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EUPT-FV17 Results
EUPT-FV17 Results Stuttgart 1st October 2015
DG SANTEMrs. Almut Bitterhof
ORGANISING GROUPAmadeo R. Fernández-AlbaMilagros MezcuaOctavio MalatoCarmen Ferrer
QUALITY CONTROL GROUPAntonio ValverdeStewart Reynolds
STATISTICAL GROUPCarmelo Rodríguez
ADVISORY GROUPMichelangelo AnastassiadesMiguel GamónMagnus JezussekAndré de KokRalf Lippold Sonja MasselterTuija Pihlström Mette Erecius PoulsenDarinka StajnbaherFinbarr O’ReganPhilippe Gros
EUPT-Panel
Mrs. Veerle Vanheusden
EUPT-FV17 Results Stuttgart 1st October 2015
Broccoli
EUPT-FV17 Results Stuttgart 1st October 2015
Organic broccolis were grown in a greenhouse in Almería. Spain.
EUPT-FV17 Results Stuttgart 1st October 2015
EUPT-FV17 Results Stuttgart 1st October 2015
Before harvest the broccolis were treated with commercial formulations
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticide Type Commercial Product
Bupirimate Commercial Formulation Nimrod Quattro
Carbendazim Commercial Formulation Bengu 50 Flow
Diazinon Commercial Formulation Zoogama-D
Difenoconazole Commercial Formulation Core
Diflubenzuron Commercial Formulation Dimilin 25
Methoxyfenozide Commercial Formulation Runner
Pendimetalin Commercial Formulation Stonp LE
Permethrin Commercial Formulation Defendog
Spinosad Commercial Formulation Spintor 480 SG
Thiabendazole Commercial Formulation Textar 60
Trifloxystrobin Commercial Formulation Flint
Commercial products used to treat the sample
EUPT-FV17 Results Stuttgart 1st October 2015
Preparation of the test item
EUPT-FV17 Results
ParticipationN
o of
Lab
s
EUPT-FV17 Results
Country No. of Labs Country No. of Labs Country No. of LabsAustria 2 Hungary 4 Serbia 2
Belgium 3 Iceland 1 Singapore 1
Brazil 2 Ireland 1 Slovakia 2
Bulgaria 2 Italy 23 Slovenia 3
China 1 Jamaica 1 Spain 32
Costa Rica 1 Kenya 2 Sweden 2
Croatia 6 Latvia 1 Switzerland 2
Cyprus 1 Lebanon 1 Thailand 1
Czech Republic 3 Lithuania 1 The Netherlands 4
Denmark 2 Luxembourg 1 Turkey 1
Egypt 1 Norway 1 United Kingdom 4
Estonia 2 Peru 1 Uruguay 1
Finland 2 Poland 11Total No. of Labs = 185Total No. of Non-EU countries Labs = 17Total No. of Countries = 44
EU countries. EFTA countries. Other countries
France 7 Portugal 2
Germany 29 Romania 4
Greece 10 Saudi Arabia 1
EUPT-FV17 Results Stuttgart 1st October 2015
Total No. of Labs = 185
EU/EFTA Labs = 168
Other countries Labs = 17
Participation
(27 EU + 3 EFTA + 2 Candidate countries + 12 other countries)
Total No. of Countries = 44
EU/EFTA countries = 30
Other countries = 14
EUPT-FV17 Results Stuttgart 1st October 2015
183 pesticides3-hydroxy-carbofuranAcephateAcetamipridAcrinathrinAldicarbAldicarb SulfoneAldicarb SulfoxideAzinphos-methylAzoxystrobinBenfuracarbBenomylBifenthrinBitertanolBoscalidBromopropylateBromuconazoleBupirimateBuprofezinCadusafosCarbarylCarbendazim CarbofuranCarbosulfanChlorfenapyrChlorfenvinphosChlorobenzilateChlorothalonilChlorpropham (only parent compound)ChlorpyrifosChlorpyrifos-methylClofentezine (only parent compound)ClothianidinCyfluthrin (cyfluthrin incl. other mixtures of constituent isomers (sum of isomers))Cypermethrin Cyproconazole Cyprodinil
DeltamethrinDemeton-S-methylsulfoneDesmethyl-pirimicarbDiazinonDichlofluanid (only parent compound)DichlorvosDicloranDicofolDiethofencarbDifenoconazoleDiflubenzuronDimethoateDimethomorphDimethylaminosulfotoluidide (DMST)DiniconazoleDiphenylamineEndosulfan alphaEndosulfan betaEndosulfan sulfateEPNEpoxiconazoleEthionEthirimolEthoprophosEtofenproxFenamidoneFenamiphosFenamiphos sulfoneFenamiphos sulfoxideFenarimolFenazaquinFenbuconazoleFenhexamidFenitrothionFenoxycarbFenpropathrin
