ammonia plant design for 1 mtpa

7/23/2019 Ammonia Plant Design for 1 Mtpa

1/43

NAADBGN YENBP @JVGMB CD\ > APYN

(6969 APY@)

N Y\JVJBPNPGDB DB

LHN\NP GBVPGPZPJ DC PJFBDEDMW, AJJ\ZP

FHJAGFNE @JYN\PAJBP

LW?

Y\NPJJK ANEE

PNZCJJ^ NHAN@

ADH@. ^NVGA


2/43

GBP\D@ZFPGDB

Naadbgn dbj dc thj adst gapdrtnbtlnsgf fhjagfne dc thj wdre`.

Anodr suppegjr dc thj cjrtgegzjr bgtrdmjb.

Dthjr usjs, gb ldth drmnbgf nb`

gbdrmnbgf fhjagfne prd`uftgdb.

Angb cubftgdb dc naadbgn gs td suppey

bgtrdmjb gb n rjnftgvj cdra.

Naadbgn n prjfursdr td cdd`stuccs nb`

cjrtgegzjrs fdbtrglutjs td butrgtgdbne

bjj`s.

Naadbgn gs ldth fnustgf ns wjee ns

hnznr`dus.


3/43

AJPHD@V DC NAADBGN

Y\D@ZFPGDB

Hnljrs Yrdfjss

Fynbnag`j Yrdfjss

Jejftrdeysgs Yrdfjss

Ynrtgne Dxg`ntgdb dc Hy`rdfnrldbs

N`gnlntgf Yrj-\jcdragbm

Fdne Mnsgcgfntgdb Yrdfjss

>.

Eurmg Yrdfjss


4/43

EGB@J NAADBGN FDBFJYP (ENF)

ENF gs n bdvje lrjnkthrdumh gb thj `jsgmb phgedsdphy

dc naadbgn penbts.

MVCF naadbgn-GS penbt gs cgrst penbt gb thj wdre`

lnsj` db ENF.

Jegagbntgdb dc thrjj fntneytgf prdfjss stjps (g.j.

sjfdb`nry rjcdragbm, HP shgct fdbvjrsgdb nb`

ajthnbntgdb).

\j`ufgbm thj tdtne fntneyst vdeuaj td npprdx. :9% dc

thnt gb n fdbvjbtgdbne penbt.


5/43


6/43

ENF N@SNBPNMJV

Yrdvgsgdb dc rjcdraj` mns purgcgfntgdb systja ly prjssurj swgbmn`sdrptgdb whgfh hns n prdvjb nb` ubantfhj` rjegnlgegty.

Phj mjbjrntgdb dc gbjrt crjj sybthjsgs mns, rjsuetgbm gb sgmbgcgfnbt

snvgbms gb sybthjsgs eddp nb` jegagbntgbm n purmj mns purgcgfntgdb stjp.

Yurj hy`rdmjb nb` purj bgtrdmjb nrj `grjftey nvngenlej crda prdfjss

stjnas.

Phj sgapegcgj` cedw-shjjt nesd rjsuet gb n rj`ufj` stnrt up tgaj nb`

gapdrtnbt snvgbm gb cjj` stdfk fdbsuaptgdb.

Nb dvjrnee sgapegcgfntgdb dc fenssgfne `jsgmb, rjsuetgbm gb snvgbms gb

gbvjstajbt fdsts, fdbstruftgdb tgaj, nb` sgtj nrjn ns wjee ns fntneyst

rjpenfjajbts fdsts.


