attachment no. g resource use and energy efficiency … · this application is seeking permission...

28
Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G G - 1 of 28 October 2009 ATTACHMENT No. G RESOURCE USE AND ENERGY EFFICIENCY TABLE OF CONTENTS G.1. Raw Materials, Intermediates and Products .........................................................2 G.2. Energy Efficiency ........................................................................................................3 For inspection purposes only. Consent of copyright owner required for any other use. EPA Export 26-07-2013:16:18:36

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  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 1 of 28

    October 2009

    ATTACHMENT No. G

    RESOURCE USE AND ENERGY EFFICIENCY

    TABLE OF CONTENTS

    G.1. Raw Materials, Intermediates and Products ......................................................... 2

    G.2. Energy Efficiency ........................................................................................................ 3

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  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

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    October 2009

    G.1. Raw Materials, Intermediates and Products G.1.1 Raw Materials and Process Materials

    The principal raw materials, by-products and ancillary materials used at Irish Cement Ltd (ICL) Platin Works are listed in Tables G.1(i) and G.1(ii). The associated risk and safety phrases have been obtained from the relevant Safety Data Sheets.

    G.1.2 Process Intermediates

    There are three process intermediates associated with ICL’s activities. They are:

    • Raw meal

    • Clinker

    • By-pass and filter dusts

    Raw meal is the product of primary crushing of limestone, shale, bauxite and iron oxide. The Raw meal is blended in homogenising silos before being converted to cement clinker in the kiln systems.

    Clinker is the main component of cement.

    By-pass dust and filter dust are generated in the by-pass and filter systems. This material is all transported by screw conveyor and then returned into the process stream.

    G.1.3 Finished Products

    Five types of finished product cement are produced at ICL. They are:

    • CEM I Normal Portland Cement

    • CEM II Portland Limestone Cement

    • CEM I Rapid Hardening Portland Cement

    • Sulphate Resisting Portland Cement

    • Slag Binder

    • Specials according to market requirements.

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    G.2. Energy Efficiency G.2.1 Energy Usage

    Energy is consumed at ICL in the form of petroleum coke (coal may also be used), diesel oil and electricity. Small quantities of propane gas are consumed.

    Energy consumption data is provided to the Agency in the Annual Environmental Reports (AERs) (the 2008 AER is included in Attachment No. F) for the facility. Table G.1 summarises the energy consumption at the site for 2008.

    Table G.1 Energy Consumption (2008) at ICL

    Energy Source Unit Consumption

    Petroleum coke / coal tonnes 159,502

    Diesel / light fuel oil tonnes 1,835

    Electricity kWhrs 197,518,269

    This application is seeking permission to substitute some of the traditional fossil fuel types with Alternative Fuels in the Kiln 3 system.

    Table G.2 Maximum Quantities of Alternative Fuels as defined in Planning Permission SA803066

    Alternative Fuel Tonnes/year Solid Recovered Fuel (SRF) 90,000 Tyre chips 30,000 Meat and Bone Meal (MBM) 40,000

    A review is requested of IPPC Licence Reg. No. P0030-03 to allow for the substitution of a proportion of the fossil fuel currently used in Platin with the alternative fuels listed above, up to a maximum of 120,000 tonnes per annum when used in combination. Planning permission for this activity was received from Meath Co. Council on 26th February 2009. A copy of the planning permission is included in Attachment No. B. G.2.2 Energy Saving Measures

    The ICL environmental policy requires all its facilities to optimise the use of energy and material resources. ICL Platin Works operates under EPA Licence Reg. No. P0030-03. The primary aim of IPC/IPPC licensing is to prevent or reduce emissions to air, water and land, to reduce waste and to use energy efficiently. ICL Platin achieves this by using advanced, energy-efficient methods to create a range of high quality cements as well as operating under an established Environmental Management System (EMS). ICL Platin's EMS is to international standard ISO 14001, which strives to achieve continuous improvement in many environmental aspects, including energy use.

    An Environmental Management Plan (EMP) is agreed annually and provided to the Agency. The EMP sets targets and objectives for the year ahead and aims to achieve continuous improvement of the Environmental Management System.

