arcadis - sampling plan for pore water collection … · mdeq-rrd-superfund constitution hall - 3rd...

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13 ARCADIS Infrastructure Water Environment Buildings Mr. Keith M. Krawczyk Project Coordinator MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS CENTER REGION 5 ARCADIS 6723 Towpath Road P 0 Box 66 Syracuse New Yorl< 13214-0066 Tel 315 446 9120 Fax 315 449 0017 www.arcadis-us.com 434847 ENVIRONMENT Subject: Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site King Highway Landfill Operable Unit 3 Sampling Plan for Pore Water Collection System Outfalls Dear Mr. Krawczyk: On behalf of Georgia-Pacific LLC (Georgia-Pacific), ARCADIS has prepared this Sampling Plan for Pore Water Collection System Outfalls (Sampling Plan) to establish procedures for proposed pore water outfall sampling at the King Highway Landfill (KHL) of the King Highway Landfill Operable Unit 3 (KHL OU) located in Kalamazoo, Michigan. During rainfall events, water infiltrates through the vegetative and drainage/barrier protection layers of the KHL final cover system and encounters the 40-mil linear low- density polyethylene (LLDPE) flexible membrane liner (FML). The water then runs along the top of the FML and is collected by the pore water collection system (perforated high density polyethylene [HOPE] piping) that is located at the toe of the final cover system along the southern, western, and northern boundaries of the KHL (see Figure 1). The southern pore water outlet pipe discharges pore water through a riprap spillway into a detention basin along the southwestern portion of the property, while the northern pore water outlet pipe discharges directly to a riprap apron that drains to the Kalamazoo River. The pore water collection system promotes drainage from the soils in the final cover system to maintain the stability of the soil cover over the FML by collecting and conveying water to outlets. Date: March 20, 2012 Contact: Patrick McGuire Phone: 315.671.9233 Email: [email protected] Our ref: B0064583.0003.00907 During construction of the landfill and since construction of the final cover system, Georgia-Pacific and the Michigan Department of Environmental Quality (MDEQ) have observed an orange-red color in the pore water at the outfalls - this discoloration has been attributed to the oxidation of iron from iron oxides in the drainage/barrier protection layer. However, no pore water sampling has been performed to date to confirm this assumption. As such, Georgia-Pacific is proposing to conduct pore water sampling at the KHL to identify the origin of the orange-red stains that have been observed at the pore water outfalls. G:\Clients\GP KHL\05 Correspondence\2012 Correspondence Docs\B0O64583_0011211100_Pore Water Outfall Sampling Plan.Docx Project Number: B0064583.0003.00675

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Page 1: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

13 ARCADIS Infrastructure • Water • Environment • Buildings

Mr. Keith M. Krawczyk Project Coordinator MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926

us EPA RECORDS CENTER REGION 5

ARCADIS

6723 Towpath Road

P 0 Box 66

Syracuse

New Yorl< 13214-0066

Tel 315 446 9120

Fax 315 449 0017

www.arcadis-us.com

434847

ENVIRONMENT

Subject:

Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site King Highway Landfill Operable Unit 3 Sampling Plan for Pore Water Collection System Outfalls

Dear Mr. Krawczyk:

On behalf of Georgia-Pacific LLC (Georgia-Pacific), ARCADIS has prepared this Sampling Plan for Pore Water Collection System Outfalls (Sampling Plan) to establish procedures for proposed pore water outfall sampling at the King Highway Landfill (KHL) of the King Highway Landfill Operable Unit 3 (KHL OU) located in Kalamazoo, Michigan.

During rainfall events, water infiltrates through the vegetative and drainage/barrier protection layers of the KHL final cover system and encounters the 40-mil linear low-density polyethylene (LLDPE) flexible membrane liner (FML). The water then runs along the top of the FML and is collected by the pore water collection system (perforated high density polyethylene [HOPE] piping) that is located at the toe of the final cover system along the southern, western, and northern boundaries of the KHL (see Figure 1). The southern pore water outlet pipe discharges pore water through a riprap spillway into a detention basin along the southwestern portion of the property, while the northern pore water outlet pipe discharges directly to a riprap apron that drains to the Kalamazoo River. The pore water collection system promotes drainage from the soils in the final cover system to maintain the stability of the soil cover over the FML by collecting and conveying water to outlets.

Date:

March 20, 2012

Contact:

Patrick McGuire

Phone:

315.671.9233

Email:

[email protected]

Our ref:

B0064583.0003.00907

During construction of the landfill and since construction of the final cover system, Georgia-Pacific and the Michigan Department of Environmental Quality (MDEQ) have observed an orange-red color in the pore water at the outfalls - this discoloration has been attributed to the oxidation of iron from iron oxides in the drainage/barrier protection layer. However, no pore water sampling has been performed to date to confirm this assumption. As such, Georgia-Pacific is proposing to conduct pore water sampling at the KHL to identify the origin of the orange-red stains that have been observed at the pore water outfalls.

G:\Clients\GP KHL\05 Correspondence\2012 Correspondence Docs\B0O64583_0011211100_Pore Water Outfal l Sampling Plan.Docx Project Number: B0064583.0003.00675

Page 2: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

^ ARCADIS Mr. Keith M. Krawczyk March 20, 2012

To support development of a pore water sampling plan, the pertinent details of the construction and composition of the final cover system are summarized below, along with the results of relevant historical analytical testing of the vegetative and drainage/barrier protection layers, a brief review of the characteristics of soils native to the Kalamazoo area, and the previous groundwater sampling analytical results for iron. This document is organized as follows:

1. Final cover system components and prior sampling results 2. Characterization of native soils 3. Previous groundwater analytical data results 4. Sampling plan for pore water collection system outfalls 5. Schedule and reporting

These items are discussed in further detail below.

1. Final Cover System Components and Prior Sampling Results

As previously indicated, pore water at the KHL OU percolates through the vegetative and drainage/barrier protection layers until it reaches the top of the FML installed during the cleanup and closure activities at the OU (ARCADIS 2012). The vegetative layer is comprised of approximately 6 inches of topsoil and the drainage/barrier protection layer is approximately 24 inches of imported sand fill. Refer to Figure 2 for a representative cross-section of the final cover system at the KHL OU.

As part of the design and construction of the final cover system, aggregates were sampled and analyzed by accredited laboratories. In 1998, the topsoil and sand fill from Balkema Sand & Gravel used for construction of the final cover system were certified by Aggregate Resources, Inc., to be virgin, native materials and free from contaminants. The certification of aggregates from Aggregate Resources, Inc. has been included as Attachment 1 to this letter. The topsoil and sand fill used for the vegetative and drainage/barrier protection layers were analyzed by Western Michigan Environmental Services, Inc., for chemical constituents identified in the letters from RMT, Inc. to Blasland, Bouck, & Lee, Inc. dated November 11, 1998 (Bailey 1998) (included in Attachment 2).

Prior to placement of the topsoil and sand fill, the materials were sampled and analyzed for a range of targeted constituents as identified in the November 11, 1998 RMT letters. The letters indicate that the results for volatile organic compounds (VOCs), polychlorinated biphenyls (PCBs), phenol, and 4-methylphenol, were all below detection limits, and that metals were detected at levels less than the criteria in place at the time. However, none of the aggregate samples were analyzed for iron.

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Page 3: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

^ ARCADIS Mr. Keith M. Krawczyk March 20, 2012

2. Characterization of Native Sands

Georgia-Pacific's assertion that the orange-red stains at the pore water outfalls are caused by iron-rich sands is supported by several other reputable organizations. A study by the United States Department of Agriculture (USDA) states that sands in the vicinity of Kalamazoo River "are slightly stained by iron, which has imparted to the soil a yellowish tinge" (USDA 1901). On the Kalamazoo County Government website, iron is described as "the primary coloring agent of soil in the state of Michigan and in aerobic soil environments it is usually yellow, red or brown" (KalCounty.com 2012). Additionally, Terra Contracting, LLC (Terra), the contractor performing quarterly inspections and maintenance of the KHL on behalf of Georgia-Pacific, has confirmed that the observation of orange-red staining in sands sourced from local quarries is a common occurrence. Terra has also confirmed that after periods of rain, water that collects in the pore water detention basin along the southern side of the OU adjacent to King Highway also appears to be stained a reddish-orange color.

The 2005 Michigan Background Soil Survey (MBSS; MDEQ 2005) presents a compilation of soil sampling data that represents what is assumed to be the naturally occurring background concentration of metals in Michigan soils. The MBSS was originally compiled in 1991 and was updated by MDEQ in 2005 to include additional soil sampling data. The soil samples were divided into general soil types, including topsoil, clay, sand and silt, and sand. Statistical analyses were performed for each metal, including the percentage of non-detect values, as well as the mean, median, standard deviations, quantiles, and the range of concentrations for a metal. The metal data for each soil type is also broken down by geographical location, using glacial geology distinctions. Kalamazoo is located within the Michigan glacial lobe. Table 2 of the MBSS provides the metal concentrations detected in 38 samples collected from topsoil within the Michigan glacial lobe area. The statistical analyses of the 38 topsoil samples included in Table 2 indicate that the mean iron concentration is 2,432,000 pg/L with a standard deviation of 1,910 |jg/L. Table 3 of the MBSS provides the metal concentrations detected in 17 samples collected from sand within the Michigan glacial lobe area. The statistical analyses of the 17 sand samples included in Table 3 indicate that the mean iron concentration 3,418,000 pg/L with a standard deviation of 1,880 \^glL.

3. Previous Groundwater Analytical Data Results

Groundwater samples collected from existing monitoring wells MW-1AR, MW-2, MW-3A, MW-7, MW-8AR, MW-8BR, MW-11RR, MW-12AR, MW-12B, MW-13AR, MW-13B, MW-14AR, MW-15AR, MW-16A, and MW-16B during the past eight years of groundwater sampling have been analyzed for iron concentrations (well locations are shown on Figure 1). The validated analytical data results for iron concentrations from

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Page 4: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

^ ARCADIS Mr. Keith M. Krawczyk March 20, 2012

January 2003 through November 2010 are included in Table 2. The summary table of iron concentrations indicates that the maximum iron concentration detected at the 15 groundwater monitoring wells over the 8-year period was 174,000 micrograms per liter (pg/L), and the average iron concentration over that same time period was 22,545 [iglL. Since there is no generic groundwater-surface water interface (GSI) criterion or site-specific water quality-based effluent limit (WQBEL) for iron, the results of the groundwater sampling were compared to the groundwater contact criterion and risk-based screening level of 58,000,000 pg/L for iron from MDEQ's Part 201 Generic Cleanup Criteria (MDEQ 2011). The iron concentrations that have been detected in the groundwater at the KHL OU are significantly lower that the MDEQ's Part 201 Generic Cleanup Criteria.

