annual report ictja 2013
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2 ANNUAL REPORT ICTJA 2013
Foto portada: Coring campaign at Maule (Chile) (photo by Santiago Giralt, ICTJA-CSIC)
Disseny i maquetació: Masgrau-Yani, SL
ANNUAL REPORT ICTJA 2013 3
Foreword
Montserrat TorneDirector
ICTJA main mission is to advance scientific understanding of Earth System Science by improving our knowledge of geological processes, mitigation of geohazards and exploration of geological resources applying advanced experimental and analytical methodologies. Central to our mission is quality training of the next generation of Earth Sciences researchers and technicians.
Following the main guidelines of ICTJA-Strategic Plan 2010-2013, during 2013 our research activities have been developed through research projects funded by public competitive sources and by industry, as well as a small percentage coming from analytical services.
Despite being still immerse in the aftershocks of the so called “perfect storm” provoked by the financial crisis, ICTJA activities has no suffered too much (yet). Thus, income from grants in 2013 has decreased somewhat from 2012, mainly due to research budget cuts. This coupled with the fact that in 2013 there were no public calls from the 7th Framework Programme has resulted in a decrease in public funding of about 30%. Funds raised from public competitive sources both National and European accounted for 31.5% of the total (319,351.57 ¤), while funds coming from industry accounted for 62.6% of the total (634,590.44 ¤). The remaining 6.3% corresponds to funds raised from agreements with the public sector and from services. These figures are calculated as the yearly granted contribution for pluriannual projects.
Regarding the scientific activities, the number of ISI articles authored or coauthored by ICTJA staff slightly increased from 68 in 2012 to 82 in 2013, averaging 3.15 pub/res, while total publications amount to 90 (3.46
pub/res). A total of 17 PhD students were trained in 2013, which combined with the actively participation of senior researchers and postdocs (10) in doctorate and master programs, demonstrates our compromise with quality training and teaching of young researchers.
ICTJA has also been quite active in the organization of a number of specialized seminars, conferences, lectures and in disseminating our research results to the society. Among them it is worth highlighting our participation in the GEOflaix! Exhibition, an alternative look at daily objects from the perspective of Earth Sciences; Espai Ciència-Saló de l’Ensenyament, where thousands of young people and teachers got advice at the fair; and EXPOMINER, a collector’s heaven. Those events were organized jointly with the Faculty of Geology of the University of Barcelona and the former Geological Institute of Catalonia.
It is worth mentioning that 2013 has also been the year of designing ICTJA 2014-2017 strategy (available at the www.ictja.csic.es site). The imminent launch in 2014 of Horizon 2020 and the recent launch of the National Plan for Scientific and Technological Research and Innovation together with the scarcity of funding at national level requires the necessity to define a research strategy for the coming years that maintains and moves forward ICTJA’s momentum and competitiveness at both national and international levels. This excercise has also served as the basis for the development not only ofICTJA-CSIC Action Plan 2014-2017 but for our active participation in the preparation of the scientific brochures of the Natural Resources CSIC Research Area. The strategy focusses on the mission and aims of the Institute and sets out ICTJA’s flagships with the aim to achieve scientific advancement while providing strong support of industrial and societal needs. ICTJA’s flagships are:
– Knowledge-driven Research– Applied Research– Responding to societal needs– Training and support of early career Researchers and Technicians
Last but not least, in the year 2013 the governing board of ICTJA approved the establishing of ICTJA-SPA Awards to the best oral and poster presentation. The aim is to help improving PhD presentations skills at EGU and AGU like conferences.
ANNUAL REPORT ICTJA 2013 5
ContentsICTJA at a glance.............................................................................................................................................................6
Our.Mission.......................................................................................................................................................................6
Our.Aims............................................................................................................................................................................7
ICTJA organization chart..............................................................................................................................................8
Service units and Labs.................................................................................................................................................10
Scientific.Services.......................................................................................................................................................... 12
labGEOTOP.Service............................................................................................................................................. 12
X-.Ray.Diffraction.Service.................................................................................................................................. 13
Paleomagnetism.Service.(CSIC-UB)............................................................................................................... 14
Research.Laboratories................................................................................................................................................... 16
Seismic.Laboratory.............................................................................................................................................. 16
Raman.Spectroscopy.and.Photoluminiscence.Laboratory........................................................................ 17
LARX.–.Laboratory.of.X-ray.Analytical.Applications.................................................................................. 18
U-Th.Geochronology.Laboratory.................................................................................................................... 20
Scientific.Boreholes.(Almera-1.&.2)................................................................................................................ 21
SIMGEO.(UB-CSIC)............................................................................................................................................22
Personnel........................................................................................................................................................................ 24
How to reach us............................................................................................................................................................ 25
ICTJA Research Groups.............................................................................................................................................. 26
Earth’s.structure.and.dynamics..................................................................................................................................27
Group.members....................................................................................................................................................27
Research.outline.................................................................................................................................................. 28
Publications.2013................................................................................................................................................ 29
Research.projects.2013.......................................................................................................................................32
Crystallography.and.Optical.properties.................................................................................................................. 34
Group.members................................................................................................................................................... 34
Research.outline.................................................................................................................................................. 34
Publications.2013.................................................................................................................................................35
Research.projects.2013.......................................................................................................................................35
Environmental.Changes.in.the.Geological.Record................................................................................................ 36
Group.members................................................................................................................................................... 36
Research.outline.................................................................................................................................................. 36
Publications.2013................................................................................................................................................ 38
Research.projects.2013....................................................................................................................................... 41
Geophysical.and.Geochemical.Modelling.of.Geohazards.Processes.and.Subsurface.Resources............ 42
Group.members................................................................................................................................................... 42
Research.outline.................................................................................................................................................. 42
Publications.2013................................................................................................................................................44
Research.projects.2013......................................................................................................................................46
ICTJA 10 highlighted papers....................................................................................................................................48
Theses, Seminars and Courses................................................................................................................................ 66
Editorial and Assessment activities...................................................................................................................... 69
International Committees and Collaboration.................................................................................................... 69
ICTJA-SPA Awards 2013............................................................................................................................................. 71
Outreach Activities......................................................................................................................................................73
ICTJA in numbers..........................................................................................................................................................76
6 ANNUAL REPORT ICTJA 2013
ICTJA at a glance
Our Mission
ICTJA.is.an.international.geosciences.research.institute.of.excellence.whose.mission.is.to.advance.the.understanding.of.Earth.System.Science..We.will.achieve.this.by.applying.advanced. (forefront). ex-perimental. and.analytical.methodologies.to.well-defined,.knowledge-driven.research.objectives..A.key.
part.of.our.mission.is.to.meet.industrial.and.societal.needs.through.knowledge.transfer.applied.to.geohazards.and.exploration.and.exploitation.of.geological.resources..Central.to.our.mission.is.quality.training.of.the.next.generation.of.Earth.Science.researchers.and.technicians.
ANNUAL REPORT ICTJA 2013 7
Our Aims
a).Identify.new.and.emerging,.high-priority.research.opportunities.
b).Enhance.our.training.capabilities.of.the.next.generation.of.Earth.scientists.
c). Increase. our. support. of. early. career.researchers.
d). Raise. our. level. of. international.collaboration.
e).Create.and.translate.breakthroughs.in.knowledge-driven.research.into.practical.applications. that. provide. the. knowledge.transfer.that.industry.and.society.seeks.
f).Advance.knowledge.and.understanding.within. and. across. the. different. fields. of.Earth.Sciences.
One. of. our. aims. is. to. define. a. research.strategy. for. the. period. 2014-2017.. The.imminent.launch.of.Horizon.2020.(H2020).and.the.recent.launch.of.the.National Plan for Scientific and Technological Research and Innovation. (PNIDI). include. both.fundamental. and. applied. science,. but.their. focus. are. squarely. on:. a). Societal.challenges,.b).Training.programs,.and.c).Infrastructures.
Furthermore,.the scarcity of funding.that.will.be.raised.at.a.national. level.requires.that. we. define. research strategies. for.the. coming. years. that. maintains. and.moves. forward. ICTJA’s. momentum. and.
competiveness. at. both. the. national. and.international.level..Significantly,.these.aims.must.intersect.both:
•.The.portfolio.of.ICTJA.research.interests.and.capacities.
•.The.portfolio.of.HORIZON.2020;.PNIDI,.and.industry.interests.
The ICTJA at a glance
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Service Units
Management and General Services
The. Management. and. General. Services.depend.directly.on.the.Institute’s.Manager.and.provide.service.to.all.research.groups;.services.and. labs.. In. particular,. the. Management.Service.performs.the.following.tasks:
•.Human. resources.. Management. of.fixed.personnel,.contract.personnel.and.trainees:.taking.up.their.posts,.contracts,.grants,.end.of.contract,.reporting.joiners.and.leavers.to.the.Social.Security.system,.rounds.of.Social.Action.funding,.handling.the.paperwork.for.occupational.accidents,.residency.permits,.managing.and.moni-toring. holidays,. temporary. incapacity,.medical.check-ups,.insurance,.etc.
Service units and Labs
•..Project.management..This.includes.applying.for,.monitoring.and.financial.management.of.national.and.international.projects,.both.public.(based.on.a.competitive.basis).and.private.(mainly.contracts.and.agreements.with.Foundations.and.Industry).
•..Purchasing.and.procurement..This.includes.administrative.procurements.–.purchase.of.supplies,. technical. consultancy. contracts,.service.and.works.contracts,.and.maintenance.–.buildings,.special.infrastructures,.technical.services,.vehicles.
The. General. Services. are. responsible. for.maintenance.of.electrical.and.mechanical.installations. and. devices,. porter,. mailing,.and.cleaning.
ManagerJosé Luis López Burguillo
Administrative supportMaría Consuelo PalacioEsmeralda RodríguezFrancisco MosqueraLeonor FernándezElisa Zamorano
MaintenanceÓscar ÁvilaMiquel Ángel GonzálezDimas Calvo (INEM contract)
Call centerXavier PascualAlejandro Tatevosian
LibraryDolores Fernández
ANNUAL REPORT ICTJA 2013 11
Staff Joan Benavent, Technical staff (CSIC)Marc Español, CSIC-Contract
Service units and Labs
Computing and Communications Service
The. main. objective. of. this. service. is. to.facilitate.the.communication.and.computing.tools.and.basic.and.advanced.services.to.allow.researchers.of.ICTJA.to.achieve.their.scientific. objectives.. The. unit. manages. a.network. infrastructure. compose. of. about.150.medium.size.computers,.a.wifi.spread.throughout. the. building,. some. server-oriented.computing,.storage.and.connectivity.with. the. Scientifc. Ring/RedIris/Geant2..ICTJA.facilitates.the.access.to.5.CSIC.research.institutes.(CID,.IBB,.CEAB,.IBMB.and.IIBB).to.the.Scientific.Ring."Anella.Científica"..The.Institute.also.collaborates.with.the.Barcelona.Supercomputing. Center. through. the. IBM.Marenostrum.Supercomputer.
Library
The.Library.of.Geology.(UB-CSIC),.housed.in.the.Faculty.of.Geology,.is.jointly.managed.by.the.Faculty.of.Geology.of.the.University.of.Barcelona.(UB).and.the.Institute.of.Earth.Sciences. Jaume. Almera. (ICTJA-CSIC)..Founded.in.1966,.aims.at.the.dissemination.of. journal. articles,. books,. maps,. etc.. in.the.broad.field.of.the.Earth.Sciences..The.publication.of.the.journal.Geological.Acta.is.also.managed.through.this.service.
Library Service
This.library.is.one.of.the.most.important.geology.libraries.in.Spain.in.terms.of.repository.of.journals.and.books.and.quality.of.service..Books.may.be.consulted.via.the.computerized.catalogues.of.
the.CSIC.and.UB,.including.Internet..The.library.has.16,500.volumes.and.1054.journals.(700.are.received.regularly),.15,000.maps.and.20,000.aerial. photographs. in. addition. to. the. major.bibliographic.databases.(GEOREF,.PASCAL,.SCI,.Current.Contents,.CINDOC,.and.bibliography.of.the.geology.of.Spain).Biblioteca.(ICTJA):.http://www.ictja..csic.es/gt/biblio/almerahome.htmlWeb. Biblioteca.(UB):.http://www.bib.ub.edu/.biblioteques/geologia/
Publication of Geologica Acta
It.is.an.international.journal.of.Earth.Science.providing.an.innovative.and.high.quality.media.of.scientific.dissemination..Geologica.Acta.aims.to.stimulate.rapid.diffusion.of. results.and.efficient.exchange.of. ideas.among.the.widespread. communities. of. Earth. Science.researchers. (with. special. emphasis. on.Latin-American,.the.Caribbean,.Europe,.and.the.Mediterranean.regions)..The.Journal. is.edited. in. collaboration. with. the. University.of.Barcelona..Since.2007,.Geologica.Acta.is.included.in.the.Journal.Citation.Report.of.ISI.Thomson.with.an.Impact.Factor.(IF).of.1.262.in.2012.and.a.5.year.IF.of.1.653.Web.Geologica.Acta:.http://www.geologica-acta.com/
BIGPI Database
The.library.is.currently.compiling.a.data-base.on.Bibliography.of.Earth.Sciences.of.the.Iberian.Peninsula.(BIGPI):.it.consists.of.a.database.of.articles,.lectures,.books,.theses,.etc..on.any.aspect.of.the.geology.of.the.Iberian.Peninsula.with. references. to.Geology,.Geochemistry,.Geophysics,. Mineralogy,. Geomorphology,.Natural.Disasters,.Palaeontology,.Environment,.Soil.Science,.etc.Web.BIGPI:.http://www.bib.ub.edu/fileadmin/bigpi/bigpi.htm
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Scientific Services.
labGEOTOP Service
The labGEOTOP Service,. Laboratory. of.Elemental. and. Isotopic. Geochemistry. for.Petrological. Applications,. carry. out. multi-disciplinary.research.in.Solid.Earth.Sciences.using. an. established. core. of. world. class.equipment. and. laboratories,. and. expertise.in.the.technical.and.applied.aspects.of.their.use..The.service.plays.a.key.role.in.catalysing.leading.edge.cross-disciplinary.research.within.the.CSIC.and.into.Spain.
The.labGEOTOP.Service.provides.a.central.mass.of.equipment.that.enables.significant.scientific.collaboration.on.a.regional,.national.and. international. scale.. We. undertake. a.wide.variety.of.analytical.work.for.scientific.institutions.and.industry..The.labGEOTOP.offer.elemental.and.isotopic.analysis.of.solids.and.liquids.covering.the.range.of.elements.determined.by.high.resolution-inductively.coupled.plasma-mass.spectrometry.
The service focuses on the analytical needs of R&D projects on:
•..Compositional.structure.and.evolution.of.Earth’s.mantle:.mantle.geochemistry.mainly.through.the.open.window.of.the.volcanic.rocks;.origin.of.mantle.plumes.
•..Compositional.structure.and.evolution.of.the.lithosphere:.geochemical.processes.at.the.margins.of.tectonic.plates.
•..Geochemical.evolution.of.magmatic.and.metamorphic.processes.
•..Sedimentary. geology. and. paleoclimate.reconstruction:.geochronology.and.processes.related.to.climate.change.
•..Volcanism:. temporal.evolution.of.pre-.and.syn-eruptive.magmatic.processes:.geochemical. flows. related. to. volcanic.activity.
•..Experimental.petrology.and.mineralogy.
The. analytical. services. provided. by. the.labGEOTOP.go.beyond.ICTJA.needs.and.represent.a.significant.breakthrough.in.the.analytical.services.required.by.the.Spanish.and. international. scientific. community.on. element. and. isotope. geochemistry.for. process. modelling. in. both. whole.rock. and. high. resolution. single. mineral.analysis..The.labGEOTOP.is.a.Project.co-financed. by. ERDF. through. the. Scientific.and.Technological.Infrastructure.National.Program.in.the.National.Plan.for.Scientific.Research,.Development.and.Technological.Innovation.(R&D).of.the.Ministry.of.Science.and.Innovation.(CSIC08-4E-001).
Service units and Labs
Staff
José-Luis Fernandez-Turiel, Scientific DirectorMarta Rejas, Technical DirectorJonathan Cotano, CSIC-contract
ANNUAL REPORT ICTJA 2013 13
Service units and Labs
X- Ray Diffraction Service
The. X-ray. Diffraction. Service. of. ICTJA-CSIC.is.an.analytical.facility.focused.on.the.qualitative.and.quantitative.characterization.of.the.crystalline.phases.of.materials..The.XRD.Service,.with.more.than.30.years.of.experience. in. the.field,.offers.support. to.ICTJA. researchers. and. also. to. external.users.from.public.and.private.universities.and.companies.
One. of. the. main. objectives. of. the. XRD.Service. at. ICTJA. is. to. support. the.ongoing. investigations. carried. out. by.ICTJA. researchers. on. Earth. Sciences.topics,. including. studies. of. volcanology,.petrology. and. sedimentology.. The. XRD.Service. offers. also. support. to. external.researchers.working.in.geology,.materials.science,.environment,.chemistry,.pharmacy,.archaeology,. etc.. A. large. number. of.companies. and. organizations. from. the.
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Service units and Labs
public.or.private.sectors.make.use.of.the.XRD.Service.at. ICTJA.for.their. industrial.applications,.quality.control,.environmental.studies,.forensics,.etc.
Range of services offered:
•.Identification.of.crystalline.phases
•.Crystal-quality.assessment,.composition.determination.and.microstructural.analyses
•..Semi-quantitative.and.quantitative.analysis.of. crystalline. phases. and. amorphous.content
•.Application.of.the.Rietveld.method.for.profile.adjustment,.structure.refinement.and.quantitative.phase.analyses
•.Investigation.of.small.or.inhomogeneous.samples.with.micro-diffraction
Staff
Jordi Ibañez, Scientific DirectorJosep Elvira, Technical DirectorMaría Soledad Alvarez, Technical Staff
•.Determination.of.crystalline.structures
•.Non-destructive. X-ray. fluorescence.analyses. with. a. handheld. spectrometer.for.field.work.and.cultural.heritage.studies
Some examples of applications provided by the laboratory to research groups and companies:
•.Phase.identification.and.quantification.of.geological.samples..Identification.and.analysis.of.clay.minerals
•.Analysis.of.mineral.phases.in.building.materials:.cement,.concrete,.aggregates,.etc..Study.of.degraded.calcium.aluminate.cements,.identification.of.fiber.cements,.etc.
•.Determination.of.the.amorphous.content.in.ashes.and.synthetic.mixtures
•.Study.of.corrosion.products
•.Determination. of. crystalline. silica. in.respirable.airborne.dusts.by.direct-on-filter.methods
ANNUAL REPORT ICTJA 2013 15
Paleomagnetism Service (CSIC-UB)
The.Paleomagnetic.Laboratory.was.founded.in.1989.as.result.of.an.agreement.between.the. CSIC. and. the. Catalonian. Geological.Service. of. the. Generalitat. de. Catalunya..Since.1998,.the.laboratory.depends.on.the.CCiT-University.of.Barcelona.and.the.CSIC.
The.laboratory.provides.technical.support.to.research.groups.working.on.several.research.topics. within. the. Earth. Sciences,. among.them:
•.Magnetostratigraphic.dating.of.sedimentary.sequences.and.correlation.with.their.fossil.and.paleoenvironmental.record.
•.Archaeomagnetic.dating.of.archaeological.remains.
•.Paleomagnetism.applied.to.the.study.of.orogenic.belts.and.plate.tectonics.
•.Environmental.magnetic.studies.aimed.to.unravelling.paleoenvironmental.and.climatic. variations. in. the. sedimentary.record.
Staff
Elisabet Beamud, Technical Director (UB)Ana Gómez, Technical StaffYlenia Almar, CSIC-Contract
Service units and Labs
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Research Laboratories
Seismic Laboratory
ICTJA.Seismic.Facility.is.composed.by.two.main.sections,.the.Data.Acquisition.Instrumentation.Pool.and.the.Seismic.Processing.Center.
The.Data.Acquisition.Instrumentation.Pool.includes.seismic.equipment.intended.to.be.used. in. temporary. deployments.. Broad-band.and.short.period.seismic.acquisition.systems.are.available.to.allow.managing.both.short-term.active.seismic.profiling.and.long-term. passive. seismic. deployments..The. Seismic. Processing. Center. includes.up. to. 10. Linux. work. stations. with.dedicated.processing.software.as.well.as.computational.libraries.Seismic.processing.software.as.well.as.computational.libraries.is.equipped.with.three.main.servers.and.up.to.18.Tbytes.of.disk.space..The.lab.also.
features. connectivity. with. the. Barcelona.Supercomputing. Center. that. hosts. one.of. the. largest. computers. in. Europe. the.Marenostrum.. Furthermore,. the. lab. also.has. research. relationships. with. other.computation,.processing,.interpretation.and.modelling.facilities.such.as.GEO¬MODELS.(University.of.Barcelona).and.the.Barcelona.Center.for.Subsurface.Imaging.
Service units and Labs
Staff
Josep Gallart, Scientific DirectorMario Ruíz, Technical Staff
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Raman Spectroscopy and Photoluminiscence Laboratory
The.Laboratory.of.Raman.Spectrocopy.and.Photoluminescence.is.focused.on.the.study.of.the.optical.properties.of.semiconductor.materials..Among.others,. the. lab.carries.out.Raman.scattering.studies.on.a.variety.
Staff
Lluís Artús, Scientific DirectorRamon Cuscó, Research ScientistJordi Ibañez, Research Scientist
of.III-V.compound.systems.such.as.GaN,.InN,. InGaN,. InAs/GaAs,. InGaAs,. InP,.AlGaSb,. InAsSb,. GaSb,. GaAsN,. as. well.as.on.ZnO,.a.II-VI.wide.band.gap.material.which. is. intensively. being. investigated.because. of. its. potential. applications. in.transparent. electronics. and. in. blue. and.UV.light.emitters.
Service units and Labs
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Service units and Labs
LARX – Laboratory of X-ray Analytical Applications
The.LARX.research.laboratory,.created.in.1994,.is.an.excellence’s.research.facility.of.ICTJA..The.activities.of.LARX.are.focused.on. the. development. of. methodologies.for.the.study.of.solid.matter.using.X-ray.spectroscopies.such.as.X-ray.fluorescence.(WDXRF,. EDXRF,. TRXRF. and. micro-EDXRF),.X-ray.diffraction.(XRD).and.other.solid-state. non-invasive. analytical. tools..Likewise,.LARX.staff.is.leading.collaborative.research.projects.related.to.Environmental.Geosciences.and.Geochemistry.
Since.its.creation,.the.laboratory.has.also.undertaken. many. teaching. and. training.activities.at.national.and.international.level,.in.collaboration.with.the.European.X-ray.Spectrometry. Association. (EXSA),. the.International.Atomic.Energy.Agency.(IAEA).and.X-ray.instrumentation.manufacturing.
companies..During.last.decade,.and.within.this.initiative.have.taken.several.doctoral.and.master.thesis.in.the.fields.of.environmental.pollution.and.cultural.heritage.materials.
At.now,.LARX.is.a.joint.associated.laboratory.with.the.Analytical.Chemistry.Department.of.the.University.of.Girona.(Spain).and.the.Hydrogeochemistry.Group.of.the.Institute.of.Environmental.Assessment.and.Water.Research.(IDAEA-CSIC).
The.instrumentation.of.this.infrastructure.allows. the. determination. of. major,. trace.and.ultratrace.elements.in.solids.(minerals,.rocks,.particulate.matter,.filters,.industrial.wastes,.etc.),.including.chemical.mapping.and.microprobe.analysis,. layer.thickness.determination. at. nanometre. scale. and.chemical.speciation.
Through.research.collaborative.agreements.the.laboratory.provides.technical.support.for.research.groups.working.on:
•.Cultural.Heritage.materials.and.artworks,.especially. studies. of. paint. pigments,.old. coinage. and. metallic. artefacts,.manuscripts.and.wall.paint.materials.
•.Environmental. geochemistry. of. soil,.water.and.vegetation,.including.biogeo-chemical.modelling.
•.Forensic.research.related.to.the.use.of.inorganic.chemistry.data.
Staff
Ignasi Queralt, Scientific Director
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U-Th Geochronology Laboratory
The.Laboratory.of.Geochronology.was.founded.in.1989.and.fully.updated.in.2010.with.the.acquisition.of.two.8-channel.ORTEC.alpha.spectrometers..The.laboratory.is.specially.designed.for.dating.marine.and.continental.carbonates.such.as.travertines,.speleothems,.endogenic. lacustrine. carbonates,. corals.and.marine.crusts,.although.it.is.possible.to.date.primary.sulphates.(gypsum).and.chlorides.(halite).using.the.uranium.series.desequilibrium.method.(230Th/234U).
Service units and Labs
Staff
Santiago Giralt, Scientific DirectorGraciela Monzon, Technical Director
The.laboratory.provides.technical.support.for.research.groups.working.on:
•. Absolute. dating. of. upper. Pleistocene.and. Holocene. continental. and. marine.carbonate. samples. for. a. large. variety.of.purposes.such.as.climate,.anthropic,.geologic. and/or. environmental.reconstructions.
•. Absolute. dating. of. human. and. other.archaeological.carbonate.prehistorical.rests.
ANNUAL REPORT ICTJA 2013 21
Scientific Boreholes (Almera-1 & 2)
Two.scientific.boreholes.were.drilled.in.2012.in.the.UB.campus.of.Barcelona.as.part.of.the.subsurface.research.studies.of.the.Institute.of.Earth.Sciences.Jaume.Almera.(ICTJA).in.cooperation.with.the.Faculty.of.Geology.of.the.University.of.Barcelona.(UB).
The.Almera-1.borehole.is.214.20.m.deep.and. is. used. as. an. experimental. facility.for.the.development.of.geophysical.data.logging.methods..The.hole.Almera-2.is.1.m.away.from.Almera-1,.reaching.a.depth.of.46.m,.and.is.meant.to.carry.out.routine.piezometric.measurements.and.cross.hole.experiments.
A. subsurface. connection. for. cables. and.tools. with. the. borehole. and. monitoring.research.lab.inside.ICTJA.building.facilitate.long.term.and.continuous.monitoring.and.control.from.the.lab..This.facility.is.equipped.with. a. complete. system. of. geophysical.logging.tools.and.borehole.monitoring.data.loggers. that. are. used. for. testing. of. new.devices.and.experiments. in.the.frame.of.ongoing.research.projects.
Service units and Labs
Staff
M. José Jurado, Scientific Director José Crespo, CSIC-JAE TechnicianCarlos Viñolo, CSIC-contractFrancesc Castelltort, CSIC-contract
22 ANNUAL REPORT ICTJA 2013
SIMGEO (UB-CSIC)
The. Laboratory. of. Geological. Processes.Simulation.(SIMGEO).was.created.in.1995.as.a.joint.venture.between.the.Faculty.of.Geology.of.the.University.of.Barcelona.(UB).and.the.Institute.of.Earth.Sciences.Jaume.Almera.(ICTJA).in.the.field.of.experimental.and. theoretical. modelling. of. geological.processes.
SIMGEO. seeks. to. promote. application.of. experimental. and. theoretical. models.to.the.study.of.geological.processes.and,.
Service units and Labs
Staff
Joan Martí, Scientific co-Director (CSIC)Ferran Colombo, Scientific co-Director (UB)
in.particular,.processes.that.involve.a.risk.to. people. and. the. environment,. through.funding.raised.by.public.and.private.research.projects.and.contracts.and.agreements.
SIMGEO.offers.researchers.a.large.space.and. equipment. to. design. and. develop.experimental.models..The.SIMGEO.has.a.laboratory.of.experimental.petrology.and.mineral.synthesis,.a.hydraulic.channel.16.m. length. and. a. computer. lab. equipped.with. the. necessary. software. to. develop.mathematical.models.and.simulations.using.geographic.information.systems.
24 ANNUAL REPORT ICTJA 2013
Personnel
INEM Contract 1
Researchers Permanent Staff 27
Administration Permanent Staff 6
Services Permanent Staff 5
Technicians Permanent Staff 6
INEM Contract - 1Researchers Permanent Staff - 27Administration Permanent Staff - 6Services Permanent Staff - 5Technicians Permanent Staff - 6Post-doc Researchers - 13PhD Researchers - 16IGME Visiting Scientists - 2Contracted Technicians - 17
1
27
6
5
613
16
2
17
INEM Contract - 1Researchers Permanent Staff - 27Administration Permanent Staff - 6Services Permanent Staff - 5Technicians Permanent Staff - 6Post-doc Researchers - 13PhD Researchers - 16IGME Visiting Scientists - 2Contracted Technicians - 17
1
27
6
5
613
16
2
17
Post-doc Researchers 13
PhD Researchers 16
IGME Visiting Scientists 2
Contracted Technicians 17
INEM Contract - 1Researchers Permanent Staff - 27Administration Permanent Staff - 6Services Permanent Staff - 5Technicians Permanent Staff - 6Post-doc Researchers - 13PhD Researchers - 16IGME Visiting Scientists - 2Contracted Technicians - 17
1
27
6
5
613
16
2
17
TOTAL 93
ANNUAL REPORT ICTJA 2013 25
How to reach us
The. Institute. of. Earth. Sciences. Jaume.Almera.(ICTJA).is.located.at.the.Pedralbes.Campus.of.the.University.of.Barcelona.