    ICL is also committed to entering the Sustainable Energy Ireland (SEI) Energy Agreements Programme. This programme has been developed under the new Irish Energy Management Standard, IS 393 and provides companies with a structured approach to reducing energy costs and improving energy management through the implementation of a schedule of energy efficient measures.

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  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

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    IPPC Licence Application Tables

    G.1(i)

    G.1(ii)

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    Table G.1(i) Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes) 1 Limestone N/A None 60,000 1,806,825 Cement production N/A N/A 2 Shale N/A None 21,000 13,042 Cement production N/A N/A

    3 Clay Overburden N/A None 40,000 m3 477,764 Cement production N/A N/A

    4 Ground granulated Blast Furnace Slag N/A Irritant 1,500 41,788 Foundry by-product N/A N/A

    5 Bauxite (Aluminium hydroxide) 21645-51-2 Irritant 2,000 m3 74,037 Process intermediate R36 S26

    6 Iron (III) oxide 1309-37-1 Irritant 400 m3 7,173 Process intermediate R36/37/38 S26 7 Pulverised Fly Ash N/A None 0 0 Cement production None None 8 Raw Meal N/A None 35,000 2,250,000 Process intermediate None None 9 Clinker N/A None 120,000 1,450,000 Process intermediate None None

    10 Cement Mixture Irritant 60,000

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes) 23 Tin Sulphate 7488-55-3 Irritant 5 180 Process Intermediate R36/37 S22/26 24 Ferrous Sulphate 7720-78-7 Harmful 60 515 Cement additive R22/38, R37 S2, S46 25 Acetic Acid 64-19-7 Corrosive, Flammable 2.5 L 2.5 L Laboratory chemical R10, R35 S2, S23, S26

    26 Ammonia Soln. 35% 1336-21-6 Corrosive, Dangerous for the environment 2.5 L 0.1 L Laboratory chemical R34-50 S26-36/37/39-45-61

    27 Ethylene Glycol 107-21-1 Harmful 2,000 L 4,000 L Laboratory chemical R22 S2 28 Hydrochloric Acid 7647-01-0 Corrosive 50 L 160 L Laboratory chemical R34, R37 S2, S26 29 Kerosene/Paraffin 8008-20-6 Flammable, Harmful 5 L 2 L Laboratory chemical R10, R38 S16, S36

    30 Kerosene for degreasing (Safety Kleen) 64742-47-8 Harmful, Flammable 0 500 L Degreasing machine parts

    R10, R38, R51/53, R65,66

    S16, 23, 24, 43, 61, 62

    31 Methylated Spirit 99% 64-17-5 Highly flammable, Harmful 100 L 50 L Laboratory chemical R11-20/21/22-68/20/21/22 S16, 23, 24, 33, 36/37-45

    32 Nitric Acid 7697-37-2 Oxidising, Corrosive 7.5 L 0.5 L Laboratory chemical R8, R35 S23, S26, S36

    33 Potassium Hydroxide 40% 1310-58-3 Harmful, Corrosive 2.5 L 2.5 L Laboratory chemical R20, R21, R22, R35, R41

    S26, S36, S37, S39, S45

    34 Triethanolamine 102-71-6 None 100 L 1 L Chemical Regent R36, R38 S26, S36

    35 Lithium Tetraborate 12007-60-2 None 0.07 0.11 Laboratory chemical R36, R37, R38 None

    36 Paraffin/Binding Wax 8002-74-2 None 0.025 0.07 Laboratory chemical None None 37 Sodium Carbonate 497-19-8 None 0.005 0.0025 Laboratory chemical R36, R37 S22, S26

    38 Barium Chloride 10326-27-9 Dangerous for the environment, Harmful 0.001 L

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes) R23, R33

    44 Tickopur RW77 Mixture Irritant 5 L 1 L Laboratory chemical R36/38 S2 S26-37/38 45 Tickopur R27 Mixture Corrosive 5 L 1 L Laboratory chemical R34 S2 S26-37/39

