acido hipocloroso (1)

8/18/2019 acido hipocloroso (1)

1/19

pCa Ca0 01 0.1

1.5 0.031622782 0.01

2.5 0.00316228

3 0.0013.5 0.00031623

4 0.00014.5 3.1623E-005

5 0.000015.5 3.1623E-006

6 0.0000016.5 3.1623E-007

7 0.0000001


2/19

ka 3,0*10-8pka= 7,52pKa/2=3,76


3/19

pCa pH (lineal) pH (cua!a"icpH ( cu#ica)0 3.76 3.76 3.761 4.2614 4.2615 4.2615

1.5 4.5088 4.50$ 4.50$2 4.7614 4.7618 4.7618

2.5 5.5228 5.00$5 5.00$6

3 5.2614 5.2626 5.26253.5 5.5088 5.510$ 5.5107

4 5.7614 5.7652 5.76444.5 6.0114 6.0181 6.01576

5 6.2614 6.2733 6.26565.5 6.5114 6.5325 6.8754$5

6 6.7614 6.7$$ 6.72246.5 7.0114 7.078 6.8754

7 7.2614 7.378$ 6.$53$

0 1 2 30

1

2

3

4

5

6

7

8

%!&'ca

pH


4/19

pC pH0 3.76 0 1 6 71 4.2614 1 2 6 7

1.5 4.5088 1.5 2.5 6 72 4.7614 2 3 6 7

2.5 5.00$5 2.5 3.5 6 7

3 5.2626 3 4 6 73.5 5.510$ 3.5 4.5 6 7

4 5.7652 4 5 6 74.5 6.0181 4.5 5.5 6 7

5 6.2733 5 6 6 75.5 6.5325 5.5 7

6 6.7224 6 76.5 6.8754 6.5 7

7 6.$53$ 7 7

cofcie

0.$$5

4 5 6 7 8

e pH (!) pC

pC


5/19

nte de correlación


6/19

pCa p1 Ecua. 7 p1 Ecua. 8 p1 Ecua. $ pCa0 3.76 3.76 3.76 01 3.261$ 3.2615 3.2614 1

1.5 3.014$ 3.0142 3.014 1.52 2.763 2.761$ 2.7614 2

2.5 2.5168 2.5147 2.514 2.5

3 2.2665 2.2626 2.2614 33.5 2.0231 2.0163 2.014 3.5

4 1.7777 1.767 1.761$ 44.5 1.5404 1.5228 1.5228 4.5

5 1.312$ 1.2733 0.2614 55.5 1.107$ 1.0362 1.18 5.5

6 1.00$ 1.00$ 1.0$85 66.5 1.006 1.006 1.123 6.5

7 1.003 1.003 1.2015 7

c+e'ecien"e e c+!!elacin0.$724

00

1

23

4

5

6

7

8

p1


7/19

3.76 6 1 73.261$ 5 1 73.014$ 4.5 1 72.763 4 1 7

2.5168 3.5 1 7

2.2665 3 1 72.0231 2.5 1 71.7777 2 1 71.5404 1.5 1 71.312$ 1 1 7

1.18 1 71.0$85 1 71.123 1 7

1.2015 1 7

p

1 2 3 4 5 6 7 8

%!&-ica e p*1 (!) pCa

pCa


8/19

pH

3.76 3.764.2614 3.261$4.5088 3.014$4.7614 2.763

5.00$5 2.51685.2626 2.26655.510$ 2.02315.7652 1.77776.0181 1.54046.2733 1.312$6.5325 1.186.7224 1.0$856.8754 1.1236.$53$ 1.2015

p

3.5 4 4.50

0.51

1.5

2

2.5

3

3.5

4

%!.-ic

p


9/19

CEECEE0.$77

5 5.5 6 6.5 7 7.5

e p*1 (!) pH

pH


10/19

E CEC


11/19

pCa pH (lineal) pH (cua!a"icpH ( cu#ica)

0 3.76 3.76 3.761 4.2614 4.2615 4.2615

1.5 4.5088 4.50$ 4.76182 4.7614 4.7618 5.00$

2.5 5.5228 5.00$5 5.26263 5.2614 5.2626 5.2626

3.5 5.5088 5.510$ 5.51144 5.7614 5.7652 5.764$

4.5 6.0114 6.0181 6.01725 6.2614 6.2733 6.27

5.5 6.5114 6.5325 6.52146 6.7614 6.7$$ 6.761$

6.5 7.0114 7.078 6.$5$7 7.2614 7.378$ 7.0824


12/19

pCa pH

0 3.76 0.17 1.17 6.17 7.171 4.2614 1.17 2.17 6.17 7.17

1.5 4.5088 1.67 2.67 6.17 7.172 4.7614 2.17 3.17 6.17 7.17

2.5 5.00$5 2.67 3.67 6.17 7.173 5.2626 3.17 4.17 6.17 7.17

3.5 5.510$ 3.67 4.67 6.17 7.174 5.7652 4.17 5.17 6.17 7.17

4.5 6.0181 4.67 5.67 6.17 7.175 6.2733 5.17 6.17 6.17 7.17

5.5 6.5214 5.67 7.176 6.761$ 6.17 7.17

6.5 6.$5$ 6.67 7.177 7.0824 7.17 7.17

7.67 7.17

0 1 2 3 4 5 60

2

4

6

8

pH (!) pCa

C+lu9n H C+lu9n C+lu9n : C+lu9n K C+lu

pCa

pH


13/19

CEECE E CEC0.$$83

8

n


14/19

pCa p1 Ecua. 7 p1 Ecua. 8 p1 Ecua. $ pCa0 3.76 3.76 3.76 0

1 3.2618 3.2615 3.2614 1

1.5 3.015 3.0142 3.014 1.52 2.7601 2.761$ 2.7614 2

2.5 2.7151 2.5147 2.514 2.53 2.266 2.2626 2.2614 3

3.5 2.020$ 2.0163 2.014 3.54 1.7$58 1.767 1.761$ 4

4.5 1.5376 1.5228 1.5228 4.55 1.301 1.2733 0.2614 5

5.5 1.080$ 1.0362 1.18 5.56 0.8827 1.00$ 1.0$85 6

6.5 0.7212 1.006 1.123 6.57 0.6103 1.003 1.2015 7


15/19

p13.76

3.2618

3.0152.7601

2.5142.266

2.020$1.7$581.5376

1.3011.18

1.0$851.123

1.1715

0 1 2 3 4 50

0.5

1

1.5

2

2.5

3

3.5

4

p* (!) pCa 15 ;!a+)

pCa

p


16/19

CECEE E CEC0.$$36

6 7 8


17/19

pH p13.76 3.76

4.2614 3.2618

4.5088 3.015 CEC4.7614 2.7601 0.$6615.00$5 2.51475.2626 2.26265.510$ 2.01635.7652 1.7676.0181 1.52286.2733 1.27336.5214 1.156.761$ 1.0$85

6.$5$ 1.1237.0824 1.1785

3.5 4 4.50

0.5

1

1.5

2

2.5

3

3.5

4

p*1

p


18/19

EE E CEC

5 5.5 6 6.5 7 7.5

(!) pH 15 ;!a+)

pH


19/19

0

acido hipocloroso (1)

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