a revolutionary, yet economical new blowing agent
TRANSCRIPT
![Page 1: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/1.jpg)
A Revolutionary, Yet Economical
New Blowing Agent
![Page 2: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/2.jpg)
A Revolutionary, Yet Economical
New Blowing Agent
![Page 3: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/3.jpg)
ecomate® advantages A True LIQUID Blowing Agent Patented: US 6,753,357 w others Pending To Replace HCFC’s, HFC’s, HC’s SNAP Approved ZERO ODP, ZERO GWP, VOC Exempt Economically Advantageous Good Solubility Low Volatility Good Foam Properties Good Foam Flammability Resistance
![Page 4: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/4.jpg)
ecomate® Blowing Agent Properties
Clear, Colorless, Flammable Liquid
Boiling Pt Flash Point LEL \ UEL LAMBDA, gas ( 25 °C)
Vapor Pressure ( 25 °C)
Auto Ignition Temp Specific Gravity Molecular Weight
88,7 F 31,5 C
-26 F -32 C
5 - 23% 5 - 23%
0,074 10,7
11,4 psig 586 mm
>840 F >450 C
0,982 0,982
60 60
![Page 5: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/5.jpg)
BA COMPARISONecomate 141b 245fa 365mf
c
365/227
93 / 7
n-C5 cC5
Mol wt 60 117 134 148 149,6 72 70
Bpt, C 31,5 32 15,3 40,2 30 36 49
Sp Gr 0,982 1,24 1,32 1,25 1,28 0,62 0,75
Lambda 10,7 10 12,2 10,6 10,7 14* 11*
LEL/UEL 5,0 – 23,0
7,6 – 17,7 n/a 3,5 – 9,0
3,8 – 13,3
1,4 – 17,8
1,4 – 8,0
![Page 6: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/6.jpg)
GAS LAMBDA VALUES
10.1 10.6 10.7 12.213.7 15.0 16.3
0.0
5.0
10.0
15.0
20.0L
am
bd
a @
25C
[mW
/m.k
]
![Page 7: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/7.jpg)
ecomate® Blowing Agent - Environmental Characteristics
ecomate blowing agent is an attractive long term environmental option
ODP GWP VOC
CFC 11 1 4000 NO
CFC 12 1 8500 NO
HCFC 141b 0,1 630 NO
HCFC 22 0,05 1700 NO
HCFC 124 0,02 480 NO
HCFC 142b 0,06 2000 NO
HFC 134a 0 1300 NO
HFC 245fa 0 790 -1040 NO
Cyclopentane 0 11 YES
ecomate 0 0 NO
![Page 8: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/8.jpg)
Cost Efficiency
Blowing Agent €/kg Mol Wt Factor €/mole
HCFC-141b ** 117 1,00 Ref
HFC-245fa ****** 134 1,15 +380%
HFC-365/227 **** 149 1,27 +280%
cC5 * 70 0,60 -70%
nC5 * 72 0,62 -75%
ecomate® ** 60 0,51 -60%
![Page 9: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/9.jpg)
Key Cost Points ecomate® has resulted in reduced foam
density as low as 22,4 kg/m3 Free Rise Density.
Commercial experience shows ecomate requires less molar equivalents than HC’s.
ecomate requires less flame retardant to achieve rated foam than HC’s.
ecomate is a small part of overall demand for the molecule and there are multiple plants in the world.