7/43

ENF Y\DFJVV @JVF\GYPGDB

YENBP FNYNFGPW

Egqug` BH6 6969 APY@BH6? 77.:% ]t. Agb.H


8/43


\N] ANPJ\GNE

Bnturne Mns

Ajthnbj 80 td 79%Jthnbj : td 8%FD td :%Yrdpnbj > td 0%g-Lutnbj 9 td 9.>999

Kfne/BA6Bjt ? 8:99 td 7999 Kfne/

BA6@jbsgty 9.88 td 9.79 m/ae


9/43


FNPNEWVPV \J^ZG\J@

Vr. Bd. FNPNEWVP ZVJ@ CD\- FNPNEWVP ZVJ@->. \jcdrajr

Pdp Lj`Ldttda Lj` YdtnshBg-Fr


10/43


ZPGEGPGJV

@j-agbjrnegzj` wntjr ?

pH ? 8-7

Vgegfn ? 59.9< ppa

Fhedrgbj ? 59.9> ppa

Fdb`uftgvgty ? >9 A-ahd/ fa anx

Vtjna?

Hgmh prjssurj (HY) stjna ? >>9 lnr m

Aj`gua prjssurj (AY) stjna ? 68 lnr m

Edw prjssurj (EY) stjna ? 0.: lnr m

Ngr?

@jw pdgbt? 5-89f

Jejftrgf Ydwjr?

>> KS - 6.6 KS - 009 S -


11/43



12/43

HW@\DMJB VJFPGDB

VPJNA \JCD\AJ\ VJFPGDB

Yrjssurj rj`uftgdb sjftgdb 60 lnr.

Yrjhjntgbm gb \jcdrajr fdbvjftgdb

sjftgdb td 68:f.

Mns rdutj` td `jsuecurgzjr.

Mns td stjna rntgd 6.

Curthjr prjhjntgbm td ::9f.

Phgs prjhjntj` rjnftgdb agxturj gs

`gstrglutj` td thj tdp dc n Bg fntneyst cgeej`

rjcdrajr tuljs gb thj rjcdrajr curbnfj.

Jxgt mns tjaprnturj 8:9 f.

Ydtnsh Fntneyst nb` agbgaua stjna ejvje

angbtngbj` td nvdg` fnrldb cdratgdb nb`

`jpdsgtgdb.

\JCD\AJ\ \JNFPGDB

FH0+ H


13/43

VPJNA

BM

Y\

V

@JVZ

ECZ\\G_J\

\JCD\AJ\

CZJE

Y\JH

JNPJ\

Y\JHJNPJ\


14/43

@JVZECZ\G_NPGDB VJFPGDB

@JVZECZ\G_NPGDB \JNFPGDB

_bD + H


15/43

FN\LDB @GDXG@J \JADSNE VJFPGDB

FD


16/43

Y\JVVZ\J V]GBM N@VD\YPGDB

Mns agxturj gs cj` td n`sdrljr nt nalgjbt tjapjrnturj nb` gbfrjnsj` prjssurj.

YVN prdfjss wdrks ljtwjjb twd prjssurj ejvjes? (>) N`sdrptgdb & (


17/43

BGP\DMJB VJFPGDB

NG\ VJYN\NPGDB VJFPGDB

Ngr sjpnrntgdb penbt lnsj` db edw tjapjrnturj prdfjss, usgbm adejfuenr sgjvjnlsdrljr cdr fejnbgbm thj ngr ljcdrj jbtjrgbm thj edw tjapjrnturj sjftgdb.

Yrdfjss ngr gs fdaprjssj` td :.< lnr ly ajnbs dc thj prdfjss ngr fdaprjssdr

Fddegbm dc prdfjss ngr td +89f tnkjs penfj gb thj prdfjss ngr fddejr.

Fddej` prdfjss ngr pnssjs thrdumh dbj dc twd adejfuenr sgjvj nlsdrljrs,

whjrj fnrldb `gdxg`j, hy`rdfnrldb nb` thj rjangbgbm wntjr vnpdr nrjrjadvj`.

Yrdfjss ngr sjpnrntjs gbtd twd pnrts. Dbj pnrt jbtjrs thj fde` ldx `grjftey,

whjrj gt fddes `dwb td ->=69f (bjnrey egqujcnftgdb) gb thj angb hjnt jxfhnbmjr.