    46 Hydrochloric acid 0.1N 7647-01-0 Corrosive, Toxic 15 L 50 L Laboratory chemical R23 R24 R25 R34 R36 R37 R38

    S26 S36 S37 S39 S45

    47 Hydrochloric acid 37% 7647-01-1 Corrosive, Toxic 15 L 20 L Laboratory chemical R23 R24 R25 R34 R36 R37 R39

    S26 S36 S37 S39 S46

    48 Sulphuric acid (98%) 7664-93-9 Corrosive, Toxic 6 L 6 L Laboratory chemical R23 R24 R25 R35 R36 R37 R38 R49

    S23 S30 S36 S37 S39 S45

    49 Nitric acid (70%) 7697-37-2 Harmful, Oxidising, Corrosive 5 L 0.5 L Laboratory chemical R8 R23 R24 R25 R34 R41

    S23 S26 S36 S37 S39 S45

    50 Xylene 108-38-3 Flammable, Harmful, Toxic 2.5 L

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes)

    63 Hydrofluoric acid (48%) 7664-39-3 Corrosive, Very Toxic 2 L

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes)

    85 Bromo cresol green indicator 76-60-8 Highly Flammable, Toxic 0.00005 0.000005 Laboratory chemical R11-23/25-36/38 S7-16-24-33-45

    86 Buffer solution pH 10 N/A Irritant 1 L 0.5 L Laboratory chemical R36/38 S26 87 Buffer solution pH 4 N/A Irritant 1 L 0.5 L Laboratory chemical None None

    88 Potassium hydroxide soln. 40% 1310-58-3 Corrosive, Harmful 2 L 0.5 L Laboratory chemical R35 S26-36/37/39-45

    89 Sodium hydrogen Carbonate 144-55-8 None 0.0002 0.000025 Laboratory chemical None None

    90 Potassium hydroxide pellets Granulated 1310-58-3 Corrosive 0.0005

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes) 106 Oxygen 07782-44-7 Oxidising 660 m3 3,500 m3 Compressed Air R8 S9, S17 107 Carbon dioxide 00124-38-9 None 200 m3 200 m3 Compressed Air None S9, S23 108 Alumina Refractory Bricks N/A None 3,600 550 Refractory material None None

    109 Mag. Spinel Refractory Bricks Mixture None 600 100 Refractory material None None

    110 Lightweight Refractory Bricks Mixture None 30 35 Refractory material None None 111 Refractory Castable N/A None 20 25 Refractory material None None

    112 Sodium Silicate 1344-09-8 Harmful, Corrosive 2.2 3.5 Brick installation R22, R34, R38, R41

    S23, S24, S25, S26, S27, S36, S37, S39

    113 Ag Mortar 1309-48-4 None 6 6 Used for laying refractory bricks. None None

    114 Ox Mortar Mixture None 5 5 Used for laying lightweight refractory bricks.

    None None

    115 Dsf. 80 P Cement Mixture None 4 4 Used in laying high alumina refractory mills. R37, R40 None

    116 Mobilplex 47 N/A None 0

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes) 126 Castrol RX 10 - 208L barrel N/A None 208 L

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes) 148 Hyspin Aws 10 N/A None 400 L 800 L Engineering material None None 149 Hyspin Aws 46 N/A None 624 L 625 L Engineering material None None 150 Hyspin Aws 32 N/A None 800 L 4000 L Engineering material None None 151 Castrol SRG Grease N/A Irritant 0.0125

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes)

    171 Grippa 60 S 400 g Mixture Harmful, Flammable 0

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    Ref. No or

    Material/ Substance(1)

    CAS Number

    Danger(2) Category

    AmountStored

    Annual Usage

    Nature of Use R(3) - Phrase S(3) - Phrase

    Code (tonnes) (tonnes)

    198 Cleanline lavender polish mixture Extremely flammable, pressurised container 0.25 L 2 L Furniture polish R12, 66 S16, 2, 23A, 51

    199 E-Pine Disinfectant None none 5 L 20 L disinfectant None S2, S26, S46 200 Pink pearl soaps None None 5 L 20 L Hand and body soap None None 201 Calgonite Lemon Gel None None 5 L 20 L Hard surface cleaner None None