Lluís Solé i Sabaris s/n08028 Barcelona (Spain)Phone: +34 934095410Fax: +34 934110012
Carrer Pau Gargallo
Carrer Menéndez y Pelayo
Carrer Martí i Franquès
Av. Diagonal
Carrer Solé i Sabaris
Campus UB
Facultat de Química
Facultat de Biologia
Facultat de Geologia
PALAU REIAL
645
643L97-101
7-33-67-75-L14-L79-L97
7-33-67-75-113L14-L79-H6
L3
L3
ICTJA
26 ANNUAL REPORT ICTJA 2013
ICTJA Research Groups
• Earth’s structure and dynamics• Crystallography and Optical properties• Environmental Changes in the Geological Record• Geophysical and Geochemical Modelling of Geohazards
Processes and Subsurface Resources
ANNUAL REPORT ICTJA 2013 27
Group members
Earth’s structure and dynamics
Andrés Perez-Estaún, Research ProfessorManel Fernández, Research ProfessorRamón Carbonell, Research ProfessorDennis Brown, Senior Research ScientistJaume Vergés, Senior Research ScientistJoaquina Alvarez-Marrón, Senior Research ScientistJordi Díaz, Senior Research ScientistMontserrat Torne, Senior Research ScientistAntonio Villaseñor, Research ScientistDaniel García-Castellanos, Research ScientistIvonne Jiménez, Research ScientistMartin Schimmel, Research ScientistContxi Ayala, IGME Visiting Research ScientistEduard Saura, CSIC-JAE post-docAlexandra Robert, CSIC contract post-docArantzazu Ugalde, CSIC contract post-docCharlotte Fillon, CSIC contract post-doc
David Martí, CSIC contract post-docEmilio Casciello, CSIC contract post-docIgnacio Marzan, CSIC contract post-docJuan Diego Martin, CSIC contract post-docJan Globig, Marie Curie pre-docSiddique Akhtar, Marie Curie pre-docAlba Gil, FPI pre-docLavinia Tunini, FPI pre-docAlberto Carballo, JAE pre-docGiovanni Cammani, JAE pre-docBeatriz Gaite, CSIC contractDaniel Vázquez, CSIC contractIsrael Cruz, CSIC contractMar Moragas, CSIC contractMarcel Cembrowski, CSIC contractSofia Casquero, CSIC contractVinyet Baqués, CSIC contract
ICTJA Research Groups
Josep Gallart,.Group Leader - Research Professor
28 ANNUAL REPORT ICTJA 2013
Research outline
The.multidisciplinary.research.investigates.the. structure. and. dynamic. processes. of.the. Earth’s. interior.. The. main. objective.is.to.understand.how.the.Earth.works.at.different. scales. through. the. integration.of.a.wide.range.of.different.datasets.and.methodologies,.including.Geophysics.and.Geology,. Numerical. Modeling,. Geodesy,.and.Geochemistry.
ICTJA Research Groups
The.acquisition.of.high.resolution.seismic,.potential. field. data. and. surface. geology.is. combined. with. numerical. models. to.achieve.an.integrate.approach.to.basic.and.applied.research.in.Earth.Sciences..Related.projects.to.industry.include.applications.for.hydrocarbon. exploration,. waste. disposal.and.geological.storage.of.greenhouse.gas.emissions.(CO
2).
ANNUAL REPORT ICTJA 2013 29
é
Publications 2013
Alcalde, J.,.D. Martí,.A. Calahorrano,.I. Marzan,.P. Ayarza,.R. Carbonell,.C. Juhlin,.and.A. Pérez-Estaún.(2013),.Active.seismic.characterization.experiments.of.the.Hontomín.research.facility.for.geological.storage.of.CO2,.Spain,.International.Journal.of.Greenhouse.Gas.Control,.19,.785-795,.doi:.10.1016/j.ijggc.2013.01.039.
Aucelli, P. P. C.,.E. Casciello,.M. Cesarano,.S. Perriello Zampelli,.and.C. M. Rosskopf.(2013),.A.deep,.stratigraphically.and.structurally.controlled.landslide:.The.case.of.Mount.La.Civita.(Molise,.Italy),.Landslides,.10(5),.645-656,.doi:.10.1007/s10346-012-0351-7.
Bécel, A.,.J. Diaz,.M. Laigle,.and.A. Hirn.(2013),.Searching.for.unconventional.seismic.signals.on.a.subduction.zone.with.a.submerged.forearc:.OBS.offshore.the.Lesser.Antilles,.Tectonophysics,.603,.21-31,.doi:.10.1016/j.tecto.2012.10.031.
Bezada, M. J.,.E. D. Humphreys,.D. R. Toomey,.M. Harnafi,.J. M. Dávila,.and.J. Gallart.(2013),.Evidence.for.slab.rollback.in.westernmost.Mediterranean.from.improved.upper.mantle.imaging,.Earth.and.Planetary.Science.Letters,.368,.51-60,.doi:.10.1016/j.epsl.2013.02.024.
Bonatto, L.,.M. Schimmel,.J. Gallart,.and.J. Morales.(2013),.Studying.the.410-km.and.660-km.discontinuities.beneath.spain.and.morocco.through.detection.of.p-to-s.conversions,.Geophysical.Journal.International,.194(2),.920-935,.doi:.10.1093/gji/ggt129.
Calvet, M.,.M. Sylvander,.L. Margerin,.and.A. Villaseñor.(2013),.Spatial.variations.of.seismic.attenuation.and.heterogeneity.in.the.Pyrenees:.Coda.Q.and.peak.delay.time.analysis,.Tectonophysics,.608,.428-439,.doi:.10.1016/j.tecto.2013.08.045.
Carbonell, R.,.A. Levander,.and.R. Kind.(2013),.The.Mohorovicic.discontinuity.beneath.the.continental.crust:.An.overview.of.seismic.constraints,.Tectonophysics,.609,.353-376,.doi:.10.1016/j.tecto.2013.08.037.
Casciello, E.,.P. Esestime,.M. Cesarano,.G. Pappone,.M. Snidero,.and.J..Vergés.(2013),.Lower.plate.geometry.controlling.the.development.of.a.thrust-top.basin:.The.tectonosedimentary.evolution.of.the.ofanto.basin.(Southern.Apennines),.Journal.of.the.Geological.Society,.170(1),.147-158,.doi:.10.1144/jgs2011-066.
Díaz, J.,.A. Gil,.and.J. Gallart.(2013),.Uppermost.mantle.seismic.velocity.and.anisotropy.in.the.euro-mediterranean.region.from.pn.and.sn.tomography,.Geophysical.Journal.International,.192(1),.310-325,.doi:.10.1093/gji/ggs016.
Escuder-Viruete, J.,.and.A. Pérez-Estaún.(2013),.Contrasting.exhumation.P-T.paths.followed.by. high-P. rocks. in. the. northern. Caribbean. subduction-accretionary. complex:. Insights.from.the.structural.geology,.microtextures.and.equilibrium.assemblage.diagrams,.Lithos,.160-161(1),.117-144,.doi:.10.1016/j.lithos.2012.11.028.
Escuder-Viruete, J.,.P. Valverde-Vaquero,.Y. Rojas-Agramonte,.J. Jabites,.and.A. Pérez-Estaún.(2013),.From.intra-oceanic.subduction.to.arc.accretion.and.arc-continent.collision:.
ICTJA Research Groups
30 ANNUAL REPORT ICTJA 2013
Insights.from.the.structural.evolution.of.the.Río.San.Juan.metamorphic.complex,.northern.Hispaniola,.Journal.of.Structural.Geology,.46,.34-56,.doi:.10.1016/j.jsg.2012.10.008.
Escuder-Viruete, J.,.P. Valverde-Vaquero,.Y. Rojas-Agramonte,.J. Gabites,.M. Castillo-Carrión,.and.A. Pérez-Estaún.(2013),.Timing.of.deformational.events.in.the.Río.San.Juan.complex:.Implications.for.the.tectonic.controls.on.the.exhumation.of.high-P.rocks.in.the.northern.Caribbean.subduction-accretionary.prism,.Lithos,.177,.416-435,.doi:.10.1016/j.lithos.2013.07.006.
Evain, M.,. A. Galve,. P. Charvis,. M. Laigle,. H. Kopp,. A. Bécel,. W. Weinzierl,. A. Hirn,.E. R. Flueh,.and.J. Gallart.(2013),.Structure.of.the.Lesser.Antilles.subduction.forearc.and.backstop.from.3D.seismic.refraction.tomography,.Tectonophysics,.603,.55-67,.doi:.10.1016/j.tecto.2011.09.021.
Fichtner, A.,.J. Trampert,.P. Cupillard,.E. Saygin,.T. Taymaz,.Y. Capdeville,.and.A. Villaseñor.(2013),.Multiscale.full.waveform.inversion,.Geophysical.Journal.International,.194(1),.534-556,.doi:.10.1093/gji/ggt118.
Grobe, R. W.,.J. Alvarez-Marrón,.U. A. Glasmacher,.and.F. M. Stuart.(2013),.Mesozoic.exhumation.history.and.palaeolandscape.of.the.Iberian.Massif. in.eastern.Galicia.from.apatite.fission-track.and.(U+Th)/He.data,.International.Journal.of.Earth.Sciences,.1-23,.doi:.10.1007/s00531-013-0976-3.
Gualtieri, L., E. Stutzmann,.Y. Capdeville,.F. Ardhuin,.M. Schimmel,.A. Mangeney,.and.A. Morelli.(2013),.Modelling.secondary.microseismic.noise.by.normal.mode.summation,.Geophysical.Journal.International,.193(3),.1732-1745,.doi:.10.1093/gji/ggt090.
Laigle, M.,.et.al..(2013),.Seismic.structure.and.activity.of.the.north-central.Lesser.Antilles.subduction. zone. from. an. integrated. approach:. Similarities. with. the. Tohoku. forearc,.Tectonophysics,.603,.1-20,.doi:.10.1016/j.tecto.2013.05.043.
Martín-Martín, J. D.,.et.al..(2013),.The.Upper.Aptian.to.Lower.Albian.syn-rift.carbonate.succession.of.the.southern.Maestrat.Basin.(Spain):.Facies.architecture.and.fault-controlled.stratabound.dolostones,.Cretaceous.Research,.41,.217-236,.doi:.10.1016/j.cretres.2012.12.008.
Messager, G.,.B. Nivière,.P. Lacan,.Y. Hervouët,.and.J. P. Xavier.(2013),.Plio-Quaternary.thin-skinned.tectonics.along.the.crustal.front.flexure.of.the.southern.Central.Andes:.a.record.of.the.regional.stress.regime.or.of.local.tectonic-driven.gravitational.processes?,.International.Journal.of.Earth.Sciences,.1-23,.doi:.10.1007/s00531-013-0983-4.
Moragas, M.,.C. Martínez,.V. Baqués,.E. Playà,.A. Travé,.G. Alías,.and.I. Cantarero.(2013),.Diagenetic.evolution.of.a.fractured.evaporite.deposit.(Vilobí.Gypsum.Unit,.Miocene,.NE.Spain),.Geofluids,.13(2),.180-193,.doi:.10.1111/gfl.12017.
Nivière, B.,.G. Messager,.S. Carretier,.and.P. Lacan.(2013),.Geomorphic.expression.of.the.southern.Central.Andes.forebulge.(37°S,.Argentina),.Terra.Nova,.25(5),.361-367,.doi:.10.1111/ter.12044.
ICTJA Research Groups
ANNUAL REPORT ICTJA 2013 31
ICTJA Research Groups
Obrebski, M.,.F. Ardhuin,.E. Stutzmann,.and.M. Schimmel.(2013),.Detection.of.microseismic.compressional.(P).body.waves.aided.by.numerical.modeling.of.oceanic.noise.sources,.Journal.of.Geophysical.Research.B:.Solid.Earth,.118(8),.4312-4324,.doi:.10.1002/jgrb.50233.
Replumaz, A.,.S. Guillot,.A. Villaseñor,.and.A. M. Negredo.(2013),.Amount.of.Asian.lithospheric.mantle.subducted.during.the.India/Asia.collision,.Gondwana.Research,.24(3-4),.936-945,.doi:.10.1016/j.gr.2012.07.019.
Ruiz, M.,.et.al..(2013),.Seismic.activity.offshore.Martinique.and.Dominica.islands.(Central.Lesser.Antilles.subduction.zone).from.temporary.onshore.and.offshore.seismic.networks,.Tectonophysics,.603,.68-78,.doi:.10.1016/j.tecto.2011.08.006.
Rushlow, C. R.,.J. B. Barnes,.T. A. Ehlers,.and.J. Vergés.(2013),.Exhumation.of.the.southern.Pyrenean.fold-thrust.belt.(Spain).from.orogenic.growth.to.decay,.Tectonics,.32(4),.843-860,.doi:.10.1002/tect.20030.
Saura, E.,.J. C. Embry,.J. Vergés,.D. W. Hunt,.E. Casciello,.and.S. Homke.(2013),.Growth.fold.controls.on.carbonate.distribution.in.mixed.foreland.basins:.Insights.from.the.Amiran.foreland.basin.(NW.Zagros,.Iran).and.stratigraphic.numerical.modelling,.Basin.Research,.25(2),.149-171,.doi:.10.1111/j.1365-2117.2012.00552.x.
Sergeant A., Stutzmann E., Maggi A., Schimmel M., Ardhuin F., Obrebski M., Frequency-dependent. noise. sources. in. the. North. Atlantic. Ocean,. Geochemestry,. Geophysics,.Geosystems,.14,.doi:10.1002/2013GC004905,.2013.
Silveira, G.,.N. Afonso Dias,.and.A. Villaseñor.(2013),..Seismic.imaging.of.the.western.Iberian.crust.using.ambient.noise:.Boundaries.and.internal.structure.of.the.Iberian.Massif,.Tectonophysics,.589,.186-194,.doi:.10.1016/j.tecto.2012.12.025.
Simancas, J. F.,.P. Ayarza,.A. Azor,.R. Carbonell,.D. Martínez Poyatos,.A. Pérez-Estaún,.and.F. González Lodeiro. (2013),.A.seismic.geotraverse.across.the. Iberian.Variscides:.Orogenic.shortening,.collisional.magmatism,.and.orocline.development,.Tectonics,.32(3),.417-432,.doi:.10.1002/tect.20035.
Ugalde, A..(2013),.S-wave.envelope.broadening.characteristics.of.microearthquakes.in.the.Canary.Islands,.Journal.of.Seismology,.17(2),.771-782,.doi:.10.1007/s10950-012-9353-0.
Ugalde, A.,.A. Villaseñor,.B. Gaite,.S. Casquero,.D. Martí,.A. Calahorrano,.I. Marzán,.R. Carbonell,.and.A. P. Estaún.(2013),.Passive.seismic.monitoring.of.an.experimental.CO2.geological.storage.site. in.Hontomín.(Northern.Spain),.Seismological.Research.Letters,.84(1),.75-84,.doi:.10.1785/0220110137.
Valera, J. L.,.A. M. Negredo,.M. I. Billen,.and.I. Jiménez-Munt.(2013),.Lateral.migration.of.a.foundering.high-density.root:.Insights.from.numerical.modeling.applied.to.the.southern.Sierra.Nevada,.Lithos,.doi:.10.1016/j.lithos.2013.08.021.
Zlotnik, S.,. I. Jiménez-Munt,.and.M. Fernàndez. (2013),.Coupled.mantle.dripping.and.lateral.dragging.controlling.the.lithosphere.structure.of.the.NW-Moroccan.margin.and.the.Atlas.Mountains:.A.numerical.experiment,.Lithos,.doi:.10.1016/j.lithos.2013.10.016.
