[acs symposium series] materials for nonlinear optics volume 455 (chemical perspectives) ||...

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ACS SYMPOSIUM SERIES 455 Materials for Nonlinear Optics Chemical Perspectives Seth R. Marder, E DITOR Jet Propulsion Laboratory, California Institute of Technology John E. Sohn, E DITOR AT&T Bell Laboratories Galen D. Stucky, E DITOR University of California, Santa Barbara Developed from a symposium sponsored by the Divisions of Organic Chemistry and Inorganic Chemistry at the 199th National Meeting of the American Chemical Society, Boston, Massachusetts, April 22-27, 1990 American Chemical Society, Washington, DC 1991 Downloaded by EAST CAROLINA UNIV on August 28, 2013 | http://pubs.acs.org Publication Date: March 11, 1991 | doi: 10.1021/bk-1991-0455.fw001 In Materials for Nonlinear Optics; Marder, S., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.

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Page 1: [ACS Symposium Series] Materials for Nonlinear Optics Volume 455 (Chemical Perspectives) || Materials for Nonlinear Optics, Copyright, ACS Symposium Series, Foreword

A C S S Y M P O S I U M S E R I E S 455

Materials for Nonlinear Optics Chemical Perspectives

Seth R. Marder, EDITOR

Jet Propulsion Laboratory, California Institute of Technology

John E. Sohn, EDITOR

AT&T Bell Laboratories

Galen D. Stucky, EDITOR

University of California, Santa Barbara

Developed from a symposium sponsored by the Divisions of Organic Chemistry

and Inorganic Chemistry at the 199th National Meeting

of the American Chemical Society, Boston, Massachusetts, April 22-27, 1990

American Chemical Society, Washington, DC 1991

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In Materials for Nonlinear Optics; Marder, S., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.

Page 2: [ACS Symposium Series] Materials for Nonlinear Optics Volume 455 (Chemical Perspectives) || Materials for Nonlinear Optics, Copyright, ACS Symposium Series, Foreword

Library of Congress Cataloging-in-Publication Data

Materials for nonlinear optics: chemical perspectives / Seth R. Marder, editor, John E. Sohn, editor, Galen D. Stucky, editor.

p. cm.—(ACS symposium series; 455)

"Developed from a symposium sponsored by the Divisions of Organic Chemistry and Inorganic chemistry at the 199th National Meeting of the American Chemical Society, Boston, Massachusetts, April 22—27, 1990."

Includes bibliographical references and indexes.

ISBN 0-8412-1939-7

1. Materials—Optical properties—Congresses. 2. Stereochemistry— Congresses. 3. Nonlinear optics—Congresses.

I. Marder, Seth R. (Seth Richard) II. Sohn, John E., 1952- . III. Stucky, Galen D., 1936- . IV. American Chemical Society. Division of Organic Chemistry. V. American Chemical Society. Division of Inorganic Chemistry. VI. American Chemical Society. Meeting (199th: 1990: Boston, Mass.) VII. Series.

QD473.M29 1991 535.2—dc20 90-25768

CIP

The paper used in this publication meets the minimum requirements of American National Standard for Information Sciences—Permanence of Paper for Printed Library Materials, ANSI Z39.48-1984.

Copyright © 1991

American Chemical Society

All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per-copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, MA 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means—graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter.

The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, spécification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law.

PRINTED IN THE UNITED STATES OF AMERICA

Library 1155 18th St., N.W.

Washington, D £ 20036

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In Materials for Nonlinear Optics; Marder, S., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.

Page 3: [ACS Symposium Series] Materials for Nonlinear Optics Volume 455 (Chemical Perspectives) || Materials for Nonlinear Optics, Copyright, ACS Symposium Series, Foreword

ACS Symposium Series

M. Joan Comstock, Series Editor

1991 ACS Books Advisory Board

V. Dean Adams Tennessee Technological

University

Paul S. Anderson Merck Sharp & Dohme

Research Laboratories

Alexis T. Bell University of California—Berkeley

Malcolm H. Chisholm Indiana University

Natalie Foster Lehigh University

Dennis W. Hess University of California—Berkeley

Mary A. Kaiser E. I. du Pont de Nemours and

Company

Gretchen S. Kohl Dow-Corning Corporation

Michael R. Ladisch Purdue University

Bonnie Lawlor Institute for Scientific Information

John L. Massingill Dow Chemical Company

Robert McGorrin Kraft General Foods

Julius J. Menn Plant Sciences Institute,

U.S. Department of Agriculture

Marshall Phillips Office of Agricultural Biotechnology,

U.S. Department of Agriculture

Daniel M. Quinn University of Iowa

A. Truman Schwartz Macalaster College

Stephen A. Szabo Conoco Inc.

Robert A. Weiss University of Connecticut

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In Materials for Nonlinear Optics; Marder, S., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.

Page 4: [ACS Symposium Series] Materials for Nonlinear Optics Volume 455 (Chemical Perspectives) || Materials for Nonlinear Optics, Copyright, ACS Symposium Series, Foreword

Foreword

i H E A C S SYMPOSIUM SERIES was founded in 1974 to provide a medium for publishing symposia quickly in book form. The format of the Series parallels that of the continuing A D V A N C E S IN CHEMISTRY SERIES except that, in order to save time, the papers are not typeset, but are reproduced as they are submit­ted by the authors in camera-ready form. Papers are reviewed under the supervision of the editors with the assistance of the Advisory Board and are selected to maintain the integrity of the symposia. Both reviews and reports of research are acceptable, because symposia may embrace both types of presentation. However, verbatim reproductions of previously published papers are not accepted.

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In Materials for Nonlinear Optics; Marder, S., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.

Page 5: [ACS Symposium Series] Materials for Nonlinear Optics Volume 455 (Chemical Perspectives) || Materials for Nonlinear Optics, Copyright, ACS Symposium Series, Foreword

We dedicate this book to the memory of Donald Ulrich, a program manager

at the Air Force Office of Scientific Research and a strong advocate and supporter

of the field of nonlinear optics.

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In Materials for Nonlinear Optics; Marder, S., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 1991.