BC at surfaceBC C-130 #11 April 19th What Do The Observations and Models Tell Us About Emissions?

Field Experiments Employ Mobile Super-Sites & Provide Opportunities to Characterize Emissions The Informatics Problem: Observations

Source Information Air Mass Markers

Model Runs w/wo SourceSectorsFreidli et al., JGR submitted

Outline of the studyRAMS, MM5STEM-2k1NCEPSchematic of Analysis

Example of Use of Model with Emission Markers Frontal outflow of biomass burning plumes E of Hong KongObserved CO Sacshe et al.

Observed aerosol potassium - Weber et al.

Biomass burning CO forecast

Longitude100 ppb

P-3BSO2Large-Scale Structure is Captured by Model But Peaks are UnderestimatedData: Kondo et al., Thorton, Sacshe

--- CO > 700--- CO > 600--- CO > 500Figure 7Under-predicted Points Are In The Yellow SeaWhat does this tell us about the model?-Model deficiency?-Emissions problem?

Observed and Modeled Ratios Can Be Classified By Source Region Using Trajectories - Age Can Also Be Estimated

Chart1

1.1861.597

1.80052.299

2.5522.628

1.43361.181

1.43930.918

1.50921.192

0.971372.329

1.4121.257

1.1052.17

1.1662.132

1.1210.922

0.8441.256

1.1270.856

1.1871.102

1.2981.145

0.9061.171

2.00171.185

1.91681.154

1.59031.242

1.7751.338

1.3861.578

1.82310.987

2.29881.792

1.2361.769

1.3981.473

1.79311.89

1.62112.46

1.241

1.303

1.082

1.245

2.501

1.942

1.051

1.453

1.57

1.802

2.261

0.823

0.964

1.709

2.249

2.128

2.013

0.93

1.734

C2H6 / CO measured

C2H6 / CO model

CO Concentration

C2H6 Concentration

Hong Kong

Total Data_new_Jul15 (2)

jdayage(day)time(GMT)LAT(degree)LON(degree)Alt(m)O3(ppbv)CO(ppbv)CO editedformaldehyde editedNO(ppbv)NO2(ppbv)NOy(ppbv)NOx(ppbv)HNO3(ppbv)N0iSO2(ppbv)SO4(ppbv)SO2+SO4(ppbv)N0i editedSO2+SO4 editedCO editedEthyne editedSO2+SO4 editedRNO3(ppbv)N0i editedCO editedEthane editedCO editedEthane(ppbv)Propane(ppbv)Ethene(ppbv)Ethene editedEthane editedPropene(ppbv)Ethane editedEthyne editedEthyne(ppbv)formaldehyde(ppbv)acetadehyde(ppbv)acetone(ppbv)PAN(ppbv)MEK(ppbv)ARO1(ppbv)BC(ug/stdm3)model O3(ppbv)model CO(ppbv)model NO (ppbv)model NO2 (ppbv)model NOy(ppbv)model NOx(ppbv)model HNO3(ppbv)mN0imodel SO2 (ppbv)model SO4(ppbv)mSO2+mSO4model RNO3(ppbv)model Ethane(ppbv)model Propane (ppbv)model Ethene(ppbv)model Propene(ppbv)model Ethyne(ppbv)model formaldehyde (ppbv)model acetaldehyde(ppbv)model acetone(ppbv)model PAN (ppbv)model MEK(ppbv)model ARO1(ppbv)model BC(ug/std m3)

20010630.068.583321.847114.432709.652.315122.22273.670.60168000.2185670.160564270.510.835740.1605641.64E-020.218567270.511.186122.221.1860.2241.50E-021.50E-021.1861.1860.3060.3066.10E-0253.851199.5580.0060.0234.40E-022.89E-020.1050.1340.4290.5751.0040.0681.5970.3870.1610.0020.4180.420.8990.2510.4610.1060.55616

20010630.068.666722.211114.31788.254.529171.36209.450.60804000.805510.618236.160.6270.6184.13E-020.59453155.451.8005171.361.80050.5370.1270.1271.80051.80050.7270.7270.33650.5723258.039257.9880.0220.1070.17350.129020.3880.5171.3111.7283.0390.1242.2990.5890.2810.0030.6860.7550.9260.6930.5060.1860.76039

20010630.068.7522.371114.11915.8359.74329.36259.590.53257000.813050.652883200.340.460.6528838.20E-020.80551236.162.552329.362.5520.9620.7513.74E-021.43369.80E-022.5521.6961.6961.2550.6696768.89313.1750.1671.1950.4431.36170.8642.2262.6392.3574.9960.2352.6280.7480.350.0150.9191.6561.0191.2190.5780.2910.95086

20010660.151.2522.104113.851899.6318.67270.510.14664000.781320.720531206.870.4560.7205310.81305200.341.4336273.671.40E-021.43931.43360.735343.356846.788203.5770.0160.0617.71E-020.3330.410.0770.5250.6020.0431.1810.2320.02400.2570.5720.6870.1490.3890.0340.3012

20010660.0610.666721.807114.452945.1273.67155.450.17827000.764990.715204.790.4590.7151.49E-020.78132206.871.4393209.451.43360.163913.74E-026.37E-021.50921.43930.569480.735340.601680.146734.259338.053176.6080.0030.0282.05E-023.16E-020.2470.2780.0410.3230.3640.0170.9180.1490.00600.160.3830.6010.1290.2630.0120.17695

20010660.0610.7522.216114.291532.7209.45236.160.33508000.3620660.31103129.030.2930.311032.60E-020.76499204.791.5092270.511.43930.228571.40E-027.00E-031.4121.50920.835740.569480.608040.3310.4313.00E-020.141241.918354.732170.740.0370.5523.78E-020.589851.3731.9621.0611.0192.080.0661.1920.2250.0430.0050.2760.9160.3490.4310.30.0470.29117

20010680.061.083322.287114.111500.255.998200.340.29355000.5333930.294168.620.4530.2940.362066129.030.97137155.456.00E-031.1050.971370.2730651.753447.2770.0270.2590.286290.3290.6151.1250.9292.0540.3862.3290.8030.7020.0371.0621.5281.9021.180.9140.5441.9261

20010690.06922.057113.871885220.35206.870.308000.5063640.29708179.250.5790.297080.533393168.621.412236.168.00E-031.1661.4120.6271.342544.26219.3050.0270.1230.149730.5840.7340.2421.0741.3160.0561.2570.2830.03500.3680.6640.5360.4240.3420.0580.70897

20010720.062.333322.288114.171606.859.952204.790.36771000.3664080.38194140.070.5330.381940.506364179.251.105200.346.00E-031.1211.1050.461.189547.981355.6570.0260.0990.125120.340.4650.7680.9961.7640.1792.170.7770.4730.0090.8571.1571.9320.7330.7910.4261.5594

20010720.0610.2521.939114.11787.659.455259.59129.030.31914000.4817240.444953134.840.210.4449530.366408140.071.166206.871.30E-020.8441.1660.4560.532571.1281.1280.2731.061952.059356.6550.0140.1340.147350.5010.6490.6341.3341.9680.1552.1320.7090.20600.8480.9011.3960.8280.8070.2591.5911

20010760.06122.257114.23193343.515228.8168.620.43371000.0975270.338586337.331.1370.3385860.481724134.841.121204.792.20E-021.1271.1210.4590.9641.9680.341.111433.655213.8370.0210.0719.15E-020.3010.3930.0480.4160.4640.0740.9220.1590.02400.2030.7510.8330.1360.4180.0260.7841