    202 Sundance Floor cleaner 68439-50-9 None 5 L 20 L Concentrated floor cleaner None None

    203 TTC Cleaner None Irritant 1 L 10 L Toilet cleaner and descaler None None

    204 Suma Max D9.2 None Irritant 5 L 10 L Kitchen Cleaner R 36/38 S23,26,37,51 205 Suma Scale D5.2 None Irritant 5 L 10 L Kitchen Cleaner R 36/38 S23,26,37,51 206 Suma Inox Classic D.7 None None 5 L 10 L Kitchen Cleaner None None 207 Suma Multi Conc. D.2 None Harmful 5 L 10 L Kitchen Cleaner R22,37/38,41 S23,26,37/39

    208 Suma Bac Multi Conc. D.10 None Corrosive 5 L 10 L Kitchen Cleaner R34 S26,28, 36/37/39, 45

    209 Suma Lima L3 None Corrosive 25 L 50 L Dishwasher detergent R31, 35 S26,28, 36/37/39,45

    210 Suma Rince aid A5 None None 25 L 50 L Dishwasher detergent R 38, 41 S22, 26, 37/39 211 Suma Shine K2 None Irritant 5 L 10 L Kitchen cleaner R 38, 41 S22, 26

    212 Cleanline stainless steel cleaner mixture Extremely flammable, pressurised container 0.25 L 1 L Stainless steel cleaner R12, 66

    S16, 2, 23A, 51

    213 Descale 7647-01-0 Irritant 40 L 120 L Descaler R36/38 S1/2,24/25, 26, 36/37 214 Organic acid ZC 40 Mixture None 300 L 500 L Cleaning agent None None 215 Con-clean None Irritant 200 L 400 L Cleaning Agent None None

    216 Kluberfluid CF3 ultra – 180 kg None None 180 kg 180 kg Engineering material None None

    Notes: 1. In cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance. 2. c.f. Article 2(2) of SI No 77/94

    3. c.f. Schedules 9 and 10 of SI No 62/2004

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    Table G.1(ii) Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II 1 Limestone - No Not applicable - - - - - 2 Shale - No Not applicable - - - - - 3 Clay Overburden - No Not applicable - - - - -

    4 Ground granulated Blast Furnace Slag - No Not applicable - - - - -

    5 Bauxite (Aluminium hydroxide) - No Not applicable - - - - -

    6 Iron (III) oxide - Not available - - - - - 7 Pulverised fly ash - No Not applicable - - - - - 8 Raw Meal - No Not applicable - - - - - 9 Clinker - No Not applicable - - - - - 10 Cement - No Not applicable - - - - -

    11 Gypsum - Yes Slight musty odour Not available - - - -

    12 Coal - No Not applicable - (7) - (7) - 13 Petroleum Coke - No Not applicable - (7) - (7) -

    14 Solid Recovered Fuel (SRF) - No Not applicable - - - - -

    15 Tyre Chips - No Not applicable - - - - -

    16 Meat and Bone Meal (MBM) - No Not applicable - - - - -

    17 Light Fuel Oil - Yes Asphaltic odour Not available (7) - (7) -

    18 Diesel - Yes Pungent petroleum odour Not available (7) - (7) -

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    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II 19 Propane - No Not applicable - - - - -

    20 Ammonia water soln 24.5% - Yes Ammonia odour Not available - - - (7)

    21 Grinding aid Type 1 - Yes Slightly ammonical Not available - - - -

    22 Grinding aid Type 2 - Yes Characteristic Not available - - - -

    23 Tin Sulphate - No Not applicable - - (1) - (1) 24 Ferrous Sulphate - No Not applicable - - - -

    25 Acetic Acid II Yes Strong, vinegar - like Not Available - (3) - (3)

    26 Ammonia Soln. 35% - Yes Pungent characteristic odour Not

    Available - (8) - (7)

    27 Ethylene Glycol III Yes Almost odourless - - - - -

    28 Hydrochloric Acid - Yes Pungent

    Not Available - - - -

    29 Kerosene/Paraffin III Yes Petroleum hydrocarbon odour

    Not

    Available (7) - (7) -

    30 Kerosene for degreasing (Safety Kleen) III Yes Petroleum hydrocarbon odour

    Not available (7) - (7) -

    31 Methylated Spirit 99% I Yes Fresh, characteristic Not available - - - -

    32 Nitric Acid - Yes Pungent Not available - - - -

    33 Potassium Hydroxide 40% - No Not applicable - - - - - 34 Triethanolamine - No Not applicable - - - - - 35 Lithium Tetraborate - No Not applicable - - - - -

