annual report ictja 2013

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Annual Report ICTJA-2013 Institute of Earth Sciences Jaume Almera (A Geosciences Institute)

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Annual ReportICTJA-2013

Institute of Earth Sciences Jaume Almera(A Geosciences Institute)

2 ANNUAL REPORT ICTJA 2013

Foto portada: Coring campaign at Maule (Chile) (photo by Santiago Giralt, ICTJA-CSIC)

Disseny i maquetació: Masgrau-Yani, SL

ANNUAL REPORT ICTJA 2013 3

Foreword

Montserrat TorneDirector

ICTJA main mission is to advance scientific understanding of Earth System Science by improving our knowledge of geological processes, mitigation of geohazards and exploration of geological resources applying advanced experimental and analytical methodologies. Central to our mission is quality training of the next generation of Earth Sciences researchers and technicians.

Following the main guidelines of ICTJA-Strategic Plan 2010-2013, during 2013 our research activities have been developed through research projects funded by public competitive sources and by industry, as well as a small percentage coming from analytical services.

Despite being still immerse in the aftershocks of the so called “perfect storm” provoked by the financial crisis, ICTJA activities has no suffered too much (yet). Thus, income from grants in 2013 has decreased somewhat from 2012, mainly due to research budget cuts. This coupled with the fact that in 2013 there were no public calls from the 7th Framework Programme has resulted in a decrease in public funding of about 30%. Funds raised from public competitive sources both National and European accounted for 31.5% of the total (319,351.57 ¤), while funds coming from industry accounted for 62.6% of the total (634,590.44 ¤). The remaining 6.3% corresponds to funds raised from agreements with the public sector and from services. These figures are calculated as the yearly granted contribution for pluriannual projects.

Regarding the scientific activities, the number of ISI articles authored or coauthored by ICTJA staff slightly increased from 68 in 2012 to 82 in 2013, averaging 3.15 pub/res, while total publications amount to 90 (3.46

pub/res). A total of 17 PhD students were trained in 2013, which combined with the actively participation of senior researchers and postdocs (10) in doctorate and master programs, demonstrates our compromise with quality training and teaching of young researchers.

ICTJA has also been quite active in the organization of a number of specialized seminars, conferences, lectures and in disseminating our research results to the society. Among them it is worth highlighting our participation in the GEOflaix! Exhibition, an alternative look at daily objects from the perspective of Earth Sciences; Espai Ciència-Saló de l’Ensenyament, where thousands of young people and teachers got advice at the fair; and EXPOMINER, a collector’s heaven. Those events were organized jointly with the Faculty of Geology of the University of Barcelona and the former Geological Institute of Catalonia.

It is worth mentioning that 2013 has also been the year of designing ICTJA 2014-2017 strategy (available at the www.ictja.csic.es site). The imminent launch in 2014 of Horizon 2020 and the recent launch of the National Plan for Scientific and Technological Research and Innovation together with the scarcity of funding at national level requires the necessity to define a research strategy for the coming years that maintains and moves forward ICTJA’s momentum and competitiveness at both national and international levels. This excercise has also served as the basis for the development not only ofICTJA-CSIC Action Plan 2014-2017 but for our active participation in the preparation of the scientific brochures of the Natural Resources CSIC Research Area. The strategy focusses on the mission and aims of the Institute and sets out ICTJA’s flagships with the aim to achieve scientific advancement while providing strong support of industrial and societal needs. ICTJA’s flagships are:

– Knowledge-driven Research– Applied Research– Responding to societal needs– Training and support of early career Researchers and Technicians

Last but not least, in the year 2013 the governing board of ICTJA approved the establishing of ICTJA-SPA Awards to the best oral and poster presentation. The aim is to help improving PhD presentations skills at EGU and AGU like conferences.

ANNUAL REPORT ICTJA 2013 5

ContentsICTJA at a glance.............................................................................................................................................................6

Our.Mission.......................................................................................................................................................................6

Our.Aims............................................................................................................................................................................7

ICTJA organization chart..............................................................................................................................................8

Service units and Labs.................................................................................................................................................10

Scientific.Services.......................................................................................................................................................... 12

labGEOTOP.Service............................................................................................................................................. 12

X-.Ray.Diffraction.Service.................................................................................................................................. 13

Paleomagnetism.Service.(CSIC-UB)............................................................................................................... 14

Research.Laboratories................................................................................................................................................... 16

Seismic.Laboratory.............................................................................................................................................. 16

Raman.Spectroscopy.and.Photoluminiscence.Laboratory........................................................................ 17

LARX.–.Laboratory.of.X-ray.Analytical.Applications.................................................................................. 18

U-Th.Geochronology.Laboratory.................................................................................................................... 20

Scientific.Boreholes.(Almera-1.&.2)................................................................................................................ 21

SIMGEO.(UB-CSIC)............................................................................................................................................22

Personnel........................................................................................................................................................................ 24

How to reach us............................................................................................................................................................ 25

ICTJA Research Groups.............................................................................................................................................. 26

Earth’s.structure.and.dynamics..................................................................................................................................27

Group.members....................................................................................................................................................27

Research.outline.................................................................................................................................................. 28

Publications.2013................................................................................................................................................ 29

Research.projects.2013.......................................................................................................................................32

Crystallography.and.Optical.properties.................................................................................................................. 34

Group.members................................................................................................................................................... 34

Research.outline.................................................................................................................................................. 34

Publications.2013.................................................................................................................................................35

Research.projects.2013.......................................................................................................................................35

Environmental.Changes.in.the.Geological.Record................................................................................................ 36

Group.members................................................................................................................................................... 36

Research.outline.................................................................................................................................................. 36

Publications.2013................................................................................................................................................ 38

Research.projects.2013....................................................................................................................................... 41

Geophysical.and.Geochemical.Modelling.of.Geohazards.Processes.and.Subsurface.Resources............ 42

Group.members................................................................................................................................................... 42

Research.outline.................................................................................................................................................. 42

Publications.2013................................................................................................................................................44

Research.projects.2013......................................................................................................................................46

ICTJA 10 highlighted papers....................................................................................................................................48

Theses, Seminars and Courses................................................................................................................................ 66

Editorial and Assessment activities...................................................................................................................... 69

International Committees and Collaboration.................................................................................................... 69

ICTJA-SPA Awards 2013............................................................................................................................................. 71

Outreach Activities......................................................................................................................................................73

ICTJA in numbers..........................................................................................................................................................76

6 ANNUAL REPORT ICTJA 2013

ICTJA at a glance

Our Mission

ICTJA.is.an.international.geosciences.research.institute.of.excellence.whose.mission.is.to.advance.the.understanding.of.Earth.System.Science..We.will.achieve.this.by.applying.advanced. (forefront). ex-perimental. and.analytical.methodologies.to.well-defined,.knowledge-driven.research.objectives..A.key.

part.of.our.mission.is.to.meet.industrial.and.societal.needs.through.knowledge.transfer.applied.to.geohazards.and.exploration.and.exploitation.of.geological.resources..Central.to.our.mission.is.quality.training.of.the.next.generation.of.Earth.Science.researchers.and.technicians.

ANNUAL REPORT ICTJA 2013 7

Our Aims

a).Identify.new.and.emerging,.high-priority.research.opportunities.

b).Enhance.our.training.capabilities.of.the.next.generation.of.Earth.scientists.

c). Increase. our. support. of. early. career.researchers.

d). Raise. our. level. of. international.collaboration.

e).Create.and.translate.breakthroughs.in.knowledge-driven.research.into.practical.applications. that. provide. the. knowledge.transfer.that.industry.and.society.seeks.

f).Advance.knowledge.and.understanding.within. and. across. the. different. fields. of.Earth.Sciences.

One. of. our. aims. is. to. define. a. research.strategy. for. the. period. 2014-2017.. The.imminent.launch.of.Horizon.2020.(H2020).and.the.recent.launch.of.the.National Plan for Scientific and Technological Research and Innovation. (PNIDI). include. both.fundamental. and. applied. science,. but.their. focus. are. squarely. on:. a). Societal.challenges,.b).Training.programs,.and.c).Infrastructures.

Furthermore,.the scarcity of funding.that.will.be.raised.at.a.national. level.requires.that. we. define. research strategies. for.the. coming. years. that. maintains. and.moves. forward. ICTJA’s. momentum. and.

competiveness. at. both. the. national. and.international.level..Significantly,.these.aims.must.intersect.both:

•.The.portfolio.of.ICTJA.research.interests.and.capacities.

•.The.portfolio.of.HORIZON.2020;.PNIDI,.and.industry.interests.

The ICTJA at a glance

8 ANNUAL REPORT ICTJA 2013

ICTJA organization chart

ANNUAL REPORT ICTJA 2013 9

10 ANNUAL REPORT ICTJA 2013

Service Units

Management and General Services

The. Management. and. General. Services.depend.directly.on.the.Institute’s.Manager.and.provide.service.to.all.research.groups;.services.and. labs.. In. particular,. the. Management.Service.performs.the.following.tasks:

•.Human. resources.. Management. of.fixed.personnel,.contract.personnel.and.trainees:.taking.up.their.posts,.contracts,.grants,.end.of.contract,.reporting.joiners.and.leavers.to.the.Social.Security.system,.rounds.of.Social.Action.funding,.handling.the.paperwork.for.occupational.accidents,.residency.permits,.managing.and.moni-toring. holidays,. temporary. incapacity,.medical.check-ups,.insurance,.etc.

Service units and Labs

•..Project.management..This.includes.applying.for,.monitoring.and.financial.management.of.national.and.international.projects,.both.public.(based.on.a.competitive.basis).and.private.(mainly.contracts.and.agreements.with.Foundations.and.Industry).

•..Purchasing.and.procurement..This.includes.administrative.procurements.–.purchase.of.supplies,. technical. consultancy. contracts,.service.and.works.contracts,.and.maintenance.–.buildings,.special.infrastructures,.technical.services,.vehicles.

The. General. Services. are. responsible. for.maintenance.of.electrical.and.mechanical.installations. and. devices,. porter,. mailing,.and.cleaning.

ManagerJosé Luis López Burguillo

Administrative supportMaría Consuelo PalacioEsmeralda RodríguezFrancisco MosqueraLeonor FernándezElisa Zamorano

MaintenanceÓscar ÁvilaMiquel Ángel GonzálezDimas Calvo (INEM contract)

Call centerXavier PascualAlejandro Tatevosian

LibraryDolores Fernández

ANNUAL REPORT ICTJA 2013 11

Staff Joan Benavent, Technical staff (CSIC)Marc Español, CSIC-Contract

Service units and Labs

Computing and Communications Service

The. main. objective. of. this. service. is. to.facilitate.the.communication.and.computing.tools.and.basic.and.advanced.services.to.allow.researchers.of.ICTJA.to.achieve.their.scientific. objectives.. The. unit. manages. a.network. infrastructure. compose. of. about.150.medium.size.computers,.a.wifi.spread.throughout. the. building,. some. server-oriented.computing,.storage.and.connectivity.with. the. Scientifc. Ring/RedIris/Geant2..ICTJA.facilitates.the.access.to.5.CSIC.research.institutes.(CID,.IBB,.CEAB,.IBMB.and.IIBB).to.the.Scientific.Ring."Anella.Científica"..The.Institute.also.collaborates.with.the.Barcelona.Supercomputing. Center. through. the. IBM.Marenostrum.Supercomputer.

Library

The.Library.of.Geology.(UB-CSIC),.housed.in.the.Faculty.of.Geology,.is.jointly.managed.by.the.Faculty.of.Geology.of.the.University.of.Barcelona.(UB).and.the.Institute.of.Earth.Sciences. Jaume. Almera. (ICTJA-CSIC)..Founded.in.1966,.aims.at.the.dissemination.of. journal. articles,. books,. maps,. etc.. in.the.broad.field.of.the.Earth.Sciences..The.publication.of.the.journal.Geological.Acta.is.also.managed.through.this.service.

Library Service

This.library.is.one.of.the.most.important.geology.libraries.in.Spain.in.terms.of.repository.of.journals.and.books.and.quality.of.service..Books.may.be.consulted.via.the.computerized.catalogues.of.

the.CSIC.and.UB,.including.Internet..The.library.has.16,500.volumes.and.1054.journals.(700.are.received.regularly),.15,000.maps.and.20,000.aerial. photographs. in. addition. to. the. major.bibliographic.databases.(GEOREF,.PASCAL,.SCI,.Current.Contents,.CINDOC,.and.bibliography.of.the.geology.of.Spain).Biblioteca.(ICTJA):.http://www.ictja..csic.es/gt/biblio/almerahome.htmlWeb. Biblioteca.(UB):.http://www.bib.ub.edu/.biblioteques/geologia/

Publication of Geologica Acta

It.is.an.international.journal.of.Earth.Science.providing.an.innovative.and.high.quality.media.of.scientific.dissemination..Geologica.Acta.aims.to.stimulate.rapid.diffusion.of. results.and.efficient.exchange.of. ideas.among.the.widespread. communities. of. Earth. Science.researchers. (with. special. emphasis. on.Latin-American,.the.Caribbean,.Europe,.and.the.Mediterranean.regions)..The.Journal. is.edited. in. collaboration. with. the. University.of.Barcelona..Since.2007,.Geologica.Acta.is.included.in.the.Journal.Citation.Report.of.ISI.Thomson.with.an.Impact.Factor.(IF).of.1.262.in.2012.and.a.5.year.IF.of.1.653.Web.Geologica.Acta:.http://www.geologica-acta.com/

BIGPI Database

The.library.is.currently.compiling.a.data-base.on.Bibliography.of.Earth.Sciences.of.the.Iberian.Peninsula.(BIGPI):.it.consists.of.a.database.of.articles,.lectures,.books,.theses,.etc..on.any.aspect.of.the.geology.of.the.Iberian.Peninsula.with. references. to.Geology,.Geochemistry,.Geophysics,. Mineralogy,. Geomorphology,.Natural.Disasters,.Palaeontology,.Environment,.Soil.Science,.etc.Web.BIGPI:.http://www.bib.ub.edu/fileadmin/bigpi/bigpi.htm

12 ANNUAL REPORT ICTJA 2013

Scientific Services.

labGEOTOP Service

The labGEOTOP Service,. Laboratory. of.Elemental. and. Isotopic. Geochemistry. for.Petrological. Applications,. carry. out. multi-disciplinary.research.in.Solid.Earth.Sciences.using. an. established. core. of. world. class.equipment. and. laboratories,. and. expertise.in.the.technical.and.applied.aspects.of.their.use..The.service.plays.a.key.role.in.catalysing.leading.edge.cross-disciplinary.research.within.the.CSIC.and.into.Spain.

The.labGEOTOP.Service.provides.a.central.mass.of.equipment.that.enables.significant.scientific.collaboration.on.a.regional,.national.and. international. scale.. We. undertake. a.wide.variety.of.analytical.work.for.scientific.institutions.and.industry..The.labGEOTOP.offer.elemental.and.isotopic.analysis.of.solids.and.liquids.covering.the.range.of.elements.determined.by.high.resolution-inductively.coupled.plasma-mass.spectrometry.

The service focuses on the analytical needs of R&D projects on:

•..Compositional.structure.and.evolution.of.Earth’s.mantle:.mantle.geochemistry.mainly.through.the.open.window.of.the.volcanic.rocks;.origin.of.mantle.plumes.

•..Compositional.structure.and.evolution.of.the.lithosphere:.geochemical.processes.at.the.margins.of.tectonic.plates.

•..Geochemical.evolution.of.magmatic.and.metamorphic.processes.

•..Sedimentary. geology. and. paleoclimate.reconstruction:.geochronology.and.processes.related.to.climate.change.

•..Volcanism:. temporal.evolution.of.pre-.and.syn-eruptive.magmatic.processes:.geochemical. flows. related. to. volcanic.activity.

•..Experimental.petrology.and.mineralogy.

The. analytical. services. provided. by. the.labGEOTOP.go.beyond.ICTJA.needs.and.represent.a.significant.breakthrough.in.the.analytical.services.required.by.the.Spanish.and. international. scientific. community.on. element. and. isotope. geochemistry.for. process. modelling. in. both. whole.rock. and. high. resolution. single. mineral.analysis..The.labGEOTOP.is.a.Project.co-financed. by. ERDF. through. the. Scientific.and.Technological.Infrastructure.National.Program.in.the.National.Plan.for.Scientific.Research,.Development.and.Technological.Innovation.(R&D).of.the.Ministry.of.Science.and.Innovation.(CSIC08-4E-001).

Service units and Labs

Staff

José-Luis Fernandez-Turiel, Scientific DirectorMarta Rejas, Technical DirectorJonathan Cotano, CSIC-contract

ANNUAL REPORT ICTJA 2013 13

Service units and Labs

X- Ray Diffraction Service

The. X-ray. Diffraction. Service. of. ICTJA-CSIC.is.an.analytical.facility.focused.on.the.qualitative.and.quantitative.characterization.of.the.crystalline.phases.of.materials..The.XRD.Service,.with.more.than.30.years.of.experience. in. the.field,.offers.support. to.ICTJA. researchers. and. also. to. external.users.from.public.and.private.universities.and.companies.

One. of. the. main. objectives. of. the. XRD.Service. at. ICTJA. is. to. support. the.ongoing. investigations. carried. out. by.ICTJA. researchers. on. Earth. Sciences.topics,. including. studies. of. volcanology,.petrology. and. sedimentology.. The. XRD.Service. offers. also. support. to. external.researchers.working.in.geology,.materials.science,.environment,.chemistry,.pharmacy,.archaeology,. etc.. A. large. number. of.companies. and. organizations. from. the.

14 ANNUAL REPORT ICTJA 2013

Service units and Labs

public.or.private.sectors.make.use.of.the.XRD.Service.at. ICTJA.for.their. industrial.applications,.quality.control,.environmental.studies,.forensics,.etc.

Range of services offered:

•.Identification.of.crystalline.phases

•.Crystal-quality.assessment,.composition.determination.and.microstructural.analyses

•..Semi-quantitative.and.quantitative.analysis.of. crystalline. phases. and. amorphous.content

•.Application.of.the.Rietveld.method.for.profile.adjustment,.structure.refinement.and.quantitative.phase.analyses

•.Investigation.of.small.or.inhomogeneous.samples.with.micro-diffraction

Staff

Jordi Ibañez, Scientific DirectorJosep Elvira, Technical DirectorMaría Soledad Alvarez, Technical Staff

•.Determination.of.crystalline.structures

•.Non-destructive. X-ray. fluorescence.analyses. with. a. handheld. spectrometer.for.field.work.and.cultural.heritage.studies

Some examples of applications provided by the laboratory to research groups and companies:

•.Phase.identification.and.quantification.of.geological.samples..Identification.and.analysis.of.clay.minerals

•.Analysis.of.mineral.phases.in.building.materials:.cement,.concrete,.aggregates,.etc..Study.of.degraded.calcium.aluminate.cements,.identification.of.fiber.cements,.etc.

•.Determination.of.the.amorphous.content.in.ashes.and.synthetic.mixtures

•.Study.of.corrosion.products

•.Determination. of. crystalline. silica. in.respirable.airborne.dusts.by.direct-on-filter.methods

ANNUAL REPORT ICTJA 2013 15

Paleomagnetism Service (CSIC-UB)

The.Paleomagnetic.Laboratory.was.founded.in.1989.as.result.of.an.agreement.between.the. CSIC. and. the. Catalonian. Geological.Service. of. the. Generalitat. de. Catalunya..Since.1998,.the.laboratory.depends.on.the.CCiT-University.of.Barcelona.and.the.CSIC.

The.laboratory.provides.technical.support.to.research.groups.working.on.several.research.topics. within. the. Earth. Sciences,. among.them:

•.Magnetostratigraphic.dating.of.sedimentary.sequences.and.correlation.with.their.fossil.and.paleoenvironmental.record.

•.Archaeomagnetic.dating.of.archaeological.remains.

•.Paleomagnetism.applied.to.the.study.of.orogenic.belts.and.plate.tectonics.

•.Environmental.magnetic.studies.aimed.to.unravelling.paleoenvironmental.and.climatic. variations. in. the. sedimentary.record.

Staff

Elisabet Beamud, Technical Director (UB)Ana Gómez, Technical StaffYlenia Almar, CSIC-Contract

Service units and Labs

16 ANNUAL REPORT ICTJA 2013

Research Laboratories

Seismic Laboratory

ICTJA.Seismic.Facility.is.composed.by.two.main.sections,.the.Data.Acquisition.Instrumentation.Pool.and.the.Seismic.Processing.Center.

The.Data.Acquisition.Instrumentation.Pool.includes.seismic.equipment.intended.to.be.used. in. temporary. deployments.. Broad-band.and.short.period.seismic.acquisition.systems.are.available.to.allow.managing.both.short-term.active.seismic.profiling.and.long-term. passive. seismic. deployments..The. Seismic. Processing. Center. includes.up. to. 10. Linux. work. stations. with.dedicated.processing.software.as.well.as.computational.libraries.Seismic.processing.software.as.well.as.computational.libraries.is.equipped.with.three.main.servers.and.up.to.18.Tbytes.of.disk.space..The.lab.also.

features. connectivity. with. the. Barcelona.Supercomputing. Center. that. hosts. one.of. the. largest. computers. in. Europe. the.Marenostrum.. Furthermore,. the. lab. also.has. research. relationships. with. other.computation,.processing,.interpretation.and.modelling.facilities.such.as.GEO¬MODELS.(University.of.Barcelona).and.the.Barcelona.Center.for.Subsurface.Imaging.

Service units and Labs

Staff

Josep Gallart, Scientific DirectorMario Ruíz, Technical Staff

ANNUAL REPORT ICTJA 2013 17

Raman Spectroscopy and Photoluminiscence Laboratory

The.Laboratory.of.Raman.Spectrocopy.and.Photoluminescence.is.focused.on.the.study.of.the.optical.properties.of.semiconductor.materials..Among.others,. the. lab.carries.out.Raman.scattering.studies.on.a.variety.

Staff

Lluís Artús, Scientific DirectorRamon Cuscó, Research ScientistJordi Ibañez, Research Scientist

of.III-V.compound.systems.such.as.GaN,.InN,. InGaN,. InAs/GaAs,. InGaAs,. InP,.AlGaSb,. InAsSb,. GaSb,. GaAsN,. as. well.as.on.ZnO,.a.II-VI.wide.band.gap.material.which. is. intensively. being. investigated.because. of. its. potential. applications. in.transparent. electronics. and. in. blue. and.UV.light.emitters.

Service units and Labs

18 ANNUAL REPORT ICTJA 2013

Service units and Labs

LARX – Laboratory of X-ray Analytical Applications

The.LARX.research.laboratory,.created.in.1994,.is.an.excellence’s.research.facility.of.ICTJA..The.activities.of.LARX.are.focused.on. the. development. of. methodologies.for.the.study.of.solid.matter.using.X-ray.spectroscopies.such.as.X-ray.fluorescence.(WDXRF,. EDXRF,. TRXRF. and. micro-EDXRF),.X-ray.diffraction.(XRD).and.other.solid-state. non-invasive. analytical. tools..Likewise,.LARX.staff.is.leading.collaborative.research.projects.related.to.Environmental.Geosciences.and.Geochemistry.

Since.its.creation,.the.laboratory.has.also.undertaken. many. teaching. and. training.activities.at.national.and.international.level,.in.collaboration.with.the.European.X-ray.Spectrometry. Association. (EXSA),. the.International.Atomic.Energy.Agency.(IAEA).and.X-ray.instrumentation.manufacturing.

companies..During.last.decade,.and.within.this.initiative.have.taken.several.doctoral.and.master.thesis.in.the.fields.of.environmental.pollution.and.cultural.heritage.materials.

At.now,.LARX.is.a.joint.associated.laboratory.with.the.Analytical.Chemistry.Department.of.the.University.of.Girona.(Spain).and.the.Hydrogeochemistry.Group.of.the.Institute.of.Environmental.Assessment.and.Water.Research.(IDAEA-CSIC).

The.instrumentation.of.this.infrastructure.allows. the. determination. of. major,. trace.and.ultratrace.elements.in.solids.(minerals,.rocks,.particulate.matter,.filters,.industrial.wastes,.etc.),.including.chemical.mapping.and.microprobe.analysis,. layer.thickness.determination. at. nanometre. scale. and.chemical.speciation.

Through.research.collaborative.agreements.the.laboratory.provides.technical.support.for.research.groups.working.on:

•.Cultural.Heritage.materials.and.artworks,.especially. studies. of. paint. pigments,.old. coinage. and. metallic. artefacts,.manuscripts.and.wall.paint.materials.

•.Environmental. geochemistry. of. soil,.water.and.vegetation,.including.biogeo-chemical.modelling.

•.Forensic.research.related.to.the.use.of.inorganic.chemistry.data.

Staff

Ignasi Queralt, Scientific Director

ANNUAL REPORT ICTJA 2013 19

Plomo Arsénico

20 ANNUAL REPORT ICTJA 2013

U-Th Geochronology Laboratory

The.Laboratory.of.Geochronology.was.founded.in.1989.and.fully.updated.in.2010.with.the.acquisition.of.two.8-channel.ORTEC.alpha.spectrometers..The.laboratory.is.specially.designed.for.dating.marine.and.continental.carbonates.such.as.travertines,.speleothems,.endogenic. lacustrine. carbonates,. corals.and.marine.crusts,.although.it.is.possible.to.date.primary.sulphates.(gypsum).and.chlorides.(halite).using.the.uranium.series.desequilibrium.method.(230Th/234U).

Service units and Labs

Staff

Santiago Giralt, Scientific DirectorGraciela Monzon, Technical Director

The.laboratory.provides.technical.support.for.research.groups.working.on:

•. Absolute. dating. of. upper. Pleistocene.and. Holocene. continental. and. marine.carbonate. samples. for. a. large. variety.of.purposes.such.as.climate,.anthropic,.geologic. and/or. environmental.reconstructions.

•. Absolute. dating. of. human. and. other.archaeological.carbonate.prehistorical.rests.

ANNUAL REPORT ICTJA 2013 21

Scientific Boreholes (Almera-1 & 2)

Two.scientific.boreholes.were.drilled.in.2012.in.the.UB.campus.of.Barcelona.as.part.of.the.subsurface.research.studies.of.the.Institute.of.Earth.Sciences.Jaume.Almera.(ICTJA).in.cooperation.with.the.Faculty.of.Geology.of.the.University.of.Barcelona.(UB).

The.Almera-1.borehole.is.214.20.m.deep.and. is. used. as. an. experimental. facility.for.the.development.of.geophysical.data.logging.methods..The.hole.Almera-2.is.1.m.away.from.Almera-1,.reaching.a.depth.of.46.m,.and.is.meant.to.carry.out.routine.piezometric.measurements.and.cross.hole.experiments.

A. subsurface. connection. for. cables. and.tools. with. the. borehole. and. monitoring.research.lab.inside.ICTJA.building.facilitate.long.term.and.continuous.monitoring.and.control.from.the.lab..This.facility.is.equipped.with. a. complete. system. of. geophysical.logging.tools.and.borehole.monitoring.data.loggers. that. are. used. for. testing. of. new.devices.and.experiments. in.the.frame.of.ongoing.research.projects.

Service units and Labs

Staff

M. José Jurado, Scientific Director José Crespo, CSIC-JAE TechnicianCarlos Viñolo, CSIC-contractFrancesc Castelltort, CSIC-contract

22 ANNUAL REPORT ICTJA 2013

SIMGEO (UB-CSIC)

The. Laboratory. of. Geological. Processes.Simulation.(SIMGEO).was.created.in.1995.as.a.joint.venture.between.the.Faculty.of.Geology.of.the.University.of.Barcelona.(UB).and.the.Institute.of.Earth.Sciences.Jaume.Almera.(ICTJA).in.the.field.of.experimental.and. theoretical. modelling. of. geological.processes.

SIMGEO. seeks. to. promote. application.of. experimental. and. theoretical. models.to.the.study.of.geological.processes.and,.

Service units and Labs

Staff

Joan Martí, Scientific co-Director (CSIC)Ferran Colombo, Scientific co-Director (UB)

in.particular,.processes.that.involve.a.risk.to. people. and. the. environment,. through.funding.raised.by.public.and.private.research.projects.and.contracts.and.agreements.

SIMGEO.offers.researchers.a.large.space.and. equipment. to. design. and. develop.experimental.models..The.SIMGEO.has.a.laboratory.of.experimental.petrology.and.mineral.synthesis,.a.hydraulic.channel.16.m. length. and. a. computer. lab. equipped.with. the. necessary. software. to. develop.mathematical.models.and.simulations.using.geographic.information.systems.

ANNUAL REPORT ICTJA 2013 23

Service units and Labs

24 ANNUAL REPORT ICTJA 2013

Personnel

INEM Contract 1

Researchers Permanent Staff 27

Administration Permanent Staff 6

Services Permanent Staff 5

Technicians Permanent Staff 6

INEM Contract - 1Researchers Permanent Staff - 27Administration Permanent Staff - 6Services Permanent Staff - 5Technicians Permanent Staff - 6Post-doc Researchers - 13PhD Researchers - 16IGME Visiting Scientists - 2Contracted Technicians - 17

1

27

6

5

613

16

2

17

INEM Contract - 1Researchers Permanent Staff - 27Administration Permanent Staff - 6Services Permanent Staff - 5Technicians Permanent Staff - 6Post-doc Researchers - 13PhD Researchers - 16IGME Visiting Scientists - 2Contracted Technicians - 17

1

27

6

5

613

16

2

17

Post-doc Researchers 13

PhD Researchers 16

IGME Visiting Scientists 2

Contracted Technicians 17

INEM Contract - 1Researchers Permanent Staff - 27Administration Permanent Staff - 6Services Permanent Staff - 5Technicians Permanent Staff - 6Post-doc Researchers - 13PhD Researchers - 16IGME Visiting Scientists - 2Contracted Technicians - 17

1

27

6

5

613

16

2

17

TOTAL 93

ANNUAL REPORT ICTJA 2013 25

How to reach us

The. Institute. of. Earth. Sciences. Jaume.Almera.(ICTJA).is.located.at.the.Pedralbes.Campus.of.the.University.of.Barcelona.

Lluís Solé i Sabaris s/n08028 Barcelona (Spain)Phone: +34 934095410Fax: +34 934110012

Carrer Pau Gargallo

Carrer Menéndez y Pelayo

Carrer Martí i Franquès

Av. Diagonal

Carrer Solé i Sabaris

Campus UB

Facultat de Química

Facultat de Biologia

Facultat de Geologia

PALAU REIAL

645

643L97-101

7-33-67-75-L14-L79-L97

7-33-67-75-113L14-L79-H6

L3

L3

ICTJA

26 ANNUAL REPORT ICTJA 2013

ICTJA Research Groups

• Earth’s structure and dynamics• Crystallography and Optical properties• Environmental Changes in the Geological Record• Geophysical and Geochemical Modelling of Geohazards

Processes and Subsurface Resources

ANNUAL REPORT ICTJA 2013 27

Group members

Earth’s structure and dynamics

Andrés Perez-Estaún, Research ProfessorManel Fernández, Research ProfessorRamón Carbonell, Research ProfessorDennis Brown, Senior Research ScientistJaume Vergés, Senior Research ScientistJoaquina Alvarez-Marrón, Senior Research ScientistJordi Díaz, Senior Research ScientistMontserrat Torne, Senior Research ScientistAntonio Villaseñor, Research ScientistDaniel García-Castellanos, Research ScientistIvonne Jiménez, Research ScientistMartin Schimmel, Research ScientistContxi Ayala, IGME Visiting Research ScientistEduard Saura, CSIC-JAE post-docAlexandra Robert, CSIC contract post-docArantzazu Ugalde, CSIC contract post-docCharlotte Fillon, CSIC contract post-doc

David Martí, CSIC contract post-docEmilio Casciello, CSIC contract post-docIgnacio Marzan, CSIC contract post-docJuan Diego Martin, CSIC contract post-docJan Globig, Marie Curie pre-docSiddique Akhtar, Marie Curie pre-docAlba Gil, FPI pre-docLavinia Tunini, FPI pre-docAlberto Carballo, JAE pre-docGiovanni Cammani, JAE pre-docBeatriz Gaite, CSIC contractDaniel Vázquez, CSIC contractIsrael Cruz, CSIC contractMar Moragas, CSIC contractMarcel Cembrowski, CSIC contractSofia Casquero, CSIC contractVinyet Baqués, CSIC contract

ICTJA Research Groups

Josep Gallart,.Group Leader - Research Professor

28 ANNUAL REPORT ICTJA 2013

Research outline

The.multidisciplinary.research.investigates.the. structure. and. dynamic. processes. of.the. Earth’s. interior.. The. main. objective.is.to.understand.how.the.Earth.works.at.different. scales. through. the. integration.of.a.wide.range.of.different.datasets.and.methodologies,.including.Geophysics.and.Geology,. Numerical. Modeling,. Geodesy,.and.Geochemistry.

ICTJA Research Groups

The.acquisition.of.high.resolution.seismic,.potential. field. data. and. surface. geology.is. combined. with. numerical. models. to.achieve.an.integrate.approach.to.basic.and.applied.research.in.Earth.Sciences..Related.projects.to.industry.include.applications.for.hydrocarbon. exploration,. waste. disposal.and.geological.storage.of.greenhouse.gas.emissions.(CO

2).

ANNUAL REPORT ICTJA 2013 29

é

Publications 2013

Alcalde, J.,.D. Martí,.A. Calahorrano,.I. Marzan,.P. Ayarza,.R. Carbonell,.C. Juhlin,.and.A. Pérez-Estaún.(2013),.Active.seismic.characterization.experiments.of.the.Hontomín.research.facility.for.geological.storage.of.CO2,.Spain,.International.Journal.of.Greenhouse.Gas.Control,.19,.785-795,.doi:.10.1016/j.ijggc.2013.01.039.

Aucelli, P. P. C.,.E. Casciello,.M. Cesarano,.S. Perriello Zampelli,.and.C. M. Rosskopf.(2013),.A.deep,.stratigraphically.and.structurally.controlled.landslide:.The.case.of.Mount.La.Civita.(Molise,.Italy),.Landslides,.10(5),.645-656,.doi:.10.1007/s10346-012-0351-7.

Bécel, A.,.J. Diaz,.M. Laigle,.and.A. Hirn.(2013),.Searching.for.unconventional.seismic.signals.on.a.subduction.zone.with.a.submerged.forearc:.OBS.offshore.the.Lesser.Antilles,.Tectonophysics,.603,.21-31,.doi:.10.1016/j.tecto.2012.10.031.

Bezada, M. J.,.E. D. Humphreys,.D. R. Toomey,.M. Harnafi,.J. M. Dávila,.and.J. Gallart.(2013),.Evidence.for.slab.rollback.in.westernmost.Mediterranean.from.improved.upper.mantle.imaging,.Earth.and.Planetary.Science.Letters,.368,.51-60,.doi:.10.1016/j.epsl.2013.02.024.

Bonatto, L.,.M. Schimmel,.J. Gallart,.and.J. Morales.(2013),.Studying.the.410-km.and.660-km.discontinuities.beneath.spain.and.morocco.through.detection.of.p-to-s.conversions,.Geophysical.Journal.International,.194(2),.920-935,.doi:.10.1093/gji/ggt129.

Calvet, M.,.M. Sylvander,.L. Margerin,.and.A. Villaseñor.(2013),.Spatial.variations.of.seismic.attenuation.and.heterogeneity.in.the.Pyrenees:.Coda.Q.and.peak.delay.time.analysis,.Tectonophysics,.608,.428-439,.doi:.10.1016/j.tecto.2013.08.045.

Carbonell, R.,.A. Levander,.and.R. Kind.(2013),.The.Mohorovicic.discontinuity.beneath.the.continental.crust:.An.overview.of.seismic.constraints,.Tectonophysics,.609,.353-376,.doi:.10.1016/j.tecto.2013.08.037.

Casciello, E.,.P. Esestime,.M. Cesarano,.G. Pappone,.M. Snidero,.and.J..Vergés.(2013),.Lower.plate.geometry.controlling.the.development.of.a.thrust-top.basin:.The.tectonosedimentary.evolution.of.the.ofanto.basin.(Southern.Apennines),.Journal.of.the.Geological.Society,.170(1),.147-158,.doi:.10.1144/jgs2011-066.

Díaz, J.,.A. Gil,.and.J. Gallart.(2013),.Uppermost.mantle.seismic.velocity.and.anisotropy.in.the.euro-mediterranean.region.from.pn.and.sn.tomography,.Geophysical.Journal.International,.192(1),.310-325,.doi:.10.1093/gji/ggs016.

Escuder-Viruete, J.,.and.A. Pérez-Estaún.(2013),.Contrasting.exhumation.P-T.paths.followed.by. high-P. rocks. in. the. northern. Caribbean. subduction-accretionary. complex:. Insights.from.the.structural.geology,.microtextures.and.equilibrium.assemblage.diagrams,.Lithos,.160-161(1),.117-144,.doi:.10.1016/j.lithos.2012.11.028.

Escuder-Viruete, J.,.P. Valverde-Vaquero,.Y. Rojas-Agramonte,.J. Jabites,.and.A. Pérez-Estaún.(2013),.From.intra-oceanic.subduction.to.arc.accretion.and.arc-continent.collision:.

ICTJA Research Groups

30 ANNUAL REPORT ICTJA 2013

Insights.from.the.structural.evolution.of.the.Río.San.Juan.metamorphic.complex,.northern.Hispaniola,.Journal.of.Structural.Geology,.46,.34-56,.doi:.10.1016/j.jsg.2012.10.008.

Escuder-Viruete, J.,.P. Valverde-Vaquero,.Y. Rojas-Agramonte,.J. Gabites,.M. Castillo-Carrión,.and.A. Pérez-Estaún.(2013),.Timing.of.deformational.events.in.the.Río.San.Juan.complex:.Implications.for.the.tectonic.controls.on.the.exhumation.of.high-P.rocks.in.the.northern.Caribbean.subduction-accretionary.prism,.Lithos,.177,.416-435,.doi:.10.1016/j.lithos.2013.07.006.

Evain, M.,. A. Galve,. P. Charvis,. M. Laigle,. H. Kopp,. A. Bécel,. W. Weinzierl,. A. Hirn,.E. R. Flueh,.and.J. Gallart.(2013),.Structure.of.the.Lesser.Antilles.subduction.forearc.and.backstop.from.3D.seismic.refraction.tomography,.Tectonophysics,.603,.55-67,.doi:.10.1016/j.tecto.2011.09.021.

Fichtner, A.,.J. Trampert,.P. Cupillard,.E. Saygin,.T. Taymaz,.Y. Capdeville,.and.A. Villaseñor.(2013),.Multiscale.full.waveform.inversion,.Geophysical.Journal.International,.194(1),.534-556,.doi:.10.1093/gji/ggt118.

Grobe, R. W.,.J. Alvarez-Marrón,.U. A. Glasmacher,.and.F. M. Stuart.(2013),.Mesozoic.exhumation.history.and.palaeolandscape.of.the.Iberian.Massif. in.eastern.Galicia.from.apatite.fission-track.and.(U+Th)/He.data,.International.Journal.of.Earth.Sciences,.1-23,.doi:.10.1007/s00531-013-0976-3.

Gualtieri, L., E. Stutzmann,.Y. Capdeville,.F. Ardhuin,.M. Schimmel,.A. Mangeney,.and.A. Morelli.(2013),.Modelling.secondary.microseismic.noise.by.normal.mode.summation,.Geophysical.Journal.International,.193(3),.1732-1745,.doi:.10.1093/gji/ggt090.

Laigle, M.,.et.al..(2013),.Seismic.structure.and.activity.of.the.north-central.Lesser.Antilles.subduction. zone. from. an. integrated. approach:. Similarities. with. the. Tohoku. forearc,.Tectonophysics,.603,.1-20,.doi:.10.1016/j.tecto.2013.05.043.

Martín-Martín, J. D.,.et.al..(2013),.The.Upper.Aptian.to.Lower.Albian.syn-rift.carbonate.succession.of.the.southern.Maestrat.Basin.(Spain):.Facies.architecture.and.fault-controlled.stratabound.dolostones,.Cretaceous.Research,.41,.217-236,.doi:.10.1016/j.cretres.2012.12.008.

Messager, G.,.B. Nivière,.P. Lacan,.Y. Hervouët,.and.J. P. Xavier.(2013),.Plio-Quaternary.thin-skinned.tectonics.along.the.crustal.front.flexure.of.the.southern.Central.Andes:.a.record.of.the.regional.stress.regime.or.of.local.tectonic-driven.gravitational.processes?,.International.Journal.of.Earth.Sciences,.1-23,.doi:.10.1007/s00531-013-0983-4.

Moragas, M.,.C. Martínez,.V. Baqués,.E. Playà,.A. Travé,.G. Alías,.and.I. Cantarero.(2013),.Diagenetic.evolution.of.a.fractured.evaporite.deposit.(Vilobí.Gypsum.Unit,.Miocene,.NE.Spain),.Geofluids,.13(2),.180-193,.doi:.10.1111/gfl.12017.

Nivière, B.,.G. Messager,.S. Carretier,.and.P. Lacan.(2013),.Geomorphic.expression.of.the.southern.Central.Andes.forebulge.(37°S,.Argentina),.Terra.Nova,.25(5),.361-367,.doi:.10.1111/ter.12044.

ICTJA Research Groups

ANNUAL REPORT ICTJA 2013 31

ICTJA Research Groups

Obrebski, M.,.F. Ardhuin,.E. Stutzmann,.and.M. Schimmel.(2013),.Detection.of.microseismic.compressional.(P).body.waves.aided.by.numerical.modeling.of.oceanic.noise.sources,.Journal.of.Geophysical.Research.B:.Solid.Earth,.118(8),.4312-4324,.doi:.10.1002/jgrb.50233.

Replumaz, A.,.S. Guillot,.A. Villaseñor,.and.A. M. Negredo.(2013),.Amount.of.Asian.lithospheric.mantle.subducted.during.the.India/Asia.collision,.Gondwana.Research,.24(3-4),.936-945,.doi:.10.1016/j.gr.2012.07.019.

Ruiz, M.,.et.al..(2013),.Seismic.activity.offshore.Martinique.and.Dominica.islands.(Central.Lesser.Antilles.subduction.zone).from.temporary.onshore.and.offshore.seismic.networks,.Tectonophysics,.603,.68-78,.doi:.10.1016/j.tecto.2011.08.006.

Rushlow, C. R.,.J. B. Barnes,.T. A. Ehlers,.and.J. Vergés.(2013),.Exhumation.of.the.southern.Pyrenean.fold-thrust.belt.(Spain).from.orogenic.growth.to.decay,.Tectonics,.32(4),.843-860,.doi:.10.1002/tect.20030.

Saura, E.,.J. C. Embry,.J. Vergés,.D. W. Hunt,.E. Casciello,.and.S. Homke.(2013),.Growth.fold.controls.on.carbonate.distribution.in.mixed.foreland.basins:.Insights.from.the.Amiran.foreland.basin.(NW.Zagros,.Iran).and.stratigraphic.numerical.modelling,.Basin.Research,.25(2),.149-171,.doi:.10.1111/j.1365-2117.2012.00552.x.

Sergeant A., Stutzmann E., Maggi A., Schimmel M., Ardhuin F., Obrebski M., Frequency-dependent. noise. sources. in. the. North. Atlantic. Ocean,. Geochemestry,. Geophysics,.Geosystems,.14,.doi:10.1002/2013GC004905,.2013.

Silveira, G.,.N. Afonso Dias,.and.A. Villaseñor.(2013),..Seismic.imaging.of.the.western.Iberian.crust.using.ambient.noise:.Boundaries.and.internal.structure.of.the.Iberian.Massif,.Tectonophysics,.589,.186-194,.doi:.10.1016/j.tecto.2012.12.025.

Simancas, J. F.,.P. Ayarza,.A. Azor,.R. Carbonell,.D. Martínez Poyatos,.A. Pérez-Estaún,.and.F. González Lodeiro. (2013),.A.seismic.geotraverse.across.the. Iberian.Variscides:.Orogenic.shortening,.collisional.magmatism,.and.orocline.development,.Tectonics,.32(3),.417-432,.doi:.10.1002/tect.20035.

Ugalde, A..(2013),.S-wave.envelope.broadening.characteristics.of.microearthquakes.in.the.Canary.Islands,.Journal.of.Seismology,.17(2),.771-782,.doi:.10.1007/s10950-012-9353-0.

Ugalde, A.,.A. Villaseñor,.B. Gaite,.S. Casquero,.D. Martí,.A. Calahorrano,.I. Marzán,.R. Carbonell,.and.A. P. Estaún.(2013),.Passive.seismic.monitoring.of.an.experimental.CO2.geological.storage.site. in.Hontomín.(Northern.Spain),.Seismological.Research.Letters,.84(1),.75-84,.doi:.10.1785/0220110137.

Valera, J. L.,.A. M. Negredo,.M. I. Billen,.and.I. Jiménez-Munt.(2013),.Lateral.migration.of.a.foundering.high-density.root:.Insights.from.numerical.modeling.applied.to.the.southern.Sierra.Nevada,.Lithos,.doi:.10.1016/j.lithos.2013.08.021.

Zlotnik, S.,. I. Jiménez-Munt,.and.M. Fernàndez. (2013),.Coupled.mantle.dripping.and.lateral.dragging.controlling.the.lithosphere.structure.of.the.NW-Moroccan.margin.and.the.Atlas.Mountains:.A.numerical.experiment,.Lithos,.doi:.10.1016/j.lithos.2013.10.016.

