siloxane based organic-inorganic hybrid polymer and their...

Publikasi di Jurnal Internasional Terindeks Scopus

ISSN: 1978-3051

http://journal.itb.ac.id/index.php?li=article_detail&id=804

Siloxane based Organic-Inorganic Hybrid

Polymer and their Application for

Nanostructure Optical/Photonic

Component

ITB Journal of Engineering Science

Vol 44 No 3, 207-219 (2012), April 2013 DOI Number : 10.5614/itbj.eng.sci.2012.44.3.1

Rahmat Hidayat, Widiyanta Gomulya, Pina Pitriana, Ryan

Irmansyah, Rany Miranti, Herman, Sahrul Hidayat,

Fitrilawati, Akihiko Fuji, Masanori Ozaki

Editorial Board

Journal of Engineering and Technological Sciences

Tjandra Setiadi, Prof.,Ph.D [ Executive Editor ] Faculty of Industrial Technology, ITB, Indonesia

tjandra@che.itb.ac.id

Sigit Sukmono, Dr.Ir., MSc. Faculty of Mining and Petroleum Engineering,

ITB, Indonesia sukmono@gf.itb.ac.id

Deddy Kurniadi, Prof.Dr.

Faculty of Industrial Technology, ITB, Indonesia kurniadi@tf.itb.ac.id

Tatacipta Dirgantara, Dr.Ir., MT.

Faculty of Mechanical and Aerospace Engineering, ITB, Indonesia

tdirgantara@ftmd.itb.ac.id

Indah Rachmatiah Siti Salami, Ir.,MSc.,PhD.

Faculty of Civil and Environmental Engineering, ITB, Indonesia

indahrss@yahoo.com

Hasanuddin Z. Abidin, Prof.

Faculty of Earth Sciences and Technology, ITB,

Indonesia

hzabidin@gd.itb.ac.id

Masyhur Irsyam, Prof.Dr.Ir.,MSE.

Faculty of Civil and Environmental Engineering,

ITB, Indonesia

masyhur.irsyam@yahoo.co.id

Prof. Louis Jezequel

Structural and System Dynamics and Control, Ecole Centrale, Lyon, France

louis.jezequel@ecl-lyon.fr

Aiqin Wang, Dr.

Center for Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese

Academy of Sciences , P.R. China aqwang@licp.cas.cn

Teruyuki Kato, Prof. Earthquake Research Institute, Univ. of Tokyo,

Japan tkato@mri-jma.go.jp

Masaaki Okuma, Prof.

Department of Mechanical and Aerospace Engineering, Tokyo Institute of Technology,

Japan

mokuma@mech.titech.ac.jp

Suwarno, Prof.Dr.Ir.,MT. School of Electrical Engineering and Informatics,

ITB, Indonesia suwarno@stei.itb.ac.id

Graeme Fairweather, Prof. Department of Mathematical and Computer

Science, Colorado School of Mines Golden, USA gfairwea@mines.edu

Andrew F. Seybert, Prof.

Dept. Mechanical Eng., Univ. Kentucky, USA seybert@engr.uky.edu

El Sayed Youssef, Prof. Geology Department, Faculty of Science, Cairo

University, Giza, Egypt elsayedyoussef2005@yahoo.com,

elsayedyoussef@hotmail.com

Pekik Argo Dahono, Dr.Ir.

Indonesian Engineering Association (PII), Indonesia

padahono@gmail.com

Prof.dr.ir. Marinus Cornelis Maria (Mark)

