

Features

LCMS-8060

High Speedand

High Sensitivity

Scan Speed30000u / sec

MRM555 Ch / Sec

Applicable Methods Custom Methods

Analysis Subjects Additives in polymers

MS Chromatograms of Polymer Additives

Analysis of Additives in Plastic

Applicable Methods EPA 8270B, TO -14, IP-585 Custom Methods

Analysis Subjects Volatile organic compounds Arsine phosphine in ethylene FAME in jet fuel

HS-20 Headspace Analysis System

TD-30 Thermal Desorption System

GCMS-QP2020 NX

Accessories HS,TD and P&T

High Sensitivityand Reduced

Cost

High EfficiencyMulticomponent

Analysis



AA-7000

EDX-7000/8000/8100

Inductively Coupled Plasma Mass Spectrometer (ICP-MS)

Features

ICP Atomic Emission Spectrometer (ICPE)

Features

Atomic Absorption Spectrophotometer (AAS)

Features

Energy DispersiveX-ray FluorescenceSpectrometer (EDX)

Features

Easy MethodDevelopment

LowestRunning Costs

High Stability,High Sensitivity

and LowInterference

Applicable Methods Customized

Analysis Subjects Trace elements in naphtha Determination of toxic arsenic species using LC-ICP-MS

Arsenic Chromatogram

AsVAsIII

DMAsAsB

Easy MethodDevelopment

Low ArgonConsumption

All WavelengthAcquisition

Applicable Methods Elemental Analysis ASTM D4951, D5184 ASTM D4951,D5184 UOP 389, UOP 303 UOP 714, APHA 3120, IFP 9507

Analysis Subjects All elements Lubricating oils Petroleum naphtha, gasoline Marine fuel, fuel oil, heavy oils

Cr in Naphtha with ISO Mist Kit

Cr 267.716Cond 2

Inte

nsity

Inte

nsity

ICPE-9800 Series

Applicable Methods ASTM D6595, D3237, D3567, D3605, D3635, D3831,

D3919, D4628, IFP9312, UOP946, D5863

Analysis Subjects Additives in polymers All elements Lubricating oil Petroleum oils Lead in gasoline

Abs=0.011100Conc+0.0043463 r=0.9989

0.000 5.000 10.000 15.000 20.000Conc(NONE)

0.000

0.100

0.200Abs

Arsenic in Vacuum Gas Oil (VGO)

Unique 3DDouble Beam

Optics

ComprehensiveSafety Functions

DualBackgroundCorrectionFunctions

Applicable Methods ASTM D5839, ASTM D4294, C114 ISO 8754

Analysis Subjects Sulfur in oil All elements

Zn in Lubricant Oil

10.0

8.0

6.0

4.0

2.0

0.0

002

001

003

004

Mea

sure

d In

ten

sity

(cp

s/u

A)

Standard Value (ppm)

0.0 50.0 100.0 150.0 200.0 250.0 300.0

High Sensitivity,High Speed andHigh Resolution

Large SampleChamber

Easy-To-UseOperation





DSC-60 PlusIRSpirit

UV-1900

Fourier Transform Infrared Spectrophotometer (FTIR)

Features

UV-VIS Spectrophotometer (UV-Vis)

Features

Thermal Analyzers

Features

Spectrofluorophotometer

Features

Space Efficient with High

Expandability

Dedicated IR Pilot Program

HighReliability

Applicable Methods D7371, EN 14078, D7575, D7678 Custom Methods

Analysis Subjects Fame in biodiesel Total petroleum hydrocarbons Additives in polymers Oil in water

Enlarged View of PeaksAround 2920 cm-1

27202740276027802800282028402860288029002920294029602980300030203040306030803100cm-1

0.0

0.2

0.4

0.6

0.8

1.0

1.2

Abs

CSD1CSD2CSD3CSD4CSD5CSD6CSD7

Sample AbsorbanceConcentration

[ppm]

