amet,tm sample canada cpr-whmis ghs sds

7/31/2019 Amet,Tm Sample Canada Cpr-whmis Ghs Sds

1/20

SAMPLE CANADA (MATERIAL) SAFETY DATA SHEET_ENGLISHPrepared to CPR-WHMIS and GHS Standards

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 20Product Code: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/ 07/2012

1.1 Identification of the substance or mixture 1.1.1 Mixture name : Fendell Cleaning Solvent Blend No. 31.1.2 Product/SDS Code : FCSB No. 31.1.3 Product description : Mixture of solvents.

1.2 Uses of the mixture and uses advised against1.2.1 Uses of the mixture : Flushing and cleaning of proprietary equipments.1.2.2 Uses advised against : For industrial use only. Not for home use.

1.3 Company Identification 1.3.1 Manufacturer/Supplier : Sao Boso Chemical Company, Ltd.1.3.2 Contact information

Street address : Fendell Industrial Park 3729 Bensonville Hwy, # A-1 ComplexAny town, Our State, 12345-6789U.S.A

Telephone number : 1-(877)-000-0000 (USA)Fax number : 1-(877)-000-0012 (USA)

1.3.3 E-mail of contact person : [email protected]

1.4 Emergency telephone number (s) : CANUTEC: 1-613-996-6666 (Canada)* 666 on a cellular phone.

Poison Control Center: 1-800-268-9017 (ONTARIO)

1.4.1 Further information obtainable from : Regulatory AffairsMonday to Friday: 6 am - 6 pm (Pacific Time)

2.1 Classification of the substance or mixtureProduct definition : Mixture of solvents.

2.1.1 Emergency Overview : Flammable liquid and vapor. Irritating to eyes, skin, andrespiratory tract. Harmful or fatal if swallowed, if inhaled,and in contact with skin. May be absorbed through intact skin.Avoid prolonged contact with skin.

Potential Health Effects : WARNING! FLAMMABLE LIQUID AND VAPOR.HARMFUL! Keep away from open flame, heat, and staticdischarge sources. Aspiration hazard if swallowed. Irritant andcentral nervous system depressant. High vapor concentrationsare irritating to the nose, throat, and respiratory tract.

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

2. HAZARDS IDENTIFICATION


2/20

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 2 of 20Product Code: FCSB No. 3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/07/2012

Avoid inhalation of vapor and contact with skin and eyes. May be harmful or if swallowed. Remove victim to fresh air if overcome with vapor/mist/fumes due to inhalation. If splashed ineyes, flush with water for 15 minutes. If in contact with skin,

flush with water and wash with mild soap. In medical emergency,CALL A PHYSICIAN, OR POISON CONTROL CENTER (1-800-268-9017) IMMEDIATELY .

Chronic Effects : No evidence of adverse effects from available information.

CONTACT CANUTEC 24 Hours/day (in the event of emergency involving dangerous goods).EMERGENCY : (613) 996-6666 (call collect)Cellular phone : * 666FAX : (613) 954-5101

Note : Read product Safety Data Sheet completely and thoroughlybefore using this product.

2.2 Classification according to WHMIS and GHS

WHMIS ClassificationWHMIS Classes Class DefinitionClass B-2 Flammable and combustible material - Flammable liquidClass D-2B Poisonous and infectious material - Other effects Toxic

Classification according to GHSGHS Classification

Potential Hazards : Highly flammable liquid and vapor. Irritating to eyes, skin, andrespiratory tract. A component in the product may cause centralnervous system effects. Such central nervous system effects caninclude drowsiness, headache, and dizziness. Repeated exposuremay cause skin dryness or cracking.

Hazard Class Category Hazard Code Hazard StatementFlam. Liq. 2 H225 Highly flammable liquid and vapor.Acute tox. (dermal) 4 H312 Harmful in contact with skin.Acute tox. (inhalation) 4 H332 Harmful if inhaled.Acute tox. (oral) 4 H302 Harmful if swallowed.Aspiration hazard 1 H304 May be fatal if swallowed and enters airways.Skin corro./irrit. 2 H315 Causes skin irritation.Serious eye dam./Eye irrit. 1 H318 Causes serious eye damage.Reprod. tox. D 2 H361d Suspected of damaging fertility or the unborn

Child.STOT SE: RTI 3 H335 May cause respiratory irritation.STOT SE: NE 3 H336 May cause drowsiness or dizziness.STOT SE: RE 2 H373 May cause damage to organs through

Prolonged or repeated exposure.Other Hazards - EUH066 Repeated exposure may cause skin dryness or crackin


3/20

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 3 of 20Product Code: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/07/2012

Hazard symbol(s)/Indication of DangerF : Flammable. X i : Irritant. Xn : Harmful.