van Loosdrecht

Department of Biochemical Engineering, Delft

University of Technology M.C.M.vanLoosdrecht@tudelft.nl

Contents

Journal Vol. 44B No. 3, 2012

1. Miscibility Development Computation in Enhanced Oil Recovery by Flare Gas

Flooding, Tjokorde Walmiki Samadhi, Utjok W.R. Siagian, Angga P. Budiono

2. Confinement of Reinforced-Concrete Columns with Non-Code Compliant

Confining Reinforcement plus Supplemental Pen-Binder, Anang Kristianto,

Iswandi Imran, Made Suarjana & Ivindra Pane

3. Experimental Study of Confined Low-, Medium- and High-Strength Concrete

Subjected to Concentric Compression, Antonius, Iswandi Imran

4. Characteristics of Oxidative Storage Stability of Canola Fatty Acid Methyl Ester

Stabilised with Antioxidants, Tirto Prakoso, Parncheewa Udomsap, Akiko

Tanaka, Toshihiro Hirotsu & Shinichi Goto

5. Siloxane based Organic-Inorganic Hybrid Polymers and their Applications for

Nanostructured Optical/Photonic Components, Rahmat Hidayat, Widiyanta

Gomulya, Pina Pitriana, Ryan Irmansyah, Rany Miranti, Herman, Sahrul

Hidayat, Fitrilawati, Akihiko Fuji, Masanori Ozaki

6. The Power Consumption Performance of an Orbiting Screw Solid-Solid Mixer,

Semuel Pati Senda, Renanto, Achmad Roesyadi, Wahono Sumaryono & Yazid

Bindar, Renanto Handogo, Achmad Roesyadi, Wahono Sumaryono, Yazid

Bindar

7. The Effect of Ozonation Process on Bromide-Containing Groundwaters in

Bandung Area and Its Surroundings, Mindriany Syafila, Sukandar & Eric

Haryanto

ITB J. Eng. Sci., Vol. 44, No. 3, 2012, 207-219 207

Received January 11th, 2011, Revised February 28

th, 2012, Accepted for publication May 20

th, 2012.

Copyright © 2012 Published by LPPM ITB & PII, ISSN: 1978-3051, DOI: 10.5614/itbj.eng.sci.2012.44.3.1

Siloxane based Organic-Inorganic Hybrid Polymers and

their Applications for Nanostructured Optical/Photonic

Components

Rahmat Hidayat1*, Widiyanta Gomulya

1, Pina Pitriana

1, Ryan Irmansyah

1,

Rany Miranti1, Herman

1, Sahrul Hidayat

2, Fitrilawati

2, Akihiko Fujii

3 &

Masanori Ozaki3

1Physics of Photonics and Magnetism Research Division, Faculty of Mathematics and

Natural Sciences, Bandung Institute of Technology, Indonesia 2Department of Physics, Faculty of Mathematics and Natural Sciences,

Padjadjaran University, Indonesia 3Division of Electrical, Electronic and Information Engineering, Faculty of Engineering,

Osaka University, Japan

E-mail: rahmat@fi.itb.ac.id

Abstract. We have studied the preparation of organic-inorganic hybrid polymer

precursors by sol-gel technique and their utilization for nanostructured optical

components for photonic applications. The gel polymer precursors were prepared from siloxane modified by polymerizable acrylate groups, which can be

processed further by photopolymerization process. Molecular structure

characterizations by means of the FTIR measurements indicate the conversion of

C=C bonds into C-C bonds after photopolymerization. This bond conversion

produces high cross-linking between the organic and inorganic moieties,

resulting in thermally stable and chemically resistant thin polymer layer which

provide unique advantages of this material for particular optical/photonic

applications. By employing laser interference technique, gratings with

periodicity between 400-1000 nm have been successfully fabricated. Application

of those sub-micron periodicity of grating structure as active elements in

optically pumped polymer laser system and Surface Plasmon Resonance (SPR) based measurement system have been also explored. The experimental results

therefore also show the potential applications of this hybrid polymer as a

building material for micro/nano-photonics components.

Keywords: hybrid polymers; nano-optics; optically pumped polymer laser; pulsed

laser interference; sol-gel materials; surface Plasmon resonance.

1 Introduction

Functional polymers have attracted much attention for various applications in conventional optics, micro/nano-optical components, such as photonic band gap

(PBG) structure, and micro-electro-mechanic systems (MEMS) [1-6].Easiness

in fabrication process, which commonly does not require high temperature, is one of the main advantages of polymers. Such processing condition allows the