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06/18/22 1 Hazard Communication with Hazard Communication with Globally Harmonized Globally Harmonized System of Classification System of Classification and Labeling of Chemicals and Labeling of Chemicals (GHS) Update (GHS) Update

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Page 1: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 1

Hazard Communication Hazard Communication with Globally Harmonized with Globally Harmonized System of Classification System of Classification

and Labeling of Chemicals and Labeling of Chemicals (GHS) Update (GHS) Update

Page 2: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

HazCom with GHS HazCom with GHS UPDATEUPDATE

04/19/23 2

NO CHANGES

to the HazCom

Standard!!

UPDATE to

HazCom Standard!

Page 3: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Purpose of HazCom

04/19/23 3

All employees have a right to know the hazards and identities of chemicals they may be exposed to when working.

They also need to know what protective measures are available to prevent adverse effects from occurring.

The OSHA Hazard Communication Standard, 29 CFR 1910.1200, requires employers to identify materials/chemicals used in the workplace, (properly classify) them as “hazardous” and inform their employees of their potential exposure along with the measures necessary to prevent exposure to these hazards.

Hazard CommunicationHazard Communication NO

CHANGES!

!

Page 4: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Purpose of the GHS

04/19/23 4

Globally Harmonized SystemGlobally Harmonized SystemUPDATE

!

The GHS was developed to “harmonize” existing chemical classification and labeling systems so that a single global system could be used to address the classification of chemicals, labels and data sheets.

It does not replace the Hazard Communication Standard, but will require updates of:“hazard classification” replaces “hazard determination” “labeling” (more specifications).“safety data sheet” replaces “material safety data Sheet”.

NOTE: Training is essentially the same with updates to the above sections.

Page 5: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Why use GHS?

04/19/23 5

Globally Harmonized SystemGlobally Harmonized System

The GHS is expected to:

1)Enhance the protection of human health and the environment.

2)Provide a framework for those countries with no current system.

3)Reduce the need for testing & evaluation of chemicals.

4)Facilitate international trade.

UPDATE

!

Page 6: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

OSHA-Final Rule

04/19/23 6

Globally Harmonized SystemGlobally Harmonized System

Effective Dates:

12/1/13: All employees must be trained on new label elements and SDS format.

6/1/15: Manufacturers and distributors must comply with all modified provisions except that distributors have until 12/1/15 to provide revised labels for all products shipped.

6/1/16: OSHA enforcement starts: Employers must update all labels and HazCom program, provide additional training for workers on newly identified physical or health hazards.

During transition period, employers can comply with old or new standard as far as labels and SDSs.

UPDATE

!

Page 7: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Requirements are the SameRequirements are the Same

04/19/23 7

Everyone who works with or is potentially exposed to hazardous chemicals must receive initial Hazard Communication training prior to working with a chemical.

Retraining will be required if new hazards are introduced into the workplace, processes change or exposures increase.

Hazard Communication Hazard Communication

NO

CHANGES!

!

Page 8: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 8

Hazard Communication with Hazard Communication with GHS UpdateGHS UpdateTraining Topics

Employees still must receive information and training and have an understanding of: The OSHA Hazard Communication Standard; The hazards of chemicals found in their

workplace; Chemical Classifications per GHS; How exposures could occur; Labeling methods (Including GHS Labels); How to read and interpret a Safety Data Sheets

(SDSs); Methods to prevent exposure.

UPDATE

!

Page 9: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Major Changes to HazCom per GHS

04/19/23 9

Globally Harmonized SystemGlobally Harmonized System

UPDATE

!

NEW Hazard ClassificationsPhysical hazards (16 classes)Health hazards (10 classes)Environmental (2 classes)

Hazard CommunicationLabeling (New classifications/Categories)Safety Data Sheets (Replaces Material Safety Data Sheets)

Page 10: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

NEW Hazard Classifications

04/19/23 10

Globally Harmonized SystemGlobally Harmonized System

UPDATE

!

Physical Hazards: Explosive substances Flammable substances Oxidizers Self-reactive substances Self-heating substances Pyrophoric substancesSubstances corrosive to metals

Page 11: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 11

Globally Harmonized SystemGlobally Harmonized System

UPDATE!

Health Hazards:Acute ToxicitySkin Corrosion/IrritationSerious Eye Damage/Eye IrritationRespiratory or Skin SensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicityTarget Organ Systemic ToxicitySingle and Repeat Exposure

NEW Hazard Classifications

Page 12: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 12

Globally Harmonized SystemGlobally Harmonized System

UPDATE!

Environmental Hazards:Aquatic ToxicityChronic Aquatic ToxicityHazardous to Ozone Layer (Non-

Mandatory)

NEW Hazard Classifications

Page 13: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Links to New GHS Hazard Classifications:

04/19/23 13

Globally Harmonized Globally Harmonized SystemSystem

Chemicals will still continue to be classified but the criteria for classification is found in Appendix A: http://www.osha.gov/dsg/hazcom/appendix_a.pdfAppendix B: http://www.osha.gov/dsg/hazcom/appendix_b.pdf

Page 14: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 14

Globally Harmonized SystemGlobally Harmonized System

UPDATE!