2.3 Label Elements and Hazard Symbols [WHMIS and GHS]

2.3.1 WHMIS Hazard Symbols

2.3.2 GHS Hazard Symbols/ Label ElementsHazard Pictograms

Signal word: Danger

Hazard statement(s)H225 : Highly flammable liquid and vapor.H302 : Harmful if swallowed.H304 : May be fatal if swallowed and enters airways.H312 : Harmful in contact with skin.H315 : Causes skin irritation.H318 : Cause serious eye damage.H332 : Harmful if inhaled.H335 : May cause respiratory irritation.H336 : May cause drowsiness or dizziness.H361d : Suspected of damaging fertility or the unborn child.H373 : May cause damage to organ(s) through prolonged or repeated

exposure.Precautionary statement(s)P210 : Keep away from heat/sparks/open flames/hot surfaces No

smoking.P233 : Keep container tightly closed.P261 : Avoid breathing dust/fume/gas/mist/vapors/spray.P264 : Wash hands with soap and plenty of water after handling.P280 : Wear protective gloves/protective clothing/eye protection/face

protection.P310 : Immediately call a POISON CENTER or doctor/physician.P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.P501 : Dispose of contents/container to be in accordance with


4/20


local/regional/national regulations.2.4 Other hazards

Substance meets the criteria : No.for PBT (Persistent,

Bioaccumulative, and Toxic)

Substance meets the criteria : No.for vPvB (very Persistent andvery Bioaccumulative)

Other hazards which do not : Repeated exposure may cause skin dryness or cracking.result in classification

This product is considered to be hazardous according to the Canadian Controlled Product Regulation.

3.1 Description of the substance/mixture : Mixture of solvents.

HAZARDOUS COMPONENTS

3.1.1 WHMIS ClassificationsIngredient/Chemical Name CAS No. WHMIS Classes* WHMIS Health Effects CriteriaButan-2-one 78-93-3 B2

D2B Eye irritation-toxic-other

Butan-1-ol 71-36-3 B2D2B Eye/Skin irritation-toxic-other

Ethyl hydroxide 64-17-5 B2D2B Eye irritation-toxic-other

Propan-2-ol 67-63-0 B2D2B Eye irritation-toxic-other

Methylbenzene 108-88-3 B2D2A

D2B

Teratogenicity and embryotoxicity -very toxic other Skin irritation - toxic - other

Xylol 1330-20-7 B2D2A

D2B

Teratogenicity and embryotoxicity -very toxic other Skin irritation - toxic - other

*WHMIS Classification :B2 - Flammable and combustible material - Flammable liquidD2A - Poisonous and infectious material - Other effects - Very toxicD2B - Poisonous and infectious material - Other effects Toxic

3. COMPOSITION/INFORMATION ON INGREDIENTS


5/20


3.1.2 GHS ClassificationsComponent CAS No. EC No. Index No. UN No. Percent GHS Classification TypeButan-2-one 78-93-3 201-159-0 606-002-00-3 1193 40 - 60 Flam. Liq. 2, H225

Eye Irrit. 2, H319STOT SE 3, H336EUH066

[1]

[2]

Butan-1-ol 71-36-3 200-751-6 603-004-00-6 1120 30 - 60 Flam. Liq. 3, H226Acute Tox. 4 * , H302STOT SE 3, H335Skin Irrit. 2, H315Eye Dam. 1, H318STOT SE 3, H336

[1]

[2]

Ethyl hydroxide 64-17-5 200-578-6 603-002-00-5 1987 10 - 40 Flam. Liq. 2, H225 [2]Propan-2-ol 67-63-0 200-661-7 603-117-00-0 1219 10 - 20 Flam. Liq. 2, H225

Eye Irrit. 2, H319STOT SE 3, H336

[1]

[2]Methylbenzene 108-88-3 203-625-9 601-021-00-3 1294 1 - 5 Flam. Liq. 2, H225

Repr. 2, H361d ***

Asp. Tox. 1, H304STOT RE 2, H373 **

Skin Irrit. 2, H315STOT SE 3, H336

[1]

[2]

Xylol 1330-20-7 215-535-7 601-022-00-9 1307 1 - 5 Flam. Liq. 3, H226Acute Tox. 4 *, H332Acute Tox. 4 *, H312Skin Irrit. 2, H315

[1]

[2]Components in this product are not known or reported to be carcinogenic in humans by any reference sourceincluding US OSHA, IARC, US NTP, US ACGIH, or US EPA.

