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zz. rirriuoli? ar: a rtrrJfrfi?uiiluar: s 'leiar:
A + 38 ---------+ 2C + D
t v v / | .s/ si t - gt^'=^F'n: r r,l r t Osr.t n I t ru dru rYu r : v ri i r I n r t t t trl ru rl u ru O 3 t tn A v d I : nU t ? n I lil U fl { 1 I
0 2 4 6 B 10trar (s)
t-
v d j rnso c -t v drYntEuuerunfr r"[n-irn: tvriil no t fl n: 11l fl {u
fl. fi,rul a iurfi frn:rnr:aoa{uo{l s rYirffuffn:ln-l:rfintoa c
lJ. 6'sr:rnr:tfronJfrfiSurtqAuluoru z iurfitt:n finirriosnjr o'+ 'nol
dm-"-'
j a d dv a laaa -V-..^^t-S '1fl. frpar q iurfr fro'n:rnr:rfrnilfln5ul{oun?lYlt?al 2 ?ullli.rqaa d a 4 ' :flirfiotrarr^iru'hjsiurfi{. ilflniutuoYlnflrluoul':cI}JU
valaaa+-"1 --taddlto. on:1nt:riopJfrfr|urrqfiiltur l{r?ar 0 - 2 ?1{rYl tilu 2 r1lrzu0':
tadu?{t?al 4-6?U]n
A I Y Y 9/clnt:?tn: lvfi9{a1Jl{flU1J 0 [nIn
lu1. nltavttllll{u
-N\1\/ 1l fl ttav i*7
5. ii n llRv f,
o4.
2.2
z
a 1.8
€,uv 1.4Ez 1.2
,3 1
€ ouF ooE o+
0.2
0
c ltavf,-l: D fr'sarunr:
,i'zu [[av fl tllluu
n t [[av i]
DAB
--l 6:rl 9rr -\tt,-' \//
UAd:?ld?Tt 59 rflt:v ^ /-i?uor119ru11 8 iln:tnlj 2555
@&vtfr\({=NrETs_\*-- dnruuMor ron.sindEnon6 loonnr$rwl
-.
ttuls@/{dljEg'frsl'*rP\*@l
nr?r 22
r?at 11.00 - 12.30 u.
z:. rJfrfi3urnr:6rnrurrfi'a'lulsr:r0ulJouonulryri (No) l#ufi'ooonfrrouuavuti'a
'l uTsr : r o u rfi o fi u #ur r n fi q su n n fi #o r usiuroo rfi ru or : il : y n o uTa ri v u r { u fi aqg
a.r'hfl u rJs ru r ur d n rio u rJ fr fr3 u r o r rfi s, {u o d r r : r sr r i r ni ql ord u fl u,drr r?r,qvv
. v y <cd a{a a dl. cn:gtilgluNnunr.ntytruiu
2i, o n : r n r : r u ffu zu o sul uI n : r o rru o u o n'lry oiu I n dul
a^ er s) t, }q u zo &( 3I n?tlJrlJlJlJuzuot [u lsr:rouruouon"[ryrin^{iltu\./4. ar:il:vnoulouydrfi ruri r'l#onrunfi a.:duqU
v I o) 1 raaas. ild{{rurioffrurTupiruo.rrJfrfi3o-ru"uu
--]w*${t
:*'aitr 59 rnri (&KYlfrv a ei \K€NIETSiuoriisrufr 8 ?tn:rnrl 2sss Y"#H1T':flT::H:slffi
vnir 23
t?at 1 t.t9z- 12.30 u.
r0^'t-' tz'
24. dr: A rrayfir: u rirrJfrfi:^uiffurY.:auni: \
d..^4'
- v r r et 9r /. jo d t j I v2. oer: ]d?u: y?l?'r.:fl ? tljrljlJUu1j 0.1H\ : c llu)gtultslor? n try{lln tnu
2.3 x 1o s
mot clm-3s- S'$Nh-tSdvrrgtyitorv3. 0 gl:tcY?l{:v?i?t{fi?rrlrlJ}JlJlrljo{fr r: A nana{l9ro[?nts{ltl]t nu
A
A5.