FenpropimorphFenpyroximateFenthionFenthion oxonFenthion oxon sulfoneFenthion oxon sulfoxideFenthion sulfoneFenthion sulfoxideFenvalerate and EsfenvalerateFipronil (only parent compound)FludioxonilFlufenoxuronFluopicolide FluopyramFluquinconazoleFlusilazoleFlutolanil FlutriafolFosthiazateHexaconazoleHexythiazoxImazalilImidaclopridIndoxacarb (Indoxacarb as sum of the isomers S and R)IprodioneIprovalicarbIsocarbophosIsofenphos-methylIsoprothiolaneKresoxim-methylLambda-CyhalothrinLinuronLufenuronMalaoxonMalathion
MandipropamidMepanipyrim (only parent compound)MetaflumizoneMetalaxyl and metalaxyl-MMetconazoleMethamidophosMethidathionMethiocarbMethiocarb sulfoneMethiocarb sulfoxideMethomylMethoxyfenozideMonocrotophosMyclobutanilOmethoateOrthophenylphenolOxadixylOxamylOxydemeton-methylPaclobutrazoleParaoxon-methylParathion-ethylParathion-methyl PenconazolePencycuronPendimethalinPermethrinPhenthoatePhosalonePhosmet Phosmet oxonPhoximPirimicarbPirimiphos-methylProchloraz (only parent compound)Procymidone
ProfenofosPropargitePropiconazolePropyzamideProthioconazole (Prothioconazole-desthio)ProthiofosPyraclostrobinPyridabenPyrimethanilPyriproxyfenQuinoxyfenSpinosad (sum of spinosyn A and spinosyn SpirodiclofenSpiroxamineTau-FluvalinateTebuconazoleTebufenozideTebufenpyradTeflubenzuronTefluthrinTerbuthylazineTetraconazoleTetradifonThiabendazoleThiaclopridThiamethoxamThiodicarbThiophanate-methylTolclofos-methylTolylfluanidTriadimefonTriadimenolTriazophosTrichlorfon (only parent compound)TrifloxystrobinTriflumuronTrifluralinTriticonazoleVinclozolin (only parent compound)Zoxamide
Target List
12 New compounds
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides used for thetreatment
Bupirimate PendimetalinCarbendazim Permethrin*Diazinon SpinosadDifenoconazole ThiabendazoleDiflubenzuron TrifloxystrobinMethoxyfenozide Total: 11
ALL INCLUDED IN MACPCOMMISSION IMPLEMENTING REGULATION (EU)
No 400/2014 of 22 April 2014concerning a coordinated multiannual controlprogramme of the Union for 2015, 2016 and 2017 toensure compliance with maximum residue levels ofpesticides and to assess the consumer exposureto pesticide residues in and on food of plant andanimal origin .
* New in the target list
EUPT-FV17 Results Stuttgart 1st October 2015
ACTIVITY DATE
- Publishing the Target Pesticide List. Calendar and Matrix on the Web page. 15th December 2014
- Receiving Application Form from invited laboratories. 12th Jan-13th Feb 2015
- Specific Protocol published on the Web site. 23rd Feb 2015 at the latest
- Deadline for receiving Laboratory scope: Form 0 23rd Feb-6th March 2015
- Sample distribution. 16th March 2015
- Deadline for receiving sample acceptance: Form 1 20th March 2015
- Deadline for receiving results: Forms 2. 3 and 4 13th April 2015
- Filling in Form 5 20th-24th April 2015
- Preliminary Report: only results. no statistical treatment. May 2015
- Final Report distributed to the Laboratories. December 2015
Calendar
EUPT-FV17 Results Stuttgart 1st October 2015
The homogeneity in the treated sample was studiedusing the 2006 Harmonised Protocol.
Homogeneity
All the pesticides passed the homogeneity test
EUPT-FV17 Results Stuttgart 1st October 2015
Homogeneity
mg/kg
EUPT-FV17 Results Stuttgart 1st October 2015
Stability
ISO 13528. Annex B
Sub-sample1
Sub-sample 2
Sub-sample 3
Sub-sample 4
Sub-sample 5
Sub-sample 6
EUPT-FV17 Results Stuttgart 1st October 2015
Stability
2nd Analysis - after the deadline for reporting results
1st Analysis - prior to the sample shipment
3rd Analysis - reproducing the delivery conditions that the samples experienced during 48 hours
ISO 13528. Annex B
| x1 - yi | ≤ 0.3×σ
All the pesticides passed the stability test
EUPT-FV17 Results
Results