20010763.586.833330.13135.443616.555.209270.51179.250.378872.59E-022.83E-025.42E-020.164370.2185672.16E-020.1390.1605640.1013030.305628321.361.07340.3056283.18E-020.097527337.330.844129.031.50920.296216.37E-024.50E-021.1870.8440.2930.835740.146640.49320.301080.3054446.804208.1330.0030.0088.69E-021.15E-020.0020.0130.0990.1410.240.0751.2560.3080.0870.0010.3950.4151.1460.3840.4470.0910.66033

20010771.313.083322.589117.971689.729.242155.45140.070.242320.594530.5945300.0723660.458529262.050.855420.4585291.16E-020.101303321.361.127168.620.971378.15E-023.90E-021.2981.1270.4530.273060.178270.6820.9864.03E-030.1125.07E-020.4841735.122160.5130.0230.0336.52E-035.51E-020.4970.5530.3430.5760.9190.0430.8560.1470.0320.0010.2080.6480.3220.1470.2260.0350.4646

20010771.583.166722.834118.241216.241.872236.16134.840.378430.805510.805510.6180.6180.074190.279383114.590.8891.125611.93E-020.072366262.051.187179.251.4120.1567.00E-033.88E-022.00171.1870.5790.6270.335081.40E-020.1230.9488343.96209.4790.0370.0681.70E-020.105190.7310.8360.9070.9861.8930.1631.1020.2680.1350.0030.4211.0860.7040.3850.4720.1220.72975

20010771.673.2523.087118.621217.739.867200.340.813050.813053.49E-020.6180.6528830.2149670.68599193.860.67050.53461.73E-020.07419114.591.298140.071.1050.1316.00E-033.40E-021.91681.2980.5330.460.293550.8231.1440.1410.1050.6745646.779222.2550.0440.0882.40E-020.132560.8170.9491.0351.0752.110.1891.1450.290.1410.0030.4551.1730.7890.4820.5480.1340.79679

20010771.943.333323.337118.991216.238.972206.870.781320.781321.77E-020.702880.7205310.303981.0294317.940.969330.8483571.70E-020.214967193.860.906134.841.1660.1348.00E-033.00E-031.7750.9060.210.4560.3080.6611.0580.140.1020.7019849.417234.6550.0670.1372.30E-020.203740.9461.151.1131.0922.2050.2051.1710.3020.1370.0030.4591.2910.8560.6010.6110.1420.85307

20010771.793.416723.576119.341217.639.402204.790.764990.764990.7150.7150.106640.94259341.951.02971.2923371.59E-020.30398317.942.0017337.331.1210.1116.00E-031.95E-021.3862.00171.1370.4590.367710.6591.0071.77E-020.1269.50E-020.7014949.377246.3630.0710.1512.20E-020.221140.8911.1131.0381.0192.0570.2131.1850.3050.1390.0040.4551.3130.9670.6280.6730.1460.90459

20010801.63.916725.537125.993662.450.317129.033.11E-022.89E-026.00E-020.302110.3620660.311030.311030.0918121.50689307.610.5250.07711.65E-020.10664341.951.9168321.360.8440.1531.30E-024.98E-021.82311.91681.07340.2930.319140.24860.1220.1920344.483234.8250.0170.0194.50E-023.66E-020.2120.2480.3840.6171.0010.1121.1540.3010.1220.0040.3580.6051.1360.370.5290.1190.81784

20010801.4425.829125.633663.161.688168.625.51E-025.53E-020.110370.423020.5333930.2940.2940.2136161.3004196.030.6730.1223942.61E-020.091812307.611.5903262.051.1270.2662.20E-020.110112.29881.59030.855420.4530.433710.336740.2450.2957948.059239.8050.0180.0238.80E-024.10E-020.1820.2230.4470.6211.0680.1291.2420.3450.1640.0060.4150.6811.3570.4050.5740.1480.81814

20010801.294.083326.113125.263662.762.037179.258.03E-028.55E-020.165770.340590.5063640.297080.297080.1632920.57457372.190.814290.7146822.95E-020.213616196.031.775346.421.1870.274.50E-028.00E-031.3981.7750.8890.5790.378870.28840.320.2054251.52242.2150.0130.0180.13.09E-020.1140.1450.4510.5751.0260.1391.3380.3910.2110.0090.4750.6981.5940.4130.6050.1760.80848

20010803.754.2526.964125.033603.867.103140.072.28E-025.22E-027.50E-020.291420.3664087.99E-020.3020.381940.1383960.48773282.340.917061.303381.67E-020.163292372.191.386213.511.2980.2123.90E-022.10E-021.79311.3860.67050.5330.242320.1540.2960.57229.90E-020.1171.896752.743260.1320.0060.0082.80E-021.32E-020.0360.050.4880.6011.0890.1641.5780.4940.3350.0140.610.7042.1830.4440.7060.2490.93085

20010834.715.166724.236136.83047.661.465134.841.32E-021.52E-022.84E-020.453350.4817243.30E-020.4120.4449531.012341.12561346.421.09E-020.138396282.341.8231296.030.9069.80E-020.113181.62111.82310.969330.210.378434.77E-023.30E-020.4708539.896190.0610.0050.011.30E-021.51E-020.2590.2740.1040.5680.6720.0340.9870.2020.02300.2370.3910.5760.1910.3840.0320.53508

20010631.756.2518.448118.661533.157.311337.333.30E-026.46E-020.721280.0975274.33E-020.295260.3385860.7243480.5346213.514.30E-021.01234346.422.2988281.552.00170.451123.88E-022.29881.02971.1370.174130.3167952.784257.9090.0290.1022.0150.4940.8861.0170.7161.0681.7840.1211.7920.4370.1130.0010.4510.6310.4370.5580.4940.116na

20010631.756.333318.214118.321531.557.326321.363.44E-026.69E-020.702640.1013034.31E-020.262480.3056280.5572480.391733273.323.66E-020.724348213.511.236236.151.91680.425213.40E-021.2360.5251.07340.165450.2844652.395252.5770.0290.1021.9090.4590.8450.9760.6631.0241.6870.1141.7690.4260.1030.0010.4360.6080.4260.5490.4590.109na

20010631.027.083317.488116.242031.358.744262.052.91E-024.33E-020.789931.50E-040.0723664.30E-020.415510.4585290.9784840.848357296.032.87E-020.557248273.321.398218.451.59030.311221.3980.6730.855420.17170.1927549.728209.9110.0170.0571.1140.2390.430.5040.2970.6140.9110.0631.4730.3260.05500.3070.4570.3260.4730.2390.061na

20010630.068.166721.864114.432273.754.134114.592.14E-025.27E-020.261087.01E-050.074192.69E-020.252470.2793831.1825421.292337281.550.978484296.031.7931261.11.79310.814290.1081353.214228.3060.0110.0420.9820.390.1870.240.7260.9651.6910.0891.890.4630.2270.0030.520.9590.4630.5220.390.143na

20010630.068.2522.207114.311545.654.359193.866.53E-020.149681.03910.2149670.685990.685990.3289760.0771236.151.182542281.551.6211291.651.62110.917060.3862561.629279.9070.0550.3072.530.9050.5620.9241.7552.0013.7560.1672.460.6550.320.0060.7870.9740.6550.540.9050.229na

20010660.212.333322.221113.81145.784.318317.940.106050.197931.95920.303981.02941.02940.3885950.122394218.450.328976236.150.161550.301171.50.3410.5552.3630.2010.8331.7290.6950.7191.4140.0461.2410.250.050.0050.2880.420.250.2780.2010.056na

20010660.062.416722.034113.993024.571.618341.953.33E-027.33E-022.05110.106640.942590.942590.1430420.97673360.870.388595218.450.370144.061281.0770.0120.0241.1030.2960.4270.4630.1090.5210.630.0821.3030.2920.05700.3121.1740.2920.610.2960.071na

20010660.069.916722.072114.391920.7307.619.18E-021.73020.0918120.210491.29641.506890.2578860.714682261.10.257886261.19.01E-0246.766167.4570.0130.0861.2530.2150.7070.8060.2750.6730.9480.0191.0820.1740.00700.2070.3490.1740.2480.2150.01na

20010660.061022.35114.281380.3196.038.47E-030.205150.830530.2136161.30041.30040.171722.4031319.870.17172319.8760.716176.5040.10.8864.1490.6242.0122.9981.7341.2773.0110.1021.2450.2580.0640.0070.3170.3710.2580.3570.6240.071na

20010680.061.166722.318114.061067.352.08372.195.20E-020.111341.17280.1632920.574570.574570.0724390.79882291.650.505808291.650.460750.87417.0830.1180.8734.0431.3890.5431.5342.0621.4173.4790.4112.5010.9080.910.0671.3141.7760.9080.871.3890.692na

20010680.061.2522.159114.352896.458.621282.343.67E-020.10171.33670.1383960.487730.487730.5058081.303380.542753.398538.8380.0170.0882.4490.9360.1660.2710.3940.5650.9590.321.9420.6240.4360.0160.632.2690.6240.9550.9360.341na

20010684.693.2520.002123.352966.393.372346.424.22E-025.28E-022.40861.73E-040.917331.012340.135190.990421.125611.86E-021.7750.1353.00E-030.8890.20910.14438.903242.9120.0210.0230.9160.3280.240.2840.1060.4260.5320.0451.0510.1970.02200.2330.5090.1970.3970.3280.035na

20010680.068.2521.195114.732693.674.356213.514.95E-020.14281.29491.10E-040.532070.7243480.102540.432060.53461.70E-021.3860.1691.95E-020.67050.36630.1347.037348.7340.0210.0541.5440.6010.2690.3440.2540.610.8640.1021.4530.3550.0840.0010.4161.0310.3550.6480.6010.1na

20010680.068.333321.535114.532690.163.51273.323.14E-029.22E-021.22219.88E-050.433670.5572485.41E-020.337650.3917330.3634548.734379.1910.0180.0571.6520.6790.2190.2940.2970.6070.9040.1341.570.4140.1310.0010.4791.3020.4140.7220.6790.141na

20010680.068.416721.803114.262015.164.996296.033.60E-020.113661.57369.69E-050.828870.9784849.88E-020.749510.8483573.39E-021.82310.351264.98E-020.969330.57510.2503453.169404.7430.020.0962.1690.8770.3530.4690.4640.8081.2720.1791.8020.5180.1780.0020.6211.3340.5180.810.8770.193na

20010680.068.522.006113.951073.459.014281.551.70E-020.240511.67729.83E-050.9251.1825426.74E-021.22491.2923376.50E-022.29880.768850.110111.02970.536670.4805856.174399.0140.0450.783.9531.330.691.5151.4481.7713.2190.2842.2610.7740.4980.0211.0441.5630.7740.8411.330.455na

20010690.068.7521.616114.362763.858.87236.152.62E-026.39E-020.968328.46E-050.238870.3289766.36E-021.35E-020.07711.54E-021.2360.1030.5250.19259.60E-0230.825142.7850.0180.0310.570.120.2510.30.060.4730.5330.0130.8230.1140.00600.1480.3720.1140.1420.120.013na

20010690.068.833321.89114.12520.563.305218.452.97E-028.53E-021.07177.97E-050.273640.3885956.45E-025.78E-020.1223941.75E-021.3980.1438.00E-030.6730.241250.12635.056168.6590.0210.0520.8550.2030.3530.4260.1010.6560.7570.0250.9640.1660.01300.2150.4530.1660.2070.2030.024na

20010690.088.916722.139113.81966.9158.888360.874.236943.2038.35546.24E-0547.43994.23E-021.3111.353310.6268755.779294.4850.0591.0593.6930.8861.0032.1211.0661.6852.7510.1391.7090.5020.1440.0090.6390.7580.5020.5560.8860.184na

20010720.06122.18114.212212.84.22E-020.100811.14120.1430420.976730.976730.402345.593381.3430.0410.1721.960.8040.310.5230.9310.8951.8260.1912.2490.8210.5670.0140.9242.0670.8210.8490.8040.488na

20010720.068.916721.95114.041873.1261.12.72E-026.14E-020.853984.93E-050.169270.2578864.50E-020.669690.7146823.39E-021.79310.360952.10E-020.814290.289130.2388751.634356.470.0230.1052.1120.8340.4780.6060.6611.2841.9450.1532.1280.7120.2180.0010.8461.4160.7120.8070.8340.266na

20010720.06922.166113.77794.86319.875.15E-050.171720.171722.40312.40310.694560.093299.4270.1010.7893.8021.0310.9231.8131.1191.7052.8240.2012.0130.6770.240.0090.831.1990.6770.6451.0310.316na

20010760.061.083322.219114.282266.541.4393.63E-023.61E-020.825410.0724390.798820.798827.20E-0233.377229.140.0210.0680.7230.1720.2930.3820.0630.4070.470.0920.930.1680.03300.2141.0080.1680.4830.1720.036na

20010763.584.833329.154124.51780.850.512291.653.85E-023.94E-021.19982.66E-040.4280.5058084.63E-021.25711.303383.24E-021.62110.303150.113180.917060.26380.325341.215279.2070.1250.432.6960.7490.2410.7961.3920.5441.9360.3731.7340.5370.7380.0710.8631.7550.5370.7140.7490.472na

Total Data_new_Jul15 (2)