32 ANNUAL REPORT ICTJA 2013
ICTJA Research Groups
National Funding Agencies
Project Title: ALCUDIA WA–Propiedades físicas de la litosfera en la Zona Centro Ibérica (Península Ibérica)Financed by: PNIDI-CGL.-.CGL2010-17280Years:.2011-2013PI:.R..Carbonell
Project Title: ATIZA – Caracterización del manto litosferico debajo de la cadena orogénica alpina a partir de métodos numéricosFinanced by: PNIDI-CGL.-.CGL2009-09662Years:.2010-2013PI:.I..Jimenez.Munt
Project Title: PROTAI – Procesos de colisión Arco-Continente en TaiwanFinanced by: PNIDI-CGL.-.CGL2009-11843Years:.2010-2013PI:.D..Brown
Research projects 2013
Project Title: RIFSIS – Estructura sísmica de la corteza bajo la cordillera del RifFinanced by: PNIDI-CGL.-.CGL2009-09727Years:.2010-2013PI:.J..Gallart
Project Title: TECLA – Interacción entre la tectónica y el clima árido de sistemas orogeno-CuencaFinanced by: PNIDI-CGL.-.CGL2011-26670Years:.2012-2014PI:.D..García-Castellanos
Project Title: TOPOIBERIA – Geociencias en Iberia: estudios integrados de topografía y evolución 4DFinanced by: PNIDI-CONSOLIDER.-.CSD2006-00041Years:.2006-2013PI:.J..Gallart
ANNUAL REPORT ICTJA 2013 33
ICTJA Research Groups
International Funding Agencies
Project Title: EPOS – European Plate Observing SystemFinanced by: European.Unión.-.7PM-PP.26229Years:.2010-2014PI: J..Gallart
Project Title: NERA – Network of European Research Insfrastructures for Eartquake Risk Assessment and MigrationFinanced by: European.Unión.-.7PM-PP.262330Years:.2010-2014PI: J..Gallart
Project Title: TOPOMOD-Sculpting the Earth’s topography: Insights from modelling deep-surface processesFinanced by: European.Unión.-.7PM-.RTN.264157Years:.2011-2014PI: M..Fernandez
Project Title: Performance of the conversion to digital form of the phase arrival times for all earthquakes includes in the bulletins of the international seismological summaryFinanced by: International.Seismological.CenterYears:.2013-2014PI: A..Villaseñor
Industry
Project Title: Integrated structural and geodynamics geological research studiesFinanced by: STATOIL-HYDRO.PETROLEUM.ASAYears:.2008-2013PI: J..Vergés
Project Title: Seguimiento geofísico del confinamiento geológico de CO2
Financed by: REPSOL.YPF,.S.A.Years:.2010-2013PI: A..Villaseñor
Project Title: Identificación y validación de métodos geofísicos para la detección y caracterización de discontinuidades en medios sedimentarios recientes.Financed by: ENRESAYears:.2013-2015PI: A..Pérez-Estaún
34 ANNUAL REPORT ICTJA 2013
Research outline
This.line.of.research.is.focused.on.the.study.of.the.optical.properties.of.semiconductor.materials..Over.the.past.few.years.we.have.carried. out. Raman. scattering. studies. on.a.variety.of.III-V.compound.systems.such.as.GaN,.InN,.InGaN,.InAs/GaAs,.InGaAs,.InP,.AlGaSb,.InAsSb,.GaSb,.GaAsN,.as.well.as.on.ZnO,.a.II-VI.wide.band.gap.material.which. is. intensively. being. investigated.because. of. its. potential. applications. in.transparent. electronics. and. in. blue. and.UV.light.emitters.
Group members
Lluis Artús,.Group Leader – Senior Research Scientist
Ramon Cuscó,.Research ScientistJordi Ibañez,.Research ScientistNuria Domènech,.FPU pre-docRobert Oliva,.FPI pre-doc
Crystallography and Optical properties
ICTJA Research Groups
ANNUAL REPORT ICTJA 2013 35
National Funding Agencies
Project Title: OPTOFOT Propiedades ópticas de materiales opto electrónicos y fotovoltaicosFinanced by: PNIDI-MAT:.MT2010-16116Years:.2011-2014PI:.Ll..Artús
Publications 2013
Ibáñez Insa, J..(2013),.Reformulating.table.salt.under.pressure,.Science,.342(6165),.1459-1460,.doi:.10.1126/science.1247699.
Ibáñez, J.,.O. Font,.N. Moreno,.J. J. Elvira,.S. Alvarez,.and.X. Querol.(2013),.Quantitative.Rietveld.analysis.of.the.crystalline.and.amorphous.phases.in.coal.fly.ashes,.Fuel,.105,.314-317,.doi:.10.1016/j.fuel.2012.06.090.
Ibáñez, J.,.R. Oliva,.F. J. Manjón,.A. Segura,.T. Yamaguchi,.Y. Nanishi,.R. Cuscó,.and.L. Artús. (2013),. High-pressure. lattice. dynamics. in. wurtzite. and. rocksalt. indium. nitride.investigated.by.means.of.Raman.spectroscopy,.Physical.Review.B.-.Condensed.Matter.and.Materials.Physics,.88(11),.doi:.10.1103/PhysRevB.88.115202.
Oliva, R.,.J. Ibáñez,.L. Artús,.R. Cuscó,.J. Zúñiga-Pérez,.and.V. Muñoz-Sanjosé.(2013),.High-pressure.Raman.scattering.of.CdO.thin.films.grown.by.metal-organic.vapor.phase.epitaxy,.Journal.of.Applied.Physics,.113(5),.doi:.10.1063/1.4790383.
Rioboo, R. J. J.,.C. Prieto,.R. Cuscó,.L. Artús,.C. Boney,.A. Bensaoula,.T. Yamaguchi,.and.Y. Nanishi.(2013),.Temperature.dependence.of.surface.acoustic.wave.propagation.velocity.in. InxGa1-xN. films. obtained. by. high-resolution. brillouin. spectroscopy:. Determination.of. temperature. coefficient. of. frequency,. Applied. Physics. Express,. 6(5),. doi:. 10.7567/APEX.6.056601.
Torréns-Martín, D.,.L. Fernández-Carrasco,.S. Martínez-Ramírez,.J. Ibáñez,.L. Artús,.and.T. Matschei.(2013),.Raman.spectroscopy.of.anhydrous.and.hydrated.calcium.aluminates.and.sulfoaluminates,.Journal.of.the.American.Ceramic.Society,.96(11),.3589-3595,.doi:.10.1111/jace.12535.
Research projects 2013
ICTJA Research Groups
36 ANNUAL REPORT ICTJA 2013
Environmental Changes in the Geological RecordGroup members
Research outline
Our. multidisciplinary. group. promotes.the. reconstruction.of.environmental.and.climate.changes,.their.causes,.and.dynamic.interactions. through. the. multiproxy.characterization. of. the. geologic. record..Throughout.the.history.of.our.planet,.the.geological.processes.in.general.and.climate.change. in. particular. have. fingerprinted.the.sedimentary.record..Furthermore,.the.increasing.anthropogenic.influence.in.the.recent. past. is. also. readily. identifiable. in.this.geological.record.
This.research.is.carried.out.using.a.multiproxy.approach.and.focuses.on.lake.sedimentology.and.global.change,.impact.of.geological.and.
anthropogenic. processes. on. the. natural.geochemical.balances,.sedimentary.processes.and.biomineralization,.geochronological.dating.and.physical.and.magnetic.properties.of.the.sediments.as. indicators.of.environmental.and.climatic.processes.
The.objective.of.the.research.group.is.the.robust.and.accurate.reconstruction.of.past.climate. oscillations. and. environmental.fluctuations.as.well.as.identify.short,.medium.and. long. term. trends. of. these. changes.through.the.multiproxy.characterization.of.the.geological.sedimentary.record..These.reconstructions.provide.valuable.data. to.put.into.a.broad.temporal.perspective.the.current.climate.and.environmental.trends.as.well.as.they.provide.useful.insights.about.which.has.been.the.historical.and.current.anthropogenic.role.in.the.recent.evolution.of.the.Earth..These.climatic.and.environmental.reconstructions. also. provide. data. that.allows.the.establishment.of.possible.future.climatic.and.environmental.scenarios.
To.achieve.this.goal.the.group.is.developing.the.following.research.lines:–. reconstruction. of. climatic. and.
environmental. changes. using. a. high.temporal.resolution.multiproxy.approach.of.lacustrine.sedimentary.re-cords;
–. determining.the.geochemical.impact.of.large-scale. geological. processes. (e.g.,.explosive.volcanic.eruptions.or.floods);
–. evaluating. the. relationships. between.processes.and.sedimentary.environments.and.biomineralization,.and.characterizing.physical.and.magnetic.properties.of.the.sedimentary.record.as.proxies.of.climatic.and.environmental.events.
ICTJA Research Groups
Ramón Julià,.Research Professor (Ad-honorem) Pere Anadón,.Senior Research ScientistAntonio Vazquez, Research ScientistRosa Utrilla, Research ScientistSantiago Giralt, Research ScientistAgustin Lobo, CSIC contract researcherJuan Cruz Larrasoaña, IGME Visiting Research ScientistMiriam Gómez-Paccard, CSIC JAE-doc and Visiting Marie-Curie post-docMaria Jesús Rubio,.FPI pre-docGuiomar Sánchez,.JAE pre-docAlejandro Rodríguez,.CSIC-contractMaria Dolores Jiménez,.CSIC-JAE Technician
José Luis Fernandez-Turiel,.Group Leader – Senior Research Scientist
38 ANNUAL REPORT ICTJA 2013
Publications 2013
Anadón, P.,.C. Canet,.and.W. L. Friedrich.(2013),.Aragonite.stromatolitic.buildups.from.Santorini. (Aegean. Sea,. Greece):. Geochemical. and. palaeontological. constraints. of. the.caldera.palaeoenvironment.prior.to.the.Minoan.eruption.(ca.3600.yr.bp),.Sedimentology,.60(5),.1128-1155,.doi:.10.1111/sed.12025.
Barreiro-Lostres, F.,.A. Moreno,.S. Giralt,.and.B. L. Valero-Garcés.(2013),.Sedimentary.evolution.of.La.Parra.karstic.lake.(Cuenca).over.the.last.1600.years:.Paleohydrology,.climate,.and.human.impact,.Evolución.sedimentaria.del.lago.kárstico.de.La.Parra.(Cuenca).durante.los.últimos.1600.años:.Paleohidrología,.clima.e.impacto.humano,.39(1),.179-193.
Canet, C.,.P. Anadón,.P. Alfonso,.R. M. Prol-Ledesma,.R. E. Villanueva-Estrada,.and.M. García-Vallès.(2013),.Gas-seep.related.carbonate.and.barite.authigenic.mineralization.in.the.northern.Gulf.of.California,.Marine.and.Petroleum.Geology,.43,.147-165,.doi:.10.1016/j.marpetgeo.2013.02.011.
Cañellas-Boltà, N.,. V. Rull,. A. Sáez,. O. Margalef,. R. Bao,. S. Pla-Rabes,. M. Blaauw,.B. Valero-Garcés,.and.S. Giralt.(2013),.Vegetation.changes.and.human.settlement.of.Easter.Island.during.the.last.millennia:.A.multiproxy.study.of.the.Lake.Raraku.sediments,.Quaternary.Science.Reviews,.72,.36-48,.doi:.10.1016/j.quascirev.2013.04.004.
Cimarelli, C.,.F. Di Traglia,.D. de Rita,.D. Gimeno Torrente,.and.J. L. Fernandez Turiel.(2013),.Space-time.evolution.of.monogenetic.volcanism.in.the.mafic.Garrotxa.Volcanic.Field.(NE.Iberian.Peninsula),.Bulletin.of.Volcanology,.75(11),.1-18,.doi:.10.1007/s00445-013-0758-6.
Corella, J. P.,. V. Stefanova,. A. El Anjoumi,. E. Rico,. S. Giralt,. A. Moreno,. A. Plata-Montero,.and.B. L. Valero-Garcés.(2013),.A.2500-year.multi-proxy.reconstruction.of.climate.change.and.human.activities.in.northern.Spain:.The.Lake.Arreo.record,.Palaeogeography,.Palaeoclimatology,.Palaeoecology,.386,.555-568,.doi:.10.1016/j.palaeo.2013.06.022.
Costa, E.,.M. Garcés,.M. López-Blanco,.J. Serra-Kiel,.G. Bernaola,.L. Cabrera,.and.E. Beamud.(2013),.The.Bartonian-Priabonian.marine.record.of.the.eastern.south.Pyrenean.foreland.basin.(NE.Spain):.A.new.calibration.of.the.larger.foraminifers.and.calcareous.nannofossil.biozonation,.Geologica.Acta,.11(2),.177-193,.doi:.10.1344/105.000001779.
Daura, J.,.et.al..(2013),.Terrasses.de.la.Riera.dels.Canyars.(Gavà,.Barcelona):.The.landscape.of.Heinrich.Stadial.4.north.of.the.".Ebro.frontier".and.implications.for.modern.human.dispersal.into.Iberia,.Quaternary.Science.Reviews,.60,.26-48,.doi:.10.1016/j.quascirev.2012.10.042.
Gil, A.,.A. Lobo,.M. Abadi,.L. Silva,.and.H. Calado.(2013),.Mapping.invasive.woody.plants.in.Azores.Protected.Areas.by.using.very.high-resolution.multispectral.imagery,.European.Journal.of.Remote.Sensing,.46(1),.289-304,.doi:.10.5721/EuJRS20134616.
ICTJA Research Groups
ANNUAL REPORT ICTJA 2013 39
Gómez-Paccard, M.,. E. Beamud,. G. Mc Intosh,. and. J. C. Larrasoaña. (2013),. New.archaeomagnetic.data.recovered. from.the.study.of. three.roman.kilns. from.north-east.spain:.A.contribution.to.the.iberian.palaeosecular.variation.curve,.Archaeometry,.55(1),.159-177,.doi:.10.1111/j.1475-4754.2012.00675.x.
Gómez-Paccard, M.,.J. C. Larrasoaña,.C. Sancho,.A. Muñoz,.E. McDonald,.E. J. Rhodes,.M. C. Osácar,. E. Costa,. and. E. Beamud. (2013),. Environmental. response. of. a. fragile,.semiarid.landscape.(Bardenas.Reales.Natural.Park,.NE.Spain).to.Early.Holocene.climate.variability:. A. paleo-. and. environmental-magnetic. approach,. Catena,. 103,. 30-43,. doi:.10.1016/j.catena.2011.05.013.
Hernández, A.,.R. Bao,.S. Giralt,.A. Sáez,.M. J. Leng,.P. A. Barker,.C. P. Kendrick,.and.H. J. Sloane.(2013),.Climate,.catchment.runoff.and.limnological.drivers.of.carbon.and.oxygen.isotope. composition. of. diatom. frustules. from. the. central. andean. altiplano. during. the.Lateglacial.and.Early.Holocene,.Quaternary.Science.Reviews,.66,.64-73,.doi:.10.1016/j.quascirev.2012.10.013.
López-García, J. M.,.H. A. Blain,.R. Julià,.and.J. Maroto.(2013),.Environment.and.climate.during.MIS.7.and.their.implications.for.the.later.Middle.Pleistocene.hominins:.The.contribution.of.Mollet.cave,.Serinyà,.Girona,.northeastern.Spain,.Quaternary.International,.doi:.10.1016/j.quaint.2012.12.025.
Margalef, O.,.et.al..(2013),.A.70,000.year.multiproxy.record.of.climatic.and.environmental.change.from.Rano.Aroi.peatland.(Easter.Island),.Global.and.Planetary.Change,.108,.72-84,.doi:.10.1016/j.gloplacha.2013.05.016.
