i • received jan 6 1996 alamos national labs... · 2013. 6. 13. · ms. haight -2- january 10,...
Post on 31-Mar-2021
2 Views
Preview:
TRANSCRIPT
) <;
'
I •
RECEIVED JAN 1 6 1996
January 10, 1996 ( .. 1Hrl_~ RC!J'fE TO: _J-/ \....../_J.
- ...:rRO-'
Ms. Pat Haight Kentucky Division of Solid Waste
14 Reilly Road
~fCLv
Ff.B 0 5 mJ C JJJJ ,_/ '/rg~:~~ ...
~:;·re.-
Frankfurt, Kentucky 40601
Dear Ms. Haight:
TOXIC SUBSTANCES CONTROL ACT INCINERATOR RESIDUALS RESULTING
FROM TREATMENT OF PADUCAH GASEOUS DIFFUSION PLANT WASTES
As requested during the teleconference on Monday, December 18, 1995, the following information is
provided: 1) Resources Conservation and Recovery Act (RCRA) waste codes and radionuclides
expected to be present in the residuals, 2) estimated quantities of residuals, which would be prorated
to Paducah Gaseous Diffusion Plant (PGDP), together with formulas showing how the prorated
share is calculated, and 3) available characterization information for residuals, which have been
generated and are being disposed of at the Envirocare disposal facility in Utah. As discussed, PGDP
liquid wastes will be coburned together with liquid waste from other sites, as well as solid waste
(including soils added to moderate the burn temperature) from the Oak Ridge Reservation (ORR).
Radionuclide and hazardous constituent information is based on actual analyses of residuals
generated to date, as well as review of the Toxic Substances Control Act (TSCA) Incinerator waste
acceptance criteria. Table A provides a list of radionuclides that have been accepted for treatment
and found in the residuals to date. Table B lists the waste codes that have been accepted for
treatment and are associated with residuals generated to date. These tables represent characteristics
anticipated to be associated with future TSCA Incinerator residuals.
Based on a more detailed review of the TSCA Incinerator permit, the listing provided in TableD
includes all waste codes, which the TSCA Incinerator may accept and which could potentially be
associated with residuals generated in the future. Although all the waste codes are listed in portions
of the pending PGDP RCRA storage permit modification (Revision 10), there are six codes that are
not included in all sections of the permit modification. The waste codes are F006, F008, U248,
U328, U353, and U359. PGDP personnel will submit a permit modification (Revision ll) to add
these six waste codes. Based on conversations between PGDP personnel and Kentucky Division of
Solid Waste personnel, we understand this would be considered a minor permit modification.
Available analytical data for TSCA Incinerator sludge and ash generated to date and currently being
disposed at the Envirocare facility is enclosed. As ORR solids are coburned in the incinerator
beginning in Fiscal Year (FY) 1996, some constituent concentrations are expected to chagge;
however, no new hazardous or radiological constituents are expected to be introduced. If new
1111111 IIIII 1111111111 11111111
1764
,-==-Fc 4
Ms. Haight -2- January 10, 1996
hazardous or radiological- constituents not included in Tables A and B are introduced during
FY 1996, we will notify you. Additional characterization data for residuals resulting from
cobuming of solids with the liquid wastes is expected to be available in the summer of 1996 and will
be provided to you when available.
Table C contains estimated amounts of liquid waste to be received from PGDP and the
corresponding estimated prorated share ofTSCA Incinerator residuals which would be returned to
PGD P if Oak Ridge's current method of direct disposal were to become unavailable. The quantity
estimates for residuals generation and prorating of residuals are based on historical TSCA
Incinerator operational information for "liquids only" bums. A detailed explanation of the prorating
calculation is included in Table C. Although the information provided is based on the FY 1996
TSCA Incinerator Bum Plan, the same method would be used to prorate residues from treatment of
PGDP liquids in future years.
The information provided in this letter applies only to the residuals generated from treatment of
PGDP's liquid wastes in the TSCA Incinerator and does not apply to any residues that might be
generated from the treatment ofPGDP solids wastes in the future. The prorating assumptions for
solids must be developed in the future based on operational experience gained through processing
ORR solids. Quantity estimates and additional waste characterization information will be provided
to address prorating of residues from processing solid waste as that information becomes available.
This information can be included in a future version of the PGDP residuals management
contingency plan.
Based on this information, please verify whether the residuals from treatment of the PGDP liquid
waste scheduled for FY 1996 could be returned to the PGDP site for storage, if required as a
contingency, under the terms of PG D P 's RCRA storage permit and modifications discussed above.
As discussed in the teleconference of January 3, 1996, return of the residuals would not take place
until FY 1997. In particular, please verify whether the 1.6 drums of residuals resulting from the
waste to be received and burned in January 1996 could be returned sometime in FY 1997, if
necessary, under the terms of the storage permit and modifications discussed above.
Ifyou have questions or need additional information, please call Joy Sager of my staff at
(423) 576-0850.
Enclosures
(cc's on page 3)
Sincerely,
~Rad7~ Waste Mana ement and Technology
Development Division
' I
. '
Ms. Haight
cc w/enclosures: E. Leming, TDEC, OR V. Adams, EW-96 W. Cahill, EW -91 N. Cames/R. Blumenfeld, CC-10 J. Hodges, EF-21 B. Hightower, K-1037, MS 7357 T. Morris/L. Mezga, K-1037, MS 7357
-3- January 10, 1996
-~ ·.~
TABLE A
RADIONUCLIDES IN TSCA INCINERATOR RESIDUES TO DATE
Cs-137, Pa-234m, Co-57, Co-60, I-131, Np-237,
Sr-89/90, Tc-99, Th-228, Th-230, Th-232,
Th-234, Pu-238, Pu-239, Am-241, U-234, U-235,
U-238
TABLE B
RCRA WASTE CODES FOR TSCA INCINERATOR RESIDUES TO DATE
FOOl, F002, F003, F004, FOOS, F006, F039
U002, U003, U019, U031, U037, U052, U070, U078,
U080, Ul03, U108, U112, Ull7, Ul21, U122, Ul31,
Ul54, Ul61, U188, Ul96, U210, U211, U213, U220,
U226, U228, U239, U359
I I
Liquids 1996 Treated
Jan. 85.000 lb
FY 434,300 lb
TABLE C
PADUCAH GASEOUS DIFFUSION PLANT PRORA.TED RESIDUALS
Prorated Slud~e Prorated Ash
1.5 drums (654 !b) 0.1 drum (35 !b)
7.5 drums (3340 lb) 0.4 drum (180 lb)
Total Prorated Residual Amount
1.6 drums (689 !b)
7.9 drums (3520 !b)
As wastes are treated in the TSCA Incinerator. the volume _is reduced.
1. Sludge
Based on historical data, the volume reduction factor for estimating the volume of
residual sludge resulting from the treatment of liquid wastes is 26:1. Since these sludges
are approximately 90 to 95% water, their volume is further reduced by a factor of 5:1
through dewatering. The final volume reduction factor for sludge is 130:1. The prorated
amount of sludge is calculated by applying this volume requction factor to the amount of
liquid waste processed (i.e. 85,000 lb I 130 = 654 lb).
2. Ash
Based on historical data. the volume reduction factor for estimating the volume of
residual ash resulting from the treatment of liquid wastes is 2400: I. The prorated amount
of ash is calculated by applying this volume reduction factor to the amount of liquid
waste processed (i.e. 85,000 lb /2400 = 35 !b).
The sludge residues are not expected to change significantly in character due to the
introduction of solids being coburned with liquids. The soils being co burned with the
liquids and combustible solids will be present mainly in the ash residues. In order to
minimize concerns related to the return of residual ash containing Oak Ridge soils to
PGDP, while assuring the quantity of residues returned is equitable and consistent with
the volume of original waste treated. the total prorated residuals amount could be returned
as dewatered sludge (i.e. I .6 drums of sludge would be returned. rather than 1.5 drums of
sludge and 0. l drums of ash)
' I
TABLED
SUMMARY OF WASTE CODES ACCEPTED AT THE TSCA INCINERATOR
Hazardous Waste Hazard EPA Hazardous Waste Code
Ignitable DOOl
Corrosive 0002
Arsenic Toxic D004
Barium Toxic D005
Cadmium Toxic D006
Chromium Toxic 0007
Lead. Spent Batteries Toxic D008
Mercurv Toxic D009
Selenium Toxic DOlO
Silver Toxic DOll
End.rin Toxic D012
Undane Toxic D013
Methoxychlor Toxic D014
Toxaphene Toxic 0015
2, 4-0 Toxic 0016
2, 4, 5-TP Toxic 0017
Benzene Toxic 0018
Carbon Tetrachloride Toxic 0019 I
Chlordane Toxic D020
Chi oro benzene Toxic D021
Chloroform Toxic D022
o-Cresol Toxic 0023
m-Cresol Toxic D024
p-Cresol Toxic 0025
Cresol (specific isomer is unknown) Toxic D026
1. 4-Dichlorobenzene Toxic D027
1.2-Dichloroethane Toxii}.- 0028
1.1-0ichloroethvlene Toxic 0029
2. 4-0initrotoluene Toxic 0030 I
TABLED
SUMMARY OF WASTE CODES ACCEPTED AT THE TSCA INCINERATOR
Hazardous Waste Hazard EPA
Hazardous Waste Code
Heptachlor Toxic 0031
Hexachlorobenzene Toxic 0032
Hexachlorobutadiene Toxic 0033
Hexachloroerllane Toxic 0034
Methyl Ethvl Ketone Toxic 0035
Nitrobenzene Toxic 0036
Pentachlorophenol Toxic 0037
PYridine Toxic 0038
Tetrachloroethylene Toxic 0039
Trichloroethylene Toxic 0040
2, 4, 5-Trichlorophenol Toxic 0041
2, 4, 6-Trichlorophenol Toxic 0042
Vinyl Chloride Toxic 0043
Spent Halogenated Solvents, Sludges from the Recovery of Specific Solvents Toxic FOOl and F002
Spent Non-Halogenated Solvents, Sludges from the Recovery of Specific Ignitable F003
Solvents
Spent Non-Hazardous Solvents, Sludges from the Recovery of Specific Toxic F004
Solvents
Spent Non-Halogenated Solvents Sludges from the Recovery of Specific Ignitable, FOOS
Solvents Toxic
Waste Water Treatment Sludges from Electroplating Operations except from Toxic F006
Specific Processes
Plating Bath Residues from the Bottom of Plating Baths from Electroplating Reactive, F008
Operations where Cyanides are used in the Process Toxic
I I
-TABLED
SUMMARY OF WASTE CODES ACCEPTED AT THE TSCA INCINERATOR
"P" and "U" HAZARDOUS WASTE CODES
The basis for hazardous designation for all EPA Hazardous Waste Codes is derived from Tennessee Rule
Chapter 1200-1-11-.02. The name of the substance is also found in Tennessee Rule Chapter 1200-1-11-.02.
"P" Hazardous Waste Codes
POOl P013 P027 P041 P056 P069 P084 P099 P113
P002 P014 P028 P042 P0 57 P070 P085 PlOl Pl14
P003 POlS P029 P043 P058 P071 P087 Pl02 P115
P004 P016 P030 P044 P059 P072 P088 P103 Pl16
POOS P017 P031 P045 P060 P073 P089 Pl04 P118
P006 P018 P033 P046 P062 P074 P092 P105 P119
P007 P020 P034 P047 P063 P075 P093 P106 Pl20
P008 P021 P036 P048 P064 P076 P094 Pl08 Pl21
P009 P022 P037 P049 P065 P077 P095 P109 Pl22
POlO P023 P038 P050 P066 P078 P096 PllO P123
POll P024 P039 P051 P067 P081 P097 Plll -
P012 P026 P040 P0 54 P068 P082 P098 P112
I I
TABLED
SUMMARY OF WASTE CODES ACCEPTED AT THE TSCA INCINERATOR
"P" and "U" HAZARDOUS WASTE CODES
The basis for hazardous designation for all EPA Hazardous Waste Codes is derived from Tennessee Rule
Chapter 1200-1-11-.02. The name of the substance is also found in Tennessee Rule Chapter 1200-1-11-.02.
"U" Hazardous Waste Codes
U001 U028 U056 U083 Ulll U137 Ul64 U191 U221
U002 U029 U057 U084 Ul12 U138 U165 U192 U222
U003 U030 U058 U085 U113 U140 U166 U193 U223
U004 U031 U059 U086 U114 Ul41 U167 Ul94 U225
U005 U032 U060 U087 U115 Ul42 Ul68 Ul96 U226
U006 U033 U061 U088 Ul16 U143 Ul69 Ul97 U227
U007 U034 U062 U089 U117 Ul44 U170 U200 U228
U008 U035 U063 U090 U118 U145 Ul71 U201 U234
U009 U036 U064 U091 Ul19 Ul46 U172 U202 U235
UOlO U037 U066 U092 U120 Ul47 U173 U203 U236
UOll U038 U067 U093 U121 Ul48 U174 U204 U237
U012 U039 U068 U094 U122 Ul49 Ul76 U205 U238
U014 U041 U069 U095 U123 U150 Ul77 U206 U239
U015 U042 U070 0096 Ul24 U151 0178 0207 0240
U016 U043 U071 U097 U125 U152 0179 U208 0243
U017 U044 0072 U098 Ul26 U153 Ul80 U209 U244
U018 U045 U073 0099 U127 U154 Ul81 U210 U246
U019 U046 U074 UlOl U128 U155 U182 U211 U247
U020 U047 U075 U102 Ul29 U156 Ul83 U213 U248
U021 U048 U076 Ul03 U130 U157 Ul84 U214 U249
U022 U049 U077 U105 U131 U158 U185 U215 U328
U023 U050 U078 U106 U132 U159 U186 U216 U353
U024 U051 U079 0107 U133 U160 U187 U217 U359
U025 U052 U080 0108 Ul34 Ul61 Ul88 U218
U026 U053 U081 U109 U135 U162 Ul89 U219
U027 U055 U082 uno 0136 U163 U190 U220
·~
. .-~..1- 1-l ~ '~ "e A-n:e
SL-uDhi!:
Table 2: Analytical Results from.lndividual Drums and Composite (May 16, 1995 Validated Data)
Analyte No. of Av. Max. Composite EnviroCare Samples Limit
TCLP Metals (mg/L)
Antimony NA NA NA <0.50 2.1
Arsenic 6 0.0394 0.0617 <0.50 5.0
Barium 17 0.313 0.971 <10 7.6
Beryllium NA NA NA <0.010 0.014
Cadmium 17 0.0359 0.065 <0.10 0.19
Chromium 17 0.0411 0.094 <0.50 0.86
Lead 17 0.0907U .15U <0.50 0.37
Nickel NA NA NA 1.9 5.0
Thallium NA NA <0.05 1 <0.20 0.16
Selenium 17 0.0199 0.0544 <0.50 0.30
Silver 17 0.0340U 0.05U <0.50 0.078
Vanadium NA NA NA <0.10 0.23
Zinc NA NA NA 0.53 5.3
Mercury 17 0.0002U 0.0002U <0.02 0.025
1 Analytical Results indicate "total metal concentration (ppm) of thallium is < 1.0 ppm. Utilizing accepted industry standard of
dividing "total metals concentration" by 20 to estimate minimum TCLP (mg/L) results in estimated value of < 0.05 thus satisfying Land Disposal Requirements (LOR) Universal Treatment Standards (UTS).
'
Analyte No. of Av. Max. Composite EnviroCare Samples Limit
'
TCLP Volatile Organics (mg/L)2
Carbon Tetrachloride 25 0.04832 0.058U 0.05U 0.5
Chlorobenzene 25 4.42600 lOU lOU 100
Chloroform 25 0.2900 0.6U 0.6U 6.0
Tetra- 11 0.05 0.05U 0.07U 0.7 chloroethene
Trichloroethene 11 0.07 0.07U 0.05U 0.5
Vinyl Chloride 25 0.0608 O.lU 0.02U 0.2
1,2-Dichloroethane 25 0.04800 0.05U 0.05U 0.5
1,1-Dichloroethene 11 0.07 0.07U 0.07U 0.7
2-Butanone (Methyl ethyl ketone) 25 8.8520 20U 20U 200
Benzene 25 0.04800 0.05U 0.05U 0.5
1,4-Dichlorobenzene 25 0.06 O.lU 0.75U 7.5 ---------- -- . __
-~-------
2Results from total analyses available in Attachment 2.2. All individual volatile analytes below required reporting limit.
_;i:i.
Analyte No. of Av. Max. Composite EnviroCare Samples Limit
TCLP Base-Neutral, Acids3
2,4-Dinitrotoluene 25 0.06 O.lU 0.013U 0.02
Hexachlorobenzene 25 0.06 0.1U O.Ol3U 0.13
Hexachlorobutadiene 25 0.06 O.lU 0.05U 0.5
' Hexachloroethane 25 0.06 0.1U 0.3U 3.0
Nitrobenzene 25 0.06 O.lU 0.2U 2.0
Pyridine 14 0.1 0.1U 0.5U 5.0
2,4, 6-Trichlorophenol 25 0.28 0.5U 0.2U 2.0
Pentachlorophenol 25 0.28 0.5U lOU 100
0-Cresol 11 0.01 0.01U lOU 200
M&P-Cresol 11 0.02 0.02U 40U 200
2, 4,5-Trichlorophenol 25 0.28 0.5U 40U 400
1 ,4-Dichlorobenzene 25 0.06 0.1U 0.75U 7.5
TCLP Pesticides (mg/L)
Chlordane 25 0.01397 0.003U <0.003 0.03
Endrin 25 0.00101 0.002U <0.002 0.02
Lindane 25 0.017666 0.04U <0.04 0.4
Heptachlor 25 0.000418 0.0008U <0.0008 0.008 ---------- ~L___ ______ ,_
--------- ----- -------
3 All individual analyte results included in Attachment 2.2. All detects were phthalate esters, common lab contaminants.
...
------ - --- ----·-
Analyte No. of Av. Max. Composite EnviroCare II
Samples Limit
Methoxychlor 25 0.44066 1U < 1.0 10
Toxaphene 25 0.0233 0.05U <0.05 0.5
TCLP Herbicides (mg/L)
Silvex 19 0.030 0.1U <0.004 1.0
2,4-D 19 0.27 IU <0.02 10.0
2,4,5T 14 0.005 0.005U <0.02 .2
PCBs (arochlor) (ug/g) 25 0.3251 0.95U 50 ppm
PCBs (congeners) See Table 2.0 ppm per 1 TSCA permit
-·--
(
:lP
- ---- ------------------------
Analyte No. of Av. Max. Composite EnviroCare Samples Limit
Radiochemistry (pCi/g)4 ,5
Total Activity Biased 7.69E3 (+/-Low 2.4E2)
Alpha Activity 27 8078.7 13798.5 2.84E3 ( +/-(2423.6) (4139.5) 1.5E2)
Beta Activity 27 10516.1 19796.2 3.32E3 (+I-(3154.8) (5938.8) l.2E2)
Cs-137 26 <0.74 <2.1 -8.37E-2 ( + 1- 5.6E2 (.222) (.63) l.9E-l)
Pa-234m 18 8251.50 17310 3.14E3 (+/- Daughter of U-(2475.5) (5193) 6.4El) 238
Th-234 19 7947.223 15800 9.46El ( +/-4.3) Daughter of U-(2384.1) (4740) 238
Co-60 25 <0.40 < 1.2 NA 3.6E2
Np-237 27 3.40 9.7 2.08-El ( + 1- 2.0E3 (1.02) (2.91) 7.2E-l)
Sr-89/90 26 7.74 21.7 -6.44 (+/- 2.0E4 (2.32) (6.51) I. 7E 1)
---
, 4 Average and Maximum values on the containers were reported on a dry weight basis. "As received" values have been calculated
by multiplying by the maximum solids value (30%) and are displayed within the parentheses.
5 Ac-228, Tl-208, Bi-212 are daughters of Th-232 and Pb-214 is the daughter of U-238; all daughter activity is accounted for by the parent.