0.601680.42

0.608040.755

0.532571.656

0.146640.572

0.178270.383

0.335080.916

0.293551.528

0.3080.664

0.367711.157

0.319140.901

0.433710.751

0.378870.415

0.242320.648

0.378431.086

1.173

1.291

1.313

0.605

0.681

0.698

0.704

0.391

0.631

0.608

0.457

0.959

0.974

0.42

1.174

0.349

0.371

1.776

2.269

0.509

1.031

1.302

1.334

1.563

0.372

0.453

0.758

2.067

1.416

1.199

1.008

1.755

HCHO / CO measured

HCHO / CO model

Ageless

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

C2H6 / CO measured

C2H6 / CO model

CO Concentration

C2H6 Concentration

Hong Kong

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

C2H6 / C2H2 measured

C2H6 / C2H2 model

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

C2H6 / C2H4 measured

C2H6 / C2H4 model

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

SO2 / C2H2 measured

SO2 / C2H2 model

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

NOi / CO measured

NOi / CO model

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

SO2 / CO measured

SO2i / CO model

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

NOi / SO2 measured

NOi/ SO2 model

jdayage(day)time(GMT)LAT(degree)LON(degree)Alt(m)O3(ppbv)O3(ppbv)CO(ppbv)CO(ppbv)COformaldehyde(ppbv)NO(ppbv)NO2(ppbv)NOy(ppbv)NO+NO2O3(ppbv)N0iO3(ppbv)N0xN0iCO(ppbv)N0xNOx(ppbv)HNO3(ppbv)SO2(ppbv)SO4(ppbv)SO2+SO4CO(ppbv)Ethyne(ppbv)SO2+SO4N0iCO(ppbv)SO2+SO4Ethane(ppbv)Ethyne(ppbv)SO2+SO4Ethyne(ppbv)RNO3(ppbv)Ethane(ppbv)Ethane(ppbv)CO(ppbv)Propane(ppbv)Ethene(ppbv)Propene(ppbv)Ethyne(ppbv)formaldehyde(ppbv)acetadehyde(ppbv)acetone(ppbv)PAN(ppbv)MEK(ppbv)ARO1(ppbv)BC(ug/stdm3)model O3(ppbv)model CO(ppbv)model NO (ppbv)model NO2 (ppbv)mNO+mNO2model NOy(ppbv)model NOx(ppbv)model HNO3(ppbv)m N0imodel SO2 (ppbv)model SO4(ppbv)mSO2+mSO4model RNO3(ppbv)model Ethane(ppbv)model Propane (ppbv)model Ethene(ppbv)model Propene(ppbv)model Ethyne(ppbv)model formaldehyde (ppbv)model acetaldehyde(ppbv)model acetone(ppbv)model PAN (ppbv)model MEK(ppbv)model ARO1(ppbv)model BC(ug/std m3)

20010630.068.583321.847114.432709.652.31552.315122.22122.22273.670.60168054.1340.0741954.1340.074190114.590.074190122.220.3060.2793830.07419114.590.2793831.1860.3060.53460.67051.64E-021.1861.186122.220.2241.50E-020.3066.10E-0253.851199.5580.0060.0230.0294.40E-022.89E-020.1050.1340.4290.5751.0040.0681.5970.3870.1610.0020.4180.420.8990.2510.4610.1060.55616

20010630.068.666722.211114.31788.254.52954.529171.36171.36209.450.60804054.3590.21496754.3590.2149670193.860.2149670171.360.7270.685990.214967193.860.685991.80050.7270.8483570.969334.13E-021.80051.8005171.360.5370.1270.7270.33650.5723258.039257.9880.0220.1070.1290.17350.129020.3880.5171.3111.7283.0390.1242.2990.5890.2810.0030.6860.7550.9260.6930.5060.1860.76039

20010630.068.7522.371114.11915.8359.7459.74329.36329.36259.590.53257084.3180.3039884.3180.303980317.940.303980329.361.6961.02940.30398317.941.02942.5521.6961.2923371.02978.20E-022.5522.552329.360.9620.7519.80E-021.6961.2550.6696768.89313.1750.1671.1951.3620.4431.36170.8642.2262.6392.3574.9960.2352.6280.7480.350.0150.9191.6561.0191.2190.5780.2910.95086

20010630.068.166721.864114.432273.754.13454.134114.59114.592.14E-025.27E-020.261080.0741971.6180.1066471.6180.106640.07419341.950.106647.01E-052.69E-020.252470.279383273.670.735340.942590.10664341.950.942591.43360.735340.07710.5251.4336273.670.1081353.214228.3060.0110.0420.0530.9820.390.1870.240.7260.9651.6910.0891.890.4630.2270.0030.520.9590.4630.5220.390.143na

20010630.068.2522.207114.311545.654.35954.359193.86193.866.53E-020.149681.03910.21496752.080.16329252.080.1632920.214967307.610.0918120.685990.68599209.450.569481.506890.091812307.611.506891.43930.569480.1223940.6731.4393209.450.3862561.629279.9070.0550.3070.3622.530.9050.5620.9241.7552.0013.7560.1672.460.6550.320.0060.7870.9740.6550.540.9050.229na

20010660.151.2522.104113.851899.659.455259.59318.67058.6210.13839658.6210.1383960196.030.2136160213.510.67051.30040.213616196.031.30041.3860.67050.7146820.814291.386213.513.356846.788203.5770.0160.0610.0777.71E-020.3330.410.0770.5250.6020.0431.1810.2320.02400.2570.5720.6870.1490.3890.0340.3012

20010660.0610.666721.807114.452945.143.515228.8273.67074.3560.72434874.3560.7243480372.190.1632920296.030.969330.574570.163292372.190.574571.82310.969331.49E-021.43361.8231296.030.163913.74E-020.735340.601680.146734.259338.053176.6080.0030.0280.0312.05E-023.16E-020.2470.2780.0410.3230.3640.0170.9180.1490.00600.160.3830.6010.1290.2630.0120.17695

20010660.0610.7522.216114.291532.784.318317.94209.45063.510.55724863.510.5572480282.340.1383960281.551.02970.487730.138396282.340.487732.29881.02972.60E-021.43932.2988281.550.228571.40E-020.569480.608040.3310.4313.00E-020.141241.918354.732170.740.0370.5520.5893.78E-020.589851.3731.9621.0611.0192.080.0661.1920.2250.0430.0050.2760.9160.3490.4310.30.0470.29117

20010680.061.083322.287114.111500.255.99871.618341.95064.9960.97848464.9960.9784840213.510.7243480236.150.5250.53460.724348213.510.53461.2360.5251.236236.1551.753447.2770.0270.2590.2860.286290.3290.6151.1250.9292.0540.3862.3290.8030.7020.0371.0621.5281.9021.180.9140.5441.9261

20010690.06922.057113.87188552.08372.19220.35059.0141.18254259.0141.1825420273.320.5572480218.450.6730.3917330.557248273.320.3917331.3980.6731.398218.451.342544.26219.3050.0270.1230.150.149730.5840.7340.2421.0741.3160.0561.2570.2830.03500.3680.6640.5360.4240.3420.0580.70897

20010720.062.333322.288114.171606.859.95258.621282.34058.870.32897658.870.3289760296.030.9784840261.10.814290.8483570.978484296.030.8483571.79310.814291.7931261.11.189547.981355.6570.0260.0990.1250.125120.340.4650.7680.9961.7640.1792.170.7770.4730.0090.8571.1571.9320.7330.7910.4261.5594

20010720.0610.2521.939114.11787.659.45574.356213.51259.59063.3050.38859563.3050.3885950281.551.18254201.2923371.182542281.551.2923370.532571.1281.1280.2731.061952.059356.6550.0140.1340.1480.147350.5010.6490.6341.3341.9680.1552.1320.7090.20600.8480.9011.3960.8280.8070.2591.5911

20010760.06122.257114.23193343.51563.51273.32228.8041.4390.07243941.4390.0724390236.150.32897600.07710.328976236.150.07710.9641.9680.341.111433.655213.8370.0210.0710.0929.15E-020.3010.3930.0480.4160.4640.0740.9220.1590.02400.2030.7510.8330.1360.4180.0260.7841

20010660.212.333322.221113.81145.784.31864.996296.03317.940.106050.197931.95920.303980.30398218.450.3885951.02941.02940.1223940.388595218.450.1223940.161550.301171.50.3410.5550.8962.3630.2010.8331.7290.6950.7191.4140.0461.2410.250.050.0050.2880.420.250.2780.2010.056na