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    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II 36 Paraffin/Binding Wax III No Not applicable - - - - - 37 Sodium Carbonate - No Not applicable - - - - - 38 Barium Chloride - No Not applicable - - - - -

    39 Ammonium thiocyanate - Yes Slight ammonia odour Not available - - - -

    40 Silver Nitrate - No Not applicable - - (1) - (1)

    41 Acetone III Yes Fragrant, mint-like Not available - - - -

    42 Citric acid monohydrate - No Not applicable - - - - - 43 Mercury - No Not applicable - (5) - (5)

    44 Tickopur RW77 - Yes

    Weak ammonia odour

    Not available - - - -

    45 Tickopur R27 - Yes Weak characteristic odour Not

    available - - - -

    46 Hydrochloric acid 0.1N - Yes Pungent odour Not available - - - -

    47 Hydrochloric acid 37% - Yes Pungent odour Not available - - - -

    48 Sulphuric acid (98%) - No Not applicable - - - - -

    49 Nitric acid (70%) - Yes Pungent Not available - - - -

    50 Xylene II Yes Light, aromatic Not available - - -

    51 Kerosin (Kerosene) III Yes Petroleum hydrocarbon odour Not

    Available (7) - (7) -

    52 Hydrogen peroxide soln. 5 % - Yes Slight acrid odour Not

    available - - - -

    53 Nitrogen Gas - No Not applicable - - - - -

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    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II 54 Oxygen (High purity) - No Not applicable - - - -

    55 Butane - Yes Slight Not available - - - -

    56 Aluminium oxide - No Not applicable - - - - -

    57 Shell Corena Oil P68 - Yes Low odour Not available (7) - (7) -

    58 Duckhams admix B3 - No Not applicable - - - - - 59 Castrol castcon 51 - Yes Sharp - (7) - (7) -

    60 Sikament HE 200 - Yes Pungent Not available - - - -

    61 DP Lubricant blue - Yes Alcohol odour Not available - - - -

    62 EDTA titration solution (0.2N) - No Not applicable - - - - -

    63 Hydrofluoric acid (48%) - Yes Acrid odour Not available - - - -

    64 Argon (90%) – Methane (10%) mixture gas - No Not applicable - - - - -

    65 Oxalic acid - No Not applicable - - - - -

    66 Diethyl ether - Yes Sweetish, pungent, ethereal Not

    available - - - -

    67 1,1,1-Trichloroethan - Yes Sweet Not

    available - - -

    68 Titanium dioxide - No Not applicable - - (1) - (1) 69 Zinc - granulated - No Not applicable - - (1) - (1) 70 Thymolphthalein - indicator - No Not applicable - - - - - 71 Quartz fine granular - No Not applicable - - - - - 72 Silica gel - No Not applicable - - (4) - (4) 73 Total Hardness indicator - No Not applicable - - - - -

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    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II tablets

    74 Benzoic acid - Not available - - - - -

    75 Methyl red indicator - Yes Alcohol odour Not available - - - -

    76 Phenolphthalein - No Not applicable - - - - - 77 High vacuum grease - No Not applicable - - - - - 78 Aluminium foil - No Not applicable - - - - -

    79 Potassium hydrogen sulphate - No Not applicable - - - - -

    80 Calcium Carbonate - No Not applicable - - - - - 81 Sodium Chloride - No Not applicable - - - - - 82 Cupric Sulphate - No Not applicable - - - - - 83 Sodium Hydroxide pellets - No Not applicable - - - - -

    84 Di-n-butyl phthalate - Yes Slight aromatic odour Not available - - - -

    85 Bromo cresol green indicator - No Not applicable - - - - -

    86 Buffer solution pH 10 - No Not applicable - - - - -

    87 Buffer solution pH 4 - Yes Slight thymol odour Not available - - - -

    88 Potassium hydroxide soln. 40% - No Not applicable - - - - -

    89 Sodium hydrogen carbonate - No Not applicable - - - - -

    90 Potassium hydroxide pellets Granulated - No Not applicable - - - - -

    91 Ammonium Iron (III) Sulphate dodecahydrate - No Not applicable

    - - - - -

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    EPA Export 26-07-2013:16:18:36

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 20 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II 92 1,5-DiphenylCarbazide - Not available - - - - - 93 Potassium dichromate - No Not applicable - - - - - 94 Pyrogallol solution 60% w/v - Not available - - - - - 95 Sulphamic acid - No Not applicable - - - - -

    96 Ammonium thiocyanate (0.1N) - No Not applicable - - - - -

    97 Boric acid - No Not applicable - - - - -

    98 Manometervaeske MF 0,88 ROD Indeholder petroleum - DiBromethane

    - No Not applicable - - - - -

    99 Lecocel II accelerator - No Not Applicable - - - - - 100 Potassium chloride - No Not applicable - - - - - 101 Pureshield argon - No Not applicable - - - - - 102 Propane - No Not applicable - - - - - 103 Nitrogen - No Not applicable - - - - - 104 Conplas 717 admixture - No Not applicable - - - - -

    105 Acetylene - Yes Garlic like Not available - - - -

    106 Oxygen - No Not applicable - - - - -

    107 Carbon dioxide - Yes Sharp in high concentrations Not

    available - - - -

    108 Alumina Refractory Bricks - No Not applicable

    - - - - -

    109 Mag. Spinel Refractory Bricks - No Not applicable - - - - -

    110 Lightweight Refractory Bricks - No Not applicable - - - - -

    111 Refractory Castable - No Not applicable - - - - -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 21 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II 112 Sodium Silicate - No Not applicable - - - - - 113 Ag Mortar - No Not applicable - - - - - 114 Ox Mortar - No Not applicable - - - - - 115 Dsf. 80 P Cement - Not available - - - - -

    116 Mobilplex 47 - Yes Mild Not available (7) - (7) -

    117 Mobil Rarus SHC 1024 Oil - Yes Mild Not available (7) - (7) -

    118 Magna 68 - 208 litre barrel - Yes Mild Not available (7) - (7) -

    119 Castrol Aircol Pd46 - 208 litre barrel - Yes Mild Not

    available (7) - (7) -

    120 Perfecto T68 - 208 liter barrel - Yes Oily Not

    available (7) - (7) -

    121 Super Cylinder 600W oil- 208 liter barrel - Yes Petroleum oil odour Not

    available (7) - (7) -

    122 Castrol TFC 410 - 208 barrel - Yes Mild Not

    available (7) - (7) -

    123 Cooledge BI (was FE) 25 liter drum) - Yes Mild Not

    available (7) - (7) -

    124 Cresta SHS - 208 litre barrel - Yes Mild Not

    available (7) - (7) -

    125 Creasta VA 3008 - 208 liter barrel - Yes Mild Not

    available (7) - (7) -

    126 Castrol RX 10 - 208L barrel - Yes Mild Not available (7) - (7) -

    127 Alpha Sp 68 208 L barrel - Yes Mild Not available (7) - (7) -

    128 Hyspin Aws 10 208L Liter - Yes Mild Not (7) - (7) -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 22 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II barrel available

    129 Agri Powertrans plus 10W30 - 208 liter barrel - Yes Mild Not

    available (7) - (7) -

    130 Airline oil series 200, No.097079 - 25 L - Yes Mild Not

    available (7) - (7) -

    131 Syntheso D 680 EP -180kg drum - Yes Product specific Not

    available (7) - (7) -

    132 Alpha Sp 1000 - Yes Mild Not available (7) - (7) -

    133 Acheson kiln tyre lubricant - Yes Mineral oil Not available - - - -

    134 Hyvis 7000/45 (polybutene) - Yes Characteristic Not available (7) - (7) -

    135 Alpha SP100 - 25 liter drum - Yes Mild Not available (7) - (7) -

    136 Syntheso D 1000 -180kg drum - Yes Product specific Not

    available (7) - (7) -

    137 Hyspin VG 32 oil - 25L drum - Yes Mild Not

    available (7) - (7) -

    138 Castrol VT2 Oil - 208 L - Yes Mild Not available (7) - (7) -

    139 Chevron Cetus PA046 oil (was synerol 32) - 25 liter - Yes Hydro carbon odour Not

    available (7) - (7) -

    140 Castrol 50W TFC450, transmission oil - 208 L - Yes Mild Not

    available (7) - (7) -

    141 Kaeser sigma fluid S-460 - 200 L - Yes Mild hydrocarbon Not

    available (7) - (7) -

    142 Mobil 10W40 Oil - Yes Mild Not

    available (7) - (7) -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 23 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II

