anaerobic wasterwater treatment

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    The Wastewater Treatment

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    INTRO: WWT Process Categories

    Suspended Growth Process microorganisms

    are maintained afloat in the reactor by an

    appropriate mixing method, i.e. activatedsludge, ponds and lagoons, and digesters.

    Attached Growth Process microorganisms

    are fixed to some object, i.e. trickling filters,

    rotating biological contactors.

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    INTRO: Types of Treatment

    Aerobic Treatment with oxygen

    Anaerobic Treatment without

    oxygen

    Anoxic Treatment BNR

    NOTE: selection depends on degreeof treatment and pollution load

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    Anaerobic WWT Process

    Breakdown of organic matter bymicrobiological population in an

    oxygen-free environment

    Literally means without air

    Used for high organic load

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    Anaerobic WWT Process

    a multi-stage process occurringsimultaneously

    Every stage is accomplished bydifferent group of bacteria eachproducing by-products

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    Anaerobic Metabolic Steps

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    Acidogenesis & Acetogenesis

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    Acidogenesis

    acid production process

    fermenting bacteria

    volatile acids (butyric, propionic),alcohol, carbon dioxide, and

    hydrogen

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    Acidogenesis & Acetogenesis

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    Methanogenesis

    production of methane

    aceticlastic and H2-oxidizing

    methanogens (domain Archaea)methane and carbon dioxide

    N.B. within a certain range of pH (6.5-

    7.6) and temperature (35-37)

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    A Closer Look at the H2Productionvia Anaerobic Oxidation

    Rxn2 FermentationH2 produced is small

    Most H2 comes from

    oxidation of volatileand long chain fattyacids, Rxns 3 & 4called anaerobicoxidation

    Rxns inhibited byhigh H2 partialpressures

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    Interspecies Hydrogen Transport

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    Interspecies Hydrogen Transport

    where vikis the stoichiometric coefficient for component i in

    reaction k withmkcomponents, a

    iis the activity of component

    i, R is the universal gas constant, and T is absolute temperature

    A close syntrophic relationship exist among microbial species

    The same relationship and phenomenon occurs with butyrate

    and propionate conversion to acetic acid and H2

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    Interspecies Hydrogen Transport

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    Interspecies Hydrogen Transport

    where J is the flux of H2bet. the organisms

    (mol.sec-1); Rtis the H2 turnover rate (sec-1),Mdis the H2 mass in solution (mol); Az is thedistancebetween species (cm); C, and C, arethe H2concentrations at the surface of theH2-producing and H2-consuming species,respectively (mol.cm-3); and A is the cross-sectional area across which diffusion occurs(cm2); D is the molecular diffusivity of H2inwater (cm2 sec-1).

    Diffusion drives the H2 transportbetween producing and

    consuming species

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    Typical SRT in Anaerobic at 35oC

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    Dis/Advantagesof Anaerobic Systems

    Low production of sludge/biosolids

    High treatment efficiency, up to

    90% COD removalLow capital cost, reactor tank

    No O2, low power reqt

    Methane prodn, biofuel

    Sensitive to temperature and pH

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    THANK YOU

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    The Case of Biofilm

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    The Case of Biofilm

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    The Case of Biofilm

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    The Case of Biofilm