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides Robust mean (mg/kg)
Uncertainty(mg/kg)
Spinosad 0.051 0.003Pendimethalin 0.062 0.003Diazinon 0.071 0.003Bupirimate 0.16 0.006Permethrin 0.17 0.007Diflubenzuron 0.32 0.019Methoxyfenozide 0.35 0.014Trifloxystrobin 0.47 0.016Carbendazim 0.51 0.023Difenoconazole 0.53 0.016Thiabendazole 1.90 0.071
Assigned valuesEU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides Robust mean (mg/kg)Spinosad 0.051Pendimethalin 0.062Diazinon 0.071Bupirimate 0.16Permethrin 0.17Diflubenzuron 0.32Methoxyfenozide 0.35Trifloxystrobin 0.47Carbendazim 0.51Difenoconazole 0.53Thiabendazole 1.90
0.051-0.100 mg/kg
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides Robust mean (mg/kg)Spinosad 0.051Pendimethalin 0.062Diazinon 0.071Bupirimate 0.16Permethrin 0.17Diflubenzuron 0.32Methoxyfenozide 0.35Trifloxystrobin 0.47Carbendazim 0.51Difenoconazole 0.53Thiabendazole 1.90
0.051-0.100 mg/kg
0.100-0.500 mg/kg
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides Robust mean (mg/kg)Spinosad 0.051Pendimethalin 0.062Diazinon 0.071Bupirimate 0.16Permethrin 0.17Diflubenzuron 0.32Methoxyfenozide 0.35Trifloxystrobin 0.47Carbendazim 0.51Difenoconazole 0.53Thiabendazole 1.90
0.051-0.100 mg/kg
0.100-0.500 mg/kg
> 0.500 mg/kg
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Bupirimate
mg/kg
Freq
uenc
y
0 0.3 0.6 0.9 1.2 1.5 1.80
20
40
60
80Mean: 0.165 mg/kg
Mean: 0.469 mg/kg
Distribution of data-HistogramsCarbendazim
mg/kg
Freq
uenc
y
0 1 2 3 4 50
10
20
30
40
50
60
Diazinon
mg/kg
Freq
uenc
y
0 0.03 0.06 0.09 0.12 0.15 0.180
10
20
30
40
50
60
Difenocozole
mg/kg
Freq
uenc
y
0 0.2 0.4 0.6 0.80
20
40
60
80
Mean: 0.512 mg/kg
Mean: 0.071 mg/kg Mean: 0.530 mg/kg
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Distribution of data-HistogramsDiflubenzuron
mg/kg
Freq
uenc
y
0 0.4 0.8 1.2 1.6 20
10
20
30
40
Methoxyfenozide
mg/kg
Freq
uenc
y
0 0.2 0.4 0.6 0.80
10
20
30
40
50
60
Pendimethalin
mg/kg
Freq
uenc
y
0 0.05 0.1 0.15 0.2 0.250
20
40
60
80
100
Permethrin
mg/kg
Freq
uenc
y
0 0.2 0.4 0.6 0.8 10
10
20
30
40
50
60
Mean: 0.319 mg/kg Mean: 0.349 mg/kg
Mean: 0.062 mg/kg Mean: 0.174 mg/kg
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Spinosad
mg/kg
Freq
uenc
y
0 0.05 0.1 0.15 0.2 0.25 0.30
10
20
30
40
50
Thiabendazole
mg/kg
Freq
uenc
y
0 1 2 3 4 5 60
20
40
60
80
Trifloxystrobin
mg/kg
Freq
uenc
y
0 0.2 0.4 0.6 0.8 10
10
20
30
40
50
60
Distribution of data-Histograms
Mean: 0.051 mg/kg Mean: 1.90 mg/kg
Mean: 0.466 mg/kg
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides MRRL (mg/kg) Robust mean (mg/kg) CV (%)
Bupirimate 0.010 0.165 18.2
Carbendazim 0.010 0.512 21.1
Diazinon 0.010 0.071 18.5
Difenoconazole 0.010 0.530 15.1
Diflubenzuron 0.010 0.319 25.6
Methoxyfenozide 0.010 0.349 17.7
Pendimethalin 0.010 0.062 21.6
Permethrin 0.010 0.174 21.4Spinosad (sum of spinosyn A a spinosyn D. expr. as spinosad) 0.010 0.051 24.0
Thiabendazole 0.010 1.900 18.0
Trifloxystrobin 0.010 0.466 17.5
EU/EFTA Laboratories
Dispersion of Results
EUPT-FV17 Results Stuttgart 1st October 2015
Dispersion of ResultsEU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
PesticidesNo. of
Reported Results
No. of False Negative
Results
No. of Not Analysed
Results
Percentage of Reported Results
(out of 165)
Bupirimate 154 0 11 93Carbendazim 140 0 25 85Diazinon 160 2 3 97Difenoconazole 151 1 13 92Diflubenzuron 111 2 52 67Methoxyfenozide 128 0 37 78Pendimethalin 152 1 12 92Permethrin 152 1 12 92Spinosad 125 2 38 76Thiabendazole 143 2 20 87Trifloxystrobin 152 0 13 92
EU/EFTA Laboratories
EUPT-FV17 Results
z-Scores
EUPT-FV17 Results Stuttgart 1st October 2015
Acceptable Questionable Unacceptable
z-Scores classificationEU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Pesticides Robust Mean (mg/kg)
% Acceptable z-scores
% Questionable
z-scores
% Unacceptable z-scores
Bupirimate 0.165 93.5 1.9 4.5Carbendazim 0.512 86.4 5.7 7.9Diazinon 0.071 92.6 4.3 3.1Difenoconazole 0.530 97.4 1.3 1.3Diflubenzuron 0.319 84.1 8.0 8.0Methoxyfenozide 0.349 96.1 3.1 0.8Pendimethalin 0.062 92.2 5.9 2.0Permethrin 0.174 93.5 2.6 3.9Spinosad(sum of spinosyn A aspinosyn D. expr. as spinosad)
0.051 90.6 1.6 7.9
Thiabendazole 1.900 93.1 1.4 5.5Trifloxystrobin 0.466 96.7 1.3 2.0
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Bupirimate
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab158Lab017Lab025Lab071Lab093Lab156Lab005Lab011Lab115Lab131Lab154Lab019Lab148Lab152Lab163Lab053Lab124Lab119Lab026Lab036Lab054Lab170Lab103Lab069Lab120Lab166Lab009Lab012Lab034Lab037Lab044Lab049Lab092Lab117Lab133Lab134Lab048Lab132Lab111Lab101Lab107Lab038Lab161Lab031Lab151Lab182Lab073Lab160Lab062Lab137Lab157Lab130Lab135Lab024Lab147Lab181Lab183Lab002Lab030Lab171Lab018Lab035Lab040Lab056Lab058Lab102Lab113Lab146Lab185Lab051Lab106Lab121Lab168Lab149Lab162Lab169Lab105Lab081Lab082Lab022Lab079Lab080Lab136Lab013Lab027Lab065Lab076Lab085Lab089Lab094Lab099Lab110Lab142Lab067Lab108Lab144Lab014Lab015Lab084Lab006Lab021Lab179Lab095Lab057Lab041Lab074Lab109Lab159Lab070Lab088Lab116Lab100Lab114Lab016Lab098Lab176Lab047Lab077Lab083Lab086Lab143Lab052Lab029Lab072Lab097Lab129Lab138Lab140Lab078Lab045Lab010Lab060Lab064Lab167Lab032Lab068Lab128Lab123Lab141Lab087Lab046Lab126Lab001Lab003Lab007Lab091Lab061Lab145Lab043Lab042Lab174Lab023Lab112Lab020
or L ≡ LCor G ≡ GCor B ≡ Both0 False Negative
93.5 % Acceptable1.9 % Questionable4.5 % Unacceptable
Robust Mean: 0.165 mg/kg
EUPT-FV17 Results Stuttgart 1st October 2015
Carbendazim
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab158Lab112Lab045Lab119Lab038Lab017Lab169Lab128Lab154Lab015Lab003Lab133Lab101Lab143Lab168Lab111Lab025Lab134Lab093Lab011Lab031Lab034Lab064Lab107Lab183Lab019Lab012Lab024Lab135Lab179Lab009Lab014Lab067Lab160Lab105Lab156Lab087Lab043Lab167Lab013Lab044Lab077Lab095Lab048Lab079Lab046Lab076Lab126Lab026Lab049Lab065Lab040Lab042Lab171Lab174Lab007Lab170Lab018Lab070Lab072Lab138Lab185Lab060Lab030Lab086Lab147Lab032Lab097Lab117Lab137Lab053Lab102Lab027Lab148Lab084Lab144Lab159Lab123Lab140Lab023Lab162Lab010Lab020Lab069Lab006Lab091Lab108Lab050Lab182Lab098Lab089Lab094Lab114Lab099Lab161Lab181Lab083Lab100Lab036Lab056Lab078Lab082Lab109Lab058Lab005Lab073Lab047Lab029Lab074Lab124Lab041Lab080Lab068Lab120Lab035Lab136Lab062Lab037Lab071Lab116Lab176Lab121Lab106Lab057Lab022Lab021Lab113Lab132Lab061Lab088Lab145Lab052Lab054Lab173Lab085Lab166Lab150Lab103Lab110Lab142
or L ≡ LCor G ≡ GCor B ≡ Both0 False Negative
86.4 % Acceptable5.7 % Questionable7.9 % Unacceptable
Robust Mean: 0.512 mg/kg
EUPT-FV17 Results Stuttgart 1st October 2015
Diazinon
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab110Lab169Lab158Lab017Lab150Lab025Lab011Lab173Lab071Lab166Lab148Lab075Lab005Lab026Lab044Lab092Lab131Lab077Lab133Lab008Lab043Lab015Lab038Lab101Lab124Lab128Lab163Lab120Lab062Lab009Lab019Lab031Lab037Lab039Lab054Lab117Lab134Lab152Lab168Lab183Lab144Lab001Lab160Lab012Lab049Lab088Lab041Lab029Lab102Lab113Lab105Lab013Lab022Lab127Lab174Lab048Lab149Lab179Lab182Lab045Lab083Lab142Lab145Lab035Lab052Lab111Lab121Lab126Lab157Lab021Lab034Lab087Lab093Lab115Lab119Lab185Lab002Lab014Lab036Lab042Lab051Lab076Lab082Lab132Lab040Lab171Lab147Lab137Lab027Lab053Lab072Lab162Lab073Lab078Lab081Lab086Lab106Lab130Lab151Lab018Lab024Lab109Lab135Lab138Lab139Lab159Lab079Lab010Lab064Lab069Lab098Lab099Lab100Lab136Lab058Lab091Lab094Lab108Lab067Lab003Lab020Lab046Lab097Lab154Lab047Lab023Lab032Lab056Lab084Lab089Lab114Lab156Lab164Lab167Lab181Lab080Lab176Lab030Lab129Lab103Lab161Lab123Lab143Lab016Lab085Lab095Lab065Lab140Lab068Lab118Lab116Lab007Lab070Lab006Lab050Lab057Lab061Lab074Lab060Lab112Lab141Lab107