    143 Optimal Optiflex A680 Oil - 18 L drums - Yes Mild Not

    available (7) - (7) -

    144 Agri HT Trans oil 205L barrell - Yes Mild Not

    available (7) - (7) -

    145 Hyspin Awh -M 46 - 25 L - Yes Mild Not available (7) - (7) -

    146 Castrol Aircol Pd32 - Yes Mild Not available (7) - (7) -

    147 Hyspin Aws 150 - Yes Mild Not available (7) - (7) -

    148 Hyspin Aws 10 - Yes Mild Not available (7) - (7) -

    149 Hyspin Aws 46 - Yes Mild Not available (7) - (7) -

    150 Hyspin Aws 32 - Yes Mild Not available (7) - (7) -

    151 Castrol SRG Grease - Yes Mild Not available (7) - (7) -

    152 Spheerol MP 2 Grease 50 kg - Yes Mild Not

    available (7) - (7) -

    153 Ceplattyn KG 10 Grease 200kg Drum - Yes Mineral oil Not

    available (7) - (7) -

    154 Fuchs Grease 50 kg drum - Yes Characteristic Not available (7) - (7) -

    155 Ceplattyn RN (einlauf) 190 kg Drum - Yes Mineral oil Not

    available (7) - (7) -

    156 Kluberfluid CF2 Ultra 16517 Coal Mill - Yes Product specific Not

    available (7) - (7) -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 24 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II

    157 Grafloscon BF1 for 26617 Coal Mill - No Not applicable - (7) - (7) -

    158 Ceplattyn 300 15 kg drum - Yes Mineral oil Not available (7) - (7) -

    159 Ceplattyn KG 10HMF2500 Grease 190 kg drum - Yes Mineral oil Not

    available (7) - (7) -

    160 Moly grease 12.5 kg - Yes Mild Not available (7) - (7) -

    161 Ceplattyn Grease KG10HMF2500, 610kg tank

    - Yes Mineral oil Not available (7) - (7) -

    162 Matrix grease 16.5 kg drums - Yes Mineral oil Not

    available (7) - (7) -

    163 Spheerol L EP2 Grease 50kg drum - Yes Mild Not

    available (7) - (7) -

    164 MobilgreaseXPH222 180kg drums - Yes Characteristic Not

    available (7) - (7) -

    165 ROCOL BRB Grease - Yes Faint Not available (7) - (7) -

    166 Wire rope lubricant - Yes Pleasant, mild odour Not available - - - -

    167 Alpha Sp 150 - Yes Mild Not available (7) - (7) -

    168 Alpha max Sp 220 optigear BM220 - Yes Mild Not

    available (7) - (7) -

    169 Alpha max Sp 320 optigear BM320 - Yes Mild Not

    available (7) - (7) -

    170 Grippa 33 - Yes Mild Not applicable (7) - (7) -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 25 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II

    171 Grippa 60 S 400 g - Yes Sharp Not available (7) - (7) -

    172 Adzorb - Not available - - - - 173 Supersil - No Not applicable - 174 Kemex - No Not applicable - - - - -

    175 Highnoon - Yes Mild ammonia Not applicable - - - -

    176 Evan Lift cleaner - Yes Faint Solvent Not applicable - - - -

    177 Evan Clean and shine - Yes Floral Not applicable - - - -

    178 Cleanfast - Yes Fragrant odour Not applicable - - - -

    179 Time Buster StripperYes - Yes Solvent odour Not available - - - -

    180 Sprint glass cleaner - Yes Spearmint Not available - - - -

    181 Ironstone acrylic seal - Yes Mild, ammonia Not available - - - -

    182 Speedball - Yes Slightly perfumed Not available - - - -

    183 Jam – 3005 Cleaner WB II - No Not available - - - - - 184 Black Ink - No Not available - - - - -

    185 Shell Transformer oil 148 25 L - Yes Oil-type odour Not

    available (7) - (7) -

    186 Silica gel with humidity indicator - No Not applicable - - - - -

    187 ALBIDA RL2 Grease - Yes Slight hydrocarbon odour Not applicable (7) - (7) -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 26 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II