3.2 Additional information[1] Substance classified with a health or environmental hazard.[2] Substance with a workplace exposure limit.[3] Substance meets the criteria for PBT.[4] Substance meets the criteria for vPvB.

Occupational exposure limits, if available, are listed in Section 8.

See Section 2 for the full text of the H-codes declared above.

4.1 Description of first aid measures

4.1.1 General information : General first aid measures should be followed. In case of persistent adverse effects, seek immediate medical attention.Remove contaminated clothing and shoes promptly, and washthoroughly before re-use.

4. FIRST AID MEASURES


6/20

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 6 of 20Product No: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/07/2012

4.1.2 Following inhalation : NOTE: Reports have associated repeated and prolongedoccupational overexposure to solvents with permanent brainand nervous system damage. Intentional misuse by deliberatelyconcentrating and inhaling the contents may be harmful or fatal.

: Emergency responders should use positive air suppliedrespiratory protection when removing the victim from area.Remove person to fresh air. If not breathing, administer CPR until help arrives, or the victim starts to breathe on their own.Give artificial respiration if breathing has stopped. Seek medicalattention immediately.

4.1.3 Following skin contact : If exposure occurs, immediately flush the affected areathoroughly with water for at least 15 minutes. Use soap if available. Remove contaminated clothing, including shoes, after

flushing has begun. Wash clothing before re-use. If irritation persists, seek medical attention.

4.1.4 Following eye contact : Immediately flush affected eye with water for at least 20minutes. ilt the head to prevent chemical from transferring tothe unaffected eye. Seek medical attention without delay after flushing.

4.1.5 Following ingestion : DO NOT INDUCE VOMITING if swallowed. Rinse mouth outwith water. Dilute with milk or water. Never give anything todrink if the victim is unconscious or having convulsions. Seek

medical attention immediately. Contact Poison Control Center atonce.

4.1.6 Self protection of the first aider : Appropriate personal protective attire should be worn.

4.1.7 Note to the doctor : Suitable medical intervention should be provided based onsymptoms.

4.2 Most important symptoms and : Irritating to eyes, skin, and respiratory tract upon exposure. Higheffects, both acute and delayed vapour concentrations are irritating to eyes, nose, throat, and

lungs; may cause unconsciousness or other signs of central

nervous system depression. Frequent or prolonged skin contactmay irritate the skin and cause skin rash (dermatitis). May causeskin sensitization, an allergic reaction which becomes evident onre-exposure to this material. Small amounts of this liquid may bedrawn into the lungs by either swallowing or vomiting. This maycause severe and delayed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi

(bronchopneumonia). Ingestion may cause irritation of digestivetrack and diarrhea.


7/20


4.3 Indication of any immediate : Always get immediate medical attention/advice when symptomsmedical attention and special persist.treatment needed

Fire Fighting Measures : The following applies to Butan-2-oneFLASHPOINT: 26 oFSPECIFC GRAVITY: 0.806 @ 68 o FEXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%.AUTOIGNITION TEMPERATURE: 961.0 oF.

5.1 Extinguishing media

Suitable extinguishing media : Either allow fire to burn out under controlled conditions, or

extinguish with alcohol type or all purpose type foam, or drychemical powder. Try to cover liquid spills with appropriatefoam. Use water spray to cool fire exposed surfaces. Avoidspraying water directly into storage containers due to danger of

boilover. Shut off fuel to fire if possible to do so without hazard.If a spill has not ignited, use water spray to disperse the vapors.

Unsuitable extinguishing media : Do not use high volume water jet.

5.2 Special hazards arising from : Flammable liquid; may release vapors that form flammablethe mixture mixtures when temperatures are at or above the flash point.

There is a danger of explosion when container is heated or infire. Toxic gases will form upon combustion. Vapor maymay accumulate in low or confined areas or travel to aconsiderable distance to a source of ignition and flash back.Avoid runoff into storm sewers and ditches.

Hazardous combustion products : Smoke, fumes, oxides of carbon, irritating or toxic vapors or gases.

5.3 Advice for fire-fighters

Protective equipment for : Respiratory and eye protection gear is required for firefire fighters fighting personnel. Full protective equipment (Bunker Gear)and a self-contained breathing apparatus (SCBA) should beused for all indoor fires and any significant outdoor fires. Use

portable fire extinguisher for small outdoor fires. Use of SCBAmay not be required.