In addition, when the groundwater maximum and average iron concentrations are compared to the topsoil and sand background iron concentrations for the state of Michigan, the groundwater concentrations are well below the background iron concentrations measured in the topsoil and sand throughout Michigan.

4. Sampling Plan for Pore Water Collection System Outfalls

The objective of the sampling activities is to identify the origin of the orange-red stains at the pore water outfalls at the KHL. To identify the constituent(s) that cause staining at the pore water outfalls, Georgia-Pacific proposes to collect samples from both the north and south pore water outfalls during wet weather conditions. ARCADIS personnel will collect one grab sample at each of the pore water outfalls shown on Figure 1. The water samples will be obtained by slowly submerging the sample jar within the flow from the pore water outfall such that no sediment is disturbed on the bottom of the outfall during collection. ARCADIS will measure temperature, turbidity, dissolved oxygen (DO), redox, and, pH in the field, and then each sample will be sent to KAR Laboratories, Inc. located at 4425 Manchester Road in Kalamazoo, Michigan for analysis of total dissolved iron. Measurements at each sample location will be recorded on an appropriate sampling log sheet and/or field book along with other pertinent information (weather conditions, visual observations of the conditions at the pore water outfalls, etc.).

All sampling activities will be carried out in accordance with the Multi-Area Quality Assurance Project Plan for the Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site (Multi-Area QAPP; ARCADIS 2010), the Multi-Area Field Sampling Plan for the Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site (Multi-Area FSP) and relevant addenda (ARCADIS BBL 2007a), and the Multi-Area Health and Safety Plan for the Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site (Multi-Area HSP) and relevant addenda (ARCADIS BBL 2007b).

Page: G:\Clients\GP KHL\05 Cor7-espondence\2012 Correspondence Docs\B0064583_0011211100_Pore Water Outfall Sampling Plan.Docx A I Q Project Number: B0064583.0003.00675

Page 5: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

^ ARCADIS Mr. Keith M. Krawczyk March 20, 2012

5. Schedule and Reporting

Upon MDEQ approval of this Sampling Plan, ARCADIS and Georgia-Pacific will schedule the pore water sampling within approximately three months from the date of this letter, depending on precipitation events. The analytical data received from the laboratory will be validated prior to evaluation of the data. As stated above, since there is no generic GSI criterion or site-specific WQBEL for iron, the results of the sampling will be compared to the groundwater contact criterion and risk-based screening level of 58,000,000 |jg/L for iron. Sampling results will be analyzed to determine if orange-red stains at the pore water outfalls are caused by the iron-rich soil within the final cover system or if additional sampling is needed to determine the origin of the staining.

The validated laboratory analytical data and a summary letter presenting the results of sampling activities will be submitted to MDEQ within 60 days after receiving the laboratory data.

If you have any questions, please do not hesitate to contact me.

Sincerely,

ARCADIS

Patrick McGuire Principal Environmental Engineer

Copies:

Daria Devantier, MDEQ Judith Alfano, MDEQ Michael Berkoff, USEPA Region 5 Garry Griffith, P.E., Georgia-Pacific Dawn Penniman, P.E., ARCADIS

Enclosures:

Table 1: Post-Remediation Groundwater Sampling Results for Iron Figure 1: Pore Water Outfall Sampling Locations Figure 2: Final Cover System Cross-Section Detail Attachment 1: Certificate of Aggregates from Aggregate Resources, Inc. Attachment 2: November 11, 1998 RMT, Inc. Letter to Blasland, Bouck, & Lee

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Page 6: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

^ ARCADIS Mr. Keith M. Krawczyk

March 20, 2012

References

ARCADIS. 2012. Draft Final Deliverable 14 - Final Report for Completion of Construction. King Highway Landfill Operable Unit 3. January 2012.

ARCADIS. 2010. Multi-Area Quality Assurance Project Plan for the Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site, Revision 1. March 2010.

ARCADIS BBL. 2007a. Multi-Area Field Sampling Plan for the Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site, Revision 1. October 2007.

ARCADIS BBL. 2007b. Multi-Area Health and Safety Plan for the Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site. May 2007.

KalCounty.com. 2012. Environmental Health Division Soil page. Accessed at https://www.kalcountv.com/eh/soil.htm

MDEQ. 2005. Michigan Background Soil Survey. Hazardous Water Technical Support Unit. Hazardous Waste Section. Waste and Hazardous Materials Division. 2005.

MDEQ. 2011. Table 1. Groundwater: Residential and Nonresidential Part 201 Generic Cleanup Criteria and Screening Levels; Part 213 Tier 1 Risk-Based Screening Levels (RBSLs). Document release date: March 25, 2011. Accessed at http://www.michiqan.qov/documents/deq/deq-rrd-OpMemo 1-AttachmentlTablelGW 283547 7.pdf

Bailey. 1998. Letter from Sharon Bailey, RMT, Inc. to Bill Rankin P.E., Blasland, Bouck, & Lee, Inc. Re: Sand Drainage Material - King Highway Landfill, Georgia-Pacific Corporation, Kalamazoo, Michigan. November 11, 1998.

Bailey. 1998. Letter from Sharon Bailey, RMT, Inc. to Bill Rankin P.E., Blasland, Bouck, & Lee, Inc. Re: Topsoil - King Highway Landfill, Georgia-Pacific Corporation, Kalamazoo, Michigan. November 11,1998.

USDA. 1901. United States Department of Agriculture, Natural Resources Conservation Services. So;7 Survey of Allegan County, Michigan. Accessed online at http://soils.usda.qov/survev/online survevs/michiqan/alleqanMI1901/alleqanMI1901. pdf (page: 99).

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ARCADIS

Table

Page 8: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site King Highway Landfill Operable Unit

Table 1 - Post-Remediation Groundwater Sampling Analytical Results for Iron

Sample ID:

Well ID:

Date Collected: Units

H85090

MW-14AR

01/06/03

H85091

MW-15AR

01/06rt)3

H85092

MW-11RR

01/07/03

H85093

MW-16A

01/07/03

H85094

DUP [MW-12AR1

01/07/03

H85095

MW-12AR

01/07/03

H85096

MW-12B

01/08/03

H85097

MW-8AR

01/08/03

H85098 DUP

[MW-8AR] 01/08/03

H85099

MW-3AR

01/08/03

H85100

MW-1AR

01/08/03

H85101

MW-8BR

01/08ra3

H85102

MW-13AR

01/09/03

H85103

HW-13B

01/09/03

H85104

MW-16B

01/09/03

H85105

MW-7

01/09ni3

Metals 9.960 I 47.200 I 48.600 | 6,290 | 14.900 | 15.600 Iron M9/L 11.200 11.300 5.900 49.100 21.100 10.100 18.500 7,130 9,420 6,260

Sample ID:

Well ID:

Date Collected: Metals Iron

Units

pg/L

H85106

MW-1AR

05«)5«)3

28,900

H85107

MW-7

05/06«)3

2,250

H85108

MW-2R

osmms

11,300

HB5109

MW-11RR

05/07/03

5,800

H85110

MW-16A

05/07/03

10,300

H85111

MW-16B

05/09/03

9,310

H85112

MW-12B

05/08/03

5,200

H85113

MW-12AR

05/08/03

43,100

H85114

DUP [MW-12AR]

05/08/03

41,800

H85116

MW-13B

05/08/03

6,190

H85117

HW-13AR

05/09/03

32,600

H85118

MW-8BR

05/09/03

9,970

H85119

MW-8AR

05/12/03

26,200

HS5120 DUP

tMW-8ARl 05/12/03

24,400

H85121

MW-14AR

05/12/03

10,000

H85122

MW-1SAR

05/12/03

11,200

Sample ID:

Well ID:

Dale Collected: Metals Iron

Units

H9'L

H85123

MW-3AR

05/12/03

29,500

H85124

MW.7

08/12ra3

2,780 J

H85125

MW-2R

oe/i2ra3

9,770 J

H85126

MW-1AR

08/12ra3

46,700 J

H85127

MW-11RR

08/13/03

5,430 J

H85129

MW-16A

08/13/03

9,200 J

H85130

MW-16B

08/13/03

8,570 J

H85131

MW-12B

08/14/03

5,170

H85132

MW-12AR

08/14/03

47,100

H85133

DUP [MW-12AR1

08/14/03

45,600

H85134

MW-13B

08/14/03

7,860

H85135

MW-13AR

08/14/03

33,600

H85136

MW-8BR

08/14/03

10,800

H85137

MW-8AR

08/14/03

23,100

H85138 DUP

(MW-8AR] 08/14/03

24,400

H85139

MW-14AR

08/15fl)3

10,400

Sample ID:

Well ID:

Date Collected: Metals

Iron

Units

pg/L

H85140

MW-15AR

08/15/03

10,300

H85141

MW-3AR

08/15/03

12,800

H85142

MW-2R

11/03/03

9,210

H85143

MW-7

11/04/03

2,830

H85144

MW-1AR

11/04/03

36,000

H85145

MW-11RR

11/05/03

4,190

H85146

MW-12B

11/05/03

5,040

H85148

MW-12AR

11/05/03

41,600

H85149

DUP [MW-12AR]

11/05/03

40,600

H85150

MW-13B

11/06/03

5,410

H85151

MW-SBR

11/06/03

9,110

H85152

MW-13AR

11/06/03

32,700

H85153

MW-8AR

11/06/03

49,100

H85154

DUP IMW-8AR1

11/06/03

49.400

H85155

MW-16B

11/07/03

8,450

Hssise

MW-16A

11/07/03

9,540

Sample ID:

Well ID:

Dale Collected: Metals

Iron

Units

pg'L

H85157

MW-14AR

11/10/03

10,400

H851S8

MW-15AR

11/10/03

10,400

H85159

MW-3AR

11/10/03

174,000

H85160

MW-7

02/23/04

3,040

H85161

MW-2R

02/24/04

7,560

H85162

MW-1AR

02/24/04

46,200

H85163

MW-11RR

02/24/04

4,560

H85164

MW-16A

02/24/04

10,500

H85166

MW-16B

02/25/04

8,890

H85167

MW-12B

02/25/04

4,910

HB5168

MW-12AR

02/26/04

38,400

H85169

MW-13B

02/26/04

6,000

H85170

MW-13AR

02/26/04

48,500

H85171

MW-8BR

02/26/04

10,300

H85172

MW-8AR

02/27/04

33,000

H85173

DUP [MW-8ARI 02/27/04

32,800

Sample ID:

Well ID:

Date Collected: Metals

Iron

UnHs

pg/L

H85174

MW-14AR

02mm

10,500

H85175

MW-15AR

03rt)1/04

10,100

H85176

DUP [MW-15AR)

03/01/04

9,880

H85177

MW-3AR

03/01/04

106,000

H85178

MW-7

05/17/04

2,150

H85179

MW-1AR

05/18/04

75,600

H85180

MW-2R

05/18/04

7,250

H85181

MW-16A

05/18/04

10,500

H85182

MW-11RR

05/18/04

4,660

H85183

MW-12AR

05/19/04

35,800

H85184

MW-16B

05/19/04

8,820

H85186

MW-8BR

05/20/04

11,200

H85187

MW-8AR

05/20/04

32,300

H85188 DUP

[MW-8AR1 05/20/04

31,800

H85189

MW-13AR

05/20/04

52.500

H85190

MW-13B

0500/04

7,290

r Sample ID:

Well ID:

Date Collected: Units

H85191

MW-14AR

05/20/04

H85192

MW-12B

05/20/04

H85193

MW-15AR

05/21/04

H85194 DUP

[MW-15AR] 05/21/04

H85195

MW-3AR

05/21/04

H85196

MW-7

08/02/04

H85197

MW-1AR

08/02/04

H85198

MW-2R

08/03/04

H85199

MW-11RR

08/03/04

H85200

MW-16A

08/03/04

H85201

MW-16B

08/03/04

H85202

MW-12AR

08/04/04

H85203

MW-12B

08/04/04

H85204

MW-13AR

08/04/04

H85205

MW-13B

08/04/04

H85206

MW-8BR

omsm Metals

I pg/L I 9.990 I 4!600" 75,400 I 8,510 I 4,810 | 10,600 | 8,560 | 36,000 | 5,160 | 62,300 10,000 11,400 100,000 3,150 7,990 11,400

See Notes on Page 5,

G:\aiwiu\GP KHL\05 C(xr«pond90ce\2D1Z CofrospondBncs Docs\B0064583_0011211100_Por« Water Outfall Sampling Plan_Tatite 1.GW Iron ConcenlrallonE.xIsx

3/20/2012 Page 1 of 5

Page 9: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Al l ied Paper, Inc./Portage Creek/Kalamazoo River Super fund Site

King Highway Landf i l l Operable Unit

Table 1 - Post-Remediat ion Groundwater Sampl ing Analyt ica l Resul ts fo r I ron

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H8S207

MW-8AR

08/05fl)4

23,500

H85208

DUP (MW-8AR] 08/05/04

22,500

H85209

MW-14AR

08/05/04

10,000

H85210

MW-3AR

08/06/04

31,600

H85211

MW-15AR

08^6/04

10,100

H85212

DUP [MW-15AR]

08/06/04

9,700

HS5214

MW-7

11/15/04

3,020

H85215

MW-1AR

11/15/04

45,700

H85216

MW-2R

11/16/04

6,490

H85217

MW-11RR

11/16/04

4,340

H85218

MW-16A

11/16rt)4

10,200

H85219

MW-16B

11/16/04

7,850

H85220

MW-12B

11/16/04

5,160

H8S221

MW-12AR

11/17/04

37,200

H85222

MW-13B

11/17/04

8,380

H85223

MW-13AR

11/17/04 i

60,800

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H85224

MW-8BR

11/17/04

10,800

H85225

MW-8AR

11/17/04

25,200

H85226 DUP

tMW-8AR] 11/17/04

24,400

H85227

MW-15AR

11/18«)4

10,700

H85228 DUP

[MW-15AR] 11/18/04

10,800

H85229

MW-14AR

11/18/04

10,900

H85230

MW-3AR

11/18/04

78.600

H85232

MW-2R

02/07/05

4,790

H85233

MW-7

02/07/05

3,010

H85234

MW-1AR

02/07/05

69,600

H85235

MW-11RR

02/08/05

3,950

H85237

MW-16B

02/08/05

7,880

H85238

MW-16A

02/08/05

10,600

H85239

MW-12B

02/09/05

4,930

H85240

MW-13B

02/09/05

6,400

H85241

MW-12AR

02/09/05 .

31,700

Sample ID:

Well ID:

Date Collected: Units Metals Iron 1 pg/L

H85242

MW-13AR

02/09/05

60,400

H85243

MW-8AR

02/10/05

25,300

H85244

DUP [MW-8AR] 02/10/05

25,600

H85245

MW-8BR

02/10/05

10,100

H85246

MW-14AR

02/10/05

9,960

H85247

MW-15AR

02/11/05

10,600

H85248

DUP [MW-15AR1

02/11/05

10,600

H85249

MW-3AR

02/11/05

81,100

H85250

MW-7

05/23/05

1.440

H85251

MW-2R

05/23/05

12,000

H85252

MW-16A

05/24/05

12,000

H85253

HW-1AR

05/24/05

93,200

H85254

MW-11RR

05/24/05

5,240

H85255

MW-16B

05/24/05

9,380

H85256

MW-12B

05/24/05

5,210

H85257

MW-12AR

05/24/05

35,500

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H85259

MW-8BR

05/25/05

13,800

H85260

MW-13B

05/25/05

7,520

H85261

MW-8AR

05/25/05

22,300

H85262

DUP [MW-8AR1 05/25/05

22,300

H85263

MW-13AR

05/25/05

50,700

H85264

MW-14AR

05/26/05

10,900

H85265

MW-1SAR

05/26/05

11,800

H85266

DUP (MW-15ARI

05/26/05

11,500

H85267

MW-3AR

05/26/05

28,000

H85268

MW-7

08/15/05

3,290 J

H85269

MW-1AR

08/15/05

63,900 J

H85270

MW-2R

omms

10,100 J

H85271

MW-11RR

08/16/05

5,220 J

H85272

MW-16A

08/16/05

10,000 J

H85274

MW-16B

08/18/05

7,490 J

H85275

MW-12AR

08/17/05

34,600 J

: Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 iiqlL

H85276

MW-12B

08/17/05

5,290 J

H85277

MW-13B

08/17/05

7,940 J

H85278

MW-8AR

08/17/05

29,800 J

H85279 DUP

[MW-8AR] 08/17/05

29,700 J

H852B0

MW-13AR

08/18/05

45,900 J

H8S281

MW-8BR

08/17/05

12,200 J

H85282

MW-15AR

08/18/05

9,500 J

H85283 DUP

[MW-15AR1 08/18/05

9,660 J

H85284

MW-14AR

08/18/05

10,300 J

H85285

MW-3AR

08/18/05

15,700 J

H85286

MW-1AR

11/08/05

59,400

H85287

MW-2R

11/08/05

12,800

H85288

MW-7

11/08/05

4,190

H85289

MW-11RR

11/08/05

6,610

H85291

MW-12B

11/09/05

5,660

H85292

MW-16A

11/09/05

10,700

Sample ID:

Well ID:

Date Collected: Units

H85293

MW-12AR

11/09/05

H85294

MW-16B

11/09/05

H8S295

MW-13B

11/10/05

H85296

MW-8BR

11/10/05

H85297

MW-8AR

11/10/05

H85298 DUP

[MW-8AR1 11/10/05

H85299

MW-13AR

11/10/05

H85300

MW-1SAR

11/11/05

H85301 DUP

[MW-15AR] 11/11/05

H85302

MW-14AR

11/11/05

H85303

MW-3AR

11/11/05

H85304

MW-2R

02A)8/06

H85305

MW-1AR

02mi06

H85306

MW-7

02/08/06

H85308

MW-11RR

02/08/06

H85309

MW-12AR

02/09/06 Metals

19,100 I 43,400 I 10,400 4,160 I 4.850 I 33,000 Iron Ji3!kj 37,800 7,830 8,220 11,800 18,400 10.100 11,300 11,900 73,000

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H85310

MW-12B

02A)9/06

5,360

HB5311

MW-16A

02/09/06

10.800

H85312

MW-16B

02/09/06

8,100

H85313

MW-8BR

02/09/06

10,700

H85314

MW-13AR

02/09/06

97,200

HB5315

MW-13B

02/09/06

8,360

III

71,800

H85317

DUP [MW-8AR1 02/10/06

68,600

H85318

MW-3AR

02/10/06

81,500

H85319

MW-15AR

02/10/06

10,600

H85320

DUP [MW-15AR1

02/10/06

10,200

H85321

MW-14AR

02/10/06

11,000

H85322

MW-7

05/08rt)6

2.510

H85323

MW-2R

05/08/06

9,550

H85325

MW-1AR

05/09/06

91,400

H85326

MW-16A

05/09/06

9,390

See Notes on Page 5.