32 ANNUAL REPORT ICTJA 2013

ICTJA Research Groups

National Funding Agencies

Project Title: ALCUDIA WA–Propiedades físicas de la litosfera en la Zona Centro Ibérica (Península Ibérica)Financed by: PNIDI-CGL.-.CGL2010-17280Years:.2011-2013PI:.R..Carbonell

Project Title: ATIZA – Caracterización del manto litosferico debajo de la cadena orogénica alpina a partir de métodos numéricosFinanced by: PNIDI-CGL.-.CGL2009-09662Years:.2010-2013PI:.I..Jimenez.Munt

Project Title: PROTAI – Procesos de colisión Arco-Continente en TaiwanFinanced by: PNIDI-CGL.-.CGL2009-11843Years:.2010-2013PI:.D..Brown

Research projects 2013

Project Title: RIFSIS – Estructura sísmica de la corteza bajo la cordillera del RifFinanced by: PNIDI-CGL.-.CGL2009-09727Years:.2010-2013PI:.J..Gallart

Project Title: TECLA – Interacción entre la tectónica y el clima árido de sistemas orogeno-CuencaFinanced by: PNIDI-CGL.-.CGL2011-26670Years:.2012-2014PI:.D..García-Castellanos

Project Title: TOPOIBERIA – Geociencias en Iberia: estudios integrados de topografía y evolución 4DFinanced by: PNIDI-CONSOLIDER.-.CSD2006-00041Years:.2006-2013PI:.J..Gallart

ANNUAL REPORT ICTJA 2013 33

ICTJA Research Groups

International Funding Agencies

Project Title: EPOS – European Plate Observing SystemFinanced by: European.Unión.-.7PM-PP.26229Years:.2010-2014PI: J..Gallart

Project Title: NERA – Network of European Research Insfrastructures for Eartquake Risk Assessment and MigrationFinanced by: European.Unión.-.7PM-PP.262330Years:.2010-2014PI: J..Gallart

Project Title: TOPOMOD-Sculpting the Earth’s topography: Insights from modelling deep-surface processesFinanced by: European.Unión.-.7PM-.RTN.264157Years:.2011-2014PI: M..Fernandez

Project Title: Performance of the conversion to digital form of the phase arrival times for all earthquakes includes in the bulletins of the international seismological summaryFinanced by: International.Seismological.CenterYears:.2013-2014PI: A..Villaseñor

Industry

Project Title: Integrated structural and geodynamics geological research studiesFinanced by: STATOIL-HYDRO.PETROLEUM.ASAYears:.2008-2013PI: J..Vergés

Project Title: Seguimiento geofísico del confinamiento geológico de CO2

Financed by: REPSOL.YPF,.S.A.Years:.2010-2013PI: A..Villaseñor

Project Title: Identificación y validación de métodos geofísicos para la detección y caracterización de discontinuidades en medios sedimentarios recientes.Financed by: ENRESAYears:.2013-2015PI: A..Pérez-Estaún

34 ANNUAL REPORT ICTJA 2013

Research outline

This.line.of.research.is.focused.on.the.study.of.the.optical.properties.of.semiconductor.materials..Over.the.past.few.years.we.have.carried. out. Raman. scattering. studies. on.a.variety.of.III-V.compound.systems.such.as.GaN,.InN,.InGaN,.InAs/GaAs,.InGaAs,.InP,.AlGaSb,.InAsSb,.GaSb,.GaAsN,.as.well.as.on.ZnO,.a.II-VI.wide.band.gap.material.which. is. intensively. being. investigated.because. of. its. potential. applications. in.transparent. electronics. and. in. blue. and.UV.light.emitters.

Group members

Lluis Artús,.Group Leader – Senior Research Scientist

Ramon Cuscó,.Research ScientistJordi Ibañez,.Research ScientistNuria Domènech,.FPU pre-docRobert Oliva,.FPI pre-doc

Crystallography and Optical properties

ICTJA Research Groups

ANNUAL REPORT ICTJA 2013 35

National Funding Agencies

Project Title: OPTOFOT Propiedades ópticas de materiales opto electrónicos y fotovoltaicosFinanced by: PNIDI-MAT:.MT2010-16116Years:.2011-2014PI:.Ll..Artús

Publications 2013

Ibáñez Insa, J..(2013),.Reformulating.table.salt.under.pressure,.Science,.342(6165),.1459-1460,.doi:.10.1126/science.1247699.

Ibáñez, J.,.O. Font,.N. Moreno,.J. J. Elvira,.S. Alvarez,.and.X. Querol.(2013),.Quantitative.Rietveld.analysis.of.the.crystalline.and.amorphous.phases.in.coal.fly.ashes,.Fuel,.105,.314-317,.doi:.10.1016/j.fuel.2012.06.090.

Ibáñez, J.,.R. Oliva,.F. J. Manjón,.A. Segura,.T. Yamaguchi,.Y. Nanishi,.R. Cuscó,.and.L. Artús. (2013),. High-pressure. lattice. dynamics. in. wurtzite. and. rocksalt. indium. nitride.investigated.by.means.of.Raman.spectroscopy,.Physical.Review.B.-.Condensed.Matter.and.Materials.Physics,.88(11),.doi:.10.1103/PhysRevB.88.115202.

Oliva, R.,.J. Ibáñez,.L. Artús,.R. Cuscó,.J. Zúñiga-Pérez,.and.V. Muñoz-Sanjosé.(2013),.High-pressure.Raman.scattering.of.CdO.thin.films.grown.by.metal-organic.vapor.phase.epitaxy,.Journal.of.Applied.Physics,.113(5),.doi:.10.1063/1.4790383.

Rioboo, R. J. J.,.C. Prieto,.R. Cuscó,.L. Artús,.C. Boney,.A. Bensaoula,.T. Yamaguchi,.and.Y. Nanishi.(2013),.Temperature.dependence.of.surface.acoustic.wave.propagation.velocity.in. InxGa1-xN. films. obtained. by. high-resolution. brillouin. spectroscopy:. Determination.of. temperature. coefficient. of. frequency,. Applied. Physics. Express,. 6(5),. doi:. 10.7567/APEX.6.056601.

Torréns-Martín, D.,.L. Fernández-Carrasco,.S. Martínez-Ramírez,.J. Ibáñez,.L. Artús,.and.T. Matschei.(2013),.Raman.spectroscopy.of.anhydrous.and.hydrated.calcium.aluminates.and.sulfoaluminates,.Journal.of.the.American.Ceramic.Society,.96(11),.3589-3595,.doi:.10.1111/jace.12535.

Research projects 2013

ICTJA Research Groups

36 ANNUAL REPORT ICTJA 2013

Environmental Changes in the Geological RecordGroup members

Research outline

Our. multidisciplinary. group. promotes.the. reconstruction.of.environmental.and.climate.changes,.their.causes,.and.dynamic.interactions. through. the. multiproxy.characterization. of. the. geologic. record..Throughout.the.history.of.our.planet,.the.geological.processes.in.general.and.climate.change. in. particular. have. fingerprinted.the.sedimentary.record..Furthermore,.the.increasing.anthropogenic.influence.in.the.recent. past. is. also. readily. identifiable. in.this.geological.record.

This.research.is.carried.out.using.a.multiproxy.approach.and.focuses.on.lake.sedimentology.and.global.change,.impact.of.geological.and.

anthropogenic. processes. on. the. natural.geochemical.balances,.sedimentary.processes.and.biomineralization,.geochronological.dating.and.physical.and.magnetic.properties.of.the.sediments.as. indicators.of.environmental.and.climatic.processes.

The.objective.of.the.research.group.is.the.robust.and.accurate.reconstruction.of.past.climate. oscillations. and. environmental.fluctuations.as.well.as.identify.short,.medium.and. long. term. trends. of. these. changes.through.the.multiproxy.characterization.of.the.geological.sedimentary.record..These.reconstructions.provide.valuable.data. to.put.into.a.broad.temporal.perspective.the.current.climate.and.environmental.trends.as.well.as.they.provide.useful.insights.about.which.has.been.the.historical.and.current.anthropogenic.role.in.the.recent.evolution.of.the.Earth..These.climatic.and.environmental.reconstructions. also. provide. data. that.allows.the.establishment.of.possible.future.climatic.and.environmental.scenarios.

To.achieve.this.goal.the.group.is.developing.the.following.research.lines:–. reconstruction. of. climatic. and.

environmental. changes. using. a. high.temporal.resolution.multiproxy.approach.of.lacustrine.sedimentary.re-cords;

–. determining.the.geochemical.impact.of.large-scale. geological. processes. (e.g.,.explosive.volcanic.eruptions.or.floods);

–. evaluating. the. relationships. between.processes.and.sedimentary.environments.and.biomineralization,.and.characterizing.physical.and.magnetic.properties.of.the.sedimentary.record.as.proxies.of.climatic.and.environmental.events.

ICTJA Research Groups

Ramón Julià,.Research Professor (Ad-honorem) Pere Anadón,.Senior Research ScientistAntonio Vazquez, Research ScientistRosa Utrilla, Research ScientistSantiago Giralt, Research ScientistAgustin Lobo, CSIC contract researcherJuan Cruz Larrasoaña, IGME Visiting Research ScientistMiriam Gómez-Paccard, CSIC JAE-doc and Visiting Marie-Curie post-docMaria Jesús Rubio,.FPI pre-docGuiomar Sánchez,.JAE pre-docAlejandro Rodríguez,.CSIC-contractMaria Dolores Jiménez,.CSIC-JAE Technician

José Luis Fernandez-Turiel,.Group Leader – Senior Research Scientist

ANNUAL REPORT ICTJA 2013 37

38 ANNUAL REPORT ICTJA 2013

Publications 2013

Anadón, P.,.C. Canet,.and.W. L. Friedrich.(2013),.Aragonite.stromatolitic.buildups.from.Santorini. (Aegean. Sea,. Greece):. Geochemical. and. palaeontological. constraints. of. the.caldera.palaeoenvironment.prior.to.the.Minoan.eruption.(ca.3600.yr.bp),.Sedimentology,.60(5),.1128-1155,.doi:.10.1111/sed.12025.

Barreiro-Lostres, F.,.A. Moreno,.S. Giralt,.and.B. L. Valero-Garcés.(2013),.Sedimentary.evolution.of.La.Parra.karstic.lake.(Cuenca).over.the.last.1600.years:.Paleohydrology,.climate,.and.human.impact,.Evolución.sedimentaria.del.lago.kárstico.de.La.Parra.(Cuenca).durante.los.últimos.1600.años:.Paleohidrología,.clima.e.impacto.humano,.39(1),.179-193.

Canet, C.,.P. Anadón,.P. Alfonso,.R. M. Prol-Ledesma,.R. E. Villanueva-Estrada,.and.M. García-Vallès.(2013),.Gas-seep.related.carbonate.and.barite.authigenic.mineralization.in.the.northern.Gulf.of.California,.Marine.and.Petroleum.Geology,.43,.147-165,.doi:.10.1016/j.marpetgeo.2013.02.011.

Cañellas-Boltà, N.,. V. Rull,. A. Sáez,. O. Margalef,. R. Bao,. S. Pla-Rabes,. M. Blaauw,.B. Valero-Garcés,.and.S. Giralt.(2013),.Vegetation.changes.and.human.settlement.of.Easter.Island.during.the.last.millennia:.A.multiproxy.study.of.the.Lake.Raraku.sediments,.Quaternary.Science.Reviews,.72,.36-48,.doi:.10.1016/j.quascirev.2013.04.004.

Cimarelli, C.,.F. Di Traglia,.D. de Rita,.D. Gimeno Torrente,.and.J. L. Fernandez Turiel.(2013),.Space-time.evolution.of.monogenetic.volcanism.in.the.mafic.Garrotxa.Volcanic.Field.(NE.Iberian.Peninsula),.Bulletin.of.Volcanology,.75(11),.1-18,.doi:.10.1007/s00445-013-0758-6.

Corella, J. P.,. V. Stefanova,. A. El Anjoumi,. E. Rico,. S. Giralt,. A. Moreno,. A. Plata-Montero,.and.B. L. Valero-Garcés.(2013),.A.2500-year.multi-proxy.reconstruction.of.climate.change.and.human.activities.in.northern.Spain:.The.Lake.Arreo.record,.Palaeogeography,.Palaeoclimatology,.Palaeoecology,.386,.555-568,.doi:.10.1016/j.palaeo.2013.06.022.

Costa, E.,.M. Garcés,.M. López-Blanco,.J. Serra-Kiel,.G. Bernaola,.L. Cabrera,.and.E. Beamud.(2013),.The.Bartonian-Priabonian.marine.record.of.the.eastern.south.Pyrenean.foreland.basin.(NE.Spain):.A.new.calibration.of.the.larger.foraminifers.and.calcareous.nannofossil.biozonation,.Geologica.Acta,.11(2),.177-193,.doi:.10.1344/105.000001779.

Daura, J.,.et.al..(2013),.Terrasses.de.la.Riera.dels.Canyars.(Gavà,.Barcelona):.The.landscape.of.Heinrich.Stadial.4.north.of.the.".Ebro.frontier".and.implications.for.modern.human.dispersal.into.Iberia,.Quaternary.Science.Reviews,.60,.26-48,.doi:.10.1016/j.quascirev.2012.10.042.

Gil, A.,.A. Lobo,.M. Abadi,.L. Silva,.and.H. Calado.(2013),.Mapping.invasive.woody.plants.in.Azores.Protected.Areas.by.using.very.high-resolution.multispectral.imagery,.European.Journal.of.Remote.Sensing,.46(1),.289-304,.doi:.10.5721/EuJRS20134616.

ICTJA Research Groups

ANNUAL REPORT ICTJA 2013 39

Gómez-Paccard, M.,. E. Beamud,. G. Mc Intosh,. and. J. C. Larrasoaña. (2013),. New.archaeomagnetic.data.recovered. from.the.study.of. three.roman.kilns. from.north-east.spain:.A.contribution.to.the.iberian.palaeosecular.variation.curve,.Archaeometry,.55(1),.159-177,.doi:.10.1111/j.1475-4754.2012.00675.x.

Gómez-Paccard, M.,.J. C. Larrasoaña,.C. Sancho,.A. Muñoz,.E. McDonald,.E. J. Rhodes,.M. C. Osácar,. E. Costa,. and. E. Beamud. (2013),. Environmental. response. of. a. fragile,.semiarid.landscape.(Bardenas.Reales.Natural.Park,.NE.Spain).to.Early.Holocene.climate.variability:. A. paleo-. and. environmental-magnetic. approach,. Catena,. 103,. 30-43,. doi:.10.1016/j.catena.2011.05.013.

Hernández, A.,.R. Bao,.S. Giralt,.A. Sáez,.M. J. Leng,.P. A. Barker,.C. P. Kendrick,.and.H. J. Sloane.(2013),.Climate,.catchment.runoff.and.limnological.drivers.of.carbon.and.oxygen.isotope. composition. of. diatom. frustules. from. the. central. andean. altiplano. during. the.Lateglacial.and.Early.Holocene,.Quaternary.Science.Reviews,.66,.64-73,.doi:.10.1016/j.quascirev.2012.10.013.

López-García, J. M.,.H. A. Blain,.R. Julià,.and.J. Maroto.(2013),.Environment.and.climate.during.MIS.7.and.their.implications.for.the.later.Middle.Pleistocene.hominins:.The.contribution.of.Mollet.cave,.Serinyà,.Girona,.northeastern.Spain,.Quaternary.International,.doi:.10.1016/j.quaint.2012.12.025.