Muñoz, J. A.,.E. Beamud,.O. Fernández,.P. Arbués,.J. Dinarès-Turell,.and.J. Poblet.(2013),.The.Ainsa.Fold.and.thrust.oblique.zone.of.the.central.Pyrenees:.Kinematics.of.a.curved.contractional.system.from.paleomagnetic.and.structural.data,.Tectonics,.32(5),.1142-1175,.doi:.10.1002/tect.20070.
Nieto-Moreno, V.,.F. Martinez-Ruiz,.S. Giralt,.D. Gallego-Torres,.J. García-Orellana,.P. Masqué,.and.M. Ortega-Huertas.(2013),.Climate.imprints.during.the.'Medieval.Climate.Anomaly'.and.the.'Little.Ice.Age'.in.marine.records.from.the.Alboran.Sea.basin,.Holocene,.23(9),.1227-1237,.doi:.10.1177/0959683613484613.
Piñar, G.,.M. Garcia-Valles,.D. Gimeno-Torrente,.J. L. Fernandez-Turiel,.J. Ettenauer,.and.K. Sterflinger.(2013),.Microscopic,.chemical,.and.molecular-biological.investigation.of.the.decayed.medieval.stained.window.glasses.of.two.Catalonian.churches,.International.Biodeterioration.and.Biodegradation,.84,.388-400,.doi:.10.1016/j.ibiod.2012.02.008.
Riera, V.,.P. Anadón,.O. Oms, R. Estrada,.and.E. Maestro.(2013),.Dinosaur.eggshell.isotope.geochemistry.as.tools.of.palaeoenvironmental.reconstruction.for.the.upper.Cretaceous.from.the.Tremp.Formation.(Southern.Pyrenees),.Sedimentary.Geology,.294,.356-370,.doi:.10.1016/j.sedgeo.2013.06.001.
ICTJA Research Groups
40 ANNUAL REPORT ICTJA 2013
Roca, E.,.E. Beamud,.M. Rubinat,.R. Soto,.and.O. Ferrer.(2013),.Paleomagnetic.and.inner.diapiric.structural.constraints.on.the.kinematic.evolution.of.a.salt-wall:.The.Bicorb-Quesa.and. northern. Navarrés. salt-wall. segments. case. (Prebetic. Zone,. SE. Iberia),. Journal. of.Structural.Geology,.doi:.10.1016/j.jsg.2013.04.003.
Servera Vives, G.,.Y. Miras,.S. Riera,.R. Julià,.P. Allée,.H. Orengo,.S. Paradis-Grenouillet,.and.J. M. Palet.(2013),.Tracing.the.land.use.history.and.vegetation.dynamics.in.the.Mont.Lozère.(Massif.Central,.France).during.the.last.2000.years:.The.interdisciplinary.study.case.of.Countrasts.peat.bog,.Quaternary.International,.doi:.10.1016/j.quaint.2013.10.048.
Toro-Moyano, I.,.et.al..(2013),.The.oldest.human.fossil. in.Europe,. from.Orce.(Spain),.Journal.of.Human.Evolution,.65(1),.1-9,.doi:.10.1016/j.jhevol.2013.01.012.
Toro, M.,.I. Granados,.S. Pla,.S. Giralt,.D. Antoniades,.L. Galán,.A. M. Cortizas,.H. S. Lim,.and.P. G. Appleby.(2013),.Chronostratigraphy.of.the.sedimentary.record.of.Limnopolar.Lake,.Byers.Peninsula,.Livingston.Island,.Antarctica,.Antarctic.Science,.25(2),.198-212,.doi:.10.1017/S0954102012000788.
ICTJA Research Groups
ANNUAL REPORT ICTJA 2013 41
Research projects 2013
ICTJA Research Groups
National Funding Agencies
Project Title: LACATALAS – Environmental characterization of Miocene lacustrine systems with marine-like faunas from the Duero and Ebro basins: geochemistry of biogenic carbonates and palynologyFinanced by: PNIDI.CGL.-.CGL2011-23438Years:.2012-2014PI:.P..Anadón
Project Title: QUECA – Impactos medioambientales de erupciones cuaternarias en los Andes Centrales: Modelado para la prevención de los efectos de futuras erupcionesFinanced by: PNIDI.CGL.-.CGL2011-23307Years:.2012-2014PI:.J..L..Fernandez-Turiel
Project Title: PALEONAO - Evolución de la NAO durante los ultimos 15000 años en la Peninsula Ibérica y en Azores, a partir del estudio de registros lacustres y datos climáticos instrumentalesFinanced by: PNIDI.CGL.-.CGL2010-15767Years:.2011-2013PI:.S..Giralt
42 ANNUAL REPORT ICTJA 2013
Group members
Geophysical and Geochemical Modelling of Geohazard Processes and Subsurface Resources
Research outline
Geological,.geochemical.and.geophysical.studies.are.applied.to.model.natural.processes.that.can.become.geological.hazards..These.studies.include.research.topics.related.to.volcanism,.seismology,.landslides.or.geochemical.transfer.in.subsurface.and.surface. land..From.a.multidisciplinary.point.of.view,. the. research. is. focused.on.the.physics.of.hazardous.geological.processes,.development.of.analytical.tools.for.geochemistry,.borehole.geophysics.and.remote.sensing.
Among the most important techniques we highlight:
•.Simulation.of.geological.processes.using.a.combination.of.numerical.&.experimental.methods
•.Application.of.X-ray.radiation.for.the.study.of.materials.and.residual.waters
•.Borehole.geophysics.and.subsurface.imaging
•.Development.of.new.algorithms.for.remote.sensing. and. geographic. information.systems.
ICTJA Research Groups
Joan Martí,.Group Leader – Research Professor
Ignasi Queralt, Senior Research ScientistCarles Soriano, Research ScientistMaria José Jurado, Research ScientistAdelina Geyer, JdlC post-docMarta Tarraga, JAE post-docRosa Maria Sobradelo, CSIC contract post-docStèphanie Barde-Cabusson, JAE post-docHelena Gallardo, FPI pre-docRaquel Noriega, FPI pre-docDario Pedrazzi, JAE pre-docStefania Bartolini, JAE pre-docSilvia Aragó, CSIC contract pre-docXavier de Bolós, CSIC contract pre-docSara Quesada, CSIC contractLaura Becerril, CSIC contract
ANNUAL REPORT ICTJA 2013 43
Geophysical and Geochemical Modelling of Geohazard Processes and Subsurface Resources
ICTJA Research Groups
44 ANNUAL REPORT ICTJA 2013
Publications 2013
Atanassova, R.,.J. Cama,.J. M. Soler,.F. G. Offeddu,.I. Queralt,.and.I. Casanova.(2013),.Calcite. interaction. with. acidic. sulphate. solutions:. A. vertical. scanning. interferometry.and.energy-dispersive.XRF.study,.European.Journal.of.Mineralogy,.25(3),.331-351,.doi:.10.1080/1750-8487/2013/0025-2279.
Barde-Cabusson, S.,.X. Bolós,.D. Pedrazzi,.R. Lovera,.G. Serra,.J. Martí,.and.A. Casas.(2013),.Electrical.resistivity.tomography.revealing.the.internal.structure.of.monogenetic.volcanoes,.Geophysical.Research.Letters,.40(11),.2544-2549,.doi:.10.1002/grl.50538.
Bartolini, S.,.A. Cappello,.J. Martí,.and.C. Del Negro.(2013),.QVAST:.A.new.Quantum.GIS.plugin.for.estimating.volcanic.susceptibility,.Natural.Hazards.and.Earth.System.Sciences,.13(11),.3031-3042,.doi:.10.5194/nhess-13-3031-2013.
Bendaoud, R.,.A. Guilherme,.A. Zegzouti,.M. Elaatmani,.J. Coroado,.M. L. Carvalho,.and.I. Queralt.(2013),.Elemental.mapping.of.moroccan.enameled.terracotta.tile.works.(Zellij).based.on.X-ray.micro-analyses,.Applied.Radiation.and.Isotopes,.82,.60-66,.doi:.10.1016/j.apradiso.2013.07.001.
Chevrel, M. O.,.D. Giordano,.M. Potuzak,.P. Courtial,.and.D. B. Dingwell.(2013),.Physical.properties.of.CaAl2Si2O8-CaMgSi2O6-FeO-Fe2O3.melts:.Analogues.for.extra-terrestrial.basalt,.Chemical.Geology,.346,.93-105,.doi:.10.1016/j.chemgeo.2012.09.004.
D'Elia, L.,.and.J. Martí.(2013),.Caldera.events.in.a.rift.depocentre:.An.example.from.the.Jurassic.Neuquén.basin,.Argentina,.Journal.of.the.Geological.Society,.170(4),.571-584,.doi:.10.1144/jgs2012-116.
Floor, G. H.,.E. Marguí,.M. Hidalgo,.I. Queralt,.P. Kregsamer,.C. Streli,.and.G. Román-Ross (2013),.Study.of.selenium.sorption.processes.in.volcanic.ash.using.Total.Reflection.X-ray.Fluorescence.(TXRF),.Chemical.Geology,.352,.19-26,.doi:.10.1016/j.chemgeo.2013.05.034.
Kereszturi, G.,.A. Geyer,.J. Martí,.K. Németh,.and.F. J. Dóniz-Páez.(2013),.Evaluation.of.morphometry-based.dating.of.monogenetic.volcanoes-a.case.study.from.Bandas.del.Sur,.Tenerife.(Canary.Islands),.Bulletin.of.Volcanology,.75(7),.1-19,.doi:.10.1007/s00445-013-0734-1.
Kocot, K.,.B. Zawisza,.E. Marguí,.I. Queralt,.M. Hidalgo,.and.R. Sitko.(2013),.Dispersive.micro.solid-phase.extraction.using.multiwalled.carbon.nanotubes.combined.with.portable.total-reflection.X-ray.fluorescence.spectrometry.for.the.determination.of.trace.amounts.of.Pb.and.Cd.in.water.samples,.Journal.of.Analytical.Atomic.Spectrometry,.28(5),.736-742,.doi:.10.1039/c3ja50047k.
Marguí, E.,.I. Queralt,.and.M. Hidalgo.(2013a),.Determination.of.platinum.group.metal.catalyst.residues.in.active.pharmaceutical.ingredients.by.means.of.total.reflection.X-ray.spectrometry,.Spectrochimica.Acta.-.Part.B.Atomic.Spectroscopy,.86,.50-54,.doi:.10.1016/j.sab.2013.05.024.
ICTJA Research Groups
ANNUAL REPORT ICTJA 2013 45
Marguí, E.,.I. Queralt,.and.M. Hidalgo.(2013b),.Determination.of.cadmium.at.ultratrace.levels.in.environmental.water.samples.by.means.of.total.reflection.X-ray.spectrometry.after.dispersive.liquid-liquid.microextraction,.Journal.of.Analytical.Atomic.Spectrometry,.28(2),.266-273,.doi:.10.1039/c2ja30252g.
Marguí, E.,.M. Sagué,.I. Queralt,.and.M. Hidalgo.(2013),.Liquid.phase.microextraction.strategies.combined.with.total.reflection.X-ray.spectrometry.for.the.determination.of.low.amounts.of.inorganic.antimony.species.in.waters,.Analytica.Chimica.Acta,.786,.8-15,.doi:.10.1016/j.aca.2013.05.006.
Marguí, E.,.B. Zawisza, R. Skorek,.T. Theato,.I. Queralt,.M. Hidalgo,.and.R. Sitko.(2013),.Analytical.possibilities.of.different.X-ray.fluorescence.systems.for.determination.of.trace.elements.in.aqueous.samples.pre-concentrated.with.carbon.nanotubes,.Spectrochimica.Acta.-.Part.B.Atomic.Spectroscopy,.doi:.10.1016/j.sab.2013.07.004.
Martí, J.,.A. Geyer,.and.G. Aguirre-Diaz.(2013),.Origin.and.evolution.of.the.Deception.Island.caldera.(South.Shetland.Islands,.Antarctica),.Bulletin.of.Volcanology,.75(6),.1-18,.doi:.10.1007/s00445-013-0732-3.
Martí, J.,.A. Castro,.C. Rodríguez,.F. Costa,.S. Carrasquilla,.R. Pedreira,.and.X. Bolos.(2013),.Correlation.of.magma.evolution.and.geophysical.monitoring.during.the.2011-2012.El.Hierro.(Canary.Islands).submarine.eruption,.Journal.of.Petrology,.54(7),.1349-1373,.doi:.10.1093/petrology/egt014.
Martí, J., V. Pinel, C. López, A. Geyer, R. Abella,.M. Tárraga, M. J. Blanco, A. Castro,.and.C. Rodríguez.(2013),.Causes.and.mechanisms.of.the.2011-2012.El.Hierro.(Canary.Islands).submarine.eruption,.Journal.of.Geophysical.Research.B:.Solid.Earth,.118(3),.823-839,.doi:.10.1002/jgrb.50087.
Pedrazzi, D., J. Martí,.and.A. Geyer.(2013),.Stratigraphy,.sedimentology.and.eruptive.mechanisms.in.the.tuff.cone.of.El.Golfo.(Lanzarote,.Canary.Islands),.Bulletin.of.Volcanology,.75(7),.1-17,.doi:.10.1007/s00445-013-0740-3.
Phillipson, G., R. Sobradelo,.and.J. Gottsmann.(2013),.Global.volcanic.unrest.in.the.21st.century:.An.analysis.of.the.first.decade,.Journal.of.Volcanology.and.Geothermal.Research,.264,.183-196,.doi:.10.1016/j.jvolgeores.2013.08.004.
Ronchin, E., T. Masterlark, J. Marti Molist, S. Saunders,.and.W. Tao.(2013),.Solid.modeling.techniques.to.build.3D.finite.element.models.of.volcanic.systems:.An.example.from.the.Rabaul.Caldera.system,.Papua.New.Guinea,.Computers.and.Geosciences,.52,.325-333,.doi:.10.1016/j.cageo.2012.09.025.
Sigmarsson, O., D. Laporte, M. Carpentier, B. Devouard, J. L. Devidal,.and.J. Marti.(2013),.Formation.of.U-depleted.rhyolite.from.a.basanite.at.El.Hierro,.Canary.Islands,.Contributions.to.Mineralogy.and.Petrology,.165(3),.601-622,.doi:.10.1007/s00410-012-0826-5.
ICTJA Research Groups
46 ANNUAL REPORT ICTJA 2013
ICTJA Research Groups
Research projects 2013
Skorek, R., B. Zawisza, E. Marguí, I. Queralt,.and.R. Sitko.(2013),.Dispersive.micro.solidphase.extraction.using.multiwalled.carbon.nanotubes.for.simultaneous.determination.of.trace.metal.ions.by.energy-dispersive.x-ray.fluorescence.spectrometry,.Applied.Spectroscopy,.67(2),.204-209,.doi:.10.1366/12-06738.
Soriano, C., G. Giordano, R. Cas, N. Riggs,.and.M. Porreca.(2013),.Facies.architecture,.emplacement.mechanisms.and.eruption.style.of.the.submarine.andesite.El.Barronal.complex,.Cabo.de.Gata,.SE.Spain,.Journal.of.Volcanology.and.Geothermal.Research,.264,.210-222,.doi:.10.1016/j.jvolgeores.2013.07.001.