-5 -3 -t1.15 x 10 'mol dnr s
ofl:ln-l:aqa{l10nf,t::
on:l nl:aQa{10'xeTt:
41vB cu.ltn-lnU 3.8 x
1.9 x l0'. ntol dnr
l---I
\ Utr'\\
l0-3 mol dm-'.-'
-3 -l
,;'^i"*\" g
{To "\u
\6-o'
ltnv frl:dlvry{rnlnu
Ao
ll rlqd,,,!
-lJ _9,.o$9,
Acaq;t Dlnond,
A(aq) + B(aq) -------) zC(aq) \u\dl"lyrt3rv
llJo9ltrlJcn:avatu A tlau6n:avatu B lllJFt?tlrrtrutu 0.2 mol/dnr- rlnflllt , 3 . v v oi L v A r ln r aofl]{nv 3 cm nlnr:oul?arnunildt:?l.tf,o{eJf,}Jnu rr.iorrarr"iril'hJ f O iurvr
o tJl la d t 6t d a & -4 v aullu?tn:tyl{ 1,{u?rluf,t:nyntu}tf,t: c tnQtju 2.3 x 10 mol ogt51fn:tflgt
lA+rJ fr ffi alnfr rnfr ur o.: il fr fi3 u rfi ril u fi'r dolor
_r1. nllq08ruO{Ogl:lfll:AfiA{lto{Grl:pr{glUttayg{AnR[Uc1lcil{lnlnU 1.53 x t0 mol/s
[to,bCIffio ^'- ---J' -l
SExto
I
anlduMounrmrsitdt!fl !utd (oDnnlsunuu)r'd k@a dtulrdt@ 5{t@ iA4(@,1 [-]at 11.00 - 12.30 u.
nr;af* 4ll,t u{nree UA)
Hr(g) +
2 No(e)
. ^3- 9/ t m r<I 4
1\or:ilrronrrruno-lrJu
-4- d d /,ooo , etilorrrruurf n V ilfrh:^ur a) rrnz ut oyrJYueY:'lrrfrnnr.:'hjrir{Hr?,r,.,nfiu
./' 4
4 a v rqaa , L; tv votruorillJn ? u ror rr il g nE u r a) rr0 y 4 I tyirrirrfr ovrj :"u6':lufi n vr r.:'hJvyd1J1,1?iutlJtftlju
AV0. lil0aqn?til.slu././.v<lvosl:ll:?[111fl1{
ft\U€io
o 25. o tnfi u nr:rnfi rra y rirn.: fi auq n (K) ruo.:rJfr fifua) ANI{..,(S)+f Or(S)
b) N2(s) + or(e)
c) 2I{F(g) -d) 2 NQCI(g) :
&0 &t
2N, (g) j !,9(g)
2No(g)
R,(e)
+ CIz(g)
)--ffird{-w.-
{ tlav 0
K : 1x 10'8
K : 5x10-''
K : 1x l0-'t
K : 4.5xI0-3
n. rJfr fi3u rfr' wy6vfio nrr f] a'lfYr i,*,fluo\6^,rir #u
rr. ,d.,ri,,,,fi'n' o, ilnfrBsr ")
rrny b) orrjfufi\urlqnr{#ounffu*rndrr
fl.
{.
rl fr fi:^ u r b ) r ra v .) o v rJ Yu frd u fi s n r s n : s ffu {t il eiru
t'rilrfi,nlilI
W {olorqn0
I or
!,-.--ft-Tfl1hbt
3. flilayng
lv5. il tl.ltu1lJ b'1 til0.( i/ / r" N
!r' q' /6>
n', ( _f4_{E_
JIe/
.l 16'r,\,tli
:#a?rr 59 terti
v a lAiuorrrnurl 8 lJn:lflil 2555
vtfranrduruolnronrsinurinodri {o0nnrsuhuu)a,*a! 6dkd tr,-d ldft k lJ*o*iel
V ?F?iut -)[?a-l 11.00- 12.30 u.
