analise biodiesel – (andré) figura 1: cromatograma
TRANSCRIPT
ANALISE BIODIESEL – (André)
Figura 1: Cromatograma.
5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0
0.25
0.50
0.75
1.00
1.25
(x10,000,000)TIC
1 2
3
4 5
67
8
9
Peak
Ret. time
Start time
End time
Area %
Name
1 6.13 6.07 6.19 0.36 Tetradecanoic acid, metil ester
2 9.08 8.96 9.18 0.70 9-hexadecenoic acid, metil ester
3 9.49 9.30 9.60 15.16 Hexadecanoic acid, metil ester
4 11.04 10.95 11.16 0.58 10,13-eicosadienoic acid, metil ester
5 11.54 11.45 11.66 0.52 Heptadecanoic acid, metil ester
6 14.03 13.33 14.07 60.80 8,11-octadecadeinoic acid, metil ester
7 14.16 14.07 14.27 14.53 7-octadecenoic acid, metil ester
8 14.34 14.26 14.40 1.41 9,12,15-octadecatrienoic acid, metil ester
9 14.56 14.41 14.63 5.94 Octadecanoic acid, metil ester
Tabela 1: Identificação dos picos do cromatograma.
Figura 2: Fragmentograma do pico 1.
Figura 3: Fragmentograma do pico 2.
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 2400.0
25.0
50.0
75.0
100.0
%
74
87
1435543
199101 12997 157 185 211115 17139 242
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 2400.0
25.0
50.0
75.0
100.0
%
55
69
8374 97
41
110
123
152137236194135
165 20732 179 218
50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.00.0
25.0
50.0
75.0
100.0
%
74
87
143
43 22755129
185101 171 199 239 270157115 213125 27231 255
Figura 4: Fragmentograma do pico 3.
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 2500.0
25.0
50.0
75.0
100.0
%
81
67
96
110
54 123
121 137152 250166 20832 207
22151 179
Figura 5: Fragmentograma do pico 4.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.00.0
25.0
50.0
75.0
100.0
%
74
87
14332 43 55
101 241129 185 199111 157 255171 227213 284
Figura 6: Fragmentograma do pico 5.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
8167
95
55
10941
123150
262164178 294220191 205 234 24531
Figura 7: Fragmentograma do pico 6.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
55
69
41 83 97
111264
123222
138 180166
235207194 29624631 278
Figura 8: Fragmentograma do pico 7.
50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
79
9567
108
12141135
149
17316339 191 264236222207 249 292
Figura 9: Fragmentograma do pico 8.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
74
87
143
25543 19955
129101298185157 213 241 267111 171
31
Figura 10: Fragmentograma do pico 9.