ar cl ar cl... ar cl ar + - cl ar stilben e(1)
Post on 19-Dec-2015
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Ar
ClCl
Ar
ClCl.
ClCl
Ar
ClClAr
+-
ClCl
Ar
Stilbene(1)
Stilbene(2)
= HCl
Water / H2O
=
i.e.:
H3O+ ..... Cl-(aq)
HCl
+ H2O(l)
H3O+ ..... Cl-(aq)
HCl
+ H2O(l)
Ene
rgy
+
= HCl(g)
= H+Cl- (g)
Ene
rgy
r(HCl)HCl
H + Cl
H+Cl-
H+ + Cl-
HCl(g)
H+Cl- (g)
Ene
rgy
+H3O+...Cl-(aq)
r(HCl)
HCl
H+Cl-
H+ + Cl-
H3O+...Cl-(nxH2O)
+ n x H2O
HCl(g)
H+Cl- (g)
Ene
rgy
+H3O+...Cl-(aq)
r(HCl)
HCl
H+Cl-
H3O+...Cl-(nxH2O)
H+Cl-+ H2O
+ H2O
+ H2O
:::::
H+Cl-
H+Cl-
út
HX
HX/H2O
Spíttari
TurboPumpa
TOF rör
safnlinsa
MCP skynjari
sveiflusjá
tölva
Gas LaserLit- Laser
SHG Pellin Broca prisma
Stjórn-eining
LASER-tæki
jónunarklefar
TOFrör
TOF2 64 8 201816141210
s
Sample: Ar:HF = 80:20Mw: 19 - 21 amu:
HF+/H2F
+
Ionyield
Laser excitation:86616.5 cm-1
Mass spectra vs. Laser excitation
Lasercm-1
Ion yield
Fig. 3 Experimental and calculated REMPI-TOF spectra,
E
86616cm-1
0(HF)2
(HF)2
**
1
2
1
2
*
*
K = 0 K = 1
= 0
* = 0
(n
((n+1) p
(1,2): (0,0)
(1,2 ): (0,0)?
* *
J
J*
36 cm-1
Electronic-, vibrational- and rotational- resonance transitions in the (2+1) REMPI, 86618 cm-1 system.
Ab initio/DFT
Orku-lágmörkun
H
H
1. Laser ljósefnafræði og litrófsgreining:
:Victor Huasheng Wang
Gísli Hólmar Jóhannesson,Áshildur LogadóttirBenedikt G. WaageJón Matthíasson
Kristján MatthíassonÓmar Freyr Sigurbjörnsson
Oddur Ingólfsson
Haraldur Þórðarson
Hérlendir samstarfsaðilar
*
*
2. Lögun stilben- ogdioxan-afleiða:
Jón K.F. Geirsson,
Christopher Evans
Sigríður Jónsdóttir
Ásgeir KonráðssonBenedikt I. Ásgeirsson
samstarfsaðilar:
3. Lögun Si haldandi efna(NMR o.fl.):
Dr. Ingvar Árnason,
Dr. Sigríður Jónsdóttir
Pálmar I. Guðnason
Hérlendir samstarfsaðilar: