advices to handle chemicals safely and the rules in …some chemicals can be used without an...

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H25年度 RCNP 安全衛生講習会 化学薬品編 / Chemicals Advices to handle chemicals safely and the Rules in RCNP Speaker :Y. YASUDA contact: R312 / #8913 / yuusuke@rcnp

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Page 1: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

H25年度 RCNP 安全衛生講習会

化学薬品編 / Chemicals

Advices to handle chemicals safely

and

the Rules in RCNP

Speaker :Y. YASUDA

contact: R312 / #8913 / yuusuke@rcnp

Page 2: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

化学薬品編 目次Chemicals Contents

1. 担当スタッフ

2. RCNP薬品ルールの重要事項

3. ルールの新しい点

4. 薬品の借り出し/保管/返却

5. 一般的な取扱い注意

(主に初心者向け)

1. Introduction of technical staff

2. Highlights of the Chemicals Rule in

RCNP

3. Something New in the Rules

4. How to Receive / Keep / Return

Chemicals in RCNP

5. Advices in General

(for beginners)

Advices to handle chemicals safely

and

the rules in RCNP

Page 3: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

Working hour : 8:30-17:15 on Mon-Fri

Technical staff on the duty of Chemicals Management

S. ANO

R308 #8911

ano@rcnp

buy/dispose of

chemicals

H.P. YOSHIDA

R308 #8911

hidetomo@rcnp

service for experiment

users

Y. YASUDA

R312 #8913

yuusuke@rcnp

management/

service for accelerator

group

Page 4: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

RCNP薬品ルールの重要事項Highlights of the Chemicals Rule in RCNP

薬品の保管

保管・管理は担当者が行う

薬品庫で保管

OCCSに登録して管理。パーコード貼付

持ち込み、持ち出しは原則禁止

薬品購入

購入したら薬品担当に保管管理を依頼する、

または購入を依頼すること

購入前にまず相談を

薬品使用

担当者に依頼してください

薬品廃棄

どんな薬品も流しに捨ててはいけません

器具の洗浄に使用した溶剤・水も回収すること

全て回収して薬品担当者に渡すこと

Chemicals control

managed by technical staff

all chemicals are kept in chemicals safes

managed by a system of Osaka Univ.

Barcode is a management tag.

You can NOT bring chemicals to RCNP and out from RCNP.

Buying Chemicals

Ask us to buy and keep chemicals.

Contact us when you need.

All chemical wastes must be collected.

Do NOT throw used chemicals into a sink!

Disposal of Chemicals

Using Chemicals

Ask technical staff

For using almost all chemicals,

you need an application.

Page 5: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

1. エタノールは4か所の薬品庫に配架します。

AVF2Fカウンター開発室、RI棟地下、西実験室、 (東実験室)

なるべくビンは持ち出さず、ペットボトルに必要量を

一部薬品も配架

2. 薬品は使用後元の場所に返却してください

3. 空瓶回収の徹底

薬品庫の場所に回収場所

4. 借り出し中は一時保管庫にてユーザーが管理

借り出し期間は使用期間に対して余裕を見てよい

ご利用は計画的に(夜間・休日にならぬよう)

5. 廃液は廃液ボトルで回収

ルールの新しい点What’s new in the rules ?

4月末完了を目標に整備作業をすすめています

4 Ethanol station will be prepared.

Bring Ethanol by a plastic bottle as

much as you really need.Some chemicals can be used without an application.

Bring back chemicals where they were after using.

Bring back also an empty bottle.

During you have chemicals,

Use a user safe to keep them.

Use “waste bottles” to collect chemical wastes.

Page 6: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

薬品庫 / Chemicals Safes

西実験室 (1F)

West Exp. Hall

中性子実験室 (1F)

Neutron Exp. Hall

RI棟(B1)

Rl bld.

カウンター開発室AVF Counter Dvl. Room

(2F)

• Main Safe

• エタノール etc.

• イソプロパノール/アセトン

• その他 (施錠保管)

• sub safe • エタノール etc.

• sub safe (planning)• エタノール etc.

• safe for users

東実験室East Exp. Hall (1F)

Ethanol etc.

Iso-propanol / Acetone

the others (in locked safe)

Ethanol etc.

Ethanol etc.

Page 7: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

薬品の借り出し/保管/返却How to receive / keep / return chemicals in RCNP

Page 8: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

薬品の借り出しReceive chemicals from us

貸出票の記入 薬品/廃液容器/保管庫鍵受け取り貸出依頼

確認薬品庫で保管 薬品庫に名札

Write an application. Ask us. Receive chemicals, waste bottles,

a key for safe …

Check them.Put a name label on a safe door.Keep them in the safe.

Page 9: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

借り出し中は一時保管庫にてユーザーが保管管理

借り出し期間は使用期間に対して余裕を見てよい

借り出し期間中は保管庫で管理をKeep chemicals in a safe

You have a responsibility for the chemicals you have.

Page 10: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

薬品の返却Return chemicals and wastes to us

薬品/廃液容器/保管庫鍵返却

返却依頼返却物をまとめる

おしまい 確認

廃液ラベル添付

Put a label on a waste bottle. Are you prepared ? Ask us.

Return chemicals, waste bottles,

a key …

We check them.Ojigi

Page 11: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

廃液ボトルにはラベルを貼ってください

内容物、混入物の記入が必要です

廃液回収は使用者の責任です

廃液ボトルの例Examples of a waste bottle

Put a label on a waste bottle.

Contents and contaminations must be given to

the label.

You must collect chemical wastes.