CSD1 0.0020 0.73

CSD2 0.026 4.54

CSD3 0.096 15.23

CSD4 0.28 40.56

CSD5 0.60 87.57

CSD6 0.87 127.55

CSD7 1.2 168.70

r=1.0

Height

Calibration Curve and StandardSample Concentrations

Analysis of Oil in Water

Easy Operation

Allows Obtaining AnswersRapidly

Advanced Regulatory Compliance

High Performance to Meet Diverse

Needs

Applicable Methods ASTM D1840, D2008 Custom Methods

Analysis Subjects Petroleum products Turbine fuels Mineral oils

Transmittance Spectra of Colored Cellophane Tape Chromaticity Diagram of XY Color System

0.90

0.80

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00

100

80

60

40

20

0

0.00

380 500 600Wavelength (nm)

700 780

0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80x

y

Tran

smit

tan

ce (

%)

Analysis of Colored Cellophane Tape

HighPerformance

DSC / TGA

DiverseMeasurements

by SimpleOperations

HighSensitivity

Applicable Methods ASTM D3417, D3418, D4419, D4591, D5483, ASTM D3850, D6370, D6375, Custom Methods

Analysis Subjects Thermal properties of polymers DSC, TGA, TG/DTA, TMA

DSC Curves of HDPE, PP, and Blend Sample

-0 50 100 150 200

135.5 °C

160.5 °C

20.00 °C

869.90 mJ

144.90 °C 175.00 °C

72.04 mJ

-203.67 J/g

132.9 °C

-95.46 J/g163.4 °C

20.00 °C 144.90 °C 175.00 °C

69.76 J/g

HDPE

PP

Blend (PE8-PP2)

mW

-0

10

20

30

40

Temp [°C]

DSC

High SensitivityHigh Stability

andHigh Speed

High Speed3D Scanning

FluorescenceQuantum Yield

and FluorescenceQuantumEfficiency

Measurement

RF-6000

Applicable Methods ASTM D5412, JPI-5S-71-2010 Custom Methods

Analysis Subjects Measuring oil in water Coumarin in diesel

Coumarin in DieselFl

uore

scen

ce In

tens

ity

150000.0

100000.0

50000.0

0.0390.0 450.0 500.0 550.0 600.0 630.0

nm

Calibration Curve

Concentration (mg/L)

Flu

ore

scen

ce In

tens

ity



DSC-60 PlusIRSpirit

UV-1900

Fourier Transform Infrared Spectrophotometer (FTIR)

Features

UV-VIS Spectrophotometer (UV-Vis)

Features

Thermal Analyzers

Features

Spectrofluorophotometer

Features

Space Efficient with High

Expandability

Dedicated IR Pilot Program

HighReliability

Applicable Methods D7371, EN 14078, D7575, D7678 Custom Methods

Analysis Subjects Fame in biodiesel Total petroleum hydrocarbons Additives in polymers Oil in water

Enlarged View of PeaksAround 2920 cm-1

27202740276027802800282028402860288029002920294029602980300030203040306030803100cm-1

0.0

0.2

0.4

0.6

0.8

1.0

1.2

Abs

CSD1CSD2CSD3CSD4CSD5CSD6CSD7

Sample AbsorbanceConcentration

[ppm]

CSD1 0.0020 0.73

CSD2 0.026 4.54

CSD3 0.096 15.23

CSD4 0.28 40.56

CSD5 0.60 87.57

CSD6 0.87 127.55

CSD7 1.2 168.70

r=1.0

Height

Calibration Curve and StandardSample Concentrations

Analysis of Oil in Water

Easy Operation

Allows Obtaining AnswersRapidly

Advanced Regulatory Compliance

High Performance to Meet Diverse

Needs

Applicable Methods ASTM D1840, D2008 Custom Methods

Analysis Subjects Petroleum products Turbine fuels Mineral oils

Transmittance Spectra of Colored Cellophane Tape Chromaticity Diagram of XY Color System

0.90

0.80

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00

100

80

60

40

20

0

0.00

380 500 600Wavelength (nm)