.~on:
~ ------ -- -- --- ---- --- ·---·
I EnviroCare I
Analyte No. of Av. Max. Composite Samples 1 Limit
Tc-99 27 <6.06 24.8 1.05E2 (+I- 1.9E5 (7.44) 4.1El)
Th-230 27 31.15 108 1.26EI ( +/-2.8) 1.5E4 (9.34) (32.4)
Th-232 (Based on Th-228 daughter concentration) 27 4.2 9.8 2.33EO (+I- 6.8E2 (1.26) (2.9) 1.2EO)
Pu-238 . 27 3.03 10.8 2.35EO (+I- l.OE4 (0.91) (3.24) 1.1 EO)
Pu-239 27 15.17 77.6 3.97EO (+/- 9.9E3 (4.55) (23.3) l.4EO)
Am-241 35 4.10 90.3 3.17E-1 (+/- 2.3E2 ( 1.23) (27 .1) 7.8E-l)
U-234 27 2133.5 4975 NA 3.7E4 (640) (1492.5)
U-238 35 3771.7 12190 2.09E3 (+I- 2.8E4 (1131.5) (3657 .0) 3.4E1)
U-235 47 128.5 565.2 6.90E I (+I- 7.7E2 (38.5) (169.5) 6.7E-I)
U-235 (wt%) 23 0.46 0.58 0.50
Total U (ug/g) 15 20776.6 42560 4855 (6232.8) (1276~··· ----- ----- ------- ------- ------ ~-
Analyte
Wet Chemistry
pH
Total Cyanide (ug/g)
Reactive Cyanide (ug/g)
Sulfide (ug/g)
Oil and Grease (mg/Kg)
Paint Filter Test
Density (g/ml)
Total Organic Halides (ug/g)
U: Not detected at the lower reporting limit NA: Not Analyzed
.• ~.&.
No. of Samples
25
13
20
18
NA
9
25
24
Av. Max. Composite EnviroCare Limit
7.68 9.92 8.3
1.640 3.28U <1
<0.14 0.25U NA
<6.68 10 NA
<250
none none
1.91 2.66 0.973
<25 82 <25
,JI
Append ..
Martin Marietta ~nergy Systems, Inc. 101\19-1
Summary of Analytical Results for TSCA Liquid Burn Ash Generated Between October 29, 1991 and December 14, 1993 !Customer Sample
TSCA-9157 TSCA-9258 TSCA-9254 TSCA-9260 TSCA-9250 TSCA-9252 TSCA-9251 Number: !Drum Number: 40819-1 20680-1 20667-2 20691-1 20667-1 20684-1 20691-2 !Laboratory Sample I (or
940510-102 Ma'or Anahses· 940513-018 940513-025 !l40513-04l 940513-060 940517-010 940517-0il l'AKAM£TER: U/1\1 PCB: Aroclor-1254 ug/kg ND i 390 i J 820 i ND t ND ! ND I ND : llomolog ug/g 0.013 l 0.37 : 0.87 i 0.009 l 0.12 i J 0.015 ! J 0.009 l I l>ioxlns/Furans: NR NR NR NR NR NR NR TCI-P (1\letals:) As mg/L < 0.5 ! d < 0.5 d < O . .S i d < 0.5 ! d < 0.5 I d < 0.5 d < 0.5 ! d Ba mg/L < I i d < I d < I ! d < I I d < I : d < I d < I i d Cd mg/L < 0.03 l d < 0.03 d < 0.03 i d < 0.03 ! d < 0.03 i d < 0.03 d < 0.03 i d I Cr mg/L < 0.1 l d < 0.1 d < 0.1 I d < 0.1 l d < 0.1 ! d < 0.1 d < 0.1 IT! Pb mg/L < 0 . .5 : d < 0.5 d < 0.5 I d < 0 . .5 : d < 0 . .5 i d < 0.5 i d < OS i d Ni mg/1. 2.9 I 1.3 0.4.5 I 1.8 l 2 i I 0.68 ! Sc mg/L < 0.5 ! d < 0 . .5 d < 0.5 l d < 0.5 I d < O.S 'I d < 0.5 d < 0.5 i d Ag mg/L < 0.7 i d < 0.07 d < 0.07 I d < 0.07 I d < 0.07 I d < 0.07 l d < 0.07 I d llg mg/L < 0.000.5 l 0.0052 < 0.0005 i < 0.000.5 I < 0.0005 l < 0.000.5 1 < 00005 TCLP ror VOA: Mclhyl elhyl kcwne mg/L 0.056 i J ND i ND i ND ! ND i 0.11 i J 0.11 i I TCLP ror DNA: mg/L ND I ND : ND ! ND ! ND ! ND ! ! TCLP ror II~;: mg/L ND l ND l ND ! ND ! ND i ND I i Radlochemlcal: (+/-) (+/-) (+/-) (+/-) ( +/-) ( +/-) ( t /-) fc-99 pCi/g 11.1 2.9 i 50.) 6.3 i 41.1 6.1 i 10.8 4.9 : 75 6.8 i 14.9 2.1 I 9.92 2.6 i rrolal Aclivily pCi/g 1160 3.5 i 3840 80 ! 2650 70 l 335 41 3070 73 I 372 23 j_ 570 26 ! Np-237 pCi/g 0 8.1 i 13.8 16 l 0 16 l 0 16 8.7 12 I 0.96 3.9 I 4.23 6 l Pu-238 J'Ci/g -2.22 2.5 l -4.44 5 i -3.2 3.9 I -3.25 4 -2.47 4.4 I 0 8 I 0 8.HI Pu-239 pCi/g -2.22 2.5 i -2.66 4.2 ! -2.4 4.2 I -3.25 4 -1.65 2.7 I 0 8 ! 0 8.5 i Th-228 pCi/g 2.3 2 2 l 0 2.7 I 0.69 24 0 2 0 2 ! -0.332 1.1 j 0 1.4 i Th-230 pCi/g 4.99 3.0 l 3.07 3.8 i 8.97 5.3 2.11 3.1 i 3.56 3.8 ! 0.995 2 i 0.706 2 i rTh-232 pCi/g 0 1.31 0 2.7 J 0.69 1.4 0 2.4 I 2.84 2.8 L 0.663 0.94 I 0.706 I i Th-234 pCi/g 265 21 I II 841 60 ! II 575 80 I II .51.7 41 I II 696 160 I 93.4 36 I II 119 26 I II U-234 11Ci/g 23.5 13 i 789 so ! : 611 34 I 55.8 9.1 I 699 35 i 74.6 6.6 I 240 14 ! U-23.5 pCi/g 8.61 0.92 i 35.6 8.4 I 22.4 4.3 L 6.24 7.2 l E 2.5.8 2 I 2.84 6.1 E .5.09 1.1 I U-238 pCi/g 402 17 i • 1080 6.5 • J 870 40 i 87 Ill 772 37 i 113 8.1 319 16 i Cs-137 pCi/g 0.363 0.84 i E -0.177 4 . .5 F 3 . .57 3.2 I -2.91 4.4 I F 0.52 1.7 I E 2.68 .5.8 E 0.824 2.9 l E Pa-234 pCi/g 42.5 120 l II 1420 730 II 704 610! H 10.50 682 i II 887 240j_ H 489 1000 liE -176 530 I Hf Alpha Acrivily pCi/g 386 34 l 1250 81 822 67 i .56.3 31 I 988 72j 136 18 i 186 21 l Bela Acrivil}' pCi/g 456 29 l 1450 67 982 51 i 140 10 I 1160 601 ISO 17 256 21 l K-40 pCi/g NR i NR NR ! NR j NR I NR NR : Ra-226 pCi/g NR ! NR NR ! NR ! NR l NR NR l Nb-9# pCi/g NR i NR NR i NR : NR l NR NR : Cd-109 pCi/g NR l NR NR : NR I NR l NR i NR l Am-241 p{ilg NR l NR NR I NR ! NR i NR NR Mo-99 pCilg NR I NR NR ! ·NR I NR I NR NR Pb-212 pCi/g NR ! NR NR I NR I NR i NR i NR I Ac-228 pCi/g NR
-~
l_ NR NR : NR : NR i NR : NR _L_
p,Pe I of(; ,,.,.,.,, '1\fi!FIT~ f'tlf·llf;" ,.,.,,,, ,,,_. ,.