5.4 Additional information : Exposure to decomposition products may cause healthhazards. Cool containers exposed to fire with water spray.Move unexposed containers from fire area if this can be donewithout risk.

5. FIRE FIGHTING MEASURES


8/20


6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel :Protective equipment : Wear suitable personal protective equipment (e.g. clothing,

gloves, safety goggles, and mask/respirator). Ensure adequateventilation; remove all sources of ignition. Notify theappropriate authorities immediately.

Emergency procedures : Eliminate ignition source. Shut off leak if safe to do so. Takeall additional action necessary to prevent and remedy theadverse effects of the spill. Isolate hazard area and deny entryto unauthorized or unprotected personnel. Contain spilled liquidwith sand or earth. DO NOT use combustible materials such as

saw dust. Absorb spill with an inert material (e.g., sand or earth).Then place in a chemical waste container.

6.1.2 For emergency responders : Respiratory and eye protection gear is required for emergency personal protective equipment responders. Full protective equipment (Bunker Gear) and a

self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portablefire extinguisher for small outdoor fires. Use of SCBA may not

be required.

6.2 Environmental precautions : Avoid dispersal of spilt material and runoff into soil, storm

sewers and ditches which lead to natural waterways, or theimmediate environment. Inform the relevant authorities if the

product has entered into the environment.

6.2 Methods of containment and cleaning up

6.3.1 On water : If spill in water, remove from water surface by skimmingor with suitable absorbent material and place in appropriatedisposal container. If allowed by local environmentalregulatory agencies, you may use a suitable dispersant.

6.3.2 On ground/floor : Contain spill and absorb with an inert material (e.g., dry sand or earth). Then place in an appropriate waste container for disposalaccording to local regulations. Large spills should be disposed of via a licensed waste disposal establishment/contractor.

6.3.3 Other information : Contaminated absorbent material may pose similar hazard as thespill product.

6.4 Reference to other sectionsSee Section 1 for emergency contact information.See Section 8 for information on appropriate personnel protective equipment.See Section 13 for additional disposal information.

6. ACCIDENTAL RELEASE MEASURES


9/20


7.1 Precautions for safe handling

7.1.1 Protective measures : Wear appropriate personal protective equipment. Do not get ineyes, on skin, or on clothing. Do not breathe vapor or mist.Do not eat, drink, or smoke when using this product. Use onlywith adequate ventilation. Keep away from sources of ignition.Keep only in original container. Keep tightly closed when notin use. Do not reuse container. Avoid release to the environ-ment.

7.1.2 Advice on general occupational : Avoid eating, drinking and smoking in areas where this producthygiene is handled, used and stored. Wash hands before eating, drinking

and smoking, and at the end of the working period. Contamina-ted work clothing and protective equipment should not be

brought into eating, smoking and drinking areas. Wash soiledclothing before re-using.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and : Store at ambient/room temperature. Protect from extreme coldstorage conditions and heat. Store in a segregated and approved area. Store away

from strong oxidizing agents. Loosen closure cautiously withnon-sparking tools before opening. Keep only in original con-

tainer. Store and use away from sparks, heat, open flames andother ignition sources. Ground and bond containers and recei-ving equipment. Store locked up. Store away from direct sun-light in a dry, cool and well-ventilated area. Containers thathave been opened must be carefully resealed and kept uprightto prevent leakage. Ground and bond containers whentransferring material. Ventilation required along storage floor.

Packaging materials : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic bottles and containers.

7.3 Specific end use(s)

Recommendations : For industrial use only.

Industrial sector specific : Not available.solutions

There is no workplace exposure data available on the product itself.

8.1 Control parameters

7. HANDLING AND STORAGE

8. EXPOSURE CONTROL/PERSONAL PROTECTION


10/20


8.1.1 Component Occupational Exposure Limits (OELs) :

Occupational Exposure Limit (OELs) ValuesButan-2-oneCAS#: 78-93-3 Long Term Limit

(8-hour period)Short Term Limit

(15-minute(s) period)Limit Value Type

Province ppm [mg/m 3] ppm [mg/m 3] Letter Code

Alberta 200 - - - OEL ( Canada, 4/2009 )British Columbia 50 100 - - TWA/STEL, ( Canada, 9/2010 )Ontario 200 - 300 - TWA,STEL ( Canada, 7/2010 )Quebec 200 - - - TWAEV,STEV ( Canada, 6/2008 )

Occupational Exposure Limit (OELs) ValuesButan-1-ol

CAS#:71-36-3Long Term Limit(8-hour period)

Short Term Limit(15-minute(s) period)