20010660.062.416722.034113.993024.571.61859.014281.55341.953.33E-027.33E-022.05110.106640.10664261.10.2578860.942590.942590.976730.143042360.871.353310.370144.061281.0770.0120.0240.0361.1030.2960.4270.4630.1090.5210.630.0821.3030.2920.05700.3121.1740.2920.610.2960.071na

20010660.069.916722.072114.391920.758.87236.15307.619.18E-021.73020.0918120.091812319.870.171720.210491.29641.506890.7146820.257886261.10.7146829.01E-0246.766167.4570.0130.0860.0991.2530.2150.7070.8060.2750.6730.9480.0191.0820.1740.00700.2070.3490.1740.2480.2150.01na

20010660.061022.35114.281380.363.305218.45196.038.47E-030.205150.830530.2136160.2136161.30041.30042.40310.17172319.872.403160.716176.5040.10.8860.9864.1490.6242.0122.9981.7341.2773.0110.1021.2450.2580.0640.0070.3170.3710.2580.3570.6240.071na

20010680.061.166722.318114.061067.352.0858.888360.87372.195.20E-020.111341.17280.1632920.1632920.574570.574570.798820.0724390.460750.87417.0830.1180.8730.9914.0431.3890.5431.5342.0621.4173.4790.4112.5010.9080.910.0671.3141.7760.9080.871.3890.692na

20010680.061.2522.159114.352896.458.621282.343.67E-020.10171.33670.1383960.1383960.487730.487730.542753.398538.8380.0170.0880.1052.4490.9360.1660.2710.3940.5650.9590.321.9420.6240.4360.0160.632.2690.6240.9550.9360.341na

20010680.068.2521.195114.732693.674.356213.514.95E-020.14281.29490.1922780.7243481.10E-040.532070.102540.432060.53461.70E-021.3860.1691.95E-020.67050.36630.1347.037348.7340.0210.0540.0751.5440.6010.2690.3440.2540.610.8640.1021.4530.3550.0840.0010.4161.0310.3550.6480.6010.1na

20010680.068.333321.535114.532690.163.51273.323.14E-029.22E-021.22210.1235780.5572489.88E-050.433675.41E-020.337650.3917330.3634548.734379.1910.0180.0570.0751.6520.6790.2190.2940.2970.6070.9040.1341.570.4140.1310.0010.4791.3020.4140.7220.6790.141na

20010680.068.416721.803114.262015.164.996296.033.60E-020.113661.57360.1496140.9784849.69E-050.828879.88E-020.749510.8483573.39E-021.82310.351264.98E-020.969330.57510.2503453.169404.7430.020.0960.1162.1690.8770.3530.4690.4640.8081.2720.1791.8020.5180.1780.0020.6211.3340.5180.810.8770.193na

20010680.068.522.006113.951073.459.014281.551.70E-020.240511.67720.2575421.1825429.83E-050.9256.74E-021.22491.2923376.50E-022.29880.768850.110111.02970.536670.4805856.174399.0140.0450.780.8253.9531.330.691.5151.4481.7713.2190.2842.2610.7740.4980.0211.0441.5630.7740.8411.330.455na

20010690.068.7521.616114.362763.858.87236.152.62E-026.39E-020.968320.0901060.3289768.46E-050.238876.36E-021.35E-020.07711.54E-021.2360.1030.5250.19259.60E-0230.825142.7850.0180.0310.0490.570.120.2510.30.060.4730.5330.0130.8230.1140.00600.1480.3720.1140.1420.120.013na

20010690.068.833321.89114.12520.563.305218.452.97E-028.53E-021.07170.1149550.3885957.97E-050.273646.45E-025.78E-020.1223941.75E-021.3980.1438.00E-030.6730.241250.12635.056168.6590.0210.0520.0730.8550.2030.3530.4260.1010.6560.7570.0250.9640.1660.01300.2150.4530.1660.2070.2030.024na

20010690.088.916722.139113.81966.9158.888360.874.236943.2038.355447.439947.43996.24E-054.23E-021.3111.353310.6268755.779294.4850.0591.0591.1183.6930.8861.0032.1211.0661.6852.7510.1391.7090.5020.1440.0090.6390.7580.5020.5560.8860.184na

20010720.06122.18114.212212.84.22E-020.100811.14120.1430420.1430420.976730.976730.402345.593381.3430.0410.1720.2131.960.8040.310.5230.9310.8951.8260.1912.2490.8210.5670.0140.9242.0670.8210.8490.8040.488na

20010720.068.916721.95114.041873.1261.12.72E-026.14E-020.853980.0886160.2578864.93E-050.169274.50E-020.669690.7146823.39E-021.79310.360952.10E-020.814290.289130.2388751.634356.470.0230.1050.1282.1120.8340.4780.6060.6611.2841.9450.1532.1280.7120.2180.0010.8461.4160.7120.8070.8340.266na

20010720.06922.166113.77794.86319.8700.171725.15E-050.171722.40312.40310.694560.093299.4270.1010.7890.893.8021.0310.9231.8131.1191.7052.8240.2012.0130.6770.240.0090.831.1990.6770.6451.0310.316na

20010760.061.083322.219114.282266.541.4393.63E-023.61E-020.825410.0724390.0724390.798820.798827.20E-0233.377229.140.0210.0680.0890.7230.1720.2930.3820.0630.4070.470.0920.930.1680.03300.2141.0080.1680.4830.1720.036na