Margalef, O.,.et.al..(2013),.A.70,000.year.multiproxy.record.of.climatic.and.environmental.change.from.Rano.Aroi.peatland.(Easter.Island),.Global.and.Planetary.Change,.108,.72-84,.doi:.10.1016/j.gloplacha.2013.05.016.

Muñoz, J. A.,.E. Beamud,.O. Fernández,.P. Arbués,.J. Dinarès-Turell,.and.J. Poblet.(2013),.The.Ainsa.Fold.and.thrust.oblique.zone.of.the.central.Pyrenees:.Kinematics.of.a.curved.contractional.system.from.paleomagnetic.and.structural.data,.Tectonics,.32(5),.1142-1175,.doi:.10.1002/tect.20070.

Nieto-Moreno, V.,.F. Martinez-Ruiz,.S. Giralt,.D. Gallego-Torres,.J. García-Orellana,.P. Masqué,.and.M. Ortega-Huertas.(2013),.Climate.imprints.during.the.'Medieval.Climate.Anomaly'.and.the.'Little.Ice.Age'.in.marine.records.from.the.Alboran.Sea.basin,.Holocene,.23(9),.1227-1237,.doi:.10.1177/0959683613484613.

Piñar, G.,.M. Garcia-Valles,.D. Gimeno-Torrente,.J. L. Fernandez-Turiel,.J. Ettenauer,.and.K. Sterflinger.(2013),.Microscopic,.chemical,.and.molecular-biological.investigation.of.the.decayed.medieval.stained.window.glasses.of.two.Catalonian.churches,.International.Biodeterioration.and.Biodegradation,.84,.388-400,.doi:.10.1016/j.ibiod.2012.02.008.

Riera, V.,.P. Anadón,.O. Oms, R. Estrada,.and.E. Maestro.(2013),.Dinosaur.eggshell.isotope.geochemistry.as.tools.of.palaeoenvironmental.reconstruction.for.the.upper.Cretaceous.from.the.Tremp.Formation.(Southern.Pyrenees),.Sedimentary.Geology,.294,.356-370,.doi:.10.1016/j.sedgeo.2013.06.001.

ICTJA Research Groups

40 ANNUAL REPORT ICTJA 2013

Roca, E.,.E. Beamud,.M. Rubinat,.R. Soto,.and.O. Ferrer.(2013),.Paleomagnetic.and.inner.diapiric.structural.constraints.on.the.kinematic.evolution.of.a.salt-wall:.The.Bicorb-Quesa.and. northern. Navarrés. salt-wall. segments. case. (Prebetic. Zone,. SE. Iberia),. Journal. of.Structural.Geology,.doi:.10.1016/j.jsg.2013.04.003.

Servera Vives, G.,.Y. Miras,.S. Riera,.R. Julià,.P. Allée,.H. Orengo,.S. Paradis-Grenouillet,.and.J. M. Palet.(2013),.Tracing.the.land.use.history.and.vegetation.dynamics.in.the.Mont.Lozère.(Massif.Central,.France).during.the.last.2000.years:.The.interdisciplinary.study.case.of.Countrasts.peat.bog,.Quaternary.International,.doi:.10.1016/j.quaint.2013.10.048.

Toro-Moyano, I.,.et.al..(2013),.The.oldest.human.fossil. in.Europe,. from.Orce.(Spain),.Journal.of.Human.Evolution,.65(1),.1-9,.doi:.10.1016/j.jhevol.2013.01.012.

Toro, M.,.I. Granados,.S. Pla,.S. Giralt,.D. Antoniades,.L. Galán,.A. M. Cortizas,.H. S. Lim,.and.P. G. Appleby.(2013),.Chronostratigraphy.of.the.sedimentary.record.of.Limnopolar.Lake,.Byers.Peninsula,.Livingston.Island,.Antarctica,.Antarctic.Science,.25(2),.198-212,.doi:.10.1017/S0954102012000788.

ICTJA Research Groups

ANNUAL REPORT ICTJA 2013 41

Research projects 2013

ICTJA Research Groups

National Funding Agencies

Project Title: LACATALAS – Environmental characterization of Miocene lacustrine systems with marine-like faunas from the Duero and Ebro basins: geochemistry of biogenic carbonates and palynologyFinanced by: PNIDI.CGL.-.CGL2011-23438Years:.2012-2014PI:.P..Anadón

Project Title: QUECA – Impactos medioambientales de erupciones cuaternarias en los Andes Centrales: Modelado para la prevención de los efectos de futuras erupcionesFinanced by: PNIDI.CGL.-.CGL2011-23307Years:.2012-2014PI:.J..L..Fernandez-Turiel

Project Title: PALEONAO - Evolución de la NAO durante los ultimos 15000 años en la Peninsula Ibérica y en Azores, a partir del estudio de registros lacustres y datos climáticos instrumentalesFinanced by: PNIDI.CGL.-.CGL2010-15767Years:.2011-2013PI:.S..Giralt

42 ANNUAL REPORT ICTJA 2013

Group members

Geophysical and Geochemical Modelling of Geohazard Processes and Subsurface Resources

Research outline

Geological,.geochemical.and.geophysical.studies.are.applied.to.model.natural.processes.that.can.become.geological.hazards..These.studies.include.research.topics.related.to.volcanism,.seismology,.landslides.or.geochemical.transfer.in.subsurface.and.surface. land..From.a.multidisciplinary.point.of.view,. the. research. is. focused.on.the.physics.of.hazardous.geological.processes,.development.of.analytical.tools.for.geochemistry,.borehole.geophysics.and.remote.sensing.

Among the most important techniques we highlight:

•.Simulation.of.geological.processes.using.a.combination.of.numerical.&.experimental.methods

•.Application.of.X-ray.radiation.for.the.study.of.materials.and.residual.waters

•.Borehole.geophysics.and.subsurface.imaging

•.Development.of.new.algorithms.for.remote.sensing. and. geographic. information.systems.

ICTJA Research Groups

Joan Martí,.Group Leader – Research Professor

Ignasi Queralt, Senior Research ScientistCarles Soriano, Research ScientistMaria José Jurado, Research ScientistAdelina Geyer, JdlC post-docMarta Tarraga, JAE post-docRosa Maria Sobradelo, CSIC contract post-docStèphanie Barde-Cabusson, JAE post-docHelena Gallardo, FPI pre-docRaquel Noriega, FPI pre-docDario Pedrazzi, JAE pre-docStefania Bartolini, JAE pre-docSilvia Aragó, CSIC contract pre-docXavier de Bolós, CSIC contract pre-docSara Quesada, CSIC contractLaura Becerril, CSIC contract

ANNUAL REPORT ICTJA 2013 43

Geophysical and Geochemical Modelling of Geohazard Processes and Subsurface Resources

ICTJA Research Groups

44 ANNUAL REPORT ICTJA 2013

Publications 2013

Atanassova, R.,.J. Cama,.J. M. Soler,.F. G. Offeddu,.I. Queralt,.and.I. Casanova.(2013),.Calcite. interaction. with. acidic. sulphate. solutions:. A. vertical. scanning. interferometry.and.energy-dispersive.XRF.study,.European.Journal.of.Mineralogy,.25(3),.331-351,.doi:.10.1080/1750-8487/2013/0025-2279.

Barde-Cabusson, S.,.X. Bolós,.D. Pedrazzi,.R. Lovera,.G. Serra,.J. Martí,.and.A. Casas.(2013),.Electrical.resistivity.tomography.revealing.the.internal.structure.of.monogenetic.volcanoes,.Geophysical.Research.Letters,.40(11),.2544-2549,.doi:.10.1002/grl.50538.

Bartolini, S.,.A. Cappello,.J. Martí,.and.C. Del Negro.(2013),.QVAST:.A.new.Quantum.GIS.plugin.for.estimating.volcanic.susceptibility,.Natural.Hazards.and.Earth.System.Sciences,.13(11),.3031-3042,.doi:.10.5194/nhess-13-3031-2013.

Bendaoud, R.,.A. Guilherme,.A. Zegzouti,.M. Elaatmani,.J. Coroado,.M. L. Carvalho,.and.I. Queralt.(2013),.Elemental.mapping.of.moroccan.enameled.terracotta.tile.works.(Zellij).based.on.X-ray.micro-analyses,.Applied.Radiation.and.Isotopes,.82,.60-66,.doi:.10.1016/j.apradiso.2013.07.001.

Chevrel, M. O.,.D. Giordano,.M. Potuzak,.P. Courtial,.and.D. B. Dingwell.(2013),.Physical.properties.of.CaAl2Si2O8-CaMgSi2O6-FeO-Fe2O3.melts:.Analogues.for.extra-terrestrial.basalt,.Chemical.Geology,.346,.93-105,.doi:.10.1016/j.chemgeo.2012.09.004.

D'Elia, L.,.and.J. Martí.(2013),.Caldera.events.in.a.rift.depocentre:.An.example.from.the.Jurassic.Neuquén.basin,.Argentina,.Journal.of.the.Geological.Society,.170(4),.571-584,.doi:.10.1144/jgs2012-116.

Floor, G. H.,.E. Marguí,.M. Hidalgo,.I. Queralt,.P. Kregsamer,.C. Streli,.and.G. Román-Ross (2013),.Study.of.selenium.sorption.processes.in.volcanic.ash.using.Total.Reflection.X-ray.Fluorescence.(TXRF),.Chemical.Geology,.352,.19-26,.doi:.10.1016/j.chemgeo.2013.05.034.

Kereszturi, G.,.A. Geyer,.J. Martí,.K. Németh,.and.F. J. Dóniz-Páez.(2013),.Evaluation.of.morphometry-based.dating.of.monogenetic.volcanoes-a.case.study.from.Bandas.del.Sur,.Tenerife.(Canary.Islands),.Bulletin.of.Volcanology,.75(7),.1-19,.doi:.10.1007/s00445-013-0734-1.

Kocot, K.,.B. Zawisza,.E. Marguí,.I. Queralt,.M. Hidalgo,.and.R. Sitko.(2013),.Dispersive.micro.solid-phase.extraction.using.multiwalled.carbon.nanotubes.combined.with.portable.total-reflection.X-ray.fluorescence.spectrometry.for.the.determination.of.trace.amounts.of.Pb.and.Cd.in.water.samples,.Journal.of.Analytical.Atomic.Spectrometry,.28(5),.736-742,.doi:.10.1039/c3ja50047k.

Marguí, E.,.I. Queralt,.and.M. Hidalgo.(2013a),.Determination.of.platinum.group.metal.catalyst.residues.in.active.pharmaceutical.ingredients.by.means.of.total.reflection.X-ray.spectrometry,.Spectrochimica.Acta.-.Part.B.Atomic.Spectroscopy,.86,.50-54,.doi:.10.1016/j.sab.2013.05.024.

ICTJA Research Groups

ANNUAL REPORT ICTJA 2013 45

Marguí, E.,.I. Queralt,.and.M. Hidalgo.(2013b),.Determination.of.cadmium.at.ultratrace.levels.in.environmental.water.samples.by.means.of.total.reflection.X-ray.spectrometry.after.dispersive.liquid-liquid.microextraction,.Journal.of.Analytical.Atomic.Spectrometry,.28(2),.266-273,.doi:.10.1039/c2ja30252g.

Marguí, E.,.M. Sagué,.I. Queralt,.and.M. Hidalgo.(2013),.Liquid.phase.microextraction.strategies.combined.with.total.reflection.X-ray.spectrometry.for.the.determination.of.low.amounts.of.inorganic.antimony.species.in.waters,.Analytica.Chimica.Acta,.786,.8-15,.doi:.10.1016/j.aca.2013.05.006.

Marguí, E.,.B. Zawisza, R. Skorek,.T. Theato,.I. Queralt,.M. Hidalgo,.and.R. Sitko.(2013),.Analytical.possibilities.of.different.X-ray.fluorescence.systems.for.determination.of.trace.elements.in.aqueous.samples.pre-concentrated.with.carbon.nanotubes,.Spectrochimica.Acta.-.Part.B.Atomic.Spectroscopy,.doi:.10.1016/j.sab.2013.07.004.

Martí, J.,.A. Geyer,.and.G. Aguirre-Diaz.(2013),.Origin.and.evolution.of.the.Deception.Island.caldera.(South.Shetland.Islands,.Antarctica),.Bulletin.of.Volcanology,.75(6),.1-18,.doi:.10.1007/s00445-013-0732-3.

Martí, J.,.A. Castro,.C. Rodríguez,.F. Costa,.S. Carrasquilla,.R. Pedreira,.and.X. Bolos.(2013),.Correlation.of.magma.evolution.and.geophysical.monitoring.during.the.2011-2012.El.Hierro.(Canary.Islands).submarine.eruption,.Journal.of.Petrology,.54(7),.1349-1373,.doi:.10.1093/petrology/egt014.

Martí, J., V. Pinel, C. López, A. Geyer, R. Abella,.M. Tárraga, M. J. Blanco, A. Castro,.and.C. Rodríguez.(2013),.Causes.and.mechanisms.of.the.2011-2012.El.Hierro.(Canary.Islands).submarine.eruption,.Journal.of.Geophysical.Research.B:.Solid.Earth,.118(3),.823-839,.doi:.10.1002/jgrb.50087.

Pedrazzi, D., J. Martí,.and.A. Geyer.(2013),.Stratigraphy,.sedimentology.and.eruptive.mechanisms.in.the.tuff.cone.of.El.Golfo.(Lanzarote,.Canary.Islands),.Bulletin.of.Volcanology,.75(7),.1-17,.doi:.10.1007/s00445-013-0740-3.

Phillipson, G., R. Sobradelo,.and.J. Gottsmann.(2013),.Global.volcanic.unrest.in.the.21st.century:.An.analysis.of.the.first.decade,.Journal.of.Volcanology.and.Geothermal.Research,.264,.183-196,.doi:.10.1016/j.jvolgeores.2013.08.004.

Ronchin, E., T. Masterlark, J. Marti Molist, S. Saunders,.and.W. Tao.(2013),.Solid.modeling.techniques.to.build.3D.finite.element.models.of.volcanic.systems:.An.example.from.the.Rabaul.Caldera.system,.Papua.New.Guinea,.Computers.and.Geosciences,.52,.325-333,.doi:.10.1016/j.cageo.2012.09.025.

Sigmarsson, O., D. Laporte, M. Carpentier, B. Devouard, J. L. Devidal,.and.J. Marti.(2013),.Formation.of.U-depleted.rhyolite.from.a.basanite.at.El.Hierro,.Canary.Islands,.Contributions.to.Mineralogy.and.Petrology,.165(3),.601-622,.doi:.10.1007/s00410-012-0826-5.

ICTJA Research Groups

46 ANNUAL REPORT ICTJA 2013

ICTJA Research Groups

Research projects 2013

Skorek, R., B. Zawisza, E. Marguí, I. Queralt,.and.R. Sitko.(2013),.Dispersive.micro.solidphase.extraction.using.multiwalled.carbon.nanotubes.for.simultaneous.determination.of.trace.metal.ions.by.energy-dispersive.x-ray.fluorescence.spectrometry,.Applied.Spectroscopy,.67(2),.204-209,.doi:.10.1366/12-06738.