26. nila so.,ct2 rrsrnr{r'l#rrfrei so, tlnv cl, rY.:orunr:
SOrClr(s) sOr(e) + Clz(g)
rdorirnr:vraao{Iauu : : qttfi'fl Sorct, rJ3rureut,fi .:lunituvfl fl tuta 5.0 dm3-'-=.
' oi o ,-I- - :, er t v Lfl?UnlljoA{Hflrlll 127 C l"lU?l?Jf}-Jlxl9ll{l:rJnutnlnu 1.64 atm OInUUilCiOU
qqg
glA ugta a d la6a v d - Y I
nl"tiytqsutiflun{yt ouilfl niU Ifl I:llfi nel?zuo{tlfleT SO2Clz trtIqnl?vcTruqn
n u ir1 u n r t uv #ufi r ria#s *{ u n tri:l rTu 0.09 m o t/d *t Yo u a, n I : ttfl n fi2 ru o {l
urid so2ct2 finirqvirla s\$ dksihcr\q/
Siliy,,
l. 20
2. 40
(\ 60
4. 80
-\"S(0d i .
cr\f
:"sI
5. ulri mrru r : CI d r u r su'leirvl : r v'lrj vr : t u ni r nr I fr nru q
Bonz
-lE:t..\t..)
\qTto
o
t-)
A6"\\
Bounzsilv*qotd
Pallintrvt
pu bJ
D inond
sil ver
slr'v p,
Q'ld
hDo\lhz
nolD I lVtF
$lire rSi{vr r
Dinrond
Dlact P iilcrd
--^\AotN9--
UA:?icr?ur 5y rnltU A /;?uorll9rEJ?1 8 lrn:rPllJ
i\*i\YJfln:ul I{A$\,au=:$$
- rflun-.:r?o1n
At;
rii urir ex fi nr : r rn n 6'ar o.: ri r
D?61trrid;lrtrnn tn doil JitrZ- <{lA (aq) + t{2o(l) ilntfl{YttrrJfla
rnir 26
r?at I 1.00 - 12.30 u.
vrt
\q 'fl]g_Tl
-rcy
,Y,dtt.{rqL27. 6n Ko, Itar K,, lilufllFt:ilf,]tftnnt:ttnngttuo{n:floou ll2A ludunoun I
vtVdav
ttCIyuugloult 2 gltlJatflu tlay K
9,{n*tonqm
(aq) + OH (aq)
ixmq?dil----]/
$t r. K,r / K*\0
2. K,2 / K*
,Ss3. *.,,.*
"$$* |
$ro
'f0
sl a2'GNC'\\ t-/ (K,, x K,2) / K*
5. K* / (K,r x K,r)T- PNK :
1t'n r ril1
\T
{Odx$o : }oso
tstl r P luiltrro"o' o nd'c ianfi tt\*
QYO
4
/* \u\sr .)'AVrr
,'A t4 tu,q J
Tg0 0
\,y)o ---. r.t t-t \1.,
1r'7&o
\{rlo-
IYJ
l oo$o'\r
AqL=:q-
--'.t.[ [r:"'$eSt o
l*
["ut/'ur.,
l)amr' I ilri,rn ntu
1'to tfJ L
tgo6U '
Vfo
{r ruv
uad:l4cr?Yr 59 rflrJ
vadi?uolllnu?r 8 iln:tFrlJ 2555 @'#ffi*,*:#:H
,^nr{ur ,L I
[?at 11.00 - 12.30 u.
dat-l<28. finrryailqaroq:vuuflnzuurfl soO "a?' fi xrte) ur(u) uar NI{.(g) otu?u
ov;q;e)40.15 mot 0.20 mol rray 0.0s mot erllJdrrYu frqaru4finrsfi #rrfiru ru, al'hJ
is
1u : vu u rnool#n r r r r rr7ru cYuzu o s N u., fi n r r v aru q nbi ri rfi ru fi urfl u z tvi t t o s
tv
Rr?vcrilEarorru ficrruqalmrififinirersfiaruqatravdruru mbt toq H, tvir'lo
ntfl'tncrilaarq dturu mol ttoil H,
0.1 04 0.250
0.104 0.1 25
0.520 0.250
0.520 0.1 25
t.04 0.250
1.