Limit Value Type

Province ppm [mg/m 3] ppm [mg/m 3] Letter CodeAlberta 20 60 - - OEL, ( Canada, 4/2009 )British Columbia 15 - 30 - TWA,STEL, ( Canada, 10/2009 )Ontario 20 - - - TWA, STEL, ( Canada, 7/2010 )Quebec - - 50 152 TWAEV,STEV ( Canada, 6/2008 )

Occupational Exposure Limit (OELs) ValuesEthyl hydroxide

CAS#: 64-17-5Long Term Limit(8-hour period)


Limit Value Type


Alberta 1000 1880 - - OEL, ( Canada, 4/2009 )British Columbia - - 1000 - TWA,STEL, ( Canada, 10/2009 )Ontario 1000 1900 - - TWA, STEL, ( Canada, 7/2010 )Quebec 1000 1880 - - TWAEV, STEV,( Canada, 6/2008 )

Occupational Exposure Limit (OELs) ValuesPropan-2-ol



Limit Value Type


Alberta 200 492 400 984 OEL, ( Canada, 4/2009 )

British Columbia 200 - 400 - TWA,STEL, ( Canada, 10/2009 )Ontario 200 - 400 - TWA, STEL, ( Canada, 7/2010 )Quebec 200 983 500 1230 TWAEV, STEV,( Canada, 6/2008 )


11/20


Occupational Exposure Limit (OELs) ValuesMethylbenzene



Limit Value Type


Alberta 50 188 - - OEL, ( Canada, 4/2009 )British Columbia 50 - - - TWA ( Canada, 10/2009 )Ontario 50 - - - TWAEV, ( Canada, 7/2010 )Quebec 100 377 150 565 TWAEV, STEV,( Canada, 6/2008 )

Occupational Exposure Limit (OELs) ValuesXylol



Limit Value Type


Alberta 100 434 150 651 OEL, ( Canada, 4/2009 )British Columbia 100 - 150 - TWA,STEL, ( Canada, 10/2009 )Ontario 100 435 150 650 TWA, STEL, ( Canada, 7/2010 )Quebec 100 434 150 651 TWAEV, STEV,( Canada, 6/2008 )

Exposure limits provided in the above table above contains generic information and guidance on air contaminants in the workplace. Please consult applicable OEL standards of your Province.

Recommended monitoring : If this product contains ingredients with exposure limits,procedures personal, workplace atmosphere or biological monitoring may

be required to determine the effectiveness of the ventilation or

other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure

by inhalation of chemical agents and national guidancedocuments for methods for the determination of hazardoussubstances.

Derived effect levels [DNEL] : See occupational exposure limits table for guidance.

Predicted effect concentrations : Not available.(PNEC Summary)

8.1 Exposure controls

8.1.1 Appropriate engineering : Provide adequate local exhaust ventilation to maintain worker controls below exposure limits. The use of mechanical ventilation

controls is recommended whenever this product is used in aconfined space, is heated above ambient temperatures, or isagitated. Use explosion-proof ventilation equipment.


12/20


8.2 Personal protective equipment8.2.1 Eye and face protection : Safety eyewear complying with an approved standard should be

used when a risk assessment indicates this is necessary to avoid

exposure to liquid splashes, mist, or dust. See OSHA Standard(29 CFR 1910.133) or appropriate Canadian Standards.

8.2.2 Skin protectionHand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handlingchemical products if a risk assessment indicates this in necessary.Refer to 29 CFR 1910.138 or appropriate Standards of Canada.

Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved andshould be approved by a specialist before handling this product.

Consult U.S. OSHA 29 CFR 1910.136.

Other skin protection : Appropriate footwear and any additional skin protection mea-sures should be selected based on the task being performed andthe risks involved and should be approved by a specialist beforehandling this product.

Provide eyewash stations and quick-drench shower facilities .

8.3 Respiratory protection : Use approved respiratory protection equipment. Respirator selection should be based on the form and concentration of

contaminants in the air and in accordance with local regulations.See Canadian CSA Standard Z94.4-93 and applicable standardsof Canadian Provinces.

8.4 Environmental exposure : Emission from ventilation or work process equipment should be controls checked to ensure they comply with the requirements of envi-

ronmental protection legislation. Ensure that emission is at theacceptable level.

9.1 Information on physical and chemical propertiesPhysical state : Liquid.Colour : Characteristic.Odour : Solvent odour.Odour threshold : Not determined.

pH : Not available .Melting/freezing point [ o F] : Not available.

Initial boiling point/range [ o F] : Not available.