0.420.60168

0.7550.60804

1.6560.53257

0.959

0.974

0.572

0.383

0.916

1.528

0.664

1.157

0.901

0.751

0.42

1.174

0.349

0.371

1.776

2.269

1.031

1.302

1.334

1.563

0.372

0.453

0.758

2.067

1.416

1.199

1.008

model HCHO/ CO

measuredHCHO/ CO

1.5971.186

2.2991.8005

2.6282.552

1.891.4336

2.461.4393

1.1811.386

0.9181.8231

1.1922.2988

2.3291.236

1.2571.398

2.171.7931

2.132

0.922

1.241

1.303

1.082

1.245

2.501

1.942

1.453

1.57

1.802

2.261

0.823

0.964

1.709

2.249

2.128

2.013

0.93

model C2H6 / CO

measured C2H6 / CO

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

model C2H6 / C2H2

measured C2H6 / C2H2

1.0040.5346

3.0390.848357

4.9961.292337

1.6910.0771

3.7560.122394

0.6020.714682

0.364

2.08

2.054

1.316

1.764

1.968

0.464

1.414

0.63

0.948

3.011

3.479

0.959

0.864

0.904

1.272

3.219

0.533

0.757

2.751

1.826

1.945

2.824

0.47

model SO2 / C2H2

measured SO2 / C2H2

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0

0

0

0

0

0

0

0

0

0

0

0

0

0

model N0x/CO

measured N0x/CO

1.0040.279383

3.0390.68599

4.9961.0294

1.6910.94259

3.7561.50689

0.6021.3004

0.3640.57457

2.080.48773

2.0540.5346

1.3160.391733

1.7640.848357

1.9681.292337

0.4640.0771

1.4140.122394

0.631.35331

0.9480.714682

3.0112.4031

3.479

0.959

0.864

0.904

1.272

3.219

0.533

0.757

2.751

1.826

1.945

2.824

0.47

model SO2/CO

measured SO2/CO

0.0290.07419

0.1290.214967

1.3620.30398

0.0530.10664

0.3620.091812

0.0770.213616

0.0310.163292

0.5890.138396

0.2860.724348

0.150.557248

0.1250.978484

0.1481.182542

0.0920.328976

0.8960.388595

0.0360.143042

0.0990.257886

0.9860.17172

0.9910.072439

0.105

0.075

0.075

0.116

0.825

0.049

0.073

1.118

0.213

0.128

0.89

0.089

model N0x/SO2

measured N0x/SO2

0.4180.306

0.6860.727

0.9191.696

0.520.73534

0.7870.56948

0.2570.6705

0.160.96933

0.2761.0297

1.0620.525

0.3680.673

0.8570.81429

0.848

0.203

0.288

0.312

0.207

0.317

1.314

0.63

0.416

0.479

0.621

1.044

0.148

0.215

0.639

0.924

0.846

0.83

0.214

model CO/C2H2

measured CO/C2H2

53.85152.315

58.03954.529

68.8959.74

53.21454.134

61.62954.359

46.78859.455

38.05343.515

54.73284.318

51.75371.618

44.2652.08

47.98158.621

52.05974.356

33.65563.51

50.30164.996

44.06159.014

46.76658.87

60.71663.305

50.8758.888

53.398

47.037

48.734

53.169

56.174

30.825

35.056

55.779

45.593

51.634

60.093

33.377

model O3/CO

measured O3/CO

53.85154.134

58.03954.359

68.8984.318

53.21471.618

61.62952.08

46.78858.621

38.05374.356

54.73263.51

51.75364.996

44.2659.014

47.98158.87

52.05963.305

33.65541.439

50.301

44.061

46.766

60.716

50.87

53.398

47.037

48.734

53.169

56.174

30.825

35.056

55.779

45.593

51.634

60.093

33.377

model O3/NOx

measured O3/NOx

Graph1

27783154131

4201914191216763

Wuhan558164742

Taiyuan7212121611791

7983314353

3158842Hongkong434

Guiyang1144533331

ChongqingChongqingChongqing21Chongqing2142

4973111121

71177251810213

4448710221214144Shanghai

252120108241Seoul-Inchon1

201710148Pusan3123

395310KinkiKinkiKinkiKinkiKinki

301218TokyoTokyoTokyoTokyoTokyoTokyoTokyo

SaigonSaigonSaigonSaigonSaigonSaigonSaigonSaigonSaigonSaigon

Manila52Manila1ManilaManila211

0-0.5

0.5-1

1-1.5

1.5-2

2-2.5

2.5-3

3-3.5

3.5-4

4-4.5

4.5-5

tmp

0-0.50.5-11-1.51.5-22-2.52.5-33-3.53.5-44-4.54.5-55-5.5

Beijing277831541312

Tianjian4201914191216763

Wuhan5581647421

Taiyuan72121216117913

Guangzhou7983314353

Hongkong31588424341

Guiyang1144533331

Chongqing212142

Santou4973111121

Qingdao71177251810213

Shanghai44487102212141443

Seoul-Inchon25212010824111

Pusan2017101483123

Kinki395310

Tokyo301218

Saigon

Manila5212111

Bangkok1473

Graph1 (new)

0216649115

41323141244640

43621745400

0000100200

0024114854

00002110376

2025101021

22041010011

0000000000

0200000000

319180000000

11845540100

91430157101

0000000000

0000000000

0-0.5

0.5-1

1-1.5

1.5-2

2-2.5

2.5-3

3-3.5

3.5-4

4-4.5

4.5-5

tmp (new)

0-0.50.5-11-1.51.5-22-2.52.5-33-3.53.5-44-4.54.5-55-5.5

Beijing277831541312

Tianjian4201914191216763

Wuhan5581647421

Taiyuan72121216117913

Guangzhou7983314353

Hongkong31588424341

Guiyang1144533331

Chongqing212142

Santou4973111121

Qingdao71177251810213

Shanghai44487102212141443

Seoul-Inchon25212010824111

Pusan2017101483123

Kinki395310

Tokyo301218

Saigon

Manila5212111

Bangkok1473

tmp(old)

0-0.50.5-11-1.51.5-22-2.52.5-33-3.53.5-44-4.54.5-55-5.5

Beijing021664911550

Shanghai4132314124464010

Qingdao4362174540000

Chongqing000010020000

Wuhan002411485410

Guiyang0000211037620

Guangzhou202510102100

Hong Kong2204101001110

Bangkok000000000000

Manila020000000000

Tokyo31918000000000

Seoul1184554010050

Pusan9143015710100

Dhaka000000000000

Calcutta000000000000

000000000000

000000000000

000000000000

000000000000

The BC and CO Concentrations are Underpredicted but the Ratios are Accurately Captured!!DBC/DCOThis analysis suggests we need to look for improvements in a specific sector

Chart1

0.447020.76023

0.444480.8119

0.734110.1854

0.893840.79134

0.154810.22514

0.748510.84318

0.346221.0444

0.282920.77035

0.295471.1696

0.663811.1388

0.695591.0844

0.721281.0771

0.755191.0732

0.741751.0573

0.716131.1741

0.664491.179

0.657121.182

0.627380.77323

0.41710.4603

0.388890.1252

0.347230.65326

0.47542

model BC/CO

measured BC/CO

CO Concentration

BC Concentration

Beijing

Beij_ageless1

###Casenamejdayage(day)time(GMT)LAT(degree)LON(degree)Alt(m)O3(ppbv)CO(ppbv)NO(ppbv)NO2(ppbv)CO(ppbv)BC(ug/stdm3)NOy(ppbv)NOx(ppbv)SO2(ppbv)SO4(ppbv)HNO3(ppbv)NoiNoiSO2+SO4SO2(ppbv)SO4(ppbv)SO2+SO4CO(ppbv)SO2+SO4SO2+SO4Ethyne(ppbv)RNO3(ppbv)CO(ppbv)Ethane(ppbv)Ethane(ppbv)Propane(ppbv)Ethene(ppbv)Ethane(ppbv)Ethyne(ppbv)Propene(ppbv)Ethyne(ppbv)CO(ppbv)formaldehyde(ppbv)formaldehyde(ppbv)acetadehyde(ppbv)acetone(ppbv)PAN(ppbv)MEK(ppbv)SO2+SO4BC(ug/stdm3)ARO1(ppbv)BC(ug/stdm3)model O3(ppbv)model CO(ppbv)model NO (ppbv)model NO2 (ppbv)model NOy(ppbv)model NOx(ppbv)model HNO3(ppbv)mN0imodel SO2 (ppbv)model SO4(ppbv)mSO2+mSO4model RNO3(ppbv)model Ethane(ppbv)model Propane (ppbv)model Ethene(ppbv)model Propene(ppbv)model Ethyne(ppbv)model formaldehyde (ppbv)model acetaldehyde(ppbv)model acetone(ppbv)model PAN (ppbv)model MEK(ppbv)model ARO1(ppbv)model BC(ug/std m3)Chloride (ppbv)Nitrate (ppbv)Sodium (ppbv)Ammonium (ppbv)Potassium (ppbv)Magnesium (ppbv)Calcium (ppbv)Aerosol_absorption_565_nm (m-1)Scatter_550_nm (m-1)Volume_dry_.1-.75 (um3/cm3_ambient)Volume_.75-2 (um3/cm3_ambient)Volume_2-5 (um3/cm3_ambient)Volume_5-20 (um3/cm3_ambient)FSSP integral volume 0.3 um

Domestic Sector??