Phj dthjr pnrts dc thj prdfjss ngr wnras up td +6899f nb` curthjr fdaprjssjs

gb thj ngr lddstjr fdaprjssdr td npprdxgantjey 7.< lnr m.

Fdaprjssj` ngr prj fddes td npprdxgantjey ->969f nb` jxpnb`s gb edw pr

fdeuab 9.6= lnr

Yrdfjss ngr sjpnrntjs gbtd dxymjb jbrgfhj` egqug` nt thj ldttda nb` n purj

bgtrdmjb prd`uft dc thj tdp.

Bgtrdmjb tdp mns fdb`jbsj` td dltngb purj hy`dmjb


18/43

NAADBGN VWBPHJVGV VJFPGDB

NAADBGN FDBSJ\PD\

77.77% purj H06 Lrnm

prjssurj gb cdur stnmj fjbtrgcumj fdaprjssdr gs`rgvjb ly hgmh prjssurj stjna turlgbj.

Vybthjsgs mns gs prjhjntj` gb hdt jxfhnbmjr nb` gs

rdutj` td naadbgn sybthjsgs fdbvjrtjr nt >8:9f .

Vybthjsgs dc naadbgn crda mnsjdus hy`rdmjb nb`

bgtrdmjb gs nb jxdthjragf rjnftgdb. Fdbvjrtjr hns thrjj fntneyst lj`s dc thj nxgne /

rn`gne typj wgth gbtjraj`gntj fddegbm ly hjnt

jxfhnbmjr.

Nctjr fdbvjrsgdb td naadbgn, hjnt rjfdvjry gs

`dbj nt vnrgdus stnmjs, cgbne tjapjrnturj dcnaadbgn gs -


19/43

J^ZGYAJBP @JVGMB

J^ZGYAJBPV @JVGMBJ@

FN\LDB @GDXG@J NLVD\YPGDB

FDEZAB A@JN VPD\NMJ PNBK

A@JN YZAY


20/43

NLVD\YPGDB FDEZAB @JVGMB

@NPN?

F9< Cedwrntj 1 >>038=:0.= aa dc Hm

Ynrtgne Yrjssurj dc FD< gb cjj` 1 0>/>99 *>8=:0.=

1 ==98.>8 aa dc Hm

Hjbrys Fdbstnbt HFD< 13696.8: kYn/ade crnftgdbNt > w/w% YY dc FD*3696.8:

1 36.968: hYn

Pdtne Yrjssurj 1/>99*99.


21/43

Ade crnftgdb gb egqug` 1( >/00)/((>/00+77/:8.0))

1 9.9/W/Y< 1 >99.99

MW>+ EX + MW-W

EAX>1 M(W>+W1 MA/EA* (W>-W.79: . (9.09387)

X> 1 9.63=*AMA/EA

CD\ AMA/EA1 9.:

X>1 9.>9386:

NP 9.3X>1 9.>07:36

NP 9.8

X>1 9.>=9763

BDM1 >.9

BDM =.: >9.0 >>.> >:.>


22/43

FDEZAB @GNAJPJ\

Mns cedw rntj 1 :.7>9: kade/m

Egqug` cedw rntj 1 >3.98: kade/m

Vjejft 69 aa gbtnedx sn``gjs(fjrnagf)

CY(Ynfkgbm Cnftdr)1 >=9 a->

Mns `jbsgty 1 3.98:/:.7>9:)(

@jbsgty cdr .6).:*>99

1 3= %

Sw 1 ((k0*v(E-S)/(>6.>*CY(E/E).>).:

1 >0.7 Km/a0.7

1 :.0: a


23/43

@gajtjr 1 (0/*:.0:)

@gnajtjr 1 9-6)/(9-7)

1 .=>0*>9-:/9-7)

1 36.88

E]* 1 (>3.98:*:8.0/:.=30.9= Km/sa30.9= , h1 9.9:

C>1 C


24/43

HE 1 9.69:h(VF)E.: K6(:

_ 1 >3:

HM1( 9.9>>h(VF)S.:(@F/9.69:)>.>>(C>*89*=.77>.3:)

HDM 1 >.6:=

_ 1 >.6:=1 >3.6 a


25/43

VPD\NMJ PNBK @JVGMB CD\ >9999t NAADBGN NP NPADVYHJ\GF

Y\JVVZ\J

Sdeuaj \jqugrj` 1 ]jgmht gb km * @jbsgty

1 >9999*>9R6*38033


26/43

Vtdrnmj Pnbk Vhjee @jsgmb

Y 1 ( H 9.6) * 7.89=*>9-3

t 1 Y@D/(93

t 1 .=9 aa

Pnkgbm H 1 8*>93 B/a


27/43

Pnkgbm H 1 >8 a

Y 61 9.>>80*>93 B/a=.37 aa

Pnkgbm H 1 >3 aY 01 9.>9:9*>9

3B/a:.37 aa

Pnkgbm H 1 >0 aa

Y :1 9.97>3*>93 B/a6.37 aa

Pnkgbm H 1 >< a

Y 31 9.9=893 B/a>.37 aa

Pnkgbm H 1 >9 a

Y= 1 9.9307*>93 B/a


28/43

@jsgmb dc wgb` mgr`jrs, _

_ 1 9.9:8@9

1 6


29/43

A@JN Cedw rntj(^) 1 9.73699 a

Ygpj @gnajtjr 1 > a

]hjrj, u 1 vjedfgty dc ceug` nt dutejt (a/s)

u 1 0.39.8 * >9

:

(dc thj dr`jr >9

:

)Edss dc Hjn` `uj td crgftgdb gb pgpj

]hjrj,

c 1 Crgftgdb Cnftdr

(hcshc`) 1 6.


30/43

Anbdajtrgf Hjn` ( Ha) 1 >= + (hcshc`)

Ha


31/43

YENBP JFDBDAGFV


32/43

FDVP JVPGANPGDB NB@

Y\DCGPNLGEGPWLnsgs? 669 `nys dc Yrd`uftgdb pjr Wjnr

YZ\FHNVJ@ J^ZGYAJBP FDVP 1 Angb Jqugpajbt + Nuxgegnry Jqugpajbt Fdst

Jqugpajbt ^unbtgty Pdtne fdst (Frdrj \s.)\jcdrajr > >9:.:8

@jsuecurgzjrs > 6>6.=NVZ > 7.=3

Fde` Ldx > 37.8:Hjnt Jxfhnbmjrs 9:.:8

Yuaps .3=


33/43

Pdtne Fnpgtne Gbvjstajbt 1 Cgxj` Fnpgtne Gbvjstajbt + ]drkgbm Fnpgtne Gbvjstajbt

CGXJ@ FNYGPNE GBSJVPAJBP 1 (@grjft fdst + Gb`grjft fdst)

@grjft FdstVr Bd. Pypj Dc Fdst % Dc Jqugpajbt Fdst Fdst (\s. Gb

Frdrjs)> Jqugpajbt ---- :>>.3=: =3.=:6 Gbstruajbtntgdb 9=7.98: Luge`gbm >: =3.=:3 Wnr` Gaprdvjajbt 0


34/43

Gb`grjft FdstVr. Bd. Gtja % Dc Jqugpajbt Fdst Fdst (\s. Gb Frdrjs)

>. Jbmm.& Vupjrvgsgdb >: =3.=:3 8>.8=

6. Fdbtjmjbfgjs 3 69.=9Pdtne >87.6< frdrjs

PDPNE CGXJ@ FNYGPNE 1 (@G\JFP + GB@G\JFP) FNYGPNE 1 >> F\D\JV

GBGPGNE ]D\KGBM FDVP 1 >:% DC PDPNE GBGPGNE FDVP

C.F.G.(X)1 >> + 9.>: * X

X 1 >:>3.7:0 F\D\JV

CGX FNYGPNE GBSJVPAJBP1 N + L 1 \s. >:>3.7:0 frdrjs/-

]D\KGBM FNYGPNE GBSJVPAJBP

Pdtne fnpgtne Gbvjstajbt1 Cgxj` Fnpgtne Gbvjstajbt + ]drkgbm Fnpgtne

PFG1 >:>3.7:0 + 9.>: PFG

PFG1 >=80.3:< frdrj \s.