G:\atonts\GP KHL\05 CcrrespoodencsVMIZ Corraspoodiinco Docs\B00e4583_001121 llOO^Por* Water Outfall Sampling PlanTable 1-GW Iron Conconlratkxis.xlsx

3«0/2012 Page 2 of 5

Page 10: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site King Higliway Landfill Operable Unit

Table 1 - Post-Remediation Groundwater Sampling Analytical Results for Iron

Sample ID:

Well ID:

Date Collected: Units Metals Iron 1 pg/L

H85328

MW-12AR

05/09/06

34,400

H85330

MW-12B

05/09/06

4,960

H85331

MW-13AR

05/10/06

70,000

H85332

MW-13B

05/10/06

7,010

H85333

MW-8BR

05/10/06

11,700

H85334

DUP [MW-8AR] 05/10/06

37,100

H85335

MW-8AR

05/10/06

37,100

H85336

MW-14AR

05/11/06

9,670

H85337

MW-16B

05/11/06

7,840

H85338

MW-3AR

05/11/06

37,200

H85339 DUP

[MW-15AR] 05/11/06

10,100

H85340

MW-15AR

05/11/06

9,860

H85341

MW-11RR

05/11/06

5,010

H85342

MW-7

08/21/06

704 J

H85343

MW-2R

08/21/06

9,040 J

H85344

MW-1AR

08/22/06

73,000 J

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H85345

MW-11RR

08/22/06

4,710 J

H85347

MW-16B

08/22/06

6,610 J

H8534«

MW-16A

08/22/06

8,970 J

H85349

MW-12B

08/23/06

5,100 J

H85350

MW-13B

08/23/06

7,690 J

H85351

MW-12AR

08/23/06

35,200 J

H85352

MW-13AR

08/23/06

54,200 J

H85353

MW-SBR

08/24/06

10,900 J

HB,5354

MW-8AR

08/24/06

33,800 J

H85355 DUP

rMW-8AR] 08/24/06

33,700 J

H85356

MW-14AR

08tt4/06

10,300 J

H8,5357

MW-15AR

08/25/06

9,430 J

H85358

DUP [MW-15AR]

08/25/06

9,390 J

MW-3AR

08/25/06

15,200 J

H85360

MW-2R

11/06/06

8,360

H85361

MW-7

11/06^6

3,770

Sample ID:

Well ID:

Date Collected: Units Metals Iron 1 pq/L

H85362

MW-1AR

11/07/06

74,200

H85363

MW-11RR

11/07/06

5,230

H85365

MW-16A

11/07/06

10.000

H85366

MW-16B

uioem

7,580

H85367

MW-12B

11/08/06

4,940

H85368

MW-13B

11/08/06

7,680

H85369

MW-13AR

11/08/06

66,400

H85370

MW-12AR

11/08/06

33,200

H85371

MW-8AR

11/09/06

37.900

H85372

DUP [MW-8AR] 11/09/06

36,800

H85373

MW-8BR

11/09/06

9,400

H85374

MW-14AR

11/09/06

10,100

H85375

MW-3AR

11/10/06

45,600

H85376

MW-15AR

11/10/06

9,390

H85377

DUP [MW-15AR1

11/10/06

9,740

H85378

MW-7

02/05^7

4,370

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pq/L

T 8 5 3 7 9 - ' -

MW-1AR

02/06/07

83,500

•H85380

MW-2R

02/06/07

9,650

MW-16A

02m6/07

10,200

" " H 8 5 3 8 r

MW-11RR

02/06/07

4,550

H85384

MW-12B

02/07/07

4,890

H85385

MW-16B

02/07/07

7,590

H85386

MW-12AR

02/07/07

39,600

H85387

MW-13B

02/07/07

8,330

H85388

MW-8AR

02/08/07

35,500

H85389

DUP [MW-15AR]

02/08/07

35,800

H85390

MW-13AR

02/08/07

66,100

H85391

MW-8BR

02/08/07

9,620

H85392

MW-14AR

02/09/07

8,780

H85393

MW-15AR

02/09/07

9.800

H85394

DUP (MW-15AR]

02/09/07

9,720

H85395

MW-3AR

02/09/07

61,100

Sample ID:

Welt ID:

Date Collected: Units

H85396

MW-7

05/07/07

H85397

MW-2R

05/08rt)7

H8S398

MW-1AR

05/08/07

H85399

MW-11RR

05rt)8/07

H85400

MW-16A

osmmr

H85402

MW-12B

05/09/07

H85403

MW-16B

05/09/07

H85404

MW-12AR

05/09/07

H85405

MW-13B

05/09/07

H85406

MW-13AR

05/09/07

H85407

MW-8AR

05/10/07

H85408 DUP

[MW-SAR] 05/10/07

H85409

MW-SBR

05/10/07

H85410

MW-15AR

05/10/07

H85411 DUP

[MW-15AR1 05/10/07

H85412

MW-14AR

05/10/07 Metals

I 97,300 I 4,350 T 4,690 I 8,160 I 51,200 | 7,400 | 87,300 j 35,000 | 33,900 | 10,600 | 10,200 | 9,940 j 9,340 j Iron j i a ^ 3,790 8,490 10,900

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pq/L

H85413

MW-3AR

05/11/07

33,900

H85414

MW-7

08/06/07

4,650

H85415

MW-2R

08/06/07

10,100

H85416

MW-11RR

08/08/07

5,850

H85418

MW-1AR

08/08/07

98,400

H85419

MW-16B

08/08/07

11,300

H85420

MW-16A

08/08/07

7,940

H85421

MW-12B

08/08/07

5,590

H85422

MW-13B

08/08/07

6,960

H85423

MW-12AR

08/09/07

51,400

H85424

MW-13AR

08/09/07

62,400

H85425

MW-SAR

08/09/07

27,700

H85426 DUP

[MW-SAR] 08/09/07

28,600

H85427

MW-SBR

08/09/07

14,600

H85428

MW-15AR

08/10/07

10,100J

H85429

DUP [MW-15ARI

08/10/07

10,100J

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H85430

MW-14AR

08/10«)7

11,100J

H85431

MW-3AR

08/10/07

14,500 J

Hfi5437

MW-7

10/29/07

2,510

H85433

MW-1AR

10/30/07

65,400

H85434

MW-2R

10/30/07

14,900

H85435

MW-11RR

10/30/07

5,110

H85437

MW-16A

10/30/07

9,690

H85438

MW-12B

10/30/07

5,110

H85439

MW-16B

10/30/07

7,390

H85440

MW-13B

10/31/07

7,840

H8S441

MW-12AR

10/31/07

50,800

H85442

MW-13AR

10/31/07

69.500

H85443

MWSBR

10/31/07

12,500

H85444

MW-SAR

10/31/07

33,800

H85445

DUP [MW-SAR] 10/31/07

34,000

HSS446

MW-14AR

11/01/07

11,000

See Notes on Page 5.

G:\ai«nte\GP KHL\05 CorT-«6pond«ic«\2012 CorraspondorKe Docs\BO0e45a3_0011211100_Pore Walw Outfall Sampling Ptan_Table 1-GW Iron Coticenlratlors.xlsK 3/20/2012 Page 3 of 5

Page 11: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Allied Paper, Inc./Portage Creek/Kalamazoo River Superfund Site King Highway Landfill Operable Unit

Table 1 - Post-Remediation Groundwater Sampling Analytical Results for Iron

Sample ID:

Well ID:

Date Collected: Units Metals

Iron 1 pg/L

H85447

DUP [MW-14AR]

11/01/07

11,200

H85448

MW-3AR

11/02/07

51,500

HS5449

MW-15AR

11/02/07

9,600

HS5450

MW-2R

02/11/08

14,400

HS5451

MW-17

02/11/08

3,120

H85452

MW-1AR

02/12«)8

70,600

H85453

MW-11RR

02/12/08

4,180

H85455

MW-16A

02/12/08

8,590

H85456

MW-16AB

02/13/08

8,310

H85457

MW-12AR

02/13/08

47,200

H85458

MW-12B

02/13n)8

5,370

H85459

MW-SBR

02/14fl)8

10,300

H85460

MW-13B

02/14/08

7,200

H85461

MW-13AR

02/14/08

95,100

H85462

MW-SAR

02/14/08

34,700

HS546ia DUP

[MW-SAR] 02/14/08

34,500

1 Sample ID:

Well ID:

i Date Collected: Units Metals

Iron 1 pg/L

H85464

MW-14AR

02/14/08

9,770

H85465

DUP [MW-14AR]

02/14/08

9,600

HB5466

MW-15AR

02/15/08

9,950

H85467

MW-3AR

02/15/08

55,700

H85468

MW-7

05/12/08

39,100

H85469

MW-1AR

05/13/08

64,600

HS5470

MW-2R

05/13/08

17,200

H85471

MW-11RR

05/13/08

4,270

H85473

MW-16A

05/14/08

11,600

H85474

MW-16B

05/14/08

9,180

H85475

MW-12AR

05/14/08

56,300

H85476

MW-12B

05/14/08

5,360

H85477

MW-13AR

05/15/08

93,900

H85478

MW-13B

05/15/08

7,200

H85479

MW-SAR

05/15/08

33,900

HS5480

DUP [MW-SAR] 05/15/08

34,100

Sample ID:

Well ID:

i Date Collected: Units Metals

Iron 1 pq/L

H85481

MW-SBR

05/15/08

13,500

H85482

MW-14AR

05/15/08

11,000

H85483

DUP [MW-14AR]

05/15/08

11,000

H85484

MW-15AR

05/16/08

14,600

H8548S

MW-3AR

05/16/08

28,400

H8S486

MW-7

08/05/08

55,700

H85487

MW-2R

08/05/08

11,600

H854S8

MW-1AR

08/05/08

82,600

H854S9

MW-11RR

08/06/08

5,930

H85490

MW-16A

08/06/08

10,700

H85492

MW-16B

08/06/08

8,240

H85493

MW-12B

08/06/08

5,030

H85494

MW-12AR

08/07/08

53,100

H85495

MW-13B

08/07/08

6,910

H85496

MW-13AR

08/07/08

65,000

H85497

MW-8BR

08/07/08

14,000

H85501

MW-14AR

08/08/08

Sample ID

Well ID

Date Collected Units

H8S498

MW-8AR

08/07/08

H85499 DUP

[MW-SAR] 08/07/08

H85500

MW-1SAR

08/08/08

H85502 DUP

[MW-14AR] 08/08/08

H8S503

MW-3AR

08/08/08

H85504

MW-7

11/03/08

H85505

MW-2R

11/03/08

H85506

MW-1AR

11/04/08

H85507

MW-16A

11/04/08

H85508

MW-11RR

11/04/08

H85510

MW-16B

11/05/08

H85511

MW-12B

11/05/08

H8S512

MW-12AR

11/05/08

HS5513

MW-13B

11/05/08

H85514

MW-SBR

11/06/08

Metals I 24,600 I 15,100 I 53,200 | 11,700 j 4,380 j 5,160 I 65,300 I 7,240 | 12,400 j Iron I pg/L 29,100 30,800 9,550 8,980 8,970 8,190

Sample ID:

Well ID:

i H i a CollectBd: Units [Metals

bran 1 pq/L

H85515

MW-13AR

11/06/08

52,800

H85516

MW-14AR

11/06/08

10,700

H85517 DUP

[MW-14AR] 11/06/08

10,800

H85518

MW-8AR

11/06/08

36,600

H85519 DUP

[MW-SAR] 11/06/08

36,600

H85520

MW-15AR

11/07/08

8,700

H85521

MW-3AR

11/07/08

10,100

H85522

MW-7

02/02/09

4,470

H85523

MW-1AR

02/03/09

56,200

H85524

MW-2R

02/03/09

9,930

H85525

MW-11RR

02/03/09

3,930

HS5526

MW-16A

02/03/09

10,700

HS5528

MW-16B

02/04/09

7,140

H85529

MW-12B

02/04/09

4,590

H85530

MW-13B

02/04/09

6,500

H8S531

MW-12AR

02/04/09

63,000

1 Sample ID:

Well ID:

. DateCoUectad: Unite Metals iron 1 pg/L

H85532

MW-13AR

02/05/09

56,800

H85533

MW-SBR

02/05/09

11,800

HS5534 DUP [MW-

SBR] 02/05^9

11,400

H85535

MW-SAR

02rt)5/09

31,000

H85536

MW-14AR

02/05/09

10,400

HS5537

MW-15AR

02/06/09

9,640

H85538

DUP [MW-15AR]

02/06/09

9,560

H85539

MW-3AR

02/06/09

20,800

H85540

MW-7

05/18/09

5,700

H85541

MW-1AR

05/19/09

86,800

H85542

MW-2R

05/19/09

10,800

H85543

MW-11RR

05/19/09

4,120

H85544

MW-16A

05/19/09

14,600

H85546 DUP

[MW-16A] 05/19/09

14,500

H85547

MW-16B

05/20/09

7,320

H85548 1

MW-12B

05a0/09

4,330 1

; Sample ID:

Well ID:

Date Collected: Unite Metals

Iron 1 pq/L

H85551

MW-13B

05/20/09

6,540

HS5552

MW-12AR

05/20/09

62,700

HS5553

MW-13AR

05/21/09

86,800

H8S554 DUP

[MW-13AR] 05/21/09

86,800

H85555

MW-14AR

05/21/09

9,580

HS5556

MW-SBR

05/21/09

13,000

H85557

MW-SAR

05/21/09

42,900

H855S8

MW-15AR

05/22/09

10,100

HS5559

MW-3AR

05/22/09

29,900

H85560

MW-7

08/17/09

5,380

H85561

MW-1AR

08/18/09

80,900

H85562

MW-2R

08/18/09

11,100

H85563

MW-11RR

08/18/09

5,060

H85564

MW-16A

08/19/09

12,300

H85566

MW-16B

08/18/09

8,020

H85S67

MW-12B

08/18/09

4,990

See Notes on Page 5.

G:\ai«nts\GP KHL\05 CorresporTderKe\2012 Correspondence Docs\B 0064563 _0011211100 _Pore Water Outfall Sampling PlanTable 1-GW Iron Concentrations, xlsx 3/20/2012 Page 4 of 5

Page 12: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Al l ied Paper, Inc./Portage Creek/Kalamazoo River Super fund Site

K ing Highway Landf i l l Operable Unit

Table 1 - Post-Remediat ion Groundwater Sampl ing Analyt ical Resul ts for Iron

Sample ID:

Well ID:

Date Collected: Unite Metals

Iron 1 pg/L

H85568

MW-12AR

08/19/09

58,100

H85569

MW-13B

08/19/09

7,360

H85570

MW-13AR

08/19/09

71,200

H85571

DUP [MW-13AR]

08/19/09

69,700

H85572

MW-SBR

08/19/09

14,900

H85573

MW-SAR

08/19/09

40,700

H8S574

MW-14AR

08/20/09

10,900

H85575 DUP

[MW-14AR] 08/20/09

10,700

H85576

MW-15AR

08/20/09

8,970

H85577

MW-3AR

08/21/09

16,700

H85578

MW-11RR

11/10/09

5,670

H85579

MW-1AR

11/10/09

57,200

HS55S0

MW-16A

11/10/09

12,200

H85582

MW-16B

11/10/09

8,450

HS5583

MW-12B

11/10/09

5,150

H855&4 1

MW-12AR

11/11/09

52,900

1, Sample ID:

^ K Well ID:

^ ^ e Collected: Units Metals

llron 1 pg/L

H85585

MW-13B

11/11/09

7,670

H85586

MW-13AR

11/11/09

72,800

HS5587

DUP [MW-13AR]

11/11/09

72,200

HS55S8

MW-SBR

11/11/09

13,900

H85589

MW-SAR

11/12/09

32,900

H85590

MW-14AR

11/12/09

11,100

H85591 DUP

[MW-14AR] 11/12/09

10,800

H85592

MW-15AR

11/12/09

10,800

H85593

MW-3AR

11/12/09

35,300

H85594

MW-2R

11/13/09

15,100

H85595

MW-7

11/09/09

12,400

H85596

MW-2R

02/15/10

10,700

H85597

MW-7

02/15/10

5,070

H8S59S

MW-11RR

02/16/10

4,190

H85599 DUP

[MW-11RR] 02/16/10

5,310

H8S600

MW-1AR

02/16/10

57,300 1

Sample ID

Well ID

Date Collected Unite

H85602

MW-16A

02/16/10

H85603

MW-16B

02/16/10

H85604

MW-12B

02/17/10

HS5605

MW-12AR

02/17/10

H85606

MW-13B

02/17/10

H85607

DUP [MW-13B] 02/17/10

H85608

MW-13AR

02/17/10

H85609

MW-SBR

02/18/10

H85610

MW-8AR

02/18/10

H85611

MW-14AR

02/18/10

HS5612

MW-3AR

02/18/10

H85613

MW-15AR

02/18/10

H85614

MW-7

05/24/10

H85615

MW-2R

05/24/10

H85616

MW-1AR

05/24/10

H85617

MW-11RR

05/24/10 Metals

Iron _tia!L. 10,900 7,500 4,720 48,900 5,920 5,900 70,000 I 13,300 I 41,000 9.700 I 18,100 I 11.400 4,350 15,400 62,700 I 3,980 I

Sample ID

Well ID

Date Collected Units Metals

llron 1 pg/L

H85619

MW-16B

05/25/10

7,740

HS5620

MW-16A

05/25/10

12,000

H85621

MW-12B

05I25IW

3,800

H85622

DUP [MW-12B] 05/25/10

3,810

H85623

MW-12AR

05/25/10

43,600

H85624

MW-13B

05/26/10

5,970

H85625

MW-13AR

05/26/10

86,200

HS5626

MW-8AR

05/26/10

26,000

H85627

MW-8BR

05/26/10

12,000

H85628

MW-14AR

05/26/10

10,300

H85629

MW-15AR

05/27/10

11,000

HS5630

DUP [MW-15/VR]

05/27/10

10,900

H85631

MW-3AR

05I2TI^0

23,100

H85632

MW-7

08/23/10

12,500

H85633

MW-2R

08/23/10

10,700

H85634 1 DUP

[MW-2R] 08/23/10

11,200 1

Sample ID:

Well ID:

Date Conected: Units Metals

Iron 1 pg/L

H85635

MW-11RR

08/24/10

5,880

H8S636

MW-1AR

08/24/10

73,300

H8563S

MW-16A

08^4/10

12,100

H85639

MW-16B

08«4/10

7,650

H85640

MW-12AR

08/24/10

39,700

HSS641

MW-12B

08/25/10

5,130

H85642

MW-13AR

08/25/10

70,200

H85643

MW-13B

08/25/10

6,660

H85644

DUP (MW-13B] 08/25/10

6,400

H85645

MW-SBR

08ffi5/10

12,400

H8S646

MW-8AR

08^6/10

33,800

H85647

MW-14AR

08/26/10

11,000

HS5648

MW-15AR

08tt7/10

11,500

H85649

MW-3AR

08/27/10

12,300

H85650

MW-7

11/15/10

4,430

H8S651 1

MW-1AR

11/16/10

77,200

Sample ID

Well ID

Date Collected: Units

H85652

MW-2R

11/16/10

H8S653

MW-11RR

11/16/10

H85655

MW-16A

11/16/10

H856S6

MW-16B

11/16/10

H85657

MW-12B

11/17/10

H85658

MW-13B

11/17/10

H85659

MW-12AR

11/17/10

H85660 DUP [MW-

12AR] 11/17/10

H85661

MW-SBR

11/18/10

HS5662

MW-13AR

11/18/10

H85663

MW-SAR

11/18/10

H85664

MW-14AR

11/18/10

H85665

MW-3AR

11/19/10

H85666

MW-15AR

11/19/10

H85667 DUP

[MW-15ARI 11/19/10

Metals

6,390 I 42,700 | 41,800 | 13,500 | 64,800 | 27,900 I 10,100" Iron j iSlL. 10,700 6,160 10,700 7,760 4,960 10,500 10,100 9,900

Notes: 1. pg/L - Micrograms per liter. 2. Sample IDs H85549 and H85550 correspond to Matrix Spike/Matrix Spike Duplfcate samples associated with Sample ID H85548, and were therefore not included hereon.

Definitions of Data Qualifiers: J - The compound/analyte was positively Wentified: however, the associated numerical value is an estimated concentration only.