The Importance of Fossil, Biofuels and Open Burning Varies by Region -- Richness of Emissions Data Base Can be Exploited

abCan Useful Emissions Information Be Reconstructed Using Observed Ratios (or Concentrations) ? Estimated EmissionsObservation Based Reconstruction

Regional Emission Signals Can be Identified and TestedEthyneTwo Relationships Are ObservedRed Points Come From SE Asia With Heavy Influence From Biomass Burning

Top Down Approach (Inversion) emissions model predicted-fields compare predicted with observed emission inferencesKasabhatla et al., GRL, 2003

U. Iowa/Kyushu/Argonne/GFDLWith support from NSF, NASA (ACMAP,GTE), NOAA, DOE, JST

Improvements Emissions Require Creative Combination of Bottom-Up and Top-Down ApproachesModeledObservedBottom-Up Estimates

CFORS/STEM-2K1 Model Data Flow ChartLarge-scale Meteorological Fields (JMA, NCEP, ECMWF CFORS/RAMS

STEM-2K1On-Line TUV

wind velocities, temperature, pressure,water vapor content, cloud water content, rain water content and PV etc.Dust, Sea Salt, Lightning NOxBiogenicEmisisonsEmission PreprocessorBiomass EmissionsVolcanic SO2 EmissionsAnthropogenic Area EmissionsFuel/activity infoLarge PointSourcesSatellite Observations (fire counts, ozone columns, sea surface temperature, etc.)ForecastsOr PostAnalysisTracers/Markers:SO2/SulfateDMSBCOCVolcanicMegacitiesCO fossilCO-BiomassEthaneEtheneSea SaltRadonLightning NOx Dust 12 size bins

(b)BEJ (Beijing), TIJ (Tianjin), QID (Qingdao), SHA (Shanghai), HOK (Hongkong), SEL (Seoul-Inchon), PUS (Pusan), TOK (Tokyo)Using Observed Megacity Ratios Can We Cluster Cities?Extension to particles

Speciation of NMVOC Reveals Great DifferencesAmong Countries with Different Levels ofEconomic DevelopmentCitiesCountries

Chart6

105.6884611.63155228.58363539.31332713.84661525.5645670493

78.0078252.01953133.55086124.30263814.83651627.1721441961

176.9278555.48101338.04287678.112197171.19287985.541865798

192.1448293.971465155.99997222.6364517.37326267.9615309288

480.44889411.846635537.669467135.35814612.5327406184.9560425385

50.665584.22459523.60855230.1000420.20197980

240.9355455.44093829.10395344.71239385.449454283.4835273767

289.9644044.67374164.794883105.862542424105.2825714227

126.2208773.80211582.60119396.121119546306.962938166

121.5538081.9708486.62081287.759013182205.0750815624

107.3493055.2777648.77621286.465903950607.0006615614

105.3007561.1573180.23225999.47887173310.18189405330.3718903878

106.5240411.56599526.67656514.81654852617.074488568914.4641028654

38.0686751.10066107.93783667.79148719030.06740663880.1378158361

295.4646511.86333566.9318372.61921655056.810797139113.9249741455

33.49732501720.638726828130.992528015215.663395758800

301.34983165361.1267343602462.701123353276.3366430818143.1401163409439.1094

3721.74013590.9409755317.355771321.9444174288.059951122691.0881133057

1652.4229242.905781147.948283875.64081515.48625122542.7863799592

1795.16922494978.63850020333637.22283270121291.15061125084328.80901814345690.5924042293

1362.900882052854.9282873323781.7854032162451.88351455915018.15955505912992.8716953177

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (NMVOC, wt %)

Summary

SUMMARY OF ANTHROPOGENIC EMISSIONS IN ASIA IN THE YEAR 2000

RegionEmissions from Energy, Industry, and Agriculture (Tg)

CONMVOCBCOC

China20.3010.533534100.036.8414.740.942.6613.34

Other East Asia2.314.33194115.034.363.730.100.200.88

of which, Japan0.802.1911996.581.031.880.0520.0620.35

of which, Rep. of Korea0.831.324082.661.101.130.0210.0220.17

Southeast Asia3.153.06117334.0419.5011.060.321.372.96

South Asia7.104.76203362.340.8510.670.662.829.42

of which, India5.464.05168751.131.118.630.522.197.23

International Shipping1.081.29510.120.000.030.0680.0510.00

Asia Total33.9523.978731211.1101.540.232.097.0926.60

RegionEmissions from Biomass Burning (Tg)

CONMVOCBCOC

China0.080.8228315.740.542.690.110.730.23

Other East Asia0.000.21623.140.120.540.0210.200.05

Southeast Asia0.171.0652231.631.845.690.211.550.41

of which, Indonesia0.050.311508.960.531.610.0590.440.12

South Asia0.100.7126916.600.612.990.110.860.23

of which, India0.070.5419912.260.422.210.0830.650.17

Asia Total0.372.80113767.13.1011.920.453.330.92

RegionTotal Anthropogenic Emissions (Tg)

CONMVOCBCOC

China20.3911.353817115.837.3817.431.053.3813.57

Other East Asia2.334.53200318.174.474.280.120.390.92

of which, Japan0.802.2012036.811.041.920.0530.0740.35

of which, Rep. of Korea0.831.324112.821.111.160.0220.0280.17

Southeast Asia3.324.12169565.721.3516.750.532.923.37

South Asia7.195.47230278.941.4513.660.773.689.65

of which, India5.544.59188663.331.5310.840.602.847.40

International Shipping1.081.29510.120.000.030.0680.0510.00

Asia Total34.3226.779868278.6104.752.22.5410.4227.52

This work is sponsored by the TRACE-P project of the National Aeronautics and Space Administration. See the following web site for further information on this inventory, including access to gridded emissions data: http://www.cgrer.uiowa.edu/EMISSION_DATA/

megacity_ratio

WtREGIONIndustry (Gg)Power Generation (Gg)Transport (Gg)Dom_fos (Gg)Dom_bio (Gg)Biomass Burning (Gg)Total (Gg)

SO2Beijing124.3169.07.657.80.00.1358.8

Tianjin115.0222.911.039.70.00.2388.8

Hebei511.3637.923.2176.70.02.21351.3

Shanghai153.0328.216.520.00.00.2517.8

Jiansu/Anhui/Zhejiang888.01050.477.0158.80.04.82178.9

Hong Kong9.864.60.61.30.00.076.3

Guangdong364.1397.231.150.80.02.2845.3

Tokyo53.571.725.612.30.00.2163.2

Chubu62.856.513.311.20.00.2143.9

Osaka50.240.314.010.20.00.2114.8

Chugoku98.439.47.110.00.00.2155.1

Seoul, Inchon287.623.125.138.70.00.0374.5

North122.027.73.45.80.00.4159.2

Pusan38.936.372.126.40.00.0173.6

South69.934.415.51.00.00.4121.1

Singapore17.8134.83.66.90.00.0163.2

Malaysia134.797.319.68.60.012.9273.1

China7353.210028.7408.62512.20.082.620385.3

Other Easia1296.4613.4228.9174.50.021.02334.2

SE Asia1285.51181.8295.3387.30.0169.63319.4

S Asia2430.23504.7569.7591.40.098.07194.0

NOxREGIONIndustry (Gg)Power Generation (Gg)Transport (Gg)Dom_fos (Gg)Dom_bio (Gg)Biomass Burning (Gg)Total (Gg)

