cathodic protection for ast’s protection...gallon tank 396 were caused by corrosion, likely...
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1
Cathodic Protection for AST’s
Presented by:
James T. Lary
Corrpro Companies, inc.
1055 West Smith Road
Medina, Ohio 44256
jlary@corrpro.com
330-241-6615
• Preserve Assets
• Avoid Disruption of Service
• Enhance Safety
• Prevent Leaks
• Governmental Regulations
• Reduce Maintenance
Costs
Why is Cathodic Protection Important?
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Terminal Tankage
Main Line
M
Valve
OPS
Inspection
Meter M
No OPS
Inspection
OPS Inspection Stops
(Enforcement Policy)
Loading
Terminal Product
Tank
(Terminal)
Product
Tank
(Terminal)
Breakout Tank
M
Main Line
Valve
OPS
Inspection
Meter M
Product
Tank
(Breakout)
M
3
Charleston, WV Spill
The investigation found that two small
holes ranging in size from about 0.4-inch
to 0.75-inch in the bottom of the 48,000-
gallon tank 396 were caused by corrosion,
likely resulting from water leaking through
holes in the roof and settling on the tank
floor. Furthermore, the CSB inspection
found a similar hole penetrating the
bottom of nearby tank 397, containing the
same chemical at the facility, located in
Charleston. Other tanks also showed
multiple signs of pitting and metallurgical
damage, investigators said. The growing
corrosion in these tanks went unnoticed
until the bottom of 396 was breached and
up to an estimated 10,000 gallons of
product made their way through the
underlying mixture of soil and gravel
under the facility and into the Elk River on
January 9, 2014.
- Causes of Corrosion
- Cathodic Protection Applications
- Installation & Maintenance
- Rectifier Monitoring
What we will cover….
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Early Oil Tanks & Piping
did not Employ CP
IRON OXIDE REFINING MILLING
STEEL CORROSION IRON OXIDE
THE PROBLEM…..
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Anodic Area
-600mV Cathodic Area
-550mV
SAND
CURRENT FLOW
External Corrosion of
Tank Bottom
MFL Floor
Inspection
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SAND CURRENT FLOW
Corrosion Cell Caused
by Foreign Material in
Sand Cushion
CLAY
Steel Tank Floor
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DRY
SAND
MOIST SAND
WATER
Corrosion Caused by
Poor Water Drainage
New Bottom (Anode)
CURRENT FLOW
SAND
SAND
New Steel Coupled to Old Steel
Old Bottom (Cathode)
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Leak detection grove
under under bottom
Tank bottom required
30% floor
replacement
after 5 years in
service
Concrete Slab
Types of Cathodic Protection
Galvanic: Current obtained from a metal
with a higher energy level.
Impressed Current: Requires external
power source (transformer
rectifier).
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System Characteristics
Galvanic Impressed
No external power External power required
Fixed driving voltage Voltage can be varied
Limited current Current can be varied
Small current requirements High current requirements
Used in lower resistivity Used in almost any
environment resistivity environment
Usually negligible Must consider interference
interference with other structures
Above Ground Storage Tank With Galvanic Anodes
Anodes
Tank
Anodes
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Above Ground Storage Tank With Galvanic Anodes
Is Protection Being Achieved?
Anode
Tank
Uncoated Tank Bottom
Tank Grounded to Other
Structures
Test
Box
Anode
Cells
Tank
Galvanic Anodes
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• With the advent of secondary containment
liners for AST’s, some oil companies initially
installed galvanic (zinc or magnesium) anode
cathodic protection systems. Many of these
same companies have now abandoned this
approach due to the inability to obtain effective
levels of cathodic protection or limited system
design life.
• The industry preference for cathodic protection
for large AST’s is now impressed current.
Galvanic Anode Installation on AST. Note that anode life and current output are dependent upon sand / backfill conditions. Reference cells were rarely installed to monitor performance.
Galvanic
Anode
(Many galvanic systems installed by tank contractor)
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Recommended Practices
API-651 - Cathodic Protection of Aboveground Petroleum
Storage Tanks:
“Galvanic anodes method is not practical for
protection of large bare structures.”
NACE RP0193-2001 - External Cathodic Protection of On-
Grade Carbon Steel Storage Tank Bottoms:
“Galvanic protection systems can be applied to tank
bottoms where the metallic surface area exposed to
the electrolyte can be minimized through the
application of a dielectric coating or the area is small
due to the tank size or configuration.”
(+) (-)
Return
Rectifier
Anode
CURRENT FLOW
Impressed Current Cathodic Protection
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Impressed Current
Cathodic Protection System
Anodes
Rectifier
Wiring
Tanks & Piping
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Above Ground Storage Tank Vertical Impressed
Current Anodes - Existing Tanks
Sand
Anodes
Rectifier
Negative
Connection
+
-
Concrete
Ringwall
Tank
Anodes Rectifier
-
+
Negative
Connection
Tank
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Anodes
Junction
Box
Rectifier
- +
Deep Anode
Tank
(+)
(-)
Rectifier Tank
Tank Tank
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Computer Guided Horizontally
Bored Anode System
Tank
Rectifier
(+)
(-)
Anode
Splice Box
Anode
Pipe
Monitoring
Pipe
Anode Pipe
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ABOVEGROUND STORAGE TANK
CATHODIC PROTECTION
3” PVC 20%
Exposure
Anode Material
Anode Tube
10’
Typical
Test/Access
Station
Grade
Aboveground
Storage Tank
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Rectifier Units
Explosion or Non Explosion Proof ?
AC Input ?
AC Availability ?
CP Applications for Re-bottomed or
New Tanks
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CP Installation on Rebottomed Tank
Above Ground
Storage Tank Bottoms
with Secondary Containment
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Liner
Floor
Anode Conduit
CP Installation on Double Bottom Tank
New Tank Construction with Liner
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Anode
Reference
Cells
Tank
Impressed Current
Junction
Box
(-)
(+)
Rectifier
Anode & Reference Cell Placement
in High Resistance Sand
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Installation of CP System on
Lifted AST
Installation of CP System on
Lifted AST
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Cathodic Protection Survey (When Tank is Full)
Tank
Rim Potential Measurements
Portable Reference Cell
Soil
(+)
? ?
-850mV
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Soil Access Station (Thru Liner or Asphalt)
Reference Cell Placement Under Tank Bottom
(Note obtain and store native readings)
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Reference Cell Monitoring Conduit
Tank
Monitoring
Conduit
Cathodic Protection Monitoring
• Read rectifiers every
30 days.
• Conduct annual
inspection (obtain
potentials) by NACE
certified individuals.
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Hot Asphalt Tank Bottoms
Stray Current ?
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Pipeline Integrity Inspections
Qualifications
of the corrosion engineer
• Certified by N.A.C.E.
(National Association of Corrosion Engineers)
• Experienced in Cathodic Protection
• Experienced in Cathodic Protection of Fuel
Storage Systems
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Internal Corrosion
Anode Cathode
Water / Sediment
Fuel Product
Internal Corrosion
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Coating Anode
Bolt
Tank Bottom
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Recommended Practices
API-651 - Cathodic Protection of Aboveground Petroleum
Storage Tanks:
NACE RP0193-2001 - External Cathodic Protection of On-
Grade Carbon Steel Tank Bottoms:
Iron Water Fire Water
Piping
Pitting (concentrated)
corrosion attack on ductile iron
pipe.
31
Questions?
Thank You
James T Lary
Corrpro Companies, Inc.
1055 West Smith Road
Medina, Ohio 44256
330-723-5082
email jlary@corrpro.com
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