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
92.6 % Acceptable4.3 % Questionable3.1 % Unacceptable
Robust Mean: 0.071 mg/kg
**
GGGGGGL
EUPT-FV17 Results Stuttgart 1st October 2015
Difenoconazole
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab059Lab164Lab158Lab025Lab011Lab071Lab094Lab173Lab114Lab163Lab169Lab001Lab026Lab124Lab131Lab133Lab148Lab009Lab043Lab019Lab005Lab079Lab185Lab037Lab048Lab168Lab183Lab031Lab032Lab087Lab160Lab154Lab101Lab111Lab132Lab103Lab073Lab083Lab036Lab012Lab024Lab034Lab054Lab147Lab120Lab171Lab077Lab060Lab135Lab067Lab166Lab085Lab093Lab113Lab105Lab121Lab015Lab053Lab151Lab107Lab029Lab035Lab128Lab108Lab021Lab145Lab014Lab082Lab013Lab040Lab072Lab146Lab174Lab069Lab137Lab064Lab136Lab027Lab017Lab038Lab138Lab050Lab142Lab022Lab046Lab052Lab065Lab078Lab062Lab170Lab159Lab157Lab102Lab097Lab106Lab112Lab080Lab076Lab057Lab074Lab126Lab045Lab056Lab081Lab116Lab091Lab047Lab100Lab010Lab075Lab161Lab020Lab041Lab003Lab042Lab088Lab099Lab061Lab119Lab098Lab176Lab049Lab084Lab115Lab095Lab030Lab143Lab044Lab109Lab140Lab181Lab002Lab018Lab086Lab092Lab162Lab123Lab068Lab089Lab110Lab007Lab070Lab156Lab144Lab167Lab182Lab058Lab141Lab016Lab179Lab117Lab006
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
97.4 % Acceptable1.3 % Questionable1.3 % Unacceptable
Robust Mean: 0.530 mg/kg
*
GG L L L L L G L B G
EUPT-FV17 Results Stuttgart 1st October 2015
Diflubenzuron
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab019Lab158Lab173Lab116Lab071Lab105Lab112Lab162Lab025Lab079Lab091Lab126Lab166Lab026Lab053Lab168Lab160Lab120Lab031Lab044Lab161Lab020Lab027Lab035Lab037Lab124Lab015Lab171Lab082Lab135Lab013Lab032Lab080Lab128Lab102Lab100Lab012Lab005Lab108Lab095Lab061Lab067Lab084Lab024Lab021Lab159Lab144Lab069Lab103Lab064Lab085Lab137Lab119Lab042Lab049Lab086Lab101Lab147Lab076Lab009Lab060Lab087Lab132Lab048Lab078Lab097Lab062Lab046Lab083Lab109Lab030Lab093Lab176Lab010Lab098Lab167Lab070Lab072Lab073Lab050Lab111Lab088Lab018Lab092Lab011Lab040Lab143Lab029Lab068Lab047Lab179Lab014Lab022Lab182Lab123Lab156Lab094Lab169Lab077Lab089Lab041Lab185Lab181Lab142Lab183Lab058Lab038Lab057Lab036Lab136Lab043Lab054Lab074
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
84.1 % Acceptable8.0 % Questionable8.0 % Unacceptable
Robust Mean: 0.319 mg/kg
* *
L L L
EUPT-FV17 Results Stuttgart 1st October 2015
Methoxyfenozide
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab045Lab158Lab094Lab034Lab103Lab079Lab162Lab019Lab026Lab054Lab025Lab092Lab160Lab111Lab119Lab085Lab185Lab161Lab120Lab088Lab022Lab083Lab148Lab107Lab114Lab174Lab073Lab005Lab132Lab168Lab035Lab009Lab121Lab038Lab093Lab171Lab043Lab135Lab137Lab183Lab053Lab062Lab024Lab142Lab080Lab095Lab128Lab147Lab082Lab110Lab087Lab106Lab145Lab017Lab048Lab067Lab101Lab011Lab013Lab029Lab037Lab049Lab071Lab014Lab091Lab167Lab020Lab108Lab027Lab032Lab072Lab097Lab105Lab127Lab100Lab061Lab046Lab126Lab084Lab144Lab010Lab156Lab036Lab098Lab042Lab069Lab159Lab047Lab143Lab064Lab109Lab018Lab056Lab086Lab077Lab176Lab169Lab057Lab052Lab012Lab070Lab181Lab058Lab078Lab089Lab116Lab123Lab074Lab030Lab179Lab102Lab007Lab044Lab068Lab113Lab041Lab076Lab140Lab050Lab015Lab060Lab112Lab040Lab141Lab124Lab136Lab182Lab021
or L ≡ LCor G ≡ GCor B ≡ Both0 False Negative
96.1 % Acceptable3.1 % Questionable0.8 % Unacceptable
Robust Mean: 0.349 mg/kg
L L L L L L L
EUPT-FV17 Results Stuttgart 1st October 2015
Pendimethalin