2.
e4.
5.
-l6)tPt
t,-\{c',
iuCtl,tuog{o01] --+uad
:1.r i?T 1 5y rnilu a lA?uo1?1gru11 8 lJn:lnlJ 2555
lA6$vtfrWUF-I':**,,*:i:r:,xr
m#r 28
r?at 11.00- 12.30 u.
Jo
nl{'o Ttt;.v
Vw'rr@,
(wl
tv* \fi,_ -rl
. ro ll ['1, CLtn Cor t"#zq.\'lnnfiu rMt-c'u.coor t r\ rflun:oovfilurfionrir rinruffitflu'leifr":n:atravrucT\#
rfi o rfi or rJ fr fi3 u r n r ru n: u u ? u n r : nr sr r u ofi 6 ru rl o s d r r nra u#r ar u'lu qjo v o qnu ; il
3.
o
C ft, cm Hr-+ N I ctt, colrt ---+ lu 'UtndgR
irf l'r I
N H.lCr{2COPtr Nryrlocoo 2
NTI2CH2COOH
NHlCI{2COONH2 CH2COOH
ritlpr{,cooH.Yt 0- v'nf,ei6coo a
trAx'rcu2coot-t+ Nrbcr6p opr{'
:#a?n 59 rnrfi @&ylfil ri#r Zgv a aA \L€N|ETS?uotltnun 8 iln5tFtil 2555 \5-TffiTffiH':j:#*, [?at 11.00 _ 12.30 u.
l4
t2
t0
o
6
4
30. o r nn:ryl nr :'lyrryr :n sio'hJfi
A;,tiln ro I cr : fr u : : o'lu rl ? fl iil.q
dal o1 #e.r a 6'r n : r yhir s sYu
G2.
3.
4.
\o x.
\
\\:
rjsurrun:qn5ar: ) ^ t-''W
unnrfiil ey Xc\).{"
\o
s"r60120
n: ruua vlufi rr: sr pid1fr$,, r'ln,n, u,
"s
_ls'-wt
nr:'luzursr;rJn:ru aa/ilt: luu?[:stst
HCOOH KOH
HNOI KOT{
KOI{ c[{3cooH
c6HscooFI NI{4OH
H2 SO4 NH4OH
:#airr 59 rerfi 6e7f:iuorfisrrid 8 lrn:rnrr 2sss €SE"{fut**:s#L
ri#r 30
r?a-l 11.00 - 12.30 u.
:t. ririiunl#
loJ
&,
nhol '( flLF,l:
? L.o 5
--ls'..\fi
- i.l-,
6r r : d ; n r u @ r il u 6r r : n'r d r u rl o, FQ[Itr--d u, u'r o ri.,, u'l pia r : a y n r u
ri3rurn: 5oo cr'3 K0 hl 0.Jil3
o', r u, u'r u@ ril u a r : a v. : FmtrT*t, u, o,l.r, *'l plar : a v a r s
h"1il:rrrn: 100 cm-t
, A o a 9./ ln vd dnuo- v
o r ndory n fi rir nuel#'loifi nr :a; rJlifi'.r fi
fl. Gn:aynru R finrrrurfluruarurnnirar:avaru t]
u. trr:avnru n fiarrrurriru{u 1.0 mol/dm3
dlf,i. pI{ tlo.ldl:Avalu A XIfll 12.0
rioo:r,[lnanqq
ItvI. n tiltl{uI
lu2. lJ [lnUUv
I v,3. f,l tll'luu
\a./ n unv I\,/---.-\5. n [[nv fl
UA4:HGr?T] 5y [nXJ
va/.i?uotltgru11 8 lJn:rnlJ 2555
6KVlA\egNrErs
\\|]- a"r_r'mr.''n'm'cint rhrdvi rnomlsduu'\:: tk'l)\*ottr)
urir 31
r?at 11.00 - 12.30 1{.