Pictograms will be required by June 1, 2015 to alert users of chemical hazards.

Each will consist of a symbol on a white background framed with a red border.

The pictogram on the label is determined by the chemical hazard Classification.

GHS: Pictograms

Page 15: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Health HazardHealth Hazard

CarcinogenMutagenicityReproductive

ToxicityRespiratory

SensitizerTarget Organ

ToxicityAspiration Toxicity

04/19/23 15

Page 16: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

FlameFlame

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FlammablesPyrophoricsSelf-HeatingEmits

Flammable GasSelf-ReactivesOrganic

Peroxides

Page 17: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Exclamation MarkExclamation Mark

04/19/23 17

Irritant (skin & eye)Skin SensitizerAcute Toxicity

(harmful)Narcotic EffectsRespiratory Tract

IrritantHazardous to Ozone

Layer (Non-Mandatory)

Page 18: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Gas CylinderGas Cylinder

04/19/23 18

Gases Under Pressure

Page 19: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

CorrosionCorrosion

04/19/23 19

Skin Corrosion/Burns

Eye DamageCorrosive to Metals

Page 20: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Exploding BombExploding Bomb

04/19/23 20

ExplosivesSelf-ReactivesOrganic Peroxides

Page 21: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Flame over CircleFlame over Circle

04/19/23 21

Oxidizers

Page 22: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Environment (Non-Mandatory)Environment (Non-Mandatory)

04/19/23 22

Aquatic Toxicity

Page 23: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Skull and CrossbonesSkull and Crossbones

04/19/23 23

Acute Toxicity (fatal or toxic)

Page 24: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Information Link: New GHS Information Link: New GHS Labeling PictogramsLabeling Pictograms

http://www.osha.gov/Publications/OSHA3491QuickCardPictogram.pdf

04/19/23 24

Page 25: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

25

GHS: Label Must IncludeGHS: Label Must Include

Label must include:Product identifierSupplier identifierChemical identityHazard Symbols (standardized)Signal words (standardized)Hazard statements (standardized)Precautionary Statements (not

standardized; guidance offered)

UPDATE!

Page 26: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 26

Page 27: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

All Hazardous Chemical Containers must have labels applied Except:

04/19/23 27

Exceptions:1. Stationary containers with similar contents in a

single area;2. Portable containers if “for immediate use”.

HazCom Labeling…..What HazCom Labeling…..What has not changed?has not changed?

Page 28: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 28

HazCom Labeling…..What HazCom Labeling…..What has not changed?has not changed?

Other types of labeling, for example, NFPA and HMIS labels, may still be used to label “In Plant/Facility Chemical Containers”.

Page 29: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Information Link: New GHS Information Link: New GHS Labeling Quick CardLabeling Quick Card

http://www.osha.gov/Publications/HazComm_QuickCard_Labels.html

http://www.osha.gov/Publications/OSHA3492QuickCardLabel.pdf

04/19/23 29

Page 30: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

HazCom “Safety Data HazCom “Safety Data Sheets”…..What has not changed?Sheets”…..What has not changed?

04/19/23 30

Must be legible and in English;Must have one for every hazardous

chemical on site;Must be available at all times to employees;Must be reviewed to ensure most current is

on hand.

They Still:

Page 31: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

GHS Safety Data Sheets – GHS Safety Data Sheets – What has Changed? What has Changed?

“Material” has disappeared, they are now Safety Data Sheets.

The SDS has 16 instead of 12 sections.

SDS is more uniform and easier to read.

04/19/23 31

UPDATE!

Page 32: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

GHS Safety Data SheetGHS Safety Data Sheet

04/19/23 32

Page 33: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 33

GHS Safety Data SheetGHS Safety Data Sheet

Page 34: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 34

GHS Safety Data SheetGHS Safety Data Sheet

Page 35: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

04/19/23 35

GHS Safety Data SheetGHS Safety Data Sheet

Page 36: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Information Link: SDS OSHA Information Link: SDS OSHA Quick CardsQuick Cards

http://www.osha.gov/Publications/HazComm_QuickCard_SafetyData.html

http://www.osha.gov/Publications/OSHA3493QuickCardSafetyDataSheet.pdf

04/19/23 36

Page 37: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

Information Link: Updated Information Link: Updated HazCom Standard, 29 CFR HazCom Standard, 29 CFR 1910.12001910.1200Final OSHA Rule published in the Federal

Register March 26, 2012http://www.osha.gov/pls/oshaweb/

owadisp.show_document?p_table=FEDERAL_REGISTER&p_id=22607

Redlined/Strikeout Copy of 1910.1200http://www.osha.gov/dsg/hazcom/

redline.html04/19/23 37

Page 38: 8/17/20151 Hazard Communication with Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Update

38

GHS Info on OSHA

Website:http://www.osha.gov/dsg/hazcom/

index.html

Information Links: OSHA Information Links: OSHA and The Purple Book, Rev 4and The Purple Book, Rev 4

http://www.unece.org/trans/danger/publi/ghs/ghs_rev04/04files_e.html