]drkgbm Fnpgtne Gbvjstajbt 1 >:% Dc Pdtne fnpgtne Gbvjstajbt

1


35/43

PDPNE Y\D@ZFPGDB FDVP

Pdtne prdùftgdb Fdst 1 Anbucnfturgbm Fdst + Mjbjrne Jxpjbsjs

Anbucnfturgbm Fdst 1 @grjft Yrdùftgdb Fdst + Cgxj` Fhnrmjs + Yenbt Dvjrhjn`

Fdsts@grjft Yrdùftgdb Fdst

\nw Antjrgnes Nbbune\jqugrjajbt(a6) Vpjfgcgf Fdst Fdst (Frdrj \s.)

Bnturne Mns 0.=>*>98 6.:6.97@grjft Yrdùftgdb Fdst

Ztgegtgjs Nbbune\jqugrjajbt

Vpjfgcgf Fdst Fdst (Frdrj \s.)]ntjr (a6) :.03*>93 6.: \s/a6 >.7>998 9X

Yntjbts nb` \dynetgjs > % dc PYF 9.9>XPdtne =3.96< + 9.>


36/43

Cgxj` FhnrmjsYnrtgfuenrs Lnsgs Fdst (Frdrj \s.)@jprjfgntgdb ---- 36.3:

Gbtjrjst >9 % dc PFG >=8.03:Edfne Pnxjs 0 % dc CFG 39.3=8Gbsurnbfj > % dc CFG >:.>37

Pdtne 6>=.78C.F.G. 1 \s. >:>3.7:0 Frdrjs

Vnevnmj Sneuj 1 \s. 3.7:03=.78

1 396.


37/43

Mjbjrne JxpjbsjsYnrtgfuenrs Lnsgs Fdst (Frdrj \s.)

Nàgbgstrntgvj Fdsts >: % dc DE 9.9>: X@gstrglutgdb & Anrkjtgbm Fdsts >< % dc PYF 9.>< X

\ & @ 0 % dc PYF 9.90 XPdtne 9.>=: X

Pdtne Yrdùftgdb Fdst1 Anbucnfturgbm Fdst + Mjbjrne JxpjbsjsX1 396.=: X

Pdtne Yrdùftgdb Fdst1 8::.370 Frdrj \s/yr.

Anbucnfturgbm Fdst 1 =9:.7: frdrjs


38/43

GBFDAJ @ZJ PD NAADBGN VNEJ

Vnejs Yrgfj 1 \s >8:99/ AP

@ngey Yrd`uftgdb 1 6969 AP/@ny

]drkgbm @nys 1 669 @nys

Nbbune Gbfdaj crda naadbgn 16969 * >8:99 * 669

1 >807.8>: frdrjs

GBFDAJ @ZJ PD N\MDB VNEJV

Vnejs Yrgfj 1 \s 69/Ba6

@ngey Yrd`uftgdb 1 >8=38.< Ba6/@ny

]drkgbm @nys 1 669 @nys

Nbbune Gbfdaj crda Nrmdb 1 69 * >8=38.< * 669

1 >8.:8> frdrjs

PDPNE NBBZNE GBFDAJ 1 >838.673 Frdrj \s/yr.


39/43

Mrdss Nbbune Jnrbgbm 1 Pdtne Vnejs JnrbgbmPdtne Yrd`uftgdb Fdst

1 >9>: Frdrj \s/yr.