700 780

0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80x

y

Tran

smit

tan

ce (

%)

Analysis of Colored Cellophane Tape

HighPerformance

DSC / TGA

DiverseMeasurements

by SimpleOperations

HighSensitivity

Applicable Methods ASTM D3417, D3418, D4419, D4591, D5483, ASTM D3850, D6370, D6375, Custom Methods

Analysis Subjects Thermal properties of polymers DSC, TGA, TG/DTA, TMA

DSC Curves of HDPE, PP, and Blend Sample

-0 50 100 150 200

135.5 °C

160.5 °C

20.00 °C

869.90 mJ

144.90 °C 175.00 °C

72.04 mJ

-203.67 J/g

132.9 °C

-95.46 J/g163.4 °C

20.00 °C 144.90 °C 175.00 °C

69.76 J/g

HDPE

PP

Blend (PE8-PP2)

mW

-0

10

20

30

40

Temp [°C]

DSC

High SensitivityHigh Stability

andHigh Speed

High Speed3D Scanning

FluorescenceQuantum Yield

and FluorescenceQuantumEfficiency

Measurement

RF-6000

Applicable Methods ASTM D5412, JPI-5S-71-2010 Custom Methods

Analysis Subjects Measuring oil in water Coumarin in diesel

Coumarin in Diesel

Fluo

resc

ence

Inte

nsity

150000.0

100000.0

50000.0

0.0390.0 450.0 500.0 550.0 600.0 630.0

nm

Calibration Curve

Concentration (mg/L)

Flu

ore

scen

ce In

tens

ity

AG-Xplus Series

Total Organic Carbon (TOC) Analyzer

Features

On-line TOC Analyzer

Features

Testing Machines

Features

Particle Size Analyzer

Features

Applicable Methods ASTM D7573, EN 1484, EPA 415.1 APHA 5310B

Analysis Subjects TOC in various types of water, including high salt content water

TOC in Brine Solution

TOC-L Series

680 DegCCombustion

MethodHigh Salt Kit

StandaloneSystem

SuperiorSampling

Units

LowOperation

Costs

LowMaintenance

Costs


Analysis Subjects TOC in various types of water

0,35

0,3

0,25

0,2

0,15

0,1

0,05

0,00

NPO

C in

mg

/I

Number of Measurements

1 20 39 58 77 96 115 134 153 172 191 210 229 248 267

TOC Analysis in Condensate SampleMean Value 0.208mg/L, SD 0.006mg/L, DL 0.05mg/L

Short TestCycle Time

UltrafastSampling Rate

Eight FoldHigh

Resolution

Applicable Methods ISO 6892, ISO 527, ASTM D638

Analysis Subjects Tensile properties of metals Tensile properties of plastics

Tensile Test of PP, PC, PVC


Analysis Subjects Various petrochemicals streams

Samples with Broad Distribution

Polystyrene Latex ○ : 50nm, ● : 100nm, △ : 50nm + 100nm

No

rmal

ized

Par

ticl

e A

mo

un

t

Particle Diameter (nm)

No

rmal

ized

Par

ticl

e A

mo

un

tParticle Diameter (nm)

SALD-2300

Wide Range17nm-2500um

Wide Rangeof Accessories

HighSensitivity / HighConcentration



0

10

20

30

40

50

60

70

80

90

100

010 20 30 40 50 60 70 80 90 100 110 120

Displacement (Strain) (%)

Stre

ss (N

/mm

2 )

PP_1PC_1PVC_1

AG-Xplus Series

Total Organic Carbon (TOC) Analyzer

Features

On-line TOC Analyzer

Features

Testing Machines

Features

Particle Size Analyzer

Features

Applicable Methods ASTM D7573, EN 1484, EPA 415.1 APHA 5310B

Analysis Subjects TOC in various types of water, including high salt content water