Vona, A., C. Romano, D. Giordano,.and.J. K. Russell.(2013),.The.multiphase.rheology.of.magmas.from.Monte.Nuovo.(Campi.Flegrei,.Italy),.Chemical.Geology,.346,.213-227,.doi:.10.1016/j.chemgeo.2012.10.005.
National Funding Agencies
Project Title: GEOSUB/2 - Investigación en proyectos de perforación del ICDP: Preparación de un nuevo proyectoFinanced by: PNIDI-ACI.-.ACI2008-0773Years:.2009-2013PI:.M..J..Jurado
Project Title: HIERRO-DOS – Interpretación de la fase de inestabilidad precursora de la erupción del Hierro 2011Financed by: PNIDI-CGL.-.CGL2011-16144-EYears:.2012-2013PI:.M..Martí
Project Title: IMPAS - Impact in Aquifer media and Soils of non-conventional water (treated-desalinated) use and sewage sludge application: laboratory and field investigationsFinanced by: PNIDI-CGLI.-.CGLI22168-C03-01Years:.2011-2013PI:.I..Queralt
Project Title: PEVOLDEC – Análisis de la peligrosidad volcánica de la isla de DecepciónFinanced by: PNIDI-CTM.-.CTM2011-13578-EYears:.2012-2013PI:.A..Geyer
ANNUAL REPORT ICTJA 2013 47
Project Title: PLUVOL – Understanding the plutonic-volcanic connection in supervolcanoesFinanced by: PNIDI-CGL-CGL2010-22022-C02-02Years:.2011-2013PI:.J..Martí
Project Title: PROPER – Investigación y monitorización de fallas sismogenicas en sondeos para la elaboración de una propuesta de perforación al ICDP para perforación en el SE PeninsularFinanced by: PNIDI-CGL.-.CGL2010-21568Years:.2011-2014PI:.M..J..Jurado
Project Title: Desarrollo de actividades de investigación del subsuelo mediante testificación geofísicaFinanced by: IGMEYears:.2010-2013PI:.M..J..Jurado
Project Title: Investigación del subsuelo mediante sondas geofísicas. Estudios entre sondeos y monitorizaciónFinanced by: CIUDENYears:.2009-2012PI:.M..J..Jurado
Project Title: EXCAVA-Explora, caracteriza y visualizaFinanced by: PNIDI-IPT–2012-0979-380000Years:.2013-2015PI:.M..J..Jurado
Project Title: Estudio geofísico para la caracterización de límites estructurales en Tenerife y la Palma (ESTEPA)Financed by: PNIDI-CGL2011-15139Years:.2013-2014PI:.S..Barde-Cabusson.and.A..Geyer
International funding agencies
Project Title: VUELCO – Volcanic unrest in Europe and Latin America: Phenomenology, eruption precursors, hazard forecast, and risk mitigationFinanced by: European.Unión.-.Project.#.282759Years:.2011-2015PI:.J..Martí
ICTJA Research Groups
48 ANNUAL REPORT ICTJA 2013
Sodium. chloride. (NaCl),. the. main.component.of.table.salt,.is.the.archetypical.ionic. compound. of. chemistry. textbooks..The. large. electronegativity. difference.between.the.participating.elements.drives.salt.formation..Metallic.sodium.transfers.electrons. to. chlorine,. and. the. resulting.positively.and.negatively.charged.ions.are.held. together. by. electrostatic. attraction.ionic. bonds.. At. ambient. conditions,.NaCl.crystallizes.in.the.so-called.rocksalt.structure,.a.cubic.array.of.Na.and.Cl.atoms.in.equal.proportions.(1:1.stoichiometry).and.with.six-fold.coordination.
ICTJA 10 highlighted papers
Reformulating table salt under pressureWith. increasing. pressure,. a. structural.phase. transition. to. the. cubic,. eight-fold.coordinated.NaCl-B2.phase.is.observed.at.~30.GPa.[(1).and.references.therein]..Theory.suggested.that.complete.metallization.of.NaCl.should.occur.above.∼300.GPa,.and.no.Na-Cl.compounds.other.than.NaCl.were.known. to. exist.. However,. it. has. recently.been. shown. that. stable. Na-Cl. phases.with.stoichiometries.different.from.1:1.and.intriguing.properties.can.be.synthesized.in.the.lab.with.high-pressure.techniques.
Reference
Ibañez, J..Science,.342,.6165,.1459-1460.(2013)..DOI:.10.1126/science.1247699
ANNUAL REPORT ICTJA 2013 49
The. application. of. petrography,. mineral.chemistry,.geochemistry,.and.experimental.petrology,. including. mineral–melt.thermodynamic. and. diffusion. modelling,.on. quenched. basanitic. magma. samples.from. the. recent. (2011–2012). submarine.eruption. of. El. Hierro. (Canary. Islands).has.permitted.the.identification.of.major.physico-chemical. variations. prior. to. and.during.magma.eruption. that.correlate. in.time.with.monitored.geophysical.changes..After.nearly.3.months.of.seismic.unrest.the.eruption.of.El.Hierro.started.on.October.10,. 2011. and. ended. by. late. February.2012.. We. studied. 10. lava. balloons. and.pyroclastic. fragments. collected. floating.on. the. sea. surface. between. October. 15.and. late. January.. Based. on. petrological.and.geophysical.data.we.distinguish.two.main. eruptive. episodes.. Magma. erupte.d. from. the. beginning. of. the. eruption.until.late.November.2011.was.an.evolved.basanite.(≈5.wt.%.MgO),.changing.to.more.primitive.compositions.(≈8–9.wt.%.MgO).with.time,.thus.suggesting.extraction.from.a.compositionally.zoned.magma.system.
Experimental. data. and. mineral–melt.thermodynamic.modelling.indicate.that.the.erupted.magma.equilibrated.at.a.pressure.of.about.400.MPa,.which.corresponds.to.a.depth.of.12–15.km..This.depth.is.consistent.with. the. location. of. the. crust–mantle.discontinuity.beneath.El.Hierro.and.with.thehypocentral.location.of.seismicity.during.the.unrest.episode..Preliminary.modelling.
Correlation of magma evolution and geophysicalmonitoring during the 2011-2012 El Hierro (CanaryIslands) submarine eruption
of.the.olivine.chemical.zoning.of.crystals.erupted.in.this.first.episode.suggests.that.the. time. scale. for. basanite. fractionation.and.magma.replenishment.in.the.shallower.reservoir.was.of.the.order.of.a.few.months.This.is.within.the.same.time.frame.as.the.duration.of.the.unrest.episode.preceding.
ICTJA 10 highlighted papers
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the. eruption.. The. first. eruption. episode.coincided.with.intense.seismicity.mostly.located.north.of.the.island,.first.at.a.depth.of.20–25.km.and.a.few.days.later.also.at.10–15.km.depth,.with.strong.seismic.tremor.beneath.the.vent.site..An.abrupt.change.in.magma.composition.and.crystal.content.was.observed.at.the.end.of.November.2011..After.that,.more.primitive.and.less.viscous.magma.erupted.contemporaneously.with.a. change. in. the. frequency. and. intensity.of. seismic. events.. During. this. period,.seismicity.was.mostly.north.of.the.island.at.depths.of.10–15.km..At.the.same.time.the. tremor. intensity. at. the. eruption. site.significantly.dropped..This.marked.the.onset.of.the.second.eruption.episode,.which.is.correlated.with.an.intrusion.of.fresh,.more.primitive.magma.into.the.shallow.magmatic.system.that.raised.the.temperature.of.the.remaining.magma..Experiments.reveal.that.subtle. changes. in. temperature. of. about.50°C. (i.e.. 1100–1150°C). were. enough.to. produce. large. changes. in. the. crystal.
content. (10–60. wt. %).. This. non-linear.behavior. between. crystal. content. and.temperature. had. important. effects. on.magma. dynamics. during. transport. and.cooling..Our.results.suggest.the.existence.of. two. interconnected. mafic. magma.reservoirs. during. the. El. Hierro. eruption,.which.agrees.with.the.pattern.shown.by.the.seismicity..Stress.readjustments.of.the.plumbing.system,.caused.by.decompression.during. the. eruption,. influenced. the.thermodynamic.evolution.of.the.erupting.magma.and.facilitated.the.intrusion.of.the.deeper.magma.into.the.shallow.reservoir,.thus. forcing. a. change. in. its. rheological.characteristics.and.eruption.dynamics.
Reference.
Martí, J., Castro, A., Rodriguez, C., Costa, F. Carrasquilla, S., Pedreira, R..and.Bolos, X.. Journal. of. Petrology.. DOI:. 10.1093/petrology/egt104
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In. the. present. study,. and. taking. into.account. the. microanalytical. capability.of. total. reflection. X-ray. spectrometry.(TXRF),. we. explored. the. possibilities. of.hollow.fibre.liquid-phase.microextraction.(HF-LPME). and. dispersive. liquid-liquid.microextraction.(DLLME).combined.with.TXRF.for.the.determination.of.low.amounts.of.inorganic.Sb.species.in.waters..For.each.of.the.LPME.configurations.aforementioned,.experimental. parameters. affecting. Sb.extraction.but.specially.the.proper.sample.preparation.process.(deposition.volume.on.the.reflective.carrier.and.drying.mode).and.measurement. conditions. for. subsequent.TXRF.analysis.have.been.carefully.evaluated.
The. best. analytical. strategy. for. the.determination.of.Sb(III).and.Sb(V).in.the.low.micrograms.L(-1).range.was.found.to.be. the. application. of. the. DLLME. mode.before. TXRF. analysis.. The. developed.methodology.was.successfully.applied.to.the.determination.of.inorganic.Sb.speciation.in.different.types.of.spiked.water.samples.
Liquid phase microextraction strategies combined with total reflection X-ray spectrometry for the determination of low amounts of inorganic antimony species in waters
ICTJA 10 highlighted papers
Reference.
Marguí, E., Sagué, M., Queralt, I., Hidalgo. Analytica. Chimica. Acta. DOI: 10.1016/j.aca.2013.05.006.
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We. image. the. western. Mediterranean.upper. mantle. with. improved. resolution.through. the. use. of. a. large. teleseismic.dataset,a.crustal.velocity.structure.derived.from.surface.wave.modeling.iterative.3-D.ray.tracing.and.finite-frequency.kernels..Our.main.conclusions.are:
1..The.dominant.upper.mantle. feature. is.the.4.–.5%.high-velocity,.slab-like.structure.shown. in..This.structure. is.connected.to.the.surface.and.extends.to.the.bottom.of.the.transition.zone.
Evidence for slab rollback in westernmost Mediterranean from improved upper mantle imaging
2.. Its.form,.when.restored.to.the.surface,.fills.the.area.occupied.by.the.Alpine.Tethys.ocean.lithosphere.and.embedded.continental.Alborán.domain.at.30.Ma.
3..We.interpret.the.high-velocity.structure.as. a. slab. of. lithosphere. composed. of.subducted. Alborán. mantle. lithosphere.and.the.surrounding.Alpine.Tethys.ocean.lithosphere.
4..This.lithosphere.is.thought.to.have.beensubducted. during. ∼30. m.y.. of. generally.
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westdirected. subduction. rollback,. which.continued. beneath. the. Alborán. domain.by.delaminating.its.mantle.lithosphere.
5.. A. more. drip-like. delamination. of. the.Middle.Atlas.mantle. lithosphere.may.be.evidenced.by.the.irregular.but.pronounced.zone. of. low. velocities. beneath. these.mountains. at. 50–125. km. depth. and. an.underlying.high-velocity.body.at.∼400–500.km.depth.
Reference.
Bezada, M. J., Humpreys, E.D., Toomey, D.R., Harnafi, M., Davila, J.M., Gallart, J. DOI:.10.1016/J.EPSL.2013.02.024
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The.Orce.region.has.one.of.the.best.late.Pliocene.and.early.Pleistocene.continental.paleobiological. records. of. Europe.. It. is.situated.in.the.northeastern.sector.of.the.intramontane.Guadix-.Baza.Basin.(Granada,.Andalusia,. southern. Spain).. Here. we.describe.a.new.fossil.hominin.tooth.from.the.site.of.Barranco.León,.dated.between.1.02.and.1.73.Ma.(millions.of.years.ago).by.Electron.Spin.Resonance.(ESR),.which,.in. combination. with. paleomagnetic. and.biochronologic. data,. is. estimated. to. be.close.to.1.4.Ma.
While. the. range. of. dates. obtained. from.these.various.methods.overlaps.with.those.
The oldest human fossil in Europe, from Orce (Spain)published.for.the.Sima.del.Elefante.hominin.locality.(1.2.Ma),.the.overwhelming.majority.of.evidence.points.to.an.older.age..Thus,.at.the.moment,.the.Barranco.León.hominin.is.the.oldest.from.Western.Europe.
Reference.
Toro-Moyano, I.; Martínez-Navarro, B.; Agustí, J.; Souday, C.; Bermúdez de Castro, J.M.; Martinón-Torres, M.; Fajardo, B.; Duval, M.; Falguères, C.; Oms, O.; Parés, J.M.; Anadón, P.; Julià, R.; García-Aguilar, J.M.; Moigne, A.-M.; Espigares, M.P.; Ros-Montoya, S.; Palmqvist, P..DOI:.10.1016/J.JHEVOL.2013.01.012.
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Diatom-based.carbon.and.oxygen.isotope.analyses. (δ13C
diatom. and. δ18O
diatom). were.
performed. on. diatom-rich. laminated.sediments. of. Lake. Chungará. (Andean.Altiplano,.northern.Chile).deposited.during.the.Lateglacial.and.Early.Holocene.(12,400–8300.cal.years.BP).to.reconstruct.climate.change.and.environmental.response.across.this.major.climate.transition..The.δ13C
diatom.
data. show. both. centennialto-millennial.scale.changes.related.to.fluctuations.in.lake.productivity.and.CO
2.concentration.in.the.
lake.water,.and.variations.in.carbon.sources.to.the.lake.through.time..The.δ18O
diatom.data.
reflect. changes. in. lake. hydrology. and.climate.
The.combination.of.δ13Cdiatom
.and.δ18Odiatom
.data. reveals. interactions. between. the.internal.lake.processes.and.its.catchment.runoff..During.wet.periods.(low.δ18O
diatom.
values). δ13Cdiatom
. indicates. an. enhanced.contribution. of. allochthonous. carbon,.whereas.during.dry.periods.(high.δ18O
diatom).
δ13Cdiatom
.values.suggest.more.autochthonous.carbon.production.and.recycling.
These. decadal-to-centennial. oscillations.are.not.recognized.after.10,000.cal.years.BP,. possibly. as. a. result. of. ENSO-like.phenomenon.weakening..Humid.conditions.during. the. Lateglacial–Early. Holocene.transition. (12,400–10,100. cal. years. BP).were.possibly.due.to.the.establishment.of.
Climate, catchment runoff and limnological drivers of carbon and oxygen isotope composition of diatom frustules from the central andean altiplano during the Lateglacial and Early Holocene
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La.Niña-like.conditions.in.the.tropical.South.Pacific..Whereas,.dry.conditions.in.the.Early.Holocene.(10,100–9100.cal.years.BP).may.be.caused.by.the.northward.migration.of.the.ITCZ.due.to.both.ENSO-like.weakening.and.an.insolation.minimum..Finally,.a.return.to.humid.conditions.at.the.end.of.the.Early.Holocene.(9100–8300.cal.years.BP).is.coincident.with.an.increase.in.summer.insolation.