Bjt Nbbune Jnrbgbm 1 Mrdss Nbbune JnrbgbmGbfdaj PnxVurfhnrmj

@j

1 3::.=799

1 :9.=7 %


40/43

\ntj Dc \jturb 1 (Bjt Yrdcgt / P.F.G.) * >99

1 63.=: %

Yny Lnfk Yjrgd` 1 C.F.G. / Bjt Yrdcgt

1 09>.36 AP/`ny

Nftune \ntj dc Yrd`uftgdb 1 6969 AP/`ny

Lrjnkjvjb Ydgbt 1 03.


41/43

HN_N\@V NB@ VNCJPW

Naadbgn (Mns)

Pdxgf jccjfts? Phj mns grrgtntjs nee thj pnrts dc thj rjspgrntdry systja.

Hnznr`dus rjnftgdb? Cdras jxpedsgvj agxturj wgth ngr, vgdejbt rjnftgdbs wgth

Ldrdb, Hneg`js.

Hy`rdmjb

Pdxgf jccjfts? Fenssj` ns n sgapej nsphyxgntj mns.

Hnznr`dus rjnftgdb? \jnftgdb hnznr`s wgth dxg`nbts sufh ns fhedrg`j `gdxg`j,

fdppjr dxg`j

B-Ajthye @g Jthnbde Nagbj

Pdxgf jccjfts? Phj vnpdr grrgtntjs thj jyjs nb` rjspgrntdry systja.

Hnznr`dus rjnftgdb? Cdras jxpedsgvj agxturj wgth ngr, vgdejbt rjnftgdbs wgth

Ldrdb, Hneg`js.

HN_N\@


42/43

HN_N\@V NB@ VNCJPW

Lnsgf Vncjty \uejs?

Phjrj nrj cjw lnsgf sncjty ruejs

whgfh aust lj dlsjrvj` whjb

wdrkgbm gb naadbgn anbucnfturgbm

nrjn?

Bd sadkgbm

Bd `rgbkgbm jxfjpt wntjr

cdub`ntgdbs

@d bdt tnapjr wgth cnuety

jqugpajbts dr jejftrgfne cgttgbms

]jnr nee pjrsdbne prdtjftgvj

jqugpajbts prdvg`j`Yjrsdbne Yrdtjftgvj Fedthgbm nb`

Jqugpajbts?

N wg`j rnbmj dc fedthgbm nb`

jqugpajbts cdr pjrsdbne prdtjftgvj gb

n vnrgjty dc antjrgnes nrj nvngenlej,

nadbm dc whgfh nrj cdub` sugtnlej tdtnsk shdue` lj usj`?

VNCJPWVr.Bd.

Yjrsdbne Yrdtjftgvj@jvgfj

Cdr Yrdtjftgdb nmngbst

>. Vncjty hnts Fhjagfne spenshjs wdrkgbm wgth

dvjrhjn` pgpjs, tnbks, hjnt jxfhnbmjrs,

jtf.


43/43

\JCJ\JBFJV

\dljrt, H. Yjrry & Fjfge, H. Fhgetdb, Fhjagfne Jbmgbjjrs Hnb`lddk, :thJ`gtgdb,

AfMrnw-Hgee Fdapnby.

\ K Vgbbdtt, Fduesdb & \gfhnr`sdbs Fhjagfne Jbmgbjjrgbm @jsgmb, Sdeuaj 3, 0th

J`gtgdb, Jesjvgjr.

A S Odshg, S S Anhnonbg & V L Zanrog, Odshgs Yrdfjss Jqugpajbt @jsgmb, 0th

J`gtgdb , AfMrnw-Hgee Fdapnby.

L.G. Lhntt & V.A. Sdrn, Vtdgfhgdajtry, 6r`j`gtgdb, AfMrnw-Hgee Fdapnby.

A.S. Odshg & S.S. Anhnonbg, Yrdfjss Jqugpajbt @jsgmb, 6r`J`gtgdb, ANFAGEENB-

ammonia plant design for 1 mtpa

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