Soriano, C., G. Giordano, R. Cas, N. Riggs,.and.M. Porreca.(2013),.Facies.architecture,.emplacement.mechanisms.and.eruption.style.of.the.submarine.andesite.El.Barronal.complex,.Cabo.de.Gata,.SE.Spain,.Journal.of.Volcanology.and.Geothermal.Research,.264,.210-222,.doi:.10.1016/j.jvolgeores.2013.07.001.

Vona, A., C. Romano, D. Giordano,.and.J. K. Russell.(2013),.The.multiphase.rheology.of.magmas.from.Monte.Nuovo.(Campi.Flegrei,.Italy),.Chemical.Geology,.346,.213-227,.doi:.10.1016/j.chemgeo.2012.10.005.

National Funding Agencies

Project Title: GEOSUB/2 - Investigación en proyectos de perforación del ICDP: Preparación de un nuevo proyectoFinanced by: PNIDI-ACI.-.ACI2008-0773Years:.2009-2013PI:.M..J..Jurado

Project Title: HIERRO-DOS – Interpretación de la fase de inestabilidad precursora de la erupción del Hierro 2011Financed by: PNIDI-CGL.-.CGL2011-16144-EYears:.2012-2013PI:.M..Martí

Project Title: IMPAS - Impact in Aquifer media and Soils of non-conventional water (treated-desalinated) use and sewage sludge application: laboratory and field investigationsFinanced by: PNIDI-CGLI.-.CGLI22168-C03-01Years:.2011-2013PI:.I..Queralt

Project Title: PEVOLDEC – Análisis de la peligrosidad volcánica de la isla de DecepciónFinanced by: PNIDI-CTM.-.CTM2011-13578-EYears:.2012-2013PI:.A..Geyer

ANNUAL REPORT ICTJA 2013 47

Project Title: PLUVOL – Understanding the plutonic-volcanic connection in supervolcanoesFinanced by: PNIDI-CGL-CGL2010-22022-C02-02Years:.2011-2013PI:.J..Martí

Project Title: PROPER – Investigación y monitorización de fallas sismogenicas en sondeos para la elaboración de una propuesta de perforación al ICDP para perforación en el SE PeninsularFinanced by: PNIDI-CGL.-.CGL2010-21568Years:.2011-2014PI:.M..J..Jurado

Project Title: Desarrollo de actividades de investigación del subsuelo mediante testificación geofísicaFinanced by: IGMEYears:.2010-2013PI:.M..J..Jurado

Project Title: Investigación del subsuelo mediante sondas geofísicas. Estudios entre sondeos y monitorizaciónFinanced by: CIUDENYears:.2009-2012PI:.M..J..Jurado

Project Title: EXCAVA-Explora, caracteriza y visualizaFinanced by: PNIDI-IPT–2012-0979-380000Years:.2013-2015PI:.M..J..Jurado

Project Title: Estudio geofísico para la caracterización de límites estructurales en Tenerife y la Palma (ESTEPA)Financed by: PNIDI-CGL2011-15139Years:.2013-2014PI:.S..Barde-Cabusson.and.A..Geyer

International funding agencies

Project Title: VUELCO – Volcanic unrest in Europe and Latin America: Phenomenology, eruption precursors, hazard forecast, and risk mitigationFinanced by: European.Unión.-.Project.#.282759Years:.2011-2015PI:.J..Martí

ICTJA Research Groups

48 ANNUAL REPORT ICTJA 2013

Sodium. chloride. (NaCl),. the. main.component.of.table.salt,.is.the.archetypical.ionic. compound. of. chemistry. textbooks..The. large. electronegativity. difference.between.the.participating.elements.drives.salt.formation..Metallic.sodium.transfers.electrons. to. chlorine,. and. the. resulting.positively.and.negatively.charged.ions.are.held. together. by. electrostatic. attraction.ionic. bonds.. At. ambient. conditions,.NaCl.crystallizes.in.the.so-called.rocksalt.structure,.a.cubic.array.of.Na.and.Cl.atoms.in.equal.proportions.(1:1.stoichiometry).and.with.six-fold.coordination.

ICTJA 10 highlighted papers

Reformulating table salt under pressureWith. increasing. pressure,. a. structural.phase. transition. to. the. cubic,. eight-fold.coordinated.NaCl-B2.phase.is.observed.at.~30.GPa.[(1).and.references.therein]..Theory.suggested.that.complete.metallization.of.NaCl.should.occur.above.∼300.GPa,.and.no.Na-Cl.compounds.other.than.NaCl.were.known. to. exist.. However,. it. has. recently.been. shown. that. stable. Na-Cl. phases.with.stoichiometries.different.from.1:1.and.intriguing.properties.can.be.synthesized.in.the.lab.with.high-pressure.techniques.

Reference

Ibañez, J..Science,.342,.6165,.1459-1460.(2013)..DOI:.10.1126/science.1247699

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The. application. of. petrography,. mineral.chemistry,.geochemistry,.and.experimental.petrology,. including. mineral–melt.thermodynamic. and. diffusion. modelling,.on. quenched. basanitic. magma. samples.from. the. recent. (2011–2012). submarine.eruption. of. El. Hierro. (Canary. Islands).has.permitted.the.identification.of.major.physico-chemical. variations. prior. to. and.during.magma.eruption. that.correlate. in.time.with.monitored.geophysical.changes..After.nearly.3.months.of.seismic.unrest.the.eruption.of.El.Hierro.started.on.October.10,. 2011. and. ended. by. late. February.2012.. We. studied. 10. lava. balloons. and.pyroclastic. fragments. collected. floating.on. the. sea. surface. between. October. 15.and. late. January.. Based. on. petrological.and.geophysical.data.we.distinguish.two.main. eruptive. episodes.. Magma. erupte.d. from. the. beginning. of. the. eruption.until.late.November.2011.was.an.evolved.basanite.(≈5.wt.%.MgO),.changing.to.more.primitive.compositions.(≈8–9.wt.%.MgO).with.time,.thus.suggesting.extraction.from.a.compositionally.zoned.magma.system.

Experimental. data. and. mineral–melt.thermodynamic.modelling.indicate.that.the.erupted.magma.equilibrated.at.a.pressure.of.about.400.MPa,.which.corresponds.to.a.depth.of.12–15.km..This.depth.is.consistent.with. the. location. of. the. crust–mantle.discontinuity.beneath.El.Hierro.and.with.thehypocentral.location.of.seismicity.during.the.unrest.episode..Preliminary.modelling.

Correlation of magma evolution and geophysicalmonitoring during the 2011-2012 El Hierro (CanaryIslands) submarine eruption

of.the.olivine.chemical.zoning.of.crystals.erupted.in.this.first.episode.suggests.that.the. time. scale. for. basanite. fractionation.and.magma.replenishment.in.the.shallower.reservoir.was.of.the.order.of.a.few.months.This.is.within.the.same.time.frame.as.the.duration.of.the.unrest.episode.preceding.

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the. eruption.. The. first. eruption. episode.coincided.with.intense.seismicity.mostly.located.north.of.the.island,.first.at.a.depth.of.20–25.km.and.a.few.days.later.also.at.10–15.km.depth,.with.strong.seismic.tremor.beneath.the.vent.site..An.abrupt.change.in.magma.composition.and.crystal.content.was.observed.at.the.end.of.November.2011..After.that,.more.primitive.and.less.viscous.magma.erupted.contemporaneously.with.a. change. in. the. frequency. and. intensity.of. seismic. events.. During. this. period,.seismicity.was.mostly.north.of.the.island.at.depths.of.10–15.km..At.the.same.time.the. tremor. intensity. at. the. eruption. site.significantly.dropped..This.marked.the.onset.of.the.second.eruption.episode,.which.is.correlated.with.an.intrusion.of.fresh,.more.primitive.magma.into.the.shallow.magmatic.system.that.raised.the.temperature.of.the.remaining.magma..Experiments.reveal.that.subtle. changes. in. temperature. of. about.50°C. (i.e.. 1100–1150°C). were. enough.to. produce. large. changes. in. the. crystal.

content. (10–60. wt. %).. This. non-linear.behavior. between. crystal. content. and.temperature. had. important. effects. on.magma. dynamics. during. transport. and.cooling..Our.results.suggest.the.existence.of. two. interconnected. mafic. magma.reservoirs. during. the. El. Hierro. eruption,.which.agrees.with.the.pattern.shown.by.the.seismicity..Stress.readjustments.of.the.plumbing.system,.caused.by.decompression.during. the. eruption,. influenced. the.thermodynamic.evolution.of.the.erupting.magma.and.facilitated.the.intrusion.of.the.deeper.magma.into.the.shallow.reservoir,.thus. forcing. a. change. in. its. rheological.characteristics.and.eruption.dynamics.

Reference.

Martí, J., Castro, A., Rodriguez, C., Costa, F. Carrasquilla, S., Pedreira, R..and.Bolos, X.. Journal. of. Petrology.. DOI:. 10.1093/petrology/egt104

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In. the. present. study,. and. taking. into.account. the. microanalytical. capability.of. total. reflection. X-ray. spectrometry.(TXRF),. we. explored. the. possibilities. of.hollow.fibre.liquid-phase.microextraction.(HF-LPME). and. dispersive. liquid-liquid.microextraction.(DLLME).combined.with.TXRF.for.the.determination.of.low.amounts.of.inorganic.Sb.species.in.waters..For.each.of.the.LPME.configurations.aforementioned,.experimental. parameters. affecting. Sb.extraction.but.specially.the.proper.sample.preparation.process.(deposition.volume.on.the.reflective.carrier.and.drying.mode).and.measurement. conditions. for. subsequent.TXRF.analysis.have.been.carefully.evaluated.

The. best. analytical. strategy. for. the.determination.of.Sb(III).and.Sb(V).in.the.low.micrograms.L(-1).range.was.found.to.be. the. application. of. the. DLLME. mode.before. TXRF. analysis.. The. developed.methodology.was.successfully.applied.to.the.determination.of.inorganic.Sb.speciation.in.different.types.of.spiked.water.samples.

Liquid phase microextraction strategies combined with total reflection X-ray spectrometry for the determination of low amounts of inorganic antimony species in waters

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Reference.

Marguí, E., Sagué, M., Queralt, I., Hidalgo. Analytica. Chimica. Acta. DOI: 10.1016/j.aca.2013.05.006.

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We. image. the. western. Mediterranean.upper. mantle. with. improved. resolution.through. the. use. of. a. large. teleseismic.dataset,a.crustal.velocity.structure.derived.from.surface.wave.modeling.iterative.3-D.ray.tracing.and.finite-frequency.kernels..Our.main.conclusions.are:

1..The.dominant.upper.mantle. feature. is.the.4.–.5%.high-velocity,.slab-like.structure.shown. in..This.structure. is.connected.to.the.surface.and.extends.to.the.bottom.of.the.transition.zone.

Evidence for slab rollback in westernmost Mediterranean from improved upper mantle imaging

2.. Its.form,.when.restored.to.the.surface,.fills.the.area.occupied.by.the.Alpine.Tethys.ocean.lithosphere.and.embedded.continental.Alborán.domain.at.30.Ma.

3..We.interpret.the.high-velocity.structure.as. a. slab. of. lithosphere. composed. of.subducted. Alborán. mantle. lithosphere.and.the.surrounding.Alpine.Tethys.ocean.lithosphere.

4..This.lithosphere.is.thought.to.have.beensubducted. during. ∼30. m.y.. of. generally.

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westdirected. subduction. rollback,. which.continued. beneath. the. Alborán. domain.by.delaminating.its.mantle.lithosphere.

5.. A. more. drip-like. delamination. of. the.Middle.Atlas.mantle. lithosphere.may.be.evidenced.by.the.irregular.but.pronounced.zone. of. low. velocities. beneath. these.mountains. at. 50–125. km. depth. and. an.underlying.high-velocity.body.at.∼400–500.km.depth.

Reference.

Bezada, M. J., Humpreys, E.D., Toomey, D.R., Harnafi, M., Davila, J.M., Gallart, J. DOI:.10.1016/J.EPSL.2013.02.024

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The.Orce.region.has.one.of.the.best.late.Pliocene.and.early.Pleistocene.continental.paleobiological. records. of. Europe.. It. is.situated.in.the.northeastern.sector.of.the.intramontane.Guadix-.Baza.Basin.(Granada,.Andalusia,. southern. Spain).. Here. we.describe.a.new.fossil.hominin.tooth.from.the.site.of.Barranco.León,.dated.between.1.02.and.1.73.Ma.(millions.of.years.ago).by.Electron.Spin.Resonance.(ESR),.which,.in. combination. with. paleomagnetic. and.biochronologic. data,. is. estimated. to. be.close.to.1.4.Ma.

While. the. range. of. dates. obtained. from.these.various.methods.overlaps.with.those.

The oldest human fossil in Europe, from Orce (Spain)published.for.the.Sima.del.Elefante.hominin.locality.(1.2.Ma),.the.overwhelming.majority.of.evidence.points.to.an.older.age..Thus,.at.the.moment,.the.Barranco.León.hominin.is.the.oldest.from.Western.Europe.

Reference.

Toro-Moyano, I.; Martínez-Navarro, B.; Agustí, J.; Souday, C.; Bermúdez de Castro, J.M.; Martinón-Torres, M.; Fajardo, B.; Duval, M.; Falguères, C.; Oms, O.; Parés, J.M.; Anadón, P.; Julià, R.; García-Aguilar, J.M.; Moigne, A.-M.; Espigares, M.P.; Ros-Montoya, S.; Palmqvist, P..DOI:.10.1016/J.JHEVOL.2013.01.012.

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Diatom-based.carbon.and.oxygen.isotope.analyses. (δ13C

diatom. and. δ18O

diatom). were.

performed. on. diatom-rich. laminated.sediments. of. Lake. Chungará. (Andean.Altiplano,.northern.Chile).deposited.during.the.Lateglacial.and.Early.Holocene.(12,400–8300.cal.years.BP).to.reconstruct.climate.change.and.environmental.response.across.this.major.climate.transition..The.δ13C

diatom.

data. show. both. centennialto-millennial.scale.changes.related.to.fluctuations.in.lake.productivity.and.CO

2.concentration.in.the.

lake.water,.and.variations.in.carbon.sources.to.the.lake.through.time..The.δ18O

diatom.data.

reflect. changes. in. lake. hydrology. and.climate.

The.combination.of.δ13Cdiatom

.and.δ18Odiatom

.data. reveals. interactions. between. the.internal.lake.processes.and.its.catchment.runoff..During.wet.periods.(low.δ18O

diatom.

values). δ13Cdiatom

. indicates. an. enhanced.contribution. of. allochthonous. carbon,.whereas.during.dry.periods.(high.δ18O

diatom).

δ13Cdiatom

.values.suggest.more.autochthonous.carbon.production.and.recycling.

These. decadal-to-centennial. oscillations.are.not.recognized.after.10,000.cal.years.BP,. possibly. as. a. result. of. ENSO-like.phenomenon.weakening..Humid.conditions.during. the. Lateglacial–Early. Holocene.transition. (12,400–10,100. cal. years. BP).were.possibly.due.to.the.establishment.of.

Climate, catchment runoff and limnological drivers of carbon and oxygen isotope composition of diatom frustules from the central andean altiplano during the Lateglacial and Early Holocene

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La.Niña-like.conditions.in.the.tropical.South.Pacific..Whereas,.dry.conditions.in.the.Early.Holocene.(10,100–9100.cal.years.BP).may.be.caused.by.the.northward.migration.of.the.ITCZ.due.to.both.ENSO-like.weakening.and.an.insolation.minimum..Finally,.a.return.to.humid.conditions.at.the.end.of.the.Early.Holocene.(9100–8300.cal.years.BP).is.coincident.with.an.increase.in.summer.insolation.