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab169Lab158Lab025Lab011Lab115Lab148Lab054Lab003Lab015Lab039Lab071Lab131Lab152Lab037Lab170Lab034Lab075Lab049Lab073Lab005Lab030Lab120Lab127Lab133Lab029Lab038Lab077Lab019Lab031Lab101Lab117Lab126Lab132Lab183Lab143Lab111Lab142Lab145Lab147Lab009Lab021Lab069Lab121Lab157Lab044Lab026Lab168Lab056Lab124Lab144Lab149Lab102Lab105Lab053Lab097Lab160Lab179Lab041Lab045Lab094Lab103Lab134Lab154Lab182Lab185Lab012Lab062Lab084Lab106Lab017Lab027Lab036Lab085Lab137Lab047Lab013Lab035Lab128Lab135Lab171Lab022Lab040Lab061Lab082Lab146Lab151Lab048Lab130Lab162Lab018Lab052Lab058Lab083Lab139Lab010Lab076Lab081Lab099Lab156Lab078Lab086Lab107Lab167Lab176Lab080Lab014Lab043Lab067Lab023Lab032Lab060Lab089Lab092Lab100Lab110Lab159Lab181Lab002Lab042Lab050Lab001Lab108Lab109Lab112Lab079Lab024Lab088Lab095Lab164Lab098Lab114Lab161Lab046Lab072Lab116Lab068Lab091Lab138Lab065Lab007Lab064Lab087Lab070Lab057Lab123Lab141Lab093Lab113Lab119Lab074Lab136Lab016Lab166
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
92.2 % Acceptable5.9 % Questionable2.0 % Unacceptable
Robust Mean: 0.062 mg/kg
*
L L L
EUPT-FV17 Results Stuttgart 1st October 2015
Permethrin
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab019Lab119Lab025Lab011Lab052Lab008Lab038Lab115Lab183Lab111Lab120Lab071Lab145Lab148Lab173Lab139Lab093Lab036Lab031Lab049Lab017Lab126Lab069Lab103Lab121Lab009Lab039Lab113Lab118Lab134Lab152Lab185Lab157Lab168Lab143Lab094Lab048Lab073Lab034Lab021Lab029Lab037Lab054Lab133Lab012Lab132Lab005Lab164Lab022Lab124Lab130Lab171Lab053Lab105Lab075Lab135Lab159Lab015Lab144Lab160Lab077Lab142Lab010Lab026Lab032Lab078Lab097Lab162Lab001Lab059Lab062Lab030Lab079Lab002Lab045Lab102Lab137Lab013Lab018Lab027Lab035Lab099Lab107Lab110Lab117Lab127Lab131Lab169Lab100Lab149Lab156Lab088Lab147Lab174Lab098Lab040Lab086Lab179Lab023Lab041Lab044Lab068Lab084Lab151Lab060Lab076Lab108Lab128Lab057Lab042Lab046Lab064Lab082Lab080Lab065Lab138Lab072Lab083Lab070Lab114Lab024Lab087Lab161Lab116Lab061Lab067Lab051Lab167Lab091Lab056Lab089Lab182Lab014Lab050Lab109Lab081Lab047Lab003Lab146Lab074Lab043Lab123Lab176Lab181Lab058Lab141Lab092Lab112Lab095Lab163Lab007Lab016Lab166
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
93.5 % Acceptable2.6 % Questionable3.9 % Unacceptable
Robust Mean: 0.174 mg/kg
*
GGG
EUPT-FV17 Results Stuttgart 1st October 2015
Spinosad
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab054Lab128Lab158Lab103Lab114Lab071Lab082Lab142Lab079Lab031Lab037Lab005Lab034Lab025Lab026Lab119Lab087Lab011Lab019Lab068Lab109Lab124Lab185Lab015Lab077Lab029Lab048Lab120Lab123Lab133Lab085Lab092Lab111Lab093Lab168Lab083Lab088Lab107Lab144Lab147Lab161Lab009Lab080Lab062Lab038Lab069Lab078Lab101Lab110Lab174Lab017Lab049Lab105Lab121Lab135Lab183Lab013Lab136Lab171Lab176Lab041Lab072Lab023Lab106Lab181Lab022Lab126Lab024Lab160Lab007Lab053Lab086Lab097Lab162Lab010Lab058Lab073Lab108Lab046Lab061Lab116Lab067Lab003Lab014Lab074Lab084Lab100Lab112Lab047Lab098Lab102Lab132Lab137Lab030Lab060Lab064Lab056Lab095Lab141Lab179Lab032Lab113Lab182Lab027Lab089Lab159Lab035Lab143Lab167Lab012Lab148Lab040Lab156Lab057Lab070Lab169Lab094Lab021Lab018Lab127Lab036Lab044Lab043Lab091Lab042Lab050Lab076
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
90.6 % Acceptable1.6 % Questionable7.9 % Unacceptable
Robust Mean: 0.051 mg/kg
*
L L
*
EUPT-FV17 Results Stuttgart 1st October 2015
Thiabendazole
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab110Lab163Lab127Lab065Lab116Lab059Lab151Lab003Lab162Lab023Lab085Lab154Lab185Lab183Lab168Lab045Lab093Lab148Lab049Lab114Lab071Lab136Lab079Lab132Lab025Lab026Lab174Lab042Lab001Lab103Lab112Lab034Lab128Lab035Lab017Lab027Lab069Lab073Lab111Lab024Lab012Lab105Lab106Lab137Lab037Lab068Lab107Lab099Lab143Lab160Lab157Lab161Lab052Lab067Lab074Lab009Lab170Lab108Lab056Lab050Lab147Lab083Lab018Lab044Lab133Lab145Lab038Lab101Lab030Lab100Lab031Lab120Lab135Lab088Lab144Lab020Lab064Lab113Lab089Lab048Lab010Lab140Lab060Lab117Lab040Lab091Lab121Lab176Lab005Lab041Lab054Lab138Lab006Lab014Lab062Lab109Lab159Lab036Lab047Lab141Lab179Lab046Lab084Lab053Lab097Lab123Lab072Lab124Lab171Lab078Lab080Lab015Lab013Lab167Lab007Lab087Lab070Lab032Lab126Lab169Lab098Lab077Lab029Lab086Lab011Lab016Lab082Lab076Lab043Lab057Lab102Lab022Lab158Lab173Lab095Lab061Lab181Lab182Lab021Lab058Lab156Lab094Lab019Lab150Lab142
