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Interim LADCO Modeling of EPA’s 2011ed platform Alexander Cohan Photochemical Modeler

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Page 1: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Interim LADCO Modeling of

EPA’s 2011ed platform

Alexander Cohan

Photochemical Modeler

Page 2: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Acknowledgements

• EPA OAQPS

– Alison Eyth

– Kirk Baker

– Norm Possiel

– Chris Misenis

• IL EPA

– Scott Leopold

Page 3: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Domain

Page 4: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Technical Details

• Meteorology: – EPA 2011 version II

• Emissions: – EPA 2011 version I

– Supplemental Canada and Mexico emissions from 2008 NEI

• Model: – CAMx V6.00

• CB5 with CF aero

• YSU vertical diffusivity with minimum urban KV

• Modeling Period: – June 17 to September 26, 2011 with an additional 15

days of spinup

Page 5: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

O3 (PPM)

Episode: July 18 – July 23, 2011

36 KM Domain 12 KM Domain

Page 6: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

NOX (PPM)

Episode: July 18 – July 23, 2011

36 KM Domain 12 KM Domain

Page 7: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Ozone Evaluation

with AQS data

Page 8: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Bias & Error: 60 PPB O3 Threshold

Page 9: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

8HR O3 at 60 PPB Threshold

Page 10: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

12KM Domain 8HR O3 Statistics

Page 11: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

LADCO States 8HR O3 Statistics

Page 12: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Atlanta, GA

Monitor ID 131210055

Page 13: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Chicago, IL

Monitor ID 170310037

Page 14: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

St. Louis, MO

Monitor ID 291831002

Page 15: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Harford, MD

Monitor ID 240251001

Page 16: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

NOX Evaluation

with AQS data

Page 17: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Bias & Error: 60 PPB NOX Threshold

Page 18: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

1HR NOX at 60 PPB Threshold

Page 19: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Chicago, IL

Monitor ID 170310063

Page 20: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Summary

• Ozone error is generally within 35% • Ozone bias is generally within 15%

– Some under-prediction in the East and Midwestern

• NOX performance could be improved • LADCO is continuing to evaluate model

performance

** Modeling Platform in Development Stage ** ** PRELIMINARY RESULTS **

Page 21: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Model Attainment Test Software

(MATS) Results

Page 22: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

2018 Emissions

• Tier III proposed rule

– MOVES-NPRM version (not MOVES 2014)

• CAIR

– IPM 2018

• State/Federal “on-the-books” controls

Page 23: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

2011 MATS O3 Design Values

Page 24: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

2018 MATS O3 Design Values

** PRELIMINARY RESULTS **

Page 25: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

2011 - 2018 MATS O3 Design Values

** PRELIMINARY RESULTS **

Page 26: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Ozone Source Apportionment

(OSAT)

36KM CAMx modeling without minimum kv fix

Page 27: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Source Apportionment Regions

Page 28: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Atlanta, GA

Ozone apportionment with a 65 PPB threshold

** PRELIMINARY RESULTS **

Page 29: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Sheboygan, WI

Ozone apportionment with a 65 PPB threshold

** PRELIMINARY RESULTS **

Page 30: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

St. Louis, MO

Ozone apportionment with a 65 PPB threshold

** PRELIMINARY RESULTS **

Page 31: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Harford, MD

Ozone apportionment with a 65 PPB threshold

** PRELIMINARY RESULTS **

Page 32: Alexander Cohan Photochemical Modeler · Alexander Cohan Photochemical Modeler . Acknowledgements •EPA OAQPS –Alison Eyth –Kirk Baker –Norm Possiel –Chris Misenis •IL

Future Work

• CAMx V6.10 released 4/4/14 – Re-emissions model (not PiG compatible)

– CB6r2 Chemistry

– Improved PiG algorithm

• ERTAC EGU emissions – Compare IPM and ERTAC

– MATS (Mercury and Air Toxic Standards) sensitivity runs

• MEGAN biogenic emissions

• OSAT with more regions

• PM2.5 2011 and 2018 annual modeling – PSAT