Alstom’s Oxy-Firing Technology and Demonstration: Near, Medium and Long

Term CO2 Solutions

1st International Oxy-Combustion Conference

Cottbus, GermanySeptember 08, 2009

John L. Marion

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 2ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

The Alstom Group: a worldwide leader in its activities

Coal, Gas, Hydro, Nuclear, Wind = Full Power Systems Portfolio

•Total orders 2008: € 25 Billion

N°1 in air quality control systems

N°1 in services for electric utilities

N°1 in integrated power plants

N°1 in hydro power

N°1 in conventional nuclear power island

Recent acquisition of wind power

Power

Transport

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 3ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Source: Vattenfall

Pre-combustion(New only)

Power Plant with CO2 capture

Solutions developed by Alstom

CCS must be also applied to the installed base

Post-combustion Oxy-combustion(New + retrofit) (New + retrofit)

CO2 Capture Solutions within Alstom

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 4ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

CO2 Capture Solutions

Alstom Actively Developing Carbon Capture Technologies for More Than a Decade

Oxy Combustion- Oxy Pulverized Coal - Oxy Circulating Fluid Bed - Chemical Looping

Post-combustion Oxy-combustion(New + retrofit) (New + retrofit)

Post Combustion Scrubbing

- Chilled Ammonia

- Advanced Amine

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 5ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-Combustion ProcessAdvantages• Reliability: main components exist,

only adaptation to power gen and scale-up

• All types of boilers / firing systems adaptable to Oxy covering a complete fuel range

• Rapid scale-up to large size (1,000 MWe range) possible after large demos.

• Retrofit in Oxy feasible• High efficiency and competitiveness

of supercritical/ultra-supercritical cycles and large unit size will be compatible and key benefits

• Large community involved in development, contributing to reaching solid consensus

Oxy-combustion : a solid option for CO2 capture

Source: Alstom3D View of an Oxy-PC (800MWe gross)

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 6ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Large Pilot PlantsLarge Pilot Plants

DemonstrationDemonstration

Full-ScaleFull-Scale2008

2014-15

< 2020

Alstom Oxy Combustion Technology Development Steps

Lab ScaleLab Scale

2000

Scale – Up

<1 MWth

15- 30 MWth

150- 300 MWe

600-1100 MWe

*Startup years

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 7ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Large Pilot PlantsLarge Pilot Plants

DemonstrationDemonstration

Full-ScaleFull-Scale2008

2014-15

< 2020

Alstom Oxy Combustion Technology Development Steps

Lab ScaleLab Scale

2000

Scale – Up

<1 MWth

15- 30 MWth

150- 300 MWe

600-1100 MWe

Reference Design Studies

Modeling & Tool Dev.

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 8ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

800 MW Oxy-PC Reference Plant

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 9ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-PC Power Plant - Optimized Integration with ASU, Boiler, APC, FGC, and GPU

Air Separation

Unit

Boiler

Pulverizer

coal

oxygen

CO2

Gas Processing

UnitGas

CondenserFGD -NID

Fabric Filter

airnitrogen

Gas Preheater

secondary recircprimary recirc

Pipeline100%57%

43%

21%

36%

Air Separation

Unit

Boiler

Pulverizer

coal

oxygen

CO2

Gas Processing

UnitGas

CondenserFGD -NID

Fabric Filter

airnitrogen

Gas Preheater

secondary recircprimary recirc

Pipeline

Air Separation

Unit

Boiler

Pulverizer

coal

oxygen

CO2

Gas Processing

UnitGas

CondenserFGD -NID

Fabric Filter

airnitrogen

Gas Preheater

secondary recircprimary recirc

Pipeline100%57%

43%

21%

36%

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 10ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

2008

2014-15

< 2020

Alstom Oxy Combustion Technology Development Steps

Lab ScaleLab Scale

2000

Scale – Up

<1 MWth

Since 1998 and up to 500 kWth Oxy Coal Testing• Alstom Labs• U. Stuttgart• U. Cottbus • U. Hamburg-Harburg • U. Dresden• ENCAP (EC Co-funded Project)• ADECOS I & II (GER Co-funded Project)• OxyBurner (EC Co-funded Project)• OxyCorr (EC Co-funded Project)

Underfire Gas

O2 CO2 N2AirGrid Plate

Weigh Scale

Cooling CoilFilter

Cyclone

ThermocouplePort

Rotary Air Lock

Heating Element

Insulation

Exhaust

FreeboardThermocouple

Bed Thermocouple

ThermocouplePort

Fuel/Sorbent Screw Feeder

Reactant Gas Preheater

Bed Drain

Gas Analysis/DataAcquisition Systems: CO2, CO, O2, NOx, N2O, SO2, THC

Pressure Sensor

Pressure Sensor

PressureSensor

Pressure Sensor

Observation Port

Underfire Gas

O2 CO2 N2AirGrid Plate

Weigh Scale

Cooling CoilFilter

Cyclone

ThermocouplePort

Rotary Air Lock

Heating Element

Insulation

Exhaust

FreeboardThermocouple

Bed Thermocouple

ThermocouplePort

Fuel/Sorbent Screw Feeder

Reactant Gas Preheater

Bed Drain

Gas Analysis/DataAcquisition Systems: CO2, CO, O2, NOx, N2O, SO2, THC

Pressure Sensor

Pressure Sensor

PressureSensor

Pressure Sensor

Observation Port

combustion materials

Gas cleaning and condensers

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 11ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Simulation and Modeling for Oxy-Fired Power Plants

Case 2

Temp [K]

Case 1

15 MWt BSF Oxy Simulations

OXYAIR

850 MW Boiler Simulations

• CFD modeling submodel improvements:

– soot, radiation, chemistry

• Validation in small combustion tests

• Application to pilot tests and further validation

• Applied to scale up for full scale reference designs and demonstration projects

• System modeling – ASPEN, ANSYS APECS

• Boiler performance modeling – Alstom ALPRO

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 12ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Large Pilot PlantsLarge Pilot Plants

2008 to present

Alstom Oxy Combustion Technology Development Steps

Scale – Up

15- 30 MWth

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 13ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-CombustionPilot - TOTAL Lacq – 30 MWth

Main features

• Retrofit to Oxy of a 30 MWth existing boiler (natural gas)

• Located in SW of France

• Oxyfuel process to start mid 2009

• Approx 150,000 t CO2 to be stored on a 2 year-period in a depleted gas field

• ALSTOM scope : Boiler retrofit30 MWt retrofitted Boiler – Lacq, France

First CCS with pipeline transportation & storage

Source: Total

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 14ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Project Objectives:• Alstom Boiler Simulation Facility –Windsor, CT, USA

• Tangentially Fired Oxy Demonstration

• Determine boiler design and performance impacts for oxy-combustion

• Evaluate and improve engineering and simulation tools for oxy-combustion

• Design and develop innovative oxy-firing system for T-fired boilers

Schedule• October 2008 to September 2010 • 24 Months

Oxy-CombustionPilot – Alstom BSF – 15 MWth

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 15ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Ten Utility Members:AmerenATCODominion EnergyGreat River EnergyLuminant (TXU)LCRA and Austin EnergyMidWest GenerationNB Power OG&EVattenfall

Project Team:• Alstom – Power Plant Laboratories• Alstom – New & Retrofit Boiler Business• DOE NETL • ICCI• Utility Advisory Group

Oxy-CombustionPilot – Alstom BSF – 15 MWth

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 16ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Alstom Boiler Simulation Facility

Oxy T-Fired 15 MWt Pilot TestingTest Campaigns:

• BSF Campaign 1 - Subbituminous Coal (PRB) - Baseline Air-firing and Oxy-firing- Evaluate Broad Range of Oxy Process and Firing System Design Options

• BSF Campaign 2- Bituminous Coal - Optimize Selected Design

• BSF Campaign 3- High Sulfur Illinois Coal- Gas Recycle Before and After FGD

• BSF Campaign 4 - US Lignite- German Lignite for Link With 30 MWt Schwarze Pumpe Tests

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 17ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

O x yg en S to rag e and S upp ly S ys tem

New F ab ric F ilter and NID S c rub b er

A ir Pro duc ts G as Purific atio n PDU

New G as R ec yc le F an

New G as B o o s t F an

E x is ting S c rub ber

G as Heat E xc hanger

E x is ting G as -G as Preheater

B S F T es t Furnac e and C onvec tio n Pas s

Major New Equipment Oxygen Supply and Injection System Gas Recirculation SystemsFabric Filter for Particulate Removal Dry SO2 Scrubbing System (NID)Instrumentation and Controls

General Design Operate Both Air- and Oxy-fired5 Different Operating ConfigurationsControl of Oxygen Injection

- Premixed or Local Injection- Variable Concentrations- Multiple Locations, etc.

15 MWt Boiler Simulation Facility Modifications

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 18ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Boiler started Sept 08 - PAC Dec 08 – Testing on-going

Boiler

FGC CO2 Compression

Air Separation Unit

CO2 Purification

Control Room

FGD

ESP

(source: Vattenfall)

Oxy-PC pilot demonstrationSchwarze Pumpe – 30 MWth

Main features

• Boiler 30 MWth 40t/h

• Coal 5,2 t/h lignite

• Cycle 25b/330°C

• Oxygen 215 t/day

• CO2 11 t/hr

• Alstom scope:Oxy-boiler + ESP

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 19ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Results from Operation – Oxy Firing

• Burner operates in pre-mixed and „expert“ modes stable and reliable

• Limits for emissions easily met for oxy mode of operation

• Good burnout with low unburnt carbon in fly ash and slag

• Testing continues

Oxy-Firing (pre-mixed mode)

Air-Firing

Total Operation 3000 hAir Operation 1500 hOxyfuel Operation 1500 h • Burner Pre-mixed Mode 1000 h• Burner Expert Mode 500 h

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 20ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Scale-up challenge from 2008 to 2020

2X800 MWe

10 MWe

Source: Vattenfall

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 21ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Main features• Existing plant 250 MWe gross• Location: 100 km SE of Berlin• New oxy-boiler 815t/h• SH/RH 535/540°C, 165/40b• Lignite fuel• Feasibility study recently

completed with Alstom participation

EU flagship program candidate

(source: Vattenfall)

Oxy-PC Jänschwalde - 250 MWe

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 22ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Large Pilot PlantsLarge Pilot Plants

DemonstrationDemonstration

Full-ScaleFull-Scale2008

2014-15

< 2020

Alstom Oxy Combustion Technology Development Steps

Lab ScaleLab Scale

2000

Scale – Up

<1 MWth

15- 30 MWth

150- 300 MWe

600-1100 MWe

*Startup years

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 23ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-Combustion Process - Main Challenges

• Development of Oxy-Fired Boilers- Firing system - Air In-Leakage- Heat Transfer- Pollutant Formation- Ash Deposition - Fireside Corrosion- Reduced FGR

- Gas Cleanup & Condenser selection

- Development and Scale-Up of GPU

- Cost & Power reduction of ASU

- Systems Integration and Optimization (Cost minimization)

- Demonstrations

Oxy-combustion : a solid option for CO2 capture

Source: Alstom3D View of an Oxy-PC (800MWe gross)

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 24ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-Combustion Roadmap (Innovative Future Paths)

SeparatedOverfire Air

Main BurnerZone

SeparatedOverfire Air

Main BurnerZone

Reducer Oxidizer

CaSO 4

N2

Air

To Steam Cycle

CO 2

CoalCaCO 3Steam

CaS Ash, CaSO 4to Disposal

Reducer Oxidizer

CaSO 4

N2

Air

To Steam Cycle

CO 2

CoalCaCO 3Steam

CaS Ash, CaSO 4to Disposal

Fuel

FBHEW/ Bypass

Combustor

100% Oxy-FiredUsing FBHE

100% Oxy-FiredUsing FBHE

O2

FDA

Fuel

FBHEW/ Bypass

Combustor

100% Oxy-FiredUsing FBHE

100% Oxy-FiredUsing FBHE

O2

FDAFDA

Performance

Cost

TimeDemo’s &

PilotsReduced FGR

Oxy-PlantsCommercial

Advanced Oxygen

Production

Chemical Looping

Commercial

Air – OxyCommercial

[ Retrofit, CO2 Ready, New ]

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 25ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy Combustion Technology Paths

AIR

Fuel

COMBUSTOR

BACKPASS

O2

N2

ASU

VENT

GPS

H2O

AIR

Fuel

BACKPASS

O2

N2

ASU

CO2

VENT

GPS

COMBUSTOR

H2O

Pulverized Coal Firing

Circulating Fluid Bed Combustion

External Heat Exchanger

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 26ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Future potential to reduce boiler size Oxy-Fired CFB Boilers

Panels

SteamDrum

Backpass

Combustor

Cyclone &Sealpot

Air Heater

Air heaterReduced Size

CombustorPlan Area

Reduced SizeFBHE

(Added orIncreased)

SteamDrum

Cyclone &Sealpot

BackpassReduced

SizePanels

AIR-FIRED CFB BOILER OXY-FIRED CFB BOILER

350 MWe Boiler – Low and High Furnace O2 Cases

Dual Air- and Oxy-Fired CFB High Furnace O2 Oxy-Fired CFB

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 27ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

350 MW Oxy-CFB Reference Plant

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 28ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-CFB

3 MWt pilot CFBWindsor, CT, USA

• Over 300 hours pilot operations completed by Alstom with oxy-firing

• Furnace oxygen concentrations ranging from 21% (synthetic air) to >70%

• Potential for reduced recycle FGR and resultant smaller boiler & APC

• Market segmentation as with air-fired CFB’s (low quality fuels)

• Ready for demonstration

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 29ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Oxy-combustion: Chemical Looping Combustion (CLC)

CLC features• 100% CO2 Capture • No Air Separation Unit

• Lowest Cost CO2 Capture • High Net Plant Efficiency

Depleted air

carrier with O2

Cold Fuel reactor

O2O2

Coal

Combustion products

(CO2+H2O) steam

Hot

carrier without

O2

Air reactor

O2O2

Air (O2+N2)

MeO or CaSO4

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 30ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

ÉCLAIR: MeOx prototype development

32m

23m9m

4m

6m

17m

TECHN SCHEIUN VERS TÄTI IDARMSTADT

Emission Free Chemical Looping Coal Combustion Process

9th March 2009: At the University of Technology of Darmstadt, the foundation-stone was laid for the 1 MW metal oxidechemical looping pilot plant- EU RFCS project

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 31ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

AshCoolers (6)

SolidsHeater

SealpotControlValves (2)

2-StageCyclones (2)

SprayCoolers &Filters (5)

ReducerOxidizer

ProductGasBurner

Pilot Facility – Phase I/II/III programs completed:• Tested individual loops and processes• 3-year test program successfully completed• All chemistry/rates verified• Comprehensive solids transport testing

Prototype Facility – Phase IV program• Oct. 2008 – 2011• 3 MWt [1,000 lb/h coal flow]• 1st integrated operation• Auto thermal operation• Engineering/operating information

for industrial demonstration65 kWt

3 MWt

Alstom Pilot in USA

CaS Chemical Looping Development Status

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 32ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Large Pilot PlantsLarge Pilot Plants

DemonstrationDemonstration

Full-ScaleFull-Scale2008

2014-15

< 2020

Summary - Alstom Oxy-Combustion Technology Development Steps

Lab ScaleLab Scale

2000

Scale – Up

<1 MWth

15- 30 MWth

150- 300 MWe

600-1100 MWe

READY FOR THE NEXT STEP

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 33ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Summary - Alstom activity on demonstrations

We Energies Pleasant Prairie

USA - 5 MWthChilled Ammonia - Coal

Total LacqFrance - 30 MWth

Oxy - Gas

EoN KarlshamnSweden - 5 MWthChilled Ammonia -

Fuel/Gas

Vattenfall Jänschwalde

Germany - 250 MWe Oxy - Lignite

Dow Chemical Co. USA, West Virginia Advanced Amines

AEP MountaineerUSA - 30 MWth

Chilled Ammonia - Coal

Study / EngineeringRunning / Commissioning In construction

PGE BelchatowPoland - 20 MWth /

250MWe Adv. Amines - Lignite

Pre-selected for European Energy Programme for Recovery funding

Statoil MongstadNorway - 40 MWth

Chilled Ammonia - Gas

Vattenfall Schwarze Pumpe

Germany - 30 MWthOxy - Lignite

TransaltaCanada - >200 MWe

Chilled Ammonia - Coal

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 34ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

• Major large oxy pilot projects underway; Alstom active in Schwarze Pumpe, Lacq,and own labs

• These pilot programs are providing very positive feedback and, in particular, represent a strong foundation for design of next-step demonstration

• Alstom is ready for large-scale demonstration of oxy-fired PC and CFB power plants

Summary

Boiler

ESPASU

Switchgearbuilding

FGD

Flue gas-Condenser

CO2-Plant

Alstom’s Oxy-Firing Technology and Demonstration – J. MarionIEA 1st Int. Oxy-Combustion Conference, Cottbus, Germany, 7-11 Sept. 2009 - P 35ALSTOM © 2009 We reserve all rights in this document and in the information contained therein. Reproduction, use or disclosure to third parties without express authority is strictly forbidden.

Alstom – The Clean Power Specialist

Today we provide the cleanest air solutions For New PlantsFor the Installed Base

www.alstom.com