Reference.

Hernández, A.; Bao, R.; Giralt, S.; Sáez, A.; Leng, M.J.; Barker, P.A.; Kendrick, C.P.; Sloane, H.J. DOI:.10.1016/J.QUASCIREV.2012.10.013

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Earlier. palynological. studies. of. lake.sediments.from.Easter.Island.suggest.that.the.island.underwent.a.recent.and.abrupt.replacement.of.palm-dominated.forests.by.grasslands,.interpreted.as.a.deforestation.byindigenous.people..However,.the.available.evidence.is.inconclusive.due.to.the.existence.of. extended. hiatuses. and. ambiguous.chronological.frameworks.in.most.of.the.sedimentary.sequences.studied..This.has.given.rise.to.an.ongoing.debate.about.the.timing.and.causes.of.the.assumed.ecological.degradation.and.cultural.breakdown..Our.multiproxy.study.of.a.core.recovered.from.Lake. Raraku. highlights. the. vegetation.dynamics.and.environmental.shifts.in.the.catchment.and.its.surroundings.during.the.late.Holocene.

Vegetation changes and human settlement of Easter Island during the last millennia: A multiproxy study of the Lake Raraku sediments

The. sequence. contains. shorter. hiatuses.than. in. previously. recovered. cores. and.provides. a. more. continuous. history. of.environmental.changes..The.results.show.a.long,.gradual.and.stepped.landscape.shift.from.palm-dominated.forests.to.grasslands..This.change.started.c..450.BC.and.lasted.about.two.thousand.years..The.presence.of.Verbena litoralis,.a.common.weed,.which.is.associated.with.human.activities.in.the.pollen. record,. the. significant. correlation.between.shifts.in.charcoal.influx,.and.thedominant. pollen. types. suggest. human.disturbance.of.the.vegetation..Therefore,.human.settlement.on.the.island.occurred.c..450.BC,.some.1500.years.earlier.than.is.assumed.

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Climate. variability. also. exerted. a. major.influence. on. environmental. changes..Two. sedimentary. gaps. in. the. record. are.interpreted.as.periods.of.droughts.that.could.have.prevented.peat.growth.and.favoured.its. erosion. during. the. Medieval. Climate.Anomaly.and.the.Little.Ice.Age,.respectively..At.c..AD.1200,.the.water.table.rose.and.the.former.Raraku.mire.turned.into.a.shallow.lake,. suggesting. higher. precipitation/evaporation.rates.coeval.with.a.cooler.and.wetter.Pan-Pacific.AD.1300.event..Pollen.and.diatom.records.show.large.vegetation.changes.due.to.human.activities.c..AD.1200..

Other.recent.vegetation.changes.also.due.to.human.activities.entail.the.introduction.of.taxa.(e.g..Psidium guajava,.Eucalyptus.sp.).and.the.disappearance.of.indigenous.plants.such. as. Sophora toromiro. during. the. two.last.centuries..Although.the.evidence.is.not.conclusive,.the.American.origin.of.V. litoralis.re-opens.the.debate.about.the.possible.role.of.Amerindians.in.the.human.colonisation.of.Easter.Island.

Reference.

Cañellas-Boltà, N.; Rull, V.; Sáez, A.; Margalef, O.; Bao, R.; Pla-rabes, S.; Blaauw, M.; Valero-Garcés, B.; Giralt, S..DOI:.10.1016/J.QUASCIREV.2013.04.004

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Eruptive.activity.of.individual.monogenetic.volcanoes.usually.lasts.a.few.days.or.weeks..However,.their.short.lifetime.does.not.always.mean.that.their.dynamics.and.structure.are.simple..Monogenetic.cones.construction.is.rarely.witnessed.from.the.beginning.to.the.end,.and.conditions.for.observing.their.internal.structure.are.hardly.reached..We.provide.high-resolution.electrical.resistivity.sections.(10.m.electrode.spacing).of.three.monogenetic. cones. from. northeastern.Spain,.comparing.our.results.to.geological.observations.to.interpret.their.underground.continuation..The.100.m.maximum.depth.of. exploration. provides. information. on.almost. the. entire. edifices,. highlighting.the.relationships.between.Strombolian.and.hydromagmatic.deposits.in.two.multiphase.edifices..A.main.observation.is.a.column.of.distinct.resistivity.centered.on.the.Puig.d'Adri.volcano,.which.we.interpret.as.the.eruptive.conduit..This.method.can.provide.valuable.information.on.the.past.volcanic.dynamics.of.monogenetic.volcanic.fields,.which.has.real.implic.ations.for.the.forecast.of.future.activity.

Reference.Barde-Cabusson, S.; Bolós, X.; Pedrazzi, D.; Lovera, R.; Serra, G.; Martí, J.; Casas, A..DOI:.10.1002/GRL.50538

Electrical resistivity tomography revealing the internal structure of monogenetic volcanoes

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The.Río.San.Juan.metamorphic.complex.exposes. a. segment. of. a. high-pressure.subduction-accretionary. complex. built.during.convergence.between.the.Caribbean.island.arc.and.the.North.America.continental.margin..It.is.composed.of.accreted.arcand.oceanic-derived. metaigneous. rocks,.serpentinized. peridotites. and. minor.metasediments.forming.a.structural.pile..Combined.structural.geology,.microtextural.relations,. multi-equilibrium. calculations.and.thermodynamical.modelling,.together.with. published. isotopic. ages,. allow.reconstructing. the. metamorphic. P-T-t.paths.of.each.nappe/unit.and. their. links.to.the.structural.evolution..In.all.units.of.the.complex,.three.major.stages.(M1.to.M3).in.the.tectonothermal.evolution.have.been.distinguished..The.M1.stage.corresponds.to. the. prograde. evolution. towards. the.pressurepeak. of. metamorphism. under.blueschist.or.eclogitic-facies.conditions.

The. M2. stage. is. related. to. the. main.retrogressive. event. and. is. characterized.by. the. S2-L2. fabric. development. in. all.lithologies.and.at.all.scales..The.M3.stage.represents. continuous. exhumation. from.ductile.to.ductile-brittle.deformation.regimes..However,.the.shape.of.the.retrograde.P-T.path,.the.age.of.the.exhumation-related.D2.structures.and.the.tectonic.significance.of.D2.deformation.are.different.in.each.structural.unit.. In.the.upper.structural. levels.of.the.

Contrasting exhumation P-T paths followed by high-P rocks in the northern Caribbean subduction-accretionary complex: Insights from the structural geology, microtextures and equilibrium assemblage diagrams

Jagua.Clara.serpentinitic-matrix.mélange,.the.counter-clockwise.P-T.path.of.the.eclogite.blocks.is.typical.of.rocks.exhumed.in.the.early. stages. of. intra-oceanic. subduction.zones..The.clockwise.P-T.path.obtained.for.the.lower.Cuaba.unit.is.characterized.by.a.strong.isothermal.decompression.from.the.garnet-epidote.amphibolite.and.eclogite-

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facies.pressure-peak..This.P-T.evolution.can.be.explained.by.rapid.exhumation.caused.byextensional.tectonics,.in.relation.to.a.major.modification. of. convergence. conditions.across.the.subduction.zone..The.P-T.path.also.explains.local.syn-M2.partial.melting.processes,.because.it.crosses.the.wet.solidus.for.IAT.mafic.compositions..The.P-T.path.obtained.for.the.high-P.Guineal.Schists,.with.exhumation.trajectory.following.the.burial.trajectory,. can. be. related. to. exhumation.during.active.subduction..This.exhumation.was.most.likely.driven.by.a.combination.of.underthrusting.of.tectonic.units.and.erosion.processes.. Available. geochronological.data.and.T-t/P-t.estimates.reveal.a.Late.Campanian.to.Maastrichtian.retrograde.M2.

metamorphism.in.the.lower.structural.units.of.the.complex.during.a.consistent.D2.top-to-the-NE/ENE.tectonic.transport..A.similar.tectonic.transport.has.also.been.recognized.in.the.metasedimentary.nappes.of.the.Samaná.complex.during.Eocene.to.earliest.Miocene..These.relations.indicate.a.northeastward.progradation. of. deformation. during. the.successive. tectonic. incorporation. of. arc,.oceanic. and. continental-derived. terrains.to.the.developing.Caribbean.su.bduction-accretionary.complex.

Reference.Escuder-Viruete, J. and Pérez-Estaún, A..DOI:.10.1016/J.LITHOS.2012.11.028

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We. present. an. experimental. and.theoretical.lattice-dynamical.study.of.InN.at.high.hydrostatic.pressures..We.perform.Raman.scattering.measurements.on.five.InN. epilayers,. with. different. residual.strain. and. free. electron. concentrations..The. experimental. results. are. analyzed.in. terms. of. ab initio. lattice-dynamical.calculations.on.both.wurtzite.InN.(w-InN).and.rocksalt.InN.(rs-InN).as.a.function.of.pressure.. Experimental. and. theoretical.pressure.coefficients.of.the.optical.modes.in. w-InN. are. compared,. and. the. role. of.residual.strain.on.the.measured.pressure.coefficients. is. analyzed.. In. the. case. of.the.LO.band,.we.analyze.and.discuss. its.pressure.behavior.considering.the.double-resonance.mechanism.responsible.for.the.selective. excitation. of. LO. phonons. with.large.wave.vectors.in.w-InN..The.pressure.behavior.of.the.L–.coupled.mode.observed.in.a.heavily.doped.n-type.sample.allows.us.to. estimate. the. pressure. dependence. of.the.electron.effective.mass.in.w-InN..The.results.thus.obtained.are.in.good.agreement.with.k•p.theory..The.wurtzite-to-rocksalt.phase.transition.on.the.upstroke.cycle.and.the. rocksalt-to-wurtzite. backtransition.on.the.downstroke.cycle.are.investigated,.and. the. Raman. spectra. of. both. phases.are. interpreted. in. terms. of. DFT. lattice-dynamical.calculations.

Reference.

Ibáñez, J.; Oliva, R.; Manjón, F.J.; Segura, A.; Yamaguchi, T.; Nanishi, Y.; Cuscó, R.; Artús, L. DOI:.10.1103/PHYSREVB.88.115202.

High-pressure lattice dynamics in wurtzite and rocksalt indium nitride investigated by means of Raman spectroscopy

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Theses, Seminars and Courses

Title:. Análisis y aplicaciones del ruido sísmico en México, Golfo de México y Caribe: tomografía de ondas superficiales Rayleigh y Love. PhD.Student:. Beatriz.GAITE.CASTRILLOPhd.Advisor:. Antonio.VILLASEÑORPlace.&.date:. Madrid.–.07/2013

Title:. Novel technique to detect seismic signals and its application to map upper-mantle discontinuities beneath Iberia..PhD.Student:. Anahí.LUCIANA.BONATTOPhd.Advisor:. Martin.SCHIMMELPlace.&.date:. Barcelona.–.11/2013

Title:. The explosive volcanism of Teide-Pico Viejo volcanic complex, Canary island..PhD.Student:. Olaya.GARCÍA.PÉREZPhd.Advisor:. Joan.MARTÍPlace.&.date:. Barcelona.–.11/2013

Theses

ICTJA.has.co-organized.in.collaboration.with.the.Faculty.of.Geology.of.the.University.of.Barcelona.about.20.specialized.seminars,.conferences.and.lectures.during.the.year.2013..Among.them.we.would.like.to.highlight:

Seminars

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21/01"Topographic evolution of the East African Plateau",.Dr..Henry.Wichura,.Universitat.de.Postdam,.Germany.

11/04"Catastrophes in the Crust: Forecasting Volcanic Eruptions and Giant Landslides",.Dr..Christopher.Kilburn,.University.College.London,.UK.

18/04"Anticipating the news: Global ShakeMap & PAGER earthquake rapid response system",.Dr..Daniel.García.Jiménez,.USGS/GEM.External.Consultant

08/05"Recent innovative geophysics techniques applied to defining geology under cover –a global perspective",.Dr..D..FitzGerald,.Intrepid.Geophysics,.Victoria,.Austràlia.

25/06"Sismicidad en el Golfo de México: Un análisis preliminar",.Dra..Sara.Ivonne.Franco,.Instituto.de.Geofísica,.Universidad.Nacional.Autónoma.de.México.(UNAM).

27/06"Geological contribution to seismic hazard assessment for nuclear facilities (NFs)",.Dr..Stéphane.Baize,.Institut.de.Radioprotection.et.Sûreté.Nucléaire,.França.

17/09"Fluids in the Earth’s interior: from geochemical cycles to super-volcano eruptions",.Dr..Carmen.Sanchez-Valle,.Inst..Geochemistry.and.Petrology,.ETH.Zurich,.Switzerland

20/09"Yacimientos españoles de estaño asociados a intrusiones graníticas hercínicas",.Dr..José.MangasUniversidad.de.Las.Palmas.de.Gran.Canaria..Co-organized.together.with.WORKSHOP.ON.MINERAL.DEPOSITS.RELATED.TO.ACID.MAGMATISM..SGA.Barcelona.Student.Chapter

08/10"Two-dimensional probabilistic inversionof plane-wave electromagnetic data: Methodology, model constraints and joint inversion with electrical resistivity data",.Dr..Niklas.Linde,.Centre.de.Recherches.en.Environment.Terrestre,.Faculté.des.Géosciences.et.de.l'environment,.Université.de.Lausanne,.Switzerland.

18/10"Mantle, ocean crust and seawater:where are we, and what’s next in Scientific Drilling",.Dr..Benoît.Ildefons,.ECORD.Distinguished.Lecturer.2013,.Géosciences.Montpellier,.CNRS/Université.Montpellier.2,.France.

07/11"Relative contribution of tectonic inheritance and far field forces on the building of Paleozoic European crust",.Karel.Schulmann,.Institut.de.Physique.du.Globe,.Université.de.Strasbourg,.France.