TOC in Brine Solution

TOC-L Series

680 DegCCombustion

MethodHigh Salt Kit

StandaloneSystem

SuperiorSampling

Units

LowOperation

Costs

LowMaintenance

Costs


Analysis Subjects TOC in various types of water

0,35

0,3

0,25

0,2

0,15

0,1

0,05

0,00

NPO

C in

mg

/I

Number of Measurements

1 20 39 58 77 96 115 134 153 172 191 210 229 248 267

TOC Analysis in Condensate SampleMean Value 0.208mg/L, SD 0.006mg/L, DL 0.05mg/L

Short TestCycle Time

UltrafastSampling Rate

Eight FoldHigh

Resolution

Applicable Methods ISO 6892, ISO 527, ASTM D638

Analysis Subjects Tensile properties of metals Tensile properties of plastics

Tensile Test of PP, PC, PVC


Analysis Subjects Various petrochemicals streams

Samples with Broad Distribution

Polystyrene Latex ○ : 50nm, ● : 100nm, △ : 50nm + 100nm

No

rmal

ized

Par

ticl

e A

mo

un

t


No

rmal

ized

Par

ticl

e A

mo

un

t


SALD-2300

Wide Range17nm-2500um

Wide Rangeof Accessories

HighSensitivity / HighConcentration



0

10

20

30

40

50

60

70

80

90

100

010 20 30 40 50 60 70 80 90 100 110 120

Displacement (Strain) (%)St

ress

(N/m

m2 )

PP_1PC_1PVC_1

The Next Industry Standard SCDThe Nexis SCD-2030 is a next-generation sulfur chemiluminescence detection system.

It has been developed to fulfill the unmet needs of laboratories the world over.

The dramatically enhanced sensitivity and reliability, the excellent maintainability,

and the automation functions, a first for the industry, will improve laboratory productivity.

Sulfur Chemiluminescence Detection Gas Chromatograph System

SCD-2030

The New Standard in Reliability

Dramatically Improved Productivity

Best-in-Class Sensitivity

*2 It is not necessary to install LabSolutions software on the client PC for terminal service.*3 When using an iPad, the installation of Citrix’s XenApp is required. iPad is a registered trademark of Apple Inc.

*1 The acquisition controller PC controls the analytical instruments. Analysis directions and re-analysis of data can be performed using a client PC.

Laboratory or office*2Client PC *3iPad LabSolutions server

*1***1Acquisition controller PC Acquisition controller PC

Shimadzu LC Shimadzu GC Shimadzu GCShimadzu LC Agilent GC Agilent GCAgilent LC Agilent LC

Controlling other vendor’s GC and HPLC using LabSolutions DB/CS

Simple User Interface

LabSolutions CS

Agilent LC method editing

Agilent GC method editing

Agilent LC batch editing Agilent LC analysis monitoring

Agilent GC batch editing Agilent GC analysis monitoring

Launcher window

Shimadzu Analytical Network Data System

14 15

Shimadzu's Total Solutions for the H

ydrocarbon Processing IndustryC10G-E067A

www.shimadzu.com/an/

Analytical and Testing Instruments for the HPI Market

Shimadzu's Total Solutions for theHydrocarbon Processing Industry

© Shimadzu Corporation, 2019

For Research Use Only. Not for use in diagnostic procedures. This publication may contain references to products that are not available in your country. Please contact us to check the availability of these products in your country.Company names, products/service names and logos used in this publication are trademarks and trade names of Shimadzu Corporation, its subsidiaries or its affiliates, whether or not they are used with trademark symbol “TM” or “®”.Third-party trademarks and trade names may be used in this publication to refer to either the entities or their products/services, whether or not they are used with trademark symbol “TM” or “®”.Shimadzu disclaims any proprietary interest in trademarks and trade names other than its own.

The contents of this publication are provided to you “as is” without warranty of any kind, and are subject to change without notice. Shimadzu does not assume any responsibility or liability for any damage, whether direct or indirect, relating to the use of this publication.

c10g-e067a shimadzu's total solutions for the hydrocarbon … · 2021. 1. 31. · c1-c14...

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