l{or32. tlr0urdt:ayarun:qoolr IIA
vy9)flUGrl:AYnlU NaOII [utl1ll
tflurvirln
: rJGutFr: z5.oo .n,' rutulntn:st
t-l vnrfl {11nr:llfl nn?uo.tn:a HA
-l.r r v11?.1 plI tlllnU
30.050 mol/dnr
qI
-'lx 10'Il-ax10
x10-5
x10
-5x l0'Q$,or
33. n:fi uo 6fi aql rfr fi fi n lcn uroo ) rfl u n: oruo u oTrJ : fi nfi o qrJuu r rr#rj -l sr u fi auu{l
- q : ' ' "r'li,n:srffilf,r:auaru#rrir€Jrrrfr'ilrofirut a trisr avarslurit 100 cm-' rrd
ygrlNaoH lll]Jzuu 0.01 r,'ot/dm- nuirsio.:l# ruuoH 20.0 cm-. urrttirjtn
usiavtfi nfi n:ntro 6 fi ary16Qd nfi fi afi n Yrr:
l. 1.13
2. .1.5
.i 9.0\J,4. 36
5. 50
-_-.l(nItrt.t(r'
.0
.0
.0
.0
.0
:rTaiur 59 rsrfi /@6V1friuorfisrrifi I lrn:rnr 2sss W$Eilfut***rr*
9J- .l -l1ul J L
r?a] 11.00 - 12.30 u.
r+. nrirun1# n: srtrsinrt fi e:i f,ir nrfi n I : ttn nfrrzu or n : n1ur.:rduge
*-rHIi (K" : 6.8 f r o't I{cN (Ku : 4.9 x r0-'o)
C6II.COO[{ (K, : 6.6 x 10-s) HCNO (K, : 3.5 x l0-4)
dl dar) tilu eTl: nva tuntnfl otnnt:f.tdilruo{GTr:ayaru Adr:duaru fl) 1) n) [[nv
ttavGTl:aualu B
flt:CIvalu A dt:avo-lu B
n) ar:av/tu IIF 0.10 rnol/dmr 100 cml'I trl:avalu NaF 1.0 moVdml 100 cmr
{) dl:aYalU I{CN 0.20 mol/dr',rt l0 .,r.,' dl:avatu fg'A O.f O moVclmr 100 cm3
fl) al:avalU C6II.COOII 0.10 mol/d*-t 10..r,'' dl:nvalu H(ll 0.10 moUdml 50 cml
.:) fll:avdlU I{CN0 0.20 rnol/dn,-t tOO..r,' Q dl:avaru NaOH 0.10 mol/dm-t 100 "*'
nr:til3gurfisu
1. n<1J
!7'n . *P n<{4. {<n
5. lJ<.:
pII tonf,r:avarulYt ltv'loi riolorgn
fir Cra ' e r rto-l /r,jg$0,
\r 0o
-l E;'..\lc
!'..'\-/
:fiairr 5e ro'fi (ffi#E ririr 33
iuorfisrtifi 8 ilfl:rntt 25s5 V"sm':xx'x:ffiH: t?41 ll'00 - 12'30 u'
n.
lJ.
fi.
{.
r.r€+ HrO
----->
->
l.
2.
3.
"A
t)5.
1 ttav 3
1 rtav 6
3 lrav 3
3 ttou 6
6 [[Au 3
_-l€owi,
I s. rl frffi urlsr 6oufi iiran o o nfi rsrfr'u'o.: s liin16uuttila s
r{2so3 /,,r4 /obn * ,I,o
case;1 H,o
LttCIrynm6Ca(OH), + SOO, -------->
f ..-tr-T[6Y-T
r1---S{a+-*
3.<Ht€TE-a-
4. n ltav {l
N ,L( sl n tnluu
:o.,duqucrunr:6nondfi ttfr'r ov'ldnir
a clH*O + b cro. + c I{rSOo
a trau . tiJutvirlqnrildrdu
+ f I{rO
:#oisr 59 rnrfi @&Vlffiiuorfisrdd 8 iln:rnil 2sss Wilff,fu****r*-
urir 34
t?at 11.00 - t2.30 u.
