a pyrimidine-like nickel(ii) dna base pair

2005 Nucleic acids U 0700 A Pyrimidine-Like Nickel(II) DNA Base Pair. — 4-(2 ' -Pyridyl)-pyrimidinone de- oxyriboside (IV) is synthesized and characterized as DNA metallo base-pair. The crit- ical step of the synthesis is the modified Negishi coupling of pyridyl zinc bromide (III) with chloropyrimidone (II). — (SWITZER*, C.; SHIN, D.; Chem. Commun. (Cambridge) 2005, 10, 1342-1344; Dep. Chem., Univ. Calif., Riverside, CA 92521, USA; Eng.) — M. Paetzel 30- 184

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Page 1: A Pyrimidine-Like Nickel(II) DNA Base Pair

2005

Nucleic acidsU 0700 A Pyrimidine-Like Nickel(II) DNA Base Pair. — 4-(2'-Pyridyl)-pyrimidinone de-

oxyriboside (IV) is synthesized and characterized as DNA metallo base-pair. The crit-ical step of the synthesis is the modified Negishi coupling of pyridyl zinc bromide (III) with chloropyrimidone (II). — (SWITZER*, C.; SHIN, D.; Chem. Commun. (Cambridge) 2005, 10, 1342-1344; Dep. Chem., Univ. Calif., Riverside, CA 92521, USA; Eng.) — M. Paetzel

30- 184

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