or L ≡ LCor G ≡ GCor B ≡ Both*False Negative
93.1 % Acceptable1.4 % Questionable5.5 % Unacceptable
Robust Mean: 1.90 mg/kg
**
L L G L
EUPT-FV17 Results Stuttgart 1st October 2015
Trifloxystrobin
-5,0
-4,0
-3,0
-2,0
-1,0
0,0
1,0
2,0
3,0
4,0
5,0
Lab127Lab158Lab023Lab019Lab075Lab053Lab163Lab011Lab094Lab170Lab111Lab119Lab026Lab124Lab025Lab015Lab135Lab009Lab113Lab115Lab133Lab148Lab048Lab098Lab073Lab183Lab005Lab134Lab174Lab132Lab012Lab145Lab047Lab168Lab037Lab049Lab101Lab102Lab001Lab083Lab121Lab120Lab054Lab157Lab185Lab093Lab062Lab105Lab179Lab069Lab160Lab031Lab103Lab079Lab106Lab038Lab143Lab029Lab117Lab147Lab154Lab017Lab043Lab128Lab077Lab144Lab013Lab092Lab142Lab151Lab107Lab087Lab041Lab035Lab036Lab080Lab146Lab130Lab171Lab003Lab108Lab072Lab057Lab034Lab081Lab082Lab137Lab002Lab061Lab126Lab014Lab078Lab112Lab018Lab052Lab097Lab152Lab099Lab044Lab067Lab070Lab089Lab116Lab176Lab100Lab076Lab136Lab064Lab084Lab159Lab169Lab010Lab123Lab088Lab162Lab086Lab156Lab140Lab046Lab110Lab030Lab060Lab042Lab024Lab022Lab027Lab109Lab032Lab065Lab138Lab016Lab074Lab045Lab050Lab161Lab056Lab114Lab059Lab141Lab040Lab091Lab167Lab068Lab095Lab006Lab007Lab085Lab129Lab182Lab181Lab058Lab021
or L ≡ LCor G ≡ GCor B ≡ Both0 False Negative
96.7 % Acceptable1.3 % Questionable2.0 % Unacceptable
Robust Mean: 0.47 mg/kg
EUPT-FV17 Results
Combined z-Scores
EUPT-FV17 Results Stuttgart 1st October 2015
Average of Squared z-Scores
AZ2 ≤ 2.0 Good2.0 < AZ2 < 3.0 Satisfactory
AZ2 ≥ 3.0 Unsatisfactory
EUPT-FV17 Results Stuttgart 1st October 2015
NRLs OfLs
AZ2 Representation
80 % Good 7 % Satisfactory 13 % Unsatisfactory
Category A: 68.5 % of the EU/EFTA Laboratories
(113 Laboratories out of 165)
EUPT-FV16: 92 % Good 5 % Satisfactory 3 % Unsatisfactory
EUPT-FV16: 59%
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
6 different laboratories from EU/EFTA countries reported 6 pesticides as false
positives
EU/EFTA Laboratories
False Positives
EUPT-FV17 Results Stuttgart 1st October 2015
Laboratory Code Pesticide Concentration
(mg/kg)Determination
Technique RL
(mg/Kg)MRRL
(mg/Kg)
Lab027 Bromopropylate 0.014 GC-MS/MS 0.01 0.01
Lab098 Bromopropylate 0.021 GC-MS 0.01 0.01
Lab051 Bromopropylate 0.039 GC-MS 0.01 0.01
Lab173 Carbaryl 0.020 GC-MS/MS 0.01 0.01
Lab158 Fenpropathrin 0.020 GC-MS 0.01 0.01
Lab164 Kresoxim-methyl 0.015 GC-MS/MS 0.01 0.01
Lab173 Orthophenylphenol 2.95 HPLC-UV 0.1 0.01
Lab173 Tetradifon 0.014 GC-MS/MS 0.01 0.01
EU/EFTA Laboratories
False Positives
EUPT-FV17 Results Stuttgart 1st October 2015
Bromopropylate
Carbaryl
Fenpropathrin
Kresoxim-methyl
Tetradifon
False Positives
HPLC-UVOrthophenylphenol
GC-MS or GC-MS/MS
EU/EFTA Laboratories
EUPT-FV17 Results Stuttgart 1st October 2015
Bromopropylate in FV17
EUPT-FV17 Blank 10 µg/kg Std in Broccoli EUPT-FV17 Sample
Ratio: 7.1%Ratio: 0.9%
MRM1: 341 > 185MRM2: 341 > 155
EUPT-FV17 Results Stuttgart 1st October 2015
Bupirimate Carbendazim DiazinonDifenoconazole Diflubenzuron Methoxyfenozide Pendimetalin
Permethrin SpinosadThiabendazole Trifloxystrobin
Cyprodinil
Ethirimol
Fludioxonil
Concentrations below MRRL (0.01 mg/kg)
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Overview of the EUPTs-FV
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
1995-2004
• 5 PTs on MRM in FV
Proficiency Tests - History
2004 2005 2006 2007 2008 2009
