btl the bioliq process - iets · 9 engler-bunte-institut, ebi ceb institut für technische chemie,...
TRANSCRIPT
KIT – Universität des Landes Baden-Württemberg und
nationales Forschungszentrum in der Helmholtz-Gemeinschaft www.kit.edu
Engler-Bunte-Institut, Chemische Energieträger – Brennstofftechnologie, EBI ceb
Institut für Technische Chemie, Vergasungstechnologie, ITC vgt
DVGW Forschungsstelle am EBI, Gastechnologie, DVGW gt
BtL – the bioliq® process
Thomas Kolb, Mark Eberhard
2 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
Mechanische Fertigstellung Nov. 2011
3 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
regionale Pyrolyse - Anlagen
Zentraler central production of
synthesis gas and fuel
25 km
de-central production of high energy intermediate products
250 km
Transportation
distance
Specific energy
content [GJ/m3]
Straw 1,5
Slurry 15-25
Fuel 36
Regionally distributed biomass
The bioliq®-Process
4 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® process scheme
bioSyncrude
bioSyncrude
Synfuel
Bio
ma
ss
Syngas
De-central Centralized
Fuel
synthesis
DME
synthesis
Filter Sorption CO2 and water
separation Catalyst
O2 (Steam)
Gas cleaning and conditioning
High pressure
entrained flow
gasification
Slag
Fast pyrolysis
Pre-treatment
Source: Presentation of Dr. Dahmen, IKFT
5 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
Pyrolysis flow scheme
In cooperation with: 2 MWth / 500 kg/h
500°C / 3 sec
Sand Loop 10/1
6 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
Fast Pyrolysis Pilot Plant
Biomass preparation
Biosyncrude preparation Feed stock storage
Pyrolysis product recovery Fast pyrolysis
7 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
0 20 40 60 80 100
Reisstroh
Weizenstroh
Miscanthus
Holz
Produktausbeuten [%]
Asche
Koks
Kondensate
Pyrolysegas
Fast Pyrolysis of different Feed Stock /Lab Scale
From lab scale
experiment
8 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
BioSyncrude
Production / Storage
9 Engler-Bunte-Institut, EBI ceb
Institut für Technische Chemie, ITC vgt Prof. Dr.-Ing. Thomas Kolb Jahrestreffen der ProcessNet Fachgemeinschaft SuPER
5./6. November 2013, DECHEMA-Haus, Frankfurt a. M.
Slurry Specification
2 fractions organic & water
solids up to 40 wt.%
ash up to 10 wt. %
organic acids (e.g. formic / acetic acid)
alcohol (e.g. methanol)
chloride up to 1 wt.%
dynamic viscosity 50 mPas < η < 5000 mPas
density 1000 kg/m3 < ρ < 1500 kg/m3
Particle size 90% < 100 µm
pH 2 < pH < 7 Organic condensate
30% solids
10 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
Syngas
Slag
Cooling
screen
Fuel
Oxygen Coal
Residues
Biomass
Waste
heterogen
hoher Aschegehalt
Flexibilität
heterogeneous
high ash content
flexibility
High Pressure Entrained Flow Gasification
Fuel/ Load / Product – Flexibility
Flexibility
Load / Product
Efficiency
Fuels, BtL
Chemicals
Hydrogen, H2
Electricity / Heat, IGCC
11 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
N2-, O2- infrastructure
Confirmation of Funding FNR / Sept. 2008
Contract signed KIT-Lurgi / Dec. 2008
Mechanical Completion / Oct. 2011
Completion of Commissioning / July 2012
First Flame / Aug. 2012
Stable Operation with Liquid Fuel 80 bar / Dec. 2012
Performance Test with Model Slurry / Jan 2013
First Test Run July 2013
bioliq® Entrained Flow Gasifier
12 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® Entrained Flow Gasifier
5 MWth / 1 t/h
Oxygen blown
p = 40 - 80 bar
Membrane Wall
13 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® II
Tankfarm & Slurry Pump
14 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® EFG
Gasifier Top
40bar configuration
Quench upper
section
15 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® II
Quench & Slag Handling
16 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® Gasifier Prozess Optimization
17 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
High Temperature - High Pressure (HTHP)
Syngas Cleaning
Filter
Syngas
from
Gasifier
Syngas
Sorption
Entrained flow
sorption
Catalyst
Catalytic
Ceramic Filter
Syngas
from
Gasifier
Syngas
Entrained flow
sorption
Compact horizontal ceramic filter for
particle removal with CPP recleaning
Dry sorption of sour gases (HCl, H2S)
and alkalines
Catalytic conversion of organics and
N-species (HCN, NH3)
CO2 separation (optional)
700 m³/h STP synthesis gas
(40 m³/h at 80 bar, 800 °C)
Energy Savings ca. 10%
compared to state-of-the-art gas cleaning
Process Integration
Chemical Quench
18 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
bioliq® HTHP Syngas Cleaning
Nov 2013: End of commissioning phase
19 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
DME and Fuel Synthesis
DME-synthesis
One step DME synthesis
Innovative isothermal reactor
Temp. 250 °C, pressure 60 bar
DtG-synthesis
Zeolithe catalyzed dehydratization,
oligomerization and isomerization
Temp. 350 - 450 °C, pressure 25 bar
Recycling of unconverted gas
Gasoline stabilization
Flare
Air
Gasoline
Heavy fractionSeparator
Gasoline reactor
DME-reactor
WGS-reactor
Syngas
Desorber
CO
2 -Ab
so
rbe
r
CO
2 -Ab
so
rbe
r
Process water
Cycle gas
Dis
tilla
tio
n
CO2
20 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
Flow sheet Synthesis
syngas feed 700 mn³/h
fuel production max. 80 l/h
ROZ 100-110 expected from laboratory tests
21 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
Synthesis Pilot Plant
Performance Test June 2013
Acceptance July 2013
Helmholtz Virtual Institute
for Gasification Technology
Towards Sustainable Energy Systems
Thomas Kolb, Manfred Aigner, Reinhold Kneer, Michael Müller, Roman Weber
23 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
KIC InnoEnergy – Partners from 6 co-locations
24 IEA Bioenergy – Joint workshop, Nov. 19 – 20, 2013, Gothenburg, Sweden | Thomas Kolb
Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology
KIC InnoEnergy – Partners from 6 co-locations
25 IEA Task 33: Fall Meeting October 18-20, 2011, Pitea, Sweden Engler-Bunte Institute, Fuel Technology
Institute for Technical Chemistry, Gasification Technology
DVGW Research Station, Gas Technology