Reference.
Hernández, A.; Bao, R.; Giralt, S.; Sáez, A.; Leng, M.J.; Barker, P.A.; Kendrick, C.P.; Sloane, H.J. DOI:.10.1016/J.QUASCIREV.2012.10.013
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Earlier. palynological. studies. of. lake.sediments.from.Easter.Island.suggest.that.the.island.underwent.a.recent.and.abrupt.replacement.of.palm-dominated.forests.by.grasslands,.interpreted.as.a.deforestation.byindigenous.people..However,.the.available.evidence.is.inconclusive.due.to.the.existence.of. extended. hiatuses. and. ambiguous.chronological.frameworks.in.most.of.the.sedimentary.sequences.studied..This.has.given.rise.to.an.ongoing.debate.about.the.timing.and.causes.of.the.assumed.ecological.degradation.and.cultural.breakdown..Our.multiproxy.study.of.a.core.recovered.from.Lake. Raraku. highlights. the. vegetation.dynamics.and.environmental.shifts.in.the.catchment.and.its.surroundings.during.the.late.Holocene.
Vegetation changes and human settlement of Easter Island during the last millennia: A multiproxy study of the Lake Raraku sediments
The. sequence. contains. shorter. hiatuses.than. in. previously. recovered. cores. and.provides. a. more. continuous. history. of.environmental.changes..The.results.show.a.long,.gradual.and.stepped.landscape.shift.from.palm-dominated.forests.to.grasslands..This.change.started.c..450.BC.and.lasted.about.two.thousand.years..The.presence.of.Verbena litoralis,.a.common.weed,.which.is.associated.with.human.activities.in.the.pollen. record,. the. significant. correlation.between.shifts.in.charcoal.influx,.and.thedominant. pollen. types. suggest. human.disturbance.of.the.vegetation..Therefore,.human.settlement.on.the.island.occurred.c..450.BC,.some.1500.years.earlier.than.is.assumed.
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Climate. variability. also. exerted. a. major.influence. on. environmental. changes..Two. sedimentary. gaps. in. the. record. are.interpreted.as.periods.of.droughts.that.could.have.prevented.peat.growth.and.favoured.its. erosion. during. the. Medieval. Climate.Anomaly.and.the.Little.Ice.Age,.respectively..At.c..AD.1200,.the.water.table.rose.and.the.former.Raraku.mire.turned.into.a.shallow.lake,. suggesting. higher. precipitation/evaporation.rates.coeval.with.a.cooler.and.wetter.Pan-Pacific.AD.1300.event..Pollen.and.diatom.records.show.large.vegetation.changes.due.to.human.activities.c..AD.1200..
Other.recent.vegetation.changes.also.due.to.human.activities.entail.the.introduction.of.taxa.(e.g..Psidium guajava,.Eucalyptus.sp.).and.the.disappearance.of.indigenous.plants.such. as. Sophora toromiro. during. the. two.last.centuries..Although.the.evidence.is.not.conclusive,.the.American.origin.of.V. litoralis.re-opens.the.debate.about.the.possible.role.of.Amerindians.in.the.human.colonisation.of.Easter.Island.
Reference.
Cañellas-Boltà, N.; Rull, V.; Sáez, A.; Margalef, O.; Bao, R.; Pla-rabes, S.; Blaauw, M.; Valero-Garcés, B.; Giralt, S..DOI:.10.1016/J.QUASCIREV.2013.04.004
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Eruptive.activity.of.individual.monogenetic.volcanoes.usually.lasts.a.few.days.or.weeks..However,.their.short.lifetime.does.not.always.mean.that.their.dynamics.and.structure.are.simple..Monogenetic.cones.construction.is.rarely.witnessed.from.the.beginning.to.the.end,.and.conditions.for.observing.their.internal.structure.are.hardly.reached..We.provide.high-resolution.electrical.resistivity.sections.(10.m.electrode.spacing).of.three.monogenetic. cones. from. northeastern.Spain,.comparing.our.results.to.geological.observations.to.interpret.their.underground.continuation..The.100.m.maximum.depth.of. exploration. provides. information. on.almost. the. entire. edifices,. highlighting.the.relationships.between.Strombolian.and.hydromagmatic.deposits.in.two.multiphase.edifices..A.main.observation.is.a.column.of.distinct.resistivity.centered.on.the.Puig.d'Adri.volcano,.which.we.interpret.as.the.eruptive.conduit..This.method.can.provide.valuable.information.on.the.past.volcanic.dynamics.of.monogenetic.volcanic.fields,.which.has.real.implic.ations.for.the.forecast.of.future.activity.
Reference.Barde-Cabusson, S.; Bolós, X.; Pedrazzi, D.; Lovera, R.; Serra, G.; Martí, J.; Casas, A..DOI:.10.1002/GRL.50538
Electrical resistivity tomography revealing the internal structure of monogenetic volcanoes
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The.Río.San.Juan.metamorphic.complex.exposes. a. segment. of. a. high-pressure.subduction-accretionary. complex. built.during.convergence.between.the.Caribbean.island.arc.and.the.North.America.continental.margin..It.is.composed.of.accreted.arcand.oceanic-derived. metaigneous. rocks,.serpentinized. peridotites. and. minor.metasediments.forming.a.structural.pile..Combined.structural.geology,.microtextural.relations,. multi-equilibrium. calculations.and.thermodynamical.modelling,.together.with. published. isotopic. ages,. allow.reconstructing. the. metamorphic. P-T-t.paths.of.each.nappe/unit.and. their. links.to.the.structural.evolution..In.all.units.of.the.complex,.three.major.stages.(M1.to.M3).in.the.tectonothermal.evolution.have.been.distinguished..The.M1.stage.corresponds.to. the. prograde. evolution. towards. the.pressurepeak. of. metamorphism. under.blueschist.or.eclogitic-facies.conditions.
The. M2. stage. is. related. to. the. main.retrogressive. event. and. is. characterized.by. the. S2-L2. fabric. development. in. all.lithologies.and.at.all.scales..The.M3.stage.represents. continuous. exhumation. from.ductile.to.ductile-brittle.deformation.regimes..However,.the.shape.of.the.retrograde.P-T.path,.the.age.of.the.exhumation-related.D2.structures.and.the.tectonic.significance.of.D2.deformation.are.different.in.each.structural.unit.. In.the.upper.structural. levels.of.the.
Contrasting exhumation P-T paths followed by high-P rocks in the northern Caribbean subduction-accretionary complex: Insights from the structural geology, microtextures and equilibrium assemblage diagrams
Jagua.Clara.serpentinitic-matrix.mélange,.the.counter-clockwise.P-T.path.of.the.eclogite.blocks.is.typical.of.rocks.exhumed.in.the.early. stages. of. intra-oceanic. subduction.zones..The.clockwise.P-T.path.obtained.for.the.lower.Cuaba.unit.is.characterized.by.a.strong.isothermal.decompression.from.the.garnet-epidote.amphibolite.and.eclogite-
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facies.pressure-peak..This.P-T.evolution.can.be.explained.by.rapid.exhumation.caused.byextensional.tectonics,.in.relation.to.a.major.modification. of. convergence. conditions.across.the.subduction.zone..The.P-T.path.also.explains.local.syn-M2.partial.melting.processes,.because.it.crosses.the.wet.solidus.for.IAT.mafic.compositions..The.P-T.path.obtained.for.the.high-P.Guineal.Schists,.with.exhumation.trajectory.following.the.burial.trajectory,. can. be. related. to. exhumation.during.active.subduction..This.exhumation.was.most.likely.driven.by.a.combination.of.underthrusting.of.tectonic.units.and.erosion.processes.. Available. geochronological.data.and.T-t/P-t.estimates.reveal.a.Late.Campanian.to.Maastrichtian.retrograde.M2.
metamorphism.in.the.lower.structural.units.of.the.complex.during.a.consistent.D2.top-to-the-NE/ENE.tectonic.transport..A.similar.tectonic.transport.has.also.been.recognized.in.the.metasedimentary.nappes.of.the.Samaná.complex.during.Eocene.to.earliest.Miocene..These.relations.indicate.a.northeastward.progradation. of. deformation. during. the.successive. tectonic. incorporation. of. arc,.oceanic. and. continental-derived. terrains.to.the.developing.Caribbean.su.bduction-accretionary.complex.
Reference.Escuder-Viruete, J. and Pérez-Estaún, A..DOI:.10.1016/J.LITHOS.2012.11.028
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We. present. an. experimental. and.theoretical.lattice-dynamical.study.of.InN.at.high.hydrostatic.pressures..We.perform.Raman.scattering.measurements.on.five.InN. epilayers,. with. different. residual.strain. and. free. electron. concentrations..The. experimental. results. are. analyzed.in. terms. of. ab initio. lattice-dynamical.calculations.on.both.wurtzite.InN.(w-InN).and.rocksalt.InN.(rs-InN).as.a.function.of.pressure.. Experimental. and. theoretical.pressure.coefficients.of.the.optical.modes.in. w-InN. are. compared,. and. the. role. of.residual.strain.on.the.measured.pressure.coefficients. is. analyzed.. In. the. case. of.the.LO.band,.we.analyze.and.discuss. its.pressure.behavior.considering.the.double-resonance.mechanism.responsible.for.the.selective. excitation. of. LO. phonons. with.large.wave.vectors.in.w-InN..The.pressure.behavior.of.the.L–.coupled.mode.observed.in.a.heavily.doped.n-type.sample.allows.us.to. estimate. the. pressure. dependence. of.the.electron.effective.mass.in.w-InN..The.results.thus.obtained.are.in.good.agreement.with.k•p.theory..The.wurtzite-to-rocksalt.phase.transition.on.the.upstroke.cycle.and.the. rocksalt-to-wurtzite. backtransition.on.the.downstroke.cycle.are.investigated,.and. the. Raman. spectra. of. both. phases.are. interpreted. in. terms. of. DFT. lattice-dynamical.calculations.
Reference.
Ibáñez, J.; Oliva, R.; Manjón, F.J.; Segura, A.; Yamaguchi, T.; Nanishi, Y.; Cuscó, R.; Artús, L. DOI:.10.1103/PHYSREVB.88.115202.
High-pressure lattice dynamics in wurtzite and rocksalt indium nitride investigated by means of Raman spectroscopy
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L¬
66 ANNUAL REPORT ICTJA 2013
Theses, Seminars and Courses
Title:. Análisis y aplicaciones del ruido sísmico en México, Golfo de México y Caribe: tomografía de ondas superficiales Rayleigh y Love. PhD.Student:. Beatriz.GAITE.CASTRILLOPhd.Advisor:. Antonio.VILLASEÑORPlace.&.date:. Madrid.–.07/2013
Title:. Novel technique to detect seismic signals and its application to map upper-mantle discontinuities beneath Iberia..PhD.Student:. Anahí.LUCIANA.BONATTOPhd.Advisor:. Martin.SCHIMMELPlace.&.date:. Barcelona.–.11/2013
Title:. The explosive volcanism of Teide-Pico Viejo volcanic complex, Canary island..PhD.Student:. Olaya.GARCÍA.PÉREZPhd.Advisor:. Joan.MARTÍPlace.&.date:. Barcelona.–.11/2013
Theses
ICTJA.has.co-organized.in.collaboration.with.the.Faculty.of.Geology.of.the.University.of.Barcelona.about.20.specialized.seminars,.conferences.and.lectures.during.the.year.2013..Among.them.we.would.like.to.highlight:
Seminars
ANNUAL REPORT ICTJA 2013 67
21/01"Topographic evolution of the East African Plateau",.Dr..Henry.Wichura,.Universitat.de.Postdam,.Germany.
11/04"Catastrophes in the Crust: Forecasting Volcanic Eruptions and Giant Landslides",.Dr..Christopher.Kilburn,.University.College.London,.UK.
18/04"Anticipating the news: Global ShakeMap & PAGER earthquake rapid response system",.Dr..Daniel.García.Jiménez,.USGS/GEM.External.Consultant
08/05"Recent innovative geophysics techniques applied to defining geology under cover –a global perspective",.Dr..D..FitzGerald,.Intrepid.Geophysics,.Victoria,.Austràlia.
25/06"Sismicidad en el Golfo de México: Un análisis preliminar",.Dra..Sara.Ivonne.Franco,.Instituto.de.Geofísica,.Universidad.Nacional.Autónoma.de.México.(UNAM).
27/06"Geological contribution to seismic hazard assessment for nuclear facilities (NFs)",.Dr..Stéphane.Baize,.Institut.de.Radioprotection.et.Sûreté.Nucléaire,.França.
17/09"Fluids in the Earth’s interior: from geochemical cycles to super-volcano eruptions",.Dr..Carmen.Sanchez-Valle,.Inst..Geochemistry.and.Petrology,.ETH.Zurich,.Switzerland
20/09"Yacimientos españoles de estaño asociados a intrusiones graníticas hercínicas",.Dr..José.MangasUniversidad.de.Las.Palmas.de.Gran.Canaria..Co-organized.together.with.WORKSHOP.ON.MINERAL.DEPOSITS.RELATED.TO.ACID.MAGMATISM..SGA.Barcelona.Student.Chapter
08/10"Two-dimensional probabilistic inversionof plane-wave electromagnetic data: Methodology, model constraints and joint inversion with electrical resistivity data",.Dr..Niklas.Linde,.Centre.de.Recherches.en.Environment.Terrestre,.Faculté.des.Géosciences.et.de.l'environment,.Université.de.Lausanne,.Switzerland.
18/10"Mantle, ocean crust and seawater:where are we, and what’s next in Scientific Drilling",.Dr..Benoît.Ildefons,.ECORD.Distinguished.Lecturer.2013,.Géosciences.Montpellier,.CNRS/Université.Montpellier.2,.France.
07/11"Relative contribution of tectonic inheritance and far field forces on the building of Paleozoic European crust",.Karel.Schulmann,.Institut.de.Physique.du.Globe,.Université.de.Strasbourg,.France.
