biodegradable polymer layered silicate nano composites a review

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CHAPTER 8 Biodegradable Polymer/Layered Silicate Nanocomposites: A Review Masami Okamoto Advanced Polymeric Nanostructured Materials Lab, Graduate School of Engineering, Toyota Technological Institute, Hisakata 2-12-1, Tempaku, Nagoya 468 8511, Japan CONTENTS 1. I nt r od uc ti on . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2. Hi st or y of PLS Nanoc omposi tes . . . . . . . . . . . . . . . . . . . . . . . . 3 3. Struct ure o f LS and its Modi ﬁcat ion w ith S urf act ant s . . . . . . . . . 4 4. Preparation Meth ods and Structure of PLS Na no composites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 4.1. Intercalatio n of Pol ymers or Prepolyme rs f rom Solution . . . . . . . . . . . . . . . . . . . . . . . . 5 4.2. The In Situ Int erca lat ive Po lymeriz ati on Method . . . . . . . . 5 4.3. The Melt I ntercalation Method . . . . . . . . . . . . . . . . . . . . . 6 4.4. St ruct ure of P LS Nanocomposi tes . . . . . . . . . . . . . . . . . . . 6 5. Char act erization of PLS Nanocomposit es . . . . . . . . . . . . . . . . . 7 6. Bi odegrad able P ol ymer/ LS Nanoco mpos it es . . . . . . . . . . . . . . . 8 6.1. PCL/ LS Nanoc omposi te s . . . . . . . . . . . . . . . . . . . . . . . . . . 9 6.2. PVA/LS Nan oc omposites . . . . . . . . . . . . . . . . . . . . . . . . 10 6.3. PLA/LS Nano compos it es . . . . . . . . . . . . . . . . . . . . . . . . 10 6.4. PBS/ LS Nanocomposi te s . . . . . . . . . . . . . . . . . . . . . . . . . 13 6.5. PHB/LS Nanocomposites . . . . . . . . . . . . . . . . . . . . . . . . 14 6.6. Starch/LS Nanocompos it es . . . . . . . . . . . . . . . . . . . . . . . 15 6.7. Plan t Oi l/ LS Nanoc omposi te s . . . . . . . . . . . . . . . . . . . . . 15 6.8. Chitosan/LS Na no composites . . . . . . . . . . . . . . . . . . . . . 17 7. Materials Properties of Biodeg radable Poly mer/LS Nano comp os it es . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 7.1. Mechan ical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 ISBN: 1-58883-0 53-5/$00.00 Copyri ght © 2005 by Ameri can Scient iﬁc Publishers All rights of reproduction in any form reserved. 1 Handbook of Biodegradable Polymeric Materials and Their Applications Edited by Surya Mallapragada and Balaji Narasimhan Volume 1: Pages (1–45)

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