..;,_<u.
Appcna ....
Martin Marietta Energy Systems, Inc. 101\/Q .•
Summary of Analytical Results for TSCA Liquid Burn Ash Generated Between October 29, 1991 and December 14, 1993
Customer Sam pie TSCA-9257 TSCA-9258 TSCA-9154 TSCA-9260 TSCA-9250 TSCA-9252 TSCA-9253 Number:
Orum Number: 40819-1 20680-1 20667-2 20691-1 20667-1 20684-1 20691-2 Laboratory Sample I Cor
940510-102 940513~18 940513~25 940513~43 94051J~60 940517~10 940517-013 Major Analyses:
PARAMETER: UIM Radiochemical: (+/-) (+/-) ( +/-) ( +/-) (+/-) ( +/-) (U-l U (Auor) ug/g 1761 3019 1679 I 1866 988 i 1869 ! 3406 U (Auor}: Duplicalc ug/g 2864 2456 774 i 1649 2836 I 1546 i 2554 U-235 Wa% 0.49 0.2 0.64 0.02 0.6 0.02 i 0.64 0.02 0.58 0.02! 0.47 0.1 i 0.45 0.02 U-235 (Duplicale) Wa% 0.48 0.02 0.57 0.02 0.65 0.02 I 0.54 0.02 i 0.60 0.04 I 0.46 0.01 I lJ AA: As ug/g < 0.46 i 1.5 i 8.8 I < 0.58 i 0.76 i < 0.51 I < 0.53 i Se ug/g < 0.46 i < 0.46 i < 3.5 I < 0.58 i < 0.46 I < 0.51 I < 0.53 i Tl ug/g_ < 0.92 i < 0.93 i < 7 i < 1.2 ' < 0.93 I < 1.1 I < I ' llg . ug/g < 0.1 i < 0.18 ! < 0.92 i 0.084 I < 0.068 I < 0.088 i < 0.059 I ICP: Sb ug/g < 200 ! d < 130 i d < 240 i d < 230 i d < 100 I d < 180 ! d < 120 ! d Be ug/g 17 i 16 i 6.6 i 23 I 3.8 i 16 l 13 ' Cd ug/g < 12 ! d 8 i < 14 I d < 14 I d < 6 • d < II i d < 7.1 i d Cu ug/g 98 i 130 ' 33 i 66 i 15 j 230 I 62 i Pb ug/g < 200 i d < 130 i d < 240 I d < 230 i d < 100 I d 660 I 120 i Ni ug/g 2700 i 1500 i 73 I 800 I 34 _l 1200 i 220 i Ag ug/g < 23 i d < 16 i d < 29 I d < 27 I d < 12 I d < 21 I d < 14 I d Anions: NOl- (IC) ug/g < 20 i < 20 i < 20 < 20 < 20 < 20 I
< 20 t-I o-POO (IC) ug/g 23 I 47 i 36 26 40 33 J 37 Cl- (IC) ug/g < 20 i 40 i 41 < 20 26 < 20 I < 20 I S04-2 {ICJ ug/&_ 98 ! 213 i 133 32 110 I 62 ! < 20 I F- ug/g 10 I < 10 i 10 I < 10 < 10 I < 10 i < 10 I Reacaive Cyanide mg/K_g NR i NR _! NR I NR 'NR i NR I NR i Reaclive Sulfide mg/Kg NR i NR I NR I NR NR I NR i NR i Physical:
IPII 8.7 I 8.7 I 8.3 i 8.6 i 8.3 i 8.2 i 7.8 l Densiay g/mL 1.47 I 1.76 i 1.86 I 1.6 I 1.81 I 1.73 J 1.68 I
Moislure 7:. 7.1 i < I ' 23.8 I 3.5 I 47.1 ! 14.5 i 2.4 i Aash Poinl oF > 145 i > 145 i > 145 I . > 145 I > 145 I > 145 i > 145 i Painl Filler mL NR I NR i NR I NR I NR i NR I NR i Organics: Oil/Grease r. < 0.1 ! < 0.1 i < 0.1 ! < 0.1 i < 0.1 i < 0.1 i < 0.1 i TOC ug/g 140 i 1897 ' 788 I 60 I 328 I 74 I 231 i VOA· AceaJne ugfK_g_ I i ! i l i i 2-Bulanone ug!Kg i i I 10 I J i i 8 i J Melhylene chloride ug/Kg 2 i J I I ! ! ' DNA: Dieahy I phlhlllaae ug!Kg 51 i JB ! i i i I I .Ql:!!:~ ll'hlhalale ug/Kg 260 i JB 260 i JB 1600 !JB 320 i JB 1600 i JB 390 ! JB 250 i JB
Pagel of6 MARTIN MARIE'TTA ENER(JY SY'iTI'M'i IN('.
c-
Appcnc,_
Martin Marietta Energy Systems, Inc. IOIVO·I
Summary of Analytical Results for TSCA Liquid Burn Ash Generated Between October 29, 1991 and December 14, 1993 Customer Sample
TSCA-9257 Number: TSCA-9258 TSCA-9254 TSCA-9260 TSCA-9250 TSCA-9252 TSCA-9253 Urum Number: 40819-1 20680-1 20667-2 20691-1 20667-1 20684-1 20691-2 Laboratory Sample I Cor l\lajor Analyses:
940510-102 940513~18 940513~25 940513~43 940513~60 940517~10 940517~13
PARAMETER: U/M DNA: bis(2-EIIlylhcxyl) phahalm ug/Kg 150 JB 570 JB 750 JB 150 JB 320 JB 96 !m 54 JB Dimelhvl ohlhalale UI!.IKJt 130 J I Di-n-oclylphlhalale ug/Kg
! Bulvlbenzvl Phlhalale UI!.IKJt i
( Total Organic Halides
ug/g
---- --- - _ _1 -CfOXli_ __ . __
(
Page] of6 M~RTIN 1\fARIFJl'A I'NI'IHiY <;yqr~f<: tnt·
Append!..