:2. rryndtl^,lflrrnfirrierufi.:ri pt uavTari, v ,iJu,?rlr{rilr rlfrfr:^urrfll*"-ufi
xo*(rq) + Y(s) xt"(uq) + yt*(uq)
Eu,"ud -0.76 V
rioalrfloqnplo.:
- __4t dt v aln t tn. x rilustroonfr"lerci rrnrr.lfrfrEarfirfin'leyro.:
fl . pt,fl ,r#.,roTusr fi fi rJfr fi:^u r o o nfirnfi'urfi u, fi u2+dFr. y'' frnrrruarrur:olrrnr:YuErfinsr:ou'lsyfinr'r xo'
.:. r' rflufi'roonfi'lo# uay x4* rfrnrJfrfi:^uiieynfr'rr
l. n ttav n
?.. lJ ttav .:
vI .r3. n lntuun\ ,r
v n rYltuu
5. u ,rilrYu
< Etlcu{uFlt
--l *:l.t v,o _\(?
:fiaitr 59v a lA?u0l?19lu1l 8
IFI}J
iln:lFtxJ 2555
(@gmEW"J*H.{|H,H,Ji:*TH
nrir 35
r?a] 11.00 - 12.30 1{.
s8. riruusr rirffnti''luh{ r 6'.: fi
Or(e) + 2ll,O + 4c ------------> -lOll (aq)
Or(e) ',' 411" + 4e -------+ 2tl2o
Sool- (aq) + 2 e ->
zsro]- (aa)
25O: (aq) + 3ll2O + 4c --------+ S,03-(aq) + 6OH faq)
2llz}+ 2 c
-)
Hr(S) +2Oll (aq)
Na'(aq) + c ---------) Na(s)
j q^,- e) rtralh,{frrtilottgnar:aualu NerSrO-, [unr:nvarutu6l9l?ufl:
;L * 's I
yrll?trfl tvto ttovfi ffrrtolundolaqn
otr
oE,
oE
oE,
oE
oE,
+0.40 v
+1.23 \i
+0.08 v
-0.57 V
-0.83 V
-2.71\/
rga v /E{a 4
ruanRfl{fnnlnfltu
1.
ar)
3.
4.
5.
firtnrlvrer fi,,rlrrn
H, sol
o2 soi
H, sooi-
+
Na Sooi
s ol' o2
---ls;.rY.u \,(1
UAd:?1fl?Tr 59 n:iv 4 /;?uotYtslull 8 lJnStfilJ 2555
rir7r 36
t-lat 11.00 - 12.30 u.
3e. ri rnufi rirfr'nfh^lvlrrr rnr g ruoT:fi
IAAA d /ufln:utn:,:lcuan E" (v)
Al''(uq) + 3c At(s) -r.67
+0i34
7+Fe (aq) + 2c Fe(s) -0.44
Sn2*1aq1+ 2e-
-; Sn(s) -0.14
2tZn (aq) + 2e Zn(s) -0.76
yaa o v S a ; 4 s -l a j0t uRtrl{v?1ta?u t nHUTu9t?11{.rU::0 f,t: ny nlulnGiolJ o I lnuv6 nt il9t111-i I
n r r uylu #o1 a'lrirfi sr n r : rl n io uq
/--\ a -r 4r v dI I ) nmuyoyailluuilu::Q611:ayatulnnolJo.:d{nyd\Jqra
2. nrruvAunu:TQGn:ayarurnfrozuo,:no{ltor{qq
3. niruv#rnvfru::osr:ayarulnfioro.rrHfin
4. Rryl{yoyafr tfi ururr ::o trt:aynturnfior.rolyro.:rrasgq
dzta<5. Rl1rl{VflUnU::0611:ayaturnnolo.Soyg}ilurJrJ
--:l,t s,\.\{'4,
:#aitr 5e terfr (ffffiJpe rnir 37,i
5uorfisrdfi 8 lJn:rfl?t 2555 \s>'-:T::::ff:,1:l:*'":"J:*: t2nl ll'00- l2'30 lt'
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