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Proficiency Tests - History
2010 2011 2012 2013 2014
ISO/IEC 17043
2015
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Participant countries-Other countries (18)
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
EUPT Nº Matrices Nº of Participants
Nº of PossiblePesticides
Nº of pesticidesevaluated in test
item
1 Pepper 88 33 6
2 Apple 85 41 6
3 Cucumber 116 48 14
4 Orange 117 57 14
5 Lettuce 127 57 15
6 Tomato 130 57 13
7 Grape 128 65 16
8 Aubergine 129 68 16
9 Strawberry 137 82 19
10 Carrot 132 113 18
11 Cauliflower 151 128 21
12 Leek 153 144 17
13 Mandarin 154 144 19
14 Pear 167 175 18
15 Potato 175 175 18
16 Pepper 183 175 22
17 Broccoli 185 183 11
EUPT-FV1 to EUPT-FV17 in numbers
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Acephate Difenoconazole Kresoxim-methyl PirimicarbAcetamiprid Diflubenzuron Lambda-Cyhalothrin Pirimphos-methylAcrinathrin Dimethoate Linuron ProchlorazAldicarb(sum) Diphenilamine Malathion ProcydimoneAmitraz (DMPF&DMF) Dithiocarbamates(CS2) Mecarbam PropoxurAzinphos-methyl Endosulfan Metalaxyl PropyzamideAzoxystrobin EPN Metamidophos ProthiofosBifenthrin Fenamiphos Methidathion PyraclostrobinBoscalid Fenamiphos sulfone Methiocarb sum PyridabenBromopropylate Fenamiphos sulfoxide Methiocarb PyrimethanilBupirimate Ethion Methomyl PyriproxifenBuprofezin Fenhexamid Methoxyfenozide QuinoxyfenCadusafos Fenitrothion Methyl-Tiophanate QuintozeneCaptan Fenpropathrin Mevinphos SpinosadCarbaryl Fludioxinil Monocrotophos SpirodiclofenCarbendazim Flufenoxuron Myclobutanil TebuconazoleCarbofuran sum Fluopicolide Omethoate Tetraconazole Chlorpropham Flutolanil Ortophenilphenol ThiabendazoleChlorpyrifos Folpet Oxamyl ThiaclopridChlorpyrifos-methyl Fosthiazate Oxydemeton-methyl Tolclofos-methylChlothalonil Hexythiazox Parathion TolyfluanidCypermethrin Imazalil Penconazole TriadimenolCyprodinil Imidacloprid Pencycuron TriazophosDelthamethrin Indoxacarb Pendimethalin TrifloxystrobinDiazinon Iprodione Permethrin TriflumuronDichlofluanid Iprovalicarb Phosalone VinclozolinDicofol Isofenphos-methyl Phosmet
Pesticides Used to Treat the Sample in last ten EUPT-FVs
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Summary of Results
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Number of results reported by extraction method
Extraction methods
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Acceptable Ques tionable Inacceptable Acceptable Ques tionable Inacceptable Acceptable Ques tionable InacceptableE UPT ‐FV16 91,7 7,7 0,6 93,9 2,9 3,2 95,5 2,9 1,6E UPT ‐FV15 93,0 3,4 3,6 87,7 4,2 8,2 88,6 3,9 7,5E UPT ‐FV14 96,2 1,8 2 93,9 3,1 3 94,3 3 2,7
Acetone QuE C hE R S AcE t
Classification of z-scores by extraction method
Extraction methods
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
0
10
20
30
40
50
60
25% FFP RSD
(Qn
RSD
, %)
EUPT 1 EUPT 2 EUPT 3 EUPT 4 EUPT 5 EUPT 6 EUPT 7 EUPT 8
EUPT 9 EUPT 10 EUPT 11 EUPT 12 EUPT 13 EUPT 14 EUPT 15 EUPT 16
Dispersion of Results (RSD, %)
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
No.
Dispersion of Results (RSD, %)
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
Acceptable Questionable Unacceptable
%
1776results
1950results
1590results
2363results
1555results
2254results
2209results
2486results
3133results
Classification of z-scores
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
71 %
51 % 51 % 51 %
45 %
56 %52 % 52 %
59 %
%
Laboratories in Category A
68.5 %
Overview of the EUPTs-FV
Stuttgart 1st October 2015Overview of the EUPTs-FV
False Negatives and Positives
EUPT-FV17 Results Stuttgart 1st October 2015
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