s Wf
-cr~
Martin Marietta hnergy Systems, Inc. 101\191
Summary of Analytical Results for TSCA Liquid Burn Ash Generated Between October 29, 1991 and December 14, 1993 Customer Sample
TSCA-9255 TSCA-9259 TSCA-9151 TSCA-9156 TSCA-9161 TSCA-9162 TSCA-101170 Number: lllrum Number: 20682-1 20682-2 20680-2 20684-2 44158-1 44160-1 Composite 1'-aboralory Sample I Cor
94051HIJ6 940517-019 940518-009 940518-012 940518-015 940518-018 46124 (SWRI) 11\talor Analvses: PARAMETER: ll/1\1 PCB: Aroclur-1254 URikR ND j ND i 26 i I 38 i l 51 i I 32 i l ND Homolog ug/g 0.002 i I 0.001 ! I 0.019 ! I 0.035 ! I 0.13 ! 0.11 I NR : llloxlns/Furans: NR NR NR NR NR NR NO TCLP (Metals:)
. { As mg/L < 0.5 i d < 0.5 i d < O.S i d < O.S i d < O.S i d < 0.5 i d < 0.25 Ba mg/L < I i d < I i d < I I d < I i d < I i d < I i d < 0.358 B 11 Cd mg/L < 0.03 i d < 0.03 i d < 0.03 I d < 0.03 I d < 0.03 i d < 0.03 i d < 0.05 Cr mg/L < 0.1 i d < 0.1 i d < 0.1 I d < 0.1 i d < 0.1 i d < 0.1 ! d < 0.05 Pb mg/L < 0.5 : d < 0.5 i d < 0.5 I d < 0.5 i d < 0.5 I d < 0.5 i d < 0.125 Ni mg/L 0.42 : 0.48 i 0.84 ! 3.8 I 0.48 I 0.26 i NR Se mg/L < 0.5 i d < 0.5 ! d < 0.5 i d < 0.5 I d < 0.5 I d < 0.5 I d < 0.01 Ag mg/L < 0.07 i d < 0.07 i d < 0.07 i d < 0.07 I d < 0.07 i d < 0.07 ! d < 0.05 llg mg/L < 00005 i < 0.0005 i < 0.0005 I < 0.0005 i < 0.0005 i < 0.0005 i < 0.0002 TCLP Cor VOA: Mcahyl eahyl ke1o11C: mg/L : ! j 0.19 i J 0.032 l l 0.1 ! I ND I TCLP Cor DNA: mg/L i : ! J ! I NO I TCLP Cor Ill!: mg/L ! : I I i i NO i Radlocbcmlcul: (+/-) (-1 /-) ( +/-) (+I-) ( t/-) ( t/-) ( 1/-) rc-99 J>Ci!.g_ 16.1 2.7 i 8.09 2.4! 106 4.7 I 11.4 2.1 I 93.1 4 j 96 3 4.5 i 2.41 0.04 i Tolal Aclivily pCi/g 294 22 i 303 21 I 967 30 367 23 I 802 26 I 935 30 i 6089 74 i Np-237 pCi/g 0 6.9 i 0 7.1 I 0 7.6+ 2.33 4.7 I 0 6.3 i 4.47 6.3 i 6.92 i Pu-238 pCi/g 2.24 4.5 i 0 8 i 0 8 0 8.7 I 0 7.1 ! 0 8.4 : < 0.015 i Pu-239 pCi/g 0 7.8 i 0 8 ! 0 8 0 8.7 I 0 7.1 ! 0 8.4 i 0.046 0.022! Th-228 pCi/g -0.322 II! -0.664 1.51 -0.667 1.5 -0.726 1.6 -0.586 1.31 -0.349 1.2! 0.027 0.014! Th-230 pCi/g -0.322 1.4 i 3.32 2.7 i 2 2.3 0 1.8+ 3.81 2.6 i 3.84 2.9 : 1.68 0.14 I Th-232 pCi/g 0 1.1 I 0 1.2 I 0.334 0.67 0 1.3 0.293 0.59 I 0 1.2 11.4 0.64 i Th-234 pCi/g 69.8 35 I II -39.2 21 IIIG -1.75 33 IIF 55.9 24 I II 132 35 I II 197 25 II 95.8 0.08 ! U-234 pCi/g 188 IOi 73.3 6.7 ! 248 12 131 9.9 ! 70.1 6.5 I 72 7.3 116 15 I U-235 pCi/g -2.38 6 i F -16.6 3.9 I G 3.96 1.4j 4.13 3.2 I 8.01 4.1 15.3 4 i 88.9 46.4 i U-238 pCi/g 248 12! 87.6 7.3 ! 315 131 202 12 i 102 7.8 88.4 8 i 188 98 i Cs-137 pCi/g -1.49 6.3 i F 0.477 2.7 I E -1.17 1.5 F 0.133 2.7 i E 2.58 5.3 E -0.847 2.3 ! F NO I Pa-234 pCi/g 25.3 1100 i liE 1160 510 i II 39.8 190 II 578 430 : H 867 890 HE 59.1 440 I liE NO I Alpha Activity pCi/g 144 18 I 137 18 i 404 30 166 20 i 308 2.5 i 348 29 : i Beta Activity pCi/g 135 16 134 16 ! 384 24 182 18 : 352 22 394 25 K-40 pCi/g NR NR ! NR I NR ! NR NR 2.87 0.19 Ra-226 pCi/g NR NR ! NR i NR ! NR NR 1.96 0.14 Nb-~5 pCi/g NR NR NR : NR i NR NR 6.71 0.05 Cd-109 pCilg NR NR i NR : NR i NR NR 17.7 0.6 Am-241 p(i/g NR NR : NR I NR i NR i NR 7.34 0.19 M<>-99 pCjlg NR NR l NR I NR i NR i NR 1.91 0.23 Pb-212 pCi/g NR NR i NR I NR i NR i NR 1.76 0.03 • Ac-nB Qg{g._ ___ NR NR : NR ! NR i NR : NR 1.1 () tJ : ----
P•Pe 4 ofti 1-.f ~ llTf~l ~1'\Rll'lT.A FNI'IHIY <:yq Ft f~ !~If'
:; ~;{i
Appendt.
Martin Marietta bnergy Systems, Inc. 10/IN·l
Summary of Analytical Results for TSCA Liquid Burn Ash Generated Between October 29, 1991 and December l4. 1993
Customer Sample TSCA-9255 TSCA-9259 TSCA-9251 TSCA-9256 TSCA-9261 TSCA-9262 TSCA-10K70 Number:
I>rwn Number: 20682-1 20682-2 20680-2 20684-2 44158-1 44160-1 Composile Laboralory Sample I Cor l\lajor Analyses:
9405 17-{116 940517-019 940518-009 940518-012 940518-015 940518-018 461H (S\\'RI}
'I'ARAMETER: U/M Radiochemical: ( +/-) ( t/-) (+/·) (+/·) ( +/-) (+/-) lJ (Auor) uglg_ 1856 1799 1188 3097 l 1020 ! 1977 i 532 IU (Auor): Duplicate ug/g 1786 1461 2587 3732 i 1002 i 758 l £ ,U-235 WI?:. 0.56 0.02 0.59 0.02 0.58 0.04 0.46 0.02 i 0.58 0.02 I 0.53 0 04 ! \ U-235 !Duelicacc} WI?:. 0.55 0.02 0.57 0.02 0.59 004 0.46 0.02 j 0.54 0.02 i 0.55 0.02 !