Page 12: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

飲み物の容器に薬品を入れないこと

薬品を移し替えた容器には必ず内容物と責任者氏名を書くこと

時が経てば不明薬品

作業場所での飲食は厳禁

やってはいけないことDo NOT ….

Do NOT eat and drink

where you use chemicals

Write Content on the bottle.Do NOT use a drink bottle.

Bottled liquid with no label will become an unknown chemical.

Page 13: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

社会責任/法令順守

法律を守るのは当たり前

使用量/排出量などの届け出が必要 (PRTR/VOC)

大学だから薬品が使える 使用する責任

安全なくして研究成果なし

利便性

不足なく必要な薬品を提供

リスクマネジメント

必要以上の薬品を持つことは危険を増やす

有害性 / 反応性 / 環境への影響 なるべく低く

薬品管理の必要性Necessity of Chemicals Control

for responsibility for the society

No safe, No Nobel prize.

We have to report how much

chemicals we used.

for usability

We will prepare chemicals you need.

for risk management

Page 14: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

RC NPの状況

他機関からのユーザーが多い

使用頻度、使用量が少ない

借り出し品が返ってこない

現在の取り組み

薬品登録

まず持たない、持つなら 小限

不明薬品を減らす

今後の取り組み

安全な作業環境の確立

安全な作業方法の指導

作業場所の限定

RCNP薬品管理の取り組みWe RCNP Chemicals Control are trying to …

features of RCNP environment

Many users come from other universities.

Small amount of chemicals are used.

Stuff have gone anywhere.

We are doing ...

registration of all chemicals we have.

preparation of minimum amount of

chemicals (We don’t have too much.)

prevention of new unknown

chemicals

We will ...

make safe environment for users.

advise safe usage of chemicals.

limit the place where you can use

chemicals.

Page 15: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

一般的な取扱い注意Advices in General

Page 16: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

危険性・有毒性を知ろう

「化学物質には、なんらかの危険有害性が存在する」

人体への影響 / 混ぜるな危険!

保護具を使用しよう 特に目!

自分も回りも

トラブル時の対応を知る(パニックにならないために)

避難路 /応急処置 /救急/火災など連絡方法

正しい廃棄 一般廃棄物とは異なる

微量でも自然水域、土壌、大気などの環境に放出しない

無理な実験はしない

夜間単独は絶対ダメ / 不安定状態で実験しない / 指導者とのコミュニケーションを

基本的なことFundamentals

from

THE NAVEL TREATY

Strand Magazine

Lean hazards of chemicals

Use protectors. Use glasses for your eyes!

for you and your colleagues

Learn what to do in an emergency.

We need special attention to chemical wastes.

Make a plan of your experiment properly. You must NOT do an experiment alone midnight.

Page 17: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

MSDS(Material Safety Data Sheet)

薬品の性状、取扱いに関する情報(指定化学物質等は提供が義務)

薬品庫に配置

薬品のカタログ

薬品ビンの表示

GHS( Globally Harmonized System of Classification and Labelling of Chemicals、世界統一の危険表示)

危険性・有毒性を知ろうLearn hazards of chemicals

可燃性引火性etc

爆発物etc 高圧ガス 急性毒性呼吸器感作性発がん性etc

急性毒性皮膚刺激性etc

水性環境有毒性

金属腐食性物質etc

支燃性酸化性etc

ExplosiveFlammable OxidisingCompressed

Gas

CorrosiveToxic Health

harzard

Irritant Environmentally

Damaging

From

you can get information about physical data, safety, hazards,

health ….

catalogs of chemicals

label sign IN Japan, Detailed description is only written in Japanese .

Page 18: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

ex. MSDS for アセトン(Acetone)

可燃性引火性etcFlammable

呼吸器感作性発がん性etc

Health

harzard

急性毒性皮膚刺激性etc

Irritant

in an emergency

composition

Flammable

Irritant to eyes

Use it in a draft chamber

Use a mask and gloves

caution

physical and chemical data

Page 19: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

試薬がはねて目にはいる事故が多い 安全メガネを!

隣りで実験をおこなっている人の飛沫が目に飛んできた事故(もらい事故)という事例も多い

保護マスク(有機溶剤使用時)

保護具を使用しようUse protectors

大阪大学安全衛生講習会資料より

Use glasses when you use chemicals.

Use glasses also when you are an observer.

Use protection mask when you use a strong organic solvent.

Page 20: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

アセトンで洗ったフラスコを乾燥機に入れたら爆発、乾燥機の扉が吹き飛んだ。(第4類を加熱)*

冷蔵庫の電気火花でアセトンに引火し冷蔵庫吹き飛んだ。(第4類に電気火花) *

フッ化水素を運搬中にビンが割れて皮膚にかかった。グルコン酸カルシウム(ゼリー?)を塗って応急処置し、受診した。(O大学K学部)

水銀の小粒がはねて口に飛び込み、飲み込んでしまったので、卵白10個分を飲んだら、下痢をしたが事なきを得た。**

事故事例Accidents

*大阪大学安全衛生講習会資料より**「実験を安全に行うために」化学同人編集部

Japanese only. Sorry.

Page 21: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

事故のないよう安全に

薬品管理はみなさんのご理解とご協力が必要です。

後に…

Finally…

Use glasses (also an observer)

A large sleeve can make trouble.

Be safe !

Thank you for your cooperation !

Page 22: Advices to handle chemicals safely and the Rules in …Some chemicals can be used without an application.much as you really need. Bring back chemicals where they were after using

おしまい / END