    188 Chesterton cleaner 273 - Yes Mild odour Not available - - - -

    189 Contract Hard surface cleaner - No Not applicable - - - - -

    192 Evans Clear - Yes Alcoholic Not available - - - -

    193 Dextra Duo - Yes Fragranced Not available - - - -

    194 Dextra Anti-Bac - Yes Very mild fragranced Not available - - - -

    195 Johnson Glade Spring - Yes Characteristic

    Not available - - - -

    196 Contract Bleach - Yes Odour of hypochlorites Not available - - - -

    197 Galtec Dextra mild - Yes Fragranced Not available - - - -

    198 Cleanline lavender polish - Yes Lavender Not available - - - -

    199 E-Pine Disinfectant - Yes Fresh pine Not available - - - -

    200 Pink pearl soaps - Yes Floral Not available - - - -

    201 Calgonite Lemon Gel - Yes Citrus Not available - - - -

    202 Sundance Floor cleaner - Yes Characteristic Not available - - - -

    203 TTC Cleaner - Yes Violet Not available - - - -

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 27 of 28

    October 2009

    Ref. No or

    Material/

    TA Luft Class 1,

    Odour EU Lists I and II (Tick and specify Group/Family Number)

    Code Substance(1) 2 or 3 Odourous Yes/No

    Description

    Threshold

    Dangerous Substances Directive

    76/464/EEC

    Groundwater Directive 80/68/EEC

    µg/m3 List I List II +1294 List I List II

    204 Suma Max D9.2 - Yes Characteristic Not available - - - -

    205 Suma Scale D5.2 - Yes Characteristic Not available - - - -

    206 Suma Inox Classic D.7 - Yes Characteristic Not available - - - -

    207 Suma Multi Conc. D.2 - Yes Slightly perfumed Not available - - - -

    208 Suma Bac Multi Conc. D.10 - Yes Characteristic Not available - - - -

    209 Suma Lima L3 - Yes Chlorine like Not available - - - -

    210 Suma Rince aid A5 - Yes Characteristic Not available - - - -

    211 Suma Shine K2 - Yes Characteristic Not available - - - -

    212 Cleanline stainless steel cleaner - Yes Characteristic Not

    available - - - -

    213 Descale - No Odourless Not available - - - -

    214 Organic acid ZC 40 - Yes Characteristic Not available - - - -

    215 Con-clean - Yes Pleasant Not available - - - -

    216 Kluberfluid CF3 180 kg - Yes Product specific Not available - - - -

    Notes (cont.): 4. The European Commission priority candidate list 76/464/EEC List I (7): Persistent mineral oils and hydrocarbons of petroleum origin 76/464/EEC List I (5): Mercury and its compounds

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    EPA Export 26-07-2013:16:18:37

  • Irish Cement Ltd Platin Works IPPC Licence Review Attachment No. G

    G - 28 of 28

    October 2009

    76/464/EEC List II (1): Listed metalloids and their compounds 76/464/EEC List II (3): Substances which have a deleterious effect on the taste and/or smell of the products for human consumption derived from the aquatic environment, and compounds liable to give rise to such substances in water 76/464/EEC List II (4): Toxic or persistent organic compounds of silicon, and substances which may give rise to such compounds in water, excluding those which are biologically harmless and are rapidly converted in water into harmless substances. 76/464/EEC List II (8): Substances which have an adverse effect on the oxygen balance, particularly: ammonia, nitrites. 80/68/EEC List I (7): Mineral oils and hydrocarbons 80/68/EEC List I (5): Mercury and its compounds 80/68/EEC List II (3): Substances which have a deleterious effect on the taste and/or odour of groundwater, and compounds liable to cause the formation of such substances in such water and to render it unfit for human consumption 80/68/EEC List II (7): Ammonia and nitrites 80/68/EEC List II (1): Listed metalloids and metals and their compounds 80/68/EEC List II (4): Toxic or persistent organic compounds of silicon, and substances which may cause the formation of such compounds in water, excluding those which are biologically harmless or are rapidly converted in water into harmless substances

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