G:\Cltants\GP KHL\05 Corr»6p«id8»ico^2012 Correspondence Docs\B0Oe45fl3_0O1121 IIOO^Pw* Water Outfall Sampling Plan Table 1-GW Iron CoocenlratlonE xlsx Page 5 of 5

Page 13: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

ARCADIS

Figures

Page 14: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

>s

[

A

V-1-2A

SOUTH PORE WATER OUTLET DETAIL 0

£ 3 3

40'

GRAPHIC SCALE

80'

M W - 1 4 - ^

RG-3 ®-GW-2 A

LEGEND:

APPROMIllATE P/UtCEL BOUNO/^RY

DITCH LINE

ABANDONED RAILROAD

SHEETPILE WAU

ACCESS ROAD

RIPRAP

CULVERT PIPE

RNAL AS-BUILT INDEX CONTOUR

nNAL AS-BUILT INTERMEDIATE CONTOUR

SECURITY FENCE

PORE WATER COLLECTION PIPE

PORE WATER DRAIN

APPROXIMATE WATER EDGE

GAS VENTS (ORIQNAL 23: ONLY FOUR WERE GIVEN IDs)

CUTOFF TRENCH GAS VENTS

L A N O n a GAS CUTOFF TRENCH

FLOW DIRECTION

MONITORING WELL

RIVER GAUGE STATION

LOCATION OF GAS MONITORING PROBES

PARCa C DEMARCATION LAYER (ORANGE NON-WOVEN GEOTEXTILE LOCATED APPROXIMATELY 1

FOOT e a o w G R A D E )

P A R c a c P R O P E R T Y B O U N D A R Y

APPROXIMATE LOCATION OF INSTALLED PERMANENT MARKERS

BASE MAP INFORMATION OBTAINED FROM CADO DRAWING FILE DEVELOPED BY RMT INC. ANN ARBOR. MICHIGAN (CADD FILE: L1630SU01.DWG AS-BUILT SURVEY; 8 / 2 1 / 0 0 ) .

RNAL AS-BUILT CONTOUR ELEVATIONS ARE SHOWN AND ARE BASED ON A FIELD SURNtY BY ATWELL-HICKS. INC.. DATED S / 2 7 / 0 0 WITH REVISIONS DATED 1 0 / 2 3 / 0 0 . 12 /21 /O t . 1 2 / 1 0 / 0 2 . AND 7 / 2 4 / 0 3 .

HNAL AS-BUILT CONTOUR ELEVATIONS OF SEDIMENTATION BASIN ARE BASED ON A HELD SURVEY BY PRDN & NE\l»IOF. DATED 2 / 3 / 0 * .

DEMARCATION LAYER. PROPERTY BOUNDARY. AND FINAL AS-BUILT CONTOUR ELEVATIONS OF PARCEL C AND SURROUNDING AREAS BASED ON A HELD SURVEY BY PREIN & NEWHOF. DATED 11/19/2010.

ELEVATIONS ARE BASED ON NGVD OF 1929 (MSL).

PROPERTY SURVEY PERFORMED BY WILKINS ft KHEATON ENGINEERING CO., INC., ON 7 / 1 / 9 6 .

TOPOGRAPHIC CONTOUR INTERVAL IS 1 FOOT

LOCATIONS OF GW-5. GW-6. GW-7. GW-B. GW-9. AND GW-10 ARE BASED ON A FIELD SURVEY BY TERRA CONTRACTING LLC. DATED 9 / 2 3 / 0 5 .

LOCATION OF GW-11 IS BASED ON A RELD SURVEY BY TERRA CONTRACTING LLC. DATED 1 /11 /06 .

LOCATIONS OF RG-6 . V - * - 4 , V - 4 - 5 . AND V - 4 - 6 ARE BASED ON A RELD SUR\ tY BY TERRA CONTRACTING LLC. DATED 6 / 7 / 0 6 .

LOCATIONS OF V - 1 - 2 THROUGH V - 1 - 6 , V - 2 - 3 . V - 2 - 1 0 . AND V - 2 - t 8 ARE BASED ON MULTIPLE FIELD SURVEYS CONDUCTED BY TERRA CONTRACTING, LLC. IN APRIL 200B. GAS VENTS V - 2 - 4 THROUGH V - 2 - 9 . AND V - 2 - 1 1 THROUGH V - 2 - 1 7 ARE NOT SHO«l»l FOR CLARITY PURPOSES (THESE VENTS ARE LOCATED ALONG TT?ENCH C).

12. LOCATION OF GW-12 IS APPROXIMATE.

LOCATIONS OF GW-13 THROUGH GW-17 BASED ON HELD SURVEY CONDUCTED BY PRDN ft NEVWOF ON 11 /1 /11 .

14. LOCATION OF SHEETPILE W A a AND A PORTION OF THE MONITORING WELLS ARE BASED ON A FIELD SURVEY BY ATHKLL-HICKS. INC. DATED 9 / 2 7 / 0 0 .

PARCELS 1. Z 10, A, B. AND THE TRIANGLE PARCEL ARE OWNED BY GEORGIA-PACinC.

16. GEORGIA-PACinC PURCHASED THIS PORTION OF THE PROPERTY (THE •TRIANGLE PARCEL") FROM THE MICHIGAN DEPARTMENT OF TRANSPORTATION (MtXJT) IN EARLY 2006.

GEORGIA-PACIFIC PURCHASED THIS PORTION OF THE KING HIGHWAY ( M - 9 6 ) RIGHT-OF-WAY THAT IS ENaOSED BY THE KING HIGHWAY LANOFia SITE BOUNDARY FENCE IN JUNE 2008, WHICH IS COMPRISED OF PARCEL A (PREVIOUSLY OVINED BY MOOT) AND PARCEL B (PREVIOUSLY OWNED BY THE OTY OF KALAMAZOO).

ALLIED PAPER, INC./PORTAGE CREEK/ KALAMAZOO RIVER SUPERFUND SITE

SAMPLING PLAN FOR PORE WATER COLLECTION SYSTEM OUTFALLS

SITE PLAN AND PROPOSED SAMPLE LOCATIONS

^ ARCADIS FIGURE

1

Page 15: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Native Vegetation

6" Vegetative Topsoil Layer

24" Drainage/Barrier Protection Layer (Sandfill)

40 mil Linear Low-Density Polyethylene (LLDPE) Flexible Membrane Liner (FML)

6" Gas Venting Layer

Subgrade

FINAL COVER SYSTEM DETAIL NOT TO SCALE

so:

Ii NOTE: 1.The barrier protection and gas venting layers

consists of imported, permeable, clean soil.

ALLIED PAPER, INC./PORTAGE CREEK/ KALAIVIAZOO RIVER SUPERFUND SITE

SAMPLING PLAN FOR PORE WATER COLLECTION SYSTEM OUTFALLS

FINAL COVER SYSTEM CROSS-SECTION DETAIL

^ ARCADIS FIGURE

Page 16: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

ARCADIS

Attachment 1

Certificate of Aggregates from Aggregate Resources, Inc.

Page 17: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

0 4 / 2 3 / 2 0 0 8 10 :57 FAX 12693451137 BALKEMA EXCAVATING @)002/002

AGGREGATE RESOURCES, INC. AGGREGATE PRODUCTION AND SALES

1500 RIVER STREET KALAMAZOO, MICHIGAN 49048 PHONE (269) 345-5289 FAX (269) 345-1137

AGGREGATE MIDWAY 4™ STREET RESOURCES AGGREGATE AGGREGATE MDOT39-fi9 MDOT 39.64 MDOT 39-73

QUINCY RAVINE HART AGGREGATE AGGREGATE AGGREGATE MDOT 12-37 MDOT 39-56 MDOT38'100

Gun River Aggregates MOOT 03-106

R£: Certification of Aggregates; Aggregate Resources, Inc.'s above listed pits.

Please consider this correspondence as formal notice that all Aggregates from the above named facilities are virgin and native materials that are produced/mined at the site. The products are free from contaminants and will meet the parameters of clean material as defined by the MDEQ.

If you or your Engineer on site have any questions please feel free to contact me at 269-345-5289 or my cell 269-209-3931

Phil Cole Sales Mgr.

Page 18: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

ARCADIS

Attachment 2

November 11,1998 Sharon Bailey,

RMT, Inc. Letters to Bill Rankin, P.E.

Blasland, Bouck, & Lee, Inc.

Page 19: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

November 11,1998

Mr. BiU Rankin Project Engineer Blasland Bouck & Lee 6723 Towpath Road Syracuse, NY 13214

Subject

Dear Bill:

Sand Drainage Material King Highway Landfill Georgia-Pacific Corporation Kalamazoo, Michigan

D REVIEWED & NOTED

• ^

REVIEWED SOUEY FOR O a C M . CCMPUANCE WITH COMIMCT OOCUUaiTS ?LASLA^4P. BPMpK&LEE. INC.

OSobl

\ I RESUBMIT j 1 REACTED

RMT, Inc, Michigan (RMT) has reviewed the laboratory data on the sand drainage material

supplied by Taplin Envirorunental Contracting (Taplin) for use in stabilizing Cell 4 at the King

Highway Landfill. Two samples of the material were collected and submitted to a testing

laboratory for chemical analysis. Prior to the sampling event, it was agreed by RMT and

Blasland Bouck & Lee that two roimds of sampling would be conducted on each of the

proposed borrow sources for the list of parameters identified by the Michigan Department of

Environmental Quality in BB&L's letter dated October 7,1998, as potential constituents of

concern.

In reviewing the results of the two rotmds of sampUng, the VOCs (includiag acteone and

naphthalene), PCBs, phenol, and 4-methylphenol were all below detection limits; metals were

detected at levels less that the State of Michigan's Soil Residential and Cormnercial 1 direct

contact cleanup criteria and in many instances were less than the state's generic background

levels. After reviewing this information, it is our opinion that the suppUed material is

acceptable for its intended use and is in general conformance with the overall intent of the

project design and specifications.

Sincerely,

RMT, Inc., Michigan

Sharon L. Bailey, P.E. Senior Project Manager

Attachments: cc: B Paul Montney, Georgia-Pacific

RMT, INC., MICHIGAN

1143 HiGHUHD DRIVE, SUITE B - 48108-2237

P.O. Box 991 - 48106-0991

AHH ARBOt, Ml

734/971-7080 - 734/971-9022 FAX

C:\WPAA M\PrA(XM«254\45\ljOin2S6.4SA

Page 20: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

WESTERN MICHIGAN

ENVIRONMENTAL SERVICES, INC. Analytical Uboratoty and Testing Services

3352 128th Avenue, Hoiiand, Michigan 49'}24-9263 Phone :616 -399-6070 FAX 616-399-6185 E-mait: /nfo®vvmesi f om Internet; ^^Itp:/A^^wv.w/T)^^6].coff)

CLIENT: Taplin Environmental Cont 5100 West Michigan Avenue Xalantazoo, MI 49006

DATE:

ANALYSIS OF:

REPORTED BY:

DATE RECEIVED:

Attn: Steve Taplin

Be: RMT: G-P (King Highway LF)

October 9, 1998

Soil Samples

Robert K. Zahray./>^aborator^14anager

Received from client on October 2, 1998.

