a series of new mixed-ligand complexes based on 3,6- · a series of new mixed-ligand complexes...
TRANSCRIPT
![Page 1: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/1.jpg)
A series of new mixed-ligand complexes based on 3,6-
bis(imidazol-1-yl)pyridazine: syntheses, structures, and
catalytic activitiesSheng-Bin Zhoua, Xin-Fang Wanga, Ceng-Ceng Dua, Duo-Zhi Wang*a, b, Dianzeng Jiab
aCollege of Chemistry and Chemical Engineering, Xinjiang University, Urumqi Xinjiang, 830046, P. R.
China.
bKey Laboratory of Energy Materials Chemistry, Ministry of Education, Institute of Applied Chemistry,
Xinjiang University, Urumqi Xinjiang, 830046, P. R. China.
The
IR spectra of complex 1
Electronic Supplementary Material (ESI) for CrystEngComm.This journal is © The Royal Society of Chemistry 2017
![Page 2: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/2.jpg)
The IR spectra of complex 2
The IR spectra of complex 3
![Page 3: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/3.jpg)
The IR spectra of complex 4
The IR spectra of complex 5
![Page 4: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/4.jpg)
The IR spectra of complex 6
The IR spectra of complex 7
Fig. S1. The IR spectra of complexes 1-7
![Page 5: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/5.jpg)
![Page 6: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/6.jpg)
Fig. S2. PXRD patterns of 17.
Fig. S3. TGA curves of complexes 17.
![Page 7: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/7.jpg)
Figure S4. Diffuse reflectance UV-VIS-NIR spectra of K–M functions versus energy (eV) of complexes
1−7.
1H NMR spectra for Bibenzene
1H NMR (400 MHz, CDCl3): δ: 7.59 (dd, J = 8.4, 1.6 Hz, 4H), 7.44 (t, J = 10.4Hz, 4H), 7.35 (dd, J = 4.4,
2.0 Hz, 2H).
![Page 8: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/8.jpg)
1H NMR spectra for 4,4′-Dimethylbiphenyl1H NMR (400 MHz, CDCl3): δ: 7.49 (t, J = 6.4, 2.0 Hz, 4H), 7.24 (d, J = 7.2 Hz, 2.0 Hz, 4H), 2.40 (s, 6H).
1H NMR spectra for 4,4′-Dimethoxybiphenyl
1H NMR (400 MHz, CDCl3): δ: 7.49 (t, J = 6.4, 2.0 Hz, 4H), 7.24 (t, J = 6.8 Hz, 2.0 Hz, 4H), 3.84 (s, 6H).
![Page 9: A series of new mixed-ligand complexes based on 3,6- · A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities](https://reader030.vdocuments.mx/reader030/viewer/2022021700/5c611c6e09d3f2006c8c8a5e/html5/thumbnails/9.jpg)