As ug/g < 0.54 i < 0.53 ! < 0.59 ! < 0.56 ! 0.73 i < 0.58 l 0 29 ! Se ug/g < 0.54 i < 0.53 i < 0.59 I < 0.56 ! < 0.62 i < 0.58 ! 0.8 ill Tl ug/g < 1.1 ! < 1.1 i < 1.2 ! < 1.1 ! < 1.2 ! < 1.2 I 0.2 ill IJg ug/g < 0.13 i < 0.098 i < 0.11 i < 0.1 ! < 0.12 i < 0.12 ! 0.09 ill ICP: Sb ug/g < 270 l d < 200 l d < 230 i d < 210 i d < 250 l d < 230 l d 53 lu De ug/g 8.8 ! 2.1 i 5.1 ! 9.2 i 7.7 ! 3.2 ! 2.8 ! Cd ug/g < 16 ! d < 12 i d < 14 I d < 12 ! d < IS ! d < 14 ! d 0.85 jiJ Cu ug/B, 190 I 37 I 77 ! 100 i 190 i 130 i 40 i Pb ug/g < 270 ! d < 200 i d < 230 i d < 210 I d < 250 i d < 230 i d 21.7 i Ni ug/g 2400 ! 630 ! 1100 ! 1300 ! 790 ! 6800 ! 381 I Ag Ull,/11, < 32 i d < 23 i d < 27 i d < 25 i d < 30 i d < 28 i d 1.3 jll Anions: N03- {J_CJ ug/g < 20 i < 20 I
< 20 I < 20 < 20 i < 20 i i o-P04-3 (IC) ug/g < 0.1 I < 0.1 I < 0.1 26 36 i 47 I Cl- (IC) ug/g < 20 i < 20 ! < 20 < 20 < 20 i < 20 I 504-2 (IC) ug/g 93 ! 63 I 361 65 1178 I 801 F- Ug/£ < 10 < 10 I < 10 < 10 < 10 ! < 10 Reaclive Cyanide mg/Kg NR : NR i NR I NR NR I NR < 0.05 i -~ Reaclive Sulfide mg/Kg NR I NR ! NR I NR I NR i NR ! < 10 I Physical:
t ~ I i I I i pll 8.5 8.3 9.3 8.1 8.3 8.4 8.26 Densily g/mL 1.87 ! 1.53 ! 2.34 J 1.65 i_ 2.15 _I 1.56 I I Moislure r. 17.3 I 19.2 i 39 I s i 44.8 I 27.1 i i Aash Poinl oF > 145 I > 145 ! > 145 I > 145 i > 145 I > 145 i > 212 ! Paine Filler mL NR ! NR i NR ! NR I NR NR 0 ! Organics:
! ! I i ! Oil/Grease % < 0.1 < 0.1 I < 0.1 < 0.1 I < 0.1 i < 0.1 rroc uglg 139 ! 241 ! 142 I 117 l 741 I 137 i I vot I Ace one ug/Kg i i ! i 25 ! J 35 ! J I
2-Bucanone ug/Kg i i i I i I i Melliylene chloride ug/Kg i ! 25 I J i i ! ! DNA: Dielhyl phlhalale ug/Kg 180 ! JB J ! JB I ! ! i 140 I
Di-n-bulvlohlhalale URIKR 640 !Ill 260 .... ~LJB 1100 ! JB S20 i JB 870 iJD 1900 i B I
f \ fJii "IT' l'l !\:n I' I 1
.. Ui
Appcw ..
Martin Marietta bnergy Systems, Inc. 101)/9.(
Summary of Analytical Results for TSCA Liquid Burn Ash Generated Between October 29, 1991 and December 14, 1993
Cuslomer Sample TSCA-9255 TSCA-9259 TSCA-9251 Number: TSCA-9256 TSCA-9261 TSCA-9262 TSCA-101170
Drum Number: 20682-1 20682-2 20680-2 20684-2 44158-1 44160-1 Composite Laboratory Sample I Cor
94051HII6 1\lajor Analyses: 940517-019 940518-009 940518-011 940518-015 940518-018 46124 (S\\'RIJ
PARAMETER: U/M DNA: bis(2-EthylhcAyl) phthalate ug/Kg 1700 j JB 100 j JB 190 iJB 210 lJB 130 lJB 350 JB Dimeth_yl phthalate ug/Kg ! i ! I I Di-n-octylphthalatc ug/Kg 33 iJB i i i i Bu!}'_lbenzyl phthalate ug/Kg i i I S2 jJB i
( Total Organic Halides
ug/g i I i i 80 I < 25 lfffiXlL ___ ' i '
(
Page 6 of6 MARTIN !viARIETfA ENERGY '\Y'\TFMS INC.
AppcnJJX "0 ~118/1~4
Martin Marietta Energy Systems, Inc. Comparison of Hadiochcmical Analysis ofTSCA Liquid Burn Ash to Envirocare of Utah, INC. NllC License Limits
Cwlomer Sampl< TSCA-9257 TSCA-9258 TSCA-9254 TSCA-9260 TSCA-9250 TSCA-9252 TSCA-9253 Number:
l>rum Number; 40819-1 20680-1 20667-2 20691-1 20667-1 20684-1 20691-l Laboralorf Sampl< I Cor
940510-102 940513-018 940513-025 940513-043 940513-060 940517-010 940517-013 MaJor An:aiJStS:
PARAMETER: U/M NRl Umlls U/M (+I-) (+/-) (+I-) ( tt-) (+I-) ( +/-) ( t/-)
pCi/' Tc-99 pCi/g 11.1 2.9 50.3 63 47.7 6.1 10.8 4.9 15 6.11 14.9 2.7 9.92 2.6 1.90E I OS Np-237 pCi/g 0 8.1 13.8 16 0 16 0 16 8.7 12 0.96 3.9 4.23 6 2.00E+03 pCI/il Pu-218 pCi/g -2.22 2.5 -4.44 5 -3.2 3.9 -3.25 4 -2.47 4.4 0 8 0 8.5+ I.OOE-1 04 pCI/g Pu-219 pCi/g -2 22 2.5 ·2.66 4.2 -2.4 4.2 -3.25 4 -1.65 2.7 0 8 0 8.5 9.90Et03 pCi/g Th-230 pCi/g 4.99 3.0 3.07 3.8 8.97 5.3 2.11 3.1 3.56 3.8 0.995 2 0.706 2 I.SOE+04 pCi/g Th-232 pCi/g 0 1.3 0 2.7 0.69 1.4 0 2.4 2.84 2.8 0.663 0.94 0.706 I 6.80E+02 pCi/g U-234 pCi/g 235 13 789 56 J 611 34 55.8 9.1 699 35 74.6 6.6 240 14 3.70E+04 pCilg U-235 pCi/g 8.61 0.92 35.6 8.4 22.4 4.3 6.24 7.2 E 25.8 2 2.84 6.1 E 5.09 3.3 7.70E+02 pCi/g U-238 pCi/g 402 17 • 1080 65 J 870 40 87 II 772 37 113 8.1 319 16 2.80E+04 pCi/g Cs-137 pCilg 0.363 0.84 E -{).117 4.5 F 3.57 3.2 -2 91 4.4 F 0.52 1.7 E 2.68 5.8 E 0.824 2.9 E 5.60E-1 02 pCI/g K-40 pCi/g NR NR NR NR NR NR NR 1.001!+04 pCilg Ra-226 pCi/g NR NR NR NR NR NR NR 2.00E+04 pCi/g Cd-109 pCi/g NR NR NR NR NR NR NR 4 60E+04 pCi/g Am-241 pCi/g NR NR NR NR NR NR NR 2.301i+02 pCi/g Th-234 pCi/g 265 21 II 841 60 II 515 80 H 51.1 41 II 696 160 93.4 36 II 119 26 II Mo-99 pCi/g NR NR NR NR NR NR NR Pb-212 pCi/g NR NR NR NR NR NR NR Ac-228 pCi/g NR NR NR NR NR NR NR Nb-95 pCi/g NR NR NR NR NR NR NR TII-228 pCi/g 2.3 2.2 0 2.7 0.69 24 0 2 0 2 -{).332 1.1 0 1.4 . -- ------ ~- ----- ~- ---------- L___ ---- '---- -- ~--~--- 1
Page I of2 MARTIN MARIEHA ENERGY SYSIFMS, INC
-M~
.;
Appc"J'" 2 0 1(1/1919~
il1artin Marietta Energy Systems, Inc. Com1larison or Radiochemical Analysis or TSCA Liquid Burn Ash to Envirocare or Utah, INC. NRC License Limits