Theses, Seminars and Courses

68 ANNUAL REPORT ICTJA 2013

Theses, Seminars and Courses

12/11"Magnetotelluric studies in Brazil:Source effects and some application examples",.a.càrrec.de.Antonio.Lopes.Padilha,.Instituto.Nacional.de.Pesquisas.Espaciais,.São.Jose.de.Campos,.São.Paulo,.Brasil

14/11"Quantitative thinking under the volcano:A special marriage among rocks, numbers and experiments to advance the knowledge of volcanic processes",.Antonio.M..Álvarez.Valero,.Departamento.de.Geología,.Facultad.de.Ciencias,.Universidad.de.Salamanca

20/11"Geociència, Art, Wikipedia:contribuïnt amb il·lustracions lliures.Iniciativa wikiArS",.David.Gómez.Fontanills.i.Daniel.Garcia-Castellanos.(ICTJA)

21/11"Evolución geodinámica paleozoica del margen sudoccidental del Gondwana:El basamento de los Andes Centrales",.Prof..Dra..Graciela.I..Vujovich,.Instituto.de.Estudios.Andinos.“Don.Pablo.Groeber”.(IDEAN),.Universidad.de.Buenos.Aires,Consejo.Nacional.de.Investigaciones.Científicas.y.Técnicas,.Argentina

26/11"Exhumation and interactions between a mountain range and its foreland basin: thermochronology and numerical modeling of the Cenozoic Southern Pyrenees",.Charlotte.Fillon..ICTJA-CSIC

4/12"Restitución 3D de estructuras complejas, paleomagnetismo y scanner de rayos X",.Emilio.L..PueyoInstituto.Geológico.y.Minero.de.España,.Unidad.de.Zaragoza;Geología.Estructural,.Dpto..Ciencias.de.la.Tierra,.Universidad.de.Zaragoza

13/12"Un paleontólogo en la Administración: 20 años de gestión de yacimientos y colecciones fósiles en la Región de Murcia",.Gregorio.Romero.Sánchez,.Servicio.de.Patrimonio.Histórico,.Dirección.General.de.Cultura,.Consejería.de.Educación.y.Cultura.de.la.Región.de.Murcia

CoursesCourse:.. Curso Teórico-Práctico de Difracción de Rayos X en Polvo 2013Date: May, 27-28, 2013Location: ICTJA-CSIC, Barcelona

Course:.. Curso Teórico Prácticode ICP-MS 2013Date: May, 29-31, 2013Location: ICTJA-CSIC, Barcelona

Course:.. Curso Internacional de VulcanologíaDate: October, 14-27, 2013Location: Girona

Course:.. Què podem aprendre d’un sismograma?Date: December, 11, 2013, 16:00-19:00Location: ICTJA-CSIC, Barcelona

ANNUAL REPORT ICTJA 2013 69

Editorial and Assessment activities

Editorial

Editors-in-Chief.J. Marti:.Journal.of.Volcanology.and.Geothermal.ResearchJ. Alvarez-Marrón: Geologica.Acta

Editorial activities.D. Brown:.Geological.Society.of.AmericaD. Brown: Journal.of.Asian.Earth.SciencesD. Brown: Solid.EarthR. Carbonell: TectonophysicsP. Anadón: Geologica.Acta

International Committees & CollaborationCommittees

IAVCEI:.Joan Martí. Secretary General of the International Association of Volcanology and Chemestry o fthe Eart Interior (IAVCEI).

IUGG.Commission.–.GRC: Joan Martí. Member of the Executive Committee of the IUGG Commission on Geophysical Risk and Sustainability (GRC).

European. Geosciences. Union: Daniel García-Castellanos. Member of the Program Committee for the “Tectonics and Structural Geology división”.

IAL: Pere Anadón. Member of the Board of Directors. International Association of Limnogeology.

Collaboration

Invited scientists.

AUIP-Argentina:.Ignasi Queralt (Invited scientist)..IDEPA.(Instituto.Mulstidisciplinario.de.Investigación.y.Desarrollo.de.la.Patagonia.Norte).CONICET-Universidad.Nacional.del.Comahue.Neuquén..Asociación.Universitaria.Iberoamericana.de.Posgrado.(AUIP)..November.

IAEA-United.Arabian.Emirates: Ignasi Queralt (International Expert Mission)..University.of.Sharjah..IAEA.Technical.Co-operation.Expert.Mission.on.the.use.of.X-ray.diffraction.for.Environmental.and.Archaeological.research..International.Atomic.Energy.Agency.(IAEA-UN)..September.

70 ANNUAL REPORT ICTJA 2013

UNAM-Mexico: Ignasi Queralt (Invited Scientist).. Instituto. de. Ciencias. del. Mar. y.Limnología..Unidad.Académica.Mazatlán..Universidad.Nacional.Autónoma.de.Mexico..Coordinación.de.la.Investigación.Científica.-.Posgrado.en.Ciencias.del.Mar-CONICYT..June.

ICDP.Science.Conference.2013: Maria José Jurado (Invited speaker)..ICDP.Conference.“Imaging.the.Past.to.Imagine.our.Future”..Postdam,.11-14.November.

JAMSTEC-Japan: Maria José Jurado (Invited Scientist)..Chief.Scientist.of.geophysical.logging.at.Chikyu.IODP.348.Expedition.–.NanTroSEIZE..December.

Invited talks.

D. García-Castellanos:.Opening.of.the.Scholar.Year.of.the.Faculty.of.Geology.. “La gigantesca salina Mediterránea de la crisis messiniense”..University.of.Barcelona.

D. García-Castellanos:.Hutton.Club.invited.seminar..“Tectonics, erosion, and climate in the Mediterranean during the Messinian salinity crisis. Mechanistic understanding emerging from landscape evolution models”..Edinburgh.University.

D. García-Castellanos:.AGU.2013-EP43E-03..“Tectonics, erosion, and climate in the Miocene Mediterranean: a mechanistic approach to the Messinian Salinity Crisis”..San.Francisco.(USA).

D. García-Castellanos:.University.of.Postdam..“Interplay between orogen tectonics and surface processes: A numerical modeling perspective”..Berlin.(Germany).

D. García-Castellanos:.GFZ-Postdam..“Interplay between orogen tectonics and surface processes: A numerical modeling perspective”..Berlin.(Germany).

S. Giralt:."Hacia las reconstrucciones cuantitativas del Cambio Climático a partir del registro sedimentario"..3er.Congreso.Nacional.de.Investigación.en.Cambio.Climático..Mazatlán.(México).

International Committees & Collaboration

ANNUAL REPORT ICTJA 2013 71

The. assessment. of. the. probable. spatial.distribution.of.new.eruptions.is.useful.to.manage.and.reduce.the.volcanic.risk..It.can.be.achieved.in.different.ways,.but.it.becomes.especially.hard.when.dealing.with.volcanic.areas.less.studied,.poorly.monitored.and.characterized.by.a.low.frequent.activity,.as.El.Hierro..Even.though.it.is.the.youngest.of.the.Canary.Islands,.before.the.2011.eruption.in.the.“Las.Calmas.Sea”,.El.Hierro. had. been. the. least. studied. volcanic.Island.of.the.Canaries,.with.more.historically.devoted.attention. to.La.Palma,.Tenerife.and.Lanzarote..We.propose.a.probabilistic.method.to.build.the.susceptibility.map.of.El.Hierro,.i.e..the.spatial.distribution.of.vent.opening.for.future.eruptions,.based.on.the.mathematical.analysis.of.the.volcano-structural.data.collected.mostly.on.the.Island.and,.secondly,.on.the.submerged.

ICTJA –SPA Awards 2013

Spatial vent opening probability map of El Hierro Island(Canary Islands, Spain)

part.of.the.volcano,.up.to.a.distance.of.10-20.km.from.the.coast.

The. volcano-structural. data. were. collected.through. new. fieldwork. measurements,.bathymetric. information,. and. analysis. of.geological. maps,. orthophotos. and. aerial.photographs..They.have.been.divided.in.different.datasets. and. converted. into. separate. and.weighted.probability.density.functions,.which.were. then. included. in. a. non. homogeneous.Poisson. process. to. produce. the. volcanic.susceptibility.map..Future.eruptive.events.on.El.Hierro. is.mainly.concentrated.on.the.rifts.zones,. extending. also. beyond. the. shoreline..The.major.probabilities.to.host.new.eruptions.are.located.on.the.distal.parts.of.the.South.and.West.rifts,.with.the.highest.probability.reached.in.the.south-western.area.of.the.West.rift..High.probabilities.are.also.observed.in.the.Northeast.and.South.rifts,.and.the.submarine.parts.of.the.rifts..This.map.represents.the.first.effort.to.deal.with.the.volcanic.hazard.at.El.Hierro.and.can.be.a.support.tool.for.decision.makers.in.land.planning,.emergency.plans.and.civil.defence.actions.

Reference.

Becerril, L.. et. al.. (2013).. Geophysical.Research.Abstracts,.15,.EGU2013-11037.

InGaN. alloys. have. generated. a. growing.interest. for. photovoltaic. applications,.as. their.band.gap.can.be.tuned.to.cover.the. full. solar. spectrum. and. they. show. a.

Multiphonon Raman scattering in He-irradiated InGaN alloysremarkable.resistance.to.irradiation..This.makes.InGaN.an.attractive.material.system.for. outer. space. solar. cell. applications..Moreover,. owing. to. the. higher. ionicity. of.

72 ANNUAL REPORT ICTJA 2013

the.bonds.and.dynamical.annealing,.GaN.is.extremely.resistant.to.amorphization..Raman.scattering.is.a.powerful.tool.to.characterize.structural. damage. in. irradiated. crystals..With. above. band-gap. excitation,. higher.order. multiphonon. scattering. is. strongly.enhanced. by. impurity-induced. Fröhlich.interaction.. Whereas. close. to. resonance.the.strong.photoluminescence.(PL).signal.in.pure.crystals.prevents.the.clear.observation.of. multiphonon. peaks,. PL. quenching. by.high-fluence.ion-beam.irradiation.makes.it.possible.to.study.the.multiphonon.Raman.peaks.in.implanted.samples.

In.this.work.we.present.a.Raman.scattering.study.of.multiphonons.in.InGaN.alloys.with.In.content.ranging.from.17%.to.42.%.using.near-resonance.visible.excitation.(514.5.nm).and.above.band-gap.UV.excitation.(325.nm)..The.InGaN.epilayers.were.grown.by.plasma-assisted.MBE.on.sapphire.substrates.with.a.GaN.buffer..The.epilayers.were.implanted.with.He.ions.at.40,.88.and.180.keV.with.total.fluences.ranging.from.7.5E12.to.1.9E15.cm-2.to.produce.a.homogeneous.damage.profile. over. the. whole. layer.. The. free.electron.density.and.the.optical.properties.of.the.samples.were.characterized.before.and. after. implantation. by. means. of. Hall.measurements,.PL.and.optical.absorption..In.the.alloys.with.higher.In.composition.the.electron.density.increases.with.irradiation.as.expected.from.the.location.of.the.Fermi.stabilization.energy.above.the.conduction.band. edge.. The. irradiation. effects. are.corroborated.by. the.shifts. in. the.PL.peak.and.absorption.edge..For.the.highest.fluences.the.generation.of.trapping.defects.reverses.this.trend..Outgoing.resonance.conditions.occur.for.the.InGaN.layer.with.[In]=24%.under. 514.5. nm. excitation.. This. sample.

exhibits.a.one.order.of.magnitude.increase.of. the. LO. intensity.. Upon. implantation,.both.the.PL.and.the.LO.intensities.markedly.decrease.but.up.to.4LO.scattering.can.be.detected..In.the.implanted.samples.the.LO.peak.shows.a.downshift.and.an.asymmetric.broadening.which.reflects.the.implantation.damage.. The. higher. order. multiphonon.peaks.display.frequencies.in.good.agreement.with. the. multiples. of. the. LO. frequency..The. multiphonon. Raman. peaks. exhibit. a.substantial.asymmetric.broadening.at.the.low. frequency. side,. which. suggests. the.participation.of.large.wave-vector.phonons.in.the.multiple.scattering..The.Raman.spectra.obtained.with.UV.excitation.show.the.typical.multiphonon.cascade.peaks.up.to.5LO.as.well.as.E2+nLO.combinations..The.same.intensity.ratios.between.successive.order.peaks.are.observed.for.all.alloy.compositions..The.LO/.E2.and.2LO/1LO.intensity.ratios.are.shown.to.be.sensitive.indicators.of.the.irradiation.induced.damage.

Reference.

Dòmenech-Amador, N..et.al..(2013)..Multiphonon. Raman. Scattering. in. He-Irradiated. InGaN. Alloys.. Compound.Semiconductor.Materials.and.Devices..Fall.Meeting.Research.Society..Boston.(USA).

ICTJA-SPA Awards 2013

ANNUAL REPORT ICTJA 2013 73

EXPOMINER-2013 November, 14-16 “The 2013 Expominer and Colecciona edition turn Barcelona into a collector's heaven”

Outreach Activities

ICTJA.has.been.involved.in.EXPOMINER.both.giving.advice.and.actively.organizing.seminars.and.workshops..Dr..Ignasi.Queralt.has.been.a.member.of.the.Advisory.Board.since.1992.and.ICTJA.personnel.has.been.actively.participating.in.the.section.“Living Geology”.

74 ANNUAL REPORT ICTJA 2013

EspaiCiència – 2013 March, 13-17“Thousands of young people got advice at the fair”

Over.65,000.students,.relatives.and.teachers.visited.the.Saló.de.l'Ensenyament.

GEOflaix! – 2013Geoflaix!.is.a.look.at.our.lives.from.the.perspective.of.minerals.and.rocks.that.are.part.of.our.environment..From.minerals.we.obtain.materials.that.are.the.key.to.a.more.comfortable.life..The.exhibition.aims.to.show.visitors.how.the.majority.of.objects.that.surround.us.have.a.geological.basis..It.is.also.a.taste.for.exploring.the.rocks.....what.we.obtain.and.what.they.tell.us!

GEOflaix!.is.co-organized.by.the.Faculty.of.Geology.of.the.University.of.Barcelona,.the.Institute.of.Earth.Sciences.Jaume.Almera.and.the.former.Institute.of.Geology.of.Catalonia.of.the.Generalitat.de.Catalunya.

Outreach Activities

ANNUAL REPORT ICTJA 2013 75

WikiArS – 2013During.the.Week.of.Science.("Setmana.de.la.Ciència").the.Wikimedia.grantee.David.Gómez.and.Daniel.Garcia-Castellanos.(ICTJA-CSIC).gave.a.joint.conference.together.with.a.poster.display.of.illustrations.related.to.the.project.wikiArS...wikiArS.is.an.pioneer.initiative.that.brings.together.the.Academy and Arts schools[1].into.the.Wikimedia.movement's.projects.(Wikipedia,.Wiktionary,.Commons.repository,.etc).by.contributing.scientific.illustrations.that.make.human.knowledge.accessible.to.everyone.

wikiArS.is.designed.to.be.useful.to.students.in.learning.arts.skills.as.well.as.providing.images.and.content.to.the.Wikipedia.and.to.other.free-culture.projects.

Outreach Activities

76 ANNUAL REPORT ICTJA 2013

Funding (2013 Public & Private Funding)

ICTJA in numbers

Services 66.110 6%Competitive Public Funds 333.840 31%

R+D Industry 661.140 61%Public Sector Agreements 16.000 2%

Services 66.110 - 6%Competitive Public Funds 333.840 - 31%R+D Industry 661.140 - 61%Public Sector Agreements 16.000 - 2%

66.110

333.840

661.140

16.000

Services 66.11 - 6%Competitive Public Funds 333.84 - 31%R+D Industry 661.14 - 61%Public Sector Agreements 16.00 - 2%

6

31

61

2

Services 66.11 - 6%Competitive Public Funds 333.84 - 31%R+D Industry 661.14 - 61%Public Sector Agreements 16.00 - 2%

6

31

61

2

TOTAL 1.077.090

ANNUAL REPORT ICTJA 2013 77

Publications

ICTJA in numbersgrafic per edatsgrafic per edats

2006 49

2007 55

2008 59

2009 60

2010 70

2011 77

2012 68

2013 84

0

10

20

30

40

50

60

70

80

90

4955

59 60

70

77

68

84

2006 2007 2008 2009 2010 2011 2012 2013

Evolutions SCI Publications (Total 522)

Publ

icac

ions

SC

I

ICTJA h-index

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 20130

10

20

30

40

50

60

70

80

78 ANNUAL REPORT ICTJA 2013

Annual ReportICTJA-2013Institute of Earth Sciences Jaume Almera(A Geosciences Institute)