![Page 10: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/10.jpg)
ecomate® Solubility
Excellent solubility in all foam ingredients
CHEMICAL ASPECT w 20% ECOMATE
POLYESTER polyol
CLEAR
SUCROSE GLYCERIN polyol
CLEAR
AMINE polyol CLEAR
MANNICH polyol CLEAR
ISOCYANATE CLEAR
DEG CLEAR
TCPP CLEAR
Br FRA CLEAR
PROP CARBONATE
CLEAR
WATER CLEAR
![Page 11: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/11.jpg)
ecomate® System Emissions –Stored Systems in Drums/Totes
“B”Isocyanate
(ecomate® Blowing Agent)
“A”Polyol Blend
(ecomate® Blowing Agent)
< 22% LEL0-5cm above bung@ 30-32°C
22% LELwithin drum headspace
![Page 12: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/12.jpg)
Vapor Pressure (ASTM D2879, typical data)
Blowing Agent/Polyol Systemeco3-95-1.7
“A”Polyol Blend with
ecomate® Blowing Agent
Vapor Pressure of Stored ecomate® Blends
0
200
400
600
800
20 25 30 35 40 45 50 55 60 65
TEMP, C
UN 1A1 Max pressure
mm
HG
![Page 13: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/13.jpg)
Vapor Pressure (ASTM D2879, typical data)
Blowing Agent / Isocyanate Systemeco3-95-1.7
“B”ISO Blend with
ecomate® Blowing Agent
Vapor Pressure of Stored ecomate® Blends
0
200
400
600
800
20 25 30 35 40 45 50 55 60 65
TEMP, C
UN 1A1 Max pressure
mm
HG
![Page 14: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/14.jpg)
Physical Properties
Very Good Properties
PROPERTYecomate3-95-1.7
ecomate2-90-1.7
Dens, Kg/m3 36,8 33,6
CS//, kPa 317 283
CS_|_, kPa 214 186
DIM STABS
COLD, 7d -0,06 % -0,06 %
HUMID, 7d 2,0 % -0,2%
Lambda, mW/mK
20,9 20,1
![Page 15: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/15.jpg)
ecomate® Density PotentialIngredient System 1
04B73System 2
04B77
H2O 1,3 1,4134a 3,5 10,8ecomate 1,8 0
Density 23,5 26,2
Blowing Agent
![Page 16: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/16.jpg)
ecomate® Density PotentialIngredient System
104B73
System 2
04B77
Blowing Agent moles moles
H2O 0,140 0,150
134a 0,034 0,106
ecomate 0,029 0,000
0,203 0,256
Density 23,5 26,2
![Page 17: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/17.jpg)
ecomate® Fire ResistanceIngredient System 1
04B73System 2
04B77
Blowing Agent moles moles
H2O 0,140 0,150
134a 0,034 0,106
ecomate 0,029 0,000
0,203 0,256
FS 25 25
SMOKE 250 250
![Page 18: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/18.jpg)
Integral Skin
![Page 19: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/19.jpg)
Integral Skin Ability to solvate ALL polyols Good skin formation
Perfectly suited Boiling Point Economical
Half the MWt of HCFC 141b Patents Pending US EPA SNAP Approved
![Page 20: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/20.jpg)
Flexible Foams Good Solubility Fine Cells Safer than
Hydrocarbons Non-VOC
![Page 21: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/21.jpg)
Rigid Applications Moulded Roof
Panels Pipe-in-Pipe
Insulation
![Page 22: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/22.jpg)
ISOCYANURATE FOAMS HIGH vs LOW INDEX WITH / W-OUT FRA ESTER EFFECTS DENSITY TARGET RXN RATES
I = 375, 225 TCCP @ 0, 2,7% ESTERS 1 thru 6 28 - 32 kg/m3
CT 6 – 8 sec GEL 18 – 22 sec TF 20 – 30 sec
![Page 23: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/23.jpg)
OBSERVATIONS – PIR FOAMS ecomate compatible in
ALL FORMULATIONS NO HAZE – CRYSTAL CLEAR NO NEED TO EMULSIFY
VISCOSITIES : ~ 300 cps with HIGH WATER ~ 70 cps with ALL ECOMATE
![Page 24: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/24.jpg)
TYPICAL FORMULATIONSFORMULA
ESTER 10,2
FR Additive 2,7
Cat Blend 2,6
Surfactant 0,7
Water 0,8
ecomate 2,0
ISOCYANATE 81
![Page 25: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/25.jpg)
RESULTS w FRA [w/wo H20]
HI ECO Level IMPROVES RATIO FS UNCHANGED SMOKE LESS Promotes Shrinkage
I = 375 39-3 39-4