Flash point [ o F] : Not available.Evaporation rate (n-Butyl Acetate : Not available.= 1)

9. PHYSICAL AND CHEMICAL PROPERTIES


13/20


Flammability (solid, gas) : Not available.Upper flammability : Not available.Lower flammability : Not available.Vapor pressure, mm Hg @ 75 o F : Not available.

Vapor density (Air = 1) : Not available .Relative density : Not available.Solubility in water, Wt % @ 68 o F : Not available.Partition coefficient: n- : Not available.Octanol/water Auto-ignition temperature : Not available.Decomposition temperature : Not applicable.Viscosity of Liquid, CST @ 25 o C : Not available.Explosive properties : Not available.Oxidizing properties : Not available.

9.2 Other information : Experimental material. Certificate of Analysis was not generated.

10.1 Reactivity : Reactivity does not occur.

10.2 Chemical stability : Stable under normal conditions.

10.3 Possibility of hazardous reactions : Hazardous polymerization will not occur.

10.4 Conditions to avoid : Open flames and sources of ignition. Incompatible products.

10.5 Incompatible materials : Strong oxidizing agents.

10.6 Hazardous decomposition products : Burning can produce oxides of carbon.

11.1 Information on toxicological effects

11.1.2 Mixture : There is no data available on the product itself.

11.1.2.1 : Relevant effects:

Component CarcinogenicityInformation on components CAS Registry Carcinogenicity DatabasesConstituents/Ingredients CAS No. OSHA-Z NTP IARC ACGIH EPAButan-2-one 78-93-3 - - - - Group DButan-1-ol 71-36-3 - - - - -Ethyl hydroxide 64-17-5 - - - Group A4 -Propan-2-ol 67-63-0 - - Group 3 Group A4 -Methylbenzene 108-88-3 - - Group 3 Group A4 Group DXylol 1330-20-7 - - Group 3 Group A4 Group D

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION


14/20


Classifications :

ACGIH : Group A4: Not classifiable as a human carcinogen.

EPA : Group D: Not classifiable as to Human Carcinogenicity.

IARC : Group 3: Not classifiable as to its carcinogenicity to humans.

(b) IrritationInhalation : May cause irritation to the nose, throat, and lungs. High

vapor concentrations may cause unconsciousness or other signs of central nervous system depression.

Skin contact : Frequent or prolonged contact may irritate the skin andcause skin rash (dermatitis). May cause skin sensitization,

an allergic reaction which becomes evident on re-exposureto this material.

Eye contact : Severely irritating. If not removed promptly will injure eyetissue, which may result in permanent damage.

Ingestion : May cause irritation of the digestive tract and diarrhea.

(c) Corrosivity : Severely irritating to eyes. Repeated exposure may cause skindryness or cracking.

(d) Sensitization : May cause skin sensitization and or respiratory system irritationdue to extended exposure of the preparation above stated occu-

pational exposure limits.

(e) Single dose toxicity : No data available.

(f) Repeated dose toxicity : No data available.

(g) Carcinogenicity : No known significant effects or critical hazards.

(h) Mutagenicity : No information but adverse effects unlikely.

(i) Toxicity for reproduction : No known significant effects or critical hazards.

11.1.2.2 CMR effects : No known significant effects or critical hazards.(carcinogenic, mutagenic or toxic for reproduction)

11.2 Potential adverse health effects : Small amounts of this liquid may be drawn into the lungs byeither swallowing or vomiting. This may cause severe anddelayed health effects such as inflammation of the lungs (

pulmonary edema) and infection of the bronchi(broncho-


15/20


pneumonia). Ingestion may cause irritation to the digestivetract or diarrhea.

11.3 Potential chronic health effects : There is no evidence that exposure to Butan-2-one alone

causes progressive or irreversible neurotoxic effects.However, simultaneous over-exposure to Butan-2-one andn-Hexane can potentiate the known irreversible neurotoxiceffects of n-Hexane. There is no reported human evidencethat these neurotoxic effects occur when exposure to bothchemicals is maintained below established regulatory limits.

11.4 Other information : The mixture is not likely to be carcinogen in humans.

Note: Ecological testing has not been done on the product. Ecotoxicological information on components of this product is presented below.

12.1 Toxicity :Butan-2-one [CAS#: 78-93-3]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC 50 96 hour (s) Pimephales promelas 3220Acute Daphnia toxicity EC 50 48 hour (s) Daphnia magna > 520Acute algae toxicity EC3 7 days Scenedesmus quadricauda 4300

Butan-1-ol [CAS#: 71-36-3]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC 50 96 hour (s) Pimephales promelas < 1630Acute Daphnia toxicity EC 50 48 hour (s) Daphnia magna 1983Acute algae toxicity EC 50 96 hour (s) Scenedesmus subspicatus > 500

Ethyl hydroxide [CAS#: 64-17-5]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC 50 96 hour (s) Alburnus alburnus 10000 - 11500Acute Daphnia toxicity LC 50 48 hour (s) Daphnia magna 9268 - 14221Acute algae toxicity EC 50 Not specified Chlorella pyrenoidosa 9310

Propan-2-ol [CAS#: 67-63-0]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC 50 96 hour (s) Pimephales promelas 9640Acute Daphnia toxicity EC 50 48 hour (s) Daphnia magna 13299Acute algae toxicity EC 50 96 hour (s) Scenedesmus subspicatus > 1000

12. ECOLOGICAL INFORMATION


16/20


Methylbenzene [CAS#: 108-88-3]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC 50 96 hour (s) Pimephales promelas 28Acute Daphnia toxicity EC 50 48 hour (s) Daphnia magna 11.5Acute algae toxicity EC 50 48 hour (s) Scenedesmus subspicatus 125 - 160

Xylol [CAS #: 1330-20-7]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC 50 96 hour (s) Cyprinus carpio > 780Acute invertebrate toxicity LC 50 48 hour (s) Palaemonetes pugio 0.85Acute algae toxicity Mortality Unknown Scenedesmus quadricauda > 200

12.2 Persistence and degradability : No data available for this product.

(Biochemical Oxygen Demand BOD values)Substance name Quantity Degradation rate (%) Incubation time Evaluation (inoculum)Butan-2-one Unknown 83 5 days SewageButan-1-ol Unknown 66 5 days Sewage sludgeEthyl hydroxide 10 mg/l 74 5 days Filtered sewage seedPropan-2-ol 10 mg/l 78 * 20 days Filtered sewage seedMethylbenzene Unknown Completely Short duration Sewage seedXylol Isomers 72 20 days Activated sewage

* Theoretical Oxygen Demand (ThOD) value.

12.3 Bioaccumulative potential : No data available for this product.(BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log K ow) estimateSubstance name Estimated BCF log K ow RemarksButan-2-one 3 0.29 Low bioaccumulationButan-1-ol 3 0.88 Low bioaccumulationEthyl hydroxide 3 -0.31 Low bioaccumulationPropan-2-ol 3 0.05 Low bioaccumulationMethylbenzene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulationXylol 6 23.4 3.2 Low bioaccumulation

12.4 Mobility in soil : No data available for this product.

K oc The soil absorption coefficientSubstance name K oc value Remarks (soil mobility)Butan-2-one 29 Very high mobilityButan-1-ol 72 High mobilityEthyl hydroxide 1 Very high mobilityPropan-2-ol 25 Very high mobilityMethylbenzene variable High to moderate mobilityXylol 39 365 for individual isomers Very high to moderate mobility


17/20


12.5 Results of PBT and vPvB assessment PBT : No data available.vPvB : No data available.

12.6 Other adverse effects : No known significant effects or critical hazards.

13.1 Waste treatment methods Product

Methods of disposal : The generation of waste should be avoided or minimizedwhenever possible. Empty containers or liners may retainsome product residues. This material and its container must

be disposed of in a safe way. Waste product residue should not be disposed of via the foul sewer. Consult an expert on the dis-

posal of recovered and surplus material. Incinerate, or recover by distillation. Ensure disposal is in compliance with currentgovernment requirements and ensure conformity with localauthority regulations.

Packaging wasteMethods of disposal : The generation of waste should be avoided or minimized

whenever possible. Waste packaging should be recycled,or dispose of according to appropriate local and nationalrequirements.

NOTE : The use of this product should at all times comply with the

requirements of environmental protection and waste disposallegislations/statutes and any local authority requirements.

Special precautions : This material and its container must be disposed of according tolocal authority regulations. Empty containers or packaging maycontain some product residue. Avoid dispersal of spill materialand runoff to come in contact with soil, waterways, drains andsewers.

TDG ADN/ADNR IMDG ICAO-TI/IATA-DGR 14.1 UN No. 1210 1210 1210 121014.2 Proper Shipping

NamePrinting Ink RelatedMaterial

Printing Ink RelatedMaterial

Printing Ink Related Material

Printing Ink RelatedMaterial

14.3 Transport hazardclass 3 3 3 314.4 Classification code

F1 F1 F1 F114.5 Packing group II II II II

13. DISPOSAL CONSIDERATIONS

14. TRANSPORTATION INFORMATION


18/20

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 18 of 20Product No: FCSB No. 3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/07/2012

TDG ADN/ADNR IMDG ICAO-TI/IATA-DGR 14.6 Hazard label

14.7 Environmentalhazard No No

Marine pollutant: No No

14.8 Special provision(s)- - - -

Additional Information Hazard identificationnumber

33

Ltd. QtyLQ 5

Excpt. QtyE2

PackagingP001, PP1, MP19

Portable Tanks andBulk Cont.T4; TP1, TP8

-

-

-

-

-

Ltd. QtyLQ6

Excpt. Qty.E2

-

-

-

-

Emergencyschedules (EmS)

FireF-E

SpillageS-D

Ltd. Qty5l

Excpt. QtyE2

-

-

-

Passenger and CargoAircraftQuantity limitation:

1.0L

Packing instructions:Y341

353 5.0L

Cargo Aircraft onlyQuantity limitation:

60.0 L

Packaging instruction:364

-

-

14.9 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.

15.1 Regulatory Information

WHMIS Classification : This product has been classified in accordance with the hazardcriteria of the Controlled Products Regulations (CPR) and the

(M)SDS contains all information required by CPR.

Canadian DSL/NDSL Inventory Status : The components of this mixture are listed on the DSL inventory.

Canadian Environmental Control Act : The Methylbenzene, and Xylol components of this mixture are(CEPA) Priorities Substances List on the CEPA Priorities Substances List.

WHMIS Regulations : This mixture is categorized as a Controlled Product, HazardClasses B2 and D2B, as per the Controlled Product Regulations.

15. REGULATORY INFORMATION


19/20


Chemical Weapons Convention ListSchedule I Chemicals

Chemical Weapons Convention ListSchedule II Chemicals

Chemical Weapons Convention ListSchedule III Chemicals

Not listed Not listed Not listed

NOTE : The information contained within this Safety Data Sheet is for teaching purposes only. The mixture is fictitious.

16.1 Indication of changesDate of previous issue : No previous validation. Revisions : New (M)SDS.

Nature of version : Conforms to CPR-WHMIS and GHS Standards.Version : 1.00Date of issue : 07 July, 2012.

Prepared by : Theodore M. Amet, Regulatory Research Analyst

16.2 Abbreviations and acronymsACGIH: American Conference of Governmental Industrial Hygienists; ADR: Accord europen sur le transport des merchandises dangereuses par Route (European Agreementconcerning the International Carriage of Dangerous Goods by Road);CAS#: Chemical Abstract Service Registry Number;CEPA: Canadian Environmental Protection Act;EINECS: European Inventory of Existing Commercial chemicals Substances;EHS: Extremely Hazardous Substances;EPA: United States Environmental Protection Agency;

GHS: Globally Harmonized System of Classification and Labelling of Chemicals;IARC: International Agency for Research on Cancer;IATA: International Air Transport Association;IATA-DGR: Dangerous Goods Regulations by the International Air Transport Association (IATA);ICAO: International Civil Aviation Organization;ICAO-TI: Technical Instructions by the International Civil Aviation Organization (ICAO);IMDG: International Maritime Code for Dangerous Goods;

NTP: National Toxicology Program;OSHA: Occupational Safety and Health Administration;RID: Rglement international concernant le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous goods by Rail);

STEL: Short Term Exposure Limit;TDG: Transport of Dangerous GoodsTLV: Threshold Limit Value;TWA: Time Weighted Average.

16.3 Key literature references : CAMEO Chemicals;and sources of data ESIS (Existing chemical Substances Information System);

TOXNET;Information from technical literature;Internet research;Substance Material Safety Data Sheets.

16. OTHER INFORMATION


20/20


DISCLAIMER

This document was compiled for teaching purposes. Information on this sheet is based on data gathered frommany sources. No warranty is expressed or implied as to the accuracy, reliability or completeness of data

obtained from various chemical, health, toxicological, and environmental databases. Responsibility for theaccuracy and completeness of information contained herein rests with users who must satisfy themselves thatthe data is appropriate for their teaching needs. It is always a good practice to consult a sectional expert whenwriting sections of the safety data sheets to clarify and simplify technical matters. The author assumes noresponsibility for injury, damage or loss resulting from the use of this material.

END OF SAMPLE (MATERIAL) SAFETY DATA SHEET

amet,tm sample canada cpr-whmis ghs sds

Documents