Beijing47.586.278.814.20.01.4228.1

Tianjin49.0119.375.111.00.01.7256.2

Hebei192.7241.5190.940.00.020.9686.1

Shanghai62.3192.1122.14.40.01.9382.9

Jiansu/Anhui/Zhejiang413.2615.2331.975.60.045.01480.8

Hong Kong6.681.157.72.80.00.0148.2

Guangdong133.5184.4328.519.10.019.3684.8

Tokyo66.476.8439.238.90.01.2622.6

Chubu77.950.9227.626.80.01.6384.9

Osaka62.934.7239.726.70.01.2365.1

Chugoku75.357.0122.218.80.01.6274.9

Seoul, Inchon153.457.2299.740.50.00.1550.9

North37.246.362.26.60.03.5155.8

Pusan14.940.1298.426.20.00.0379.7

South21.346.1158.36.50.03.4235.6

Singapore34.845.9103.40.60.00.0184.6

Malaysia71.1142.3209.713.70.057.2494.0

China2790.44406.52631.7702.00.0816.211346.8

Other Easia924.8707.42423.8269.90.0208.94534.8

SE Asia397.3657.81753.1249.50.01064.84122.5

S Asia825.71379.91880.4673.70.0711.65471.3

COREGIONIndustry (Gg)Power Generation (Gg)Transport (Gg)Dom_fos (Gg)Dom_ bio (Gg)Biomass Burning (Gg)Total (Gg)

Beijing545.00.01731.3295.5123.432.42727.6

Tianjin361.40.0968.8220.4135.042.01727.7

Hebei1412.20.02791.4646.71454.9500.66805.8

Shanghai831.10.01111.5102.066.646.72157.8

Jiansu/Anhui/Zhejiang2431.40.04404.8526.95189.91079.913632.9

Hong Kong0.00.0125.50.41.60.0127.4

Guangdong677.70.04322.8218.9681.4484.76385.5

Tokyo221.70.01581.42.138.829.51873.5

Chubu260.40.0819.21.951.238.81171.5

Osaka208.30.0862.41.737.328.31138.1

Chugoku408.10.0440.21.751.439.1940.5

Seoul, Inchon391.00.0401.03.21.12.2798.6

North165.80.054.00.544.283.9348.4

Pusan52.80.01153.52.20.40.81209.7

South95.00.0248.50.142.680.8466.9

Singapore0.00.0138.10.00.00.0138.1

Malaysia30.00.02705.022.6425.02369.85552.5

China17998.50.038001.18217.135789.115742.9115748.7

Other Easia3974.70.09069.925.31960.03143.318173.1

SE Asia727.90.012688.2351.620276.731630.765675.2

S Asia6449.80.017794.7305.637696.216603.578849.7

BCREGIONIndustry (Gg)Power Generation (Gg)Transport (Gg)Dom_fos (Gg)Dom_bio (Gg)Biomass Burning (Gg)Total (Gg)

Beijing3.80.51.51.71.60.29.4

Tianjin1.40.51.25.21.70.310.3

Hebei9.50.14.725.318.83.762.2

Shanghai4.30.61.00.60.90.37.8

Jiansu/Anhui/Zhejiang10.30.68.49.567.08.1103.7

Hong Kong0.20.10.40.00.00.00.8

Guangdong3.10.85.24.48.83.625.8

Tokyo1.04.37.30.60.50.214.0

Chubu2.03.33.80.60.70.310.6

Osaka1.22.54.00.50.50.28.8

Chugoku1.81.42.00.50.70.36.8

Seoul, Inchon4.91.01.71.40.00.09.1

North0.40.50.20.20.60.62.5

Pusan0.11.34.91.00.00.07.4

South0.20.51.10.00.50.62.9

Singapore1.01.70.40.00.00.03.1

Malaysia1.70.83.30.15.515.126.4

China88.96.859.8317.9462.8112.41048.6

Other Easia18.520.532.46.625.620.8124.4

SE Asia10.45.437.14.0263.7208.2529.0

S Asia20.22.785.18.6542.5112.3771.4

OCREGIONIndustry (Gg)Power Generation (Gg)Transport (Gg)Dom_fos (Gg)Dom_bio (Gg)Biomass Burning (Gg)Total (Gg)

Beijing0.70.41.41.48.01.213.1

Tianjin0.60.41.04.38.71.516.5

Hebei1.70.13.920.693.918.2138.3

Shanghai0.80.50.90.54.31.78.7

Jiansu/Anhui/Zhejiang4.00.47.17.8334.839.7393.9

Hong Kong0.20.10.40.00.10.00.8

Guangdong1.80.65.43.644.018.173.5

Tokyo0.63.28.10.52.51.416.4

Chubu1.52.44.20.43.31.913.8

Osaka0.61.84.40.42.41.411.1

Chugoku0.71.12.30.43.31.99.6

Seoul, Inchon3.70.81.61.10.10.17.4

North0.10.30.20.22.93.26.9

Pusan0.01.04.70.80.00.06.5

South0.00.31.00.02.73.17.3

Singapore0.81.30.40.00.00.02.5

Malaysia1.30.63.90.127.4117.4150.7

China27.65.152.0258.22314.0728.13385.0

Other Easia12.615.434.55.1128.1195.4391.0

SE Asia7.94.136.93.21318.31547.72918.1

S Asia11.22.082.96.82712.7860.03675.5

NMVOCREGIONIndustry (Gg)Power Generation (Gg)Transport (Gg)Dom_fos (Gg)Dom_bio (Gg)Biomass Burning (Gg)Total (Gg)

Beijing105.71.6228.639.313.85.6394.6

Tianjin78.02.0133.624.314.87.2259.9

Hebei176.95.5338.078.1171.285.5855.3

Shanghai192.14.0156.022.67.48.0390.1

Jiansu/Anhui/Zhejiang480.411.8537.7135.4612.5185.01962.8

Hong Kong50.74.223.630.10.20.0108.8

Guangdong240.95.4829.144.785.483.51289.1

Tokyo290.04.7164.8105.90.05.3570.6

Chubu126.23.882.696.10.07.0315.7

Osaka121.62.086.687.80.05.1303.0

Chugoku107.35.348.886.50.07.0254.9

Seoul, Inchon105.31.2180.299.50.20.4386.7

North106.51.626.714.87.114.5171.1

Pusan38.11.1107.967.80.10.1215.1

South295.51.966.92.66.813.9387.6

Singapore33.50.631.015.70.00.080.8

Malaysia301.31.1462.776.3143.1439.11423.8

China3721.790.95317.41321.94288.12691.117431.1

Other Easia1652.442.91147.9875.615.5542.84277.2

SE Asia1795.28.63637.21291.24328.85690.616751.6

S Asia1362.954.93781.8451.95018.22992.913662.5

megacity_ratio

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (SO2, wt %)

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (NOx, wt %)

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_ bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (CO, wt %)

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (BC, wt %)

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (OC, wt %)

Industry (Gg)

Power Generation (Gg)

Transport (Gg)

Dom_fos (Gg)

Dom_bio (Gg)

Biomass Burning (Gg)

Sectoral Contrbution (NMVOC, wt %)

Ethyne

Use of Chemical Transport Models in Atmospheric Chemistry Field Experiments to Test/Improve Emissions

Combine with trajectories..on next slide