ESTER 1 10,2 21,35Water 0,8 0ecomate 2,0 7,56RATIO / 100 A 23,7 54,0FLM SPREAD 15 15SMOKE 10,2 1% WT LOSS 5,4 3,3SHRINK NO YES
![Page 26: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/26.jpg)
RESULTS w/wo FRA w/o FRA
FS - Much WORSE SMK - Much WORSE WT LOSS HIGHER
I = 375 39-4 39-10
ESTER 1 21,35 22,11FRA 2,67 0Water 0 0ecomate 7,56 7,56RATIO / 100 A 54 49FLM SPREAD 15 50SMOKE 1 29% WT LOSS 3 14SHRINK YES YES
![Page 27: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/27.jpg)
RESULTS w/o FRA HIGHER DENSITY
LESS ECO Used ELIMINATE SHRINK
NEARLY SAME FS = SMOKE - WT LOSS +
I = 375 39-12 39-10
ESTER 1 22,61 22,11FRA 0 0Water 0 0ecomate 5,67 7,56RATIO / 100 A 46 49DENSITY 34 29FLM SPREAD 50 50SMOKE 27 29% WT LOSS 16 14SHRINK NO YES
![Page 28: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/28.jpg)
RESULTS w/o FRA INCR. ECOMATE
RATIO IMPROVES FS WORSENS SMOKE VARIES WT LOSS SHRINKAGE
BEST SCENARIO ~ 0.6% H20
I = 375 39-9 39-8 39-13 39-14
ESTER 1 10,96 10,74 13,3 16,0
FRA 0 0 0 0
Water 0,8 0,6 0.4 0,2ecomate 2 4,4 5,6 7,0RATIO / 100 A 20,6 24,0 29,8 36,6FLM SPREAD 25 30 40 40SMOKE 22 10 28 26% WT LOSS 8 7 11 11SHRINK NO NO SLT YES
![Page 29: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/29.jpg)
RESULTS w/o FRA [0.6% H20]
DECR. INDEX RATIO
IMPROVES FS WORSENS SMOKE WT LOSS NO SHRINKAGE
I = VARIABLE 39-8 44-1
INDEX 375 225
ESTER 1 10,74 25,7
FRA 0 0
Water 0,6 0,6
ecomate 4,4 4,4
RATIO / 100 A 24,0 51,6
FLM SPREAD 30 35
SMOKE 10 23
% WT LOSS 7 18
SHRINK NO NO
![Page 30: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/30.jpg)
RESULTS w/o FRA [0.6% H20]
ESTER AFFECTS: FLAME SPREAD SMOKE WT LOSS
SHRINKAGE OK!
I = 225 44-1 44-2 44-4
ESTER 1 25,8
ESTER 3 29,2
ESTER 2 23,2
FRA 0 0 0
Water 0,6 0,6 0,6
ecomate 4,4 4,4 4,4
RATIO / 100 A 51,6 59,9 45,9
FLM SPREAD 35 >75 30
SMOKE 23 34 25
% WT LOSS 18 27 17
SHRINK NO NO NO
![Page 31: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/31.jpg)
RESULTS w FRA [0.6% H20]
EFFECTS ARE more SUBTILE
ESTER AFFECTS: FLAME SPREAD SMOKE WT LOSS
SHRINKAGE OK!
I = 225 44-5 44-6 44-7
ESTER 1 24,9
ESTER 3 28,2
ESTER 2 22,4
FRA 2,25 2,25 2,25
Water 0,6 0,6 0,6
ecomate 4,4 4,4 4,4
RATIO / 100 A 54,9 63,3 49,1
FLM SPREAD 30 30 25
SMOKE 10 10 8
% WT LOSS 8 8 6
SHRINK NO NO NO
![Page 32: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/32.jpg)
IMPROVED PROPERTIES CO-BLOW w H2O USE RIGHT SURFACTANT PROPER CATALYSIS
< Strong Blow ……………Strong Gel >
![Page 33: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/33.jpg)
CONCLUSIONS No Need to EMULSIFY BA ESTER Choice CRITICAL Some FRA Suggested CO-BLOWN ECO/H20 Suggested
~ 0,6% H20 Optimal Right Surfactant & Catalyst Pkg
![Page 34: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/34.jpg)
ecomate® advantages A True LIQUID Blowing Agent SNAP Approved Good Solubility Low Volatility Good Foam Properties Good Flammability Resistance Cost Competitive TRY IT….YOU’LL LIKE IT !
![Page 35: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/35.jpg)
Contacts - EUROPE BOC Specialty Gases Zoë Sturdy 10 Priestly Rd Guildford, Surrey GU2 7XY ENGLAND TEL: +44 (0)1483 244 088
![Page 36: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/36.jpg)
Contacts – S/C America PURCOM Quimica Ltda Guiseppe Santache Rua Aeroporto n° 83/115 06419 260 Barueri, SP, BRAZIL TEL:(+55 11) 4168 2829
![Page 37: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/37.jpg)
Contacts - ROW FOAM SUPPLIES INC Todd Keske 4387 North Rider Trail Earth City, MO 63045 USA TEL: 314-344-3330
![Page 38: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/38.jpg)
The Next Generation Blowing Agent
![Page 39: A Revolutionary, Yet Economical New Blowing Agent](https://reader038.vdocuments.mx/reader038/viewer/2022102923/5516b6b9550346f0208b54b3/html5/thumbnails/39.jpg)