C••hn•tr Saaplc M; TSCA-9155 TSCA-9159 TSCA-9151 TSCA-9156 TSCA-9161 TSCA-9161 TSCA-10810
()ru•ll: 10681-1 10681-1 10686-1 10684-1 44158-1 44160-1 Composite
l.abontory s •• , •• "ror 940517-016 940517-019 940518-009 940518-011 9-f0518-0IS 940518-018 -f61H (SWRI)
Major A .. I7M0:
PARAMETER: U/M ·:-·· . . . . . . . .·.·,.:··· . ··. ···:.-··· .·.·· :>.·.::: .. -:·-.-:····· ·.·.:::-:-:-:- ::-::-· .. · ·-:-:-·-.::.··-:::-:-·:·- ···:··· ··:-:-·-·.· ·.· -:<. •.·.::·-: . .... ····:-·:··.··. ·.·.·:--: -:·-·· ·- NRC l.lmlti-- ll/M (t/-) . (tl-) (+/-) (t/-)' - (+/-) .. (t/·) (t/-)
fc-99 pCilg 16.1 2.7 8.09 H 106 ni 11.4 2.7 93.1 4 96.3 .u 13.8 1.90I!i0S pCila Np-237 p<::ils 0 6.9 0 7.1 0 7.6t I 2.33 4.7 0 6.3 4.47 6.3 6.92 i.oOBiOl pci!j Pu-238 pCilg 2.24 4.5 0 I 0 8 I 0 8.7 0 7.1 0 1.4 < O.OU ·a.OOEtOi .. pCil&
Pu-239 pCils 0 7.8 0 I 0 8 0 8.7 0 7.1 0 1.4 0.046 ~-90lH03 pCils Th-230 pCilg 0.322 1.4 3.32 2.7 2 2.3 I 0 1.1+ 3.81 2.6 3.84 2.9 1.68 0.1 UOI!t04 pCila Th-232 pCila 0 - 1.1 0 1.2 0.334 o.67 I 0 1.3 0.293 0.59 0 1.2 11.4 0.6 UOEtOl pci!i ll-234 pCilg 188 10 73.3 6.1 248 12 131 9.9 70.1 6.5 6.5 7.3 116 u 3.70Et04 pcul ll-23S pCilg 2.38 6 F 16.6 3.9 G 3.96 1.4 4.13 3.2 801 4.1 IB 4 88.9 46 7.10Ei0l pCi!j U-238 pCilg 248 12 87.6 7.3 3U 13 202 12 102 7.8 88.4 I 188 98 :UOlH04 p<::j/8 Ca-131 pCilg -149 6.3 F 0.417 27 E -1.17 u F 0.133 2.7 E 2.51 D E -'1.847 2.3 IF ND HOEtOl jleili K-40 pCilg NR NR NR NR NR NR 2.81 0.19 1.00Et04 pci!a Ra-226 pCils NR NR NR NR NR NR 1.96 0.14 l.OOI!t04 i>Cill Cd-109 pCilg NR NR NR I NR NR NR 17.7 0.6 4.601!+04 pci!jj I
Am-241 pCila NR NR NR NR NR NR 7.34 0.19 . 2.30I!i0l Pcila Th-234 pCilg 69.8 3S II -39.1 21 IIG -1.15 33 IIF 55.9 24 II 132 3S II 197 2S H 9SI 0.08 ( Mo--99 pCilg NR NR NR NR NR NR 1.91 0.23
Pb--212 pCilg NR NR NR NR NR NR 1.76 0.03
Ac-228 pCilg NR NR NR NR NR NR 1.1 0.13
Nb-9S pCilg NR NR NR I NR NR I NR 6.71 o.os I
'Th-228 pCila -'1.322 u! -'1.664 u! -'1.667 u! -'1.726 1.6! -'l.S86 1,~ ! __ -Ql~ _nj_ 0.027 0.014
l'agc: 2 uf2 MARTIN MAHIETLA, ENEIHiY SYSTEMS, INC.
I '
Ms. Haight -2- January 10, 1996
hazardous or radiologicaf constituents not included in Tables A and B are introduced during FY 1996, we will notifY you. Additional characterization data for residuals resulting from cobuming of solids with the liquid wastes is expected to be available in the swnmer of 1996 and will be provided to you when available.
Table C contains estimated amounts of liquid waste to be received from PGDP and the corresponding estimated prorated share ofTSCA Incinerator residuals which would be returned to PGDP if Oak Ridge's current method of direct disposal were to become unavailable. The quantity estimates for residuals generation and prorating of residuals are based on historical TSCA Incinerator operational information for "liquids only" burns. A detailed explanation of the prorating calculation is included in Table C. Although the information provided is based on the FY 1996 TSCA Incinerator Burn Plan, the same method would be used to prorate residues from treatment of PGDP liquids in future years.
The information provided in this letter applies only to the residuals generated from treatment of PGDP's liquid wastes in the TSCA Incinerator and does not apply to any residues that might be generated from the treatment ofPGDP solids wastes in the future. The prorating assumptions for solids must be developed in the future based on operational experience gained through processing ORR solids. Quantity estimates and additional waste characterization information will be provided to address prorating of residues from processing solid waste as that information becomes available. This information can be included in a future version of the PGDP residuals management contingency plan.
Based on this information, please verity whether the residuals from treatment of the PGDP liquid waste scheduled for FY 1996 could be returned to the PGDP site for storage, if required as a contingency, under the terms ofPGDP's RCRA storage permit and modifications discussed above. As discussed in the teleconference of January 3, 1996, return of the residuals would not take place until FY 1997. In particular, please verity whether the 1.6 drums of residuals resulting from the waste to be received and burned in January 1996 could be returned sometime in FY 1997, if necessary, under the terms of the storage permit and modifications discussed above.
If you have questions or need additional information, please call Joy Sager of my staff at (423) 576-0850.
Enclosures
(cc's on page 3)
Sincerely,
x~d:~~ Waste Mana ement and Technology
Development Division
top related