Saapla ID: 003 (Class II Fill) Lab ID: 9810030-01 Collected: 09/29/98

TEST RESULT UNITS ANALYZED BY METHOD KDL

Total Solids Arsenic . Barium Chromium

-i ils Prep, Solid

Thallium Vanadium Zinc 4-Methylphenol Acid/Permanganate Cleanup Florisil Cleanup Phenol Polychlorinated Biphenyie PCB-1016 PC8-1221 PCB-1232 PCB-1242 PCB-124B PCB-1254 PCB-12 60 Total PCBa Silica Gel Cleanup Soxhlet Ext. for PCBa Soxhlet Extraction for BNA Sulfur Cleanup Volatile Organic Compounds AeryIonitrile Benzene Bromochloromethane Broroodichloromethane Bromoform Bromomethane 2-Butanone • arbon Disulfide rbon tetrachloride

' ~nlorobenzene Chloroethane

98.9 1.5 3.7 3.0 1.4

10/05/98 BDL 4.1 13 BDL

10/07/98 10/07/98

BDL

BDL BDL BDL BDL BDL BDL BDL BDL

10/07/98 10/06/98 10/06/98 10/07/98

% of eample mg/kg dry wt. ng/kg dry wt. mg/kg dry wt. tng/kg dry wt. date digested mg/kg dry wt. rag/kg dry wt. mg/kg dry wt. ;jg/kg dry wt date completed date completed ;ig/kg dry wt

pg/kg dry wt (ig/kg dry wt pg/kg dry wt ^g/kg dry wt /jg/kg dry wt ^g/kg dry wt f<g/kg dry wt ^g/kg dry wt date completed prep, date prep, date date completed

dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

Hg/kg ^g/kg pg/kg Mg/kg vg/kg Mg/kg vg/kg pg/itg Mg/i^g f g/itg Mg/wg

10/06/98 10/07/98 10/06/98 10/06/98 10/06/98

10/07/98 10/06/98 10/06/98 10/07/98

10/07/98

10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98

10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98

JA JA JA JA JA JA JA JA JA DAH DGK DGK DAH

DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK HL DGK

DAH DAH DAH DAH DAK DAH DAH DAH DAH DAH DAH

APHA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA

EPA EPA EPA EPA EPA

. 2540 B 7060 6010 6010 6010 3050 7841 6010 6010 8270 3665 3620 8270 8082

3630 3540 3S40 3660 8260

K/A 0.24 0.12 0.12 1.2

0.24 0.24 0.24 330

330

330 330 330 330 330 330 330

1,700

10 10 10 10 10 10 50 SO 10 10 10

BDL = Below Detection Limit MDL = Method Detection Limit Page 1 of 4

M T -IJV/ I woo * ^ Piln\»d on qtevdrt Paw

OT n n - C T - U B W

Page 21: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

WESTERN MICHIGAN ENVIRONMENTAL SERVICES, INC.

ID: 003 (Class II Fill) Lab ID: 9810030-01 Collected: 09/29/98

TEST RESULT UNITS AKALXZED BY HEIBOD MDL

Volatile Organic Compounds Chloroform Chloromethane Dibromochloromethane 1,2-Dibromo-3-chlor6propane Dibromomethane 1,2-Dibromoethane 1,2-DichIoroben2ene 1, 3-Dichlorobenzene 1,4-D ichlorobenzene Trans-l,4-dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cia-l,2-Dichloroethene tranB-l,2-DichIoroethene 1, 2-Dichloropropane cia-l,3-Dichloropropene trana-1,3-Dichloropropene Diethyl Ether Ethylbenzene Hexachloroethane 2-Hexanone laopropylbenzene Methylene Chloride .Hpthyl Iodide • athylnaphthalene \. .•iethyl-2-Pentanone Methyl Tertiary Butyl Ether Naphthalene 2-Propanone n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-TrimethyIbenzene 1,3,5-TrimethyIbenzene Vinyl acetate Vinyl chloride o-Xylene m-Xylene & p-Xylene

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 3DL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

M/Jtg /jg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg pg/)tg Mg/kg pg/kg pg/kg /jg/kg pg/kg pg/kg pg/kg pg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg pg/kg Mg/kg Mg/kg pg/kg

dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt

10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/9B 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98

EPA DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH

8260 10 10 • 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 50 10

250 10 10 50 50 10

250 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10

BDL = Below Detection Limit MDL = Method Detection Limit Page 2 of 4

^ J )»,itdi<) Oil Rr,<>.-li-^ P.ip.lr

Page 22: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

WESTERN MICHIGAN ENVIRONMENTAL SERVICES, INC.

>la ID: 004 (ClasB XI Fill) Lab ID: 9810030-02 Collected: 09/29/98

WR Total Solids Arsenic Barium Chromium Lead Metals Prep, Solid Thallium Vanadium Zinc 4-MethYlphenol Acid/Permanganate Cleanup Floriell Cleanup Phenol Polychlorinated Biphenyie PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 Total PCBs Silica Gel Cleanup Soxhlet Ext. for PCBa Soxhlet Extraction for BNA Sulfur Cleanup Volatile Organic Compounds

'rylonitrile V nzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-autanone Carbon Disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,2-Dibromo-3-chloropropane Dibromomethane 1,2-Dibromoethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Trana-l,4-dichloro-2-butene Dichlorodi fluorc»nethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-l,2-Dichloroethene tranB-l,2-Dichioroethene 1,2-Dichloropropane cia-l,3-Dichloropropene trans-l,3-Dichloropropene niethyl Ether ihylbenzene

.lexachloroethane 2-Hexanone IBopropyIbenzene

RESULT

99.3 1.5 88 11 22

10/06/98 BDL 25 28

BDL 10/07/98 10/07/98

BDL

BDL BDL BDL BDL BDL BDL BDL BDL

10/07/98 10/06/98 10/06/98 10/07/98

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

1 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

UNITS

% of sample mg/kg dry wt. mg/kg dry wt. mg/kg dry wt. mg/kg dry wt. date digested mg/kg dry wt. mg/kg dry wt. mg/kg dry wt. pg/kg dry wt date completed date completed Mg/kg dry wt

Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt date completed prep, date prep, date date completed

Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt Mg/kg dry wt

ANALYZED

10/06/98 10/07/98 10/06/98 10/06/98 10/06/98

10/07/98 10/06/98 10/06/98 10/07/98

10/07/98

10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98

10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98

BY

JA JA JA JA JA JA JA JA JA DAH DGK DGK DAH

DCX DGK DGK DGK DGK DGK DGK DGK DGK DGK HL DGK

DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAK DAH DAH DAH DAH DAH DAK DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH

METHOD

APHfl EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA

EPA EPA EPA EPA EPA

. 2540 B. 7060 6010 6010 6010 3050 7841 6010 6010 8270 3665 3620 8270 8082

3630 3540 3540 3660 8260

MDL

N/A 0.24 0.12 0.12" 1.2

0.24 0.24 0.24 330

330

330 330 330 330 330 330 330

1,700

10 10 10 10 10 10 50 50 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 50 10

BDL = Below Detection Limit MDL = Method Detection Limit Page 3 of 4

-11 i-s.! _jtn

^ 3 f ' t i i l 'Mt f t i i Hi.-rvrti'd H:»::ft*

Page 23: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

WESTERN MICHIGAN ENVIRONMENTAL SERVICES. INC.

l a I D : 004 ( C l a s s I I F i l l ) Lab ID: 9 8 1 0 0 3 0 - 0 2 C o l l e c t e d : 0 9 / 2 9 / 9 8

TKST RESULT UNITS ANALYZED BY METaOD MDL

Volatile Organic Compounds Methylene Chloride Methyl Iodide 2-Methylnaphthalene 4-Methy1-2-Pentanone Methyl Tertiary Butyl Ether Naphthalene 2-?ropanone n-PropyIbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1, 2,4-TrimethyIbenzene 1,3,5-TrimBthylbenzene Vinyl acetate Vinyl chloride o-Xylene m-Xylene & p-Xylene

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg Mg/kg

dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt

10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98 10/07/98

DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH DAH

EPA 8260 250 10 10 50 50 10

250 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10

NOTE: Samples were collected in bulk.

BDL = Below Detection Limit MDL = Method Detection Limit Page 4 of 4

^ ^ Hnii.-fl on ruCrdHd P;ipei

Page 24: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

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Taplin Envjjonmenlal Conlracling 5100 W. Michigan Avenue Kalamazoo. Ml 49006 616-375-9595

CHAIN-OF-CUST(|^(' RECORD

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Special Instructions (use back o( form II necessary - attach photocopies lo other pages)

REViSEO<-?-BO • OTEX Bennr.e foluenc,Em)(IB«nf8ne. Xylene; • TPH Toiar Peiroici-.Ti Hrdioca'Doris. " PNA Pov Nucta'Aerc»^atics

Page 25: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

WESTERN MICHIGAN ENVIRONMENTAL SERVICES, INC. AnalytlcAl Laboratory and Testing Services

3352 128tft Avenue, Ho;i,tnd. Mlrnigan 49424-9263 Phone:616-399-6070 FAX 616-399-6185 E-mail: [email protected] Intemec: hnpVAAAAw^/.wmesj.com

CLIENT: Taplin Environmental Cont 5100 West Michigan Avenue Kalamazoo, KI 49006

DATE:

ANALYSIS OF:

Attn: Steve Taplin

Re: RMT, Inc. (G.P. King Hwy LF)

November 1 7 , 1998

S o i l Scunplea

REPORTED BY:

DATE RECEIVED:

Robert K. Zahray, >£aboratory Man6^r

Received from client on Noi^nber 13, 1998.