Theses, Seminars and Courses
68 ANNUAL REPORT ICTJA 2013
Theses, Seminars and Courses
12/11"Magnetotelluric studies in Brazil:Source effects and some application examples",.a.càrrec.de.Antonio.Lopes.Padilha,.Instituto.Nacional.de.Pesquisas.Espaciais,.São.Jose.de.Campos,.São.Paulo,.Brasil
14/11"Quantitative thinking under the volcano:A special marriage among rocks, numbers and experiments to advance the knowledge of volcanic processes",.Antonio.M..Álvarez.Valero,.Departamento.de.Geología,.Facultad.de.Ciencias,.Universidad.de.Salamanca
20/11"Geociència, Art, Wikipedia:contribuïnt amb il·lustracions lliures.Iniciativa wikiArS",.David.Gómez.Fontanills.i.Daniel.Garcia-Castellanos.(ICTJA)
21/11"Evolución geodinámica paleozoica del margen sudoccidental del Gondwana:El basamento de los Andes Centrales",.Prof..Dra..Graciela.I..Vujovich,.Instituto.de.Estudios.Andinos.“Don.Pablo.Groeber”.(IDEAN),.Universidad.de.Buenos.Aires,Consejo.Nacional.de.Investigaciones.Científicas.y.Técnicas,.Argentina
26/11"Exhumation and interactions between a mountain range and its foreland basin: thermochronology and numerical modeling of the Cenozoic Southern Pyrenees",.Charlotte.Fillon..ICTJA-CSIC
4/12"Restitución 3D de estructuras complejas, paleomagnetismo y scanner de rayos X",.Emilio.L..PueyoInstituto.Geológico.y.Minero.de.España,.Unidad.de.Zaragoza;Geología.Estructural,.Dpto..Ciencias.de.la.Tierra,.Universidad.de.Zaragoza
13/12"Un paleontólogo en la Administración: 20 años de gestión de yacimientos y colecciones fósiles en la Región de Murcia",.Gregorio.Romero.Sánchez,.Servicio.de.Patrimonio.Histórico,.Dirección.General.de.Cultura,.Consejería.de.Educación.y.Cultura.de.la.Región.de.Murcia
CoursesCourse:.. Curso Teórico-Práctico de Difracción de Rayos X en Polvo 2013Date: May, 27-28, 2013Location: ICTJA-CSIC, Barcelona
Course:.. Curso Teórico Prácticode ICP-MS 2013Date: May, 29-31, 2013Location: ICTJA-CSIC, Barcelona
Course:.. Curso Internacional de VulcanologíaDate: October, 14-27, 2013Location: Girona
Course:.. Què podem aprendre d’un sismograma?Date: December, 11, 2013, 16:00-19:00Location: ICTJA-CSIC, Barcelona
ANNUAL REPORT ICTJA 2013 69
Editorial and Assessment activities
Editorial
Editors-in-Chief.J. Marti:.Journal.of.Volcanology.and.Geothermal.ResearchJ. Alvarez-Marrón: Geologica.Acta
Editorial activities.D. Brown:.Geological.Society.of.AmericaD. Brown: Journal.of.Asian.Earth.SciencesD. Brown: Solid.EarthR. Carbonell: TectonophysicsP. Anadón: Geologica.Acta
International Committees & CollaborationCommittees
IAVCEI:.Joan Martí. Secretary General of the International Association of Volcanology and Chemestry o fthe Eart Interior (IAVCEI).
IUGG.Commission.–.GRC: Joan Martí. Member of the Executive Committee of the IUGG Commission on Geophysical Risk and Sustainability (GRC).
European. Geosciences. Union: Daniel García-Castellanos. Member of the Program Committee for the “Tectonics and Structural Geology división”.
IAL: Pere Anadón. Member of the Board of Directors. International Association of Limnogeology.
Collaboration
Invited scientists.
AUIP-Argentina:.Ignasi Queralt (Invited scientist)..IDEPA.(Instituto.Mulstidisciplinario.de.Investigación.y.Desarrollo.de.la.Patagonia.Norte).CONICET-Universidad.Nacional.del.Comahue.Neuquén..Asociación.Universitaria.Iberoamericana.de.Posgrado.(AUIP)..November.
IAEA-United.Arabian.Emirates: Ignasi Queralt (International Expert Mission)..University.of.Sharjah..IAEA.Technical.Co-operation.Expert.Mission.on.the.use.of.X-ray.diffraction.for.Environmental.and.Archaeological.research..International.Atomic.Energy.Agency.(IAEA-UN)..September.
70 ANNUAL REPORT ICTJA 2013
UNAM-Mexico: Ignasi Queralt (Invited Scientist).. Instituto. de. Ciencias. del. Mar. y.Limnología..Unidad.Académica.Mazatlán..Universidad.Nacional.Autónoma.de.Mexico..Coordinación.de.la.Investigación.Científica.-.Posgrado.en.Ciencias.del.Mar-CONICYT..June.
ICDP.Science.Conference.2013: Maria José Jurado (Invited speaker)..ICDP.Conference.“Imaging.the.Past.to.Imagine.our.Future”..Postdam,.11-14.November.
JAMSTEC-Japan: Maria José Jurado (Invited Scientist)..Chief.Scientist.of.geophysical.logging.at.Chikyu.IODP.348.Expedition.–.NanTroSEIZE..December.
Invited talks.
D. García-Castellanos:.Opening.of.the.Scholar.Year.of.the.Faculty.of.Geology.. “La gigantesca salina Mediterránea de la crisis messiniense”..University.of.Barcelona.
D. García-Castellanos:.Hutton.Club.invited.seminar..“Tectonics, erosion, and climate in the Mediterranean during the Messinian salinity crisis. Mechanistic understanding emerging from landscape evolution models”..Edinburgh.University.
D. García-Castellanos:.AGU.2013-EP43E-03..“Tectonics, erosion, and climate in the Miocene Mediterranean: a mechanistic approach to the Messinian Salinity Crisis”..San.Francisco.(USA).
D. García-Castellanos:.University.of.Postdam..“Interplay between orogen tectonics and surface processes: A numerical modeling perspective”..Berlin.(Germany).
D. García-Castellanos:.GFZ-Postdam..“Interplay between orogen tectonics and surface processes: A numerical modeling perspective”..Berlin.(Germany).
S. Giralt:."Hacia las reconstrucciones cuantitativas del Cambio Climático a partir del registro sedimentario"..3er.Congreso.Nacional.de.Investigación.en.Cambio.Climático..Mazatlán.(México).
International Committees & Collaboration
ANNUAL REPORT ICTJA 2013 71
The. assessment. of. the. probable. spatial.distribution.of.new.eruptions.is.useful.to.manage.and.reduce.the.volcanic.risk..It.can.be.achieved.in.different.ways,.but.it.becomes.especially.hard.when.dealing.with.volcanic.areas.less.studied,.poorly.monitored.and.characterized.by.a.low.frequent.activity,.as.El.Hierro..Even.though.it.is.the.youngest.of.the.Canary.Islands,.before.the.2011.eruption.in.the.“Las.Calmas.Sea”,.El.Hierro. had. been. the. least. studied. volcanic.Island.of.the.Canaries,.with.more.historically.devoted.attention. to.La.Palma,.Tenerife.and.Lanzarote..We.propose.a.probabilistic.method.to.build.the.susceptibility.map.of.El.Hierro,.i.e..the.spatial.distribution.of.vent.opening.for.future.eruptions,.based.on.the.mathematical.analysis.of.the.volcano-structural.data.collected.mostly.on.the.Island.and,.secondly,.on.the.submerged.
ICTJA –SPA Awards 2013
Spatial vent opening probability map of El Hierro Island(Canary Islands, Spain)
part.of.the.volcano,.up.to.a.distance.of.10-20.km.from.the.coast.
The. volcano-structural. data. were. collected.through. new. fieldwork. measurements,.bathymetric. information,. and. analysis. of.geological. maps,. orthophotos. and. aerial.photographs..They.have.been.divided.in.different.datasets. and. converted. into. separate. and.weighted.probability.density.functions,.which.were. then. included. in. a. non. homogeneous.Poisson. process. to. produce. the. volcanic.susceptibility.map..Future.eruptive.events.on.El.Hierro. is.mainly.concentrated.on.the.rifts.zones,. extending. also. beyond. the. shoreline..The.major.probabilities.to.host.new.eruptions.are.located.on.the.distal.parts.of.the.South.and.West.rifts,.with.the.highest.probability.reached.in.the.south-western.area.of.the.West.rift..High.probabilities.are.also.observed.in.the.Northeast.and.South.rifts,.and.the.submarine.parts.of.the.rifts..This.map.represents.the.first.effort.to.deal.with.the.volcanic.hazard.at.El.Hierro.and.can.be.a.support.tool.for.decision.makers.in.land.planning,.emergency.plans.and.civil.defence.actions.
Reference.
Becerril, L.. et. al.. (2013).. Geophysical.Research.Abstracts,.15,.EGU2013-11037.
InGaN. alloys. have. generated. a. growing.interest. for. photovoltaic. applications,.as. their.band.gap.can.be.tuned.to.cover.the. full. solar. spectrum. and. they. show. a.
Multiphonon Raman scattering in He-irradiated InGaN alloysremarkable.resistance.to.irradiation..This.makes.InGaN.an.attractive.material.system.for. outer. space. solar. cell. applications..Moreover,. owing. to. the. higher. ionicity. of.
72 ANNUAL REPORT ICTJA 2013
the.bonds.and.dynamical.annealing,.GaN.is.extremely.resistant.to.amorphization..Raman.scattering.is.a.powerful.tool.to.characterize.structural. damage. in. irradiated. crystals..With. above. band-gap. excitation,. higher.order. multiphonon. scattering. is. strongly.enhanced. by. impurity-induced. Fröhlich.interaction.. Whereas. close. to. resonance.the.strong.photoluminescence.(PL).signal.in.pure.crystals.prevents.the.clear.observation.of. multiphonon. peaks,. PL. quenching. by.high-fluence.ion-beam.irradiation.makes.it.possible.to.study.the.multiphonon.Raman.peaks.in.implanted.samples.
In.this.work.we.present.a.Raman.scattering.study.of.multiphonons.in.InGaN.alloys.with.In.content.ranging.from.17%.to.42.%.using.near-resonance.visible.excitation.(514.5.nm).and.above.band-gap.UV.excitation.(325.nm)..The.InGaN.epilayers.were.grown.by.plasma-assisted.MBE.on.sapphire.substrates.with.a.GaN.buffer..The.epilayers.were.implanted.with.He.ions.at.40,.88.and.180.keV.with.total.fluences.ranging.from.7.5E12.to.1.9E15.cm-2.to.produce.a.homogeneous.damage.profile. over. the. whole. layer.. The. free.electron.density.and.the.optical.properties.of.the.samples.were.characterized.before.and. after. implantation. by. means. of. Hall.measurements,.PL.and.optical.absorption..In.the.alloys.with.higher.In.composition.the.electron.density.increases.with.irradiation.as.expected.from.the.location.of.the.Fermi.stabilization.energy.above.the.conduction.band. edge.. The. irradiation. effects. are.corroborated.by. the.shifts. in. the.PL.peak.and.absorption.edge..For.the.highest.fluences.the.generation.of.trapping.defects.reverses.this.trend..Outgoing.resonance.conditions.occur.for.the.InGaN.layer.with.[In]=24%.under. 514.5. nm. excitation.. This. sample.
exhibits.a.one.order.of.magnitude.increase.of. the. LO. intensity.. Upon. implantation,.both.the.PL.and.the.LO.intensities.markedly.decrease.but.up.to.4LO.scattering.can.be.detected..In.the.implanted.samples.the.LO.peak.shows.a.downshift.and.an.asymmetric.broadening.which.reflects.the.implantation.damage.. The. higher. order. multiphonon.peaks.display.frequencies.in.good.agreement.with. the. multiples. of. the. LO. frequency..The. multiphonon. Raman. peaks. exhibit. a.substantial.asymmetric.broadening.at.the.low. frequency. side,. which. suggests. the.participation.of.large.wave-vector.phonons.in.the.multiple.scattering..The.Raman.spectra.obtained.with.UV.excitation.show.the.typical.multiphonon.cascade.peaks.up.to.5LO.as.well.as.E2+nLO.combinations..The.same.intensity.ratios.between.successive.order.peaks.are.observed.for.all.alloy.compositions..The.LO/.E2.and.2LO/1LO.intensity.ratios.are.shown.to.be.sensitive.indicators.of.the.irradiation.induced.damage.
Reference.
Dòmenech-Amador, N..et.al..(2013)..Multiphonon. Raman. Scattering. in. He-Irradiated. InGaN. Alloys.. Compound.Semiconductor.Materials.and.Devices..Fall.Meeting.Research.Society..Boston.(USA).
ICTJA-SPA Awards 2013
ANNUAL REPORT ICTJA 2013 73
EXPOMINER-2013 November, 14-16 “The 2013 Expominer and Colecciona edition turn Barcelona into a collector's heaven”
Outreach Activities
ICTJA.has.been.involved.in.EXPOMINER.both.giving.advice.and.actively.organizing.seminars.and.workshops..Dr..Ignasi.Queralt.has.been.a.member.of.the.Advisory.Board.since.1992.and.ICTJA.personnel.has.been.actively.participating.in.the.section.“Living Geology”.
74 ANNUAL REPORT ICTJA 2013
EspaiCiència – 2013 March, 13-17“Thousands of young people got advice at the fair”
Over.65,000.students,.relatives.and.teachers.visited.the.Saló.de.l'Ensenyament.
GEOflaix! – 2013Geoflaix!.is.a.look.at.our.lives.from.the.perspective.of.minerals.and.rocks.that.are.part.of.our.environment..From.minerals.we.obtain.materials.that.are.the.key.to.a.more.comfortable.life..The.exhibition.aims.to.show.visitors.how.the.majority.of.objects.that.surround.us.have.a.geological.basis..It.is.also.a.taste.for.exploring.the.rocks.....what.we.obtain.and.what.they.tell.us!
GEOflaix!.is.co-organized.by.the.Faculty.of.Geology.of.the.University.of.Barcelona,.the.Institute.of.Earth.Sciences.Jaume.Almera.and.the.former.Institute.of.Geology.of.Catalonia.of.the.Generalitat.de.Catalunya.
Outreach Activities
ANNUAL REPORT ICTJA 2013 75
WikiArS – 2013During.the.Week.of.Science.("Setmana.de.la.Ciència").the.Wikimedia.grantee.David.Gómez.and.Daniel.Garcia-Castellanos.(ICTJA-CSIC).gave.a.joint.conference.together.with.a.poster.display.of.illustrations.related.to.the.project.wikiArS...wikiArS.is.an.pioneer.initiative.that.brings.together.the.Academy and Arts schools[1].into.the.Wikimedia.movement's.projects.(Wikipedia,.Wiktionary,.Commons.repository,.etc).by.contributing.scientific.illustrations.that.make.human.knowledge.accessible.to.everyone.
wikiArS.is.designed.to.be.useful.to.students.in.learning.arts.skills.as.well.as.providing.images.and.content.to.the.Wikipedia.and.to.other.free-culture.projects.
Outreach Activities
76 ANNUAL REPORT ICTJA 2013
Funding (2013 Public & Private Funding)
ICTJA in numbers
Services 66.110 6%Competitive Public Funds 333.840 31%
R+D Industry 661.140 61%Public Sector Agreements 16.000 2%
Services 66.110 - 6%Competitive Public Funds 333.840 - 31%R+D Industry 661.140 - 61%Public Sector Agreements 16.000 - 2%
66.110
333.840
661.140
16.000
Services 66.11 - 6%Competitive Public Funds 333.84 - 31%R+D Industry 661.14 - 61%Public Sector Agreements 16.00 - 2%
6
31
61
2
Services 66.11 - 6%Competitive Public Funds 333.84 - 31%R+D Industry 661.14 - 61%Public Sector Agreements 16.00 - 2%
6
31
61
2
TOTAL 1.077.090
ANNUAL REPORT ICTJA 2013 77
Publications
ICTJA in numbersgrafic per edatsgrafic per edats
2006 49
2007 55
2008 59
2009 60
2010 70
2011 77
2012 68
2013 84
0
10
20
30
40
50
60
70
80
90
4955
59 60
70
77
68
84
2006 2007 2008 2009 2010 2011 2012 2013
Evolutions SCI Publications (Total 522)
Publ
icac
ions
SC
I
ICTJA h-index
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 20130
10
20
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40
50
60
70
80