Sample ID: Sanple 05 Lab ID: 9811168-01 Collected: 11/12/98

TEST RESULT UNITS ANALYZED BY KETEOD MDL

Total solids 93.8 Arsenic 0.99 Barium S.Q Chromium 2.5 .L«>=id BDL

.Is Prep, Solid 11/14/98 ' .ilium BDL Vanadium 3.4 Zinc 8.2 4-Methylphenol BDL Acid/Permanganate Cleanup 11/16/98 Florisil Cleanup 11/16/98 Phenol BDL Polychlorinated Biphenyls PCB-1016 BDL PCB-1221 BDL PCS-1232 BDL PCB-1242 BDL PCB-1248 HDL PCB-1254 BDL PCB-1260 BDL Total PCBs BDL Silica Gel Cleanup 11/16/98 Soxhlet Ext. for PCBs 11/13/98 Soxhlet Extraction for BNA 11/13/98 Sulfur Cleanup 11/16/98 Volatile Organic Compounds Acrylonitrile BDL Benzene BDL Bromochloromethane BDL Bromodichloromethane BDL Bromoform BDL Bromomethane BDL 2-Butanone BDL Carbon Disulfide BDL

% of sample itig/kg dry wt. mg/kg dry wt. rag/kg dry wt. mg/kg dry wt. date digested mg/kg dry wt. mg/kg dry wt. mg/kg dry wt. ;jg/kg dry wt .date completed date completed ^g/kg dry wt

pg/kg dry wt pg/kg dry wt /jg/kg dry wt /jg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt date completed prep, date prep, date date completed

pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt

11/16/98 11/14/98 11/16/98 11/16/98 11/16/98

11/16/98 11/16/98 11/16/98 11/17/98

11/17/98

11/16/98 11/16/98 11/16/98 11/16/98 11/16/98 11/16/98 11/16/98 11/16/98

11/13/98 11/13/96 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98

JA JA KBR MBR HBR JA JA MBR MBR HL DGK DGK HL

DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK

HL HL HL HL HL HL HL HL

APHA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA

EPA EPA EPA EPA EPA

L 2540 7060 6010 6010 6010 3050 7841 6010 6010 8270 3665 3620 8270 8082

3630 3540 3540 3660 8260

N/A 0.048 0.24 0.24 2.4

0.048 0.48 0.48

25

25

19 19 19 19 19 19 19 95

50 10 10 10 10 50 50 50

BDL = Below Detection Limit MDL = Method Detection Limit

«:c»-pr>n-?'?OTr»

page l of 4

nW"X ^ n -AW=J M T T H W I \//T ^ i Printed on Recvclad Panti

OT oo-s i - - t^w

Page 26: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

sanple ID: Sanple 05 Lab ID: 9811168-01 C o l l e c t e d : 11 /12/98

RESULT UNITS ANALYZED BY METHOD MDL

Volatile Organic Compounds Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1, 2-DibrQmo-3-chloropropane Dibromomethane 1,2-Dibromoethane 1,2-Dichlorobenzene 1,3-DichlQrobenzene 1,4-Dichlorobenzene Trans-l,4-dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1, 2-DichlorQethane 1,1-Dichloroethene cis-l,2-Dichloroethene trane-l,2-Dichloroethene 1, 2-Dichloropropane cis-l,3-Dichloropropene trans-l,3-Dichloropropene Diethyl Ether Ethylbenzene Hexachloroethane 2-Hexanone IsopropyIbenzene

hylene Chloride ,hyl Iodide

2-Methylnaphthalene 4-Methy1-2-Pentanone Methyl Tertiary Butyl Ether Naphthalene 2-Propanone n-PropyIbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,2,4-Trichlorobenzene 1,1,2-Trichloroethar^e Trichloroethene Trichlorofluoromethane 1,2,3-TrichlorDpropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride o-Xylene m-Xylene & p-Xylene

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt fjg/^g dry wt pg/kg dry wt pg/kg dry wt ;jg/kg dry wt Jig/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt n q / k q dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt pg/kg dry wt

11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/90 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98

HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL

EPA 8260 10 10 50' 10 50 10 50 10 10 10 10 10 10 50 10 ID 10 10 10 10 10 10 100 10 10 SO 10 50 10 50 50 50 50 250 10 10 10 10 ID 10 10 50 10 10 50 10 10 10 10 50 10 20

BDL = Below Detection Limit MDL = Method Detection Limit

«c-:7nQ?'?'QTQ

Page 2 of 4

Page 27: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

Saaple ID: Sa*ple 06 Lab ID: 9811168-02 Collected: 11/12/98

r

Total Solids Arsenic Barium Chromium Lead Metals Prep, Solid Thallium Vanadium Zinc 4-Methylphenol Acid/Permanganate Cleanup Florisil Cleanup Phenol Polychlorinated Biphenyls PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-124B PCB-12S4 PCB-1260 Total PCBs Silica Gel Cleanup Soxhlet Ext. for PCBs Soxhlet Extraction for BNA Sulfur Cleanup Volatile Organic Compounds Acrylonitrile

nzene .omochloromethane

Bromodichloromethane Bromoform Bromomethane 2-Butanone Carbon Disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,2-Dibroma-3-chloropropane Dibromomethane 1,2-Dibromoethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Trans-l,4-dichloro-2-butene Dichlorodifluoromethane 1,1-Dichloroethane 1, 2-D ichloroethane 1,1-Dichloroethene cis-l,2-Dichloroethene trans-l,2-Dichloroethene 1,2-Dichloropropane ciB-l,3-Dichloropropene trans-l,3-Dichloropropene Diethyl Ether

RBSULT

90.2 1.5 5.4 2.6 3.6

11/14/98 BDL 3.8 9.8 BDL

11/16/98 11/16/98

BDL

BDL BDL BDL BDL BDL BDL BDL BDL

11/16/98 11/13/98 11/13/98 11/16/98

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

UNITS

% of 3 mg/kg mg/kg mg/kg mg/kg

ample dry wt. dry wt. dry wt. dry wt.

date digested mg/kg mg/kg mg/kg

dry wt. dry wt. dry wt.

pg/kg dry wt date completed date c pg/kg

:ompleted dry wt

pg/kg dry wt f^g/y^g pg/kg pg/V-g ;jg/kg pg/kg pg/kg pg/kg

dry wt dry wt dry wt dry wt dry wt dry wt dry wt

date completed prep. prep.

date date

date completed

pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg

dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt

pg/kg dry wt pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg

dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt

ANALYZED

11/16/98 11/14/98 11/16/98 11/16/98 11/16/98

11/16/98 11/16/98 11/16/98 11/17/98

11/17/98

11/16/98 11/16/98 11/16/98 11/16/98 11/16/98 11/16/98 11/16/98 11/16/98

11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98 11/13/98

BY

JA JA MBR MBR MBR JA JA MBR MBR HL DGK DGK HL

DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK DGK

HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL

HETBOD

APHA 2540 B. SPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA EPA

EPA EPA EPA EPA EPA

7060 6O10 6010 6010 3050 7841 6010 6010 8270 3665 3620 8270 B082

3630 3540 3540 3660 8260

MDL

N/A 0.048 0.24 0.24 2.4

0.048 0.48 0.48

25

25

27 27 27 27 27 27 27 140

50 10 10 10 10 50 50 50 10 10 50 10 50 10 50 10 10 10 10 10 10 50 10 10 10 10 10 10 10 10

100

BDL = Below Detection Limit MDL = Method Detection Limit

ei^^nct?'?'ctTC)

Page 3 of 4

-IWN d S "ANO N l - l d V X \ / e r : O T 0 0 - Q T - - t « W

Page 28: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

s a a p l a I D : S a a p l a 06 Lab I D : 9811168-02 C o l l e c t e d : 1 1 / 1 2 / 9 8

RESULT UNITS ANALYZED BY METHOD MSL

Volatile Organic Compounds Ethylbenzene Hexachloroethane 2-Hexanone laopropylbenzene Methylene Chloride Methyl Iodide 2-Methylnaphthalene 4-Methy1-2-Pentanone Methyl Tertiary Butyl Ether Naphthalene 2-Propanone n-PropyIbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,S-Trimethylbenzene Vinyl acetate Vinyl chloride

Xylene .^Xylene & p-Xylene

BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL

pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/kg pg/iig pg/kg pg/kg pg/kg pg/kg pg/kg

dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry wt dry V'Jt dry wt dry wt dry wt dry wt dry wt

EPA 8260 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11

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HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL HL

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Page 29: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

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Page 30: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

November 11,1998

Mr. Bill Rankin Project Engineer Blasland Bouck & Lee 6723 Towpath Road Syracuse, NY 13214

Subject:

Dear BiU:

Topsoil King Highway Landfill Georgia-Pacific Corporation Kalamazoo, Michigan

D REVIEWED SREVIEWEL & NOTED

REVIEWED SOLEV FOn Q8£RM. coMPUAWx vffm coNmACT c c a a s f r s BLASLANa BOUCK & LEE, INC.

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j I REJECTED

RMT, Inc, Michigan (RMT) has reviewed the laboratory data on the topsoil supplied by Taplin Envixonraental Contracting (Taplin) for use in stabilizing Cell 4 at the King Highway Landfill. Two samples of the materiail were collected and submitted to a testing laboratory for cherrucal analysis. Prior to the sampling event, it was agreed by RMT and Blasland Bouck & Lee that two rounds of sampHng would be conducted on each of the proposed borrow sources for the list of parameters identified by the Michigan Depairtment of Envirorunental Quality in BB&L's letter dated October 7,1998, as potential constituents of concern.

\

In reviewing the resxilts of the two rounds of sampUng, the VOCs (including acteone and naphthalene), PCBs, phenol, and 4-methylphenol were all below detection limits; metals were detected at levels less that the State of Michigan's Soil Residenticil and Commercial 1 direct contact cleanup criteria and in many instances were less than the state's generic background levels. After reviewing this information, it is our opinion that the suppUed material is acceptable for its intended use and is in general confonnance with the overall intent of the project design and specifications.

Sincerely,

RMT, Inc., Michigan

Sharon L. Bailey, P.E. Senior Project Mainager

Attachments:

cc: Paul Montney, Georgia-Pacific

RMT, INC., MICHIGAN

1 M 3 HiGHUND DRIVE, SUITE B - 48108-2237

P.O. Box 991 - 48106-0991

ANN ARBOR, Ml

734/971-7080 - 734/971-9022 FAX

C;\WPAAM\Pn\O<MI22M\.IS\L0OZ25*.45B

Page 31: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

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Page 32: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

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Page 33: ARCADIS - SAMPLING PLAN FOR PORE WATER COLLECTION … · MDEQ-RRD-Superfund Constitution Hall - 3rd Floor South 525 West Allegan Street Lansing, Michigan 48909-7926 us EPA RECORDS

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10/09/98 FRI 16:00 [TX/RX NO 6655]